TY  - JOUR
AU  - Vodnik, Vesna
AU  - Božanić, Dušan K.
AU  - Džunuzović, Enis
AU  - Vuković, J.
AU  - Nedeljković, Jovan
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1678
AB  - Surface modified silver nanoparticles dispersed in chloroform were encapsulated in poly(methylmethacrylate) (PMMA) by in-situ radical polymerization of methyl methacrylate initiated by 2,2'-azobisisobutyronitrile. The particle size distribution of colloidal silver nanoparticles was determined using transmission electron microscopy. The obtained transparent nanocomposite films were characterized using UV-vis spectroscopy, H-1 NMR spectroscopy and gel permeation chromatography. Effective medium Maxwell-Garnett theory was used in order to explain optical properties of nanocomposite films taking into account inhomogeneous spatial distribution of silver nanoparticles in PMMA matrix. The influence of the silver nanoparticles on the thermal properties of the PMMA matrix was investigated using thermo-gravimetric analysis and differential scanning calorimetry. Thermo-oxidative stability of the PMMA in the presence of low content of inorganic phase is significantly improved. The glass transition temperatures of nanocomposites are slightly lower compared to the pure polymer.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - European Polymer Journal
T1  - Thermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerization
EP  - 144
IS  - 2
SP  - 137
VL  - 46
DO  - 10.1016/j.eurpolymj.2009.10.022
ER  - 

@article{
author = "Vodnik, Vesna and Božanić, Dušan K. and Džunuzović, Enis and Vuković, J. and Nedeljković, Jovan",
year = "2010",
abstract = "Surface modified silver nanoparticles dispersed in chloroform were encapsulated in poly(methylmethacrylate) (PMMA) by in-situ radical polymerization of methyl methacrylate initiated by 2,2'-azobisisobutyronitrile. The particle size distribution of colloidal silver nanoparticles was determined using transmission electron microscopy. The obtained transparent nanocomposite films were characterized using UV-vis spectroscopy, H-1 NMR spectroscopy and gel permeation chromatography. Effective medium Maxwell-Garnett theory was used in order to explain optical properties of nanocomposite films taking into account inhomogeneous spatial distribution of silver nanoparticles in PMMA matrix. The influence of the silver nanoparticles on the thermal properties of the PMMA matrix was investigated using thermo-gravimetric analysis and differential scanning calorimetry. Thermo-oxidative stability of the PMMA in the presence of low content of inorganic phase is significantly improved. The glass transition temperatures of nanocomposites are slightly lower compared to the pure polymer.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Thermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerization",
pages = "144-137",
number = "2",
volume = "46",
doi = "10.1016/j.eurpolymj.2009.10.022"
}

Vodnik, V., Božanić, D. K., Džunuzović, E., Vuković, J.,& Nedeljković, J.. (2010). Thermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerization. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 46(2), 137-144.
https://doi.org/10.1016/j.eurpolymj.2009.10.022

Vodnik V, Božanić DK, Džunuzović E, Vuković J, Nedeljković J. Thermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerization. in European Polymer Journal. 2010;46(2):137-144.
doi:10.1016/j.eurpolymj.2009.10.022 .

Vodnik, Vesna, Božanić, Dušan K., Džunuzović, Enis, Vuković, J., Nedeljković, Jovan, "Thermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerization" in European Polymer Journal, 46, no. 2 (2010):137-144,
https://doi.org/10.1016/j.eurpolymj.2009.10.022 . .

TY  - JOUR
AU  - Džunuzović, Enis
AU  - Marinović-Cincović, Milena
AU  - Vuković, J.
AU  - Jeremić, Katarina B.
AU  - Nedeljković, Jovan
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1524
AB  - The surface of anatase TiO2 nanoparticles, obtained by the controlled hydrolysis of titanium tetrachloride, was modified by 6-palmitate ascorbic acid. The surface modified TiO2 nanoparticles were dispersed in methyl methacrylate and mixed with a appropriate amount of poly(methyl methacrylate) to obtain a syrup. The nano-composite sheets were made by bulk polymerization of the syrup in a glass sandwich cell using 2,2'-azobisisobutyronitrile as initiator. The molar masses and molar mass distributions of synthesized poly(methyl methacrylate) samples were determined by gel permeation chromatography. The content of unreacted double bonds in synthesized samples was determined by H-1 NMR spectroscopy. The influence of TiO2 nanoparticles on the thermal stability of the poly(methyl methacrylate) matrix was investigated using thermogravimetric analysis and differential scanning calorimetry. The synthesized samples of poly(methyl methacrylate) have different molar mass and polydispersity depending on the content of the surface modified TiO2 nanoparticles. The values of glass transition temperature of so prepared nanocomposite samples were lower than for pure poly(methyl methacrylate), while the glass transition temperature of samples preheated in inert atmosphere was very similar to the glass transition temperature of pure poly(methyl methacrylate). The thermal stability of nanocomposite samples in nitrogen and air was different from thermal stability of pure poly(methyl methacrylate). POLYM. COMPOS., 30:737-742, 2009.
PB  - Wiley-Blackwell, Malden
T2  - Polymer Composites
T1  - Thermal Properties of PMMA/TiO2 Nanocomposites Prepared by In-Situ Bulk Polymerization
EP  - 742
IS  - 6
SP  - 737
VL  - 30
DO  - 10.1002/pc.20606
ER  - 

@article{
author = "Džunuzović, Enis and Marinović-Cincović, Milena and Vuković, J. and Jeremić, Katarina B. and Nedeljković, Jovan",
year = "2009",
abstract = "The surface of anatase TiO2 nanoparticles, obtained by the controlled hydrolysis of titanium tetrachloride, was modified by 6-palmitate ascorbic acid. The surface modified TiO2 nanoparticles were dispersed in methyl methacrylate and mixed with a appropriate amount of poly(methyl methacrylate) to obtain a syrup. The nano-composite sheets were made by bulk polymerization of the syrup in a glass sandwich cell using 2,2'-azobisisobutyronitrile as initiator. The molar masses and molar mass distributions of synthesized poly(methyl methacrylate) samples were determined by gel permeation chromatography. The content of unreacted double bonds in synthesized samples was determined by H-1 NMR spectroscopy. The influence of TiO2 nanoparticles on the thermal stability of the poly(methyl methacrylate) matrix was investigated using thermogravimetric analysis and differential scanning calorimetry. The synthesized samples of poly(methyl methacrylate) have different molar mass and polydispersity depending on the content of the surface modified TiO2 nanoparticles. The values of glass transition temperature of so prepared nanocomposite samples were lower than for pure poly(methyl methacrylate), while the glass transition temperature of samples preheated in inert atmosphere was very similar to the glass transition temperature of pure poly(methyl methacrylate). The thermal stability of nanocomposite samples in nitrogen and air was different from thermal stability of pure poly(methyl methacrylate). POLYM. COMPOS., 30:737-742, 2009.",
publisher = "Wiley-Blackwell, Malden",
journal = "Polymer Composites",
title = "Thermal Properties of PMMA/TiO2 Nanocomposites Prepared by In-Situ Bulk Polymerization",
pages = "742-737",
number = "6",
volume = "30",
doi = "10.1002/pc.20606"
}

Džunuzović, E., Marinović-Cincović, M., Vuković, J., Jeremić, K. B.,& Nedeljković, J.. (2009). Thermal Properties of PMMA/TiO2 Nanocomposites Prepared by In-Situ Bulk Polymerization. in Polymer Composites
Wiley-Blackwell, Malden., 30(6), 737-742.
https://doi.org/10.1002/pc.20606

Džunuzović E, Marinović-Cincović M, Vuković J, Jeremić KB, Nedeljković J. Thermal Properties of PMMA/TiO2 Nanocomposites Prepared by In-Situ Bulk Polymerization. in Polymer Composites. 2009;30(6):737-742.
doi:10.1002/pc.20606 .

Džunuzović, Enis, Marinović-Cincović, Milena, Vuković, J., Jeremić, Katarina B., Nedeljković, Jovan, "Thermal Properties of PMMA/TiO2 Nanocomposites Prepared by In-Situ Bulk Polymerization" in Polymer Composites, 30, no. 6 (2009):737-742,
https://doi.org/10.1002/pc.20606 . .

TY  - JOUR
AU  - Džunuzović, Enis
AU  - Marinović-Cincović, Milena
AU  - Jeremić, Katarina B.
AU  - Vuković, J.
AU  - Nedeljković, Jovan
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1267
AB  - alpha-Fe2O3 nanorods were incorporated into poly(methyl methacrylate) (PMMA) by in situ radical polymerisation of methyl methacrylate initiated by 2,2 '-azobisisobutyronitrile. The alpha-Fe2O3 nanorods were synthesized by forced hydrolysis of FeCl3 and structural characterization was performed by X-ray diffraction and transmission electron microscopy. The molar mass and the polydispersity index of synthesized PMMA samples were determined by gel permeation chromatography. The content of residual monomer was determined by H-1 NMR spectroscopy. The influence of alpha-Fe2O3 nanorods on the thermal stability of the polymer was investigated using thermogravimetry and differential scanning calorimetry. The molar mass and polydispersity index of PMMA were dependent on the content of alpha-Fe2O3 nanorods. The values of the glass transition temperature of the nanocomposites were lower compared to pure PMMA. Also, the thermal stability of nanocomposites in nitrogen and air was different from that of pure PMMA.
PB  - Elsevier Sci Ltd, Oxford
T2  - Polymer Degradation and Stability
T1  - Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate
EP  - 83
IS  - 1
SP  - 77
VL  - 93
DO  - 10.1016/j.polymdegradstab.2007.10.015
ER  - 

@article{
author = "Džunuzović, Enis and Marinović-Cincović, Milena and Jeremić, Katarina B. and Vuković, J. and Nedeljković, Jovan",
year = "2008",
abstract = "alpha-Fe2O3 nanorods were incorporated into poly(methyl methacrylate) (PMMA) by in situ radical polymerisation of methyl methacrylate initiated by 2,2 '-azobisisobutyronitrile. The alpha-Fe2O3 nanorods were synthesized by forced hydrolysis of FeCl3 and structural characterization was performed by X-ray diffraction and transmission electron microscopy. The molar mass and the polydispersity index of synthesized PMMA samples were determined by gel permeation chromatography. The content of residual monomer was determined by H-1 NMR spectroscopy. The influence of alpha-Fe2O3 nanorods on the thermal stability of the polymer was investigated using thermogravimetry and differential scanning calorimetry. The molar mass and polydispersity index of PMMA were dependent on the content of alpha-Fe2O3 nanorods. The values of the glass transition temperature of the nanocomposites were lower compared to pure PMMA. Also, the thermal stability of nanocomposites in nitrogen and air was different from that of pure PMMA.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Polymer Degradation and Stability",
title = "Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate",
pages = "83-77",
number = "1",
volume = "93",
doi = "10.1016/j.polymdegradstab.2007.10.015"
}

Džunuzović, E., Marinović-Cincović, M., Jeremić, K. B., Vuković, J.,& Nedeljković, J.. (2008). Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate. in Polymer Degradation and Stability
Elsevier Sci Ltd, Oxford., 93(1), 77-83.
https://doi.org/10.1016/j.polymdegradstab.2007.10.015

Džunuzović E, Marinović-Cincović M, Jeremić KB, Vuković J, Nedeljković J. Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate. in Polymer Degradation and Stability. 2008;93(1):77-83.
doi:10.1016/j.polymdegradstab.2007.10.015 .

Džunuzović, Enis, Marinović-Cincović, Milena, Jeremić, Katarina B., Vuković, J., Nedeljković, Jovan, "Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate" in Polymer Degradation and Stability, 93, no. 1 (2008):77-83,
https://doi.org/10.1016/j.polymdegradstab.2007.10.015 . .