TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Stojmenović, Marija
AU  - Rosić, Milena
AU  - Vasić, Andrijana
AU  - Ristović, Ivica
AU  - Janković-Častvan, Ivona
AU  - Kragović, Milan
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7472
AB  - The possibility of using waste tailings produced by flotation in the lead and zinc mine of Grot, Serbia as a potential source of secondary mineral raw materials was examined. The aim of the research was primarily to carry out a detailed characterization in order to determine the dominant minerals, and, for the first time, to trace the changes occurring in the unit cells of the minerals present in that deposit. There was also a need to determine the exact proportions of the present mineral phases for their further application and utilization as natural resources in environmental protection. Samples were taken from three different sections of tailings: the crest of dam (JKB), outlet pipe of the flotation facility (JOF) and hydrocyclone overflow (JHC). Granulometric separation was performed to facilitate the extraction of certain minerals from waste. The results showed that all samples mainly contained quartz, clinochlore, calcite, albite, pyrite and biotite, but their ratios in each sample varied significantly. After characterization, samples were separated into different fractions and their mineralogical compositions were determined. Depending on the fraction, the mineralogical compositions also changed. Mineralogy and geochemical analysis indicate that waste tailings can be used as a secondary mineral raw materials source applicable in various industries.
PB  - MDPI
T2  - Applied Sciences
T1  - Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material
IS  - 3
SP  - 1167
VL  - 14
DO  - 10.3390/app14031167
ER  - 

@article{
author = "Gulicovski, Jelena and Stojmenović, Marija and Rosić, Milena and Vasić, Andrijana and Ristović, Ivica and Janković-Častvan, Ivona and Kragović, Milan",
year = "2024",
abstract = "The possibility of using waste tailings produced by flotation in the lead and zinc mine of Grot, Serbia as a potential source of secondary mineral raw materials was examined. The aim of the research was primarily to carry out a detailed characterization in order to determine the dominant minerals, and, for the first time, to trace the changes occurring in the unit cells of the minerals present in that deposit. There was also a need to determine the exact proportions of the present mineral phases for their further application and utilization as natural resources in environmental protection. Samples were taken from three different sections of tailings: the crest of dam (JKB), outlet pipe of the flotation facility (JOF) and hydrocyclone overflow (JHC). Granulometric separation was performed to facilitate the extraction of certain minerals from waste. The results showed that all samples mainly contained quartz, clinochlore, calcite, albite, pyrite and biotite, but their ratios in each sample varied significantly. After characterization, samples were separated into different fractions and their mineralogical compositions were determined. Depending on the fraction, the mineralogical compositions also changed. Mineralogy and geochemical analysis indicate that waste tailings can be used as a secondary mineral raw materials source applicable in various industries.",
publisher = "MDPI",
journal = "Applied Sciences",
title = "Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material",
number = "3",
pages = "1167",
volume = "14",
doi = "10.3390/app14031167"
}

Gulicovski, J., Stojmenović, M., Rosić, M., Vasić, A., Ristović, I., Janković-Častvan, I.,& Kragović, M.. (2024). Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material. in Applied Sciences
MDPI., 14(3), 1167.
https://doi.org/10.3390/app14031167

Gulicovski J, Stojmenović M, Rosić M, Vasić A, Ristović I, Janković-Častvan I, Kragović M. Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material. in Applied Sciences. 2024;14(3):1167.
doi:10.3390/app14031167 .

Gulicovski, Jelena, Stojmenović, Marija, Rosić, Milena, Vasić, Andrijana, Ristović, Ivica, Janković-Častvan, Ivona, Kragović, Milan, "Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material" in Applied Sciences, 14, no. 3 (2024):1167,
https://doi.org/10.3390/app14031167 . .

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Kragović, Milan
AU  - Nikolić, Katarina
AU  - Rosić, Milena
AU  - Ristić, Nenad
AU  - Janković-Častvan, Ivona
AU  - Stojmenović, Marija
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6588
AB  - Waste vitreous enamels from the heating device production process were used for partial replacement of cement in the mortar and concrete production industry. This waste, due to the high content of heavy metals, is classified as hazardous waste. At the same time, waste vitreous enamels possess pozzolanic activity and belong to class 15 (WEP—generated during the production process of heating devices, premix technology), that is 5 (WETM—generated during the production process of heating devices, classic technology) of pozzolanic materials. The purpose of this research was to develop new composites from these wastes to reduce the deposition of the toxic compounds and reduce their environmental impact. The chemical and physical-chemical characterization and pozzolanic activity of the raw waste materials were studied by a mixture of complementary methods, as well as physical-mechanical characterization and a leaching test of mortar and concrete composites. The results indicate that the replacement of cement with WEP up to 30%, or with WETM up to 20% does not significantly affect the quality of concrete in comparison to the quality of the reference concrete prepared with 100% cement. The leaching test showed no significant release of toxic elements for both obtained composites.
PB  - MDPI
T2  - Applied Sciences (Switzerland)
T1  - Possibility of Using Vitreous Enamel Waste in the Construction Industry as the Concept of Cleaner Production
IS  - 14
SP  - 8215
VL  - 13
DO  - 10.3390/app13148215
ER  - 

@article{
author = "Gulicovski, Jelena and Kragović, Milan and Nikolić, Katarina and Rosić, Milena and Ristić, Nenad and Janković-Častvan, Ivona and Stojmenović, Marija",
year = "2023",
abstract = "Waste vitreous enamels from the heating device production process were used for partial replacement of cement in the mortar and concrete production industry. This waste, due to the high content of heavy metals, is classified as hazardous waste. At the same time, waste vitreous enamels possess pozzolanic activity and belong to class 15 (WEP—generated during the production process of heating devices, premix technology), that is 5 (WETM—generated during the production process of heating devices, classic technology) of pozzolanic materials. The purpose of this research was to develop new composites from these wastes to reduce the deposition of the toxic compounds and reduce their environmental impact. The chemical and physical-chemical characterization and pozzolanic activity of the raw waste materials were studied by a mixture of complementary methods, as well as physical-mechanical characterization and a leaching test of mortar and concrete composites. The results indicate that the replacement of cement with WEP up to 30%, or with WETM up to 20% does not significantly affect the quality of concrete in comparison to the quality of the reference concrete prepared with 100% cement. The leaching test showed no significant release of toxic elements for both obtained composites.",
publisher = "MDPI",
journal = "Applied Sciences (Switzerland)",
title = "Possibility of Using Vitreous Enamel Waste in the Construction Industry as the Concept of Cleaner Production",
number = "14",
pages = "8215",
volume = "13",
doi = "10.3390/app13148215"
}

Gulicovski, J., Kragović, M., Nikolić, K., Rosić, M., Ristić, N., Janković-Častvan, I.,& Stojmenović, M.. (2023). Possibility of Using Vitreous Enamel Waste in the Construction Industry as the Concept of Cleaner Production. in Applied Sciences (Switzerland)
MDPI., 13(14), 8215.
https://doi.org/10.3390/app13148215

Gulicovski J, Kragović M, Nikolić K, Rosić M, Ristić N, Janković-Častvan I, Stojmenović M. Possibility of Using Vitreous Enamel Waste in the Construction Industry as the Concept of Cleaner Production. in Applied Sciences (Switzerland). 2023;13(14):8215.
doi:10.3390/app13148215 .

Gulicovski, Jelena, Kragović, Milan, Nikolić, Katarina, Rosić, Milena, Ristić, Nenad, Janković-Častvan, Ivona, Stojmenović, Marija, "Possibility of Using Vitreous Enamel Waste in the Construction Industry as the Concept of Cleaner Production" in Applied Sciences (Switzerland), 13, no. 14 (2023):8215,
https://doi.org/10.3390/app13148215 . .

TY  - JOUR
AU  - Pantić, Jelena R.
AU  - Urbanovich, Vladimir
AU  - Poharc-Logar, Vesna
AU  - Jokić, Bojan M.
AU  - Stojmenović, Marija
AU  - Kremenović, Aleksandar S.
AU  - Matović, Branko
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5789
AB  - Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 A degrees C, sphene undergoes into phase transition, from room-temperature phase P2(1) /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy.
PB  - Springer Verlag
T2  - Physics and Chemistry of Minerals
T1  - Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)
EP  - 782
IS  - 10
SP  - 775
VL  - 41
DO  - 10.1007/s00269-014-0693-x
ER  - 

@article{
author = "Pantić, Jelena R. and Urbanovich, Vladimir and Poharc-Logar, Vesna and Jokić, Bojan M. and Stojmenović, Marija and Kremenović, Aleksandar S. and Matović, Branko",
year = "2014",
abstract = "Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 A degrees C, sphene undergoes into phase transition, from room-temperature phase P2(1) /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy.",
publisher = "Springer Verlag",
journal = "Physics and Chemistry of Minerals",
title = "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)",
pages = "782-775",
number = "10",
volume = "41",
doi = "10.1007/s00269-014-0693-x"
}

Pantić, J. R., Urbanovich, V., Poharc-Logar, V., Jokić, B. M., Stojmenović, M., Kremenović, A. S.,& Matović, B.. (2014). Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5). in Physics and Chemistry of Minerals
Springer Verlag., 41(10), 775-782.
https://doi.org/10.1007/s00269-014-0693-x

Pantić JR, Urbanovich V, Poharc-Logar V, Jokić BM, Stojmenović M, Kremenović AS, Matović B. Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5). in Physics and Chemistry of Minerals. 2014;41(10):775-782.
doi:10.1007/s00269-014-0693-x .

Pantić, Jelena R., Urbanovich, Vladimir, Poharc-Logar, Vesna, Jokić, Bojan M., Stojmenović, Marija, Kremenović, Aleksandar S., Matović, Branko, "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)" in Physics and Chemistry of Minerals, 41, no. 10 (2014):775-782,
https://doi.org/10.1007/s00269-014-0693-x . .