Pijovic, Milena

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  • Pijovic, Milena (1)
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Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study

Pijovic, Milena; Manic, Nebojsa; Vasic-Anicijevic, Dragana; Krstic, Aleksandar; Mitric, Miodrag; Matić, Tamara; Jankovic, Bojan

(2022)

TY  - JOUR
AU  - Pijovic, Milena
AU  - Manic, Nebojsa
AU  - Vasic-Anicijevic, Dragana
AU  - Krstic, Aleksandar
AU  - Mitric, Miodrag
AU  - Matić, Tamara
AU  - Jankovic, Bojan
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5015
AB  - Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.
T2  - Diamond and Related Materials
T1  - Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study
VL  - 121
DO  - 10.1016/j.diamond.2021.108768
ER  - 
@article{
author = "Pijovic, Milena and Manic, Nebojsa and Vasic-Anicijevic, Dragana and Krstic, Aleksandar and Mitric, Miodrag and Matić, Tamara and Jankovic, Bojan",
year = "2022",
abstract = "Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 degrees C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2.g- 1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from pi-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.",
journal = "Diamond and Related Materials",
title = "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study",
volume = "121",
doi = "10.1016/j.diamond.2021.108768"
}
Pijovic, M., Manic, N., Vasic-Anicijevic, D., Krstic, A., Mitric, M., Matić, T.,& Jankovic, B.. (2022). Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials, 121.
https://doi.org/10.1016/j.diamond.2021.108768
Pijovic M, Manic N, Vasic-Anicijevic D, Krstic A, Mitric M, Matić T, Jankovic B. Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials. 2022;121.
doi:10.1016/j.diamond.2021.108768 .
Pijovic, Milena, Manic, Nebojsa, Vasic-Anicijevic, Dragana, Krstic, Aleksandar, Mitric, Miodrag, Matić, Tamara, Jankovic, Bojan, "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study" in Diamond and Related Materials, 121 (2022),
https://doi.org/10.1016/j.diamond.2021.108768 . .
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