Milosavljević, Milutin

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Authority KeyName Variants
14cae731-b636-4308-80f8-c2b24fdcfabe
  • Milosavljević, Milutin (10)
  • Milosavljević, Milutin M. (1)
Projects

Author's Bibliography

Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation

Vuksanović, Marija M.; Milošević, Milena; Dimitrijević, Ivan; Milentijević, Gordana; Babincev, Ljiljana; Gržetić, Jelena; Marinković, Aleksandar; Milosavljević, Milutin

(MDPI, 2024)

TY  - JOUR
AU  - Vuksanović, Marija M.
AU  - Milošević, Milena
AU  - Dimitrijević, Ivan
AU  - Milentijević, Gordana
AU  - Babincev, Ljiljana
AU  - Gržetić, Jelena
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7424
AB  - The increase in waste polymer recycling has helped in promoting sustainability, and together with the use of renewable raw materials, it has become a widespread concept with positive effects on both the economy and ecology. Accordingly, the aim of this study was the synthesis of “green” plasticizers, marked as LA/PG/PET/EG/LA, formed from waste poly(ethylene terephthalate) (PET) and bio-based platform chemicals propylene glycol (PG) and levulinic acid (LA). The structure of the obtained plasticizers was complex, as confirmed by results from nuclear magnetic resonance (NMR) and Fourier-transform infrared spectroscopy (FTIR) analysis. The LA/PG/PET/EG/LA plasticizers and waste poly(vinyl chloride) (PVC) were used in an optimized technology for PVC re-granulate production. The hardness of the PVC-based material with “green” plasticizers, in comparison to commercial plasticizer dioctyl terephthalate (DOTP), increased by 11.3%, while migration decreased. An improved material homogeneity and wettability of the fibers by the matrix were observed using SEM analysis of the material’s fracture surface, with a higher efficiency of intermolecular interactions leading to better mechanical performances of the newly designed materials. Thus, LA/PG/PET/EG/LA are unique materials with good compounding and plasticizing potential for PVC, as revealed by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). In that manner, the use of bio-renewable resources and recycled polymers will contribute to diminishing waste polymer generation, contributing to a lower carbon footprint.
PB  - MDPI
T2  - Processes
T1  - Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation
IS  - 3
SP  - 520
VL  - 12
DO  - 10.3390/pr12030520
ER  - 
@article{
author = "Vuksanović, Marija M. and Milošević, Milena and Dimitrijević, Ivan and Milentijević, Gordana and Babincev, Ljiljana and Gržetić, Jelena and Marinković, Aleksandar and Milosavljević, Milutin",
year = "2024",
abstract = "The increase in waste polymer recycling has helped in promoting sustainability, and together with the use of renewable raw materials, it has become a widespread concept with positive effects on both the economy and ecology. Accordingly, the aim of this study was the synthesis of “green” plasticizers, marked as LA/PG/PET/EG/LA, formed from waste poly(ethylene terephthalate) (PET) and bio-based platform chemicals propylene glycol (PG) and levulinic acid (LA). The structure of the obtained plasticizers was complex, as confirmed by results from nuclear magnetic resonance (NMR) and Fourier-transform infrared spectroscopy (FTIR) analysis. The LA/PG/PET/EG/LA plasticizers and waste poly(vinyl chloride) (PVC) were used in an optimized technology for PVC re-granulate production. The hardness of the PVC-based material with “green” plasticizers, in comparison to commercial plasticizer dioctyl terephthalate (DOTP), increased by 11.3%, while migration decreased. An improved material homogeneity and wettability of the fibers by the matrix were observed using SEM analysis of the material’s fracture surface, with a higher efficiency of intermolecular interactions leading to better mechanical performances of the newly designed materials. Thus, LA/PG/PET/EG/LA are unique materials with good compounding and plasticizing potential for PVC, as revealed by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). In that manner, the use of bio-renewable resources and recycled polymers will contribute to diminishing waste polymer generation, contributing to a lower carbon footprint.",
publisher = "MDPI",
journal = "Processes",
title = "Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation",
number = "3",
pages = "520",
volume = "12",
doi = "10.3390/pr12030520"
}
Vuksanović, M. M., Milošević, M., Dimitrijević, I., Milentijević, G., Babincev, L., Gržetić, J., Marinković, A.,& Milosavljević, M.. (2024). Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation. in Processes
MDPI., 12(3), 520.
https://doi.org/10.3390/pr12030520
Vuksanović MM, Milošević M, Dimitrijević I, Milentijević G, Babincev L, Gržetić J, Marinković A, Milosavljević M. Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation. in Processes. 2024;12(3):520.
doi:10.3390/pr12030520 .
Vuksanović, Marija M., Milošević, Milena, Dimitrijević, Ivan, Milentijević, Gordana, Babincev, Ljiljana, Gržetić, Jelena, Marinković, Aleksandar, Milosavljević, Milutin, "Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation" in Processes, 12, no. 3 (2024):520,
https://doi.org/10.3390/pr12030520 . .

One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production

Milentijević, Goran; Milošević, Milena; Milojević, Svetomir; Marković, Smiljana; Rančić, Milica; Marinković, Aleksandar; Milosavljević, Milutin

(MDPI, 2023)

TY  - JOUR
AU  - Milentijević, Goran
AU  - Milošević, Milena
AU  - Milojević, Svetomir
AU  - Marković, Smiljana
AU  - Rančić, Milica
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6375
AB  - Styrene-butadiene (SBR) and acrylonitrile-butadiene (NBR) rubber blends with tetramethyl thiuram disulfide (TMTD) and tetramethyl thiuram monosulfide (TMTS) accelerators and environmentally friendly plasticizers, obtained from PET recycling and biobased resources (LA/PG/PET/EG/LA), were prepared. The mechanical properties of the obtained rubber products were tested and compared with those of commercial dioctyl terephthalate (DOTP). TMTS was prepared by simple and efficient one-pot synthesis from dimethylamine, carbon disulfide, potassium cyanide, and ammonium chloride as catalysts in recycled isopropanol/water azeotrope as solvent. In a comparative study, methoxide, ethoxide, iodide, and amide ions were also used. The two-step reaction mechanism of TMTS synthesis involves the oxidation of the amine salt of dimethyldithiocarbamic acid to TMTD by hydrogen peroxide and sulfur elimination from the TMTD disulfide bond. Potassium cyanide appears to be the most efficient nucleophile. The simplicity of operation, mild reaction conditions, solvent recycling, high yields, and applicability to the industrial level are the advantages of this process. Shore hardness, tensile strength, and compression test results of vulcanized blends before and after aging showed similar properties for both accelerators, while somewhat better results were obtained with LA/PG/PET/EG/LA plasticizer.
PB  - MDPI
T2  - Processes
T1  - One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production
IS  - 4
SP  - 1033
VL  - 11
DO  - 10.3390/pr11041033
ER  - 
@article{
author = "Milentijević, Goran and Milošević, Milena and Milojević, Svetomir and Marković, Smiljana and Rančić, Milica and Marinković, Aleksandar and Milosavljević, Milutin",
year = "2023",
abstract = "Styrene-butadiene (SBR) and acrylonitrile-butadiene (NBR) rubber blends with tetramethyl thiuram disulfide (TMTD) and tetramethyl thiuram monosulfide (TMTS) accelerators and environmentally friendly plasticizers, obtained from PET recycling and biobased resources (LA/PG/PET/EG/LA), were prepared. The mechanical properties of the obtained rubber products were tested and compared with those of commercial dioctyl terephthalate (DOTP). TMTS was prepared by simple and efficient one-pot synthesis from dimethylamine, carbon disulfide, potassium cyanide, and ammonium chloride as catalysts in recycled isopropanol/water azeotrope as solvent. In a comparative study, methoxide, ethoxide, iodide, and amide ions were also used. The two-step reaction mechanism of TMTS synthesis involves the oxidation of the amine salt of dimethyldithiocarbamic acid to TMTD by hydrogen peroxide and sulfur elimination from the TMTD disulfide bond. Potassium cyanide appears to be the most efficient nucleophile. The simplicity of operation, mild reaction conditions, solvent recycling, high yields, and applicability to the industrial level are the advantages of this process. Shore hardness, tensile strength, and compression test results of vulcanized blends before and after aging showed similar properties for both accelerators, while somewhat better results were obtained with LA/PG/PET/EG/LA plasticizer.",
publisher = "MDPI",
journal = "Processes",
title = "One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production",
number = "4",
pages = "1033",
volume = "11",
doi = "10.3390/pr11041033"
}
Milentijević, G., Milošević, M., Milojević, S., Marković, S., Rančić, M., Marinković, A.,& Milosavljević, M.. (2023). One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production. in Processes
MDPI., 11(4), 1033.
https://doi.org/10.3390/pr11041033
Milentijević G, Milošević M, Milojević S, Marković S, Rančić M, Marinković A, Milosavljević M. One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production. in Processes. 2023;11(4):1033.
doi:10.3390/pr11041033 .
Milentijević, Goran, Milošević, Milena, Milojević, Svetomir, Marković, Smiljana, Rančić, Milica, Marinković, Aleksandar, Milosavljević, Milutin, "One-Pot Syntheses of PET-Based Plasticizer and Tetramethyl Thiuram Monosulfide (TMTS) as Vulcanization Accelerator for Rubber Production" in Processes, 11, no. 4 (2023):1033,
https://doi.org/10.3390/pr11041033 . .
1
1

Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials

Marinković, Aleksandar; Milosavljević, Milutin; Kovačević, Tihomir; Kovačina, Jovanka; Milošević, Milena D.; Jovanović, Aleksandar; Petrović, Slobodan

(OOO «Centr «AЮMЭLЬ», 2020)

TY  - CONF
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
AU  - Kovačević, Tihomir
AU  - Kovačina, Jovanka
AU  - Milošević, Milena D.
AU  - Jovanović, Aleksandar
AU  - Petrović, Slobodan
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4421
AB  - Innovative technology has been developed for the production of gelcoat and materials of reduced flammability based on unsaturated polyester resins. These materials were synthesized from raw materials obtained from waste poly(ethylene terephthalate) (PET) and bio-renewable resources. The presented technologies respect the environmental legislative as well as the principles of green and circular economy. Resulting products can be applied in various industries (construction/building, mining, polymer processing etc.).
PB  - OOO «Centr «AЮMЭLЬ»
C3  - Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the
T1  - Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials
EP  - 180
SP  - 179
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4421
ER  - 
@conference{
author = "Marinković, Aleksandar and Milosavljević, Milutin and Kovačević, Tihomir and Kovačina, Jovanka and Milošević, Milena D. and Jovanović, Aleksandar and Petrović, Slobodan",
year = "2020",
abstract = "Innovative technology has been developed for the production of gelcoat and materials of reduced flammability based on unsaturated polyester resins. These materials were synthesized from raw materials obtained from waste poly(ethylene terephthalate) (PET) and bio-renewable resources. The presented technologies respect the environmental legislative as well as the principles of green and circular economy. Resulting products can be applied in various industries (construction/building, mining, polymer processing etc.).",
publisher = "OOO «Centr «AЮMЭLЬ»",
journal = "Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the",
title = "Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials",
pages = "180-179",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4421"
}
Marinković, A., Milosavljević, M., Kovačević, T., Kovačina, J., Milošević, M. D., Jovanović, A.,& Petrović, S.. (2020). Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials. in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the
OOO «Centr «AЮMЭLЬ»., 179-180.
https://hdl.handle.net/21.15107/rcub_technorep_4421
Marinković A, Milosavljević M, Kovačević T, Kovačina J, Milošević MD, Jovanović A, Petrović S. Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials. in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the. 2020;:179-180.
https://hdl.handle.net/21.15107/rcub_technorep_4421 .
Marinković, Aleksandar, Milosavljević, Milutin, Kovačević, Tihomir, Kovačina, Jovanka, Milošević, Milena D., Jovanović, Aleksandar, Petrović, Slobodan, "Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials" in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the (2020):179-180,
https://hdl.handle.net/21.15107/rcub_technorep_4421 .

Innovative environmentally friendly technology for copper(II) hydroxide production

Milosavljević, Milutin; Babincev, Ljiljana M.; Belošević, Svetlana; Daničić, Dunja; Milošević, Milena D.; Rusmirović, Jelena; Marinković, Aleksandar

(Savez hemijskih inženjera, Beograd, 2018)

TY  - JOUR
AU  - Milosavljević, Milutin
AU  - Babincev, Ljiljana M.
AU  - Belošević, Svetlana
AU  - Daničić, Dunja
AU  - Milošević, Milena D.
AU  - Rusmirović, Jelena
AU  - Marinković, Aleksandar
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3903
AB  - The innovative laboratory procedure for the synthesis of copper(II) hydroxide in the form of the aqueous suspension was developed. The reaction mechanism consists of the reaction between copper(II) sulphate pentahydrate and sodium carbonate by successive ion exchange of carbonate ions with the hydroxide ones in a multistep process. Production of copper(II) carbonate and sodium sulphate by reacting of copper(II) sulphate with sodium carbonate was followed by addition of sodium hydroxide solution whereby the product, copper(II) hydroxide, was obtained by releasing an equimolar amount of sodium carbonate. It was determined that, the equimolar reaction of copper(II) sulphate and sodium hydroxide lead to the maximal reactants exploitation. Sodium phosphate, formed in the final process stage by addition of 10% phosphoric acid solution, acted as a copper(II) hydroxide stabilizer. High yield of the product was obtained by optimizing the synthesis parameters: reaction time, molar ratio of reactants and the reaction temperature. The obtained product was formulated to obtain a commercial product, which is used as a fungicide and bactericide.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Innovative environmentally friendly technology for copper(II) hydroxide production
EP  - 370
IS  - 6
SP  - 363
VL  - 72
DO  - 10.2298/HEMIND180630023M
ER  - 
@article{
author = "Milosavljević, Milutin and Babincev, Ljiljana M. and Belošević, Svetlana and Daničić, Dunja and Milošević, Milena D. and Rusmirović, Jelena and Marinković, Aleksandar",
year = "2018",
abstract = "The innovative laboratory procedure for the synthesis of copper(II) hydroxide in the form of the aqueous suspension was developed. The reaction mechanism consists of the reaction between copper(II) sulphate pentahydrate and sodium carbonate by successive ion exchange of carbonate ions with the hydroxide ones in a multistep process. Production of copper(II) carbonate and sodium sulphate by reacting of copper(II) sulphate with sodium carbonate was followed by addition of sodium hydroxide solution whereby the product, copper(II) hydroxide, was obtained by releasing an equimolar amount of sodium carbonate. It was determined that, the equimolar reaction of copper(II) sulphate and sodium hydroxide lead to the maximal reactants exploitation. Sodium phosphate, formed in the final process stage by addition of 10% phosphoric acid solution, acted as a copper(II) hydroxide stabilizer. High yield of the product was obtained by optimizing the synthesis parameters: reaction time, molar ratio of reactants and the reaction temperature. The obtained product was formulated to obtain a commercial product, which is used as a fungicide and bactericide.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Innovative environmentally friendly technology for copper(II) hydroxide production",
pages = "370-363",
number = "6",
volume = "72",
doi = "10.2298/HEMIND180630023M"
}
Milosavljević, M., Babincev, L. M., Belošević, S., Daničić, D., Milošević, M. D., Rusmirović, J.,& Marinković, A.. (2018). Innovative environmentally friendly technology for copper(II) hydroxide production. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 72(6), 363-370.
https://doi.org/10.2298/HEMIND180630023M
Milosavljević M, Babincev LM, Belošević S, Daničić D, Milošević MD, Rusmirović J, Marinković A. Innovative environmentally friendly technology for copper(II) hydroxide production. in Hemijska industrija. 2018;72(6):363-370.
doi:10.2298/HEMIND180630023M .
Milosavljević, Milutin, Babincev, Ljiljana M., Belošević, Svetlana, Daničić, Dunja, Milošević, Milena D., Rusmirović, Jelena, Marinković, Aleksandar, "Innovative environmentally friendly technology for copper(II) hydroxide production" in Hemijska industrija, 72, no. 6 (2018):363-370,
https://doi.org/10.2298/HEMIND180630023M . .

Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes

Budimirović, Dragoslav; Veličković, Zlate; Đokić, Veljko; Milosavljević, Milutin; Markovski, Jasmina; Lević, Steva; Marinković, Aleksandar

(Inst Chemical Engineers, Rugby, 2017)

TY  - JOUR
AU  - Budimirović, Dragoslav
AU  - Veličković, Zlate
AU  - Đokić, Veljko
AU  - Milosavljević, Milutin
AU  - Markovski, Jasmina
AU  - Lević, Steva
AU  - Marinković, Aleksandar
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3744
AB  - A novel adsorbents, 6-arm amino polyethylene glycol functionalized multiwall carbon nanotubes (PEG/MWCNT) loaded with alpha-FeOOH (Fe/PEG/MWCNT), and hybrid alpha-FeOOH/alpha-MnO2 nano-deposit (Fe-Mn/PEG/MWCNT) were used for As(V) removal. In a batch test, the influence of pH, contact time, initial ion concentration and temperature on adsorption efficiency was studied. Time-dependent adsorption was best described by pseudo-second-order kinetic model and Weber-Morris model which predicted intra-particle diffusion as a rate controlling step of overall process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of As(V) removal. Thermodynamic parameters showed that the adsorption was spontaneous and endothermic processes. Influences of the pH, iron oxide loading and interfering ions were modeled by using Visual MINTEQ software. High adsorption capacities: 49.39 and 59.78 mg g(-1) were obtained for Fe/- and Fe-Mn/PEG/MWCNT, respectively, and multi-cycle reusability indicated high applicability of obtained material. Two step removal process, in a batch study, was successfully performed by using PEG/MWCNT for cations removal in the first step, and Fe or Fe-Mn/PEG/MWCNT for As(V) removal in the second.
PB  - Inst Chemical Engineers, Rugby
T2  - Chemical Engineering Research & Design
T1  - Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes
EP  - 86
SP  - 75
VL  - 119
DO  - 10.1016/j.cherd.2017.01.010
ER  - 
@article{
author = "Budimirović, Dragoslav and Veličković, Zlate and Đokić, Veljko and Milosavljević, Milutin and Markovski, Jasmina and Lević, Steva and Marinković, Aleksandar",
year = "2017",
abstract = "A novel adsorbents, 6-arm amino polyethylene glycol functionalized multiwall carbon nanotubes (PEG/MWCNT) loaded with alpha-FeOOH (Fe/PEG/MWCNT), and hybrid alpha-FeOOH/alpha-MnO2 nano-deposit (Fe-Mn/PEG/MWCNT) were used for As(V) removal. In a batch test, the influence of pH, contact time, initial ion concentration and temperature on adsorption efficiency was studied. Time-dependent adsorption was best described by pseudo-second-order kinetic model and Weber-Morris model which predicted intra-particle diffusion as a rate controlling step of overall process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of As(V) removal. Thermodynamic parameters showed that the adsorption was spontaneous and endothermic processes. Influences of the pH, iron oxide loading and interfering ions were modeled by using Visual MINTEQ software. High adsorption capacities: 49.39 and 59.78 mg g(-1) were obtained for Fe/- and Fe-Mn/PEG/MWCNT, respectively, and multi-cycle reusability indicated high applicability of obtained material. Two step removal process, in a batch study, was successfully performed by using PEG/MWCNT for cations removal in the first step, and Fe or Fe-Mn/PEG/MWCNT for As(V) removal in the second.",
publisher = "Inst Chemical Engineers, Rugby",
journal = "Chemical Engineering Research & Design",
title = "Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes",
pages = "86-75",
volume = "119",
doi = "10.1016/j.cherd.2017.01.010"
}
Budimirović, D., Veličković, Z., Đokić, V., Milosavljević, M., Markovski, J., Lević, S.,& Marinković, A.. (2017). Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes. in Chemical Engineering Research & Design
Inst Chemical Engineers, Rugby., 119, 75-86.
https://doi.org/10.1016/j.cherd.2017.01.010
Budimirović D, Veličković Z, Đokić V, Milosavljević M, Markovski J, Lević S, Marinković A. Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes. in Chemical Engineering Research & Design. 2017;119:75-86.
doi:10.1016/j.cherd.2017.01.010 .
Budimirović, Dragoslav, Veličković, Zlate, Đokić, Veljko, Milosavljević, Milutin, Markovski, Jasmina, Lević, Steva, Marinković, Aleksandar, "Efficient As(V) removal by alpha-FeOOH and alpha-FeOOH/alpha-MnO2 embedded PEG-6-arm functionalized multiwall carbon nanotubes" in Chemical Engineering Research & Design, 119 (2017):75-86,
https://doi.org/10.1016/j.cherd.2017.01.010 . .
39
34
44

Blend of natural waxes as a matrix for aroma encapsulation

Milanović, Jelena; Ilić-Sević, Gordana; Gavrilović, Marijana; Milosavljević, Milutin; Bugarski, Branko

(Univerzitet u Nišu, Niš, 2017)

TY  - JOUR
AU  - Milanović, Jelena
AU  - Ilić-Sević, Gordana
AU  - Gavrilović, Marijana
AU  - Milosavljević, Milutin
AU  - Bugarski, Branko
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3508
AB  - In this study, the possibility of using a blend of natural waxes (bees and carnauba) for encapsulation of some aroma compounds was investigated. Melt dispersion/melt solidification technique was applied for microbeads production. Since one of the most important characteristics of the particles are the size and shape, particle size distribution as well as morphological properties are tested. Thermal characteristics are also examined as significant properties for thermal behavior at elevated temperatures, important for application of encapsulated particles in food production processes. Different contents of the carnauba wax in the mixture with beeswax are investigated, from 10% to 50% (w/w). Since one of the potential applications of the encapsulated aroma is in feed additives production, the targeted particle size range was under 300 μm to be suitable for handling and mixing with other powder substances. According to the obtained results, a higher carnauba wax content in the wax blend had an impact on particle size distribution. Also, it had an impact on the surface morphology and thermal properties. The obtained results may contribute to the development of methods of encapsulation of hydrophobic aromas in the natural wax matrix.
AB  - U radu je ispitivana mogućnost upotrebe smeše prirodnih voskova (pčelinjeg i katnauba voska) za inkapsulaciju nekih aromatičnih jedinjenja. Primenjena je metoda disperzije/očvršćavanja rastopa za dobijanje mikročestica. Budući da su veličina i oblik čestica jedne od važnijih osobina, analizirana je raspodela veličine čestica, kao i morfološke osobine čestica. Termičke osobine su takođe analizirane, zbog važnosti poznavanja termičkog ponašanja na povišenim temperaturama, što je značajno u proizvodnji hrane. Ispitane su smeše pčelinjeg i karnauba voska u različitim masenim odnosima, od 10% to 50% (w/w). Jedna od mogućih primena inkapsuliranih čestica je u proizvodnji hrane za životinje, pa je ciljni opseg veličine čestica bio ispod 300 μm, kako bi bile pogodne za rukovanje i mešanje sa drugim praškastim supstancama u smeši. Prema dobijenim rezultatima, veći sadržaj karnauba voska u smeši ima uticaja na raspodelu veličina čestica. Takođe ima uticaj na površinsku morfologiju i termičke osobine. Dobijeni rezultati mogu doprineti razvoju metoda inkapsulacije hidrofobnih aroma u nosače od prirodnih voskova.
PB  - Univerzitet u Nišu, Niš
T2  - Facta universitatis - series: Physics, Chemistry and Technology
T1  - Blend of natural waxes as a matrix for aroma encapsulation
T1  - Smeša prirodnih voskova kao nosač za inkapsulaciju aroma
EP  - 111
IS  - 2
SP  - 103
VL  - 15
DO  - 10.2298/FUPCT1702103M
ER  - 
@article{
author = "Milanović, Jelena and Ilić-Sević, Gordana and Gavrilović, Marijana and Milosavljević, Milutin and Bugarski, Branko",
year = "2017",
abstract = "In this study, the possibility of using a blend of natural waxes (bees and carnauba) for encapsulation of some aroma compounds was investigated. Melt dispersion/melt solidification technique was applied for microbeads production. Since one of the most important characteristics of the particles are the size and shape, particle size distribution as well as morphological properties are tested. Thermal characteristics are also examined as significant properties for thermal behavior at elevated temperatures, important for application of encapsulated particles in food production processes. Different contents of the carnauba wax in the mixture with beeswax are investigated, from 10% to 50% (w/w). Since one of the potential applications of the encapsulated aroma is in feed additives production, the targeted particle size range was under 300 μm to be suitable for handling and mixing with other powder substances. According to the obtained results, a higher carnauba wax content in the wax blend had an impact on particle size distribution. Also, it had an impact on the surface morphology and thermal properties. The obtained results may contribute to the development of methods of encapsulation of hydrophobic aromas in the natural wax matrix., U radu je ispitivana mogućnost upotrebe smeše prirodnih voskova (pčelinjeg i katnauba voska) za inkapsulaciju nekih aromatičnih jedinjenja. Primenjena je metoda disperzije/očvršćavanja rastopa za dobijanje mikročestica. Budući da su veličina i oblik čestica jedne od važnijih osobina, analizirana je raspodela veličine čestica, kao i morfološke osobine čestica. Termičke osobine su takođe analizirane, zbog važnosti poznavanja termičkog ponašanja na povišenim temperaturama, što je značajno u proizvodnji hrane. Ispitane su smeše pčelinjeg i karnauba voska u različitim masenim odnosima, od 10% to 50% (w/w). Jedna od mogućih primena inkapsuliranih čestica je u proizvodnji hrane za životinje, pa je ciljni opseg veličine čestica bio ispod 300 μm, kako bi bile pogodne za rukovanje i mešanje sa drugim praškastim supstancama u smeši. Prema dobijenim rezultatima, veći sadržaj karnauba voska u smeši ima uticaja na raspodelu veličina čestica. Takođe ima uticaj na površinsku morfologiju i termičke osobine. Dobijeni rezultati mogu doprineti razvoju metoda inkapsulacije hidrofobnih aroma u nosače od prirodnih voskova.",
publisher = "Univerzitet u Nišu, Niš",
journal = "Facta universitatis - series: Physics, Chemistry and Technology",
title = "Blend of natural waxes as a matrix for aroma encapsulation, Smeša prirodnih voskova kao nosač za inkapsulaciju aroma",
pages = "111-103",
number = "2",
volume = "15",
doi = "10.2298/FUPCT1702103M"
}
Milanović, J., Ilić-Sević, G., Gavrilović, M., Milosavljević, M.,& Bugarski, B.. (2017). Blend of natural waxes as a matrix for aroma encapsulation. in Facta universitatis - series: Physics, Chemistry and Technology
Univerzitet u Nišu, Niš., 15(2), 103-111.
https://doi.org/10.2298/FUPCT1702103M
Milanović J, Ilić-Sević G, Gavrilović M, Milosavljević M, Bugarski B. Blend of natural waxes as a matrix for aroma encapsulation. in Facta universitatis - series: Physics, Chemistry and Technology. 2017;15(2):103-111.
doi:10.2298/FUPCT1702103M .
Milanović, Jelena, Ilić-Sević, Gordana, Gavrilović, Marijana, Milosavljević, Milutin, Bugarski, Branko, "Blend of natural waxes as a matrix for aroma encapsulation" in Facta universitatis - series: Physics, Chemistry and Technology, 15, no. 2 (2017):103-111,
https://doi.org/10.2298/FUPCT1702103M . .
5

Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance

Taleb, Khaled; Markovski, Jasmina; Milosavljević, Milutin; Marinović-Cincović, Milena; Rusmirović, Jelena; Ristić, Mirjana; Marinković, Aleksandar

(Elsevier Science Sa, Lausanne, 2015)

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Milosavljević, Milutin
AU  - Marinović-Cincović, Milena
AU  - Rusmirović, Jelena
AU  - Ristić, Mirjana
AU  - Marinković, Aleksandar
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3151
AB  - Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance
EP  - 78
SP  - 66
VL  - 279
DO  - 10.1016/j.cej.2015.04.147
ER  - 
@article{
author = "Taleb, Khaled and Markovski, Jasmina and Milosavljević, Milutin and Marinović-Cincović, Milena and Rusmirović, Jelena and Ristić, Mirjana and Marinković, Aleksandar",
year = "2015",
abstract = "Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance",
pages = "78-66",
volume = "279",
doi = "10.1016/j.cej.2015.04.147"
}
Taleb, K., Markovski, J., Milosavljević, M., Marinović-Cincović, M., Rusmirović, J., Ristić, M.,& Marinković, A.. (2015). Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 279, 66-78.
https://doi.org/10.1016/j.cej.2015.04.147
Taleb K, Markovski J, Milosavljević M, Marinović-Cincović M, Rusmirović J, Ristić M, Marinković A. Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal. 2015;279:66-78.
doi:10.1016/j.cej.2015.04.147 .
Taleb, Khaled, Markovski, Jasmina, Milosavljević, Milutin, Marinović-Cincović, Milena, Rusmirović, Jelena, Ristić, Mirjana, Marinković, Aleksandar, "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance" in Chemical Engineering Journal, 279 (2015):66-78,
https://doi.org/10.1016/j.cej.2015.04.147 . .
49
41
50

Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2

Markovski, Jasmina; Đokić, Veljko; Milosavljević, Milutin; Mitrić, Miodrag; Perić-Grujić, Aleksandra; Onjia, Antonije; Marinković, Aleksandar

(Elsevier, Amsterdam, 2014)

TY  - JOUR
AU  - Markovski, Jasmina
AU  - Đokić, Veljko
AU  - Milosavljević, Milutin
AU  - Mitrić, Miodrag
AU  - Perić-Grujić, Aleksandra
AU  - Onjia, Antonije
AU  - Marinković, Aleksandar
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2780
AB  - A highly porous calcium carbonate (calcite; sorbent 1) was used as a support for modification with alpha-FeOOH (calcite/goethite; sorbent 2), alpha-MnO2 (calcite/alpha-MnO2; sorbent 3) and alpha-FeOOH/alpha-MnO2 (calcite/goethite/alpha-MnO2; sorbent 4) in order to obtain a cheap hybrid materials for simple and effective arsenate removal from aqueous solutions. The adsorption ability of synthesized adsorbents was studied as a function of functionalization methods, pH, contact time, temperature and ultrasonic treatment. Comparison of the adsorptive effectiveness of synthesized adsorbents for arsenate removal, under ultrasound treatment and classical stirring method, has shown better performance of the former one reaching maximum adsorption capacities of 1.73, 21.00, 10.36 and 41.94 mg g(-1), for sorbents 1-4, respectively. Visual MINTEQ equilibrium speciation modeling was used for prediction of pH and interfering ion influences on arsenate adsorption.
PB  - Elsevier, Amsterdam
T2  - Ultrasonics Sonochemistry
T1  - Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2
EP  - 801
IS  - 2
SP  - 790
VL  - 21
DO  - 10.1016/j.ultsonch.2013.10.006
ER  - 
@article{
author = "Markovski, Jasmina and Đokić, Veljko and Milosavljević, Milutin and Mitrić, Miodrag and Perić-Grujić, Aleksandra and Onjia, Antonije and Marinković, Aleksandar",
year = "2014",
abstract = "A highly porous calcium carbonate (calcite; sorbent 1) was used as a support for modification with alpha-FeOOH (calcite/goethite; sorbent 2), alpha-MnO2 (calcite/alpha-MnO2; sorbent 3) and alpha-FeOOH/alpha-MnO2 (calcite/goethite/alpha-MnO2; sorbent 4) in order to obtain a cheap hybrid materials for simple and effective arsenate removal from aqueous solutions. The adsorption ability of synthesized adsorbents was studied as a function of functionalization methods, pH, contact time, temperature and ultrasonic treatment. Comparison of the adsorptive effectiveness of synthesized adsorbents for arsenate removal, under ultrasound treatment and classical stirring method, has shown better performance of the former one reaching maximum adsorption capacities of 1.73, 21.00, 10.36 and 41.94 mg g(-1), for sorbents 1-4, respectively. Visual MINTEQ equilibrium speciation modeling was used for prediction of pH and interfering ion influences on arsenate adsorption.",
publisher = "Elsevier, Amsterdam",
journal = "Ultrasonics Sonochemistry",
title = "Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2",
pages = "801-790",
number = "2",
volume = "21",
doi = "10.1016/j.ultsonch.2013.10.006"
}
Markovski, J., Đokić, V., Milosavljević, M., Mitrić, M., Perić-Grujić, A., Onjia, A.,& Marinković, A.. (2014). Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2. in Ultrasonics Sonochemistry
Elsevier, Amsterdam., 21(2), 790-801.
https://doi.org/10.1016/j.ultsonch.2013.10.006
Markovski J, Đokić V, Milosavljević M, Mitrić M, Perić-Grujić A, Onjia A, Marinković A. Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2. in Ultrasonics Sonochemistry. 2014;21(2):790-801.
doi:10.1016/j.ultsonch.2013.10.006 .
Markovski, Jasmina, Đokić, Veljko, Milosavljević, Milutin, Mitrić, Miodrag, Perić-Grujić, Aleksandra, Onjia, Antonije, Marinković, Aleksandar, "Ultrasonic assisted arsenate adsorption on solvothermally synthesized calcite modified by goethite, alpha-MnO2 and goethite/alpha-MnO2" in Ultrasonics Sonochemistry, 21, no. 2 (2014):790-801,
https://doi.org/10.1016/j.ultsonch.2013.10.006 . .
37
33
40

The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity

Marinković, Aleksandar; Milosavljević, Milutin; Milenković, Dragan D.; Ivanović, Goran

(Association of the Chemical Engineers of Serbia, 2008)

TY  - JOUR
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
AU  - Milenković, Dragan D.
AU  - Ivanović, Goran
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1323
AB  - A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity
EP  - 255
IS  - 4
SP  - 251
VL  - 14
DO  - 10.2298/CICEQ0804251M
ER  - 
@article{
author = "Marinković, Aleksandar and Milosavljević, Milutin and Milenković, Dragan D. and Ivanović, Goran",
year = "2008",
abstract = "A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity",
pages = "255-251",
number = "4",
volume = "14",
doi = "10.2298/CICEQ0804251M"
}
Marinković, A., Milosavljević, M., Milenković, D. D.,& Ivanović, G.. (2008). The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 14(4), 251-255.
https://doi.org/10.2298/CICEQ0804251M
Marinković A, Milosavljević M, Milenković DD, Ivanović G. The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly. 2008;14(4):251-255.
doi:10.2298/CICEQ0804251M .
Marinković, Aleksandar, Milosavljević, Milutin, Milenković, Dragan D., Ivanović, Goran, "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity" in Chemical Industry & Chemical Engineering Quarterly, 14, no. 4 (2008):251-255,
https://doi.org/10.2298/CICEQ0804251M . .
2
3
4

Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate

Milosavljević, Milutin; Marinković, Aleksandar; Ceković, Boban; Ražić, Slavica

(Serbian Chemical Society, Belgrade, 2007)

TY  - JOUR
AU  - Milosavljević, Milutin
AU  - Marinković, Aleksandar
AU  - Ceković, Boban
AU  - Ražić, Slavica
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1192
AB  - The reaction kinetics of the synthesis of sodium ethyl xanthogeneacetate from potassium ethylxanthogenate and sodium chloroacetate in distilled water as the reaction medium at 25, 30, 35 and 40°C, were investigated. The obtained reaction mixture was a complex system which demanded the use of two methods for the kinetic measurements. The reaction was followed using the conductrometric and UV/Vis spectrophotometric method with equimolar initial concentrations of the reactants and under pseudo-first order conditions with respect to one of the reactants. The rate constants of the pseudo-first order and second order reactions were calculated from the data. On the basis of the reaction constants, the activation parameters were calculated and are discussed.
AB  - Ispitivana je kinetika reakcije sinteze natrijum-etil-ksantogen-acetata iz kalijum-etil-ksantogenata i natrijum-hloracetata u destilovanoj vodi kao reakcionom medijumu i temperaturama 25, 30, 35 i 40°C. Reakciona smeša je kompleksan sistem koji je zahtevao korišćenje dve metode za kinetička merenja. Reakcije su praćene korišćenjem spektrofotometrijske i konduktometrijske metode pri ekvimolarnim početnim koncentracijama reaktanata kao i pri uslovima reakcija pseudo-prvog reda u odnosu na jedan od reaktanata. Reakcione konstante pseudo-prvog reda i drugog reda izračunate su na osnovu kinetičkih podataka. Na osnovu reakcionih konstanti izračunati su i diskutovani takođe i aktivacioni parametri.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate
T1  - Kinetička ispitivanja reakcije između natrijum-hloracetata i kalijum-etil-ksantata
EP  - 100
IS  - 2
SP  - 89
VL  - 72
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1192
ER  - 
@article{
author = "Milosavljević, Milutin and Marinković, Aleksandar and Ceković, Boban and Ražić, Slavica",
year = "2007",
abstract = "The reaction kinetics of the synthesis of sodium ethyl xanthogeneacetate from potassium ethylxanthogenate and sodium chloroacetate in distilled water as the reaction medium at 25, 30, 35 and 40°C, were investigated. The obtained reaction mixture was a complex system which demanded the use of two methods for the kinetic measurements. The reaction was followed using the conductrometric and UV/Vis spectrophotometric method with equimolar initial concentrations of the reactants and under pseudo-first order conditions with respect to one of the reactants. The rate constants of the pseudo-first order and second order reactions were calculated from the data. On the basis of the reaction constants, the activation parameters were calculated and are discussed., Ispitivana je kinetika reakcije sinteze natrijum-etil-ksantogen-acetata iz kalijum-etil-ksantogenata i natrijum-hloracetata u destilovanoj vodi kao reakcionom medijumu i temperaturama 25, 30, 35 i 40°C. Reakciona smeša je kompleksan sistem koji je zahtevao korišćenje dve metode za kinetička merenja. Reakcije su praćene korišćenjem spektrofotometrijske i konduktometrijske metode pri ekvimolarnim početnim koncentracijama reaktanata kao i pri uslovima reakcija pseudo-prvog reda u odnosu na jedan od reaktanata. Reakcione konstante pseudo-prvog reda i drugog reda izračunate su na osnovu kinetičkih podataka. Na osnovu reakcionih konstanti izračunati su i diskutovani takođe i aktivacioni parametri.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate, Kinetička ispitivanja reakcije između natrijum-hloracetata i kalijum-etil-ksantata",
pages = "100-89",
number = "2",
volume = "72",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1192"
}
Milosavljević, M., Marinković, A., Ceković, B.,& Ražić, S.. (2007). Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 72(2), 89-100.
https://hdl.handle.net/21.15107/rcub_technorep_1192
Milosavljević M, Marinković A, Ceković B, Ražić S. Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate. in Journal of the Serbian Chemical Society. 2007;72(2):89-100.
https://hdl.handle.net/21.15107/rcub_technorep_1192 .
Milosavljević, Milutin, Marinković, Aleksandar, Ceković, Boban, Ražić, Slavica, "Kinetic study of the reaction between sodium chloroacetate and potassium ethylxanthogenate" in Journal of the Serbian Chemical Society, 72, no. 2 (2007):89-100,
https://hdl.handle.net/21.15107/rcub_technorep_1192 .
2
2

Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates

Milosavljević, Milutin M.; Marinković, Aleksandar; Đorđević, Siniša

(Association of Chemical Engineers of Serbia, 2006)

TY  - JOUR
AU  - Milosavljević, Milutin M.
AU  - Marinković, Aleksandar
AU  - Đorđević, Siniša
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/975
AB  - A series of N- and N,N-dialkyl-S-alkylthiolcarbamates were synthesized by the rearrangement of N- and N,N-dialkyl-O-alkylthioncarbamates in the presence of diethyl sulfate. The synthesis of some compounds without catalyst was also performed. The compounds were identified by IR, 1H NMR and MS spectroscopic methods. The starting thioncabamates were obtained from the corresponding xanthogenacetates and amines and their structures were also confirmed by IR, 1H NMR and MS data. Some of the thiolcarbamates were characterized for the first time in the literature.
AB  - U radu je izvršena sinteza N- i N,N-dialkil-S-alkiltiolkarbamata premeštanjem N- i N,N-dialkil-O-alkiltionkarbamata u prisustvu katalizatora dietilsulfata. Tako-đe je ispitana mogućnost njihove sinteze bez prisustva katalizatora. Identifikacija sintetisanih jedinjenja je izvršena IR, 1H NMR i MS spektroskopskim metodama. Polazni tionkarbamati su sintetisani iz odgovarajućih ksantogena-cetata i amina, čija struktura je, takođe potvrđena navedenim instrumentalnim metodama. Neki od sintetisanih tiolkarbamata do sada nisu okarakterisani u literaturi.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates
T1  - Sinteza N- i N,N-dialkil-S-alkiltiol-karbamata premeštanjem N- i N,N-dialkil-O-alkiltionkarbamata
EP  - 32
IS  - 1-2
SP  - 27
VL  - 60
DO  - 10.2298/HEMIND0602027M
ER  - 
@article{
author = "Milosavljević, Milutin M. and Marinković, Aleksandar and Đorđević, Siniša",
year = "2006",
abstract = "A series of N- and N,N-dialkyl-S-alkylthiolcarbamates were synthesized by the rearrangement of N- and N,N-dialkyl-O-alkylthioncarbamates in the presence of diethyl sulfate. The synthesis of some compounds without catalyst was also performed. The compounds were identified by IR, 1H NMR and MS spectroscopic methods. The starting thioncabamates were obtained from the corresponding xanthogenacetates and amines and their structures were also confirmed by IR, 1H NMR and MS data. Some of the thiolcarbamates were characterized for the first time in the literature., U radu je izvršena sinteza N- i N,N-dialkil-S-alkiltiolkarbamata premeštanjem N- i N,N-dialkil-O-alkiltionkarbamata u prisustvu katalizatora dietilsulfata. Tako-đe je ispitana mogućnost njihove sinteze bez prisustva katalizatora. Identifikacija sintetisanih jedinjenja je izvršena IR, 1H NMR i MS spektroskopskim metodama. Polazni tionkarbamati su sintetisani iz odgovarajućih ksantogena-cetata i amina, čija struktura je, takođe potvrđena navedenim instrumentalnim metodama. Neki od sintetisanih tiolkarbamata do sada nisu okarakterisani u literaturi.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates, Sinteza N- i N,N-dialkil-S-alkiltiol-karbamata premeštanjem N- i N,N-dialkil-O-alkiltionkarbamata",
pages = "32-27",
number = "1-2",
volume = "60",
doi = "10.2298/HEMIND0602027M"
}
Milosavljević, M. M., Marinković, A.,& Đorđević, S.. (2006). Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates. in Hemijska industrija
Association of Chemical Engineers of Serbia., 60(1-2), 27-32.
https://doi.org/10.2298/HEMIND0602027M
Milosavljević MM, Marinković A, Đorđević S. Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates. in Hemijska industrija. 2006;60(1-2):27-32.
doi:10.2298/HEMIND0602027M .
Milosavljević, Milutin M., Marinković, Aleksandar, Đorđević, Siniša, "Synthesis of N-and N,N-dialkyl-S-alkylthiolcarbamates by the rearrangement of N-and N,N-dialkyl-O-thioncarbamates" in Hemijska industrija, 60, no. 1-2 (2006):27-32,
https://doi.org/10.2298/HEMIND0602027M . .
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