Maksimović, Miodrag D.

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b1677ce6-6975-4fc2-9e92-f2d9e6c92228
  • Maksimović, Miodrag D. (21)
  • Maksimović, Miodrag (1)
Projects

Author's Bibliography

The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline

Bucko, Mihael; Tomić, Milorad V.; Maksimović, Miodrag D.; Bajat, Jelena

(Srpsko hemijsko društvo, Beograd, 2019)

TY  - JOUR
AU  - Bucko, Mihael
AU  - Tomić, Milorad V.
AU  - Maksimović, Miodrag D.
AU  - Bajat, Jelena
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4098
AB  - Cyclic voltammetry was used for the characterization of zinc electro-deposition on steel from ethaline deep eutectic solution (1:2 choline chloride:ethylene glycol). The influence of 4-hydroxy-benzaldehyde (HBA) as an additive was analyzed. It was shown that hydrogen evolution is inhibited in the presence of HBA and further significantly retarded upon addition of Zn2+ to the solution containing HBA. The cathodic peak for Zn2+ reduction in this type of ionic liquid (ethaline+HBA+Zn2+) resembles the zinc reduction in aqueous solution. The corrosion resistance of Zn coatings deposited at different current densities was evaluated by electrochemical methods, i.e., polarization measurements and electrochemical impedance spectroscopy in 3 % NaCl solution. The possibility of Zn-Mn alloy deposition from ethaline deep eutectic solvent was investigated for the first time. In addition, the corrosion stability of these alloy coatings was analyzed and compared to the stability of bare Zn coatings. It was shown that the optimum deposition current density for both Zn and Zn-Mn coatings with increased corrosion stability from ethaline + HBA electrolyte is 5 mA cm(-2).
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline
EP  - 1234
IS  - 11
SP  - 1221
VL  - 84
DO  - 10.2298/JSC190718084B
ER  - 
@article{
author = "Bucko, Mihael and Tomić, Milorad V. and Maksimović, Miodrag D. and Bajat, Jelena",
year = "2019",
abstract = "Cyclic voltammetry was used for the characterization of zinc electro-deposition on steel from ethaline deep eutectic solution (1:2 choline chloride:ethylene glycol). The influence of 4-hydroxy-benzaldehyde (HBA) as an additive was analyzed. It was shown that hydrogen evolution is inhibited in the presence of HBA and further significantly retarded upon addition of Zn2+ to the solution containing HBA. The cathodic peak for Zn2+ reduction in this type of ionic liquid (ethaline+HBA+Zn2+) resembles the zinc reduction in aqueous solution. The corrosion resistance of Zn coatings deposited at different current densities was evaluated by electrochemical methods, i.e., polarization measurements and electrochemical impedance spectroscopy in 3 % NaCl solution. The possibility of Zn-Mn alloy deposition from ethaline deep eutectic solvent was investigated for the first time. In addition, the corrosion stability of these alloy coatings was analyzed and compared to the stability of bare Zn coatings. It was shown that the optimum deposition current density for both Zn and Zn-Mn coatings with increased corrosion stability from ethaline + HBA electrolyte is 5 mA cm(-2).",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline",
pages = "1234-1221",
number = "11",
volume = "84",
doi = "10.2298/JSC190718084B"
}
Bucko, M., Tomić, M. V., Maksimović, M. D.,& Bajat, J.. (2019). The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 84(11), 1221-1234.
https://doi.org/10.2298/JSC190718084B
Bucko M, Tomić MV, Maksimović MD, Bajat J. The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline. in Journal of the Serbian Chemical Society. 2019;84(11):1221-1234.
doi:10.2298/JSC190718084B .
Bucko, Mihael, Tomić, Milorad V., Maksimović, Miodrag D., Bajat, Jelena, "The importance of using hydrogen evolution inhibitor during the Zn and Zn-Mn electrodeposition from ethaline" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1221-1234,
https://doi.org/10.2298/JSC190718084B . .
4
2
4

Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell

Grgur, Branimir; Žeradjanin, Aleksandar; Gvozdenović, Milica; Maksimović, Miodrag D.; Trišović, Tomislav; Jugović, Branimir

(Elsevier Science Bv, Amsterdam, 2012)

TY  - JOUR
AU  - Grgur, Branimir
AU  - Žeradjanin, Aleksandar
AU  - Gvozdenović, Milica
AU  - Maksimović, Miodrag D.
AU  - Trišović, Tomislav
AU  - Jugović, Branimir
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2172
AB  - Electrochemically synthesized polyaniline (PANI) and lead dioxide have been investigated as electrode materials for PANI/1.1 M H2SO4: 0.5 M (NH4)(2)SO4/PbO2 rechargeable cell. At constant current charge/discharge of the cell, the average discharge potential of 1.1 V. specific capacity of 50 mA h g(-1), specific energy of 55 W h kg(-1), and self discharge rate of 2.2% per day have been obtained.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Power Sources
T1  - Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell
EP  - 198
SP  - 193
VL  - 217
DO  - 10.1016/j.jpowsour.2012.06.025
ER  - 
@article{
author = "Grgur, Branimir and Žeradjanin, Aleksandar and Gvozdenović, Milica and Maksimović, Miodrag D. and Trišović, Tomislav and Jugović, Branimir",
year = "2012",
abstract = "Electrochemically synthesized polyaniline (PANI) and lead dioxide have been investigated as electrode materials for PANI/1.1 M H2SO4: 0.5 M (NH4)(2)SO4/PbO2 rechargeable cell. At constant current charge/discharge of the cell, the average discharge potential of 1.1 V. specific capacity of 50 mA h g(-1), specific energy of 55 W h kg(-1), and self discharge rate of 2.2% per day have been obtained.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Power Sources",
title = "Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell",
pages = "198-193",
volume = "217",
doi = "10.1016/j.jpowsour.2012.06.025"
}
Grgur, B., Žeradjanin, A., Gvozdenović, M., Maksimović, M. D., Trišović, T.,& Jugović, B.. (2012). Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell. in Journal of Power Sources
Elsevier Science Bv, Amsterdam., 217, 193-198.
https://doi.org/10.1016/j.jpowsour.2012.06.025
Grgur B, Žeradjanin A, Gvozdenović M, Maksimović MD, Trišović T, Jugović B. Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell. in Journal of Power Sources. 2012;217:193-198.
doi:10.1016/j.jpowsour.2012.06.025 .
Grgur, Branimir, Žeradjanin, Aleksandar, Gvozdenović, Milica, Maksimović, Miodrag D., Trišović, Tomislav, Jugović, Branimir, "Electrochemical characteristics of rechargeable polyaniline/lead dioxide cell" in Journal of Power Sources, 217 (2012):193-198,
https://doi.org/10.1016/j.jpowsour.2012.06.025 . .
19
17
17

The study of Zn-Co alloy coatings electrochemically deposited by pulse current

Bajat, Jelena; Maksimović, Miodrag D.; Tomić, Milorad V.; Pavlović, Miomir G.

(Association of Chemical Engineers of Serbia, 2012)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
AU  - Tomić, Milorad V.
AU  - Pavlović, Miomir G.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2094
AB  - The electrochemical deposition by pulse current of Zn-Co alloy coatings on steel was examined, with the aim to find out whether pulse plating could produce alloys that could offer a better corrosion protection. The influence of on-time and the average current density on the cathodic current efficiency, coating morphology, surface roughness and corrosion stability in 3% NaCl was examined. At the same Ton/Toff ratio the current efficiency was insignificantly smaller for deposition at higher average current density. It was shown that, depending on the on-time, pulse plating could produce more homogenous alloy coatings with finer morphology, as compared to deposits obtained by direct current. The surface roughness was the greatest for Zn-Co alloy coatings deposited with direct current, as compared with alloy coatings deposited with pulse current, for both examined average current densities. It was also shown that Zn-Co alloy coatings deposited by pulse current could increase the corrosion stability of Zn-Co alloy coatings on steel. Namely, alloy coatings deposited with pulse current showed higher corrosion stability, as compared with alloy coatings deposited with direct current, for almost all examined cathodic times, Ton. Alloy coatings deposited at higher average current density showed greater corrosion stability as compared with coatings deposited by pulse current at smaller average current density. It was shown that deposits obtained with pulse current and cathodic time of 10 ms had the poorest corrosion stability, for both investigated average deposition current density. Among all investigated alloy coatings the highest corrosion stability was obtained for Zn-Co alloy coatings deposited with pulsed current at higher average current density (jav = 4 A dm-2).
AB  - Ispitivano je elektrohemijsko taloženje cink-kobalt legure pulsirajućom strujom na čeliku, a s ciljem dobijanja zaštitnih prevlaka sa povećanom korozionom stabilnošću. Prevlake legura su taložene pulsirajućim režimom sa različitim srednjim gustinama struje i pri različitom trajanju katodnog pulsa. Analiziran je uticaj ovih parametara na iskorišćenje struje prilikom elektrohemijskog taloženja na izgled prevlaka (snimanje elektronskim mikroskopom), hrapavost prevlaka i njihovu korozionu stabilnost u 3% NaCl (merenjem slobodnog korozionog potencijala u agensu korozije i snimanjem polarizacionih krivih). Pokazano je da u zavisnosti od vremena pulsa, prevlake taložene pulsirajućim režimom mogu da imaju bolju homogenost, sitnije aglomerate kristalnih zrna i manju hrapavost od onih taloženih pri istim uslovima, ali konstantnom gustinom struje. Veću korozionu stabilnost pokazale su prevlake legura taložene većom srednjom gustinom struje.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - The study of Zn-Co alloy coatings electrochemically deposited by pulse current
T1  - Ispitivanje prevlaka Zn-Co legura dobijenih pulsirajućom strujom
EP  - 757
IS  - 5
SP  - 749
VL  - 66
DO  - 10.2298/HEMIND111215035B
ER  - 
@article{
author = "Bajat, Jelena and Maksimović, Miodrag D. and Tomić, Milorad V. and Pavlović, Miomir G.",
year = "2012",
abstract = "The electrochemical deposition by pulse current of Zn-Co alloy coatings on steel was examined, with the aim to find out whether pulse plating could produce alloys that could offer a better corrosion protection. The influence of on-time and the average current density on the cathodic current efficiency, coating morphology, surface roughness and corrosion stability in 3% NaCl was examined. At the same Ton/Toff ratio the current efficiency was insignificantly smaller for deposition at higher average current density. It was shown that, depending on the on-time, pulse plating could produce more homogenous alloy coatings with finer morphology, as compared to deposits obtained by direct current. The surface roughness was the greatest for Zn-Co alloy coatings deposited with direct current, as compared with alloy coatings deposited with pulse current, for both examined average current densities. It was also shown that Zn-Co alloy coatings deposited by pulse current could increase the corrosion stability of Zn-Co alloy coatings on steel. Namely, alloy coatings deposited with pulse current showed higher corrosion stability, as compared with alloy coatings deposited with direct current, for almost all examined cathodic times, Ton. Alloy coatings deposited at higher average current density showed greater corrosion stability as compared with coatings deposited by pulse current at smaller average current density. It was shown that deposits obtained with pulse current and cathodic time of 10 ms had the poorest corrosion stability, for both investigated average deposition current density. Among all investigated alloy coatings the highest corrosion stability was obtained for Zn-Co alloy coatings deposited with pulsed current at higher average current density (jav = 4 A dm-2)., Ispitivano je elektrohemijsko taloženje cink-kobalt legure pulsirajućom strujom na čeliku, a s ciljem dobijanja zaštitnih prevlaka sa povećanom korozionom stabilnošću. Prevlake legura su taložene pulsirajućim režimom sa različitim srednjim gustinama struje i pri različitom trajanju katodnog pulsa. Analiziran je uticaj ovih parametara na iskorišćenje struje prilikom elektrohemijskog taloženja na izgled prevlaka (snimanje elektronskim mikroskopom), hrapavost prevlaka i njihovu korozionu stabilnost u 3% NaCl (merenjem slobodnog korozionog potencijala u agensu korozije i snimanjem polarizacionih krivih). Pokazano je da u zavisnosti od vremena pulsa, prevlake taložene pulsirajućim režimom mogu da imaju bolju homogenost, sitnije aglomerate kristalnih zrna i manju hrapavost od onih taloženih pri istim uslovima, ali konstantnom gustinom struje. Veću korozionu stabilnost pokazale su prevlake legura taložene većom srednjom gustinom struje.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "The study of Zn-Co alloy coatings electrochemically deposited by pulse current, Ispitivanje prevlaka Zn-Co legura dobijenih pulsirajućom strujom",
pages = "757-749",
number = "5",
volume = "66",
doi = "10.2298/HEMIND111215035B"
}
Bajat, J., Maksimović, M. D., Tomić, M. V.,& Pavlović, M. G.. (2012). The study of Zn-Co alloy coatings electrochemically deposited by pulse current. in Hemijska industrija
Association of Chemical Engineers of Serbia., 66(5), 749-757.
https://doi.org/10.2298/HEMIND111215035B
Bajat J, Maksimović MD, Tomić MV, Pavlović MG. The study of Zn-Co alloy coatings electrochemically deposited by pulse current. in Hemijska industrija. 2012;66(5):749-757.
doi:10.2298/HEMIND111215035B .
Bajat, Jelena, Maksimović, Miodrag D., Tomić, Milorad V., Pavlović, Miomir G., "The study of Zn-Co alloy coatings electrochemically deposited by pulse current" in Hemijska industrija, 66, no. 5 (2012):749-757,
https://doi.org/10.2298/HEMIND111215035B . .
1
1
1

Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum

Elkais, Ali Ramadan; Gvozdenović, Milica M.; Jugović, Branimir; Trišović, Tomislav; Maksimović, Miodrag; Grgur, Branimir

(Belgrade : Association of the Chemical Engineers of Serbia, 2011)

TY  - JOUR
AU  - Elkais, Ali Ramadan
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Maksimović, Miodrag
AU  - Grgur, Branimir
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5621
AB  - The electrochemical synthesis of polyaniline (PANI) on mild steel, aluminum and copper from the sodium benzoate solutions has been investigated. It has been shown that thin, highly adherent, polyaniline films on the investigated metals could be obtained by anodic oxidation with current densities in the range of 0.5 and 1.5 mA cm-2. The corrosion behavior of mild steel, aluminum and copper with polyaniline coating in 0.5 mol dm3 NaCl (pH 3) solutions, has been investigated by polarization technique. The corrosion current densities, porosity and protection efficiency was determined. It has been shown that polyaniline coating provided corrosion protection of all mentioned metals.
AB  - U radu je ispitivana elektrohemijska sinteza polianilina (PANI) na mekom čeliku, aluminijumu i bakru iz rastvora natrijum-benzoata i monomera anilina. Ustanovljeno je da se tanki, dobro adherentni, filmovi polianilina mogu formirati na svim ispitivanim metalima pri anodnim gustinama struja od 0,5-1,5 mA cm-2. Ispitivano je koroziono ponašanje metala sa prevlakom polianilina u rastvoru 0,5 mol dm-3 NaCl (3%). Ustanovljeno je da ove prevlake pružaju korozionu zaštitu svim ispitivanim metalima u datoj korozionoj sredini.
PB  - Belgrade : Association of the Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum
EP  - 21
IS  - 1
IS  - 1
SP  - 15
VL  - 65
VL  - 65
DO  - 10.2298/HEMIND100901069E
UR  - https://hdl.handle.net/21.15107/rcub_dais_261
ER  - 
@article{
author = "Elkais, Ali Ramadan and Gvozdenović, Milica M. and Jugović, Branimir and Trišović, Tomislav and Maksimović, Miodrag and Grgur, Branimir",
year = "2011",
abstract = "The electrochemical synthesis of polyaniline (PANI) on mild steel, aluminum and copper from the sodium benzoate solutions has been investigated. It has been shown that thin, highly adherent, polyaniline films on the investigated metals could be obtained by anodic oxidation with current densities in the range of 0.5 and 1.5 mA cm-2. The corrosion behavior of mild steel, aluminum and copper with polyaniline coating in 0.5 mol dm3 NaCl (pH 3) solutions, has been investigated by polarization technique. The corrosion current densities, porosity and protection efficiency was determined. It has been shown that polyaniline coating provided corrosion protection of all mentioned metals., U radu je ispitivana elektrohemijska sinteza polianilina (PANI) na mekom čeliku, aluminijumu i bakru iz rastvora natrijum-benzoata i monomera anilina. Ustanovljeno je da se tanki, dobro adherentni, filmovi polianilina mogu formirati na svim ispitivanim metalima pri anodnim gustinama struja od 0,5-1,5 mA cm-2. Ispitivano je koroziono ponašanje metala sa prevlakom polianilina u rastvoru 0,5 mol dm-3 NaCl (3%). Ustanovljeno je da ove prevlake pružaju korozionu zaštitu svim ispitivanim metalima u datoj korozionoj sredini.",
publisher = "Belgrade : Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum",
pages = "21-15",
number = "1, 1",
volume = "65, 65",
doi = "10.2298/HEMIND100901069E",
url = "https://hdl.handle.net/21.15107/rcub_dais_261"
}
Elkais, A. R., Gvozdenović, M. M., Jugović, B., Trišović, T., Maksimović, M.,& Grgur, B.. (2011). Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum. in Hemijska industrija
Belgrade : Association of the Chemical Engineers of Serbia., 65(1), 15-21.
https://doi.org/10.2298/HEMIND100901069E
https://hdl.handle.net/21.15107/rcub_dais_261
Elkais AR, Gvozdenović MM, Jugović B, Trišović T, Maksimović M, Grgur B. Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum. in Hemijska industrija. 2011;65(1):15-21.
doi:10.2298/HEMIND100901069E
https://hdl.handle.net/21.15107/rcub_dais_261 .
Elkais, Ali Ramadan, Gvozdenović, Milica M., Jugović, Branimir, Trišović, Tomislav, Maksimović, Miodrag, Grgur, Branimir, "Electrochemical synthesis and corrosion behavior of thin polyaniline film on mild steel, copper and aluminum" in Hemijska industrija, 65, no. 1 (2011):15-21,
https://doi.org/10.2298/HEMIND100901069E .,
https://hdl.handle.net/21.15107/rcub_dais_261 .
2
2

Polyaniline as possible anode materials for the lead acid batteries

Grgur, Branimir; Ristić, V.; Gvozdenović, Milica; Maksimović, Miodrag D.; Jugović, Branimir

(Elsevier Science Bv, Amsterdam, 2008)

TY  - JOUR
AU  - Grgur, Branimir
AU  - Ristić, V.
AU  - Gvozdenović, Milica
AU  - Maksimović, Miodrag D.
AU  - Jugović, Branimir
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1331
AB  - Electrochemically formed thin film polyaniline (PANI) anode and lead dioxide (PbO2) cathode, obtained from sulfuric acid solution, for potential applications as electrode materials in PANI vertical bar H2SO4 vertical bar PbO2 aqueous based rechargeable power sources, have been studied using cyclic voltammetry and galvanostatic techniques. Based on the investigations of half cell reactions, the simulation of the charge/discharge characteristic of the possible cell has been done.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Power Sources
T1  - Polyaniline as possible anode materials for the lead acid batteries
EP  - 640
IS  - 1
SP  - 635
VL  - 180
DO  - 10.1016/j.jpowsour.2008.02.022
ER  - 
@article{
author = "Grgur, Branimir and Ristić, V. and Gvozdenović, Milica and Maksimović, Miodrag D. and Jugović, Branimir",
year = "2008",
abstract = "Electrochemically formed thin film polyaniline (PANI) anode and lead dioxide (PbO2) cathode, obtained from sulfuric acid solution, for potential applications as electrode materials in PANI vertical bar H2SO4 vertical bar PbO2 aqueous based rechargeable power sources, have been studied using cyclic voltammetry and galvanostatic techniques. Based on the investigations of half cell reactions, the simulation of the charge/discharge characteristic of the possible cell has been done.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Power Sources",
title = "Polyaniline as possible anode materials for the lead acid batteries",
pages = "640-635",
number = "1",
volume = "180",
doi = "10.1016/j.jpowsour.2008.02.022"
}
Grgur, B., Ristić, V., Gvozdenović, M., Maksimović, M. D.,& Jugović, B.. (2008). Polyaniline as possible anode materials for the lead acid batteries. in Journal of Power Sources
Elsevier Science Bv, Amsterdam., 180(1), 635-640.
https://doi.org/10.1016/j.jpowsour.2008.02.022
Grgur B, Ristić V, Gvozdenović M, Maksimović MD, Jugović B. Polyaniline as possible anode materials for the lead acid batteries. in Journal of Power Sources. 2008;180(1):635-640.
doi:10.1016/j.jpowsour.2008.02.022 .
Grgur, Branimir, Ristić, V., Gvozdenović, Milica, Maksimović, Miodrag D., Jugović, Branimir, "Polyaniline as possible anode materials for the lead acid batteries" in Journal of Power Sources, 180, no. 1 (2008):635-640,
https://doi.org/10.1016/j.jpowsour.2008.02.022 . .
26
22
27

Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte

Obradović, Maja; Bosnjakov, GZ; Stevanović, Rade M.; Maksimović, Miodrag D.; Despić, Aleksandar R.

(Elsevier, 2006)

TY  - JOUR
AU  - Obradović, Maja
AU  - Bosnjakov, GZ
AU  - Stevanović, Rade M.
AU  - Maksimović, Miodrag D.
AU  - Despić, Aleksandar R.
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5457
AB  - The effect of the potential of deposition and electrode rotation rate on current efficiency and partial current density of nickel deposition from ammonia-citrate electrolyte with and without tungstate ions was investigated. In addition, the effect of pulse deposition parameters, such as frequency and ratio between pause and deposition time, t(p)/t(c), oil current efficiency and composition of Ni-W alloys was investigated. Partial current densities of tungsten and nickel deposition were calculated from experimental results and compared with those in direct current (dc) deposition at the same average current density, as well as with those calculated using theoretical equations for the pulse current (pc) deposition process controlled by mass transport. Obtained partial current densities of tungsten are in fair agreement with those predicted by theory in both cases, as a function of dimensionless pulse period and as a function of the t(p)/t(c) ratio. That confirms that the tungsten deposition process is controlled by mass transport. Dependences of the partial current densities of nickel deposition on the rotation rate as well as on the pc variables (frequency and pause to pulse ratio) were attributed to changes in surface concentration of ammonia and the pH.
PB  - Elsevier
T2  - Surface and Coatings Technology
T1  - Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte
EP  - 4207
IS  - 14-15
SP  - 4201
VL  - 200
DO  - 10.1016/j.surfcoat.2004.12.013
ER  - 
@article{
author = "Obradović, Maja and Bosnjakov, GZ and Stevanović, Rade M. and Maksimović, Miodrag D. and Despić, Aleksandar R.",
year = "2006",
abstract = "The effect of the potential of deposition and electrode rotation rate on current efficiency and partial current density of nickel deposition from ammonia-citrate electrolyte with and without tungstate ions was investigated. In addition, the effect of pulse deposition parameters, such as frequency and ratio between pause and deposition time, t(p)/t(c), oil current efficiency and composition of Ni-W alloys was investigated. Partial current densities of tungsten and nickel deposition were calculated from experimental results and compared with those in direct current (dc) deposition at the same average current density, as well as with those calculated using theoretical equations for the pulse current (pc) deposition process controlled by mass transport. Obtained partial current densities of tungsten are in fair agreement with those predicted by theory in both cases, as a function of dimensionless pulse period and as a function of the t(p)/t(c) ratio. That confirms that the tungsten deposition process is controlled by mass transport. Dependences of the partial current densities of nickel deposition on the rotation rate as well as on the pc variables (frequency and pause to pulse ratio) were attributed to changes in surface concentration of ammonia and the pH.",
publisher = "Elsevier",
journal = "Surface and Coatings Technology",
title = "Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte",
pages = "4207-4201",
number = "14-15",
volume = "200",
doi = "10.1016/j.surfcoat.2004.12.013"
}
Obradović, M., Bosnjakov, G., Stevanović, R. M., Maksimović, M. D.,& Despić, A. R.. (2006). Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte. in Surface and Coatings Technology
Elsevier., 200(14-15), 4201-4207.
https://doi.org/10.1016/j.surfcoat.2004.12.013
Obradović M, Bosnjakov G, Stevanović RM, Maksimović MD, Despić AR. Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte. in Surface and Coatings Technology. 2006;200(14-15):4201-4207.
doi:10.1016/j.surfcoat.2004.12.013 .
Obradović, Maja, Bosnjakov, GZ, Stevanović, Rade M., Maksimović, Miodrag D., Despić, Aleksandar R., "Pulse and direct current plating of Ni-W alloys from ammonia-citrate electrolyte" in Surface and Coatings Technology, 200, no. 14-15 (2006):4201-4207,
https://doi.org/10.1016/j.surfcoat.2004.12.013 . .
46
39
47

Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries

Jugović, Branimir; Trišović, Tomislav; Stevanović, Jasmina; Maksimović, Miodrag D.; Grgur, Branimir

(Pergamon-Elsevier Science Ltd, Oxford, 2006)

TY  - JOUR
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
AU  - Maksimović, Miodrag D.
AU  - Grgur, Branimir
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/933
AB  - Electrochemical behavior of zinc and thin polyaniline (PANI) polymerized from 0.1 M HCl to 0.1 M aniline on graphite electrode, in 0.2 M ZnCl(2) and 0.50 M NH(4)Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte zinc electrode shows negative shift of the open circuit potential of similar to 130 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation. In citrate/chloride electrolyte zinc dendrite formation were suppressed. In the range of investigated charge/discharge current densities of 0.25-1 mA cm(-2), initially obtained specific capacity was in the range of 140-85 mAh g(-1), respectively. In cycling regime specific capacity and columbic efficiency were affected with anodic potential limits. For anodic potential limits of 0.32 V (SCE) citrate/chloride electrolyte shows better characteristic than chloride electrolyte, due to the influence of citrate ions on negative shift of doping reaction. Increasing anodic potential limit to 0.5 V (SCE), leads to faster decrease of specific capacity in citrate/chloride than in chloride electrolyte, which was explained by higher hydrophilic effect of citrate anions.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries
EP  - 6274
IS  - 28
SP  - 6268
VL  - 51
DO  - 10.1016/j.electacta.2006.04.009
ER  - 
@article{
author = "Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Maksimović, Miodrag D. and Grgur, Branimir",
year = "2006",
abstract = "Electrochemical behavior of zinc and thin polyaniline (PANI) polymerized from 0.1 M HCl to 0.1 M aniline on graphite electrode, in 0.2 M ZnCl(2) and 0.50 M NH(4)Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte zinc electrode shows negative shift of the open circuit potential of similar to 130 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation. In citrate/chloride electrolyte zinc dendrite formation were suppressed. In the range of investigated charge/discharge current densities of 0.25-1 mA cm(-2), initially obtained specific capacity was in the range of 140-85 mAh g(-1), respectively. In cycling regime specific capacity and columbic efficiency were affected with anodic potential limits. For anodic potential limits of 0.32 V (SCE) citrate/chloride electrolyte shows better characteristic than chloride electrolyte, due to the influence of citrate ions on negative shift of doping reaction. Increasing anodic potential limit to 0.5 V (SCE), leads to faster decrease of specific capacity in citrate/chloride than in chloride electrolyte, which was explained by higher hydrophilic effect of citrate anions.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries",
pages = "6274-6268",
number = "28",
volume = "51",
doi = "10.1016/j.electacta.2006.04.009"
}
Jugović, B., Trišović, T., Stevanović, J., Maksimović, M. D.,& Grgur, B.. (2006). Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 51(28), 6268-6274.
https://doi.org/10.1016/j.electacta.2006.04.009
Jugović B, Trišović T, Stevanović J, Maksimović MD, Grgur B. Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries. in Electrochimica Acta. 2006;51(28):6268-6274.
doi:10.1016/j.electacta.2006.04.009 .
Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Maksimović, Miodrag D., Grgur, Branimir, "Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries" in Electrochimica Acta, 51, no. 28 (2006):6268-6274,
https://doi.org/10.1016/j.electacta.2006.04.009 . .
22
22
24

Electrochemical deposition and corrosion stability of Zn-Co alloy coatings

Bajat, Jelena; Maksimović, Miodrag D.

(Engineering Society for Corrosion, Belgrade, Serbia, 2006)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/980
AB  - The influence of the type of the deposition solution, deposition current density and temperature of deposition solution on the phase structure and corrosion properties of Zn-Co alloys was examined. Alloys were deposited on a rotating disc electrode from chloride and sulphate plating bath. The phase structure was determined by anodic linear sweep voltammetry (ALSV) and corrosion properties by polarization measurements. It was shown that Zn-Co alloys with the best corrosion properties, among all investigated in this work, were obtained from chloride plating bath at room temperature at 4,5 and 5 A dm-2.
AB  - Izučavan je uticaj vrste rastvora za taloženje, gustine struje taloženja i temperature rastvora za taloženje na fazni sastav, kao i na korozionu stabilnost legura Zn-Co. Legure su taložene na rotirajućoj disk elektrodi iz sulfatnog i hloridnog rastvora. Fazni sastav legura je određivan metodom anodne linearne promene potencijala (ALPP), a koroziona stabilnost polarizacionim merenjima. Pokazano je da najveću korozionu stabilnost imaju legure dobijene taloženjem iz hloridnog rastvora na sobnoj temperaturi sa 4,5 i 5 A dm-2.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Electrochemical deposition and corrosion stability of Zn-Co alloy coatings
T1  - Elektrohemijsko taloženje i koroziona stabilnost prevlaka Zn-Co legura
EP  - 22
IS  - 4
SP  - 17
VL  - 47
UR  - https://hdl.handle.net/21.15107/rcub_technorep_980
ER  - 
@article{
author = "Bajat, Jelena and Maksimović, Miodrag D.",
year = "2006",
abstract = "The influence of the type of the deposition solution, deposition current density and temperature of deposition solution on the phase structure and corrosion properties of Zn-Co alloys was examined. Alloys were deposited on a rotating disc electrode from chloride and sulphate plating bath. The phase structure was determined by anodic linear sweep voltammetry (ALSV) and corrosion properties by polarization measurements. It was shown that Zn-Co alloys with the best corrosion properties, among all investigated in this work, were obtained from chloride plating bath at room temperature at 4,5 and 5 A dm-2., Izučavan je uticaj vrste rastvora za taloženje, gustine struje taloženja i temperature rastvora za taloženje na fazni sastav, kao i na korozionu stabilnost legura Zn-Co. Legure su taložene na rotirajućoj disk elektrodi iz sulfatnog i hloridnog rastvora. Fazni sastav legura je određivan metodom anodne linearne promene potencijala (ALPP), a koroziona stabilnost polarizacionim merenjima. Pokazano je da najveću korozionu stabilnost imaju legure dobijene taloženjem iz hloridnog rastvora na sobnoj temperaturi sa 4,5 i 5 A dm-2.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Electrochemical deposition and corrosion stability of Zn-Co alloy coatings, Elektrohemijsko taloženje i koroziona stabilnost prevlaka Zn-Co legura",
pages = "22-17",
number = "4",
volume = "47",
url = "https://hdl.handle.net/21.15107/rcub_technorep_980"
}
Bajat, J.,& Maksimović, M. D.. (2006). Electrochemical deposition and corrosion stability of Zn-Co alloy coatings. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 47(4), 17-22.
https://hdl.handle.net/21.15107/rcub_technorep_980
Bajat J, Maksimović MD. Electrochemical deposition and corrosion stability of Zn-Co alloy coatings. in Zaštita materijala. 2006;47(4):17-22.
https://hdl.handle.net/21.15107/rcub_technorep_980 .
Bajat, Jelena, Maksimović, Miodrag D., "Electrochemical deposition and corrosion stability of Zn-Co alloy coatings" in Zaštita materijala, 47, no. 4 (2006):17-22,
https://hdl.handle.net/21.15107/rcub_technorep_980 .

Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current

Bajat, Jelena; Petrović, Aleksandra B.; Maksimović, Miodrag D.

(Serbian Chemical Society, Belgrade, 2005)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Petrović, Aleksandra B.
AU  - Maksimović, Miodrag D.
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/793
AB  - Zn-Ni alloys electrochemically deposited on steel under various deposition conditions were investigated. The alloys were deposited on a rotating disc electrode and on a steel panel from chloride solutions by direct and reverse current. The influence of reverse plating variables (cathodic and anodic current densities and their time duration) on the composition, phase structure and corrosion properties were investigated. The chemical content and phase composition affect the anticorrosive properties of Zn-Ni alloys during exposure to a corrosive agent (3%NaCl solution). It was shown that the Zn-Ni alloy electrodeposited by reverse current with a full period T = 1 s and r=0.2 exhibits the best corrosion properties of all the investigated alloys deposited by reverse current.
AB  - Ispitivani su hemijski sastav i fazna struktura legura Zn-Ni dobijenih primenom različitih parametara elektrohemijskog taloženja. Legure su taložene na rotirajućoj disk elektrodi i na čeličnim pločicama konstantnom i reversnom strujom. Ispitivani su parametri reversne struje (katodne i anodne gustine struje taloženja, i njihovog vremena trajanja) na sastav, faznu strukturu i korozione osobine legura. Pokazano je da hemijski sastav i fazna struktura utiču na korozione osobine Zn-Ni legura tokom izlaganja dejstvu rastvora 3%NaCl. Legura Zn-Ni dobijena reversnom strujom sa T=1 s i r=0.2 ima najbolje korozione osobine.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current
T1  - Elektrohemijsko taloženje i karakterizacija legura cink-nikal dobijenih konstantnom i reversnom strujom
EP  - 1439
IS  - 12
SP  - 1427
VL  - 70
UR  - https://hdl.handle.net/21.15107/rcub_technorep_793
ER  - 
@article{
author = "Bajat, Jelena and Petrović, Aleksandra B. and Maksimović, Miodrag D.",
year = "2005",
abstract = "Zn-Ni alloys electrochemically deposited on steel under various deposition conditions were investigated. The alloys were deposited on a rotating disc electrode and on a steel panel from chloride solutions by direct and reverse current. The influence of reverse plating variables (cathodic and anodic current densities and their time duration) on the composition, phase structure and corrosion properties were investigated. The chemical content and phase composition affect the anticorrosive properties of Zn-Ni alloys during exposure to a corrosive agent (3%NaCl solution). It was shown that the Zn-Ni alloy electrodeposited by reverse current with a full period T = 1 s and r=0.2 exhibits the best corrosion properties of all the investigated alloys deposited by reverse current., Ispitivani su hemijski sastav i fazna struktura legura Zn-Ni dobijenih primenom različitih parametara elektrohemijskog taloženja. Legure su taložene na rotirajućoj disk elektrodi i na čeličnim pločicama konstantnom i reversnom strujom. Ispitivani su parametri reversne struje (katodne i anodne gustine struje taloženja, i njihovog vremena trajanja) na sastav, faznu strukturu i korozione osobine legura. Pokazano je da hemijski sastav i fazna struktura utiču na korozione osobine Zn-Ni legura tokom izlaganja dejstvu rastvora 3%NaCl. Legura Zn-Ni dobijena reversnom strujom sa T=1 s i r=0.2 ima najbolje korozione osobine.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current, Elektrohemijsko taloženje i karakterizacija legura cink-nikal dobijenih konstantnom i reversnom strujom",
pages = "1439-1427",
number = "12",
volume = "70",
url = "https://hdl.handle.net/21.15107/rcub_technorep_793"
}
Bajat, J., Petrović, A. B.,& Maksimović, M. D.. (2005). Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 70(12), 1427-1439.
https://hdl.handle.net/21.15107/rcub_technorep_793
Bajat J, Petrović AB, Maksimović MD. Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current. in Journal of the Serbian Chemical Society. 2005;70(12):1427-1439.
https://hdl.handle.net/21.15107/rcub_technorep_793 .
Bajat, Jelena, Petrović, Aleksandra B., Maksimović, Miodrag D., "Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and reverse current" in Journal of the Serbian Chemical Society, 70, no. 12 (2005):1427-1439,
https://hdl.handle.net/21.15107/rcub_technorep_793 .
27
30

The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings

Bajat, Jelena; Mišković-Stanković, Vesna; Maksimović, Miodrag D.

(Engineering Society for Corrosion, Belgrade, Serbia, 2005)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Maksimović, Miodrag D.
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/846
AB  - Prior to cathaporetic epoxy coating deposition steel surface was modified by chemical deposition of hot dip galvanized steel and by electrochemical deposition of zinc alloys with iron group of elements (Ni, Co and Fe). The influence of the deposition solution and different deposition parameters on the chemical content, phase structure and corrosion properties of zinc alloys was examined. It was shown that the composition of the plating bath its temperature and the deposition current density have a big influence on the corrosion behavior of zinc alloys, as well as on the corrosion stability of the protective system zinc alloy / epoxy coating. Among all investigated zinc alloys Zn-Ni alloy deposited from chloride bath at 2 A dm2 exhibited the best corrosion properties. The corrosion stability of the protective system zinc alloy / epoxy coating was investigated by determining the values of pore resistance and charge-transfer resistance (obtained from impedance measurements (EIS)). Sorption characteristics were determined by gravimetric measurements and thermal stability by thermo gravimetric analysis. The kinetics of hydrogen evolution on different substrates (the first step of epoxy coating electrode position) was determined, as well as the wet ability of different substrates by polymer solution. The influence of these two factors on the porosity and thermal stability of epoxy coatings was shown. It was shown that epoxy coating on Zn-Ni alloy obtained from chloride bath has the highest corrosion stability among all investigated protective systems (the highest values of pore resistance and charge transfer resistance), while epoxy coating on Zn-Fe alloy has the lowest corrosion stability. It was also shown that corrosion processes on the steel, under the epoxy coating, begin later on Zn-Ni.
AB  - Površina čelika je modifikovana elektrohemijskim taloženjem legura cinka sa elementima grupe gvožđa (Ni, Сo i Fe) i prevlakom cinka, pre nanošenja kataforetske epoksidne prevlake. Ispitivanje uticaj sastava rastvora za taloženje i raznih parametara taloženja na hemijski i fazni sastav legura cinka, kao i na gustine struje korozije legura. Pokazano je da sastav rastvora za taloženje, njegova temperatura i gustina struje taloženja imaju veliki uticaj na koroziono ponašanje legura cinka, kao i na korozionu stabilnost zaštitnih sistema legura cinka / epoksidna prevlaka na čeliku. Od svih ispitivanih legura Zn-Ni legura dobijena taloženjem iz hloridnog rastvora sa 2 A dm2 ima najmanju gustinu struje korozije. Zaštitna svojstva sistema legura cinka / epoksidna prevlaka na čeliku su određivana merenjem vrednosti otpornosti elektrolita u рorama prevlake i otpornosti prenosu naelektrisanja kroz graničnu površinu metal-elektroli (metoda spektroskopije elektrohemijske impedancije (SEI)). Sorpcione karakteristike su određivane gravimetrijskim merenjima, a termička stabilnost termogravimetrijskom analizom. Ispitivane su brzine izdvajanja vodonika, kao prvog stupnja u kataforetskom taloženju epoksidne prevlake, na različitim supstratima, kao i kvašljivost supstrata rastvorom polimera. Pokazano je kako ova dva faktora zajedno utiču na poroznost i termičku stabilnost epoksidnih prevlaka. S obzirom na najveće vrednosti otpornosti elektrolita u рorama prevlake i otpornosti prenosa naelektrisanja kroz graničnu površinu metal-elektrolit od svih ispitivanih legura najbolja svojstva pokazuje legura Zn-Ni a najlošija Zn-Fe. Pokazano je, takođe, da se početak korozionih procesa na čeliku, ispod prevlaka legura, najkasnije javlja u slučaju Zn-Ni legure.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings
T1  - Uticaj elektrohemijski taloženih legura cinka na čeliku na zaštitna svojstva epoksidne kataforetske prevlake
EP  - 22
IS  - 2
SP  - 11
VL  - 46
UR  - https://hdl.handle.net/21.15107/rcub_technorep_846
ER  - 
@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Maksimović, Miodrag D.",
year = "2005",
abstract = "Prior to cathaporetic epoxy coating deposition steel surface was modified by chemical deposition of hot dip galvanized steel and by electrochemical deposition of zinc alloys with iron group of elements (Ni, Co and Fe). The influence of the deposition solution and different deposition parameters on the chemical content, phase structure and corrosion properties of zinc alloys was examined. It was shown that the composition of the plating bath its temperature and the deposition current density have a big influence on the corrosion behavior of zinc alloys, as well as on the corrosion stability of the protective system zinc alloy / epoxy coating. Among all investigated zinc alloys Zn-Ni alloy deposited from chloride bath at 2 A dm2 exhibited the best corrosion properties. The corrosion stability of the protective system zinc alloy / epoxy coating was investigated by determining the values of pore resistance and charge-transfer resistance (obtained from impedance measurements (EIS)). Sorption characteristics were determined by gravimetric measurements and thermal stability by thermo gravimetric analysis. The kinetics of hydrogen evolution on different substrates (the first step of epoxy coating electrode position) was determined, as well as the wet ability of different substrates by polymer solution. The influence of these two factors on the porosity and thermal stability of epoxy coatings was shown. It was shown that epoxy coating on Zn-Ni alloy obtained from chloride bath has the highest corrosion stability among all investigated protective systems (the highest values of pore resistance and charge transfer resistance), while epoxy coating on Zn-Fe alloy has the lowest corrosion stability. It was also shown that corrosion processes on the steel, under the epoxy coating, begin later on Zn-Ni., Površina čelika je modifikovana elektrohemijskim taloženjem legura cinka sa elementima grupe gvožđa (Ni, Сo i Fe) i prevlakom cinka, pre nanošenja kataforetske epoksidne prevlake. Ispitivanje uticaj sastava rastvora za taloženje i raznih parametara taloženja na hemijski i fazni sastav legura cinka, kao i na gustine struje korozije legura. Pokazano je da sastav rastvora za taloženje, njegova temperatura i gustina struje taloženja imaju veliki uticaj na koroziono ponašanje legura cinka, kao i na korozionu stabilnost zaštitnih sistema legura cinka / epoksidna prevlaka na čeliku. Od svih ispitivanih legura Zn-Ni legura dobijena taloženjem iz hloridnog rastvora sa 2 A dm2 ima najmanju gustinu struje korozije. Zaštitna svojstva sistema legura cinka / epoksidna prevlaka na čeliku su određivana merenjem vrednosti otpornosti elektrolita u рorama prevlake i otpornosti prenosu naelektrisanja kroz graničnu površinu metal-elektroli (metoda spektroskopije elektrohemijske impedancije (SEI)). Sorpcione karakteristike su određivane gravimetrijskim merenjima, a termička stabilnost termogravimetrijskom analizom. Ispitivane su brzine izdvajanja vodonika, kao prvog stupnja u kataforetskom taloženju epoksidne prevlake, na različitim supstratima, kao i kvašljivost supstrata rastvorom polimera. Pokazano je kako ova dva faktora zajedno utiču na poroznost i termičku stabilnost epoksidnih prevlaka. S obzirom na najveće vrednosti otpornosti elektrolita u рorama prevlake i otpornosti prenosa naelektrisanja kroz graničnu površinu metal-elektrolit od svih ispitivanih legura najbolja svojstva pokazuje legura Zn-Ni a najlošija Zn-Fe. Pokazano je, takođe, da se početak korozionih procesa na čeliku, ispod prevlaka legura, najkasnije javlja u slučaju Zn-Ni legure.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings, Uticaj elektrohemijski taloženih legura cinka na čeliku na zaštitna svojstva epoksidne kataforetske prevlake",
pages = "22-11",
number = "2",
volume = "46",
url = "https://hdl.handle.net/21.15107/rcub_technorep_846"
}
Bajat, J., Mišković-Stanković, V.,& Maksimović, M. D.. (2005). The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 46(2), 11-22.
https://hdl.handle.net/21.15107/rcub_technorep_846
Bajat J, Mišković-Stanković V, Maksimović MD. The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings. in Zaštita materijala. 2005;46(2):11-22.
https://hdl.handle.net/21.15107/rcub_technorep_846 .
Bajat, Jelena, Mišković-Stanković, Vesna, Maksimović, Miodrag D., "The influence of electrochemically deposited zinc alloys on steel on the protective properties of cathaporetic epoxy coatings" in Zaštita materijala, 46, no. 2 (2005):11-22,
https://hdl.handle.net/21.15107/rcub_technorep_846 .

Electrochemical deposition and characterization of Zn-Fe alloys

Bajat, Jelena; Mišković-Stanković, Vesna; Maksimović, Miodrag D.; Dražić, Dragutin M.; Zec, Slavica

(Serbian Chemical Society, Belgrade, 2004)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Maksimović, Miodrag D.
AU  - Dražić, Dragutin M.
AU  - Zec, Slavica
PY  - 2004
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/662
AB  - Zn–Fe alloy electrochemically deposited on steel under various deposition conditions were investigated using anodic linear sweep voltammetry (ALSV) and X-ray diffraction (XRD) analysis for phase structure determination, energy dispersive X-ray (EDX) analysis for determination of chemical composition and polarization measurements and open circuit potential measurements for determination of corrosion properties. The influence of deposition current density on the chemical composition, phase structure and corrosion stability of Zn–Fe alloys was studied. It was shown that deposition current density strongly affects the corrosion stability of Zn–Fe alloys, while Zn–Fe alloy electrodeposited at 4Adm-2 exhibited the lowest corrosion rate.
AB  - Legure Zn–Fe elektrohemijski taložene na čeliku pod različitim uslovima ispitivane su primenom anodne linearne promene potencijala i difrakcije X-zraka, za određivanje fazne strukture, spektroskopije energetski dispergovanih X-zraka, za određivanje hemijskog sastava i polarizacionih merenja kao i merenja potencijala otvorenog kola, za određivanje korozione stabilnosti. Proučavan je uticaj gustine struje taloženja na hemijski sastav fazne strukture i korozionu stabilnost Zn–Fe legura. Pokazano je da gustina struje taloženja veoma utiče na korozionu stabilnost Zn–Fe legura, i da legura taložena gustinom struje od 4 Adm-2 ima najmanju brzinu korozije.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical deposition and characterization of Zn-Fe alloys
T1  - Elektrohemijsko taloženje i karakterizacija Zn-Fe legura
EP  - 815
IS  - 10
SP  - 807
VL  - 69
UR  - https://hdl.handle.net/21.15107/rcub_technorep_662
ER  - 
@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Maksimović, Miodrag D. and Dražić, Dragutin M. and Zec, Slavica",
year = "2004",
abstract = "Zn–Fe alloy electrochemically deposited on steel under various deposition conditions were investigated using anodic linear sweep voltammetry (ALSV) and X-ray diffraction (XRD) analysis for phase structure determination, energy dispersive X-ray (EDX) analysis for determination of chemical composition and polarization measurements and open circuit potential measurements for determination of corrosion properties. The influence of deposition current density on the chemical composition, phase structure and corrosion stability of Zn–Fe alloys was studied. It was shown that deposition current density strongly affects the corrosion stability of Zn–Fe alloys, while Zn–Fe alloy electrodeposited at 4Adm-2 exhibited the lowest corrosion rate., Legure Zn–Fe elektrohemijski taložene na čeliku pod različitim uslovima ispitivane su primenom anodne linearne promene potencijala i difrakcije X-zraka, za određivanje fazne strukture, spektroskopije energetski dispergovanih X-zraka, za određivanje hemijskog sastava i polarizacionih merenja kao i merenja potencijala otvorenog kola, za određivanje korozione stabilnosti. Proučavan je uticaj gustine struje taloženja na hemijski sastav fazne strukture i korozionu stabilnost Zn–Fe legura. Pokazano je da gustina struje taloženja veoma utiče na korozionu stabilnost Zn–Fe legura, i da legura taložena gustinom struje od 4 Adm-2 ima najmanju brzinu korozije.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical deposition and characterization of Zn-Fe alloys, Elektrohemijsko taloženje i karakterizacija Zn-Fe legura",
pages = "815-807",
number = "10",
volume = "69",
url = "https://hdl.handle.net/21.15107/rcub_technorep_662"
}
Bajat, J., Mišković-Stanković, V., Maksimović, M. D., Dražić, D. M.,& Zec, S.. (2004). Electrochemical deposition and characterization of Zn-Fe alloys. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 69(10), 807-815.
https://hdl.handle.net/21.15107/rcub_technorep_662
Bajat J, Mišković-Stanković V, Maksimović MD, Dražić DM, Zec S. Electrochemical deposition and characterization of Zn-Fe alloys. in Journal of the Serbian Chemical Society. 2004;69(10):807-815.
https://hdl.handle.net/21.15107/rcub_technorep_662 .
Bajat, Jelena, Mišković-Stanković, Vesna, Maksimović, Miodrag D., Dražić, Dragutin M., Zec, Slavica, "Electrochemical deposition and characterization of Zn-Fe alloys" in Journal of the Serbian Chemical Society, 69, no. 10 (2004):807-815,
https://hdl.handle.net/21.15107/rcub_technorep_662 .
16
19

Electrochemical deposition and characterization of Zn-Fe alloy coatings

Bajat, Jelena; Maksimović, Miodrag D.

(Engineering Society for Corrosion, Belgrade, Serbia, 2003)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
PY  - 2003
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/523
AB  - The influence of the deposition current density and temperature of deposition solution on the phase structure and corrosion properties of Zn-Fe alloys was examined. Alloys were deposited on a rotating disc electrode and on steel panels from alkaline plating bath. The chemical content was determined by EDX analysis, phase structure by anodic linear sweep voltammetry (ALSV) and corrosion properties by polarization measurements and by determining the time of the red rust appearance for Zn-Fe alloys. It was shown that Zn-Fe alloy with the best corrosion properties, among all investigated n this work, was obtained at room temperature at 4 A dm"2.
AB  - Izučavan je uticaj gustine struje taloženja i temperature rastvora za taloženje na hemijski i fazni sastav, kao i na korozionu stabilnost legura Zn-Fe. Legure su taložene na rotirajućoj disk elektrodi i čeličnim pločicama iz alkalnog rastvora. Hemijski sastav je određivan analizom disperzije X-zraka (EDX), fazni sastav metodom anodne linearne promene potencijala (ALPP), a koroziona stabilnost polarizacionim merenjima, kao i praćenjem promene potencijala otvorenog kola sa vremenom delovanja korozionog agensa. Pokazano je da najveću korozionu stabilnost ima legura dobijena taloženjem na sobnoj temperaturi sa 4 A dm2.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Electrochemical deposition and characterization of Zn-Fe alloy coatings
T1  - Elektrohemijsko dobijanje i karakterizacija prevlaka legura cink-gvožđe
EP  - 126
IS  - 4
SP  - 121
VL  - 44
UR  - https://hdl.handle.net/21.15107/rcub_technorep_523
ER  - 
@article{
author = "Bajat, Jelena and Maksimović, Miodrag D.",
year = "2003",
abstract = "The influence of the deposition current density and temperature of deposition solution on the phase structure and corrosion properties of Zn-Fe alloys was examined. Alloys were deposited on a rotating disc electrode and on steel panels from alkaline plating bath. The chemical content was determined by EDX analysis, phase structure by anodic linear sweep voltammetry (ALSV) and corrosion properties by polarization measurements and by determining the time of the red rust appearance for Zn-Fe alloys. It was shown that Zn-Fe alloy with the best corrosion properties, among all investigated n this work, was obtained at room temperature at 4 A dm"2., Izučavan je uticaj gustine struje taloženja i temperature rastvora za taloženje na hemijski i fazni sastav, kao i na korozionu stabilnost legura Zn-Fe. Legure su taložene na rotirajućoj disk elektrodi i čeličnim pločicama iz alkalnog rastvora. Hemijski sastav je određivan analizom disperzije X-zraka (EDX), fazni sastav metodom anodne linearne promene potencijala (ALPP), a koroziona stabilnost polarizacionim merenjima, kao i praćenjem promene potencijala otvorenog kola sa vremenom delovanja korozionog agensa. Pokazano je da najveću korozionu stabilnost ima legura dobijena taloženjem na sobnoj temperaturi sa 4 A dm2.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Electrochemical deposition and characterization of Zn-Fe alloy coatings, Elektrohemijsko dobijanje i karakterizacija prevlaka legura cink-gvožđe",
pages = "126-121",
number = "4",
volume = "44",
url = "https://hdl.handle.net/21.15107/rcub_technorep_523"
}
Bajat, J.,& Maksimović, M. D.. (2003). Electrochemical deposition and characterization of Zn-Fe alloy coatings. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 44(4), 121-126.
https://hdl.handle.net/21.15107/rcub_technorep_523
Bajat J, Maksimović MD. Electrochemical deposition and characterization of Zn-Fe alloy coatings. in Zaštita materijala. 2003;44(4):121-126.
https://hdl.handle.net/21.15107/rcub_technorep_523 .
Bajat, Jelena, Maksimović, Miodrag D., "Electrochemical deposition and characterization of Zn-Fe alloy coatings" in Zaštita materijala, 44, no. 4 (2003):121-126,
https://hdl.handle.net/21.15107/rcub_technorep_523 .

Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current

Bajat, Jelena; Maksimović, Miodrag D.; Radović, Goran R.

(Serbian Chemical Society, Belgrade, 2002)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
AU  - Radović, Goran R.
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/495
AB  - Chemical composition and phase structure of Zn-Ni alloys obtained by electrochemical deposition under various conditions were investigated. The alloys were deposited on a rotating disc electrode and steel panel from chloride solutions by direct and pulse current. The influence of the pulse plating variables (on-time, off-time, relation of off- and on-time) on the composition, phase structure and corrosion properties were investigated. The phase composition affects the anticorrosive properties of Zn-Ni alloys during exposure to a corrosive agent (3% NaCl solution). It was shown that a Zn-Ni alloy electrodeposited by pulse current with a pulse time of 1 ms and an off- and on-time ratio of 1 exhibits the best corrosion properties.
AB  - Ispitivani su hemijski sastav i fazna struktura legura Zn-Ni dobijenih primenom različitih parametara elektrohemijskog taloženja. Legure su taložene iz hloridnog rastvora na rotirajućoj disk elektrodi i na čeličnim pločicama konstantnom i pulsirajućom strujom. Ispitivani su parametri pulsirajućeg taloženja (katodnog vremena, vremena pauze i odnosa pauze i katodnog vremena) na sastav, faznu strukturu i korozione osobine legura. Pokazano je da fazni sastav utiče na antikorozione osobine Zn-Ni legura tokom izlaganja dejstvu rastvora 3% NaCl. Legura Zn-Ni dobijena pulsirajućim taloženjem sa katodnim vremenom od 1 ms i odnosom pauze i pulsa od 1 ima najbolje korozione osobine.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current
T1  - Elektrohemijsko taloženje i karakterizacija legura cink-nikal dobijenih konstantnom i pulsirajućom strujom
EP  - 634
IS  - 8-9
SP  - 625
VL  - 67
UR  - https://hdl.handle.net/21.15107/rcub_technorep_495
ER  - 
@article{
author = "Bajat, Jelena and Maksimović, Miodrag D. and Radović, Goran R.",
year = "2002",
abstract = "Chemical composition and phase structure of Zn-Ni alloys obtained by electrochemical deposition under various conditions were investigated. The alloys were deposited on a rotating disc electrode and steel panel from chloride solutions by direct and pulse current. The influence of the pulse plating variables (on-time, off-time, relation of off- and on-time) on the composition, phase structure and corrosion properties were investigated. The phase composition affects the anticorrosive properties of Zn-Ni alloys during exposure to a corrosive agent (3% NaCl solution). It was shown that a Zn-Ni alloy electrodeposited by pulse current with a pulse time of 1 ms and an off- and on-time ratio of 1 exhibits the best corrosion properties., Ispitivani su hemijski sastav i fazna struktura legura Zn-Ni dobijenih primenom različitih parametara elektrohemijskog taloženja. Legure su taložene iz hloridnog rastvora na rotirajućoj disk elektrodi i na čeličnim pločicama konstantnom i pulsirajućom strujom. Ispitivani su parametri pulsirajućeg taloženja (katodnog vremena, vremena pauze i odnosa pauze i katodnog vremena) na sastav, faznu strukturu i korozione osobine legura. Pokazano je da fazni sastav utiče na antikorozione osobine Zn-Ni legura tokom izlaganja dejstvu rastvora 3% NaCl. Legura Zn-Ni dobijena pulsirajućim taloženjem sa katodnim vremenom od 1 ms i odnosom pauze i pulsa od 1 ima najbolje korozione osobine.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current, Elektrohemijsko taloženje i karakterizacija legura cink-nikal dobijenih konstantnom i pulsirajućom strujom",
pages = "634-625",
number = "8-9",
volume = "67",
url = "https://hdl.handle.net/21.15107/rcub_technorep_495"
}
Bajat, J., Maksimović, M. D.,& Radović, G. R.. (2002). Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 67(8-9), 625-634.
https://hdl.handle.net/21.15107/rcub_technorep_495
Bajat J, Maksimović MD, Radović GR. Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current. in Journal of the Serbian Chemical Society. 2002;67(8-9):625-634.
https://hdl.handle.net/21.15107/rcub_technorep_495 .
Bajat, Jelena, Maksimović, Miodrag D., Radović, Goran R., "Electrochemical deposition and characterization of zinc-nickel alloys deposited by direct and pulse current" in Journal of the Serbian Chemical Society, 67, no. 8-9 (2002):625-634,
https://hdl.handle.net/21.15107/rcub_technorep_495 .
23
28

Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy

Bajat, Jelena; Mišković-Stanković, Vesna; Maksimović, Miodrag D.; Dražić, Dragutin M.; Zec, Slavica

(Pergamon-Elsevier Science Ltd, Oxford, 2002)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Maksimović, Miodrag D.
AU  - Dražić, Dragutin M.
AU  - Zec, Slavica
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/447
AB  - Zn-Co alloys electrochemically deposited on steel under various deposition conditions were investigated. The influence of deposition current density, temperature and composition of deposition solution on the phase structure and corrosion properties of Zn-Co alloys were studied. It was found that Zn-Co alloy obtained from chloride solution at 5 A dm(-2) showed the best corrosion properties, so this alloy was chosen for further examination. Epoxy coating was electrodeposited on steel and steel modified by Zn-Co alloy using constant voltage method. The effect of Zn-Co alloy on the corrosion behavior of the protective system based on epoxy coating is interpreted in terms of electrochemical and transport properties, as well as of thermal stability.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy
EP  - 4112
IS  - 25
SP  - 4101
VL  - 47
DO  - 10.1016/S0013-4686(02)00418-8
ER  - 
@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Maksimović, Miodrag D. and Dražić, Dragutin M. and Zec, Slavica",
year = "2002",
abstract = "Zn-Co alloys electrochemically deposited on steel under various deposition conditions were investigated. The influence of deposition current density, temperature and composition of deposition solution on the phase structure and corrosion properties of Zn-Co alloys were studied. It was found that Zn-Co alloy obtained from chloride solution at 5 A dm(-2) showed the best corrosion properties, so this alloy was chosen for further examination. Epoxy coating was electrodeposited on steel and steel modified by Zn-Co alloy using constant voltage method. The effect of Zn-Co alloy on the corrosion behavior of the protective system based on epoxy coating is interpreted in terms of electrochemical and transport properties, as well as of thermal stability.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy",
pages = "4112-4101",
number = "25",
volume = "47",
doi = "10.1016/S0013-4686(02)00418-8"
}
Bajat, J., Mišković-Stanković, V., Maksimović, M. D., Dražić, D. M.,& Zec, S.. (2002). Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 47(25), 4101-4112.
https://doi.org/10.1016/S0013-4686(02)00418-8
Bajat J, Mišković-Stanković V, Maksimović MD, Dražić DM, Zec S. Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy. in Electrochimica Acta. 2002;47(25):4101-4112.
doi:10.1016/S0013-4686(02)00418-8 .
Bajat, Jelena, Mišković-Stanković, Vesna, Maksimović, Miodrag D., Dražić, Dragutin M., Zec, Slavica, "Electrochemical deposition and characterization of Zn-Co alloys and corrosion protection by electrodeposited epoxy coating on Zn-Co alloy" in Electrochimica Acta, 47, no. 25 (2002):4101-4112,
https://doi.org/10.1016/S0013-4686(02)00418-8 . .
62
66
69

Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel

Mišković-Stanković, Vesna; Zotović, Jelena B.; Maksimović, Miodrag D.

(2001)

TY  - JOUR
AU  - Mišković-Stanković, Vesna
AU  - Zotović, Jelena B.
AU  - Maksimović, Miodrag D.
PY  - 2001
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/342
AB  - Corrosion behaviour of electrodeposited epoxy coatings on electrochemically modified steel surface by Fe-P alloys of different chemical and phase structures has been investigated by exposure to 3% NaCl. The electrochemical impedance spectroscopy (EIS), polarisation measurements and corrosion potential time measurements have been used. The steel surface was modified by electrochemical deposition of thin films of Fe-P alloys from sulfate acid solution at various cut-rent densities, with the aim of improving the corrosion resistance of organic film. Epoxy topcoat was formed by cathodic electrodeposition of an epoxy resin on previously modified steel surface using constant voltage method (resin concentration 10 wt%, temperature 299 K, applied voltage 250 V). From the time dependence of pore resistance, coating capacitance and relative Permittivity of coating, obtained from EIS and corrosion potential time measurements it can be observed that the Fe-P alloys improve the corrosion stability of the protective system based on epoxy coating. The electrodeposition current densities, which cause different chemical and phase structures of Fe-P sublayers, exhibit the great influence on the formation and characteristics of epoxy coating.
T2  - Bulletin of Electrochemistry
T1  - Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel
EP  - 247
IS  - 6
SP  - 241
VL  - 17
UR  - https://hdl.handle.net/21.15107/rcub_technorep_342
ER  - 
@article{
author = "Mišković-Stanković, Vesna and Zotović, Jelena B. and Maksimović, Miodrag D.",
year = "2001",
abstract = "Corrosion behaviour of electrodeposited epoxy coatings on electrochemically modified steel surface by Fe-P alloys of different chemical and phase structures has been investigated by exposure to 3% NaCl. The electrochemical impedance spectroscopy (EIS), polarisation measurements and corrosion potential time measurements have been used. The steel surface was modified by electrochemical deposition of thin films of Fe-P alloys from sulfate acid solution at various cut-rent densities, with the aim of improving the corrosion resistance of organic film. Epoxy topcoat was formed by cathodic electrodeposition of an epoxy resin on previously modified steel surface using constant voltage method (resin concentration 10 wt%, temperature 299 K, applied voltage 250 V). From the time dependence of pore resistance, coating capacitance and relative Permittivity of coating, obtained from EIS and corrosion potential time measurements it can be observed that the Fe-P alloys improve the corrosion stability of the protective system based on epoxy coating. The electrodeposition current densities, which cause different chemical and phase structures of Fe-P sublayers, exhibit the great influence on the formation and characteristics of epoxy coating.",
journal = "Bulletin of Electrochemistry",
title = "Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel",
pages = "247-241",
number = "6",
volume = "17",
url = "https://hdl.handle.net/21.15107/rcub_technorep_342"
}
Mišković-Stanković, V., Zotović, J. B.,& Maksimović, M. D.. (2001). Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel. in Bulletin of Electrochemistry, 17(6), 241-247.
https://hdl.handle.net/21.15107/rcub_technorep_342
Mišković-Stanković V, Zotović JB, Maksimović MD. Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel. in Bulletin of Electrochemistry. 2001;17(6):241-247.
https://hdl.handle.net/21.15107/rcub_technorep_342 .
Mišković-Stanković, Vesna, Zotović, Jelena B., Maksimović, Miodrag D., "Effect of surface modification by Fe-P alloys on corrosion behaviour of epoxy coatings electrodeposited on steel" in Bulletin of Electrochemistry, 17, no. 6 (2001):241-247,
https://hdl.handle.net/21.15107/rcub_technorep_342 .

Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition

Bajat, Jelena; Maksimović, Miodrag D.; Mišković-Stanković, Vesna; Zec, Slavica

(Springer, Dordrecht, 2001)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
AU  - Mišković-Stanković, Vesna
AU  - Zec, Slavica
PY  - 2001
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/375
AB  - The chemical composition and phase structure of Zn-Ni alloys obtained by electrodeposition under various conditions were investigated. The influence of the deposition solution and deposition current density on the composition, phase structure, current efficiency and corrosion properties of Zn-Ni alloys were examined. It was shown that the chemical composition and phase structure affect the anticorrosive properties of Zn-Ni alloys. A Zn-Ni alloy electrodeposited from a chloride solution at 20 mA cm(-2) exhibited the best corrosion properties, so this alloy was chosen for further examination. Epoxy coatings were formed by cathodic electrodeposition of an epoxy resin on steel and steel modified with a Zn-Ni alloy. From the time dependence of the pore resistance, coating capacitance and relative permittivity of the epoxy coating, the diffusion coefficient of water through the epoxy coating, D(H2O), and its thermal stability, it was shown that the Zn-Ni sublayer significantly affects the electrochemical and transport properties, as well as the thermal stability of epoxy coatings. On the basis of the experimental results it can be concluded that modification of a steel surface by a Zn-Ni alloy improves the corrosion protection of epoxy coatings.
PB  - Springer, Dordrecht
T2  - Journal of Applied Electrochemistry
T1  - Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition
EP  - 361
IS  - 3
SP  - 355
VL  - 31
DO  - 10.1023/A:1017580019551
ER  - 
@article{
author = "Bajat, Jelena and Maksimović, Miodrag D. and Mišković-Stanković, Vesna and Zec, Slavica",
year = "2001",
abstract = "The chemical composition and phase structure of Zn-Ni alloys obtained by electrodeposition under various conditions were investigated. The influence of the deposition solution and deposition current density on the composition, phase structure, current efficiency and corrosion properties of Zn-Ni alloys were examined. It was shown that the chemical composition and phase structure affect the anticorrosive properties of Zn-Ni alloys. A Zn-Ni alloy electrodeposited from a chloride solution at 20 mA cm(-2) exhibited the best corrosion properties, so this alloy was chosen for further examination. Epoxy coatings were formed by cathodic electrodeposition of an epoxy resin on steel and steel modified with a Zn-Ni alloy. From the time dependence of the pore resistance, coating capacitance and relative permittivity of the epoxy coating, the diffusion coefficient of water through the epoxy coating, D(H2O), and its thermal stability, it was shown that the Zn-Ni sublayer significantly affects the electrochemical and transport properties, as well as the thermal stability of epoxy coatings. On the basis of the experimental results it can be concluded that modification of a steel surface by a Zn-Ni alloy improves the corrosion protection of epoxy coatings.",
publisher = "Springer, Dordrecht",
journal = "Journal of Applied Electrochemistry",
title = "Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition",
pages = "361-355",
number = "3",
volume = "31",
doi = "10.1023/A:1017580019551"
}
Bajat, J., Maksimović, M. D., Mišković-Stanković, V.,& Zec, S.. (2001). Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition. in Journal of Applied Electrochemistry
Springer, Dordrecht., 31(3), 355-361.
https://doi.org/10.1023/A:1017580019551
Bajat J, Maksimović MD, Mišković-Stanković V, Zec S. Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition. in Journal of Applied Electrochemistry. 2001;31(3):355-361.
doi:10.1023/A:1017580019551 .
Bajat, Jelena, Maksimović, Miodrag D., Mišković-Stanković, Vesna, Zec, Slavica, "Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition" in Journal of Applied Electrochemistry, 31, no. 3 (2001):355-361,
https://doi.org/10.1023/A:1017580019551 . .
38
38
35

The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel

Mišković-Stanković, Vesna; Bajat, Jelena; Maksimović, Miodrag D.; Kačarević-Popović, Zorica M.

(Serbian Chemical Society, Belgrade, 2000)

TY  - JOUR
AU  - Mišković-Stanković, Vesna
AU  - Bajat, Jelena
AU  - Maksimović, Miodrag D.
AU  - Kačarević-Popović, Zorica M.
PY  - 2000
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/339
AB  - The electrochemical and transport properties, as well as the thermal stability of epoxy coatings electrodeposited on steel and steel modified by Zn-Ni alloys were investigated during exposure to 3 % NaCl. The Zn-Ni alloys were electrodeposited on steel using direct and pulse current. From the time dependence of the pore resistance of the epoxy coating (impedance measurements), the diffusion coefficient of water through the epoxy coating (gravimetric liquid sorption measurements) and the thermal stability of the epoxy coating (thermogravimetric analysis), it was shown that Zn-Ni sublayers significantly improve the corrosion stability of a protective system based on an epoxy coating. The values of the pore resistance were almost unchanged over a long period of immersion time for epoxy coatings on steel modified by Zn-Ni alloys, inidicating the great stability of these protective systems. .
AB  - Proučavane su elektrohemijske i transportne karakteristike i termička stabilnost epoksidnih elektroforetskih prevlaka na čeliku i čeliku modifikovanom Zn-Ni legurama tokom delovanja 3 % rastvora NaCl. Legure Zn-Ni su taložene na čeliku konstantnom i pulsirajućom strujom. Na osnovu vremenske zavisnosti otpornosti u porama epoksidne prevlake (impedansna merenja), koeficijenta difuzije vode kroz epoksidnu prevlaku (gravimetrijsko određivanje sorpcionih karakteristika) i njene termičke stabilnosti (termogravimetrijska analiza), pokazano je da Zn-Ni podslojevi značajno povećavaju korozionu stabilnost zaštitnog sistema na bazi epoksidne prevlake. Skoro nepromenjene vrednosti otpornosti u porama tokom dugog perioda delovanja korozionog agensa kod epoksidnih prevlaka na čeliku modifikovanom Zn-Ni legurama ukazuju na veliku stabilnost ovih zaštitnih sistema. .
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel
T1  - Uticaj Zn-Ni podslojeva na koroziono ponašanje i termičku stabilnost epoksidnih elektroforetskih prevlaka na čeliku
EP  - 933
IS  - 12
SP  - 923
VL  - 65
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2404
ER  - 
@article{
author = "Mišković-Stanković, Vesna and Bajat, Jelena and Maksimović, Miodrag D. and Kačarević-Popović, Zorica M.",
year = "2000",
abstract = "The electrochemical and transport properties, as well as the thermal stability of epoxy coatings electrodeposited on steel and steel modified by Zn-Ni alloys were investigated during exposure to 3 % NaCl. The Zn-Ni alloys were electrodeposited on steel using direct and pulse current. From the time dependence of the pore resistance of the epoxy coating (impedance measurements), the diffusion coefficient of water through the epoxy coating (gravimetric liquid sorption measurements) and the thermal stability of the epoxy coating (thermogravimetric analysis), it was shown that Zn-Ni sublayers significantly improve the corrosion stability of a protective system based on an epoxy coating. The values of the pore resistance were almost unchanged over a long period of immersion time for epoxy coatings on steel modified by Zn-Ni alloys, inidicating the great stability of these protective systems. ., Proučavane su elektrohemijske i transportne karakteristike i termička stabilnost epoksidnih elektroforetskih prevlaka na čeliku i čeliku modifikovanom Zn-Ni legurama tokom delovanja 3 % rastvora NaCl. Legure Zn-Ni su taložene na čeliku konstantnom i pulsirajućom strujom. Na osnovu vremenske zavisnosti otpornosti u porama epoksidne prevlake (impedansna merenja), koeficijenta difuzije vode kroz epoksidnu prevlaku (gravimetrijsko određivanje sorpcionih karakteristika) i njene termičke stabilnosti (termogravimetrijska analiza), pokazano je da Zn-Ni podslojevi značajno povećavaju korozionu stabilnost zaštitnog sistema na bazi epoksidne prevlake. Skoro nepromenjene vrednosti otpornosti u porama tokom dugog perioda delovanja korozionog agensa kod epoksidnih prevlaka na čeliku modifikovanom Zn-Ni legurama ukazuju na veliku stabilnost ovih zaštitnih sistema. .",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel, Uticaj Zn-Ni podslojeva na koroziono ponašanje i termičku stabilnost epoksidnih elektroforetskih prevlaka na čeliku",
pages = "933-923",
number = "12",
volume = "65",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2404"
}
Mišković-Stanković, V., Bajat, J., Maksimović, M. D.,& Kačarević-Popović, Z. M.. (2000). The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 65(12), 923-933.
https://hdl.handle.net/21.15107/rcub_vinar_2404
Mišković-Stanković V, Bajat J, Maksimović MD, Kačarević-Popović ZM. The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel. in Journal of the Serbian Chemical Society. 2000;65(12):923-933.
https://hdl.handle.net/21.15107/rcub_vinar_2404 .
Mišković-Stanković, Vesna, Bajat, Jelena, Maksimović, Miodrag D., Kačarević-Popović, Zorica M., "The effect of Zn-Ni sublayers on the corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel" in Journal of the Serbian Chemical Society, 65, no. 12 (2000):923-933,
https://hdl.handle.net/21.15107/rcub_vinar_2404 .
3
3

Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys

Bajat, Jelena; Kačarević-Popović, Zorica M.; Mišković-Stanković, Vesna; Maksimović, Miodrag D.

(Elsevier Science Sa, Lausanne, 2000)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Kačarević-Popović, Zorica M.
AU  - Mišković-Stanković, Vesna
AU  - Maksimović, Miodrag D.
PY  - 2000
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/306
AB  - The electrochemical and transport properties and thermal stability of epoxy coatings electrodeposited on hot-dip galvanized steel and steel modified by Zn-Ni alloys were investigated during exposure to 3% NaCl solution. Zn-Ni alloys were electrodeposited on steel by direct and pulse current. From the time dependence of pore resistance, coating capacitance and relative permittivity of epoxy coating, diffusion coefficient of water through epoxy coating, D(H2O) and thermal stability, it was shown that Zn-Ni sublayers significantly improve the corrosion stability of the protective system based on epoxy coating. Almost unchanged values of pore resistance were obtained over the long period of investigated time for epoxy coatings on steel modified by Zn-Ni alloys, indicating the great stability of these protective systems, due to the existence of the inner oxide phase layer and the outer layer consisting of basic salts.
PB  - Elsevier Science Sa, Lausanne
T2  - Progress in Organic Coatings
T1  - Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys
EP  - 135
IS  - 2-4
SP  - 127
VL  - 39
DO  - 10.1016/S0300-9440(00)00127-2
ER  - 
@article{
author = "Bajat, Jelena and Kačarević-Popović, Zorica M. and Mišković-Stanković, Vesna and Maksimović, Miodrag D.",
year = "2000",
abstract = "The electrochemical and transport properties and thermal stability of epoxy coatings electrodeposited on hot-dip galvanized steel and steel modified by Zn-Ni alloys were investigated during exposure to 3% NaCl solution. Zn-Ni alloys were electrodeposited on steel by direct and pulse current. From the time dependence of pore resistance, coating capacitance and relative permittivity of epoxy coating, diffusion coefficient of water through epoxy coating, D(H2O) and thermal stability, it was shown that Zn-Ni sublayers significantly improve the corrosion stability of the protective system based on epoxy coating. Almost unchanged values of pore resistance were obtained over the long period of investigated time for epoxy coatings on steel modified by Zn-Ni alloys, indicating the great stability of these protective systems, due to the existence of the inner oxide phase layer and the outer layer consisting of basic salts.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Progress in Organic Coatings",
title = "Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys",
pages = "135-127",
number = "2-4",
volume = "39",
doi = "10.1016/S0300-9440(00)00127-2"
}
Bajat, J., Kačarević-Popović, Z. M., Mišković-Stanković, V.,& Maksimović, M. D.. (2000). Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys. in Progress in Organic Coatings
Elsevier Science Sa, Lausanne., 39(2-4), 127-135.
https://doi.org/10.1016/S0300-9440(00)00127-2
Bajat J, Kačarević-Popović ZM, Mišković-Stanković V, Maksimović MD. Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys. in Progress in Organic Coatings. 2000;39(2-4):127-135.
doi:10.1016/S0300-9440(00)00127-2 .
Bajat, Jelena, Kačarević-Popović, Zorica M., Mišković-Stanković, Vesna, Maksimović, Miodrag D., "Corrosion behaviour of epoxy coatings electrodeposited on galvanized steel and steel modified by Zn-Ni alloys" in Progress in Organic Coatings, 39, no. 2-4 (2000):127-135,
https://doi.org/10.1016/S0300-9440(00)00127-2 . .
53
55
61

Study of thermal stability of epoxy coatings electrodeposited on different substrates

Kačarević-Popović, Zorica M.; Mišković-Stanković, Vesna; Maksimović, Miodrag D.; Zotović, Jelena B.; Kostoski, D

(Elsevier Sci Ltd, Oxford, 1999)

TY  - JOUR
AU  - Kačarević-Popović, Zorica M.
AU  - Mišković-Stanković, Vesna
AU  - Maksimović, Miodrag D.
AU  - Zotović, Jelena B.
AU  - Kostoski, D
PY  - 1999
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/259
AB  - The thermal stability of epoxy coatings electrodeposited on steel, phosphatized steel, steel electrochemically modified by Zn-Ni alloys and aluminium has been investigated. Epoxy coatings were formed by cathodic electrodeposition of epoxy adducts, using a constant voltage method. The rate of hydrogen evolution reaction in the polymer solution on different substrate surfaces was determined on Pt rotating disc using a slow sweep voltammetry. The characteristic thermal and thermooxidative degradation temperatures, as the measure of thermal stability, and activation energies of thermal degradation were determined by thermogravimetric analysis. It has been observed that different catalytic activities of substrates for H-2? evolution reaction give different rise to an increased amount of hydrogen bonds inside the polymer net and porosity of coating, strongly affecting the thermal and thermooxidative resistance of the polymeric material.
PB  - Elsevier Sci Ltd, Oxford
T2  - Polymer Degradation and Stability
T1  - Study of thermal stability of epoxy coatings electrodeposited on different substrates
EP  - 98
IS  - 1
SP  - 91
VL  - 65
DO  - 10.1016/S0141-3910(98)00222-5
ER  - 
@article{
author = "Kačarević-Popović, Zorica M. and Mišković-Stanković, Vesna and Maksimović, Miodrag D. and Zotović, Jelena B. and Kostoski, D",
year = "1999",
abstract = "The thermal stability of epoxy coatings electrodeposited on steel, phosphatized steel, steel electrochemically modified by Zn-Ni alloys and aluminium has been investigated. Epoxy coatings were formed by cathodic electrodeposition of epoxy adducts, using a constant voltage method. The rate of hydrogen evolution reaction in the polymer solution on different substrate surfaces was determined on Pt rotating disc using a slow sweep voltammetry. The characteristic thermal and thermooxidative degradation temperatures, as the measure of thermal stability, and activation energies of thermal degradation were determined by thermogravimetric analysis. It has been observed that different catalytic activities of substrates for H-2? evolution reaction give different rise to an increased amount of hydrogen bonds inside the polymer net and porosity of coating, strongly affecting the thermal and thermooxidative resistance of the polymeric material.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Polymer Degradation and Stability",
title = "Study of thermal stability of epoxy coatings electrodeposited on different substrates",
pages = "98-91",
number = "1",
volume = "65",
doi = "10.1016/S0141-3910(98)00222-5"
}
Kačarević-Popović, Z. M., Mišković-Stanković, V., Maksimović, M. D., Zotović, J. B.,& Kostoski, D.. (1999). Study of thermal stability of epoxy coatings electrodeposited on different substrates. in Polymer Degradation and Stability
Elsevier Sci Ltd, Oxford., 65(1), 91-98.
https://doi.org/10.1016/S0141-3910(98)00222-5
Kačarević-Popović ZM, Mišković-Stanković V, Maksimović MD, Zotović JB, Kostoski D. Study of thermal stability of epoxy coatings electrodeposited on different substrates. in Polymer Degradation and Stability. 1999;65(1):91-98.
doi:10.1016/S0141-3910(98)00222-5 .
Kačarević-Popović, Zorica M., Mišković-Stanković, Vesna, Maksimović, Miodrag D., Zotović, Jelena B., Kostoski, D, "Study of thermal stability of epoxy coatings electrodeposited on different substrates" in Polymer Degradation and Stability, 65, no. 1 (1999):91-98,
https://doi.org/10.1016/S0141-3910(98)00222-5 . .
5
8
7

Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy

Mišković-Stanković, Vesna; Zotović, Jelena B.; Kačarević-Popović, Zorica M.; Maksimović, Miodrag D.

(Pergamon-Elsevier Science Ltd, Oxford, 1999)

TY  - JOUR
AU  - Mišković-Stanković, Vesna
AU  - Zotović, Jelena B.
AU  - Kačarević-Popović, Zorica M.
AU  - Maksimović, Miodrag D.
PY  - 1999
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/260
AB  - The corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel: phosphatised steel and steel previously modified by electrodeposited Zn-Ni alloy was investigated during exposure to 3% NaCl. The electrochemical impedance spectroscopy (EIS), gravimetric liquid sorption experiments, thermogravimetric analysis (TGA) and anodic linear sweep voltammetry (ALSV) were used. Epoxy topcoat was formed by cathodic electrodeposition of an epoxy resin using constant voltage method. From the results obtained from EIS (pore resistance, coating capacitance), gravimetric liquid sorption experiment (diffusion coefficient) and TGA (water content inside the coating and thermal resistance), it can be concluded that electrochemical, transport and thermal properties of epoxy coatings are strongly affected by surface modification of the substrate. The better protective properties of epoxy coating on Zn-Ni sublayer can be explained by its less porous structure, caused by lower rate of H-2 evolution on Zn-Ni alloy, while the increased corrosion protection is due to the passive film of ZnO on the alloy surface. The mechanism of electrolyte penetration through an organic coating was also given.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy
EP  - 4277
IS  - 24
SP  - 4269
VL  - 44
DO  - 10.1016/S0013-4686(99)00142-5
ER  - 
@article{
author = "Mišković-Stanković, Vesna and Zotović, Jelena B. and Kačarević-Popović, Zorica M. and Maksimović, Miodrag D.",
year = "1999",
abstract = "The corrosion behaviour and thermal stability of epoxy coatings electrodeposited on steel: phosphatised steel and steel previously modified by electrodeposited Zn-Ni alloy was investigated during exposure to 3% NaCl. The electrochemical impedance spectroscopy (EIS), gravimetric liquid sorption experiments, thermogravimetric analysis (TGA) and anodic linear sweep voltammetry (ALSV) were used. Epoxy topcoat was formed by cathodic electrodeposition of an epoxy resin using constant voltage method. From the results obtained from EIS (pore resistance, coating capacitance), gravimetric liquid sorption experiment (diffusion coefficient) and TGA (water content inside the coating and thermal resistance), it can be concluded that electrochemical, transport and thermal properties of epoxy coatings are strongly affected by surface modification of the substrate. The better protective properties of epoxy coating on Zn-Ni sublayer can be explained by its less porous structure, caused by lower rate of H-2 evolution on Zn-Ni alloy, while the increased corrosion protection is due to the passive film of ZnO on the alloy surface. The mechanism of electrolyte penetration through an organic coating was also given.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy",
pages = "4277-4269",
number = "24",
volume = "44",
doi = "10.1016/S0013-4686(99)00142-5"
}
Mišković-Stanković, V., Zotović, J. B., Kačarević-Popović, Z. M.,& Maksimović, M. D.. (1999). Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 44(24), 4269-4277.
https://doi.org/10.1016/S0013-4686(99)00142-5
Mišković-Stanković V, Zotović JB, Kačarević-Popović ZM, Maksimović MD. Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy. in Electrochimica Acta. 1999;44(24):4269-4277.
doi:10.1016/S0013-4686(99)00142-5 .
Mišković-Stanković, Vesna, Zotović, Jelena B., Kačarević-Popović, Zorica M., Maksimović, Miodrag D., "Corrosion behaviour of epoxy coatings electrodeposited on steel electrochemically modified by Zn-Ni alloy" in Electrochimica Acta, 44, no. 24 (1999):4269-4277,
https://doi.org/10.1016/S0013-4686(99)00142-5 . .
50
48
57

Corrosion behaviour of epoxy coatings investigated by EIS

Mišković-Stanković, Vesna; Zotović, Jelena B.; Maksimović, Miodrag D.

(Trans Tech Publications Ltd, Durnten-Zurich, 1998)

TY  - JOUR
AU  - Mišković-Stanković, Vesna
AU  - Zotović, Jelena B.
AU  - Maksimović, Miodrag D.
PY  - 1998
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/202
AB  - Epoxy coatings were formed by cathodic electrodeposition of an epoxy resin on steel and on electrochemically modified steel surface by Fe-P alloy using constant voltage method (resin concentration 10 wt.%, temperature 26 degrees C, applied voltage 250 V). The corrosion behaviour of these coatings was investigated during exposure to 3% NaCl using electrochemical impedance spectroscopy (EIS), polarization curves and corrosion potential - time measurements. From the time dependences of pore resistance, coating capacitance, relative permittivity of coating and Warburg diffusion impedance, obtained from EIS, and corrosion current density, obtained from polarization curves, it can be observed that the Fe-P alloy is a good barrier to transport of corrosive agent. During prolonged exposure the Fe-P layer significantly improves stability of protective epoxy system, postponing the time when electrolyte reaches the basic substrate.
PB  - Trans Tech Publications Ltd, Durnten-Zurich
T2  - Electrochemical Methods in Corrosion Research Vi, Pts 1 and 2
T1  - Corrosion behaviour of epoxy coatings investigated by EIS
EP  - 335
SP  - 327
VL  - 289-292
DO  - 10.4028/www.scientific.net/MSF.289-292.327
ER  - 
@article{
author = "Mišković-Stanković, Vesna and Zotović, Jelena B. and Maksimović, Miodrag D.",
year = "1998",
abstract = "Epoxy coatings were formed by cathodic electrodeposition of an epoxy resin on steel and on electrochemically modified steel surface by Fe-P alloy using constant voltage method (resin concentration 10 wt.%, temperature 26 degrees C, applied voltage 250 V). The corrosion behaviour of these coatings was investigated during exposure to 3% NaCl using electrochemical impedance spectroscopy (EIS), polarization curves and corrosion potential - time measurements. From the time dependences of pore resistance, coating capacitance, relative permittivity of coating and Warburg diffusion impedance, obtained from EIS, and corrosion current density, obtained from polarization curves, it can be observed that the Fe-P alloy is a good barrier to transport of corrosive agent. During prolonged exposure the Fe-P layer significantly improves stability of protective epoxy system, postponing the time when electrolyte reaches the basic substrate.",
publisher = "Trans Tech Publications Ltd, Durnten-Zurich",
journal = "Electrochemical Methods in Corrosion Research Vi, Pts 1 and 2",
title = "Corrosion behaviour of epoxy coatings investigated by EIS",
pages = "335-327",
volume = "289-292",
doi = "10.4028/www.scientific.net/MSF.289-292.327"
}
Mišković-Stanković, V., Zotović, J. B.,& Maksimović, M. D.. (1998). Corrosion behaviour of epoxy coatings investigated by EIS. in Electrochemical Methods in Corrosion Research Vi, Pts 1 and 2
Trans Tech Publications Ltd, Durnten-Zurich., 289-292, 327-335.
https://doi.org/10.4028/www.scientific.net/MSF.289-292.327
Mišković-Stanković V, Zotović JB, Maksimović MD. Corrosion behaviour of epoxy coatings investigated by EIS. in Electrochemical Methods in Corrosion Research Vi, Pts 1 and 2. 1998;289-292:327-335.
doi:10.4028/www.scientific.net/MSF.289-292.327 .
Mišković-Stanković, Vesna, Zotović, Jelena B., Maksimović, Miodrag D., "Corrosion behaviour of epoxy coatings investigated by EIS" in Electrochemical Methods in Corrosion Research Vi, Pts 1 and 2, 289-292 (1998):327-335,
https://doi.org/10.4028/www.scientific.net/MSF.289-292.327 . .
5
3
7

The corrosion behaviour of epoxy-resin electrocoated steel

Maksimović, Miodrag D.; Mišković-Stanković, Vesna

(Pergamon-Elsevier Science Ltd, Oxford, 1992)

TY  - JOUR
AU  - Maksimović, Miodrag D.
AU  - Mišković-Stanković, Vesna
PY  - 1992
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/42
AB  - a.c. Impedance measurements carried out on epoxy-resin electrocoated steels have been used to determine the pore resistance of the organic films as a function of time of exposure to 3% NaCl solution. The time dependence of pore resistance for the electrodeposited coatings, formed at different voltages, shows the effect of applied voltage on the protective properties of organic layers. The results were interpreted in terms of a model in which the solution rapidly penetrates capillaries or defects in the coating followed by diffusion of solution through the coating. The model predicted the relationship between film thickness and useful life of the film, i.e. the model showed that useful life of coating depends on the square of film thickness.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Corrosion Science
T1  - The corrosion behaviour of epoxy-resin electrocoated steel
EP  - 279
IS  - 2
SP  - 271
VL  - 33
DO  - 10.1016/0010-938X(92)90151-R
ER  - 
@article{
author = "Maksimović, Miodrag D. and Mišković-Stanković, Vesna",
year = "1992",
abstract = "a.c. Impedance measurements carried out on epoxy-resin electrocoated steels have been used to determine the pore resistance of the organic films as a function of time of exposure to 3% NaCl solution. The time dependence of pore resistance for the electrodeposited coatings, formed at different voltages, shows the effect of applied voltage on the protective properties of organic layers. The results were interpreted in terms of a model in which the solution rapidly penetrates capillaries or defects in the coating followed by diffusion of solution through the coating. The model predicted the relationship between film thickness and useful life of the film, i.e. the model showed that useful life of coating depends on the square of film thickness.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Corrosion Science",
title = "The corrosion behaviour of epoxy-resin electrocoated steel",
pages = "279-271",
number = "2",
volume = "33",
doi = "10.1016/0010-938X(92)90151-R"
}
Maksimović, M. D.,& Mišković-Stanković, V.. (1992). The corrosion behaviour of epoxy-resin electrocoated steel. in Corrosion Science
Pergamon-Elsevier Science Ltd, Oxford., 33(2), 271-279.
https://doi.org/10.1016/0010-938X(92)90151-R
Maksimović MD, Mišković-Stanković V. The corrosion behaviour of epoxy-resin electrocoated steel. in Corrosion Science. 1992;33(2):271-279.
doi:10.1016/0010-938X(92)90151-R .
Maksimović, Miodrag D., Mišković-Stanković, Vesna, "The corrosion behaviour of epoxy-resin electrocoated steel" in Corrosion Science, 33, no. 2 (1992):271-279,
https://doi.org/10.1016/0010-938X(92)90151-R . .
35
35