TY  - JOUR
AU  - Pantić, Jelena R.
AU  - Urbanovich, Vladimir
AU  - Poharc-Logar, Vesna
AU  - Jokić, Bojan M.
AU  - Stojmenović, Marija
AU  - Kremenović, Aleksandar S.
AU  - Matović, Branko
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5789
AB  - Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 A degrees C, sphene undergoes into phase transition, from room-temperature phase P2(1) /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy.
PB  - Springer Verlag
T2  - Physics and Chemistry of Minerals
T1  - Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)
EP  - 782
IS  - 10
SP  - 775
VL  - 41
DO  - 10.1007/s00269-014-0693-x
ER  - 

@article{
author = "Pantić, Jelena R. and Urbanovich, Vladimir and Poharc-Logar, Vesna and Jokić, Bojan M. and Stojmenović, Marija and Kremenović, Aleksandar S. and Matović, Branko",
year = "2014",
abstract = "Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 A degrees C, sphene undergoes into phase transition, from room-temperature phase P2(1) /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy.",
publisher = "Springer Verlag",
journal = "Physics and Chemistry of Minerals",
title = "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)",
pages = "782-775",
number = "10",
volume = "41",
doi = "10.1007/s00269-014-0693-x"
}

Pantić, J. R., Urbanovich, V., Poharc-Logar, V., Jokić, B. M., Stojmenović, M., Kremenović, A. S.,& Matović, B.. (2014). Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5). in Physics and Chemistry of Minerals
Springer Verlag., 41(10), 775-782.
https://doi.org/10.1007/s00269-014-0693-x

Pantić JR, Urbanovich V, Poharc-Logar V, Jokić BM, Stojmenović M, Kremenović AS, Matović B. Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5). in Physics and Chemistry of Minerals. 2014;41(10):775-782.
doi:10.1007/s00269-014-0693-x .

Pantić, Jelena R., Urbanovich, Vladimir, Poharc-Logar, Vesna, Jokić, Bojan M., Stojmenović, Marija, Kremenović, Aleksandar S., Matović, Branko, "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)" in Physics and Chemistry of Minerals, 41, no. 10 (2014):775-782,
https://doi.org/10.1007/s00269-014-0693-x . .