Dimic-Misic, Katarina

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03638f9d-cb1e-4076-a9fd-7b1fe917bbd2
  • Dimic-Misic, Katarina (3)
  • Dimić-Mišić, Katarina (3)
Projects

Author's Bibliography

Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids

Barcelo, Ernest; Dimić-Mišić, Katarina; Imani, Monir; Spasojević Brkić, Vesna; Hummel, Michael; Gane, Patrick

(MDPI, 2023)

TY  - JOUR
AU  - Barcelo, Ernest
AU  - Dimić-Mišić, Katarina
AU  - Imani, Monir
AU  - Spasojević Brkić, Vesna
AU  - Hummel, Michael
AU  - Gane, Patrick
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5867
AB  - Nowadays, fossil fuels are used in a clearly unsustainable way that can bring potentially catastrophic consequences. Electricity is currently delivered to end users by generation and energy transmission companies. Previous research shows that the development of modern circular economy sets a need for the re-orientation of socio and economic development of decentralized systems, including energy basis. In addition to being ecological, the use of renewable energy sources also has economic significance by contributing to energy independence. Citizens, industries, local and national authorities become interconnected within emerging novel renewable energy sourcing communities, through which they establish trade of energy and, most importantly, models of investing and reshaping the distribution of renewable energy. The modern portfolio management of renewable energy networking is aiming toward decentralized systems of trade, where the consumer becomes a producer (prosumer) within the network, itself managed by users. Excess energy produced in the micro-grid nets within the over-arching national and transnational energy grid should be accounted for and managed with blockchain technology for financial and structural security. The decentralization of the energy market requires the establishment of strict norms that will regulate the market and taxation of profits arising. The extensive literature review on blockchain in the energy sector reflects a very pragmatic and narrow approach to the topic, although it is evident that the distribution of energy within the blockchain would enable economic development through reducing cost and ensuring more secure energy trade. Blockchain technology embeds the related digital codes, in which information will be visible to all, but also secured from hacking and duplicating. However, there are challenges to this paradigm, not least the energy consumption of the extensive nodal mesh required to perform the necessary protocols. This paper aims to provide an overview of the application of blockchain technology and the need for the development of the regulatory system and of potential solutions to the challenges posed. By undertaking an energy consumption analysis of blockchain implementation from first electronic principles, which has not been constructed before in the literature, this paper’s conclusion stresses the future demand for reducing energy consumption and considers the latest findings in the quantum coupling of light signals as a potential for solving the enormous ledger duplication structure problem.
PB  - MDPI
T2  - Sustainability
T1  - Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids
SP  - 2571
VL  - 15 (3)
DO  - 10.3390/su15032571
ER  - 
@article{
author = "Barcelo, Ernest and Dimić-Mišić, Katarina and Imani, Monir and Spasojević Brkić, Vesna and Hummel, Michael and Gane, Patrick",
year = "2023",
abstract = "Nowadays, fossil fuels are used in a clearly unsustainable way that can bring potentially catastrophic consequences. Electricity is currently delivered to end users by generation and energy transmission companies. Previous research shows that the development of modern circular economy sets a need for the re-orientation of socio and economic development of decentralized systems, including energy basis. In addition to being ecological, the use of renewable energy sources also has economic significance by contributing to energy independence. Citizens, industries, local and national authorities become interconnected within emerging novel renewable energy sourcing communities, through which they establish trade of energy and, most importantly, models of investing and reshaping the distribution of renewable energy. The modern portfolio management of renewable energy networking is aiming toward decentralized systems of trade, where the consumer becomes a producer (prosumer) within the network, itself managed by users. Excess energy produced in the micro-grid nets within the over-arching national and transnational energy grid should be accounted for and managed with blockchain technology for financial and structural security. The decentralization of the energy market requires the establishment of strict norms that will regulate the market and taxation of profits arising. The extensive literature review on blockchain in the energy sector reflects a very pragmatic and narrow approach to the topic, although it is evident that the distribution of energy within the blockchain would enable economic development through reducing cost and ensuring more secure energy trade. Blockchain technology embeds the related digital codes, in which information will be visible to all, but also secured from hacking and duplicating. However, there are challenges to this paradigm, not least the energy consumption of the extensive nodal mesh required to perform the necessary protocols. This paper aims to provide an overview of the application of blockchain technology and the need for the development of the regulatory system and of potential solutions to the challenges posed. By undertaking an energy consumption analysis of blockchain implementation from first electronic principles, which has not been constructed before in the literature, this paper’s conclusion stresses the future demand for reducing energy consumption and considers the latest findings in the quantum coupling of light signals as a potential for solving the enormous ledger duplication structure problem.",
publisher = "MDPI",
journal = "Sustainability",
title = "Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids",
pages = "2571",
volume = "15 (3)",
doi = "10.3390/su15032571"
}
Barcelo, E., Dimić-Mišić, K., Imani, M., Spasojević Brkić, V., Hummel, M.,& Gane, P.. (2023). Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids. in Sustainability
MDPI., 15 (3), 2571.
https://doi.org/10.3390/su15032571
Barcelo E, Dimić-Mišić K, Imani M, Spasojević Brkić V, Hummel M, Gane P. Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids. in Sustainability. 2023;15 (3):2571.
doi:10.3390/su15032571 .
Barcelo, Ernest, Dimić-Mišić, Katarina, Imani, Monir, Spasojević Brkić, Vesna, Hummel, Michael, Gane, Patrick, "Regulatory Paradigm and Challenge for Blockchain Integration of Decentralized Systems: Example—Renewable Energy Grids" in Sustainability, 15 (3) (2023):2571,
https://doi.org/10.3390/su15032571 . .
5
4

Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid

Kostić, Mirjana; Imani, Monireh; Ivanovska, Aleksandra; Radojević, Vesna; Dimić-Mišić, Katarina; Barać, Nemanja; Stojanović, Dušica; Janaćković, Đorđe; Uskoković, Petar; Barcelo, Ernest; Gane, Patrick

(Springer Science and Business Media B.V., 2022)

TY  - JOUR
AU  - Kostić, Mirjana
AU  - Imani, Monireh
AU  - Ivanovska, Aleksandra
AU  - Radojević, Vesna
AU  - Dimić-Mišić, Katarina
AU  - Barać, Nemanja
AU  - Stojanović, Dušica
AU  - Janaćković, Đorđe
AU  - Uskoković, Petar
AU  - Barcelo, Ernest
AU  - Gane, Patrick
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5138
AB  - Cellulose-fibre lifecycle is severely limited within today’s recycling methodology. Feedstock cellulose and filler abound in products considered uneconomic, unsuitable for standard deinking or too weak for original product re-use. Regeneration of cellulose from ionic liquid (IL) solution offers a novel valorisation route with potential to replace oil-based plastics, simultaneously bringing filler-containing cellulose waste into circular economy. To exemplify, composite cellulose-CaCO3 filaments were produced from cellulose pulp and waste office paper (already containing 27 w/w% precipitated CaCO3filler), without any pretreatment, using diazabicyclo[4.3.0]non-5-enium-acetate ([DHBN][OAc]) as IL solvent to form a dope. The dope suspension was extruded via dry-jet wet spinning. Surface morphology and elemental analysis were investigated using scanning electron microscopy with energy dispersive X-ray spectroscopy. X-ray diffraction was used to measure the degree of cellulose crystallinity. Static and dynamic mechanical properties were determined. Thermal stability was evaluated by thermogravimetric analysis. Filaments obtained from waste office paper showed that high filler levels and the presence of print toner enhanced both mechanical and thermal stability, while decreasing, as expected, ultimate breaking strength in comparison to filaments containing virgin cellulose alone. For comparison, 2 w/w% ground CaCO3 introduced into pure cellulose dope led to significant increase in cellulose crystallinity and resulting stiffness, while thermal properties remained unchanged at the low level filler addition. Such addition of CaCO3 during cellulose regeneration, or usage of already filled paper, could be an effective way to obtain high strength cellulose-CaCO3 composite materials, thus valorising in a circular economy renewable cellulosic wastes rejected from the current recycling stream.
PB  - Springer Science and Business Media B.V.
T2  - Cellulose
T1  - Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid
DO  - 10.1007/s10570-022-04575-w
ER  - 
@article{
author = "Kostić, Mirjana and Imani, Monireh and Ivanovska, Aleksandra and Radojević, Vesna and Dimić-Mišić, Katarina and Barać, Nemanja and Stojanović, Dušica and Janaćković, Đorđe and Uskoković, Petar and Barcelo, Ernest and Gane, Patrick",
year = "2022",
abstract = "Cellulose-fibre lifecycle is severely limited within today’s recycling methodology. Feedstock cellulose and filler abound in products considered uneconomic, unsuitable for standard deinking or too weak for original product re-use. Regeneration of cellulose from ionic liquid (IL) solution offers a novel valorisation route with potential to replace oil-based plastics, simultaneously bringing filler-containing cellulose waste into circular economy. To exemplify, composite cellulose-CaCO3 filaments were produced from cellulose pulp and waste office paper (already containing 27 w/w% precipitated CaCO3filler), without any pretreatment, using diazabicyclo[4.3.0]non-5-enium-acetate ([DHBN][OAc]) as IL solvent to form a dope. The dope suspension was extruded via dry-jet wet spinning. Surface morphology and elemental analysis were investigated using scanning electron microscopy with energy dispersive X-ray spectroscopy. X-ray diffraction was used to measure the degree of cellulose crystallinity. Static and dynamic mechanical properties were determined. Thermal stability was evaluated by thermogravimetric analysis. Filaments obtained from waste office paper showed that high filler levels and the presence of print toner enhanced both mechanical and thermal stability, while decreasing, as expected, ultimate breaking strength in comparison to filaments containing virgin cellulose alone. For comparison, 2 w/w% ground CaCO3 introduced into pure cellulose dope led to significant increase in cellulose crystallinity and resulting stiffness, while thermal properties remained unchanged at the low level filler addition. Such addition of CaCO3 during cellulose regeneration, or usage of already filled paper, could be an effective way to obtain high strength cellulose-CaCO3 composite materials, thus valorising in a circular economy renewable cellulosic wastes rejected from the current recycling stream.",
publisher = "Springer Science and Business Media B.V.",
journal = "Cellulose",
title = "Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid",
doi = "10.1007/s10570-022-04575-w"
}
Kostić, M., Imani, M., Ivanovska, A., Radojević, V., Dimić-Mišić, K., Barać, N., Stojanović, D., Janaćković, Đ., Uskoković, P., Barcelo, E.,& Gane, P.. (2022). Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid. in Cellulose
Springer Science and Business Media B.V...
https://doi.org/10.1007/s10570-022-04575-w
Kostić M, Imani M, Ivanovska A, Radojević V, Dimić-Mišić K, Barać N, Stojanović D, Janaćković Đ, Uskoković P, Barcelo E, Gane P. Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid. in Cellulose. 2022;.
doi:10.1007/s10570-022-04575-w .
Kostić, Mirjana, Imani, Monireh, Ivanovska, Aleksandra, Radojević, Vesna, Dimić-Mišić, Katarina, Barać, Nemanja, Stojanović, Dušica, Janaćković, Đorđe, Uskoković, Petar, Barcelo, Ernest, Gane, Patrick, "Extending waste paper, cellulose and filler use beyond recycling by entering the circular economy creating cellulose-CaCO3 composites reconstituted from ionic liquid" in Cellulose (2022),
https://doi.org/10.1007/s10570-022-04575-w . .
7
1
8

Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture

Barać, Nemanja; Barcelo, Ernest; Stojanović, Dušica; Milovanović, Stoja; Uskoković, Petar; Gane, Patrick; Dimic-Misic, Katarina; Imani, Monireh; Janaćković, Đorđe

(2022)

TY  - JOUR
AU  - Barać, Nemanja
AU  - Barcelo, Ernest
AU  - Stojanović, Dušica
AU  - Milovanović, Stoja
AU  - Uskoković, Petar
AU  - Gane, Patrick
AU  - Dimic-Misic, Katarina
AU  - Imani, Monireh
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5007
AB  - In this work, we examine two modifications of fine-ground calcium carbonate material (GCC) in order to enhanced sorption of NO2 and subsequent reaction properties toward NO2-/NO3- formation by firstly exposing the GCC to supercritical (sc) CO2 in order to increase particle surface area, a choice specifically made to avoid altering the surface chemistry, and secondly considering the potential advantage of using a surface coupling agent toward NO2. The modification by the coupling agent amino silane (AMEO silane) was applied in a supercritical CO2-ethanol mixture. The samples were characterised before and after modification by field emission scanning electron microscopy (FESEM), specific surface area determination (BET nitrogen adsorption), ATR-FTIR spectroscopy and ion chromatography to reveal the effects of the surface modification(s) on the morphology, surface textural properties and sorption versus reaction properties with NO2. The performance of the treated sorbents for NO2 capture was evaluated at room temperature. Results show that reactivity of NO2 with GCC was observed to increase as a function of increased surface area resulting from scCO(2) exposure, but that the presence of AMEO silane on the surface, while enhancing initial adsorption of NO2 was seen subsequently to act to block reactivity. Thus, judicious use of coupling agent can provide desired rapid initial adsorption of the gas, but the goal of long-term CaCO3-consuming reactivity, so as to prolong the uptake of NO2 beyond surface saturation alone, is achieved by increasing surface area while retaining chemical-free exposed CaCO3 surface.
T2  - Environmental Science and Pollution Research
T1  - Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture
EP  - 11717
IS  - 8
SP  - 11707
VL  - 29
DO  - 10.1007/s11356-021-16503-9
ER  - 
@article{
author = "Barać, Nemanja and Barcelo, Ernest and Stojanović, Dušica and Milovanović, Stoja and Uskoković, Petar and Gane, Patrick and Dimic-Misic, Katarina and Imani, Monireh and Janaćković, Đorđe",
year = "2022",
abstract = "In this work, we examine two modifications of fine-ground calcium carbonate material (GCC) in order to enhanced sorption of NO2 and subsequent reaction properties toward NO2-/NO3- formation by firstly exposing the GCC to supercritical (sc) CO2 in order to increase particle surface area, a choice specifically made to avoid altering the surface chemistry, and secondly considering the potential advantage of using a surface coupling agent toward NO2. The modification by the coupling agent amino silane (AMEO silane) was applied in a supercritical CO2-ethanol mixture. The samples were characterised before and after modification by field emission scanning electron microscopy (FESEM), specific surface area determination (BET nitrogen adsorption), ATR-FTIR spectroscopy and ion chromatography to reveal the effects of the surface modification(s) on the morphology, surface textural properties and sorption versus reaction properties with NO2. The performance of the treated sorbents for NO2 capture was evaluated at room temperature. Results show that reactivity of NO2 with GCC was observed to increase as a function of increased surface area resulting from scCO(2) exposure, but that the presence of AMEO silane on the surface, while enhancing initial adsorption of NO2 was seen subsequently to act to block reactivity. Thus, judicious use of coupling agent can provide desired rapid initial adsorption of the gas, but the goal of long-term CaCO3-consuming reactivity, so as to prolong the uptake of NO2 beyond surface saturation alone, is achieved by increasing surface area while retaining chemical-free exposed CaCO3 surface.",
journal = "Environmental Science and Pollution Research",
title = "Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture",
pages = "11717-11707",
number = "8",
volume = "29",
doi = "10.1007/s11356-021-16503-9"
}
Barać, N., Barcelo, E., Stojanović, D., Milovanović, S., Uskoković, P., Gane, P., Dimic-Misic, K., Imani, M.,& Janaćković, Đ.. (2022). Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture. in Environmental Science and Pollution Research, 29(8), 11707-11717.
https://doi.org/10.1007/s11356-021-16503-9
Barać N, Barcelo E, Stojanović D, Milovanović S, Uskoković P, Gane P, Dimic-Misic K, Imani M, Janaćković Đ. Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture. in Environmental Science and Pollution Research. 2022;29(8):11707-11717.
doi:10.1007/s11356-021-16503-9 .
Barać, Nemanja, Barcelo, Ernest, Stojanović, Dušica, Milovanović, Stoja, Uskoković, Petar, Gane, Patrick, Dimic-Misic, Katarina, Imani, Monireh, Janaćković, Đorđe, "Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide-ethanol mixture for enhanced NO2 capture" in Environmental Science and Pollution Research, 29, no. 8 (2022):11707-11717,
https://doi.org/10.1007/s11356-021-16503-9 . .
6
6

Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions

Dimic-Misic, Katarina; Kostić, Mirjana; Obradovic, Bratislav; Kuraica, Milorad; Kramar, Ana; Imani, Monireh; Gane, Patrick

(2021)

TY  - JOUR
AU  - Dimic-Misic, Katarina
AU  - Kostić, Mirjana
AU  - Obradovic, Bratislav
AU  - Kuraica, Milorad
AU  - Kramar, Ana
AU  - Imani, Monireh
AU  - Gane, Patrick
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4844
AB  - The surface of cellulose films, obtained from micro nanofibrillated cellulose produced with different enzymatic pretreatment digestion times of refined pulp, was exposed to gas plasma, resulting in a range of surface chemical and morphological changes affecting the mechanical and surface interactional properties. The action of separate and dual exposure to oxygen and nitrogen cold dielectric barrier discharge plasma was studied with respect to the generation of roughness (confocal laser and atomic force microscopy), nanostructural and chemical changes on the cellulose film surface, and their combined effect on wettability. Elemental analysis showed that with longer enzymatic pretreatment time the wetting response was sensitive to the chemical and morphological changes induced by both plasma gases, but distinctly oxygen plasma was seen to induce much greater morphological change while nitrogen plasma contributed more to chemical modification of the film surface. In this novel study, it is shown that exposure to oxygen plasma, subsequently followed by exposure to nitrogen plasma, leads first to an increase in wetting, and second to more hydrophobic behaviour, thus improving, for example, suitability for printing using polar functional inks or providing film barrier properties, respectively.
T2  - Materials
T1  - Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions
IS  - 13
VL  - 14
DO  - 10.3390/ma14133571
ER  - 
@article{
author = "Dimic-Misic, Katarina and Kostić, Mirjana and Obradovic, Bratislav and Kuraica, Milorad and Kramar, Ana and Imani, Monireh and Gane, Patrick",
year = "2021",
abstract = "The surface of cellulose films, obtained from micro nanofibrillated cellulose produced with different enzymatic pretreatment digestion times of refined pulp, was exposed to gas plasma, resulting in a range of surface chemical and morphological changes affecting the mechanical and surface interactional properties. The action of separate and dual exposure to oxygen and nitrogen cold dielectric barrier discharge plasma was studied with respect to the generation of roughness (confocal laser and atomic force microscopy), nanostructural and chemical changes on the cellulose film surface, and their combined effect on wettability. Elemental analysis showed that with longer enzymatic pretreatment time the wetting response was sensitive to the chemical and morphological changes induced by both plasma gases, but distinctly oxygen plasma was seen to induce much greater morphological change while nitrogen plasma contributed more to chemical modification of the film surface. In this novel study, it is shown that exposure to oxygen plasma, subsequently followed by exposure to nitrogen plasma, leads first to an increase in wetting, and second to more hydrophobic behaviour, thus improving, for example, suitability for printing using polar functional inks or providing film barrier properties, respectively.",
journal = "Materials",
title = "Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions",
number = "13",
volume = "14",
doi = "10.3390/ma14133571"
}
Dimic-Misic, K., Kostić, M., Obradovic, B., Kuraica, M., Kramar, A., Imani, M.,& Gane, P.. (2021). Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions. in Materials, 14(13).
https://doi.org/10.3390/ma14133571
Dimic-Misic K, Kostić M, Obradovic B, Kuraica M, Kramar A, Imani M, Gane P. Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions. in Materials. 2021;14(13).
doi:10.3390/ma14133571 .
Dimic-Misic, Katarina, Kostić, Mirjana, Obradovic, Bratislav, Kuraica, Milorad, Kramar, Ana, Imani, Monireh, Gane, Patrick, "Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions" in Materials, 14, no. 13 (2021),
https://doi.org/10.3390/ma14133571 . .
1
6
6

Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration

Gane, Patrick; Ridgway, C. J.; Kijevčanin, Mirjana; Stijepović, M.; Uskoković, Petar; Barać, Nemanja; Dimić-Mišić, Katarina; Imani, M.; Janaćković, Đorđe; Barcelo, E.

(2021)

TY  - JOUR
AU  - Gane, Patrick
AU  - Ridgway, C. J.
AU  - Kijevčanin, Mirjana
AU  - Stijepović, M.
AU  - Uskoković, Petar
AU  - Barać, Nemanja
AU  - Dimić-Mišić, Katarina
AU  - Imani, M.
AU  - Janaćković, Đorđe
AU  - Barcelo, E.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4913
AB  - A novel surface-flow filter has been designed to take advantage of a combination of both diffusion and lateral flow permeation, since active coatings, even if porous, tend to be far less permeable than through-flow constructs. The formation of a continuous coating layer virtually excludes any fluid transport into the coating other than by planar diffusion for gases or capillarity for liquids. This study considers the additional potential advantage of creating a pixelated/patterned coating, applied using a pin coater to form printed dots onto a highly permeable cellulose fibrous paper-like substrate. The coating-fine particulate calcium carbonate combined with micro-nanofibrillated cellulose as binder and humectant-reacts on exposure to NO2 gas to form calcium nitrate. Experimental results show an effective doubling of nitrate-forming efficiency using pixelated coating compared with a reference continuous layer coating. To establish an understanding of the comparative mechanisms of gas-coating contact, computational fluid dynamic modelling is used to generate surface pressure profiles combined with a pore network model of the coating to estimate theoretical fluid permeability and gas diffusion coefficients. Although pressure-driven permeation was calculated to be approximately two orders of magnitude less than the diffusive flow, it is concluded that patterned aerofoil pressure differential effects can reduce the impact of surface stagnant layering and so aid fluid transfer, boosting the diffusive transport, which in turn delivers greater contact efficiency based on the increased accessibility to the active coating.
T2  - Transport in Porous Media
T1  - Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration
EP  - 576
IS  - 3
SP  - 539
VL  - 138
DO  - 10.1007/s11242-021-01632-z
ER  - 
@article{
author = "Gane, Patrick and Ridgway, C. J. and Kijevčanin, Mirjana and Stijepović, M. and Uskoković, Petar and Barać, Nemanja and Dimić-Mišić, Katarina and Imani, M. and Janaćković, Đorđe and Barcelo, E.",
year = "2021",
abstract = "A novel surface-flow filter has been designed to take advantage of a combination of both diffusion and lateral flow permeation, since active coatings, even if porous, tend to be far less permeable than through-flow constructs. The formation of a continuous coating layer virtually excludes any fluid transport into the coating other than by planar diffusion for gases or capillarity for liquids. This study considers the additional potential advantage of creating a pixelated/patterned coating, applied using a pin coater to form printed dots onto a highly permeable cellulose fibrous paper-like substrate. The coating-fine particulate calcium carbonate combined with micro-nanofibrillated cellulose as binder and humectant-reacts on exposure to NO2 gas to form calcium nitrate. Experimental results show an effective doubling of nitrate-forming efficiency using pixelated coating compared with a reference continuous layer coating. To establish an understanding of the comparative mechanisms of gas-coating contact, computational fluid dynamic modelling is used to generate surface pressure profiles combined with a pore network model of the coating to estimate theoretical fluid permeability and gas diffusion coefficients. Although pressure-driven permeation was calculated to be approximately two orders of magnitude less than the diffusive flow, it is concluded that patterned aerofoil pressure differential effects can reduce the impact of surface stagnant layering and so aid fluid transfer, boosting the diffusive transport, which in turn delivers greater contact efficiency based on the increased accessibility to the active coating.",
journal = "Transport in Porous Media",
title = "Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration",
pages = "576-539",
number = "3",
volume = "138",
doi = "10.1007/s11242-021-01632-z"
}
Gane, P., Ridgway, C. J., Kijevčanin, M., Stijepović, M., Uskoković, P., Barać, N., Dimić-Mišić, K., Imani, M., Janaćković, Đ.,& Barcelo, E.. (2021). Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration. in Transport in Porous Media, 138(3), 539-576.
https://doi.org/10.1007/s11242-021-01632-z
Gane P, Ridgway CJ, Kijevčanin M, Stijepović M, Uskoković P, Barać N, Dimić-Mišić K, Imani M, Janaćković Đ, Barcelo E. Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration. in Transport in Porous Media. 2021;138(3):539-576.
doi:10.1007/s11242-021-01632-z .
Gane, Patrick, Ridgway, C. J., Kijevčanin, Mirjana, Stijepović, M., Uskoković, Petar, Barać, Nemanja, Dimić-Mišić, Katarina, Imani, M., Janaćković, Đorđe, Barcelo, E., "Surface Patterning Increases Fluid Sorption Efficiency in Porous Reactive Coatings: A Model for Optimised Surface-Flow Filtration" in Transport in Porous Media, 138, no. 3 (2021):539-576,
https://doi.org/10.1007/s11242-021-01632-z . .
4
1
4

Novel device for determining the effect of jetting shear on the stability of inkjet ink

Gane, Patrick; Imani, Monireh; Dimic-Misic, Katarina; Kerner, Enn

(2021)

TY  - JOUR
AU  - Gane, Patrick
AU  - Imani, Monireh
AU  - Dimic-Misic, Katarina
AU  - Kerner, Enn
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4883
AB  - Inkjet printing is a rapidly expanding technology for non-contact digital printing. The focus for the technology has changed from office printing of text and image documents increasingly toward wider applications, including large-scale printing of on demand books and packaging or ultra-small-scale functional printing of microscopic volumes of precious/rare materials formulated for use in precisely printed digitally defined patterning arrays, such as printed diagnostics, flexible electronics, anti-counterfeiting, etc. For efficiency, as well as resource management and conservation, predicting the stable runnability of an inkjet ink remains largely a key unknown. Today the only way to know often means simply trialling it, which at best takes time, and at worst incurs costs rectifying possible equipment damage. We propose a mechanically driven displacement device providing constant high-shear flow rate through an extended capillary. This differs from a standard capillary viscometer, which is commonly pressure driven only and lacks the ability to mimic consistent volume flow inkjetting. The novel method is used to study the aqueous colloidal stability of polymer solution, latex polymer suspensions and complete pigment-containing inks, including a reference pigment only comprising suspension. The results reveal the tendency to build agglomerates, determined by dynamic light scattering particle size distribution, optical and electron microscopy. Liquid phase parameters, including surface tension, and suspension intrinsic viscosity are also studied. Repeated application of high shear is seen to act as a milling process for pigment and agglomerate building tendency for latex binder. Consequences for ink jettability are discussed.
T2  - Journal of Print and Media Technology Research
T1  - Novel device for determining the effect of jetting shear on the stability of inkjet ink
EP  - 24
IS  - 1
SP  - 7
VL  - 10
DO  - 10.14622/JPMTR-2015
ER  - 
@article{
author = "Gane, Patrick and Imani, Monireh and Dimic-Misic, Katarina and Kerner, Enn",
year = "2021",
abstract = "Inkjet printing is a rapidly expanding technology for non-contact digital printing. The focus for the technology has changed from office printing of text and image documents increasingly toward wider applications, including large-scale printing of on demand books and packaging or ultra-small-scale functional printing of microscopic volumes of precious/rare materials formulated for use in precisely printed digitally defined patterning arrays, such as printed diagnostics, flexible electronics, anti-counterfeiting, etc. For efficiency, as well as resource management and conservation, predicting the stable runnability of an inkjet ink remains largely a key unknown. Today the only way to know often means simply trialling it, which at best takes time, and at worst incurs costs rectifying possible equipment damage. We propose a mechanically driven displacement device providing constant high-shear flow rate through an extended capillary. This differs from a standard capillary viscometer, which is commonly pressure driven only and lacks the ability to mimic consistent volume flow inkjetting. The novel method is used to study the aqueous colloidal stability of polymer solution, latex polymer suspensions and complete pigment-containing inks, including a reference pigment only comprising suspension. The results reveal the tendency to build agglomerates, determined by dynamic light scattering particle size distribution, optical and electron microscopy. Liquid phase parameters, including surface tension, and suspension intrinsic viscosity are also studied. Repeated application of high shear is seen to act as a milling process for pigment and agglomerate building tendency for latex binder. Consequences for ink jettability are discussed.",
journal = "Journal of Print and Media Technology Research",
title = "Novel device for determining the effect of jetting shear on the stability of inkjet ink",
pages = "24-7",
number = "1",
volume = "10",
doi = "10.14622/JPMTR-2015"
}
Gane, P., Imani, M., Dimic-Misic, K.,& Kerner, E.. (2021). Novel device for determining the effect of jetting shear on the stability of inkjet ink. in Journal of Print and Media Technology Research, 10(1), 7-24.
https://doi.org/10.14622/JPMTR-2015
Gane P, Imani M, Dimic-Misic K, Kerner E. Novel device for determining the effect of jetting shear on the stability of inkjet ink. in Journal of Print and Media Technology Research. 2021;10(1):7-24.
doi:10.14622/JPMTR-2015 .
Gane, Patrick, Imani, Monireh, Dimic-Misic, Katarina, Kerner, Enn, "Novel device for determining the effect of jetting shear on the stability of inkjet ink" in Journal of Print and Media Technology Research, 10, no. 1 (2021):7-24,
https://doi.org/10.14622/JPMTR-2015 . .