TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković-Koch, Tanja
AU  - Andrić, Milan
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1867
AB  - Kinetics of ferrocyanide electrooxidation was investigated by nonlinear frequency response analysis (NLFRA) of current output to the sinusoidal large-amplitude potential perturbation input. The aim was to establish a measurement routine and to validate experimentally the NLFRA method on an example of a simple electrochemical reaction comprising charge and mass transfer. The first-order frequency response function (FRF) contains quasi-linear information on the reaction kinetics and corresponds to electrochemical admittance. The nonlinear fingerprint of the system is contained in the second-order FRF. The first- and second-order FRFs are determined from experimental first and second harmonics. Their intensities depend on the input signal amplitude, which has to be chosen carefully to avoid the contributions of higher order harmonics. The influence of the potential and electrode rotation speed on the first- and second-order FRFs has been studied. The experimentally obtained FRFs are compared with the theoretical FRFs determined in Part I of this work. The theoretical FRFs can predict all essential experimental observations. These findings indicate that additional information on reaction kinetics can be gained from the analysis of the second-order FRF.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry C
T1  - Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation
EP  - 17358
IS  - 35
SP  - 17352
VL  - 115
DO  - 10.1021/jp201300a
ER  - 

@article{
author = "Panić, Vladimir and Vidaković-Koch, Tanja and Andrić, Milan and Petkovska, Menka and Sundmacher, Kai",
year = "2011",
abstract = "Kinetics of ferrocyanide electrooxidation was investigated by nonlinear frequency response analysis (NLFRA) of current output to the sinusoidal large-amplitude potential perturbation input. The aim was to establish a measurement routine and to validate experimentally the NLFRA method on an example of a simple electrochemical reaction comprising charge and mass transfer. The first-order frequency response function (FRF) contains quasi-linear information on the reaction kinetics and corresponds to electrochemical admittance. The nonlinear fingerprint of the system is contained in the second-order FRF. The first- and second-order FRFs are determined from experimental first and second harmonics. Their intensities depend on the input signal amplitude, which has to be chosen carefully to avoid the contributions of higher order harmonics. The influence of the potential and electrode rotation speed on the first- and second-order FRFs has been studied. The experimentally obtained FRFs are compared with the theoretical FRFs determined in Part I of this work. The theoretical FRFs can predict all essential experimental observations. These findings indicate that additional information on reaction kinetics can be gained from the analysis of the second-order FRF.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation",
pages = "17358-17352",
number = "35",
volume = "115",
doi = "10.1021/jp201300a"
}

Panić, V., Vidaković-Koch, T., Andrić, M., Petkovska, M.,& Sundmacher, K.. (2011). Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 115(35), 17352-17358.
https://doi.org/10.1021/jp201300a

Panić V, Vidaković-Koch T, Andrić M, Petkovska M, Sundmacher K. Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation. in Journal of Physical Chemistry C. 2011;115(35):17352-17358.
doi:10.1021/jp201300a .

Panić, Vladimir, Vidaković-Koch, Tanja, Andrić, Milan, Petkovska, Menka, Sundmacher, Kai, "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation" in Journal of Physical Chemistry C, 115, no. 35 (2011):17352-17358,
https://doi.org/10.1021/jp201300a . .

TY  - JOUR
AU  - Vidaković-Koch, Tanja
AU  - Panić, Vladimir
AU  - Andrić, Milan
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1866
AB  - In this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this work
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry C
T1  - Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis
EP  - 17351
IS  - 35
SP  - 17341
VL  - 115
DO  - 10.1021/jp201297v
ER  - 

@article{
author = "Vidaković-Koch, Tanja and Panić, Vladimir and Andrić, Milan and Petkovska, Menka and Sundmacher, Kai",
year = "2011",
abstract = "In this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this work",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis",
pages = "17351-17341",
number = "35",
volume = "115",
doi = "10.1021/jp201297v"
}

Vidaković-Koch, T., Panić, V., Andrić, M., Petkovska, M.,& Sundmacher, K.. (2011). Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 115(35), 17341-17351.
https://doi.org/10.1021/jp201297v

Vidaković-Koch T, Panić V, Andrić M, Petkovska M, Sundmacher K. Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis. in Journal of Physical Chemistry C. 2011;115(35):17341-17351.
doi:10.1021/jp201297v .

Vidaković-Koch, Tanja, Panić, Vladimir, Andrić, Milan, Petkovska, Menka, Sundmacher, Kai, "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis" in Journal of Physical Chemistry C, 115, no. 35 (2011):17341-17351,
https://doi.org/10.1021/jp201297v . .