TY  - JOUR
AU  - Kowal, Andrzej
AU  - Gojković, Snežana Lj.
AU  - Lee, K-S.
AU  - Olszewski, Piotr K.
AU  - Sung, Y-E.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1518
AB  - Nanoclusters of Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 were successfully synthesized by polyol method and deposited on high-area carbon. HIRTEM and XRD analysis revealed two phases in the ternary Pt-Rh-SnO2/C catalyst: solid solution of Rh in Pt and SnO2. The activity of Pt-Rh-SnO2/C for ethanol oxidation was found to be much higher than Pt/C and Pt-Rh/C and also superior to Pt-SnO2/C. Quasi steady-state measurements at various temperatures (30-60 degrees C), ethanol concentrations (0.01-1 M) and H2SO4 concentrations (0.02-0.5 M) showed that Pt-Rh-SnO2/C is about 20 times more active than Pt/C in the potential range of interest for the fuel cell application.
PB  - Elsevier Science Inc, New York
T2  - Electrochemistry Communications
T1  - Synthesis, characterization and electrocatalytic activity for ethanol oxidation of carbon supported Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 nanoclusters
EP  - 727
IS  - 4
SP  - 724
VL  - 11
DO  - 10.1016/j.elecom.2009.01.022
ER  - 

@article{
author = "Kowal, Andrzej and Gojković, Snežana Lj. and Lee, K-S. and Olszewski, Piotr K. and Sung, Y-E.",
year = "2009",
abstract = "Nanoclusters of Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 were successfully synthesized by polyol method and deposited on high-area carbon. HIRTEM and XRD analysis revealed two phases in the ternary Pt-Rh-SnO2/C catalyst: solid solution of Rh in Pt and SnO2. The activity of Pt-Rh-SnO2/C for ethanol oxidation was found to be much higher than Pt/C and Pt-Rh/C and also superior to Pt-SnO2/C. Quasi steady-state measurements at various temperatures (30-60 degrees C), ethanol concentrations (0.01-1 M) and H2SO4 concentrations (0.02-0.5 M) showed that Pt-Rh-SnO2/C is about 20 times more active than Pt/C in the potential range of interest for the fuel cell application.",
publisher = "Elsevier Science Inc, New York",
journal = "Electrochemistry Communications",
title = "Synthesis, characterization and electrocatalytic activity for ethanol oxidation of carbon supported Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 nanoclusters",
pages = "727-724",
number = "4",
volume = "11",
doi = "10.1016/j.elecom.2009.01.022"
}

Kowal, A., Gojković, S. Lj., Lee, K-S., Olszewski, P. K.,& Sung, Y-E.. (2009). Synthesis, characterization and electrocatalytic activity for ethanol oxidation of carbon supported Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 nanoclusters. in Electrochemistry Communications
Elsevier Science Inc, New York., 11(4), 724-727.
https://doi.org/10.1016/j.elecom.2009.01.022

Kowal A, Gojković SL, Lee K, Olszewski PK, Sung Y. Synthesis, characterization and electrocatalytic activity for ethanol oxidation of carbon supported Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 nanoclusters. in Electrochemistry Communications. 2009;11(4):724-727.
doi:10.1016/j.elecom.2009.01.022 .

Kowal, Andrzej, Gojković, Snežana Lj., Lee, K-S., Olszewski, Piotr K., Sung, Y-E., "Synthesis, characterization and electrocatalytic activity for ethanol oxidation of carbon supported Pt, Pt-Rh, Pt-SnO2 and Pt-Rh-SnO2 nanoclusters" in Electrochemistry Communications, 11, no. 4 (2009):724-727,
https://doi.org/10.1016/j.elecom.2009.01.022 . .

TY  - JOUR
AU  - Lović, Jelena
AU  - Tripković, Amalija
AU  - Gojković, Snežana Lj.
AU  - Popović, Ksenija
AU  - Tripković, Dušan
AU  - Olszewski, Piotr K.
AU  - Kowal, Andrzej
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/781
AB  - Oxidation of formic acid on the platinum catalyst supported on high area carbon was investigated by potent iodynamic and quasi-steady-state polarization measurements. It was found that the poisoning of the reaction occurred both in the hydrogen region and in the double-layer region, but poisons were formed faster at lower potentials. Kinetics of the reaction was consistent with the dual path mechanism. At lower potentials HCOOH was oxidized to CO, at the Pt sites uncovered by COads. If high coverage by the poisoning species was attained, the reaction reached the limiting current plateau and further increase of the Current densities started at the potential of COads oxidation. Kinetic parameters of the HCOOH oxidation suggested that the rate determining step was the transfer of the first electron from HCOOHads, which was adsorbed under the Temkin conditions, Oxidation of formic acid became pH-dependent reaction in the electrolytes of pH  lt  1 with the reaction order with respect to H+ ions of about - 0.8.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Electroanalytical Chemistry
T1  - Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
EP  - 302
IS  - 2
SP  - 294
VL  - 581
DO  - 10.1016/j.jelechem.2005.05.002
ER  - 

@article{
author = "Lović, Jelena and Tripković, Amalija and Gojković, Snežana Lj. and Popović, Ksenija and Tripković, Dušan and Olszewski, Piotr K. and Kowal, Andrzej",
year = "2005",
abstract = "Oxidation of formic acid on the platinum catalyst supported on high area carbon was investigated by potent iodynamic and quasi-steady-state polarization measurements. It was found that the poisoning of the reaction occurred both in the hydrogen region and in the double-layer region, but poisons were formed faster at lower potentials. Kinetics of the reaction was consistent with the dual path mechanism. At lower potentials HCOOH was oxidized to CO, at the Pt sites uncovered by COads. If high coverage by the poisoning species was attained, the reaction reached the limiting current plateau and further increase of the Current densities started at the potential of COads oxidation. Kinetic parameters of the HCOOH oxidation suggested that the rate determining step was the transfer of the first electron from HCOOHads, which was adsorbed under the Temkin conditions, Oxidation of formic acid became pH-dependent reaction in the electrolytes of pH  lt  1 with the reaction order with respect to H+ ions of about - 0.8.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Electroanalytical Chemistry",
title = "Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst",
pages = "302-294",
number = "2",
volume = "581",
doi = "10.1016/j.jelechem.2005.05.002"
}

Lović, J., Tripković, A., Gojković, S. Lj., Popović, K., Tripković, D., Olszewski, P. K.,& Kowal, A.. (2005). Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst. in Journal of Electroanalytical Chemistry
Elsevier Science Sa, Lausanne., 581(2), 294-302.
https://doi.org/10.1016/j.jelechem.2005.05.002

Lović J, Tripković A, Gojković SL, Popović K, Tripković D, Olszewski PK, Kowal A. Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst. in Journal of Electroanalytical Chemistry. 2005;581(2):294-302.
doi:10.1016/j.jelechem.2005.05.002 .

Lović, Jelena, Tripković, Amalija, Gojković, Snežana Lj., Popović, Ksenija, Tripković, Dušan, Olszewski, Piotr K., Kowal, Andrzej, "Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst" in Journal of Electroanalytical Chemistry, 581, no. 2 (2005):294-302,
https://doi.org/10.1016/j.jelechem.2005.05.002 . .