TY  - JOUR
AU  - Savić, Veljko
AU  - Dojčinović, Marina
AU  - Topalović, Vladimir
AU  - Cvijović-Alagić, Ivana
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7090
AB  - The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass–ceramic from vitrified fly ash. Glass–ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T = 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass–ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass–ceramic samples was determined using Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass–ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.
PB  - Springer
T2  - International Journal of Environmental Science and Technology
T1  - The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash
DO  - 10.1007/s13762-023-05411-9
ER  - 

@article{
author = "Savić, Veljko and Dojčinović, Marina and Topalović, Vladimir and Cvijović-Alagić, Ivana and Stojanović, Jovica and Matijašević, Srđan and Grujić, Snežana",
year = "2024",
abstract = "The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass–ceramic from vitrified fly ash. Glass–ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T = 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass–ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass–ceramic samples was determined using Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass–ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.",
publisher = "Springer",
journal = "International Journal of Environmental Science and Technology",
title = "The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash",
doi = "10.1007/s13762-023-05411-9"
}

Savić, V., Dojčinović, M., Topalović, V., Cvijović-Alagić, I., Stojanović, J., Matijašević, S.,& Grujić, S.. (2024). The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash. in International Journal of Environmental Science and Technology
Springer..
https://doi.org/10.1007/s13762-023-05411-9

Savić V, Dojčinović M, Topalović V, Cvijović-Alagić I, Stojanović J, Matijašević S, Grujić S. The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash. in International Journal of Environmental Science and Technology. 2024;.
doi:10.1007/s13762-023-05411-9 .

Savić, Veljko, Dojčinović, Marina, Topalović, Vladimir, Cvijović-Alagić, Ivana, Stojanović, Jovica, Matijašević, Srđan, Grujić, Snežana, "The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash" in International Journal of Environmental Science and Technology (2024),
https://doi.org/10.1007/s13762-023-05411-9 . .

TY  - JOUR
AU  - Savić, Veljko
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Jevtić, Sanja
AU  - Manić, Nebojša
AU  - Komatina, Mirko
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6579
AB  - Great waste production alongside limited natural resources represents huge environmental and economic problems worldwide. Sustainable waste management and industrial production can reduce pollution and gain some economic benefits. Eco-friendly thermal insulators such as foam glasses can be produced using secondary raw materials in open-loop recycling. Foam glasses were successfully produced using green bottle glass and sugar beet factory lime (SBFL), CaCO3-rich waste as a novel foaming agent. Glass powder was mixed with different amounts of SBFL, uniaxially pressed at 20 MPa, and sintered at different temperatures. The influence of sintering temperature and the addition of a foaming agent was examined. Obtained samples were mechanically, thermally, and microstructurally characterized. Results showed that samples sintered at 800 °C have the best properties. Obtained foam glasses can be used in a variety of industries where thermal insulation, non-flammability, and non-toxic materials are required.
PB  - Elsevier Ltd.
T2  - Heliyon
T1  - Foam glasses made from green bottle glass and sugar beet factory lime as a foaming agent
IS  - 7
SP  - e17664
VL  - 9
DO  - 10.1016/j.heliyon.2023.e17664
ER  - 

@article{
author = "Savić, Veljko and Topalović, Vladimir and Nikolić, Jelena and Jevtić, Sanja and Manić, Nebojša and Komatina, Mirko and Matijašević, Srđan and Grujić, Snežana",
year = "2023",
abstract = "Great waste production alongside limited natural resources represents huge environmental and economic problems worldwide. Sustainable waste management and industrial production can reduce pollution and gain some economic benefits. Eco-friendly thermal insulators such as foam glasses can be produced using secondary raw materials in open-loop recycling. Foam glasses were successfully produced using green bottle glass and sugar beet factory lime (SBFL), CaCO3-rich waste as a novel foaming agent. Glass powder was mixed with different amounts of SBFL, uniaxially pressed at 20 MPa, and sintered at different temperatures. The influence of sintering temperature and the addition of a foaming agent was examined. Obtained samples were mechanically, thermally, and microstructurally characterized. Results showed that samples sintered at 800 °C have the best properties. Obtained foam glasses can be used in a variety of industries where thermal insulation, non-flammability, and non-toxic materials are required.",
publisher = "Elsevier Ltd.",
journal = "Heliyon",
title = "Foam glasses made from green bottle glass and sugar beet factory lime as a foaming agent",
number = "7",
pages = "e17664",
volume = "9",
doi = "10.1016/j.heliyon.2023.e17664"
}

Savić, V., Topalović, V., Nikolić, J., Jevtić, S., Manić, N., Komatina, M., Matijašević, S.,& Grujić, S.. (2023). Foam glasses made from green bottle glass and sugar beet factory lime as a foaming agent. in Heliyon
Elsevier Ltd.., 9(7), e17664.
https://doi.org/10.1016/j.heliyon.2023.e17664

Savić V, Topalović V, Nikolić J, Jevtić S, Manić N, Komatina M, Matijašević S, Grujić S. Foam glasses made from green bottle glass and sugar beet factory lime as a foaming agent. in Heliyon. 2023;9(7):e17664.
doi:10.1016/j.heliyon.2023.e17664 .

Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Jevtić, Sanja, Manić, Nebojša, Komatina, Mirko, Matijašević, Srđan, Grujić, Snežana, "Foam glasses made from green bottle glass and sugar beet factory lime as a foaming agent" in Heliyon, 9, no. 7 (2023):e17664,
https://doi.org/10.1016/j.heliyon.2023.e17664 . .

TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Topalović, Vladimir S.
AU  - Savić, Veljko V.
AU  - Labus, Nebojša J.
AU  - Nikolić, Jelena D.
AU  - Zildžović, Snežana N.
AU  - Grujić, Snežana R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7281
AB  - The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined experimentally and theoretically.
PB  - International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - The crystal growth of NASICON phase from the lithium germanium phosphate glass
EP  - 547
IS  - 4
SP  - 539
VL  - 55
DO  - 10.2298/SOS220809022M
ER  - 

@article{
author = "Matijašević, Srđan D. and Topalović, Vladimir S. and Savić, Veljko V. and Labus, Nebojša J. and Nikolić, Jelena D. and Zildžović, Snežana N. and Grujić, Snežana R.",
year = "2023",
abstract = "The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined experimentally and theoretically.",
publisher = "International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "The crystal growth of NASICON phase from the lithium germanium phosphate glass",
pages = "547-539",
number = "4",
volume = "55",
doi = "10.2298/SOS220809022M"
}

Matijašević, S. D., Topalović, V. S., Savić, V. V., Labus, N. J., Nikolić, J. D., Zildžović, S. N.,& Grujić, S. R.. (2023). The crystal growth of NASICON phase from the lithium germanium phosphate glass. in Science of Sintering
International Institute for the Science of Sintering., 55(4), 539-547.
https://doi.org/10.2298/SOS220809022M

Matijašević SD, Topalović VS, Savić VV, Labus NJ, Nikolić JD, Zildžović SN, Grujić SR. The crystal growth of NASICON phase from the lithium germanium phosphate glass. in Science of Sintering. 2023;55(4):539-547.
doi:10.2298/SOS220809022M .

Matijašević, Srđan D., Topalović, Vladimir S., Savić, Veljko V., Labus, Nebojša J., Nikolić, Jelena D., Zildžović, Snežana N., Grujić, Snežana R., "The crystal growth of NASICON phase from the lithium germanium phosphate glass" in Science of Sintering, 55, no. 4 (2023):539-547,
https://doi.org/10.2298/SOS220809022M . .

TY  - JOUR
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Matijašević, Srđan
AU  - Stojanović, Jovica
AU  - Karamanov, Alexander
AU  - Grujić, Snežana
AU  - Jevtić, Sanja
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5272
AB  - The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass–ceramic containing bioactive β-CaP2O6, α-Ca3(PO4)2, and β-Ca3(PO4)2 phases were successfully prepared.
PB  - Springer Science and Business Media B.V.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses
DO  - 10.1007/s10973-022-11777-8
ER  - 

@article{
author = "Topalović, Vladimir and Nikolić, Jelena and Matijašević, Srđan and Stojanović, Jovica and Karamanov, Alexander and Grujić, Snežana and Jevtić, Sanja",
year = "2022",
abstract = "The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass–ceramic containing bioactive β-CaP2O6, α-Ca3(PO4)2, and β-Ca3(PO4)2 phases were successfully prepared.",
publisher = "Springer Science and Business Media B.V.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses",
doi = "10.1007/s10973-022-11777-8"
}

Topalović, V., Nikolić, J., Matijašević, S., Stojanović, J., Karamanov, A., Grujić, S.,& Jevtić, S.. (2022). The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry
Springer Science and Business Media B.V...
https://doi.org/10.1007/s10973-022-11777-8

Topalović V, Nikolić J, Matijašević S, Stojanović J, Karamanov A, Grujić S, Jevtić S. The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry. 2022;.
doi:10.1007/s10973-022-11777-8 .

Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Stojanović, Jovica, Karamanov, Alexander, Grujić, Snežana, Jevtić, Sanja, "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses" in Journal of Thermal Analysis and Calorimetry (2022),
https://doi.org/10.1007/s10973-022-11777-8 . .

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
AU  - Savić, Veljko
AU  - Zildžović, Snežana
AU  - Labus, Nebojša
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5370
AB  - The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.
T2  - Science of Sintering
T1  - The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass
EP  - 334
IS  - 3
SP  - 321
VL  - 54
DO  - 10.2298/SOS2203321M
UR  - https://hdl.handle.net/21.15107/rcub_dais_13580
ER  - 

@article{
author = "Matijašević, Srđan and Grujić, Snežana and Nikolić, Jelena and Topalović, Vladimir and Savić, Veljko and Zildžović, Snežana and Labus, Nebojša",
year = "2022",
abstract = "The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.",
journal = "Science of Sintering",
title = "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass",
pages = "334-321",
number = "3",
volume = "54",
doi = "10.2298/SOS2203321M",
url = "https://hdl.handle.net/21.15107/rcub_dais_13580"
}

Matijašević, S., Grujić, S., Nikolić, J., Topalović, V., Savić, V., Zildžović, S.,& Labus, N.. (2022). The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering, 54(3), 321-334.
https://doi.org/10.2298/SOS2203321M
https://hdl.handle.net/21.15107/rcub_dais_13580

Matijašević S, Grujić S, Nikolić J, Topalović V, Savić V, Zildžović S, Labus N. The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering. 2022;54(3):321-334.
doi:10.2298/SOS2203321M
https://hdl.handle.net/21.15107/rcub_dais_13580 .

Matijašević, Srđan, Grujić, Snežana, Nikolić, Jelena, Topalović, Vladimir, Savić, Veljko, Zildžović, Snežana, Labus, Nebojša, "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass" in Science of Sintering, 54, no. 3 (2022):321-334,
https://doi.org/10.2298/SOS2203321M .,
https://hdl.handle.net/21.15107/rcub_dais_13580 .

TY  - JOUR
AU  - Matijašević, Srdjan D.
AU  - Topalović, Vladimir S.
AU  - Grujić, Snežana
AU  - Savić, Veljko V.
AU  - Nikolić, Jelena D.
AU  - Labus, Nebojsa J.
AU  - Zildzović, Snezana N.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4818
AB  - The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.
T2  - Science of Sintering
T1  - The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass
EP  - 310
IS  - 3
SP  - 301
VL  - 53
DO  - 10.2298/SOS2103301M
ER  - 

@article{
author = "Matijašević, Srdjan D. and Topalović, Vladimir S. and Grujić, Snežana and Savić, Veljko V. and Nikolić, Jelena D. and Labus, Nebojsa J. and Zildzović, Snezana N.",
year = "2021",
abstract = "The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.",
journal = "Science of Sintering",
title = "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass",
pages = "310-301",
number = "3",
volume = "53",
doi = "10.2298/SOS2103301M"
}

Matijašević, S. D., Topalović, V. S., Grujić, S., Savić, V. V., Nikolić, J. D., Labus, N. J.,& Zildzović, S. N.. (2021). The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering, 53(3), 301-310.
https://doi.org/10.2298/SOS2103301M

Matijašević SD, Topalović VS, Grujić S, Savić VV, Nikolić JD, Labus NJ, Zildzović SN. The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering. 2021;53(3):301-310.
doi:10.2298/SOS2103301M .

Matijašević, Srdjan D., Topalović, Vladimir S., Grujić, Snežana, Savić, Veljko V., Nikolić, Jelena D., Labus, Nebojsa J., Zildzović, Snezana N., "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass" in Science of Sintering, 53, no. 3 (2021):301-310,
https://doi.org/10.2298/SOS2103301M . .

TY  - JOUR
AU  - Savic, Veljko
AU  - Topalovic, Vladimir
AU  - Matijasevic, Srdan
AU  - Nikolic, Jelena
AU  - Grujić, Snežana
AU  - Zildzovic, Snezana
AU  - Radulovic, Aleksandra
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4890
AB  - In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.
T2  - Metallurgical & Materials Engineering
T1  - Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand
EP  - 113
IS  - 1
SP  - 105
VL  - 27
DO  - 10.30544/477
ER  - 

@article{
author = "Savic, Veljko and Topalovic, Vladimir and Matijasevic, Srdan and Nikolic, Jelena and Grujić, Snežana and Zildzovic, Snezana and Radulovic, Aleksandra",
year = "2021",
abstract = "In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.",
journal = "Metallurgical & Materials Engineering",
title = "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand",
pages = "113-105",
number = "1",
volume = "27",
doi = "10.30544/477"
}

Savic, V., Topalovic, V., Matijasevic, S., Nikolic, J., Grujić, S., Zildzovic, S.,& Radulovic, A.. (2021). Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering, 27(1), 105-113.
https://doi.org/10.30544/477

Savic V, Topalovic V, Matijasevic S, Nikolic J, Grujić S, Zildzovic S, Radulovic A. Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering. 2021;27(1):105-113.
doi:10.30544/477 .

Savic, Veljko, Topalovic, Vladimir, Matijasevic, Srdan, Nikolic, Jelena, Grujić, Snežana, Zildzovic, Snezana, Radulovic, Aleksandra, "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand" in Metallurgical & Materials Engineering, 27, no. 1 (2021):105-113,
https://doi.org/10.30544/477 . .

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Matijašević, Srđan D.
AU  - Stojanović, Jovica
AU  - Nikolić, Jelena
AU  - Savić, Veljko
AU  - Popović, Daniela
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/13
AB  - The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystal growth of la(2)srb(10)o(19)from undercooled melt
DO  - 10.1007/s10973-020-10122-1
ER  - 

@article{
author = "Smiljanić, Sonja and Grujić, Snežana and Matijašević, Srđan D. and Stojanović, Jovica and Nikolić, Jelena and Savić, Veljko and Popović, Daniela",
year = "2020",
abstract = "The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystal growth of la(2)srb(10)o(19)from undercooled melt",
doi = "10.1007/s10973-020-10122-1"
}

Smiljanić, S., Grujić, S., Matijašević, S. D., Stojanović, J., Nikolić, J., Savić, V.,& Popović, D.. (2020). Crystal growth of la(2)srb(10)o(19)from undercooled melt. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht..
https://doi.org/10.1007/s10973-020-10122-1

Smiljanić S, Grujić S, Matijašević SD, Stojanović J, Nikolić J, Savić V, Popović D. Crystal growth of la(2)srb(10)o(19)from undercooled melt. in Journal of Thermal Analysis and Calorimetry. 2020;.
doi:10.1007/s10973-020-10122-1 .

Smiljanić, Sonja, Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Popović, Daniela, "Crystal growth of la(2)srb(10)o(19)from undercooled melt" in Journal of Thermal Analysis and Calorimetry (2020),
https://doi.org/10.1007/s10973-020-10122-1 . .

TY  - JOUR
AU  - Karamanov, Alexander
AU  - Smiljanić, Sonja
AU  - Karamanova, Emilia
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena
AU  - Savić, Veljko
AU  - Grujić, Snežana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4386
AB  - Sintering, crystallization and foaming of nano glass powders with composition La2O3 center dot SrO center dot 5B(2)O(3) were studied by hot stage microscopy (HSM) and simultaneous thermal analysis (DTA-TG) under non-isothermal regime at 10 degrees C/min and by optical contactless dilatometer under isothermal conditions at 700 degrees C up to 10 hours for different times. After the thermal treatments, specimens were characterized by gas pycnometry, X-ray Powder Diffraction (XRD) and Field Emission Scanning Electron Microscopes (FE-SEM). The results demonstrate that the densification completed before the crystallization process, thus forming well sintered samples. Then, during the phase formation gas is released, which leads to foaming process. After holding of 160 minutes at 700 degrees C the degree of crystallization reached about 0.8 and the foaming stopped. The obtained sample had high closed porosity and quite intriguing structure composed of two fairly different crystal arrangements. The first was "sponge-like", while the second was denser and consisted of "sheets", 10-30 nm thick. The subsequent holding led to re-crystallization, formation of larger denser zones that reached even 10-15 mu m and an increase in open porosity. These results highlight that in the case of sinter crystallization of nano powders, some intriguing features can be expected.
PB  - Elsevier, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time
VL  - 544
DO  - 10.1016/j.jnoncrysol.2020.120168
ER  - 

@article{
author = "Karamanov, Alexander and Smiljanić, Sonja and Karamanova, Emilia and Matijašević, Srđan D. and Nikolić, Jelena and Savić, Veljko and Grujić, Snežana",
year = "2020",
abstract = "Sintering, crystallization and foaming of nano glass powders with composition La2O3 center dot SrO center dot 5B(2)O(3) were studied by hot stage microscopy (HSM) and simultaneous thermal analysis (DTA-TG) under non-isothermal regime at 10 degrees C/min and by optical contactless dilatometer under isothermal conditions at 700 degrees C up to 10 hours for different times. After the thermal treatments, specimens were characterized by gas pycnometry, X-ray Powder Diffraction (XRD) and Field Emission Scanning Electron Microscopes (FE-SEM). The results demonstrate that the densification completed before the crystallization process, thus forming well sintered samples. Then, during the phase formation gas is released, which leads to foaming process. After holding of 160 minutes at 700 degrees C the degree of crystallization reached about 0.8 and the foaming stopped. The obtained sample had high closed porosity and quite intriguing structure composed of two fairly different crystal arrangements. The first was "sponge-like", while the second was denser and consisted of "sheets", 10-30 nm thick. The subsequent holding led to re-crystallization, formation of larger denser zones that reached even 10-15 mu m and an increase in open porosity. These results highlight that in the case of sinter crystallization of nano powders, some intriguing features can be expected.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time",
volume = "544",
doi = "10.1016/j.jnoncrysol.2020.120168"
}

Karamanov, A., Smiljanić, S., Karamanova, E., Matijašević, S. D., Nikolić, J., Savić, V.,& Grujić, S.. (2020). Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time. in Journal of Non-Crystalline Solids
Elsevier, Amsterdam., 544.
https://doi.org/10.1016/j.jnoncrysol.2020.120168

Karamanov A, Smiljanić S, Karamanova E, Matijašević SD, Nikolić J, Savić V, Grujić S. Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time. in Journal of Non-Crystalline Solids. 2020;544.
doi:10.1016/j.jnoncrysol.2020.120168 .

Karamanov, Alexander, Smiljanić, Sonja, Karamanova, Emilia, Matijašević, Srđan D., Nikolić, Jelena, Savić, Veljko, Grujić, Snežana, "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time" in Journal of Non-Crystalline Solids, 544 (2020),
https://doi.org/10.1016/j.jnoncrysol.2020.120168 . .

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Vulić, Predrag
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
AU  - Savić, Veljko
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4305
AB  - The crystal structure of new lanthanum strontium borate glass-ceramics was refined by the Rietveld method. The results showed that La2SrB10O19 has the monoclinic crystal structure, space group C2 (No. 5) with a = 11.1170(6), b = 6.5667(3), c = 9.2363(3) angstrom,beta = 91.481 degrees, V = 674.04(7) angstrom(3), two formula units per unit-cell, and density 3.830 g cm(-3). The main building units of the crystal structure are BO4 tetrahedra and BO3 triangles. Clusters composed of [B5O12] form an infinite double layer running perpendicular to the c-axis. Lanthanum atoms, situated in [B5O12](n) layers, are coordinated with 10 oxygen atom in a form of LaO10 polyhedra, while Sr atoms, located between [B5O12](n) layers, are coordinated with 8 oxygen atoms in a form of SrO8 polyhedra. Microstructural measurements contain both crystallite domain sizes and microstrain calculations obtained by the Warren Averbach and the simplified integral-breadth methods.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics
EP  - 399
IS  - 4
SP  - 389
VL  - 51
DO  - 10.2298/SOS1904389S
ER  - 

@article{
author = "Stojanović, Jovica and Smiljanić, Sonja and Grujić, Snežana and Vulić, Predrag and Matijašević, Srđan D. and Nikolić, Jelena D. and Savić, Veljko",
year = "2019",
abstract = "The crystal structure of new lanthanum strontium borate glass-ceramics was refined by the Rietveld method. The results showed that La2SrB10O19 has the monoclinic crystal structure, space group C2 (No. 5) with a = 11.1170(6), b = 6.5667(3), c = 9.2363(3) angstrom,beta = 91.481 degrees, V = 674.04(7) angstrom(3), two formula units per unit-cell, and density 3.830 g cm(-3). The main building units of the crystal structure are BO4 tetrahedra and BO3 triangles. Clusters composed of [B5O12] form an infinite double layer running perpendicular to the c-axis. Lanthanum atoms, situated in [B5O12](n) layers, are coordinated with 10 oxygen atom in a form of LaO10 polyhedra, while Sr atoms, located between [B5O12](n) layers, are coordinated with 8 oxygen atoms in a form of SrO8 polyhedra. Microstructural measurements contain both crystallite domain sizes and microstrain calculations obtained by the Warren Averbach and the simplified integral-breadth methods.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics",
pages = "399-389",
number = "4",
volume = "51",
doi = "10.2298/SOS1904389S"
}

Stojanović, J., Smiljanić, S., Grujić, S., Vulić, P., Matijašević, S. D., Nikolić, J. D.,& Savić, V.. (2019). Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(4), 389-399.
https://doi.org/10.2298/SOS1904389S

Stojanović J, Smiljanić S, Grujić S, Vulić P, Matijašević SD, Nikolić JD, Savić V. Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics. in Science of Sintering. 2019;51(4):389-399.
doi:10.2298/SOS1904389S .

Stojanović, Jovica, Smiljanić, Sonja, Grujić, Snežana, Vulić, Predrag, Matijašević, Srđan D., Nikolić, Jelena D., Savić, Veljko, "Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics" in Science of Sintering, 51, no. 4 (2019):389-399,
https://doi.org/10.2298/SOS1904389S . .

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Karamanova, Emilia
AU  - Grujić, Snežana
AU  - Rogan, Jelena
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan D.
AU  - Karamanov, Alexander
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3989
AB  - The peculiarities of sinter-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) fine glass powder (below 1 mu m) are investigated and discussed. The sintering was studied by contactless optical dilatometry and porosity measurements. The crystallization process was evaluated by differential scanning calorimetry (DSC) and the crystalline phase formation was analyzed by X-ray diffraction (XRD). Finally the microstructures of the samples sintered at different temperatures were observed by field emission scanning electron microscope (FESEM). The specific aim of this study was to highlight the influence of sintering temperature and heating rate on the densification process and the final structure of glass-ceramic samples. It was shown that zero water adsorption and minimum closed porosity of similar to 3% were obtained at heating rate of 2 degrees C/min and at about 1 h holding at 690 degrees C. The temperature increase accelerated intense foaming process that resulted in formation of total porosity of 35-45%. It was also demonstrated that the foaming depended on the heating rate: the higher the heating rate - the more intensive was the bloating. The observed foaming process was related to intensive crystallization and re-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) crystal phase. The phase formation processes entirely completed after 30-60 min at 730-740 degrees C with the formation of intriguing and unusual crystal structures.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate
EP  - 382
SP  - 375
VL  - 481
DO  - 10.1016/j.jnoncrysol.2017.11.009
ER  - 

@article{
author = "Smiljanić, Sonja and Karamanova, Emilia and Grujić, Snežana and Rogan, Jelena and Stojanović, Jovica and Matijašević, Srđan D. and Karamanov, Alexander",
year = "2018",
abstract = "The peculiarities of sinter-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) fine glass powder (below 1 mu m) are investigated and discussed. The sintering was studied by contactless optical dilatometry and porosity measurements. The crystallization process was evaluated by differential scanning calorimetry (DSC) and the crystalline phase formation was analyzed by X-ray diffraction (XRD). Finally the microstructures of the samples sintered at different temperatures were observed by field emission scanning electron microscope (FESEM). The specific aim of this study was to highlight the influence of sintering temperature and heating rate on the densification process and the final structure of glass-ceramic samples. It was shown that zero water adsorption and minimum closed porosity of similar to 3% were obtained at heating rate of 2 degrees C/min and at about 1 h holding at 690 degrees C. The temperature increase accelerated intense foaming process that resulted in formation of total porosity of 35-45%. It was also demonstrated that the foaming depended on the heating rate: the higher the heating rate - the more intensive was the bloating. The observed foaming process was related to intensive crystallization and re-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) crystal phase. The phase formation processes entirely completed after 30-60 min at 730-740 degrees C with the formation of intriguing and unusual crystal structures.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate",
pages = "382-375",
volume = "481",
doi = "10.1016/j.jnoncrysol.2017.11.009"
}

Smiljanić, S., Karamanova, E., Grujić, S., Rogan, J., Stojanović, J., Matijašević, S. D.,& Karamanov, A.. (2018). Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate. in Journal of Non-Crystalline Solids
Elsevier Science Bv, Amsterdam., 481, 375-382.
https://doi.org/10.1016/j.jnoncrysol.2017.11.009

Smiljanić S, Karamanova E, Grujić S, Rogan J, Stojanović J, Matijašević SD, Karamanov A. Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate. in Journal of Non-Crystalline Solids. 2018;481:375-382.
doi:10.1016/j.jnoncrysol.2017.11.009 .

Smiljanić, Sonja, Karamanova, Emilia, Grujić, Snežana, Rogan, Jelena, Stojanović, Jovica, Matijašević, Srđan D., Karamanov, Alexander, "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate" in Journal of Non-Crystalline Solids, 481 (2018):375-382,
https://doi.org/10.1016/j.jnoncrysol.2017.11.009 . .

TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Grujić, Snežana
AU  - Topalović, Vladimir S.
AU  - Nikolić, Jelena D.
AU  - Smiljanić, Sonja
AU  - Labus, Nebojša
AU  - Savić, Veljko
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3895
AB  - Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods
EP  - 203
IS  - 2
SP  - 193
VL  - 50
DO  - 10.2298/SOS1802193M
ER  - 

@article{
author = "Matijašević, Srđan D. and Grujić, Snežana and Topalović, Vladimir S. and Nikolić, Jelena D. and Smiljanić, Sonja and Labus, Nebojša and Savić, Veljko",
year = "2018",
abstract = "Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods",
pages = "203-193",
number = "2",
volume = "50",
doi = "10.2298/SOS1802193M"
}

Matijašević, S. D., Grujić, S., Topalović, V. S., Nikolić, J. D., Smiljanić, S., Labus, N.,& Savić, V.. (2018). Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(2), 193-203.
https://doi.org/10.2298/SOS1802193M

Matijašević SD, Grujić S, Topalović VS, Nikolić JD, Smiljanić S, Labus N, Savić V. Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering. 2018;50(2):193-203.
doi:10.2298/SOS1802193M .

Matijašević, Srđan D., Grujić, Snežana, Topalović, Vladimir S., Nikolić, Jelena D., Smiljanić, Sonja, Labus, Nebojša, Savić, Veljko, "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods" in Science of Sintering, 50, no. 2 (2018):193-203,
https://doi.org/10.2298/SOS1802193M . .

TY  - BOOK
AU  - Joksimović-Tjapkin, Slobodanka
AU  - Grujić, Snežana
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7293
PB  - Beograd : Tehnološko-metalurški fakultet Univerziteta
T1  - Tehnologija goriva i sagorevanja
EP  - 335
SP  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7293
ER  - 

@book{
author = "Joksimović-Tjapkin, Slobodanka and Grujić, Snežana",
year = "2017",
publisher = "Beograd : Tehnološko-metalurški fakultet Univerziteta",
title = "Tehnologija goriva i sagorevanja",
pages = "335-1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7293"
}

Joksimović-Tjapkin, S.,& Grujić, S.. (2017). Tehnologija goriva i sagorevanja. 
Beograd : Tehnološko-metalurški fakultet Univerziteta., 1-335.
https://hdl.handle.net/21.15107/rcub_technorep_7293

Joksimović-Tjapkin S, Grujić S. Tehnologija goriva i sagorevanja. 2017;:1-335.
https://hdl.handle.net/21.15107/rcub_technorep_7293 .

Joksimović-Tjapkin, Slobodanka, Grujić, Snežana, "Tehnologija goriva i sagorevanja" (2017):1-335,
https://hdl.handle.net/21.15107/rcub_technorep_7293 .

TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, Daniela
AU  - Rard, Joseph A.
AU  - Grujić, Snežana
AU  - Miladinović, Zoran P.
AU  - Miladinović, Jelena
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3587
AB  - Isopiestic (vapor pressure) measurements were made for aqueous mixtures of Mg(NO3)(2) and MgSO4 at T = (298.15 +/- 0.01) K with Mg(NO3)(2) ionic strength fractions y = (0.19691, 0.42542, 0.60113, 0.79583, and 1), along with a separate series of measurements for MgSO4(aq), y = 0, all using KCl(aq) as the reference standard. The resulting 44 molality-based osmotic coefficients for the ternary mixtures, ionic strength range I-m = (2.5924-8.4583) mol-kg(-1), were modeled with an extended form of Pitzer's ion interaction model, both with the usual Pitzer mixing terms and also with Scatchard's neutral electrolyte model mixing terms, and also with the Clegg-Pitzer-Brimblecombe model based on the mole-fraction-composition scale. The molality-based osmotic coefficients phi of these mixtures at each fixed ionic strength fraction fall in a regular order between those of the corresponding limiting binary solutions with no crossovers in this ionic strength range. Model parameters for Mg(NO3)(2)(aq) and MgSO4(aq) at T = 298.15 K needed for these calculations were evaluated by using the present isopiestic results along with other sets of reliable osmotic coefficients gleaned from the published literature. Our osmotic coefficients for the ternary system are compared with those from a previous isopiestic study and a hygrometric study and the present results were judged to be more accurate. For this ternary system, both mixing parameters are needed for the extended Pitzer model with Pitzer mixing terms {standard uncertainty of fit u(phi)= 7.0 x 10(-3)} whereas three parameters gave a significantly better fit when the Scatchard mixing terms are used {standard uncertainty of fit u(phi) = 4.0 x 10(-3); the fits with two Scatchard mixing parameters did slightly better than the fit with both Pitzer mixing terms}, as did the Clegg-Pitzer-Brimblecombe model with three mixing parameters {standard uncertainty of fit u(phi) = 5.9 x 10(-3)}, with use of the three Scatchard mixing parameters giving the most precise representation of the experimental results. Including higher-order electrostatic mixing terms did not improve the representations but had the opposite effect.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K
EP  - 103
SP  - 91
VL  - 113
DO  - 10.1016/j.jct.2017.05.006
ER  - 

@article{
author = "Ivanović, Tijana and Popović, Daniela and Rard, Joseph A. and Grujić, Snežana and Miladinović, Zoran P. and Miladinović, Jelena",
year = "2017",
abstract = "Isopiestic (vapor pressure) measurements were made for aqueous mixtures of Mg(NO3)(2) and MgSO4 at T = (298.15 +/- 0.01) K with Mg(NO3)(2) ionic strength fractions y = (0.19691, 0.42542, 0.60113, 0.79583, and 1), along with a separate series of measurements for MgSO4(aq), y = 0, all using KCl(aq) as the reference standard. The resulting 44 molality-based osmotic coefficients for the ternary mixtures, ionic strength range I-m = (2.5924-8.4583) mol-kg(-1), were modeled with an extended form of Pitzer's ion interaction model, both with the usual Pitzer mixing terms and also with Scatchard's neutral electrolyte model mixing terms, and also with the Clegg-Pitzer-Brimblecombe model based on the mole-fraction-composition scale. The molality-based osmotic coefficients phi of these mixtures at each fixed ionic strength fraction fall in a regular order between those of the corresponding limiting binary solutions with no crossovers in this ionic strength range. Model parameters for Mg(NO3)(2)(aq) and MgSO4(aq) at T = 298.15 K needed for these calculations were evaluated by using the present isopiestic results along with other sets of reliable osmotic coefficients gleaned from the published literature. Our osmotic coefficients for the ternary system are compared with those from a previous isopiestic study and a hygrometric study and the present results were judged to be more accurate. For this ternary system, both mixing parameters are needed for the extended Pitzer model with Pitzer mixing terms {standard uncertainty of fit u(phi)= 7.0 x 10(-3)} whereas three parameters gave a significantly better fit when the Scatchard mixing terms are used {standard uncertainty of fit u(phi) = 4.0 x 10(-3); the fits with two Scatchard mixing parameters did slightly better than the fit with both Pitzer mixing terms}, as did the Clegg-Pitzer-Brimblecombe model with three mixing parameters {standard uncertainty of fit u(phi) = 5.9 x 10(-3)}, with use of the three Scatchard mixing parameters giving the most precise representation of the experimental results. Including higher-order electrostatic mixing terms did not improve the representations but had the opposite effect.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K",
pages = "103-91",
volume = "113",
doi = "10.1016/j.jct.2017.05.006"
}

Ivanović, T., Popović, D., Rard, J. A., Grujić, S., Miladinović, Z. P.,& Miladinović, J.. (2017). Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 113, 91-103.
https://doi.org/10.1016/j.jct.2017.05.006

Ivanović T, Popović D, Rard JA, Grujić S, Miladinović ZP, Miladinović J. Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2017;113:91-103.
doi:10.1016/j.jct.2017.05.006 .

Ivanović, Tijana, Popović, Daniela, Rard, Joseph A., Grujić, Snežana, Miladinović, Zoran P., Miladinović, Jelena, "Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 113 (2017):91-103,
https://doi.org/10.1016/j.jct.2017.05.006 . .

TY  - JOUR
AU  - Topalović, Vladimir S.
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
AU  - Stojanović, Jovica
AU  - Smiljanić, Sonja
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3583
AB  - Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium
EP  - 12069
IS  - 15
SP  - 12061
VL  - 43
DO  - 10.1016/j.ceramint.2017.06.061
ER  - 

@article{
author = "Topalović, Vladimir S. and Grujić, Snežana and Živanović, Vladimir D. and Matijašević, Srđan D. and Nikolić, Jelena D. and Stojanović, Jovica and Smiljanić, Sonja",
year = "2017",
abstract = "Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium",
pages = "12069-12061",
number = "15",
volume = "43",
doi = "10.1016/j.ceramint.2017.06.061"
}

Topalović, V. S., Grujić, S., Živanović, V. D., Matijašević, S. D., Nikolić, J. D., Stojanović, J.,& Smiljanić, S.. (2017). Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(15), 12061-12069.
https://doi.org/10.1016/j.ceramint.2017.06.061

Topalović VS, Grujić S, Živanović VD, Matijašević SD, Nikolić JD, Stojanović J, Smiljanić S. Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International. 2017;43(15):12061-12069.
doi:10.1016/j.ceramint.2017.06.061 .

Topalović, Vladimir S., Grujić, Snežana, Živanović, Vladimir D., Matijašević, Srđan D., Nikolić, Jelena D., Stojanović, Jovica, Smiljanić, Sonja, "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium" in Ceramics International, 43, no. 15 (2017):12061-12069,
https://doi.org/10.1016/j.ceramint.2017.06.061 . .

TY  - JOUR
AU  - Nikolić, Jelena D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Đošić, Marija
AU  - Matijašević, Srđan D.
AU  - Smiljanić, Sonja
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3708
AB  - In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Dissolution behavior of a polyphosphate glass in simulated body fluid
EP  - 342
IS  - 3
SP  - 329
VL  - 82
DO  - 10.2298/JSC161031009N
ER  - 

@article{
author = "Nikolić, Jelena D. and Tošić, Mihajlo B. and Grujić, Snežana and Živanović, Vladimir D. and Đošić, Marija and Matijašević, Srđan D. and Smiljanić, Sonja",
year = "2017",
abstract = "In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Dissolution behavior of a polyphosphate glass in simulated body fluid",
pages = "342-329",
number = "3",
volume = "82",
doi = "10.2298/JSC161031009N"
}

Nikolić, J. D., Tošić, M. B., Grujić, S., Živanović, V. D., Đošić, M., Matijašević, S. D.,& Smiljanić, S.. (2017). Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(3), 329-342.
https://doi.org/10.2298/JSC161031009N

Nikolić JD, Tošić MB, Grujić S, Živanović VD, Đošić M, Matijašević SD, Smiljanić S. Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society. 2017;82(3):329-342.
doi:10.2298/JSC161031009N .

Nikolić, Jelena D., Tošić, Mihajlo B., Grujić, Snežana, Živanović, Vladimir D., Đošić, Marija, Matijašević, Srđan D., Smiljanić, Sonja, "Dissolution behavior of a polyphosphate glass in simulated body fluid" in Journal of the Serbian Chemical Society, 82, no. 3 (2017):329-342,
https://doi.org/10.2298/JSC161031009N . .

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Rard, Joseph A.
AU  - Miladinović, Zoran P.
AU  - Grujić, Snežana
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3362
AB  - Isopiestic measurements have been made for aqueous mixtures of Na2HPO4 and K2HPO4 at T = (298.15 +/- 0.01) K, at Na2HPO4 ionic strength fractions y = (0.2023, 0.4060, 0.6027, 0.8007, and 1), using KCl(aq) as the reference standard solution. The resulting 48 molality-based osmotic coefficients for the ternary mixtures were modeled with an extended form of Pitzer's ion-interaction model, with the usual Pitzer mixing terms and also with Scatchard's neutral-electrolyte model mixing terms, along with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. Model parameters for Na2HPO4(aq) at T = 298.15 K were also evaluated using the present isopiestic results (12 values) along with three other sets of osmotic coefficients from isopiestic measurements taken from the published literature, and all four sets of osmotic coefficients are in good agreement; model parameters for K2HPO4(aq) are already available from our earlier work: (PopoviAc et al. in J Solution Chem 40:907-920, 2011). For this ternary system, only one mixing parameter is needed for each of the three models because the ionic strength dependences of the osmotic coefficients of Na2HPO4(aq) and K2HPO4(aq) are very similar, as expected from their very similar chemistry, with the two variants of the extended Pitzer model giving slightly better representations of the experimental results than the Clegg-Pitzer-Brimblecombe model. Maximum differences in calculated values of mean molality-based activity coefficients for these three models are a dagger gamma (+/-)(Na2HPO4) aecurrency sign0.004 and a dagger gamma (+/-)(K2HPO4) aecurrency sign0.008 for ionic strengths I (m) aecurrency sign 2.0 mol center dot kg(-1), with the largest differences occurring for the trace and near-trace activity coefficients of one solute in a solution of the other solute at higher ionic strengths and solutions rich in K2HPO4 at intermediate ionic strengths. These new results complement our earlier investigations of aqueous common-cation mixtures of K2HPO4 with KCl, KBr, KNO3 and K2SO4.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNa(2)HPO(4) + (1-y)K2HPO4}(aq) System at T=298.15 K
EP  - 1287
IS  - 9
SP  - 1261
VL  - 45
DO  - 10.1007/s10953-015-0429-7
ER  - 

@article{
author = "Popović, Daniela and Miladinović, Jelena and Rard, Joseph A. and Miladinović, Zoran P. and Grujić, Snežana",
year = "2016",
abstract = "Isopiestic measurements have been made for aqueous mixtures of Na2HPO4 and K2HPO4 at T = (298.15 +/- 0.01) K, at Na2HPO4 ionic strength fractions y = (0.2023, 0.4060, 0.6027, 0.8007, and 1), using KCl(aq) as the reference standard solution. The resulting 48 molality-based osmotic coefficients for the ternary mixtures were modeled with an extended form of Pitzer's ion-interaction model, with the usual Pitzer mixing terms and also with Scatchard's neutral-electrolyte model mixing terms, along with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. Model parameters for Na2HPO4(aq) at T = 298.15 K were also evaluated using the present isopiestic results (12 values) along with three other sets of osmotic coefficients from isopiestic measurements taken from the published literature, and all four sets of osmotic coefficients are in good agreement; model parameters for K2HPO4(aq) are already available from our earlier work: (PopoviAc et al. in J Solution Chem 40:907-920, 2011). For this ternary system, only one mixing parameter is needed for each of the three models because the ionic strength dependences of the osmotic coefficients of Na2HPO4(aq) and K2HPO4(aq) are very similar, as expected from their very similar chemistry, with the two variants of the extended Pitzer model giving slightly better representations of the experimental results than the Clegg-Pitzer-Brimblecombe model. Maximum differences in calculated values of mean molality-based activity coefficients for these three models are a dagger gamma (+/-)(Na2HPO4) aecurrency sign0.004 and a dagger gamma (+/-)(K2HPO4) aecurrency sign0.008 for ionic strengths I (m) aecurrency sign 2.0 mol center dot kg(-1), with the largest differences occurring for the trace and near-trace activity coefficients of one solute in a solution of the other solute at higher ionic strengths and solutions rich in K2HPO4 at intermediate ionic strengths. These new results complement our earlier investigations of aqueous common-cation mixtures of K2HPO4 with KCl, KBr, KNO3 and K2SO4.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNa(2)HPO(4) + (1-y)K2HPO4}(aq) System at T=298.15 K",
pages = "1287-1261",
number = "9",
volume = "45",
doi = "10.1007/s10953-015-0429-7"
}

Popović, D., Miladinović, J., Rard, J. A., Miladinović, Z. P.,& Grujić, S.. (2016). Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNa(2)HPO(4) + (1-y)K2HPO4}(aq) System at T=298.15 K. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 45(9), 1261-1287.
https://doi.org/10.1007/s10953-015-0429-7

Popović D, Miladinović J, Rard JA, Miladinović ZP, Grujić S. Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNa(2)HPO(4) + (1-y)K2HPO4}(aq) System at T=298.15 K. in Journal of Solution Chemistry. 2016;45(9):1261-1287.
doi:10.1007/s10953-015-0429-7 .

Popović, Daniela, Miladinović, Jelena, Rard, Joseph A., Miladinović, Zoran P., Grujić, Snežana, "Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNa(2)HPO(4) + (1-y)K2HPO4}(aq) System at T=298.15 K" in Journal of Solution Chemistry, 45, no. 9 (2016):1261-1287,
https://doi.org/10.1007/s10953-015-0429-7 . .

TY  - JOUR
AU  - Nikolić, Jelena D.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Stojanović, Jovica
AU  - Grujić, Snežana
AU  - Smiljanić, Sonja
AU  - Topalović, Vladimir S.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3398
AB  - The crystallization and sintering behaviors of polyphosphate glass doped with trace elements Zn and Mn were examined. The heating experiments on bulk and powder glass samples were performed. The parent glass revealed low crystallization ability and the glass crystallization carried out under simultaneous acting of the surface and volume mechanisms. The bulk glass sample isothermally heated at T
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn
EP  - 592
IS  - 2
SP  - 585
VL  - 124
DO  - 10.1007/s10973-015-5184-x
ER  - 

@article{
author = "Nikolić, Jelena D. and Živanović, Vladimir D. and Matijašević, Srđan D. and Stojanović, Jovica and Grujić, Snežana and Smiljanić, Sonja and Topalović, Vladimir S.",
year = "2016",
abstract = "The crystallization and sintering behaviors of polyphosphate glass doped with trace elements Zn and Mn were examined. The heating experiments on bulk and powder glass samples were performed. The parent glass revealed low crystallization ability and the glass crystallization carried out under simultaneous acting of the surface and volume mechanisms. The bulk glass sample isothermally heated at T",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn",
pages = "592-585",
number = "2",
volume = "124",
doi = "10.1007/s10973-015-5184-x"
}

Nikolić, J. D., Živanović, V. D., Matijašević, S. D., Stojanović, J., Grujić, S., Smiljanić, S.,& Topalović, V. S.. (2016). Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 124(2), 585-592.
https://doi.org/10.1007/s10973-015-5184-x

Nikolić JD, Živanović VD, Matijašević SD, Stojanović J, Grujić S, Smiljanić S, Topalović VS. Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn. in Journal of Thermal Analysis and Calorimetry. 2016;124(2):585-592.
doi:10.1007/s10973-015-5184-x .

Nikolić, Jelena D., Živanović, Vladimir D., Matijašević, Srđan D., Stojanović, Jovica, Grujić, Snežana, Smiljanić, Sonja, Topalović, Vladimir S., "Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn" in Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):585-592,
https://doi.org/10.1007/s10973-015-5184-x . .

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
AU  - Topalović, Vladimir S.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3451
AB  - The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Effect of la2o3 on the structure and the properties of strontium borate glasses
EP  - 115
IS  - 1
SP  - 111
VL  - 22
DO  - 10.2298/CICEQ150213031S
ER  - 

@article{
author = "Smiljanić, Sonja and Grujić, Snežana and Tošić, Mihajlo B. and Živanović, Vladimir D. and Matijašević, Srđan D. and Nikolić, Jelena D. and Topalović, Vladimir S.",
year = "2016",
abstract = "The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Effect of la2o3 on the structure and the properties of strontium borate glasses",
pages = "115-111",
number = "1",
volume = "22",
doi = "10.2298/CICEQ150213031S"
}

Smiljanić, S., Grujić, S., Tošić, M. B., Živanović, V. D., Matijašević, S. D., Nikolić, J. D.,& Topalović, V. S.. (2016). Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry & Chemical Engineering Quarterly
Savez hemijskih inženjera, Beograd., 22(1), 111-115.
https://doi.org/10.2298/CICEQ150213031S

Smiljanić S, Grujić S, Tošić MB, Živanović VD, Matijašević SD, Nikolić JD, Topalović VS. Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry & Chemical Engineering Quarterly. 2016;22(1):111-115.
doi:10.2298/CICEQ150213031S .

Smiljanić, Sonja, Grujić, Snežana, Tošić, Mihajlo B., Živanović, Vladimir D., Matijašević, Srđan D., Nikolić, Jelena D., Topalović, Vladimir S., "Effect of la2o3 on the structure and the properties of strontium borate glasses" in Chemical Industry & Chemical Engineering Quarterly, 22, no. 1 (2016):111-115,
https://doi.org/10.2298/CICEQ150213031S . .

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran P.
AU  - Grujić, Snežana
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3055
AB  - Experimental results on isopiestic measurements for three ternary aqueous solutions of K2HPO4 with KCl, KBr, and KNO3 at T = 298.15 K were modeled with the Clegg-Pitzer-Brimblecombe equation based on mole-fraction-composition scale yielding appropriate mixing parameters, for the estimation of thermodynamic activities of solute components. The results for mean ionic activity coefficients of electrolytes in ternary solutions, calculated this way, are showing specific behavior depending on total ionic strength and ionic strength fractions of electrolytes. The activity coefficients of KCl in {yKCl + (1-y)K2HPO4}(aq) and of KBr in {yKBr + (1-y)K2HPO4}(aq) are changing consistently from the ionic strength and their ionic strength fractions contrary to activity coefficients of KNO3 in {yKNO(3) + (1-y)K2HPO4}(aq). In addition, molality of K2HPO4 aqueous saturated solution, in equilibrium with K2HPO4 center dot 3H(2)O(cr), and appropriate osmotic coefficient at T = 298.15 K, were determined by the isopiestic method.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Thermodynamics of mixed and pure aqueous solutions of K2HPO4 at T=298.15 K
EP  - 2345
IS  - 13
SP  - 2339
VL  - 89
DO  - 10.1134/S0036024415130270
ER  - 

@article{
author = "Popović, Daniela and Miladinović, Jelena and Miladinović, Zoran P. and Grujić, Snežana",
year = "2015",
abstract = "Experimental results on isopiestic measurements for three ternary aqueous solutions of K2HPO4 with KCl, KBr, and KNO3 at T = 298.15 K were modeled with the Clegg-Pitzer-Brimblecombe equation based on mole-fraction-composition scale yielding appropriate mixing parameters, for the estimation of thermodynamic activities of solute components. The results for mean ionic activity coefficients of electrolytes in ternary solutions, calculated this way, are showing specific behavior depending on total ionic strength and ionic strength fractions of electrolytes. The activity coefficients of KCl in {yKCl + (1-y)K2HPO4}(aq) and of KBr in {yKBr + (1-y)K2HPO4}(aq) are changing consistently from the ionic strength and their ionic strength fractions contrary to activity coefficients of KNO3 in {yKNO(3) + (1-y)K2HPO4}(aq). In addition, molality of K2HPO4 aqueous saturated solution, in equilibrium with K2HPO4 center dot 3H(2)O(cr), and appropriate osmotic coefficient at T = 298.15 K, were determined by the isopiestic method.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Thermodynamics of mixed and pure aqueous solutions of K2HPO4 at T=298.15 K",
pages = "2345-2339",
number = "13",
volume = "89",
doi = "10.1134/S0036024415130270"
}

Popović, D., Miladinović, J., Miladinović, Z. P.,& Grujić, S.. (2015). Thermodynamics of mixed and pure aqueous solutions of K2HPO4 at T=298.15 K. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 89(13), 2339-2345.
https://doi.org/10.1134/S0036024415130270

Popović D, Miladinović J, Miladinović ZP, Grujić S. Thermodynamics of mixed and pure aqueous solutions of K2HPO4 at T=298.15 K. in Russian Journal of Physical Chemistry A. 2015;89(13):2339-2345.
doi:10.1134/S0036024415130270 .

Popović, Daniela, Miladinović, Jelena, Miladinović, Zoran P., Grujić, Snežana, "Thermodynamics of mixed and pure aqueous solutions of K2HPO4 at T=298.15 K" in Russian Journal of Physical Chemistry A, 89, no. 13 (2015):2339-2345,
https://doi.org/10.1134/S0036024415130270 . .

TY  - JOUR
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Matijašević, Srđan D.
AU  - Stojanović, Jovica
AU  - Nikolić, J. D.
AU  - Smiljanić, Sonja
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3034
AB  - In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass
EP  - 1661
IS  - 3
SP  - 1653
VL  - 119
DO  - 10.1007/s10973-015-4390-x
ER  - 

@article{
author = "Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Matijašević, Srđan D. and Stojanović, Jovica and Nikolić, J. D. and Smiljanić, Sonja",
year = "2015",
abstract = "In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass",
pages = "1661-1653",
number = "3",
volume = "119",
doi = "10.1007/s10973-015-4390-x"
}

Živanović, V. D., Tošić, M. B., Grujić, S., Matijašević, S. D., Stojanović, J., Nikolić, J. D.,& Smiljanić, S.. (2015). DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 119(3), 1653-1661.
https://doi.org/10.1007/s10973-015-4390-x

Živanović VD, Tošić MB, Grujić S, Matijašević SD, Stojanović J, Nikolić JD, Smiljanić S. DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry. 2015;119(3):1653-1661.
doi:10.1007/s10973-015-4390-x .

Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, J. D., Smiljanić, Sonja, "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass" in Journal of Thermal Analysis and Calorimetry, 119, no. 3 (2015):1653-1661,
https://doi.org/10.1007/s10973-015-4390-x . .

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Rard, Joseph A.
AU  - Miladinović, Zoran P.
AU  - Grujić, Snežana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2726
AB  - The molality-based osmotic coefficients of aqueous mixtures of K2SO4 and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method, at K2SO4 ionic strength fractions y = (0.21008, 0.39887, 0.60657, 0.80517, and 1) over the ionic strength range (1.3167 to 1.9587) mol . kg(-1), using KCl(aq) as the reference standard solution. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte solution mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. Model parameters for K2SO4(aq) at T = 298.15 K were also evaluated using the present results along with seven sets of osmotic coefficients taken from the published literature. For the {yK(2)SO(4) + (1 - y) K2HPO4}(aq) system, few or no mixing terms were needed for the three models because the ionic strength dependences of the osmotic coefficients of K2SO4(aq) and K2HPO4(aq) are very similar and their curves nearly parallel, as are those of the mixtures which are intermediate and nearly equally spaced as a function of the ionic strength fraction.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yK(2)SO(4) + (1-y)K2HPO4}(aq) system at T=298.15 K
EP  - 93
SP  - 84
VL  - 79
DO  - 10.1016/j.jct.2014.07.010
ER  - 

@article{
author = "Popović, Daniela and Miladinović, Jelena and Rard, Joseph A. and Miladinović, Zoran P. and Grujić, Snežana",
year = "2014",
abstract = "The molality-based osmotic coefficients of aqueous mixtures of K2SO4 and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method, at K2SO4 ionic strength fractions y = (0.21008, 0.39887, 0.60657, 0.80517, and 1) over the ionic strength range (1.3167 to 1.9587) mol . kg(-1), using KCl(aq) as the reference standard solution. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte solution mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. Model parameters for K2SO4(aq) at T = 298.15 K were also evaluated using the present results along with seven sets of osmotic coefficients taken from the published literature. For the {yK(2)SO(4) + (1 - y) K2HPO4}(aq) system, few or no mixing terms were needed for the three models because the ionic strength dependences of the osmotic coefficients of K2SO4(aq) and K2HPO4(aq) are very similar and their curves nearly parallel, as are those of the mixtures which are intermediate and nearly equally spaced as a function of the ionic strength fraction.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yK(2)SO(4) + (1-y)K2HPO4}(aq) system at T=298.15 K",
pages = "93-84",
volume = "79",
doi = "10.1016/j.jct.2014.07.010"
}

Popović, D., Miladinović, J., Rard, J. A., Miladinović, Z. P.,& Grujić, S.. (2014). Isopiestic determination of the osmotic and activity coefficients of the {yK(2)SO(4) + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 79, 84-93.
https://doi.org/10.1016/j.jct.2014.07.010

Popović D, Miladinović J, Rard JA, Miladinović ZP, Grujić S. Isopiestic determination of the osmotic and activity coefficients of the {yK(2)SO(4) + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2014;79:84-93.
doi:10.1016/j.jct.2014.07.010 .

Popović, Daniela, Miladinović, Jelena, Rard, Joseph A., Miladinović, Zoran P., Grujić, Snežana, "Isopiestic determination of the osmotic and activity coefficients of the {yK(2)SO(4) + (1-y)K2HPO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 79 (2014):84-93,
https://doi.org/10.1016/j.jct.2014.07.010 . .

TY  - JOUR
AU  - Prstić, Aurel
AU  - Acimović-Pavlović, Zagorka
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Grujić, Snežana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2769
AB  - In this study, new refractory coatings based on synthesized cordierite for the casting applications were developed. The investigation included starting raw materials characterization, synthesis of the cordierite, design of the refractory coating as final product, and its application testing. The obtained results pointed out that coating suspension sediment stability was crucial quality parameter. Design and optimization of the coatings composition, with controlled rheological properties included, were achieved by application of different coating components, namely different suspension agents and by alteration of the coating production procedure. Cordierite, used as filler, was obtained by means of synthesis in the solid-state reaction on the basis of talc, kaolin, and alumina. The investigation showed that the application of these particular types of water/alcohol-based coatings has positive influence on surface quality and structural and mechanical properties of the castings of aluminum alloys obtained by casting into sand molds by means of evaporable models method, that is, evaporate pattern casting process.
PB  - Wiley, Hoboken
T2  - International Journal of Applied Ceramic Technology
T1  - Development of New Cordierite-Based Refractory Coatings for Casting Applications
EP  - 331
IS  - 2
SP  - 321
VL  - 11
DO  - 10.1111/ijac.12010
ER  - 

@article{
author = "Prstić, Aurel and Acimović-Pavlović, Zagorka and Terzić, Anja and Pavlović, Ljubica and Grujić, Snežana",
year = "2014",
abstract = "In this study, new refractory coatings based on synthesized cordierite for the casting applications were developed. The investigation included starting raw materials characterization, synthesis of the cordierite, design of the refractory coating as final product, and its application testing. The obtained results pointed out that coating suspension sediment stability was crucial quality parameter. Design and optimization of the coatings composition, with controlled rheological properties included, were achieved by application of different coating components, namely different suspension agents and by alteration of the coating production procedure. Cordierite, used as filler, was obtained by means of synthesis in the solid-state reaction on the basis of talc, kaolin, and alumina. The investigation showed that the application of these particular types of water/alcohol-based coatings has positive influence on surface quality and structural and mechanical properties of the castings of aluminum alloys obtained by casting into sand molds by means of evaporable models method, that is, evaporate pattern casting process.",
publisher = "Wiley, Hoboken",
journal = "International Journal of Applied Ceramic Technology",
title = "Development of New Cordierite-Based Refractory Coatings for Casting Applications",
pages = "331-321",
number = "2",
volume = "11",
doi = "10.1111/ijac.12010"
}

Prstić, A., Acimović-Pavlović, Z., Terzić, A., Pavlović, L.,& Grujić, S.. (2014). Development of New Cordierite-Based Refractory Coatings for Casting Applications. in International Journal of Applied Ceramic Technology
Wiley, Hoboken., 11(2), 321-331.
https://doi.org/10.1111/ijac.12010

Prstić A, Acimović-Pavlović Z, Terzić A, Pavlović L, Grujić S. Development of New Cordierite-Based Refractory Coatings for Casting Applications. in International Journal of Applied Ceramic Technology. 2014;11(2):321-331.
doi:10.1111/ijac.12010 .

Prstić, Aurel, Acimović-Pavlović, Zagorka, Terzić, Anja, Pavlović, Ljubica, Grujić, Snežana, "Development of New Cordierite-Based Refractory Coatings for Casting Applications" in International Journal of Applied Ceramic Technology, 11, no. 2 (2014):321-331,
https://doi.org/10.1111/ijac.12010 . .

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2800
AB  - Glasses with a constant B2O3 and an increasing La2O3 content in the system La2O3-SrO-B2O3 were obtained by the usual melt quenching procedure. The crystallization and sinterability of the glasses were investigated by hot stage microscopy (HSM), differential thermal analysis (DTA), X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). XRD analysis of the bulk samples evidenced the formation of the crystalline phases: La2SrB10O19, SrB6O10 and SrLaBO4. XRD and TEM/SAED analyses showed a polymorphic crystallization of the glass sample containing 14.3 mol% La2O3 with precipitation of the La2SrB10O19 phase. SEM analysis confirmed the surface crystallization mechanism of this sample. The kinetics of crystallization of the same sample was examined by DTA and the activation energy of crystal growth was calculated by the Kissinger model to be E-a=458 +/- 63 kJ mol(-1).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3
EP  - 305
IS  - 1
SP  - 297
VL  - 40
DO  - 10.1016/j.ceramint.2013.06.002
ER  - 

@article{
author = "Smiljanić, Sonja and Grujić, Snežana and Tošić, Mihajlo B. and Živanović, Vladimir D. and Stojanović, Jovica and Matijašević, Srđan D. and Nikolić, Jelena D.",
year = "2014",
abstract = "Glasses with a constant B2O3 and an increasing La2O3 content in the system La2O3-SrO-B2O3 were obtained by the usual melt quenching procedure. The crystallization and sinterability of the glasses were investigated by hot stage microscopy (HSM), differential thermal analysis (DTA), X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). XRD analysis of the bulk samples evidenced the formation of the crystalline phases: La2SrB10O19, SrB6O10 and SrLaBO4. XRD and TEM/SAED analyses showed a polymorphic crystallization of the glass sample containing 14.3 mol% La2O3 with precipitation of the La2SrB10O19 phase. SEM analysis confirmed the surface crystallization mechanism of this sample. The kinetics of crystallization of the same sample was examined by DTA and the activation energy of crystal growth was calculated by the Kissinger model to be E-a=458 +/- 63 kJ mol(-1).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3",
pages = "305-297",
number = "1",
volume = "40",
doi = "10.1016/j.ceramint.2013.06.002"
}

Smiljanić, S., Grujić, S., Tošić, M. B., Živanović, V. D., Stojanović, J., Matijašević, S. D.,& Nikolić, J. D.. (2014). Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3. in Ceramics International
Elsevier Sci Ltd, Oxford., 40(1), 297-305.
https://doi.org/10.1016/j.ceramint.2013.06.002

Smiljanić S, Grujić S, Tošić MB, Živanović VD, Stojanović J, Matijašević SD, Nikolić JD. Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3. in Ceramics International. 2014;40(1):297-305.
doi:10.1016/j.ceramint.2013.06.002 .

Smiljanić, Sonja, Grujić, Snežana, Tošić, Mihajlo B., Živanović, Vladimir D., Stojanović, Jovica, Matijašević, Srđan D., Nikolić, Jelena D., "Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3" in Ceramics International, 40, no. 1 (2014):297-305,
https://doi.org/10.1016/j.ceramint.2013.06.002 . .

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran P.
AU  - Grujić, Snežana
AU  - Todorović, Milica D.
AU  - Rard, Joseph A.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2532
AB  - The molality-based osmotic coefficients of aqueous mixtures of KBr and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method at KBr ionic strength fractions y = (0.18328, 0.38241, 0.58031, 0.79186, and 1) and over the ionic strength range (2.5452 to 10.0418) mol . kg (-1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These experiments were performed using glass sample dishes because preliminary experiments showed that some corrosion of our usual gold-plated silver dishes occurred with dissolution of silver, presumably by "pinhole" corrosion at imperfections in the gold layer. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. The present assessment yields mixing parameters for these models. Model parameters for KBr(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with four sets of osmotic coefficients taken from the published literature. For the {yKBr + (1 -y)K2HPO4}(aq) system, the model with five Scatchard mixing terms gave a significantly better representation of the osmotic coefficients than any of the other models and is therefore recommended for calculation of osmotic and activity coefficients.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K
EP  - 161
SP  - 151
VL  - 62
DO  - 10.1016/j.jct.2013.03.003
ER  - 

@article{
author = "Popović, Daniela and Miladinović, Jelena and Miladinović, Zoran P. and Grujić, Snežana and Todorović, Milica D. and Rard, Joseph A.",
year = "2013",
abstract = "The molality-based osmotic coefficients of aqueous mixtures of KBr and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method at KBr ionic strength fractions y = (0.18328, 0.38241, 0.58031, 0.79186, and 1) and over the ionic strength range (2.5452 to 10.0418) mol . kg (-1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These experiments were performed using glass sample dishes because preliminary experiments showed that some corrosion of our usual gold-plated silver dishes occurred with dissolution of silver, presumably by "pinhole" corrosion at imperfections in the gold layer. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. The present assessment yields mixing parameters for these models. Model parameters for KBr(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with four sets of osmotic coefficients taken from the published literature. For the {yKBr + (1 -y)K2HPO4}(aq) system, the model with five Scatchard mixing terms gave a significantly better representation of the osmotic coefficients than any of the other models and is therefore recommended for calculation of osmotic and activity coefficients.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K",
pages = "161-151",
volume = "62",
doi = "10.1016/j.jct.2013.03.003"
}

Popović, D., Miladinović, J., Miladinović, Z. P., Grujić, S., Todorović, M. D.,& Rard, J. A.. (2013). Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 62, 151-161.
https://doi.org/10.1016/j.jct.2013.03.003

Popović D, Miladinović J, Miladinović ZP, Grujić S, Todorović MD, Rard JA. Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2013;62:151-161.
doi:10.1016/j.jct.2013.03.003 .

Popović, Daniela, Miladinović, Jelena, Miladinović, Zoran P., Grujić, Snežana, Todorović, Milica D., Rard, Joseph A., "Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 62 (2013):151-161,
https://doi.org/10.1016/j.jct.2013.03.003 . .