TY  - JOUR
AU  - Jovanović, Jovan D.
AU  - Milošević, Ivana T.
AU  - Majstorović, Divna M.
AU  - Živković, Nikola V.
AU  - Živković, Emila M.
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5149
AB  - The free volume theory model was used to estimate viscosity of eight pure substances and their twenty-three binary mixtures. The selected viscosity data included compounds such as alcohol, ether, lactam, amine and polymer, measured at atmospheric pressure and in the temperature range (288.15–318.15/323.15/333.15) K depending on the used pure chemical. For pure substances free volume theory is a correlative three-parameter model, while for mixtures different approaches were tested regarding the number of parameters in the proposed extended logarithmic mixing rule, and showed that the optimal one in terms of complexity and yet with good results, also has three parameters to be optimized. The usage of the simplified model, without dilute gas term, was justified by the values of absolute average deviations for both pure component and mixtures. The model was also coupled with different equations of state (Peng-Robinson and Soave-Redlich-Kwong) for calculation of needed density data, in cases when experimental density data are missing. For pure chemicals, values of absolute average deviations are up to 2.3% for tested polymers, and below 0.8% for other classes of chemicals. For binary mixtures overall deviations go to 1% for eleven systems without polymer and to 3.8% for twelve systems with polymer as one compound. Comparison with friction theory is slightly in favor of friction theory for pure compounds, but involves higher number of parameters, while for the mixtures free volume theory showed significantly better results with the same number of optimized parameters. © 2022 Elsevier B.V.
T2  - Journal of Molecular Liquids
T2  - Journal of Molecular Liquids
T1  - Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents
EP  - 119369
VL  - 359
DO  - 10.1016/j.molliq.2022.119369
ER  - 

@article{
author = "Jovanović, Jovan D. and Milošević, Ivana T. and Majstorović, Divna M. and Živković, Nikola V. and Živković, Emila M.",
year = "2022",
abstract = "The free volume theory model was used to estimate viscosity of eight pure substances and their twenty-three binary mixtures. The selected viscosity data included compounds such as alcohol, ether, lactam, amine and polymer, measured at atmospheric pressure and in the temperature range (288.15–318.15/323.15/333.15) K depending on the used pure chemical. For pure substances free volume theory is a correlative three-parameter model, while for mixtures different approaches were tested regarding the number of parameters in the proposed extended logarithmic mixing rule, and showed that the optimal one in terms of complexity and yet with good results, also has three parameters to be optimized. The usage of the simplified model, without dilute gas term, was justified by the values of absolute average deviations for both pure component and mixtures. The model was also coupled with different equations of state (Peng-Robinson and Soave-Redlich-Kwong) for calculation of needed density data, in cases when experimental density data are missing. For pure chemicals, values of absolute average deviations are up to 2.3% for tested polymers, and below 0.8% for other classes of chemicals. For binary mixtures overall deviations go to 1% for eleven systems without polymer and to 3.8% for twelve systems with polymer as one compound. Comparison with friction theory is slightly in favor of friction theory for pure compounds, but involves higher number of parameters, while for the mixtures free volume theory showed significantly better results with the same number of optimized parameters. © 2022 Elsevier B.V.",
journal = "Journal of Molecular Liquids, Journal of Molecular Liquids",
title = "Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents",
pages = "119369",
volume = "359",
doi = "10.1016/j.molliq.2022.119369"
}

Jovanović, J. D., Milošević, I. T., Majstorović, D. M., Živković, N. V.,& Živković, E. M.. (2022). Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents. in Journal of Molecular Liquids, 359.
https://doi.org/10.1016/j.molliq.2022.119369

Jovanović JD, Milošević IT, Majstorović DM, Živković NV, Živković EM. Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents. in Journal of Molecular Liquids. 2022;359:null-119369.
doi:10.1016/j.molliq.2022.119369 .

Jovanović, Jovan D., Milošević, Ivana T., Majstorović, Divna M., Živković, Nikola V., Živković, Emila M., "Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents" in Journal of Molecular Liquids, 359 (2022),
https://doi.org/10.1016/j.molliq.2022.119369 . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Majstorović, Divna
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4531
AB  - Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
EP  - 3062
IS  - 6
SP  - 3044
VL  - 65
DO  - 10.1021/acs.jced.0c00083
ER  - 

@article{
author = "Živković, Nikola V. and Majstorović, Divna and Kijevčanin, Mirjana and Živković, Emila",
year = "2020",
abstract = "Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
pages = "3062-3044",
number = "6",
volume = "65",
doi = "10.1021/acs.jced.0c00083"
}

Živković, N. V., Majstorović, D., Kijevčanin, M.,& Živković, E.. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083

Živković NV, Majstorović D, Kijevčanin M, Živković E. Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical and Engineering Data. 2020;65(6):3044-3062.
doi:10.1021/acs.jced.0c00083 .

Živković, Nikola V., Majstorović, Divna, Kijevčanin, Mirjana, Živković, Emila, "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical and Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 . .

TY  - JOUR
AU  - Živković, Emila
AU  - Živković, Nikola V.
AU  - Majstorović, Divna
AU  - Stanimirović, Andrej M.
AU  - Kijevčanin, Mirjana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3981
AB  - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
EP  - 154
SP  - 135
VL  - 119
DO  - 10.1016/j.jct.2017.12.023
ER  - 

@article{
author = "Živković, Emila and Živković, Nikola V. and Majstorović, Divna and Stanimirović, Andrej M. and Kijevčanin, Mirjana",
year = "2018",
abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes",
pages = "154-135",
volume = "119",
doi = "10.1016/j.jct.2017.12.023"
}

Živković, E., Živković, N. V., Majstorović, D., Stanimirović, A. M.,& Kijevčanin, M.. (2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 119, 135-154.
https://doi.org/10.1016/j.jct.2017.12.023

Živković E, Živković NV, Majstorović D, Stanimirović AM, Kijevčanin M. Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2018;119:135-154.
doi:10.1016/j.jct.2017.12.023 .

Živković, Emila, Živković, Nikola V., Majstorović, Divna, Stanimirović, Andrej M., Kijevčanin, Mirjana, "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 119 (2018):135-154,
https://doi.org/10.1016/j.jct.2017.12.023 . .

TY  - JOUR
AU  - Jovanović, Jovan
AU  - Majstorović, Divna
AU  - Živković, Nikola V.
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3901
AB  - In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n-methyl-2-pyrrolidone and n,n-dimethylaniline, in mixtures with alcohols 1-butanol, 2-butanol or 1-hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 02% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Molecular Liquids
T1  - The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes
EP  - 703
SP  - 696
VL  - 271
DO  - 10.1016/j.molliq.2018.09.043
ER  - 

@article{
author = "Jovanović, Jovan and Majstorović, Divna and Živković, Nikola V. and Kijevčanin, Mirjana and Živković, Emila",
year = "2018",
abstract = "In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n-methyl-2-pyrrolidone and n,n-dimethylaniline, in mixtures with alcohols 1-butanol, 2-butanol or 1-hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 02% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Liquids",
title = "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes",
pages = "703-696",
volume = "271",
doi = "10.1016/j.molliq.2018.09.043"
}

Jovanović, J., Majstorović, D., Živković, N. V., Kijevčanin, M.,& Živković, E.. (2018). The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids
Elsevier Science Bv, Amsterdam., 271, 696-703.
https://doi.org/10.1016/j.molliq.2018.09.043

Jovanović J, Majstorović D, Živković NV, Kijevčanin M, Živković E. The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids. 2018;271:696-703.
doi:10.1016/j.molliq.2018.09.043 .

Jovanović, Jovan, Majstorović, Divna, Živković, Nikola V., Kijevčanin, Mirjana, Živković, Emila, "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes" in Journal of Molecular Liquids, 271 (2018):696-703,
https://doi.org/10.1016/j.molliq.2018.09.043 . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Živković, Emila
AU  - Šerbanović, Slobodan P.
AU  - Majstorović, Divna
AU  - Kijevčanin, Mirjana
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3697
AB  - Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes
EP  - 180
SP  - 162
VL  - 108
DO  - 10.1016/j.jct.2017.01.018
ER  - 

@article{
author = "Živković, Nikola V. and Živković, Emila and Šerbanović, Slobodan P. and Majstorović, Divna and Kijevčanin, Mirjana",
year = "2017",
abstract = "Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes",
pages = "180-162",
volume = "108",
doi = "10.1016/j.jct.2017.01.018"
}

Živković, N. V., Živković, E., Šerbanović, S. P., Majstorović, D.,& Kijevčanin, M.. (2017). Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 108, 162-180.
https://doi.org/10.1016/j.jct.2017.01.018

Živković NV, Živković E, Šerbanović SP, Majstorović D, Kijevčanin M. Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2017;108:162-180.
doi:10.1016/j.jct.2017.01.018 .

Živković, Nikola V., Živković, Emila, Šerbanović, Slobodan P., Majstorović, Divna, Kijevčanin, Mirjana, "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 108 (2017):162-180,
https://doi.org/10.1016/j.jct.2017.01.018 . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Živković, Emila
AU  - Kijevčanin, Mirjana
AU  - Stefanović, Predrag
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2638
AB  - In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.
AB  - Za ublažavanje klimatskih promena, neophodno je izvršiti smanjenje emisija gasova sa efektom staklene bašte među koje spadaju i sumporni oksidi iz stacionarnih termoenergetskih postrojenja. Ublažavanje promena je uslovljeno zakonskim okvirom Evropske Unije. Ispunjenje ove obaveze je i pred Republikom Srbijom u narednim godinama. S obzirom na prioritete i aktuelnost navedene pr blematike, u radu je data kategorizacija mokrih postupaka za uklanjanje sumpornih oksida iz dimnih gasova iz termoelektrana i prikazane su karakteristike odgovarajućih solvenata za regenerativne postupke. Opisan je u praksi najzastupljeniji mokri krečni postupak. Predstavljeni su postupci sa termalnom regeneracijom solventa zasnovani na hemijskoj ili fizičkoj apsorpciji, koji u poslednje vreme imaju sve veći značaj. Prikazani su rezultati eksperimentalnog određivanja termofizičkih svojstva komercijalno primenjenih i alternativnih solvenata, koja su od primarnog značaja za projektovanje opreme i optimizaciju procesa. Izmerene vrednosti gustine i viskoznosti čistih rastvarača, polietilenglikol 200 i 400 (PEG 200 i PEG 400), tetraetilenglikola-dimetil-etar (TEGDME), N-metil-2-pirolidona (NMP) i dimetilanilina (DMA), na atmosferskom pritisku, predstvljene su u funkciji temperature.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination
T1  - Pregled mokrih postupaka za odsumporavanje dimnih gasova i određivanje termofizičkih svojstava njima odgovarajućih rastvarača
EP  - 500
IS  - 4
SP  - 491
VL  - 68
DO  - 10.2298/HEMIND130610074Z
ER  - 

@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Živković, Emila and Kijevčanin, Mirjana and Stefanović, Predrag",
year = "2014",
abstract = "In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature., Za ublažavanje klimatskih promena, neophodno je izvršiti smanjenje emisija gasova sa efektom staklene bašte među koje spadaju i sumporni oksidi iz stacionarnih termoenergetskih postrojenja. Ublažavanje promena je uslovljeno zakonskim okvirom Evropske Unije. Ispunjenje ove obaveze je i pred Republikom Srbijom u narednim godinama. S obzirom na prioritete i aktuelnost navedene pr blematike, u radu je data kategorizacija mokrih postupaka za uklanjanje sumpornih oksida iz dimnih gasova iz termoelektrana i prikazane su karakteristike odgovarajućih solvenata za regenerativne postupke. Opisan je u praksi najzastupljeniji mokri krečni postupak. Predstavljeni su postupci sa termalnom regeneracijom solventa zasnovani na hemijskoj ili fizičkoj apsorpciji, koji u poslednje vreme imaju sve veći značaj. Prikazani su rezultati eksperimentalnog određivanja termofizičkih svojstva komercijalno primenjenih i alternativnih solvenata, koja su od primarnog značaja za projektovanje opreme i optimizaciju procesa. Izmerene vrednosti gustine i viskoznosti čistih rastvarača, polietilenglikol 200 i 400 (PEG 200 i PEG 400), tetraetilenglikola-dimetil-etar (TEGDME), N-metil-2-pirolidona (NMP) i dimetilanilina (DMA), na atmosferskom pritisku, predstvljene su u funkciji temperature.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination, Pregled mokrih postupaka za odsumporavanje dimnih gasova i određivanje termofizičkih svojstava njima odgovarajućih rastvarača",
pages = "500-491",
number = "4",
volume = "68",
doi = "10.2298/HEMIND130610074Z"
}

Živković, N. V., Šerbanović, S. P., Živković, E., Kijevčanin, M.,& Stefanović, P.. (2014). Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija
Association of Chemical Engineers of Serbia., 68(4), 491-500.
https://doi.org/10.2298/HEMIND130610074Z

Živković NV, Šerbanović SP, Živković E, Kijevčanin M, Stefanović P. Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija. 2014;68(4):491-500.
doi:10.2298/HEMIND130610074Z .

Živković, Nikola V., Šerbanović, Slobodan P., Živković, Emila, Kijevčanin, Mirjana, Stefanović, Predrag, "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination" in Hemijska industrija, 68, no. 4 (2014):491-500,
https://doi.org/10.2298/HEMIND130610074Z . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2415
AB  - Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.
PB  - Springer/Plenum Publishers, New York
T2  - International Journal of Thermophysics
T1  - Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME
EP  - 1020
IS  - 6
SP  - 1002
VL  - 34
DO  - 10.1007/s10765-013-1469-0
ER  - 

@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Kijevčanin, Mirjana and Živković, Emila",
year = "2013",
abstract = "Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.",
publisher = "Springer/Plenum Publishers, New York",
journal = "International Journal of Thermophysics",
title = "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME",
pages = "1020-1002",
number = "6",
volume = "34",
doi = "10.1007/s10765-013-1469-0"
}

Živković, N. V., Šerbanović, S. P., Kijevčanin, M.,& Živković, E.. (2013). Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics
Springer/Plenum Publishers, New York., 34(6), 1002-1020.
https://doi.org/10.1007/s10765-013-1469-0

Živković NV, Šerbanović SP, Kijevčanin M, Živković E. Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics. 2013;34(6):1002-1020.
doi:10.1007/s10765-013-1469-0 .

Živković, Nikola V., Šerbanović, Slobodan P., Kijevčanin, Mirjana, Živković, Emila, "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME" in International Journal of Thermophysics, 34, no. 6 (2013):1002-1020,
https://doi.org/10.1007/s10765-013-1469-0 . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2469
AB  - Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone
EP  - 3341
IS  - 12
SP  - 3332
VL  - 58
DO  - 10.1021/je400486p
ER  - 

@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Kijevčanin, Mirjana and Živković, Emila",
year = "2013",
abstract = "Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone",
pages = "3341-3332",
number = "12",
volume = "58",
doi = "10.1021/je400486p"
}

Živković, N. V., Šerbanović, S. P., Kijevčanin, M.,& Živković, E.. (2013). Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 58(12), 3332-3341.
https://doi.org/10.1021/je400486p

Živković NV, Šerbanović SP, Kijevčanin M, Živković E. Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data. 2013;58(12):3332-3341.
doi:10.1021/je400486p .

Živković, Nikola V., Šerbanović, Slobodan P., Kijevčanin, Mirjana, Živković, Emila, "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone" in Journal of Chemical and Engineering Data, 58, no. 12 (2013):3332-3341,
https://doi.org/10.1021/je400486p . .