TY  - JOUR
AU  - Katnić, Đurica
AU  - Porobić, Slavica J.
AU  - Lazarević-Pašti, Tamara
AU  - Kojić, Marija
AU  - Tasić, Tamara
AU  - Marinović-Cincović, Milena
AU  - Živojinović, Dragana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11871
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6802
AB  - The removal of environmental pollutants is significant because of their harmful effects on living organisms. Biochar is favorable as a natural adsorbent of environmental pollutants due to its advantages, such as environmental acceptability and economic profitability. This study evaluated the potential of pyrolyzed plum pomace (PyrPP) as an adsorbent for environmental pollutants: Pb2+ ions, pesticides (chlorpyrifos and malathion), as well as organic pollutants BTEX. In order to ameliorate the adsorption capacity of PyrPP, modification by gamma irradiation was performed. Irradiated plum pomace biochar (IrPyrPP) has been shown to be an effective adsorbent, and the material is also sterilized by irradiation, which makes this material potentially sterile adsorbents of the most environmental pollutants from water. The irradiated biochar showed better adsorption performances for the removal of Pb2+ ions, BTEX, and chlorpyrifos. Maximum adsorption capacity (Qmax) of PyrPP for Pb2+, BTEX, chlorpyrifos, and malathion adsorption was 157.0, 17.6, 0.219, and 1.067 mg g− 1 , while Qmax of IrPyrPP for Pb2+, BTEX, chlorpyrifos and malathion was 271.0, 48.0, 0.428 and 0.593 mg g− 1 , respectively. The results obtained during this research suggest that biomass pyrolysis and modification of this biomass by irradiation is a promising way to produce efficient natural sterile sorbents for wastewater treatment.
T2  - Journal of Water Process Engineering
T1  - Sterilized plum pomace biochar as a low-cost effective sorbent of environmental contaminants
SP  - 104487
VL  - 56
DO  - 10.1016/j.jwpe.2023.104487
ER  - 

@article{
author = "Katnić, Đurica and Porobić, Slavica J. and Lazarević-Pašti, Tamara and Kojić, Marija and Tasić, Tamara and Marinović-Cincović, Milena and Živojinović, Dragana",
year = "2023",
abstract = "The removal of environmental pollutants is significant because of their harmful effects on living organisms. Biochar is favorable as a natural adsorbent of environmental pollutants due to its advantages, such as environmental acceptability and economic profitability. This study evaluated the potential of pyrolyzed plum pomace (PyrPP) as an adsorbent for environmental pollutants: Pb2+ ions, pesticides (chlorpyrifos and malathion), as well as organic pollutants BTEX. In order to ameliorate the adsorption capacity of PyrPP, modification by gamma irradiation was performed. Irradiated plum pomace biochar (IrPyrPP) has been shown to be an effective adsorbent, and the material is also sterilized by irradiation, which makes this material potentially sterile adsorbents of the most environmental pollutants from water. The irradiated biochar showed better adsorption performances for the removal of Pb2+ ions, BTEX, and chlorpyrifos. Maximum adsorption capacity (Qmax) of PyrPP for Pb2+, BTEX, chlorpyrifos, and malathion adsorption was 157.0, 17.6, 0.219, and 1.067 mg g− 1 , while Qmax of IrPyrPP for Pb2+, BTEX, chlorpyrifos and malathion was 271.0, 48.0, 0.428 and 0.593 mg g− 1 , respectively. The results obtained during this research suggest that biomass pyrolysis and modification of this biomass by irradiation is a promising way to produce efficient natural sterile sorbents for wastewater treatment.",
journal = "Journal of Water Process Engineering",
title = "Sterilized plum pomace biochar as a low-cost effective sorbent of environmental contaminants",
pages = "104487",
volume = "56",
doi = "10.1016/j.jwpe.2023.104487"
}

Katnić, Đ., Porobić, S. J., Lazarević-Pašti, T., Kojić, M., Tasić, T., Marinović-Cincović, M.,& Živojinović, D.. (2023). Sterilized plum pomace biochar as a low-cost effective sorbent of environmental contaminants. in Journal of Water Process Engineering, 56, 104487.
https://doi.org/10.1016/j.jwpe.2023.104487

Katnić Đ, Porobić SJ, Lazarević-Pašti T, Kojić M, Tasić T, Marinović-Cincović M, Živojinović D. Sterilized plum pomace biochar as a low-cost effective sorbent of environmental contaminants. in Journal of Water Process Engineering. 2023;56:104487.
doi:10.1016/j.jwpe.2023.104487 .

Katnić, Đurica, Porobić, Slavica J., Lazarević-Pašti, Tamara, Kojić, Marija, Tasić, Tamara, Marinović-Cincović, Milena, Živojinović, Dragana, "Sterilized plum pomace biochar as a low-cost effective sorbent of environmental contaminants" in Journal of Water Process Engineering, 56 (2023):104487,
https://doi.org/10.1016/j.jwpe.2023.104487 . .

TY  - CONF
AU  - Nikolić, Nataša
AU  - Porobić, Slavica
AU  - Tadić, Julijana
AU  - Vujčić, Ivica
AU  - Kojić, Marija
AU  - Lađarević, Jelena
AU  - Mijin, Dušan
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6753
AB  - Polymeric materials are widely used in the chemical and optical industries, the packaging materials industry, and biomedicine. New technologies and the search for innovative and sustainable solutions have contributed to the development of polymer sensors and smart materials. Poly(vinyl-alcohol) (PVA) is a thermoplastic polymer soluble in water. It belongs to the group of non-toxic and completely biodegradable polymers, with excellent thermal and mechanical properties. Polymer-colored films have great potential as sensor systems, primarily due to their visual color change, which makes them easy to use. Azo dyes, which are used for coloring polymer films, represent the most important class of synthetic dyes, and their exceptional properties are reflected in high extinction coefficients, as well as excellent fastness to light and wet processing. Traditionally, azo dyes are used in the food and cosmetic industries, and are also used as pH indicators.
In this work, in addition to the synthesis of azo pyridone dyes, polymeric films were also synthesized. The first series of films were synthesized based on PVA and newly synthesized azo dyes, and the sensory properties of the new films were tested. The second series of films were synthesized in order to test the films as dosimeters for γ-radiation, and for this reason, TTC was added to their synthesis. The dye used in the experiments were characterized by ATR-FTIR, NMR and UV-Vis spectra. The chemical structure of the synthesized films was analyzed by ATR-FTIR spectroscopy. The sensory properties of the film were tested in solutions of different pH values, while the possibility for application in dosimetry was tested at different doses of γ-radiation at the 60Co source. Changes in the color of the films were monitored spectrophotometrically by recording reflection spectra.
PB  - Niš : RAD Centre
C3  - Book of Abstracts / Eleventh International Conference on Radiation, Natural Sciences, Medicine, Engineering, Technology and Ecology (RAD 2023 Conference), June 19-25, Herceg Novi, Montenegro
T1  - Sensory properties of new films based on poly(vinyl-alcohol) and pyridone azo dyes
SP  - 180
DO  - 10.21175/rad.abstr.book.2023.32.10
ER  - 

@conference{
author = "Nikolić, Nataša and Porobić, Slavica and Tadić, Julijana and Vujčić, Ivica and Kojić, Marija and Lađarević, Jelena and Mijin, Dušan",
year = "2023",
abstract = "Polymeric materials are widely used in the chemical and optical industries, the packaging materials industry, and biomedicine. New technologies and the search for innovative and sustainable solutions have contributed to the development of polymer sensors and smart materials. Poly(vinyl-alcohol) (PVA) is a thermoplastic polymer soluble in water. It belongs to the group of non-toxic and completely biodegradable polymers, with excellent thermal and mechanical properties. Polymer-colored films have great potential as sensor systems, primarily due to their visual color change, which makes them easy to use. Azo dyes, which are used for coloring polymer films, represent the most important class of synthetic dyes, and their exceptional properties are reflected in high extinction coefficients, as well as excellent fastness to light and wet processing. Traditionally, azo dyes are used in the food and cosmetic industries, and are also used as pH indicators.
In this work, in addition to the synthesis of azo pyridone dyes, polymeric films were also synthesized. The first series of films were synthesized based on PVA and newly synthesized azo dyes, and the sensory properties of the new films were tested. The second series of films were synthesized in order to test the films as dosimeters for γ-radiation, and for this reason, TTC was added to their synthesis. The dye used in the experiments were characterized by ATR-FTIR, NMR and UV-Vis spectra. The chemical structure of the synthesized films was analyzed by ATR-FTIR spectroscopy. The sensory properties of the film were tested in solutions of different pH values, while the possibility for application in dosimetry was tested at different doses of γ-radiation at the 60Co source. Changes in the color of the films were monitored spectrophotometrically by recording reflection spectra.",
publisher = "Niš : RAD Centre",
journal = "Book of Abstracts / Eleventh International Conference on Radiation, Natural Sciences, Medicine, Engineering, Technology and Ecology (RAD 2023 Conference), June 19-25, Herceg Novi, Montenegro",
title = "Sensory properties of new films based on poly(vinyl-alcohol) and pyridone azo dyes",
pages = "180",
doi = "10.21175/rad.abstr.book.2023.32.10"
}

Nikolić, N., Porobić, S., Tadić, J., Vujčić, I., Kojić, M., Lađarević, J.,& Mijin, D.. (2023). Sensory properties of new films based on poly(vinyl-alcohol) and pyridone azo dyes. in Book of Abstracts / Eleventh International Conference on Radiation, Natural Sciences, Medicine, Engineering, Technology and Ecology (RAD 2023 Conference), June 19-25, Herceg Novi, Montenegro
Niš : RAD Centre., 180.
https://doi.org/10.21175/rad.abstr.book.2023.32.10

Nikolić N, Porobić S, Tadić J, Vujčić I, Kojić M, Lađarević J, Mijin D. Sensory properties of new films based on poly(vinyl-alcohol) and pyridone azo dyes. in Book of Abstracts / Eleventh International Conference on Radiation, Natural Sciences, Medicine, Engineering, Technology and Ecology (RAD 2023 Conference), June 19-25, Herceg Novi, Montenegro. 2023;:180.
doi:10.21175/rad.abstr.book.2023.32.10 .

Nikolić, Nataša, Porobić, Slavica, Tadić, Julijana, Vujčić, Ivica, Kojić, Marija, Lađarević, Jelena, Mijin, Dušan, "Sensory properties of new films based on poly(vinyl-alcohol) and pyridone azo dyes" in Book of Abstracts / Eleventh International Conference on Radiation, Natural Sciences, Medicine, Engineering, Technology and Ecology (RAD 2023 Conference), June 19-25, Herceg Novi, Montenegro (2023):180,
https://doi.org/10.21175/rad.abstr.book.2023.32.10 . .

TY  - JOUR
AU  - Kojić, Marija
AU  - Mihajlović, Marija
AU  - Marinović-Cincović, Milena
AU  - Petrović, Jelena
AU  - Katnić, Đurica
AU  - Krstić, Aleksandar
AU  - Butulija, Svetlana
AU  - Onjia, Antonije
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5142
AB  - A calcium-pyro-hydrochar (Ca-PHC) can be distinguished as a novel sorbent of Pb2+ and Cd2+ from an aqueous solution. It was obtained using hydrothermal treatment of the spent mushroom substrate (SMS), followed by a CaCl2·5H2O activation and pyrolysis. The characterisation of chars before and after modifications was done by scanning electron microscope (SEM), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR). Batch experiments were performed to examine Ca-PHC’s sorption properties and binding mechanisms to selected metal ions. The maximum sorption capacities of Ca-PHC for Pb2+ and Cd2+ were 297 mg g−1, and 131 mg g−1, respectively. The obtained results demonstrated that the sorption of Pb2+ and Cd2+ by Ca-PHC follows a pseudo-second kinetic model and Freundlich isotherm. The binding of the selected metals onto Ca-PHC was enabled by the ion-exchange mechanism, surface complexation, mineral precipitation and cation–π interaction. Thermodynamic parameters indicate that metal ions binding by Ca-PHC are spontaneous and endothermic. Due to the high adsorption capacities, the obtained Ca-PHC has good potential for application in industrial wastewater treatment. In addition, the demonstrated use of SMS highlights another possibility of applying this specific biomass relevant to sustainable and economical waste management in the growing mushroom industry.
PB  - SAGE Publications Ltd
T2  - Waste Management and Research
T1  - Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions
DO  - 10.1177/0734242X221093951
ER  - 

@article{
author = "Kojić, Marija and Mihajlović, Marija and Marinović-Cincović, Milena and Petrović, Jelena and Katnić, Đurica and Krstić, Aleksandar and Butulija, Svetlana and Onjia, Antonije",
year = "2022",
abstract = "A calcium-pyro-hydrochar (Ca-PHC) can be distinguished as a novel sorbent of Pb2+ and Cd2+ from an aqueous solution. It was obtained using hydrothermal treatment of the spent mushroom substrate (SMS), followed by a CaCl2·5H2O activation and pyrolysis. The characterisation of chars before and after modifications was done by scanning electron microscope (SEM), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR). Batch experiments were performed to examine Ca-PHC’s sorption properties and binding mechanisms to selected metal ions. The maximum sorption capacities of Ca-PHC for Pb2+ and Cd2+ were 297 mg g−1, and 131 mg g−1, respectively. The obtained results demonstrated that the sorption of Pb2+ and Cd2+ by Ca-PHC follows a pseudo-second kinetic model and Freundlich isotherm. The binding of the selected metals onto Ca-PHC was enabled by the ion-exchange mechanism, surface complexation, mineral precipitation and cation–π interaction. Thermodynamic parameters indicate that metal ions binding by Ca-PHC are spontaneous and endothermic. Due to the high adsorption capacities, the obtained Ca-PHC has good potential for application in industrial wastewater treatment. In addition, the demonstrated use of SMS highlights another possibility of applying this specific biomass relevant to sustainable and economical waste management in the growing mushroom industry.",
publisher = "SAGE Publications Ltd",
journal = "Waste Management and Research",
title = "Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions",
doi = "10.1177/0734242X221093951"
}

Kojić, M., Mihajlović, M., Marinović-Cincović, M., Petrović, J., Katnić, Đ., Krstić, A., Butulija, S.,& Onjia, A.. (2022). Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions. in Waste Management and Research
SAGE Publications Ltd..
https://doi.org/10.1177/0734242X221093951

Kojić M, Mihajlović M, Marinović-Cincović M, Petrović J, Katnić Đ, Krstić A, Butulija S, Onjia A. Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions. in Waste Management and Research. 2022;.
doi:10.1177/0734242X221093951 .

Kojić, Marija, Mihajlović, Marija, Marinović-Cincović, Milena, Petrović, Jelena, Katnić, Đurica, Krstić, Aleksandar, Butulija, Svetlana, Onjia, Antonije, "Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions" in Waste Management and Research (2022),
https://doi.org/10.1177/0734242X221093951 . .