TY  - JOUR
AU  - Molina, Ricardo
AU  - Teixidó, Josep Maria
AU  - Kan, Chi-Wai
AU  - Jovančić, Petar
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5823
AB  - Plasma polymerization using hydrophobic monomers in the gas phase is a well-known technology to generate hydrophobic coatings. However, synthesis of functional hydrophobic coatings using plasma technology in liquids has not yet been accomplished. This work is consequently focused on polymerization of a liquid fluorinated monomer on cotton fabric initiated by atmospheric plasma in a dielectric barrier discharge configuration. Functional hydrophobic coatings on cotton were successfully achieved using in situ atmospheric plasma-initiated polymerization of fluorinated monomer dissolved in ethanol. Gravimetric measurements reveal that the amount of polymer deposited on cotton substrates can be modulated with the concentration of monomer in ethanol solution, and cross-linking reactions occur during plasma polymerization of a fluorinated monomer even without the presence of a cross-linking agent. FTIR and XPS analysis were used to study the chemical composition of hydrophobic coatings and to get insights into the physicochemical processes involved in plasma treatment. SEM analysis reveals that at high monomer concentration, coatings possess a three-dimensional pattern with a characteristic interconnected porous network structure. EDX analysis reveals that plasma polymerization of fluorinated monomers takes place preferentially at the surface of cotton fabric and negligible polymerization takes place inside the cotton fabric. Wetting time measurements confirm the hydrophobicity of cotton coatings obtained although equilibrium moisture content was slightly decreased. Additionally, the abrasion behavior and resistance to washing of plasma-coated cotton has been evaluated.
PB  - American Chemical Society
T2  - ACS Applied Materials and Interfaces
T1  - Hydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutions
EP  - 5521
IS  - 6
SP  - 5513
VL  - 9
DO  - 10.1021/acsami.6b15812
ER  - 

@article{
author = "Molina, Ricardo and Teixidó, Josep Maria and Kan, Chi-Wai and Jovančić, Petar",
year = "2017",
abstract = "Plasma polymerization using hydrophobic monomers in the gas phase is a well-known technology to generate hydrophobic coatings. However, synthesis of functional hydrophobic coatings using plasma technology in liquids has not yet been accomplished. This work is consequently focused on polymerization of a liquid fluorinated monomer on cotton fabric initiated by atmospheric plasma in a dielectric barrier discharge configuration. Functional hydrophobic coatings on cotton were successfully achieved using in situ atmospheric plasma-initiated polymerization of fluorinated monomer dissolved in ethanol. Gravimetric measurements reveal that the amount of polymer deposited on cotton substrates can be modulated with the concentration of monomer in ethanol solution, and cross-linking reactions occur during plasma polymerization of a fluorinated monomer even without the presence of a cross-linking agent. FTIR and XPS analysis were used to study the chemical composition of hydrophobic coatings and to get insights into the physicochemical processes involved in plasma treatment. SEM analysis reveals that at high monomer concentration, coatings possess a three-dimensional pattern with a characteristic interconnected porous network structure. EDX analysis reveals that plasma polymerization of fluorinated monomers takes place preferentially at the surface of cotton fabric and negligible polymerization takes place inside the cotton fabric. Wetting time measurements confirm the hydrophobicity of cotton coatings obtained although equilibrium moisture content was slightly decreased. Additionally, the abrasion behavior and resistance to washing of plasma-coated cotton has been evaluated.",
publisher = "American Chemical Society",
journal = "ACS Applied Materials and Interfaces",
title = "Hydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutions",
pages = "5521-5513",
number = "6",
volume = "9",
doi = "10.1021/acsami.6b15812"
}

Molina, R., Teixidó, J. M., Kan, C.,& Jovančić, P.. (2017). Hydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutions. in ACS Applied Materials and Interfaces
American Chemical Society., 9(6), 5513-5521.
https://doi.org/10.1021/acsami.6b15812

Molina R, Teixidó JM, Kan C, Jovančić P. Hydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutions. in ACS Applied Materials and Interfaces. 2017;9(6):5513-5521.
doi:10.1021/acsami.6b15812 .

Molina, Ricardo, Teixidó, Josep Maria, Kan, Chi-Wai, Jovančić, Petar, "Hydrophobic Coatings on Cotton Obtained by in Situ Plasma Polymerization of a Fluorinated Monomer in Ethanol Solutions" in ACS Applied Materials and Interfaces, 9, no. 6 (2017):5513-5521,
https://doi.org/10.1021/acsami.6b15812 . .

TY  - CONF
AU  - Mihailović, Darka
AU  - Radetić, Maja
AU  - Radoičić, Marija
AU  - Molina, Ricardo
AU  - Puač, Nevena
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Šaponjic, Zoran
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6501
AB  - This study was aimed to examine the possibility of using RF plasma at low pressure for the surface activation of polyester fabrics in order to improve the binding efficiency of colloidal TiO2 nanoparticles. Colloidal TiO2 nanoparticles were synthesized without stabilizers by acid hydrolysis method. Air and argon were used as plasma gases. Polyester fabrics modified by RF plasma and TiO2 nanoparticles exhibited excellent antibacterial efficiency against E. coli which was preserved after five washing cycles. The presence of TiO2 nanoparticles contributed to a significant increase in UV protection factor (UPF) of fabrics. These values correspond to UPF rating of 50+, which designates the maximum UV protection. Additionally, irradiated polyester fabrics loaded with TiO2 nanoparticles demonstrated satisfactory self-cleaning efficiency.
PB  - Department of Materials, Textiles and Chemical Engineering
C3  - Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium
T1  - Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles
EP  - 218
SP  - 213
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6501
ER  - 

@conference{
author = "Mihailović, Darka and Radetić, Maja and Radoičić, Marija and Molina, Ricardo and Puač, Nevena and Jovančić, Petar and Nedeljković, Jovan and Šaponjic, Zoran",
year = "2009",
abstract = "This study was aimed to examine the possibility of using RF plasma at low pressure for the surface activation of polyester fabrics in order to improve the binding efficiency of colloidal TiO2 nanoparticles. Colloidal TiO2 nanoparticles were synthesized without stabilizers by acid hydrolysis method. Air and argon were used as plasma gases. Polyester fabrics modified by RF plasma and TiO2 nanoparticles exhibited excellent antibacterial efficiency against E. coli which was preserved after five washing cycles. The presence of TiO2 nanoparticles contributed to a significant increase in UV protection factor (UPF) of fabrics. These values correspond to UPF rating of 50+, which designates the maximum UV protection. Additionally, irradiated polyester fabrics loaded with TiO2 nanoparticles demonstrated satisfactory self-cleaning efficiency.",
publisher = "Department of Materials, Textiles and Chemical Engineering",
journal = "Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium",
title = "Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles",
pages = "218-213",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6501"
}

Mihailović, D., Radetić, M., Radoičić, M., Molina, R., Puač, N., Jovančić, P., Nedeljković, J.,& Šaponjic, Z.. (2009). Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium
Department of Materials, Textiles and Chemical Engineering., 213-218.
https://hdl.handle.net/21.15107/rcub_technorep_6501

Mihailović D, Radetić M, Radoičić M, Molina R, Puač N, Jovančić P, Nedeljković J, Šaponjic Z. Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium. 2009;:213-218.
https://hdl.handle.net/21.15107/rcub_technorep_6501 .

Mihailović, Darka, Radetić, Maja, Radoičić, Marija, Molina, Ricardo, Puač, Nevena, Jovančić, Petar, Nedeljković, Jovan, Šaponjic, Zoran, "Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles" in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium (2009):213-218,
https://hdl.handle.net/21.15107/rcub_technorep_6501 .

TY  - CONF
AU  - Ilić, Vesna
AU  - Šaponjic, Zoran
AU  - Mihailović, Darka
AU  - Molina, Ricardo
AU  - Jovančić, Petar
AU  - Nedeljković
AU  - Bokorov, Miloš
AU  - Radetić, Maja
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6521
PB  - Srpsko hemijsko društvo
C3  - 47. Savetovanje Srpskog Hemijskog Društva, Beograd, 21. 03. 2009.
T1  - Ispitivanje morfologije i hemijske strukture PA i PES vlakana modifikovanih korona pražnjenjem na atmosferskom pritisku
EP  - 229
SP  - 226
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6521
ER  - 

@conference{
author = "Ilić, Vesna and Šaponjic, Zoran and Mihailović, Darka and Molina, Ricardo and Jovančić, Petar and Nedeljković and Bokorov, Miloš and Radetić, Maja",
year = "2009",
publisher = "Srpsko hemijsko društvo",
journal = "47. Savetovanje Srpskog Hemijskog Društva, Beograd, 21. 03. 2009.",
title = "Ispitivanje morfologije i hemijske strukture PA i PES vlakana modifikovanih korona pražnjenjem na atmosferskom pritisku",
pages = "229-226",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6521"
}

Ilić, V., Šaponjic, Z., Mihailović, D., Molina, R., Jovančić, P., Nedeljković, Bokorov, M.,& Radetić, M.. (2009). Ispitivanje morfologije i hemijske strukture PA i PES vlakana modifikovanih korona pražnjenjem na atmosferskom pritisku. in 47. Savetovanje Srpskog Hemijskog Društva, Beograd, 21. 03. 2009.
Srpsko hemijsko društvo., 226-229.
https://hdl.handle.net/21.15107/rcub_technorep_6521

Ilić V, Šaponjic Z, Mihailović D, Molina R, Jovančić P, Nedeljković, Bokorov M, Radetić M. Ispitivanje morfologije i hemijske strukture PA i PES vlakana modifikovanih korona pražnjenjem na atmosferskom pritisku. in 47. Savetovanje Srpskog Hemijskog Društva, Beograd, 21. 03. 2009.. 2009;:226-229.
https://hdl.handle.net/21.15107/rcub_technorep_6521 .

Ilić, Vesna, Šaponjic, Zoran, Mihailović, Darka, Molina, Ricardo, Jovančić, Petar, Nedeljković, Bokorov, Miloš, Radetić, Maja, "Ispitivanje morfologije i hemijske strukture PA i PES vlakana modifikovanih korona pražnjenjem na atmosferskom pritisku" in 47. Savetovanje Srpskog Hemijskog Društva, Beograd, 21. 03. 2009. (2009):226-229,
https://hdl.handle.net/21.15107/rcub_technorep_6521 .

TY  - CONF
AU  - Šaponjic, Zoran
AU  - Ilić, Vesna
AU  - Vodnik, Vesna
AU  - Molina, Ricardo
AU  - Mihailović, Darka
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6514
AB  - The possibility of using a corona treatment for fibre surface activation, which can facilitate the loading of colloidal Ag nanoparticles onto the polyester fabrics and thus enhance their antimicrobial activity, was studied. Antimicrobial efficiency and its laundering durability of polyester fabrics loaded with Ag nanoparticles against Gram-negative bacterium Escherichia coli, Gram-positive bacterium Staphylococcus aureus and fungus Candida albicans were examined. The deposition of colloidal Ag nanoparticles onto corona pretreated polyester fabrics provides excellent antimicrobial activity and satisfactory laundering durability of obtained effects.
C3  - Proc. 2nd Aachen-Dresden International Textile Conference, 4-5 December, 2008, Dresden, Germany
T1  - The Antimicrobial Efficiency of Corona Pretreated Polyester Fabrics Loaded with Silver Nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6514
ER  - 

@conference{
author = "Šaponjic, Zoran and Ilić, Vesna and Vodnik, Vesna and Molina, Ricardo and Mihailović, Darka and Jovančić, Petar and Nedeljković, Jovan and Radetić, Maja",
year = "2008",
abstract = "The possibility of using a corona treatment for fibre surface activation, which can facilitate the loading of colloidal Ag nanoparticles onto the polyester fabrics and thus enhance their antimicrobial activity, was studied. Antimicrobial efficiency and its laundering durability of polyester fabrics loaded with Ag nanoparticles against Gram-negative bacterium Escherichia coli, Gram-positive bacterium Staphylococcus aureus and fungus Candida albicans were examined. The deposition of colloidal Ag nanoparticles onto corona pretreated polyester fabrics provides excellent antimicrobial activity and satisfactory laundering durability of obtained effects.",
journal = "Proc. 2nd Aachen-Dresden International Textile Conference, 4-5 December, 2008, Dresden, Germany",
title = "The Antimicrobial Efficiency of Corona Pretreated Polyester Fabrics Loaded with Silver Nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6514"
}

Šaponjic, Z., Ilić, V., Vodnik, V., Molina, R., Mihailović, D., Jovančić, P., Nedeljković, J.,& Radetić, M.. (2008). The Antimicrobial Efficiency of Corona Pretreated Polyester Fabrics Loaded with Silver Nanoparticles. in Proc. 2nd Aachen-Dresden International Textile Conference, 4-5 December, 2008, Dresden, Germany.
https://hdl.handle.net/21.15107/rcub_technorep_6514

Šaponjic Z, Ilić V, Vodnik V, Molina R, Mihailović D, Jovančić P, Nedeljković J, Radetić M. The Antimicrobial Efficiency of Corona Pretreated Polyester Fabrics Loaded with Silver Nanoparticles. in Proc. 2nd Aachen-Dresden International Textile Conference, 4-5 December, 2008, Dresden, Germany. 2008;.
https://hdl.handle.net/21.15107/rcub_technorep_6514 .

Šaponjic, Zoran, Ilić, Vesna, Vodnik, Vesna, Molina, Ricardo, Mihailović, Darka, Jovančić, Petar, Nedeljković, Jovan, Radetić, Maja, "The Antimicrobial Efficiency of Corona Pretreated Polyester Fabrics Loaded with Silver Nanoparticles" in Proc. 2nd Aachen-Dresden International Textile Conference, 4-5 December, 2008, Dresden, Germany (2008),
https://hdl.handle.net/21.15107/rcub_technorep_6514 .