TY  - JOUR
AU  - Kojić, Marija
AU  - Mihajlović, Marija
AU  - Marinović-Cincović, Milena
AU  - Petrović, Jelena
AU  - Katnić, Đurica
AU  - Krstić, Aleksandar
AU  - Butulija, Svetlana
AU  - Onjia, Antonije
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5142
AB  - A calcium-pyro-hydrochar (Ca-PHC) can be distinguished as a novel sorbent of Pb2+ and Cd2+ from an aqueous solution. It was obtained using hydrothermal treatment of the spent mushroom substrate (SMS), followed by a CaCl2·5H2O activation and pyrolysis. The characterisation of chars before and after modifications was done by scanning electron microscope (SEM), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR). Batch experiments were performed to examine Ca-PHC’s sorption properties and binding mechanisms to selected metal ions. The maximum sorption capacities of Ca-PHC for Pb2+ and Cd2+ were 297 mg g−1, and 131 mg g−1, respectively. The obtained results demonstrated that the sorption of Pb2+ and Cd2+ by Ca-PHC follows a pseudo-second kinetic model and Freundlich isotherm. The binding of the selected metals onto Ca-PHC was enabled by the ion-exchange mechanism, surface complexation, mineral precipitation and cation–π interaction. Thermodynamic parameters indicate that metal ions binding by Ca-PHC are spontaneous and endothermic. Due to the high adsorption capacities, the obtained Ca-PHC has good potential for application in industrial wastewater treatment. In addition, the demonstrated use of SMS highlights another possibility of applying this specific biomass relevant to sustainable and economical waste management in the growing mushroom industry.
PB  - SAGE Publications Ltd
T2  - Waste Management and Research
T1  - Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions
DO  - 10.1177/0734242X221093951
ER  - 

@article{
author = "Kojić, Marija and Mihajlović, Marija and Marinović-Cincović, Milena and Petrović, Jelena and Katnić, Đurica and Krstić, Aleksandar and Butulija, Svetlana and Onjia, Antonije",
year = "2022",
abstract = "A calcium-pyro-hydrochar (Ca-PHC) can be distinguished as a novel sorbent of Pb2+ and Cd2+ from an aqueous solution. It was obtained using hydrothermal treatment of the spent mushroom substrate (SMS), followed by a CaCl2·5H2O activation and pyrolysis. The characterisation of chars before and after modifications was done by scanning electron microscope (SEM), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR). Batch experiments were performed to examine Ca-PHC’s sorption properties and binding mechanisms to selected metal ions. The maximum sorption capacities of Ca-PHC for Pb2+ and Cd2+ were 297 mg g−1, and 131 mg g−1, respectively. The obtained results demonstrated that the sorption of Pb2+ and Cd2+ by Ca-PHC follows a pseudo-second kinetic model and Freundlich isotherm. The binding of the selected metals onto Ca-PHC was enabled by the ion-exchange mechanism, surface complexation, mineral precipitation and cation–π interaction. Thermodynamic parameters indicate that metal ions binding by Ca-PHC are spontaneous and endothermic. Due to the high adsorption capacities, the obtained Ca-PHC has good potential for application in industrial wastewater treatment. In addition, the demonstrated use of SMS highlights another possibility of applying this specific biomass relevant to sustainable and economical waste management in the growing mushroom industry.",
publisher = "SAGE Publications Ltd",
journal = "Waste Management and Research",
title = "Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions",
doi = "10.1177/0734242X221093951"
}

Kojić, M., Mihajlović, M., Marinović-Cincović, M., Petrović, J., Katnić, Đ., Krstić, A., Butulija, S.,& Onjia, A.. (2022). Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions. in Waste Management and Research
SAGE Publications Ltd..
https://doi.org/10.1177/0734242X221093951

Kojić M, Mihajlović M, Marinović-Cincović M, Petrović J, Katnić Đ, Krstić A, Butulija S, Onjia A. Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions. in Waste Management and Research. 2022;.
doi:10.1177/0734242X221093951 .

Kojić, Marija, Mihajlović, Marija, Marinović-Cincović, Milena, Petrović, Jelena, Katnić, Đurica, Krstić, Aleksandar, Butulija, Svetlana, Onjia, Antonije, "Calcium-pyro-hydrochar derived from the spent mushroom substrate as a functional sorbent of Pb2+ and Cd2+ from aqueous solutions" in Waste Management and Research (2022),
https://doi.org/10.1177/0734242X221093951 . .

TY  - JOUR
AU  - Porobić, Slavica
AU  - Krstić, Aleksandar D.
AU  - Jovanović, Dragana J.
AU  - Lađarević, Jelena
AU  - Katnić, Đurica B.
AU  - Mijin, Dušan
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4072
AB  - Thermal degradation properties of 5-(4-substitutedphenylazo)-3-amido-6-hydroxy-4-methy1-2-pyridones and 5-(4-substitutedphenylazo)-3-cyano-6-hydroxy-4-methy1-2-pyridones dyes, differing in electron withdrawing and electron donating substitttents in para-position of diazo components were examined. The structure of the synthesized compourtds has been confirmed by H-1 NMR,C-13 NMR, FITR, UV-Vis and XRD analysis techniques. The results obtained with thermogravimetric analysis (TGA) - derivative thermogravimetry (DTG) and differential thermal analysis (DTA) were combined with GC-mass spectral fragmentation to obtain thermal decomposition mechanism. Non-isothermal kinetics were monitored by application of TGA-DTG-DTA. For Kinetic behavior of the investigated dyes during their degradation in an inert atmosphere, Kissinger, Ozawa, Flynn-Wall-Ozawa (FWO) and Kissinger-Alcahira-Sunose (KAS) isoconversional (model-free) methods were applied. It was found that different thermal stabilities of investigated dyes are the consequence of their different chemical structures, including diverse substituents.
PB  - Elsevier Sci Ltd, Oxford
T2  - Dyes and Pigments
T1  - Synthesis and thermal properties of arylazo pyridone dyes
VL  - 170
DO  - 10.1016/j.dyepig.2019.107602
ER  - 

@article{
author = "Porobić, Slavica and Krstić, Aleksandar D. and Jovanović, Dragana J. and Lađarević, Jelena and Katnić, Đurica B. and Mijin, Dušan and Marinović-Cincović, Milena",
year = "2019",
abstract = "Thermal degradation properties of 5-(4-substitutedphenylazo)-3-amido-6-hydroxy-4-methy1-2-pyridones and 5-(4-substitutedphenylazo)-3-cyano-6-hydroxy-4-methy1-2-pyridones dyes, differing in electron withdrawing and electron donating substitttents in para-position of diazo components were examined. The structure of the synthesized compourtds has been confirmed by H-1 NMR,C-13 NMR, FITR, UV-Vis and XRD analysis techniques. The results obtained with thermogravimetric analysis (TGA) - derivative thermogravimetry (DTG) and differential thermal analysis (DTA) were combined with GC-mass spectral fragmentation to obtain thermal decomposition mechanism. Non-isothermal kinetics were monitored by application of TGA-DTG-DTA. For Kinetic behavior of the investigated dyes during their degradation in an inert atmosphere, Kissinger, Ozawa, Flynn-Wall-Ozawa (FWO) and Kissinger-Alcahira-Sunose (KAS) isoconversional (model-free) methods were applied. It was found that different thermal stabilities of investigated dyes are the consequence of their different chemical structures, including diverse substituents.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Dyes and Pigments",
title = "Synthesis and thermal properties of arylazo pyridone dyes",
volume = "170",
doi = "10.1016/j.dyepig.2019.107602"
}

Porobić, S., Krstić, A. D., Jovanović, D. J., Lađarević, J., Katnić, Đ. B., Mijin, D.,& Marinović-Cincović, M.. (2019). Synthesis and thermal properties of arylazo pyridone dyes. in Dyes and Pigments
Elsevier Sci Ltd, Oxford., 170.
https://doi.org/10.1016/j.dyepig.2019.107602

Porobić S, Krstić AD, Jovanović DJ, Lađarević J, Katnić ĐB, Mijin D, Marinović-Cincović M. Synthesis and thermal properties of arylazo pyridone dyes. in Dyes and Pigments. 2019;170.
doi:10.1016/j.dyepig.2019.107602 .

Porobić, Slavica, Krstić, Aleksandar D., Jovanović, Dragana J., Lađarević, Jelena, Katnić, Đurica B., Mijin, Dušan, Marinović-Cincović, Milena, "Synthesis and thermal properties of arylazo pyridone dyes" in Dyes and Pigments, 170 (2019),
https://doi.org/10.1016/j.dyepig.2019.107602 . .