Ćirković, Milorad

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  • Ćirković, Milorad (2)
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Author's Bibliography

Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia

Ćirković, Milorad; Kamberović, Željko; Bugarin, Mile

(Association of Metallurgical Engineers of Serbia, 2016)

TY  - JOUR
AU  - Ćirković, Milorad
AU  - Kamberović, Željko
AU  - Bugarin, Mile
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3188
AB  - This work presents the laboratory testing results of kinetics the oxidation process and sample processing of the sulphide polymetallic concentrate Blagojev Kamen. The aim of investigation is recovery of these types of raw material, present in large quantities in the peripheral parts of already used primary mineral deposits of copper, because of their high economic potential due to the content of a large number of metals and especially precious metals. Characterization of this raw material is based on the chemical analyses, XRD results, DTA analysis, etc. For these investigations, the sulphide concentrate with the following content was used in %: Cu - 2.3; Fe - 19.8; S - 27.19; Zn - 9.13; As - 0.167; Pb - 15.63; SiO2 - 17.93; CaO - 0.97; Al2O3 - 1.43; Ag - 480 g/t; Au - 659 g/t. Kinetic investigations of oxidation processes were carried out under the isothermal conditions within the temperature range of 400 to 625 oC. The Sharp’s model was used for determination the kinetics parameters, and determined values of activation energy are 67 kJ/mole for the first period, and 47 kJ/mole for the second period. Pyrometallurgical treatment of this type of polymetallic concentrate, in the laboratory conditions, was carried out using the oxidative roasting and, then the reduction smelting was done in the Taman’s furnace. Gold from 90.5 to 97.95% and silver from 77.28 to 93.37% are moved into the raw lead (smelting product). Gold from 1.1 to 3.92% and silver from 4.35 to 8.42% are moved into the polymetallic copper matte. Gold from 0.58 to 1.6% and silver from 2.45 to 6.82% are moved into the slag.
PB  - Association of Metallurgical Engineers of Serbia
T2  - Metallurgical & Materials Engineering
T1  - Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia
EP  - 127
IS  - 2
SP  - 117
VL  - 22
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3188
ER  - 
@article{
author = "Ćirković, Milorad and Kamberović, Željko and Bugarin, Mile",
year = "2016",
abstract = "This work presents the laboratory testing results of kinetics the oxidation process and sample processing of the sulphide polymetallic concentrate Blagojev Kamen. The aim of investigation is recovery of these types of raw material, present in large quantities in the peripheral parts of already used primary mineral deposits of copper, because of their high economic potential due to the content of a large number of metals and especially precious metals. Characterization of this raw material is based on the chemical analyses, XRD results, DTA analysis, etc. For these investigations, the sulphide concentrate with the following content was used in %: Cu - 2.3; Fe - 19.8; S - 27.19; Zn - 9.13; As - 0.167; Pb - 15.63; SiO2 - 17.93; CaO - 0.97; Al2O3 - 1.43; Ag - 480 g/t; Au - 659 g/t. Kinetic investigations of oxidation processes were carried out under the isothermal conditions within the temperature range of 400 to 625 oC. The Sharp’s model was used for determination the kinetics parameters, and determined values of activation energy are 67 kJ/mole for the first period, and 47 kJ/mole for the second period. Pyrometallurgical treatment of this type of polymetallic concentrate, in the laboratory conditions, was carried out using the oxidative roasting and, then the reduction smelting was done in the Taman’s furnace. Gold from 90.5 to 97.95% and silver from 77.28 to 93.37% are moved into the raw lead (smelting product). Gold from 1.1 to 3.92% and silver from 4.35 to 8.42% are moved into the polymetallic copper matte. Gold from 0.58 to 1.6% and silver from 2.45 to 6.82% are moved into the slag.",
publisher = "Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering",
title = "Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia",
pages = "127-117",
number = "2",
volume = "22",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3188"
}
Ćirković, M., Kamberović, Ž.,& Bugarin, M.. (2016). Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia. in Metallurgical & Materials Engineering
Association of Metallurgical Engineers of Serbia., 22(2), 117-127.
https://hdl.handle.net/21.15107/rcub_technorep_3188
Ćirković M, Kamberović Ž, Bugarin M. Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia. in Metallurgical & Materials Engineering. 2016;22(2):117-127.
https://hdl.handle.net/21.15107/rcub_technorep_3188 .
Ćirković, Milorad, Kamberović, Željko, Bugarin, Mile, "Laboratory testing results of kinetics and processing technology of the polymetallic sulphide concentrate Blagojev Kamen - Serbia" in Metallurgical & Materials Engineering, 22, no. 2 (2016):117-127,
https://hdl.handle.net/21.15107/rcub_technorep_3188 .
1

Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor

Ivšić-Bajčeta, Dragana; Kamberović, Željko; Rogan, Jelena; Ćirković, Milorad; Pavlović, Toplica

(Association of Metallurgical Engineers of Serbia, 2013)

TY  - JOUR
AU  - Ivšić-Bajčeta, Dragana
AU  - Kamberović, Željko
AU  - Rogan, Jelena
AU  - Ćirković, Milorad
AU  - Pavlović, Toplica
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2325
AB  - The previous inadequate treatment of off-gas in RTB Bor in Serbia has resulted in serious pollution of the environment and the possibly high losses of copper through the effluent flows. The project of New Copper Smelter RTB Bor, besides the new flash smelting furnace (FSF) and the reconstruction of Pierce-Smith converter (PSC), includes more effective effluent treatment. Paper presents an analysis of the new FSF and PSC off-gas treatment, determination of copper losses throughout generated wastewaters and discussion of its possible valorization. Assumptions about the solubility of metals phases present in the FSF and PSC off-gas, obtained by the treatment process simulation, were compared with the leaching results of flue dusts. Determined wastewaters characteristics indicate that the PSC flow is significantly richer in copper, mostly present in insoluble metallic/sulfide form, while the FSF flow has low concentration of copper in the form of completely soluble oxide/sulfate. The possible scenario for the copper valorization, considering arsenic and lead as limiting factors, is the separation of the FSF and PSC flows, return of the metallic/sulfide solid phase to the smelting process and recovery from the sulfate/oxide liquid phase.
PB  - Association of Metallurgical Engineers of Serbia
T2  - Metallurgical & Materials Engineering
T1  - Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor
EP  - 231
IS  - 3
SP  - 217
VL  - 19
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2325
ER  - 
@article{
author = "Ivšić-Bajčeta, Dragana and Kamberović, Željko and Rogan, Jelena and Ćirković, Milorad and Pavlović, Toplica",
year = "2013",
abstract = "The previous inadequate treatment of off-gas in RTB Bor in Serbia has resulted in serious pollution of the environment and the possibly high losses of copper through the effluent flows. The project of New Copper Smelter RTB Bor, besides the new flash smelting furnace (FSF) and the reconstruction of Pierce-Smith converter (PSC), includes more effective effluent treatment. Paper presents an analysis of the new FSF and PSC off-gas treatment, determination of copper losses throughout generated wastewaters and discussion of its possible valorization. Assumptions about the solubility of metals phases present in the FSF and PSC off-gas, obtained by the treatment process simulation, were compared with the leaching results of flue dusts. Determined wastewaters characteristics indicate that the PSC flow is significantly richer in copper, mostly present in insoluble metallic/sulfide form, while the FSF flow has low concentration of copper in the form of completely soluble oxide/sulfate. The possible scenario for the copper valorization, considering arsenic and lead as limiting factors, is the separation of the FSF and PSC flows, return of the metallic/sulfide solid phase to the smelting process and recovery from the sulfate/oxide liquid phase.",
publisher = "Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering",
title = "Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor",
pages = "231-217",
number = "3",
volume = "19",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2325"
}
Ivšić-Bajčeta, D., Kamberović, Ž., Rogan, J., Ćirković, M.,& Pavlović, T.. (2013). Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor. in Metallurgical & Materials Engineering
Association of Metallurgical Engineers of Serbia., 19(3), 217-231.
https://hdl.handle.net/21.15107/rcub_technorep_2325
Ivšić-Bajčeta D, Kamberović Ž, Rogan J, Ćirković M, Pavlović T. Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor. in Metallurgical & Materials Engineering. 2013;19(3):217-231.
https://hdl.handle.net/21.15107/rcub_technorep_2325 .
Ivšić-Bajčeta, Dragana, Kamberović, Željko, Rogan, Jelena, Ćirković, Milorad, Pavlović, Toplica, "Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the new copper smelter RTB Bor" in Metallurgical & Materials Engineering, 19, no. 3 (2013):217-231,
https://hdl.handle.net/21.15107/rcub_technorep_2325 .