TY  - JOUR
AU  - Vossmeyer, Tobias
AU  - Katsikas, Lynne
AU  - Giersig, M.
AU  - Popović, Ivanka
AU  - Diesner, K.
AU  - Chemseddine, A.
AU  - Eychmüller, A.
AU  - Weller, Horst
PY  - 1994
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/56
AB  - Improved synthetic routes and size-selective precipitation have enabled the preparation of almost monodisperse CdS clusters. Six samples of 1-thioglycerol stabilized clusters with diameters of approximately 13, 14, 16, 19, 23, and 39 Å have been prepared as fully redispersible powders and were characterized by elemental analysis, powder X-ray diffraction, electron microscopy, thermogravimetric analysis, and UV-vis spectroscopy. Small-angle X-ray scattering was used to determine the mean cluster size. The well-structured UV-vis spectra reveal that the size-dependent shift of the 1s-1s excitonic transition is in agreement with the tight-binding theory and the pseudopotential theory. Moreover, as expected by quantum mechanical calculations the oscillator strength of the transition increases proportional to 1/r3. UV-vis spectra taken at various temperatures between 4 and 295 K have shown that the temperature shift of the excitonic transition energy becomes stronger with decreasing particle size. Strong, reversible absorbance shifts were observed, upon transferring the clusters from their solutions onto quartz plates and vice versa.
T2  - Journal of Physical Chemistry
T1  - CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift
EP  - 7673
IS  - 31
SP  - 7665
VL  - 98
DO  - 10.1021/j100082a044
ER  - 

@article{
author = "Vossmeyer, Tobias and Katsikas, Lynne and Giersig, M. and Popović, Ivanka and Diesner, K. and Chemseddine, A. and Eychmüller, A. and Weller, Horst",
year = "1994",
abstract = "Improved synthetic routes and size-selective precipitation have enabled the preparation of almost monodisperse CdS clusters. Six samples of 1-thioglycerol stabilized clusters with diameters of approximately 13, 14, 16, 19, 23, and 39 Å have been prepared as fully redispersible powders and were characterized by elemental analysis, powder X-ray diffraction, electron microscopy, thermogravimetric analysis, and UV-vis spectroscopy. Small-angle X-ray scattering was used to determine the mean cluster size. The well-structured UV-vis spectra reveal that the size-dependent shift of the 1s-1s excitonic transition is in agreement with the tight-binding theory and the pseudopotential theory. Moreover, as expected by quantum mechanical calculations the oscillator strength of the transition increases proportional to 1/r3. UV-vis spectra taken at various temperatures between 4 and 295 K have shown that the temperature shift of the excitonic transition energy becomes stronger with decreasing particle size. Strong, reversible absorbance shifts were observed, upon transferring the clusters from their solutions onto quartz plates and vice versa.",
journal = "Journal of Physical Chemistry",
title = "CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift",
pages = "7673-7665",
number = "31",
volume = "98",
doi = "10.1021/j100082a044"
}

Vossmeyer, T., Katsikas, L., Giersig, M., Popović, I., Diesner, K., Chemseddine, A., Eychmüller, A.,& Weller, H.. (1994). CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift. in Journal of Physical Chemistry, 98(31), 7665-7673.
https://doi.org/10.1021/j100082a044

Vossmeyer T, Katsikas L, Giersig M, Popović I, Diesner K, Chemseddine A, Eychmüller A, Weller H. CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift. in Journal of Physical Chemistry. 1994;98(31):7665-7673.
doi:10.1021/j100082a044 .

Vossmeyer, Tobias, Katsikas, Lynne, Giersig, M., Popović, Ivanka, Diesner, K., Chemseddine, A., Eychmüller, A., Weller, Horst, "CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift" in Journal of Physical Chemistry, 98, no. 31 (1994):7665-7673,
https://doi.org/10.1021/j100082a044 . .