Panić, Vladimir

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Authority KeyName Variants
orcid::0000-0002-8358-7956
  • Panić, Vladimir (24)
  • Panić, V. (3)
Projects

Author's Bibliography

Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers

Mijailović, Daniel; Vukčević, Marija; Stević, Zoran; Kalijadis, Ana; Stojanović, Dušica; Panić, Vladimir; Uskoković, Petar

(Electrochemical Soc Inc, Pennington, 2017)

TY  - JOUR
AU  - Mijailović, Daniel
AU  - Vukčević, Marija
AU  - Stević, Zoran
AU  - Kalijadis, Ana
AU  - Stojanović, Dušica
AU  - Panić, Vladimir
AU  - Uskoković, Petar
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3720
AB  - Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons.
PB  - Electrochemical Soc Inc, Pennington
T2  - Journal of the Electrochemical Society
T1  - Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers
EP  - A1068
IS  - 6
SP  - A1061
VL  - 164
DO  - 10.1149/2.0581706jes
ER  - 
@article{
author = "Mijailović, Daniel and Vukčević, Marija and Stević, Zoran and Kalijadis, Ana and Stojanović, Dušica and Panić, Vladimir and Uskoković, Petar",
year = "2017",
abstract = "Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons.",
publisher = "Electrochemical Soc Inc, Pennington",
journal = "Journal of the Electrochemical Society",
title = "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers",
pages = "A1068-A1061",
number = "6",
volume = "164",
doi = "10.1149/2.0581706jes"
}
Mijailović, D., Vukčević, M., Stević, Z., Kalijadis, A., Stojanović, D., Panić, V.,& Uskoković, P.. (2017). Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society
Electrochemical Soc Inc, Pennington., 164(6), A1061-A1068.
https://doi.org/10.1149/2.0581706jes
Mijailović D, Vukčević M, Stević Z, Kalijadis A, Stojanović D, Panić V, Uskoković P. Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society. 2017;164(6):A1061-A1068.
doi:10.1149/2.0581706jes .
Mijailović, Daniel, Vukčević, Marija, Stević, Zoran, Kalijadis, Ana, Stojanović, Dušica, Panić, Vladimir, Uskoković, Petar, "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers" in Journal of the Electrochemical Society, 164, no. 6 (2017):A1061-A1068,
https://doi.org/10.1149/2.0581706jes . .
11
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High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis

Šekularac, Gavrilo; Košević, Milica; Dekanski, Aleksandar; Đokić, Veljko; Panjan, Matjaz; Panić, Vladimir

(Wiley-VCH Verlag Gmbh, Weinheim, 2017)

TY  - JOUR
AU  - Šekularac, Gavrilo
AU  - Košević, Milica
AU  - Dekanski, Aleksandar
AU  - Đokić, Veljko
AU  - Panjan, Matjaz
AU  - Panić, Vladimir
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3629
AB  - A simple one-step microwave-assisted and temperature-controlled hydrothermal synthesis was applied to prepare a nanocrystalline RuO2 dispersion from an aqueous solution of RuCl3 for supercapacitive applications. The obtained RuO2 dispersions were subjected to dynamic light scattering in order to analyze the particle size distribution, whereas morphology and structural properties of the solid phase were investigated by using AFM, SEM, EDX, TEM, and XRD techniques. Ellipsoidally shaped 100-500 nm-sized compact grains, joined into highly ordered prismatic agglomerates, are observed. Two types of grains are observed: more regular ones consisting of spherical, amorphous particles of a few nanometers in size, and irregular ones made of partially crystalline 10-80 nm-sized particles. Consequently, the most dominant structure is 250-nm grains. The particles tend to join tightly across their crystalline domains, which appears responsible for the formation of prismatic shapes of several micrometers. This arraying causes high capacitive activity - specific capacitances of up to 800 Fg(-1) are registered, which negligibly depend on the charging/discharging rate. The synthesized material is of highly accessible internal structure, and is an excellent candidate for both low- and high-power applications.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Chemelectrochem
T1  - High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis
EP  - 2541
IS  - 10
SP  - 2535
VL  - 4
DO  - 10.1002/celc.201700609
ER  - 
@article{
author = "Šekularac, Gavrilo and Košević, Milica and Dekanski, Aleksandar and Đokić, Veljko and Panjan, Matjaz and Panić, Vladimir",
year = "2017",
abstract = "A simple one-step microwave-assisted and temperature-controlled hydrothermal synthesis was applied to prepare a nanocrystalline RuO2 dispersion from an aqueous solution of RuCl3 for supercapacitive applications. The obtained RuO2 dispersions were subjected to dynamic light scattering in order to analyze the particle size distribution, whereas morphology and structural properties of the solid phase were investigated by using AFM, SEM, EDX, TEM, and XRD techniques. Ellipsoidally shaped 100-500 nm-sized compact grains, joined into highly ordered prismatic agglomerates, are observed. Two types of grains are observed: more regular ones consisting of spherical, amorphous particles of a few nanometers in size, and irregular ones made of partially crystalline 10-80 nm-sized particles. Consequently, the most dominant structure is 250-nm grains. The particles tend to join tightly across their crystalline domains, which appears responsible for the formation of prismatic shapes of several micrometers. This arraying causes high capacitive activity - specific capacitances of up to 800 Fg(-1) are registered, which negligibly depend on the charging/discharging rate. The synthesized material is of highly accessible internal structure, and is an excellent candidate for both low- and high-power applications.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Chemelectrochem",
title = "High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis",
pages = "2541-2535",
number = "10",
volume = "4",
doi = "10.1002/celc.201700609"
}
Šekularac, G., Košević, M., Dekanski, A., Đokić, V., Panjan, M.,& Panić, V.. (2017). High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis. in Chemelectrochem
Wiley-VCH Verlag Gmbh, Weinheim., 4(10), 2535-2541.
https://doi.org/10.1002/celc.201700609
Šekularac G, Košević M, Dekanski A, Đokić V, Panjan M, Panić V. High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis. in Chemelectrochem. 2017;4(10):2535-2541.
doi:10.1002/celc.201700609 .
Šekularac, Gavrilo, Košević, Milica, Dekanski, Aleksandar, Đokić, Veljko, Panjan, Matjaz, Panić, Vladimir, "High Energy/Power Supercapacitor Performances of Intrinsically Ordered Ruthenium Oxide Prepared through Fast Hydrothermal Synthesis" in Chemelectrochem, 4, no. 10 (2017):2535-2541,
https://doi.org/10.1002/celc.201700609 . .
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Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications

Šekularac, Gavrilo; Eraković, Sanja; Mijin, Dušan; Pavelkić, Vesna; Stevanović, Jasmina; Panić, Vladimir

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Šekularac, Gavrilo
AU  - Eraković, Sanja
AU  - Mijin, Dušan
AU  - Pavelkić, Vesna
AU  - Stevanović, Jasmina
AU  - Panić, Vladimir
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3586
AB  - For the preparation of RuO2 coatings on Ti substrate, the RuO2 was synthesized in acidic aqueous medium by simple one-step low temperature-controlled microwave (MW) irradiation. The physical composition of synthesized solid phase was analysed through particle size distribution (PSD), whereas the coating was investigated for its capacitive response and activity in oxygen evolution reaction (OER). The oxide phase was found highly polydisperse, with overlapped fractions within rather narrow particle size range and clear tendency toward agglomeration. The smallest particles and their best resolved fractions were synthesized at the temperature just above the boiling point of the reaction medium, and quite below the chloride-to-oxide conversion temperature. Consequently, the highest OER activity was registered for RuO2/Ti anodes prepared from this sample, with strong indication of different oxide structure, with respect to the electrodes prepared from samples synthesized at higher temperatures. However, the coatings from high temperature samples have considerably higher capacitance than those synthesized at lower temperatures. These findings can be rather correlated to the MW temperature-dependent oxide structure than to different morphology analysed through PSD.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications
EP  - 709
IS  - 6
SP  - 695
VL  - 82
DO  - 10.2298/JSC161229040S
ER  - 
@article{
author = "Šekularac, Gavrilo and Eraković, Sanja and Mijin, Dušan and Pavelkić, Vesna and Stevanović, Jasmina and Panić, Vladimir",
year = "2017",
abstract = "For the preparation of RuO2 coatings on Ti substrate, the RuO2 was synthesized in acidic aqueous medium by simple one-step low temperature-controlled microwave (MW) irradiation. The physical composition of synthesized solid phase was analysed through particle size distribution (PSD), whereas the coating was investigated for its capacitive response and activity in oxygen evolution reaction (OER). The oxide phase was found highly polydisperse, with overlapped fractions within rather narrow particle size range and clear tendency toward agglomeration. The smallest particles and their best resolved fractions were synthesized at the temperature just above the boiling point of the reaction medium, and quite below the chloride-to-oxide conversion temperature. Consequently, the highest OER activity was registered for RuO2/Ti anodes prepared from this sample, with strong indication of different oxide structure, with respect to the electrodes prepared from samples synthesized at higher temperatures. However, the coatings from high temperature samples have considerably higher capacitance than those synthesized at lower temperatures. These findings can be rather correlated to the MW temperature-dependent oxide structure than to different morphology analysed through PSD.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications",
pages = "709-695",
number = "6",
volume = "82",
doi = "10.2298/JSC161229040S"
}
Šekularac, G., Eraković, S., Mijin, D., Pavelkić, V., Stevanović, J.,& Panić, V.. (2017). Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(6), 695-709.
https://doi.org/10.2298/JSC161229040S
Šekularac G, Eraković S, Mijin D, Pavelkić V, Stevanović J, Panić V. Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications. in Journal of the Serbian Chemical Society. 2017;82(6):695-709.
doi:10.2298/JSC161229040S .
Šekularac, Gavrilo, Eraković, Sanja, Mijin, Dušan, Pavelkić, Vesna, Stevanović, Jasmina, Panić, Vladimir, "Low-temperature-synthesized RuO2 from acidic chloride solution for the electrode coating applications" in Journal of the Serbian Chemical Society, 82, no. 6 (2017):695-709,
https://doi.org/10.2298/JSC161229040S . .
1
1
2

Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent

Košević, Milica; Panić, Vladimir; Bajat, Jelena; Mišković-Stanković, Vesna

(Engineering Society for Corrosion, Belgrade, Serbia, 2016)

TY  - JOUR
AU  - Košević, Milica
AU  - Panić, Vladimir
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3210
AB  - Electrochemical impedance characteristics of bare Al and Al with CeO2 coating prepared sol-gel procedure from the ceria sol are investigated. The corrosion behavior is monitored during the exposure to 3 wt. % NaCl aqueous solution. Experimental data are fitted to various equivalent electrical circuits with special attention to inductive features. Equivalent electrical circuits involving inductivity represent impedance response equally well as the ones without inductivity, although the parameter values gained from the former correspond better to the proposed model of physicochemical changes during corrosion of investigated samples.
AB  - Korozione karakteristike aluminijuma i aluminijuma na koji je naneta prevlaka oksida cerijuma sol-gel postupkom ispitivane su primenom spektroskopije elektrohemijske impedancije tokom izlaganja u vodenom rastvoru 3 mas. % NaCl. Dobijeni podaci analizirani su ekvivalentnim električnim kolima različite konfiguracije uz posebnu diskusiju koja se odnosi na pojavu induktivnog ponašanja. Ekvivalentna kola sa induktivnim elementom i bez njega podjednako dobro opisuju impedansne odgovore, mada vrednosti parametara kola u kojima je uključena induktivnost više odgovaraju predloženom modelu fizičko-hemijskih promena tokom procesa korozije ispitivanih sistema.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent
T1  - Impedansni odgovor aluminijuma sa zaštitnom prevlakom oksida cerijuma tokom izlaganja hloridnoj korozionoj sredini
EP  - 313
IS  - 2
SP  - 305
VL  - 57
DO  - 10.5937/ZasMat1602305k
ER  - 
@article{
author = "Košević, Milica and Panić, Vladimir and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2016",
abstract = "Electrochemical impedance characteristics of bare Al and Al with CeO2 coating prepared sol-gel procedure from the ceria sol are investigated. The corrosion behavior is monitored during the exposure to 3 wt. % NaCl aqueous solution. Experimental data are fitted to various equivalent electrical circuits with special attention to inductive features. Equivalent electrical circuits involving inductivity represent impedance response equally well as the ones without inductivity, although the parameter values gained from the former correspond better to the proposed model of physicochemical changes during corrosion of investigated samples., Korozione karakteristike aluminijuma i aluminijuma na koji je naneta prevlaka oksida cerijuma sol-gel postupkom ispitivane su primenom spektroskopije elektrohemijske impedancije tokom izlaganja u vodenom rastvoru 3 mas. % NaCl. Dobijeni podaci analizirani su ekvivalentnim električnim kolima različite konfiguracije uz posebnu diskusiju koja se odnosi na pojavu induktivnog ponašanja. Ekvivalentna kola sa induktivnim elementom i bez njega podjednako dobro opisuju impedansne odgovore, mada vrednosti parametara kola u kojima je uključena induktivnost više odgovaraju predloženom modelu fizičko-hemijskih promena tokom procesa korozije ispitivanih sistema.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent, Impedansni odgovor aluminijuma sa zaštitnom prevlakom oksida cerijuma tokom izlaganja hloridnoj korozionoj sredini",
pages = "313-305",
number = "2",
volume = "57",
doi = "10.5937/ZasMat1602305k"
}
Košević, M., Panić, V., Bajat, J.,& Mišković-Stanković, V.. (2016). Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 57(2), 305-313.
https://doi.org/10.5937/ZasMat1602305k
Košević M, Panić V, Bajat J, Mišković-Stanković V. Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent. in Zaštita materijala. 2016;57(2):305-313.
doi:10.5937/ZasMat1602305k .
Košević, Milica, Panić, Vladimir, Bajat, Jelena, Mišković-Stanković, Vesna, "Impedance characteristics of aluminum with sol-gel ceria protective coating during the exposure to chloride corrosion agent" in Zaštita materijala, 57, no. 2 (2016):305-313,
https://doi.org/10.5937/ZasMat1602305k . .

Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium

Gulicovski, Jelena; Bajat, Jelena; Jokić, Bojan; Panić, V.; Mišković-Stanković, Vesna; Milonjić, Slobodan K.

(Springer, New York, 2016)

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Bajat, Jelena
AU  - Jokić, Bojan
AU  - Panić, V.
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3375
AB  - Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.
PB  - Springer, New York
T2  - Journal of Solid State Electrochemistry
T1  - Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium
EP  - 303
IS  - 1
SP  - 293
VL  - 20
DO  - 10.1007/s10008-015-3040-3
ER  - 
@article{
author = "Gulicovski, Jelena and Bajat, Jelena and Jokić, Bojan and Panić, V. and Mišković-Stanković, Vesna and Milonjić, Slobodan K.",
year = "2016",
abstract = "Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.",
publisher = "Springer, New York",
journal = "Journal of Solid State Electrochemistry",
title = "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium",
pages = "303-293",
number = "1",
volume = "20",
doi = "10.1007/s10008-015-3040-3"
}
Gulicovski, J., Bajat, J., Jokić, B., Panić, V., Mišković-Stanković, V.,& Milonjić, S. K.. (2016). Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry
Springer, New York., 20(1), 293-303.
https://doi.org/10.1007/s10008-015-3040-3
Gulicovski J, Bajat J, Jokić B, Panić V, Mišković-Stanković V, Milonjić SK. Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry. 2016;20(1):293-303.
doi:10.1007/s10008-015-3040-3 .
Gulicovski, Jelena, Bajat, Jelena, Jokić, Bojan, Panić, V., Mišković-Stanković, Vesna, Milonjić, Slobodan K., "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium" in Journal of Solid State Electrochemistry, 20, no. 1 (2016):293-303,
https://doi.org/10.1007/s10008-015-3040-3 . .
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6

Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor

Šekularac, Gavrilo; Dekanski, Aleksandar; Pavelkić, Vesna; Stevanović, Sanja; Košević, Milica; Drmanić, Saša; Kostić, Ivana; Panić, Vladimir

(Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria, 2015)

TY  - CONF
AU  - Šekularac, Gavrilo
AU  - Dekanski, Aleksandar
AU  - Pavelkić, Vesna
AU  - Stevanović, Sanja
AU  - Košević, Milica
AU  - Drmanić, Saša
AU  - Kostić, Ivana
AU  - Panić, Vladimir
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2881
AB  - One-step simple temperature-controlled microwave synthesis was applied to prepare nanocrystalline RuO2 dispersion from aqueous RuCl3. RuO2 dispersion was subjected to dynamic light scattering in order to analyze the synthesized particles, whereas structural and morphological properties of the solid phase are investigated by AFM, SEM, EDAX and XRD techniques. The ordered unusual shape of ca. 100-nm native particles, as well as highlyordered prismatic agglomerate sheets are observed. Capacitive properties of RuO2 was investigated by cyclic   voltammetry and electrochemical impedance spectroscopy in 1 M H2SO4 and standard three-electrode cell, with ink-type working electrode on glassy carbon substrate A specific capacitances as high as 750 F/g were obtained, which negligibly depend on sweep rate in 5–500 mV/s range. These findings are quite unusual for this kind of material consisted of rather large particles, and makes it excellent candidate for both low and high power applications. The capacitive response appears stable during prolonged charge/discharge cycling.
PB  - Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria
C3  - 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
T1  - Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor
EP  - 93
SP  - 93
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2881
ER  - 
@conference{
author = "Šekularac, Gavrilo and Dekanski, Aleksandar and Pavelkić, Vesna and Stevanović, Sanja and Košević, Milica and Drmanić, Saša and Kostić, Ivana and Panić, Vladimir",
year = "2015",
abstract = "One-step simple temperature-controlled microwave synthesis was applied to prepare nanocrystalline RuO2 dispersion from aqueous RuCl3. RuO2 dispersion was subjected to dynamic light scattering in order to analyze the synthesized particles, whereas structural and morphological properties of the solid phase are investigated by AFM, SEM, EDAX and XRD techniques. The ordered unusual shape of ca. 100-nm native particles, as well as highlyordered prismatic agglomerate sheets are observed. Capacitive properties of RuO2 was investigated by cyclic   voltammetry and electrochemical impedance spectroscopy in 1 M H2SO4 and standard three-electrode cell, with ink-type working electrode on glassy carbon substrate A specific capacitances as high as 750 F/g were obtained, which negligibly depend on sweep rate in 5–500 mV/s range. These findings are quite unusual for this kind of material consisted of rather large particles, and makes it excellent candidate for both low and high power applications. The capacitive response appears stable during prolonged charge/discharge cycling.",
publisher = "Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria",
journal = "5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts",
title = "Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor",
pages = "93-93",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2881"
}
Šekularac, G., Dekanski, A., Pavelkić, V., Stevanović, S., Košević, M., Drmanić, S., Kostić, I.,& Panić, V.. (2015). Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor. in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria., 93-93.
https://hdl.handle.net/21.15107/rcub_technorep_2881
Šekularac G, Dekanski A, Pavelkić V, Stevanović S, Košević M, Drmanić S, Kostić I, Panić V. Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor. in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts. 2015;:93-93.
https://hdl.handle.net/21.15107/rcub_technorep_2881 .
Šekularac, Gavrilo, Dekanski, Aleksandar, Pavelkić, Vesna, Stevanović, Sanja, Košević, Milica, Drmanić, Saša, Kostić, Ivana, Panić, Vladimir, "Microwave Synthesis of Unusually-Shaped Crystalline RuO2 Supercapacitor" in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts (2015):93-93,
https://hdl.handle.net/21.15107/rcub_technorep_2881 .

Cerium oxide as conversion coating for the corrosion protection of aluminum

Gulicovski, Jelena; Bajat, Jelena; Mišković-Stanković, Vesna; Jokić, Bojan; Panić, Vladimir; Milonjić, Slobodan K.

(International Association of Physical Chemists (IAPC), 2013)

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Jokić, Bojan
AU  - Panić, Vladimir
AU  - Milonjić, Slobodan K.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2282
AB  - CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, pre­viously prepared by forced hydrolysis of Ce(NO3)4. The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coa­tings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are sub­jected to more pronounced diffusion limitations in com­parison to the processes below passive aluminum oxide film, as the consequence of the formation of highly com­pact protective coating. The results show that the deposi­tion of ceria coatings is an effective way to improve corro­sion resistance for aluminum.
PB  - International Association of Physical Chemists (IAPC)
T2  - Journal of Electrochemical Science and Engineering
T1  - Cerium oxide as conversion coating for the corrosion protection of aluminum
EP  - 156
IS  - 4
SP  - 151
VL  - 3
DO  - 10.5599/jese.2013.0037
ER  - 
@article{
author = "Gulicovski, Jelena and Bajat, Jelena and Mišković-Stanković, Vesna and Jokić, Bojan and Panić, Vladimir and Milonjić, Slobodan K.",
year = "2013",
abstract = "CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, pre­viously prepared by forced hydrolysis of Ce(NO3)4. The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coa­tings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are sub­jected to more pronounced diffusion limitations in com­parison to the processes below passive aluminum oxide film, as the consequence of the formation of highly com­pact protective coating. The results show that the deposi­tion of ceria coatings is an effective way to improve corro­sion resistance for aluminum.",
publisher = "International Association of Physical Chemists (IAPC)",
journal = "Journal of Electrochemical Science and Engineering",
title = "Cerium oxide as conversion coating for the corrosion protection of aluminum",
pages = "156-151",
number = "4",
volume = "3",
doi = "10.5599/jese.2013.0037"
}
Gulicovski, J., Bajat, J., Mišković-Stanković, V., Jokić, B., Panić, V.,& Milonjić, S. K.. (2013). Cerium oxide as conversion coating for the corrosion protection of aluminum. in Journal of Electrochemical Science and Engineering
International Association of Physical Chemists (IAPC)., 3(4), 151-156.
https://doi.org/10.5599/jese.2013.0037
Gulicovski J, Bajat J, Mišković-Stanković V, Jokić B, Panić V, Milonjić SK. Cerium oxide as conversion coating for the corrosion protection of aluminum. in Journal of Electrochemical Science and Engineering. 2013;3(4):151-156.
doi:10.5599/jese.2013.0037 .
Gulicovski, Jelena, Bajat, Jelena, Mišković-Stanković, Vesna, Jokić, Bojan, Panić, Vladimir, Milonjić, Slobodan K., "Cerium oxide as conversion coating for the corrosion protection of aluminum" in Journal of Electrochemical Science and Engineering, 3, no. 4 (2013):151-156,
https://doi.org/10.5599/jese.2013.0037 . .
4

Cerium oxide as conversion coating for the corrosion protection of aluminum

Gulicovski, Jelena; Bajat, Jelena; Mišković-Stanković, Vesna; Jokić, Bojan; Panić, Vladimir; Milonjić, Slobodan K.

(Modtech Publishing House, Iasi, 2012)

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Jokić, Bojan
AU  - Panić, Vladimir
AU  - Milonjić, Slobodan K.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2163
AB  - CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, previously prepared by forced hydrolysis of Ce(NO3)(4). The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coatings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are subjected to more pronounced diffusion limitations in comparison to the processes below passive aluminum oxide film, as the consequence of the formation of highly compact protective coating. The results show that the deposition of ceria coatings is an effective way to improve corrosion resistance for aluminum.
PB  - Modtech Publishing House, Iasi
T2  - Modtech 2012: New Face of T M C R, Vols I and II
T1  - Cerium oxide as conversion coating for the corrosion protection of aluminum
EP  - 432
SP  - 429
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7011
ER  - 
@article{
author = "Gulicovski, Jelena and Bajat, Jelena and Mišković-Stanković, Vesna and Jokić, Bojan and Panić, Vladimir and Milonjić, Slobodan K.",
year = "2012",
abstract = "CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, previously prepared by forced hydrolysis of Ce(NO3)(4). The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coatings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are subjected to more pronounced diffusion limitations in comparison to the processes below passive aluminum oxide film, as the consequence of the formation of highly compact protective coating. The results show that the deposition of ceria coatings is an effective way to improve corrosion resistance for aluminum.",
publisher = "Modtech Publishing House, Iasi",
journal = "Modtech 2012: New Face of T M C R, Vols I and II",
title = "Cerium oxide as conversion coating for the corrosion protection of aluminum",
pages = "432-429",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7011"
}
Gulicovski, J., Bajat, J., Mišković-Stanković, V., Jokić, B., Panić, V.,& Milonjić, S. K.. (2012). Cerium oxide as conversion coating for the corrosion protection of aluminum. in Modtech 2012: New Face of T M C R, Vols I and II
Modtech Publishing House, Iasi., 429-432.
https://hdl.handle.net/21.15107/rcub_vinar_7011
Gulicovski J, Bajat J, Mišković-Stanković V, Jokić B, Panić V, Milonjić SK. Cerium oxide as conversion coating for the corrosion protection of aluminum. in Modtech 2012: New Face of T M C R, Vols I and II. 2012;:429-432.
https://hdl.handle.net/21.15107/rcub_vinar_7011 .
Gulicovski, Jelena, Bajat, Jelena, Mišković-Stanković, Vesna, Jokić, Bojan, Panić, Vladimir, Milonjić, Slobodan K., "Cerium oxide as conversion coating for the corrosion protection of aluminum" in Modtech 2012: New Face of T M C R, Vols I and II (2012):429-432,
https://hdl.handle.net/21.15107/rcub_vinar_7011 .

The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium

Đošić, Marija; Panić, V.; Stojanović, Jovica; Mitrić, Miodrag; Mišković-Stanković, Vesna

(Elsevier, Amsterdam, 2012)

TY  - JOUR
AU  - Đošić, Marija
AU  - Panić, V.
AU  - Stojanović, Jovica
AU  - Mitrić, Miodrag
AU  - Mišković-Stanković, Vesna
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2246
AB  - Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite.
PB  - Elsevier, Amsterdam
T2  - Colloids and Surfaces A-Physicochemical and Engineering Aspects
T1  - The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium
EP  - 43
SP  - 36
VL  - 400
DO  - 10.1016/j.colsurfa.2012.02.040
ER  - 
@article{
author = "Đošić, Marija and Panić, V. and Stojanović, Jovica and Mitrić, Miodrag and Mišković-Stanković, Vesna",
year = "2012",
abstract = "Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite.",
publisher = "Elsevier, Amsterdam",
journal = "Colloids and Surfaces A-Physicochemical and Engineering Aspects",
title = "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium",
pages = "43-36",
volume = "400",
doi = "10.1016/j.colsurfa.2012.02.040"
}
Đošić, M., Panić, V., Stojanović, J., Mitrić, M.,& Mišković-Stanković, V.. (2012). The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces A-Physicochemical and Engineering Aspects
Elsevier, Amsterdam., 400, 36-43.
https://doi.org/10.1016/j.colsurfa.2012.02.040
Đošić M, Panić V, Stojanović J, Mitrić M, Mišković-Stanković V. The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2012;400:36-43.
doi:10.1016/j.colsurfa.2012.02.040 .
Đošić, Marija, Panić, V., Stojanović, Jovica, Mitrić, Miodrag, Mišković-Stanković, Vesna, "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium" in Colloids and Surfaces A-Physicochemical and Engineering Aspects, 400 (2012):36-43,
https://doi.org/10.1016/j.colsurfa.2012.02.040 . .
46
41
50

Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution

Cvijović-Alagić, Ivana; Cvijović, Zorica; Mitrović, Slobodan; Panić, V.; Rakin, Marko

(Pergamon-Elsevier Science Ltd, Oxford, 2011)

TY  - JOUR
AU  - Cvijović-Alagić, Ivana
AU  - Cvijović, Zorica
AU  - Mitrović, Slobodan
AU  - Panić, V.
AU  - Rakin, Marko
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1935
AB  - Wear and corrosion behaviour of cold-rolled Ti-13Nb-13Zr alloy, with martensitic microstructure, and Ti-6Al-4V ELI alloy, in martensitic and two-phase (alpha + beta) microstructural conditions, was studied in a Ringer's solution. The wear experiments were performed at room temperature with a normal load of 40 N and sliding speeds 0.26. 0.5 and 1.0 m/s. The corrosion behaviour was studied at 37 degrees C using open circuit potential-time measurements and potentiodynamic polarization. It was found that Ti-13Nb-13Zr alloy has a substantially lower wear resistance than Ti-6Al-4V ELI alloy in both microstructural conditions. Surface damage extent increases with sliding speed increase and is always smallest for martensitic Ti-6Al-4V ELI alloy with highest hardness. Both alloys exhibit spontaneous passivity in Ringer's solution. Corrosion potential values are similar for all three materials. However, Ti-13Nb-13Zr and martensitic Ti-6Al-4V ELI alloys show improved corrosion resistance comparatively to Ti-6Al-4V ELI alloy with (alpha + beta) microstructure. Martensitic Ti-6Al-4V ELI alloy possesses the best combination of both corrosion and wear resistance, although its corrosion resistance is found to be slightly higher than that of the Ti-13Nb-13Zr alloy.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Corrosion Science
T1  - Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution
EP  - 808
IS  - 2
SP  - 796
VL  - 53
DO  - 10.1016/j.corsci.2010.11.014
ER  - 
@article{
author = "Cvijović-Alagić, Ivana and Cvijović, Zorica and Mitrović, Slobodan and Panić, V. and Rakin, Marko",
year = "2011",
abstract = "Wear and corrosion behaviour of cold-rolled Ti-13Nb-13Zr alloy, with martensitic microstructure, and Ti-6Al-4V ELI alloy, in martensitic and two-phase (alpha + beta) microstructural conditions, was studied in a Ringer's solution. The wear experiments were performed at room temperature with a normal load of 40 N and sliding speeds 0.26. 0.5 and 1.0 m/s. The corrosion behaviour was studied at 37 degrees C using open circuit potential-time measurements and potentiodynamic polarization. It was found that Ti-13Nb-13Zr alloy has a substantially lower wear resistance than Ti-6Al-4V ELI alloy in both microstructural conditions. Surface damage extent increases with sliding speed increase and is always smallest for martensitic Ti-6Al-4V ELI alloy with highest hardness. Both alloys exhibit spontaneous passivity in Ringer's solution. Corrosion potential values are similar for all three materials. However, Ti-13Nb-13Zr and martensitic Ti-6Al-4V ELI alloys show improved corrosion resistance comparatively to Ti-6Al-4V ELI alloy with (alpha + beta) microstructure. Martensitic Ti-6Al-4V ELI alloy possesses the best combination of both corrosion and wear resistance, although its corrosion resistance is found to be slightly higher than that of the Ti-13Nb-13Zr alloy.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Corrosion Science",
title = "Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution",
pages = "808-796",
number = "2",
volume = "53",
doi = "10.1016/j.corsci.2010.11.014"
}
Cvijović-Alagić, I., Cvijović, Z., Mitrović, S., Panić, V.,& Rakin, M.. (2011). Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution. in Corrosion Science
Pergamon-Elsevier Science Ltd, Oxford., 53(2), 796-808.
https://doi.org/10.1016/j.corsci.2010.11.014
Cvijović-Alagić I, Cvijović Z, Mitrović S, Panić V, Rakin M. Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution. in Corrosion Science. 2011;53(2):796-808.
doi:10.1016/j.corsci.2010.11.014 .
Cvijović-Alagić, Ivana, Cvijović, Zorica, Mitrović, Slobodan, Panić, V., Rakin, Marko, "Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution" in Corrosion Science, 53, no. 2 (2011):796-808,
https://doi.org/10.1016/j.corsci.2010.11.014 . .
235
166
246

Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation

Panić, Vladimir; Vidaković-Koch, Tanja; Andrić, Milan; Petkovska, Menka; Sundmacher, Kai

(Amer Chemical Soc, Washington, 2011)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković-Koch, Tanja
AU  - Andrić, Milan
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1867
AB  - Kinetics of ferrocyanide electrooxidation was investigated by nonlinear frequency response analysis (NLFRA) of current output to the sinusoidal large-amplitude potential perturbation input. The aim was to establish a measurement routine and to validate experimentally the NLFRA method on an example of a simple electrochemical reaction comprising charge and mass transfer. The first-order frequency response function (FRF) contains quasi-linear information on the reaction kinetics and corresponds to electrochemical admittance. The nonlinear fingerprint of the system is contained in the second-order FRF. The first- and second-order FRFs are determined from experimental first and second harmonics. Their intensities depend on the input signal amplitude, which has to be chosen carefully to avoid the contributions of higher order harmonics. The influence of the potential and electrode rotation speed on the first- and second-order FRFs has been studied. The experimentally obtained FRFs are compared with the theoretical FRFs determined in Part I of this work. The theoretical FRFs can predict all essential experimental observations. These findings indicate that additional information on reaction kinetics can be gained from the analysis of the second-order FRF.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry C
T1  - Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation
EP  - 17358
IS  - 35
SP  - 17352
VL  - 115
DO  - 10.1021/jp201300a
ER  - 
@article{
author = "Panić, Vladimir and Vidaković-Koch, Tanja and Andrić, Milan and Petkovska, Menka and Sundmacher, Kai",
year = "2011",
abstract = "Kinetics of ferrocyanide electrooxidation was investigated by nonlinear frequency response analysis (NLFRA) of current output to the sinusoidal large-amplitude potential perturbation input. The aim was to establish a measurement routine and to validate experimentally the NLFRA method on an example of a simple electrochemical reaction comprising charge and mass transfer. The first-order frequency response function (FRF) contains quasi-linear information on the reaction kinetics and corresponds to electrochemical admittance. The nonlinear fingerprint of the system is contained in the second-order FRF. The first- and second-order FRFs are determined from experimental first and second harmonics. Their intensities depend on the input signal amplitude, which has to be chosen carefully to avoid the contributions of higher order harmonics. The influence of the potential and electrode rotation speed on the first- and second-order FRFs has been studied. The experimentally obtained FRFs are compared with the theoretical FRFs determined in Part I of this work. The theoretical FRFs can predict all essential experimental observations. These findings indicate that additional information on reaction kinetics can be gained from the analysis of the second-order FRF.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation",
pages = "17358-17352",
number = "35",
volume = "115",
doi = "10.1021/jp201300a"
}
Panić, V., Vidaković-Koch, T., Andrić, M., Petkovska, M.,& Sundmacher, K.. (2011). Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 115(35), 17352-17358.
https://doi.org/10.1021/jp201300a
Panić V, Vidaković-Koch T, Andrić M, Petkovska M, Sundmacher K. Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation. in Journal of Physical Chemistry C. 2011;115(35):17352-17358.
doi:10.1021/jp201300a .
Panić, Vladimir, Vidaković-Koch, Tanja, Andrić, Milan, Petkovska, Menka, Sundmacher, Kai, "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part II. Measurement Routine and Experimental Validation" in Journal of Physical Chemistry C, 115, no. 35 (2011):17352-17358,
https://doi.org/10.1021/jp201300a . .
26
18
27

Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis

Vidaković-Koch, Tanja; Panić, Vladimir; Andrić, Milan; Petkovska, Menka; Sundmacher, Kai

(Amer Chemical Soc, Washington, 2011)

TY  - JOUR
AU  - Vidaković-Koch, Tanja
AU  - Panić, Vladimir
AU  - Andrić, Milan
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1866
AB  - In this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this work
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry C
T1  - Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis
EP  - 17351
IS  - 35
SP  - 17341
VL  - 115
DO  - 10.1021/jp201297v
ER  - 
@article{
author = "Vidaković-Koch, Tanja and Panić, Vladimir and Andrić, Milan and Petkovska, Menka and Sundmacher, Kai",
year = "2011",
abstract = "In this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this work",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis",
pages = "17351-17341",
number = "35",
volume = "115",
doi = "10.1021/jp201297v"
}
Vidaković-Koch, T., Panić, V., Andrić, M., Petkovska, M.,& Sundmacher, K.. (2011). Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 115(35), 17341-17351.
https://doi.org/10.1021/jp201297v
Vidaković-Koch T, Panić V, Andrić M, Petkovska M, Sundmacher K. Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis. in Journal of Physical Chemistry C. 2011;115(35):17341-17351.
doi:10.1021/jp201297v .
Vidaković-Koch, Tanja, Panić, Vladimir, Andrić, Milan, Petkovska, Menka, Sundmacher, Kai, "Nonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysis" in Journal of Physical Chemistry C, 115, no. 35 (2011):17341-17351,
https://doi.org/10.1021/jp201297v . .
26
23
32

Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure

Panić, Vladimir; Dekanski, Aleksandar; Mišković-Stanković, Vesna; Milonjić, Slobodan K.; Nikolić, Branislav Ž.

(Serbian Chemical Society, Belgrade, 2010)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1597
AB  - The electrochemical characteristics of Ti0.6Ir0.4O2/Ti and Ti0.6Ru0.4O2/Ti anodes prepared by the sol-gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H2SO4 solution indicate that Ti0.6Ir0.4O2/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 VSCE, this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti0.6Ru0.4O2/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti0.6Ir0.4O2/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti0.6Ru0.4O2/ /Ti electrode behaved like a capacitor over a wider potential range than the Ti0.6Ir0.4O2/Ti electrode, with fully-developed pseudocapacitive properties at potentials positive to 0.60 VSCE. However, the impedance characteristics of the Ti0.6Ir0.4O2/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior.
AB  - U radu su ispitivane elektrohemijske karakteristike Ti0,6Ir0,4O2/Ti i Ti0,6Ru0,4O2/Ti anoda dobijenih sol-gel postupkom iz oksidnih solova sintetisanih forsiranom hidrolizom odgovarajućih hlorida metala. Voltametrijske karakteristike u rastvoru H2SO4 ukazuju na više izraženo pseudokapacitivno ponašanje Ti0,6Ir0,4O2/Ti elektrode koje je posledica površinskih redoks prelaza u čvrstom stanju uz učešće protona. Na potencijalima negativnijim od 0,0 VZKE ova elektroda pokazuje slabu provodnost i aktivnost, dok voltametrijskim ponašanjem Ti0,6Ru0,4O2/Ti elektrode dominira prodor protona u strukturu oksida. Ti0,6Ir0,4O2/Ti anoda je elektrokatalitički aktivnija za reakciju izdvajanja kiseonika, dok su anode sličnih aktivnosti za reakciju izdvajanja hlora. Impedansne karakteristike formiranih anoda pokazuju da se Ti0,6Ru0,4O2/Ti elektroda ponaša slično kondenzatoru u širem opsegu potencijala nego što je to slučaj sa Ti0,6Ir0,4O2/Ti elektrodom, sa potpuno razvijenim pseudokapacitivnim svojstvima na potencijalima pozitivnijim od 0,60 VZKE. S druge strane, za Ti0,6Ir0,4O2/Ti elektrodu se uočava prelaz sa karakteristika sličnih otporniku na karakteristike slične kondenzatoru sa porastom potencijala elektrode.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure
T1  - Razlike u elektrohemijskom ponašanju oksida rutenijuma i iridijuma u elektrokatalitičkim prevlakama aktiviranih titanskih anoda dobijenih sol-gel postupkom
EP  - 1420
IS  - 10
SP  - 1413
VL  - 75
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1597
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2010",
abstract = "The electrochemical characteristics of Ti0.6Ir0.4O2/Ti and Ti0.6Ru0.4O2/Ti anodes prepared by the sol-gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H2SO4 solution indicate that Ti0.6Ir0.4O2/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 VSCE, this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti0.6Ru0.4O2/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti0.6Ir0.4O2/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti0.6Ru0.4O2/ /Ti electrode behaved like a capacitor over a wider potential range than the Ti0.6Ir0.4O2/Ti electrode, with fully-developed pseudocapacitive properties at potentials positive to 0.60 VSCE. However, the impedance characteristics of the Ti0.6Ir0.4O2/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior., U radu su ispitivane elektrohemijske karakteristike Ti0,6Ir0,4O2/Ti i Ti0,6Ru0,4O2/Ti anoda dobijenih sol-gel postupkom iz oksidnih solova sintetisanih forsiranom hidrolizom odgovarajućih hlorida metala. Voltametrijske karakteristike u rastvoru H2SO4 ukazuju na više izraženo pseudokapacitivno ponašanje Ti0,6Ir0,4O2/Ti elektrode koje je posledica površinskih redoks prelaza u čvrstom stanju uz učešće protona. Na potencijalima negativnijim od 0,0 VZKE ova elektroda pokazuje slabu provodnost i aktivnost, dok voltametrijskim ponašanjem Ti0,6Ru0,4O2/Ti elektrode dominira prodor protona u strukturu oksida. Ti0,6Ir0,4O2/Ti anoda je elektrokatalitički aktivnija za reakciju izdvajanja kiseonika, dok su anode sličnih aktivnosti za reakciju izdvajanja hlora. Impedansne karakteristike formiranih anoda pokazuju da se Ti0,6Ru0,4O2/Ti elektroda ponaša slično kondenzatoru u širem opsegu potencijala nego što je to slučaj sa Ti0,6Ir0,4O2/Ti elektrodom, sa potpuno razvijenim pseudokapacitivnim svojstvima na potencijalima pozitivnijim od 0,60 VZKE. S druge strane, za Ti0,6Ir0,4O2/Ti elektrodu se uočava prelaz sa karakteristika sličnih otporniku na karakteristike slične kondenzatoru sa porastom potencijala elektrode.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure, Razlike u elektrohemijskom ponašanju oksida rutenijuma i iridijuma u elektrokatalitičkim prevlakama aktiviranih titanskih anoda dobijenih sol-gel postupkom",
pages = "1420-1413",
number = "10",
volume = "75",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1597"
}
Panić, V., Dekanski, A., Mišković-Stanković, V., Milonjić, S. K.,& Nikolić, B. Ž.. (2010). Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 75(10), 1413-1420.
https://hdl.handle.net/21.15107/rcub_technorep_1597
Panić V, Dekanski A, Mišković-Stanković V, Milonjić SK, Nikolić BŽ. Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2010;75(10):1413-1420.
https://hdl.handle.net/21.15107/rcub_technorep_1597 .
Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Milonjić, Slobodan K., Nikolić, Branislav Ž., "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure" in Journal of the Serbian Chemical Society, 75, no. 10 (2010):1413-1420,
https://hdl.handle.net/21.15107/rcub_technorep_1597 .
10
13

The electrochemical synthesis of different Ag/PVP nanocomposites

Jovanović, Željka; Panić, Vladimir; Nikolić, Branislav; Mišković-Stanković, Vesna

(Serbian Chemical Society, Belgrade, 2010)

TY  - CONF
AU  - Jovanović, Željka
AU  - Panić, Vladimir
AU  - Nikolić, Branislav
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1557
AB  - The potential use of Ag/poly(N-vinyl-2-pyrrolidone) (PVP) nanocomposites is in wound dressings or soft tissue implants, where Ag nanoparticles (AgNPs) serve as the antimicrobial agent. Ag/PVP nanocomposites were electrochemically synthesized, by the electrochemical reduction of Ag+ ions into the AgNPs in the PVP aqueous solution and within the crosslinked PVP matrix, forming the non-crosslinked and crosslinked Ag/PVP nanocomposite, respectively. The synthesis of AgNPs was performed in an electrochemical cell with Pt working and counter electrodes and the saturated calomel electrode (SCE) as the reference. The non-crosslinked Ag/PVP nanocomposite was obtained by galvanostatic reduction of Ag+ ions from the aqueous solution consisted of 0.10 M KNO3, 3.9 mM AgNO3 and 10 wt. % PVP. The crosslinked Ag/PVP nanocomposite was obtained by in situ potentiostatic reduction of Ag+ ions within PVP hydrogel, previously prepared by -irradiation of the 10 wt. % PVP aqueous solution. Hydrogels were swollen in two different aqueous solutions ((a) 3.9 mM AgNO3, (b) 3.9 mM AgNO3 + 0.10 M KNO3) for 24 h. Ag/PVP nanocomposite systems were characterized by UV-Vis spectroscopy, FTIR, TEM, XRD, Z-sizer analysis and cyclic voltammetry.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
T1  - The electrochemical synthesis of different Ag/PVP nanocomposites
EP  - 155
SP  - 155
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1557
ER  - 
@conference{
author = "Jovanović, Željka and Panić, Vladimir and Nikolić, Branislav and Mišković-Stanković, Vesna",
year = "2010",
abstract = "The potential use of Ag/poly(N-vinyl-2-pyrrolidone) (PVP) nanocomposites is in wound dressings or soft tissue implants, where Ag nanoparticles (AgNPs) serve as the antimicrobial agent. Ag/PVP nanocomposites were electrochemically synthesized, by the electrochemical reduction of Ag+ ions into the AgNPs in the PVP aqueous solution and within the crosslinked PVP matrix, forming the non-crosslinked and crosslinked Ag/PVP nanocomposite, respectively. The synthesis of AgNPs was performed in an electrochemical cell with Pt working and counter electrodes and the saturated calomel electrode (SCE) as the reference. The non-crosslinked Ag/PVP nanocomposite was obtained by galvanostatic reduction of Ag+ ions from the aqueous solution consisted of 0.10 M KNO3, 3.9 mM AgNO3 and 10 wt. % PVP. The crosslinked Ag/PVP nanocomposite was obtained by in situ potentiostatic reduction of Ag+ ions within PVP hydrogel, previously prepared by -irradiation of the 10 wt. % PVP aqueous solution. Hydrogels were swollen in two different aqueous solutions ((a) 3.9 mM AgNO3, (b) 3.9 mM AgNO3 + 0.10 M KNO3) for 24 h. Ag/PVP nanocomposite systems were characterized by UV-Vis spectroscopy, FTIR, TEM, XRD, Z-sizer analysis and cyclic voltammetry.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra",
title = "The electrochemical synthesis of different Ag/PVP nanocomposites",
pages = "155-155",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1557"
}
Jovanović, Ž., Panić, V., Nikolić, B.,& Mišković-Stanković, V.. (2010). The electrochemical synthesis of different Ag/PVP nanocomposites. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
Serbian Chemical Society, Belgrade., 155-155.
https://hdl.handle.net/21.15107/rcub_technorep_1557
Jovanović Ž, Panić V, Nikolić B, Mišković-Stanković V. The electrochemical synthesis of different Ag/PVP nanocomposites. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra. 2010;:155-155.
https://hdl.handle.net/21.15107/rcub_technorep_1557 .
Jovanović, Željka, Panić, Vladimir, Nikolić, Branislav, Mišković-Stanković, Vesna, "The electrochemical synthesis of different Ag/PVP nanocomposites" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra (2010):155-155,
https://hdl.handle.net/21.15107/rcub_technorep_1557 .

Photovoltaics of sol-gel processed titanium oxide coating

Panić, Vladimir; Mišković-Stanković, Vesna; Jovanović, Branislav; Milonjić, Slobodan K.; Nikolić, Branislav

(Serbian Chemical Society, Belgrade, 2010)

TY  - CONF
AU  - Panić, Vladimir
AU  - Mišković-Stanković, Vesna
AU  - Jovanović, Branislav
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1555
AB  - Titanium oxide is applied as a photocatalyst in organic synthesis and for waste water treatment and outdoor air purification. In this work, photoelectrochemical (PEC) activity of titanium oxide coating on titanium substrate, prepared by the sol–gel procedure from the oxide sol obtained by forced hydrolysis of chloride was investigated. Electrochemical and PEC parameters at photoelectrode change intensively upon UV illumination when organic compounds (alcohols, aldehydes, acids, etc.) are present in the electrolyte (H2SO4), which proves coating activity for their oxidation. Electrochemical impedance (EIS) characteristics of the coating are found to be sensitive to the photoelectrode potential and UV light. EIS characteristics are discussed on the basis of the values of parameters of equivalent electrical circuit used to fit experimental impedance data.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
T1  - Photovoltaics of sol-gel processed titanium oxide coating
EP  - 88
SP  - 88
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1555
ER  - 
@conference{
author = "Panić, Vladimir and Mišković-Stanković, Vesna and Jovanović, Branislav and Milonjić, Slobodan K. and Nikolić, Branislav",
year = "2010",
abstract = "Titanium oxide is applied as a photocatalyst in organic synthesis and for waste water treatment and outdoor air purification. In this work, photoelectrochemical (PEC) activity of titanium oxide coating on titanium substrate, prepared by the sol–gel procedure from the oxide sol obtained by forced hydrolysis of chloride was investigated. Electrochemical and PEC parameters at photoelectrode change intensively upon UV illumination when organic compounds (alcohols, aldehydes, acids, etc.) are present in the electrolyte (H2SO4), which proves coating activity for their oxidation. Electrochemical impedance (EIS) characteristics of the coating are found to be sensitive to the photoelectrode potential and UV light. EIS characteristics are discussed on the basis of the values of parameters of equivalent electrical circuit used to fit experimental impedance data.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra",
title = "Photovoltaics of sol-gel processed titanium oxide coating",
pages = "88-88",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1555"
}
Panić, V., Mišković-Stanković, V., Jovanović, B., Milonjić, S. K.,& Nikolić, B.. (2010). Photovoltaics of sol-gel processed titanium oxide coating. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
Serbian Chemical Society, Belgrade., 88-88.
https://hdl.handle.net/21.15107/rcub_technorep_1555
Panić V, Mišković-Stanković V, Jovanović B, Milonjić SK, Nikolić B. Photovoltaics of sol-gel processed titanium oxide coating. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra. 2010;:88-88.
https://hdl.handle.net/21.15107/rcub_technorep_1555 .
Panić, Vladimir, Mišković-Stanković, Vesna, Jovanović, Branislav, Milonjić, Slobodan K., Nikolić, Branislav, "Photovoltaics of sol-gel processed titanium oxide coating" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra (2010):88-88,
https://hdl.handle.net/21.15107/rcub_technorep_1555 .

Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite

Jovanović, Željka; Panić, Vladimir; Krklješ, Aleksandra; Kačarević-Popović, Zorica M.; Nikolić, Branislav; Mišković-Stanković, Vesna

(Serbian Chemical Society, Belgrade, 2010)

TY  - CONF
AU  - Jovanović, Željka
AU  - Panić, Vladimir
AU  - Krklješ, Aleksandra
AU  - Kačarević-Popović, Zorica M.
AU  - Nikolić, Branislav
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1554
AB  - Hydrogel nanocomposites of silver nanoparticles (AgNPs) and crosslinked poly(N-vinyl-2-pyrrolidone) (PVP) were synthesized in situ by a novel electrochemical method. PVPhydrogels, crosslinked by gamma-irradiation, were swollen in the solution containing0.1 M KNO3 and 3.9 mM AgNO3. PVP polymer matrix nanocavities were used asnanoreactors for AgNPs synthesis. The reduction of silver cations was performed usingtwo-Pt-electrode electrochemical cell. The polarity of the electrodes was changed on thehalf of the implementation time, enabling the Ag+ ions reduction in the bulk. Cyclicvoltammetry (CV) was performed in a three-electrode electrochemical cell, using thesaturated calomel electrode (SCE) as a reference. Ag/PVP nanocomposites werescanned by CV immediately after the synthesis and after drying followed by reswelling in0.1 M KNO3. Ag/PVP was compared with CVs of the following systems: Pt electrode in0.1 M KNO3; Pt/PVP system in 0.1 M KNO3; Ag/Pt system in 0.1 M KNO3 + 3.9 mMAgNO3 solution.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
T1  - Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite
EP  - 32
SP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1554
ER  - 
@conference{
author = "Jovanović, Željka and Panić, Vladimir and Krklješ, Aleksandra and Kačarević-Popović, Zorica M. and Nikolić, Branislav and Mišković-Stanković, Vesna",
year = "2010",
abstract = "Hydrogel nanocomposites of silver nanoparticles (AgNPs) and crosslinked poly(N-vinyl-2-pyrrolidone) (PVP) were synthesized in situ by a novel electrochemical method. PVPhydrogels, crosslinked by gamma-irradiation, were swollen in the solution containing0.1 M KNO3 and 3.9 mM AgNO3. PVP polymer matrix nanocavities were used asnanoreactors for AgNPs synthesis. The reduction of silver cations was performed usingtwo-Pt-electrode electrochemical cell. The polarity of the electrodes was changed on thehalf of the implementation time, enabling the Ag+ ions reduction in the bulk. Cyclicvoltammetry (CV) was performed in a three-electrode electrochemical cell, using thesaturated calomel electrode (SCE) as a reference. Ag/PVP nanocomposites werescanned by CV immediately after the synthesis and after drying followed by reswelling in0.1 M KNO3. Ag/PVP was compared with CVs of the following systems: Pt electrode in0.1 M KNO3; Pt/PVP system in 0.1 M KNO3; Ag/Pt system in 0.1 M KNO3 + 3.9 mMAgNO3 solution.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings",
title = "Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite",
pages = "32-29",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1554"
}
Jovanović, Ž., Panić, V., Krklješ, A., Kačarević-Popović, Z. M., Nikolić, B.,& Mišković-Stanković, V.. (2010). Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
Serbian Chemical Society, Belgrade., 29-32.
https://hdl.handle.net/21.15107/rcub_technorep_1554
Jovanović Ž, Panić V, Krklješ A, Kačarević-Popović ZM, Nikolić B, Mišković-Stanković V. Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings. 2010;:29-32.
https://hdl.handle.net/21.15107/rcub_technorep_1554 .
Jovanović, Željka, Panić, Vladimir, Krklješ, Aleksandra, Kačarević-Popović, Zorica M., Nikolić, Branislav, Mišković-Stanković, Vesna, "Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings (2010):29-32,
https://hdl.handle.net/21.15107/rcub_technorep_1554 .

Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics

Panić, Vladimir; Vidaković-Koch, Tanja; Živković, Luka; Petkovska, Menka; Sundmacher, Kai

(Serbian Chemical Society, Belgrade, 2010)

TY  - CONF
AU  - Panić, Vladimir
AU  - Vidaković-Koch, Tanja
AU  - Živković, Luka
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1545
AB  - In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
T1  - Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics
EP  - 148
SP  - 145
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1545
ER  - 
@conference{
author = "Panić, Vladimir and Vidaković-Koch, Tanja and Živković, Luka and Petkovska, Menka and Sundmacher, Kai",
year = "2010",
abstract = "In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings",
title = "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics",
pages = "148-145",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1545"
}
Panić, V., Vidaković-Koch, T., Živković, L., Petkovska, M.,& Sundmacher, K.. (2010). Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
Serbian Chemical Society, Belgrade., 145-148.
https://hdl.handle.net/21.15107/rcub_technorep_1545
Panić V, Vidaković-Koch T, Živković L, Petkovska M, Sundmacher K. Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings. 2010;:145-148.
https://hdl.handle.net/21.15107/rcub_technorep_1545 .
Panić, Vladimir, Vidaković-Koch, Tanja, Živković, Luka, Petkovska, Menka, Sundmacher, Kai, "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings (2010):145-148,
https://hdl.handle.net/21.15107/rcub_technorep_1545 .

Hydroxyapatite coatings on TiO2 nanotubes

Eraković, Sanja; Panić, Vladimir; Jokić, Bojan; Stevanović, Sanja; Mišković-Stanković, Vesna

(Engineering Society for Corrosion, Belgrade, Serbia, 2010)

TY  - JOUR
AU  - Eraković, Sanja
AU  - Panić, Vladimir
AU  - Jokić, Bojan
AU  - Stevanović, Sanja
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1646
AB  - The aim of this work was to obtain nanotubular TiO2 layer by anodization of titanium substrate, and to prepare hydroxyapatite (HAP) coatings by electrophoretic deposition over nanotubular TiO2 layer. The presence of fluoride ion in the electrolyte for anodization causes the formation of TiO2 nanotubes. The Ti surface modified with TiO2 nanotubes was used for fabrication of HAP coatings by electrophoretic deposition. Acidic medium provides formation of short nanotubes which are more suitable for deposition of HAP coatings. Ti plates were thermally treated after anodization in order to gain more defined structure of nanotubular TiO2 layer. Compact HAP coatings with good adhesion were produced by electrophoretic deposition on thermally treated and untreated anodized specimens. The results showed that coating mass increases with deposition time, but prolongation of the deposition time causes the decrease of HAP coating adhesion. .
AB  - Cilj ovog rada je dobijanje nanotubularnog TiO2 sloja na titanu postupkom anodizacije i ispitivanje parametara elektroforetskog taloženja prevlaka hidroksiapatita (HAP) na formiranom međusloju nanotubularnog TiO2. Pokazano je da anodizacija titana u elektrolitu koji sadrži fluoridne jone omogućava formiranje nanotuba TiO2 na površini titana. Površina titana modifikovana nanotubama TiO2 je korišćena kao podloga za kataforetsko taloženje prevlaka hidroksiapatita iz etanolske suspenzije. Kisela sredina za anodizaciju titana omogućava dobijanje kraćih nanotuba koje su se pokazale kao bolja podloga za nanošenje HAP prevlaka. Nakon anodizacije, titanske pločice su termički tretirane da bi se dobila definisanija struktura nanotubularnog TiO2 sloja. Kataforetskim taloženjem dobijene su dobro prianjajuće i kompaktne HAP prevlake na termički tretiranim i netretiranim anodiziranim uzorcima. Rezultati pokazuju da pri vremenima taloženja dužim od 45 min dolazi do smanjenja adhezije prevlake hidroksiapatita.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Hydroxyapatite coatings on TiO2 nanotubes
T1  - Prevlake hidroksiapatita na nanotubama oksida titana
EP  - 28
IS  - 1
SP  - 24
VL  - 51
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1646
ER  - 
@article{
author = "Eraković, Sanja and Panić, Vladimir and Jokić, Bojan and Stevanović, Sanja and Mišković-Stanković, Vesna",
year = "2010",
abstract = "The aim of this work was to obtain nanotubular TiO2 layer by anodization of titanium substrate, and to prepare hydroxyapatite (HAP) coatings by electrophoretic deposition over nanotubular TiO2 layer. The presence of fluoride ion in the electrolyte for anodization causes the formation of TiO2 nanotubes. The Ti surface modified with TiO2 nanotubes was used for fabrication of HAP coatings by electrophoretic deposition. Acidic medium provides formation of short nanotubes which are more suitable for deposition of HAP coatings. Ti plates were thermally treated after anodization in order to gain more defined structure of nanotubular TiO2 layer. Compact HAP coatings with good adhesion were produced by electrophoretic deposition on thermally treated and untreated anodized specimens. The results showed that coating mass increases with deposition time, but prolongation of the deposition time causes the decrease of HAP coating adhesion. ., Cilj ovog rada je dobijanje nanotubularnog TiO2 sloja na titanu postupkom anodizacije i ispitivanje parametara elektroforetskog taloženja prevlaka hidroksiapatita (HAP) na formiranom međusloju nanotubularnog TiO2. Pokazano je da anodizacija titana u elektrolitu koji sadrži fluoridne jone omogućava formiranje nanotuba TiO2 na površini titana. Površina titana modifikovana nanotubama TiO2 je korišćena kao podloga za kataforetsko taloženje prevlaka hidroksiapatita iz etanolske suspenzije. Kisela sredina za anodizaciju titana omogućava dobijanje kraćih nanotuba koje su se pokazale kao bolja podloga za nanošenje HAP prevlaka. Nakon anodizacije, titanske pločice su termički tretirane da bi se dobila definisanija struktura nanotubularnog TiO2 sloja. Kataforetskim taloženjem dobijene su dobro prianjajuće i kompaktne HAP prevlake na termički tretiranim i netretiranim anodiziranim uzorcima. Rezultati pokazuju da pri vremenima taloženja dužim od 45 min dolazi do smanjenja adhezije prevlake hidroksiapatita.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Hydroxyapatite coatings on TiO2 nanotubes, Prevlake hidroksiapatita na nanotubama oksida titana",
pages = "28-24",
number = "1",
volume = "51",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1646"
}
Eraković, S., Panić, V., Jokić, B., Stevanović, S.,& Mišković-Stanković, V.. (2010). Hydroxyapatite coatings on TiO2 nanotubes. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 51(1), 24-28.
https://hdl.handle.net/21.15107/rcub_technorep_1646
Eraković S, Panić V, Jokić B, Stevanović S, Mišković-Stanković V. Hydroxyapatite coatings on TiO2 nanotubes. in Zaštita materijala. 2010;51(1):24-28.
https://hdl.handle.net/21.15107/rcub_technorep_1646 .
Eraković, Sanja, Panić, Vladimir, Jokić, Bojan, Stevanović, Sanja, Mišković-Stanković, Vesna, "Hydroxyapatite coatings on TiO2 nanotubes" in Zaštita materijala, 51, no. 1 (2010):24-28,
https://hdl.handle.net/21.15107/rcub_technorep_1646 .

The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties

Panić, Vladimir; Dekanski, Aleksandar; Mitrić, Miodrag; Milonjić, Slobodan K.; Mišković-Stanković, Vesna; Nikolić, Branislav Ž.

(Royal Soc Chemistry, Cambridge, 2010)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mitrić, Miodrag
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, Branislav Ž.
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1578
AB  - Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.
PB  - Royal Soc Chemistry, Cambridge
T2  - Physical Chemistry Chemical Physics
T1  - The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties
EP  - 7528
IS  - 27
SP  - 7521
VL  - 12
DO  - 10.1039/b921582d
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mitrić, Miodrag and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, Branislav Ž.",
year = "2010",
abstract = "Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Physical Chemistry Chemical Physics",
title = "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties",
pages = "7528-7521",
number = "27",
volume = "12",
doi = "10.1039/b921582d"
}
Panić, V., Dekanski, A., Mitrić, M., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B. Ž.. (2010). The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics
Royal Soc Chemistry, Cambridge., 12(27), 7521-7528.
https://doi.org/10.1039/b921582d
Panić V, Dekanski A, Mitrić M, Milonjić SK, Mišković-Stanković V, Nikolić BŽ. The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics. 2010;12(27):7521-7528.
doi:10.1039/b921582d .
Panić, Vladimir, Dekanski, Aleksandar, Mitrić, Miodrag, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, Branislav Ž., "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties" in Physical Chemistry Chemical Physics, 12, no. 27 (2010):7521-7528,
https://doi.org/10.1039/b921582d . .
17
17
19

A comparative study of the electrochemical properties of carbon nanotubes and carbon black

Obradović, Maja; Vuković, Goran D.; Stevanović, Sanja; Panić, Vladimir; Uskoković, Petar; Kowal, Andrzej; Gojković, Snežana Lj.

(Elsevier Science Sa, Lausanne, 2009)

TY  - JOUR
AU  - Obradović, Maja
AU  - Vuković, Goran D.
AU  - Stevanović, Sanja
AU  - Panić, Vladimir
AU  - Uskoković, Petar
AU  - Kowal, Andrzej
AU  - Gojković, Snežana Lj.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1420
AB  - Two samples of commercial multi-walled carbon nanotubes (Sigma-Aldrich and Sun Nanotech) and a sample of carbon black (Vulcan XC-72R) were investigated in raw state and after the activation in nitric and sulfuric acid by ultrasound agitation. Atomic force microscopy revealed that activated Sigma-Aldrich nanotubes are straight with corrugated walls (bamboo-like structure), while Sun Nanotech nanotubes are tortuous with smooth walls. Fourier transform infrared spectroscopy showed that abundance of oxygen-containing functional groups was formed on both Sigma-Aldrich and Sun Nanotech carbon nanotubes, as well as on carbon black surfaces. Electrochemical properties were studied by cyclic voltammetry and electrochemical impedance spectroscopy. It was found that the electrochemically active surface area of all carbon samples is expanded, charge storage ability is enhanced and the electron-transfer kinetics, probed by Fe(CN)(6)(3-)/Fe(CN)(6)(4-) redox couple, is promoted upon activation. The characteristics of carbon nanotubes were superior to Carbon black. Morphology of the carbon nanotubes was found to be important; nanotubes with corrugated walls showed faster electron-transfer and pseudocapacitive redox kinetics than nanotubes with smooth walls. This was explained by the higher proportion of edge and defect sites, which are known as more electrochemically active than the walls of uniform graphene structure.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Electroanalytical Chemistry
T1  - A comparative study of the electrochemical properties of carbon nanotubes and carbon black
EP  - 30
IS  - 1
SP  - 22
VL  - 634
DO  - 10.1016/j.jelechem.2009.07.001
ER  - 
@article{
author = "Obradović, Maja and Vuković, Goran D. and Stevanović, Sanja and Panić, Vladimir and Uskoković, Petar and Kowal, Andrzej and Gojković, Snežana Lj.",
year = "2009",
abstract = "Two samples of commercial multi-walled carbon nanotubes (Sigma-Aldrich and Sun Nanotech) and a sample of carbon black (Vulcan XC-72R) were investigated in raw state and after the activation in nitric and sulfuric acid by ultrasound agitation. Atomic force microscopy revealed that activated Sigma-Aldrich nanotubes are straight with corrugated walls (bamboo-like structure), while Sun Nanotech nanotubes are tortuous with smooth walls. Fourier transform infrared spectroscopy showed that abundance of oxygen-containing functional groups was formed on both Sigma-Aldrich and Sun Nanotech carbon nanotubes, as well as on carbon black surfaces. Electrochemical properties were studied by cyclic voltammetry and electrochemical impedance spectroscopy. It was found that the electrochemically active surface area of all carbon samples is expanded, charge storage ability is enhanced and the electron-transfer kinetics, probed by Fe(CN)(6)(3-)/Fe(CN)(6)(4-) redox couple, is promoted upon activation. The characteristics of carbon nanotubes were superior to Carbon black. Morphology of the carbon nanotubes was found to be important; nanotubes with corrugated walls showed faster electron-transfer and pseudocapacitive redox kinetics than nanotubes with smooth walls. This was explained by the higher proportion of edge and defect sites, which are known as more electrochemically active than the walls of uniform graphene structure.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Electroanalytical Chemistry",
title = "A comparative study of the electrochemical properties of carbon nanotubes and carbon black",
pages = "30-22",
number = "1",
volume = "634",
doi = "10.1016/j.jelechem.2009.07.001"
}
Obradović, M., Vuković, G. D., Stevanović, S., Panić, V., Uskoković, P., Kowal, A.,& Gojković, S. Lj.. (2009). A comparative study of the electrochemical properties of carbon nanotubes and carbon black. in Journal of Electroanalytical Chemistry
Elsevier Science Sa, Lausanne., 634(1), 22-30.
https://doi.org/10.1016/j.jelechem.2009.07.001
Obradović M, Vuković GD, Stevanović S, Panić V, Uskoković P, Kowal A, Gojković SL. A comparative study of the electrochemical properties of carbon nanotubes and carbon black. in Journal of Electroanalytical Chemistry. 2009;634(1):22-30.
doi:10.1016/j.jelechem.2009.07.001 .
Obradović, Maja, Vuković, Goran D., Stevanović, Sanja, Panić, Vladimir, Uskoković, Petar, Kowal, Andrzej, Gojković, Snežana Lj., "A comparative study of the electrochemical properties of carbon nanotubes and carbon black" in Journal of Electroanalytical Chemistry, 634, no. 1 (2009):22-30,
https://doi.org/10.1016/j.jelechem.2009.07.001 . .
46
41
48

The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure

Panić, Vladimir; Dekanski, Aleksandar; Mišković-Stanković, Vesna; Nikolić, B. Z.

(Croatian Society of Chemical Engineers, 2009)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B. Z.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1361
AB  - The changes in capacitive behavior of C/H(x)RuO(y) composite material prepared by impregnating the Vulcan (R) XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion (R)-covered composite. The techniques of cyclic voltammetry and electrochemical impedance spectroscopy are used. Results of the investigation reveal the influence of potential cycling and the exposure time to the electrolyte on registered capacitive characteristics of composite. The cycling in a wide potential range causes the decrease in energy storage ability which depends on oxide particle size. Impedance measurements, however, show that the ability initially decreases and subsequently increases during exposure to the electrolyte as the consequence of the presence of Nafion (R) top-layer. Due to wettability and resistance issues, Nafion (R) top-layer can affect the pseudo-capacitive characteristics, and the energy storage ability of the composite consequently decreases.
PB  - Croatian Society of Chemical Engineers
T2  - Chemical and Biochemical Engineering Quarterly
T1  - The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure
EP  - 30
IS  - 1
SP  - 23
VL  - 23
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1361
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Nikolić, B. Z.",
year = "2009",
abstract = "The changes in capacitive behavior of C/H(x)RuO(y) composite material prepared by impregnating the Vulcan (R) XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion (R)-covered composite. The techniques of cyclic voltammetry and electrochemical impedance spectroscopy are used. Results of the investigation reveal the influence of potential cycling and the exposure time to the electrolyte on registered capacitive characteristics of composite. The cycling in a wide potential range causes the decrease in energy storage ability which depends on oxide particle size. Impedance measurements, however, show that the ability initially decreases and subsequently increases during exposure to the electrolyte as the consequence of the presence of Nafion (R) top-layer. Due to wettability and resistance issues, Nafion (R) top-layer can affect the pseudo-capacitive characteristics, and the energy storage ability of the composite consequently decreases.",
publisher = "Croatian Society of Chemical Engineers",
journal = "Chemical and Biochemical Engineering Quarterly",
title = "The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure",
pages = "30-23",
number = "1",
volume = "23",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1361"
}
Panić, V., Dekanski, A., Mišković-Stanković, V.,& Nikolić, B. Z.. (2009). The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure. in Chemical and Biochemical Engineering Quarterly
Croatian Society of Chemical Engineers., 23(1), 23-30.
https://hdl.handle.net/21.15107/rcub_technorep_1361
Panić V, Dekanski A, Mišković-Stanković V, Nikolić BZ. The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure. in Chemical and Biochemical Engineering Quarterly. 2009;23(1):23-30.
https://hdl.handle.net/21.15107/rcub_technorep_1361 .
Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Nikolić, B. Z., "The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure" in Chemical and Biochemical Engineering Quarterly, 23, no. 1 (2009):23-30,
https://hdl.handle.net/21.15107/rcub_technorep_1361 .
7
6

Electrochemical properties of mixed WC and Pt-black powders

Obradović, Maja; Babić, Biljana M.; Kowal, Andrzej; Panić, Vladimir; Gojković, Snežana Lj.

(Serbian Chemical Society, Belgrade, 2008)

TY  - JOUR
AU  - Obradović, Maja
AU  - Babić, Biljana M.
AU  - Kowal, Andrzej
AU  - Panić, Vladimir
AU  - Gojković, Snežana Lj.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1305
AB  - The electrochemical characteristics of a mixture of Pt-black and WC powders and its catalytic activity for methanol and formic acid oxidation were investigated in acid solution. XRD and AFM measurements revealed that the WC powder employed for the investigation was a single-phase material consisting of crystallites/spherical particles of average size of about 50 nm, which were agglomerated into much larger particles. Cyclic voltammetry showed that the WC underwent electrochemical oxidation, producing tungstate species. In the case of the mixed Pt + WC powders, the tungstate species were deposited on the Pt as a thin film of hydrous tungsten oxide. Enhanced hydrogen intercalation in the hydrous tungsten oxide was observed and it was proposed to be promoted in mixed powders by the presence of hydrogen adatoms on bare Pt sites. The determination of Pt surface area in the Pt + WC layer by stripping of underpotentially deposited Cu revealed that the entire Pt surface was accessible for underpotential deposition of Cu. Investigation of the electrochemical oxidation of methanol and formic acid on Pt + WC and pure Pt layers did not indicate electrocatalytic promotion due to the presence of WC.
AB  - U radu su ispitivane elektrohemijske karakteristike smeše prahova Pt i WC i njena katalitička aktivnost za reakcije oksidacije metanola i mravlje kiseline u kiselom rastvoru. Analiza rezultata difrakcije X-zraka (XRD) i mikroskopije atomskih sila (AFM) pokazuju da je prah WC jednofazni materijal sa prosečnom veličinom kristalita od oko 50 nm, koji su aglomerisani u mnogo veće čestice. Ciklična voltametrija ukazuje na to da WC podleže oksidaciji kojom nastaju volframatne vrste. U slučaju smeše prahova Pt i WC, volframatne vrste najverovatnije se talože na Pt u obliku tankog sloja hidratisanih oksida volframa. Primećeno je povećanje interkalacije vodonika u sloju hidratisanih volframata i pretpostavlja se da prisustvo adatoma vodonika na površini Pt potpomaže proces vodonične interkalacije. Određivanje površine Pt u sloju Pt + WC desorpcijom monosloja Cu taloženog na potpotencijalima ukazuje da je čitava površina Pt dostupna za taloženje atoma Cu. Ispitivanje elektrohemijskih reakcija oksidacije metanola i mravlje kiseline na sloju smeše Pt + WC i sloju čiste Pt ukazuje da prisustvo praha WC ne utiče na elektrokatalitička svojstva Pt.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical properties of mixed WC and Pt-black powders
T1  - Elektrohemijska svojstva smeše prahova WC i Pt
EP  - 1209
IS  - 12
SP  - 1197
VL  - 73
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1305
ER  - 
@article{
author = "Obradović, Maja and Babić, Biljana M. and Kowal, Andrzej and Panić, Vladimir and Gojković, Snežana Lj.",
year = "2008",
abstract = "The electrochemical characteristics of a mixture of Pt-black and WC powders and its catalytic activity for methanol and formic acid oxidation were investigated in acid solution. XRD and AFM measurements revealed that the WC powder employed for the investigation was a single-phase material consisting of crystallites/spherical particles of average size of about 50 nm, which were agglomerated into much larger particles. Cyclic voltammetry showed that the WC underwent electrochemical oxidation, producing tungstate species. In the case of the mixed Pt + WC powders, the tungstate species were deposited on the Pt as a thin film of hydrous tungsten oxide. Enhanced hydrogen intercalation in the hydrous tungsten oxide was observed and it was proposed to be promoted in mixed powders by the presence of hydrogen adatoms on bare Pt sites. The determination of Pt surface area in the Pt + WC layer by stripping of underpotentially deposited Cu revealed that the entire Pt surface was accessible for underpotential deposition of Cu. Investigation of the electrochemical oxidation of methanol and formic acid on Pt + WC and pure Pt layers did not indicate electrocatalytic promotion due to the presence of WC., U radu su ispitivane elektrohemijske karakteristike smeše prahova Pt i WC i njena katalitička aktivnost za reakcije oksidacije metanola i mravlje kiseline u kiselom rastvoru. Analiza rezultata difrakcije X-zraka (XRD) i mikroskopije atomskih sila (AFM) pokazuju da je prah WC jednofazni materijal sa prosečnom veličinom kristalita od oko 50 nm, koji su aglomerisani u mnogo veće čestice. Ciklična voltametrija ukazuje na to da WC podleže oksidaciji kojom nastaju volframatne vrste. U slučaju smeše prahova Pt i WC, volframatne vrste najverovatnije se talože na Pt u obliku tankog sloja hidratisanih oksida volframa. Primećeno je povećanje interkalacije vodonika u sloju hidratisanih volframata i pretpostavlja se da prisustvo adatoma vodonika na površini Pt potpomaže proces vodonične interkalacije. Određivanje površine Pt u sloju Pt + WC desorpcijom monosloja Cu taloženog na potpotencijalima ukazuje da je čitava površina Pt dostupna za taloženje atoma Cu. Ispitivanje elektrohemijskih reakcija oksidacije metanola i mravlje kiseline na sloju smeše Pt + WC i sloju čiste Pt ukazuje da prisustvo praha WC ne utiče na elektrokatalitička svojstva Pt.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical properties of mixed WC and Pt-black powders, Elektrohemijska svojstva smeše prahova WC i Pt",
pages = "1209-1197",
number = "12",
volume = "73",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1305"
}
Obradović, M., Babić, B. M., Kowal, A., Panić, V.,& Gojković, S. Lj.. (2008). Electrochemical properties of mixed WC and Pt-black powders. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 73(12), 1197-1209.
https://hdl.handle.net/21.15107/rcub_technorep_1305
Obradović M, Babić BM, Kowal A, Panić V, Gojković SL. Electrochemical properties of mixed WC and Pt-black powders. in Journal of the Serbian Chemical Society. 2008;73(12):1197-1209.
https://hdl.handle.net/21.15107/rcub_technorep_1305 .
Obradović, Maja, Babić, Biljana M., Kowal, Andrzej, Panić, Vladimir, Gojković, Snežana Lj., "Electrochemical properties of mixed WC and Pt-black powders" in Journal of the Serbian Chemical Society, 73, no. 12 (2008):1197-1209,
https://hdl.handle.net/21.15107/rcub_technorep_1305 .
10
12

Photoelectrochemical properties of sol-gel obtained titanium oxide

Panić, Vladimir; Stevanović, Sanja; Mišković-Stanković, Vesna; Jovanović, Bratislav Ž.; Nikolić, Branislav Ž.

(Serbian Chemical Society, Belgrade, 2008)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Stevanović, Sanja
AU  - Mišković-Stanković, Vesna
AU  - Jovanović, Bratislav Ž.
AU  - Nikolić, Branislav Ž.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1306
AB  - The photoelectrochemical properties of a sol-gel prepared titanium oxide coating applied onto a Ti substrate were investigated. The oxide coating was formed from an inorganic sol thermally treated in air at 350°C. The coating consisted of agglomerates of narrow size distribution around 100 nm. The photoelectrochemical characteristics were evaluated by investigating the changes in the open circuit potential, current transients and impedance characteristics of a Ti/TiO2 electrode upon illumination by UV light in H2SO4 solution and in the oxidation of benzyl alcohol. The electrode was found to be active for photoelectrochemical reactions in the investigated solutions.
AB  - Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel portupkom ispitivana su na oksidnoj prevlaci nanetoj na titansku podlogu. Prevlaka je termički tretirana u vazduhu na temperaturi od 350°C. Prevlaka se sastoji od zrna ujednačene raspodele po veličini od oko 100 nm. Fotoelektrohemijske karakteristike ustanovljene su ispitivanjem promena potencijala otvorenog kola, vremenske zavisnosti struje i impedansnih karakteristika Ti/TiO2 elektrode pri osvetljenosti UV svetlošću u rastvoru H2SO4 i pri oksidaciji benzil-alkohola. Ustanovljena je fotoaktivnost elektrode u ispitivanim sistemima.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Photoelectrochemical properties of sol-gel obtained titanium oxide
T1  - Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel postupkom
EP  - 1221
IS  - 12
SP  - 1211
VL  - 73
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1306
ER  - 
@article{
author = "Panić, Vladimir and Stevanović, Sanja and Mišković-Stanković, Vesna and Jovanović, Bratislav Ž. and Nikolić, Branislav Ž.",
year = "2008",
abstract = "The photoelectrochemical properties of a sol-gel prepared titanium oxide coating applied onto a Ti substrate were investigated. The oxide coating was formed from an inorganic sol thermally treated in air at 350°C. The coating consisted of agglomerates of narrow size distribution around 100 nm. The photoelectrochemical characteristics were evaluated by investigating the changes in the open circuit potential, current transients and impedance characteristics of a Ti/TiO2 electrode upon illumination by UV light in H2SO4 solution and in the oxidation of benzyl alcohol. The electrode was found to be active for photoelectrochemical reactions in the investigated solutions., Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel portupkom ispitivana su na oksidnoj prevlaci nanetoj na titansku podlogu. Prevlaka je termički tretirana u vazduhu na temperaturi od 350°C. Prevlaka se sastoji od zrna ujednačene raspodele po veličini od oko 100 nm. Fotoelektrohemijske karakteristike ustanovljene su ispitivanjem promena potencijala otvorenog kola, vremenske zavisnosti struje i impedansnih karakteristika Ti/TiO2 elektrode pri osvetljenosti UV svetlošću u rastvoru H2SO4 i pri oksidaciji benzil-alkohola. Ustanovljena je fotoaktivnost elektrode u ispitivanim sistemima.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Photoelectrochemical properties of sol-gel obtained titanium oxide, Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel postupkom",
pages = "1221-1211",
number = "12",
volume = "73",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1306"
}
Panić, V., Stevanović, S., Mišković-Stanković, V., Jovanović, B. Ž.,& Nikolić, B. Ž.. (2008). Photoelectrochemical properties of sol-gel obtained titanium oxide. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 73(12), 1211-1221.
https://hdl.handle.net/21.15107/rcub_technorep_1306
Panić V, Stevanović S, Mišković-Stanković V, Jovanović BŽ, Nikolić BŽ. Photoelectrochemical properties of sol-gel obtained titanium oxide. in Journal of the Serbian Chemical Society. 2008;73(12):1211-1221.
https://hdl.handle.net/21.15107/rcub_technorep_1306 .
Panić, Vladimir, Stevanović, Sanja, Mišković-Stanković, Vesna, Jovanović, Bratislav Ž., Nikolić, Branislav Ž., "Photoelectrochemical properties of sol-gel obtained titanium oxide" in Journal of the Serbian Chemical Society, 73, no. 12 (2008):1211-1221,
https://hdl.handle.net/21.15107/rcub_technorep_1306 .
1
1

Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure

Panić, Vladimir; Vidaković, Tanja; Dekanski, Aleksandar; Mišković-Stanković, Vesna; Nikolić, B.Z.

(Elsevier Science Sa, Lausanne, 2007)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković, Tanja
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B.Z.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1137
AB  - The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different masses of coating (thin and thick coating) were prepared from an ink suspension of the oxide synthesized by hydrolysis of ruthenium-ethoxide in ethanolic solution. The capacitive characteristics were found to be dependent on the coating mass and the electrolyte composition. It was shown that the impedance data of the prepared electrodes, registered at the open circuit potential, can be interpreted by a transmission line model of the equivalent electrical circuit. In this interpretation, the number of parallel branches containing resistor and capacitor in series is different for thin and thick coatings and in different electrolytes. More branches were required to describe the impedance behavior of the thick coating and to simulate the impedance data in NaCl solution. Simulation of the impedance data with the transmission line model of the equivalent circuit was also used to analyze the distribution of capacitance throughout the porous coating. The simulation indicated a more pronounced contribution of the capacitance of the outer coating layer to the total coating capacitance in the case of the proton-rich electrolyte. On the other hand, the presence of chloride ions in the electrolyte promoted a charging process at the inner coating surface, which is hardly accessible to the electrolyte.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Electroanalytical Chemistry
T1  - Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure
EP  - 128
IS  - 2
SP  - 120
VL  - 609
DO  - 10.1016/j.jelechem.2007.06.011
ER  - 
@article{
author = "Panić, Vladimir and Vidaković, Tanja and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Nikolić, B.Z.",
year = "2007",
abstract = "The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different masses of coating (thin and thick coating) were prepared from an ink suspension of the oxide synthesized by hydrolysis of ruthenium-ethoxide in ethanolic solution. The capacitive characteristics were found to be dependent on the coating mass and the electrolyte composition. It was shown that the impedance data of the prepared electrodes, registered at the open circuit potential, can be interpreted by a transmission line model of the equivalent electrical circuit. In this interpretation, the number of parallel branches containing resistor and capacitor in series is different for thin and thick coatings and in different electrolytes. More branches were required to describe the impedance behavior of the thick coating and to simulate the impedance data in NaCl solution. Simulation of the impedance data with the transmission line model of the equivalent circuit was also used to analyze the distribution of capacitance throughout the porous coating. The simulation indicated a more pronounced contribution of the capacitance of the outer coating layer to the total coating capacitance in the case of the proton-rich electrolyte. On the other hand, the presence of chloride ions in the electrolyte promoted a charging process at the inner coating surface, which is hardly accessible to the electrolyte.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Electroanalytical Chemistry",
title = "Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure",
pages = "128-120",
number = "2",
volume = "609",
doi = "10.1016/j.jelechem.2007.06.011"
}
Panić, V., Vidaković, T., Dekanski, A., Mišković-Stanković, V.,& Nikolić, B.Z.. (2007). Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure. in Journal of Electroanalytical Chemistry
Elsevier Science Sa, Lausanne., 609(2), 120-128.
https://doi.org/10.1016/j.jelechem.2007.06.011
Panić V, Vidaković T, Dekanski A, Mišković-Stanković V, Nikolić B. Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure. in Journal of Electroanalytical Chemistry. 2007;609(2):120-128.
doi:10.1016/j.jelechem.2007.06.011 .
Panić, Vladimir, Vidaković, Tanja, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Nikolić, B.Z., "Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure" in Journal of Electroanalytical Chemistry, 609, no. 2 (2007):120-128,
https://doi.org/10.1016/j.jelechem.2007.06.011 . .
19
23
24

Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route

Panić, Vladimir; Dekanski, Aleksandar; Milonjić, Slobodan K.; Mišković-Stanković, Vesna; Nikolić, Branislav

(Serbian Chemical Society, Belgrade, 2006)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, Branislav
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/946
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
AB  - Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
T1  - Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom
EP  - 1186
IS  - 11
SP  - 1173
VL  - 71
UR  - https://hdl.handle.net/21.15107/rcub_technorep_946
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, Branislav",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass., Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route, Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom",
pages = "1186-1173",
number = "11",
volume = "71",
url = "https://hdl.handle.net/21.15107/rcub_technorep_946"
}
Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 71(11), 1173-1186.
https://hdl.handle.net/21.15107/rcub_technorep_946
Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić B. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
https://hdl.handle.net/21.15107/rcub_technorep_946 .
Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, Branislav, "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://hdl.handle.net/21.15107/rcub_technorep_946 .
8
8