TY  - CONF
AU  - Zdravković, Jelena D.
AU  - Radovanović, Lidija
AU  - Poleti, Dejan
AU  - Rogan, Jelena
AU  - Mészásaros Szécsényi, Katalin
AU  - Vulić, Predrag J.
AU  - Minić, Dragica M.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6702
AB  - The design and synthesis of various mixed ligand complexes with amazing architecture and
topology are promoted due to their potential applications as functional materials in fields such as
gas storage, chemical separation, catalysis and luminescence [1].
The structural diversity and properties of these materials strongly depend on the organic Odonor ligand. For example, dianion of isophthalic (ipht) acid is widely used as ligand due to its
ability to coordinate up to four metal centres with different coordination modes. The addition of Ndonor ligands significantly contributes to their structural versatility increasing their thermal stability
[2].
There are only three ipht complexes containing dipya (2,2’-dipyridylamine) as N-donor
ligand recently published: [Cu(dipya)(ipht)]·H2O [2, 3], [Mn(dipya)(ipht)]n [4] and
[Zn(dipya)(ipht)]n [5]. The highest thermal stability was observed for [Zn(dipya)(ipht)]n. In
addition, [Zn(dipya)(ipht)]n exhibits also a great antibacterial activity [4].
The decomposition of [Zn(dipya)(ipht)]n was studied in detail using simultaneous TG/DSC
analysis in conjunction with TG/MS measurements and XRPD analysis in nitrogen atmosphere
under non-isothermal conditions at four heating rates: 15, 20, 25 and 30 ºC min−1
. The first two
decomposition steps are highly overlapped and for that reason the peak deconvolution using FraserSuzuki function was employed. The deconvolution was performed at each heating rate and the three
single step processes were isolated. The application of isoconversional method confirmed that
deconvoluted steps are individual processes while the determination of conversion functions was
done according to the Màlek algorithm [6]. The third degradation step ends around 970 ºC,
depending on the heating rate, yielding ZnO.
PB  - Central and Eastern European Committee for Thermal Analysis and Calorimetry
C3  - Book of abstracts / 4th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC4), 28-31 August 2017, Chişinău, Moldova
T1  - Non-isothermal degradation of zinc–isophthalate complex with 2,2’-dipyridylamine
SP  - 209
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6702
ER  - 

@conference{
author = "Zdravković, Jelena D. and Radovanović, Lidija and Poleti, Dejan and Rogan, Jelena and Mészásaros Szécsényi, Katalin and Vulić, Predrag J. and Minić, Dragica M.",
year = "2017",
abstract = "The design and synthesis of various mixed ligand complexes with amazing architecture and
topology are promoted due to their potential applications as functional materials in fields such as
gas storage, chemical separation, catalysis and luminescence [1].
The structural diversity and properties of these materials strongly depend on the organic Odonor ligand. For example, dianion of isophthalic (ipht) acid is widely used as ligand due to its
ability to coordinate up to four metal centres with different coordination modes. The addition of Ndonor ligands significantly contributes to their structural versatility increasing their thermal stability
[2].
There are only three ipht complexes containing dipya (2,2’-dipyridylamine) as N-donor
ligand recently published: [Cu(dipya)(ipht)]·H2O [2, 3], [Mn(dipya)(ipht)]n [4] and
[Zn(dipya)(ipht)]n [5]. The highest thermal stability was observed for [Zn(dipya)(ipht)]n. In
addition, [Zn(dipya)(ipht)]n exhibits also a great antibacterial activity [4].
The decomposition of [Zn(dipya)(ipht)]n was studied in detail using simultaneous TG/DSC
analysis in conjunction with TG/MS measurements and XRPD analysis in nitrogen atmosphere
under non-isothermal conditions at four heating rates: 15, 20, 25 and 30 ºC min−1
. The first two
decomposition steps are highly overlapped and for that reason the peak deconvolution using FraserSuzuki function was employed. The deconvolution was performed at each heating rate and the three
single step processes were isolated. The application of isoconversional method confirmed that
deconvoluted steps are individual processes while the determination of conversion functions was
done according to the Màlek algorithm [6]. The third degradation step ends around 970 ºC,
depending on the heating rate, yielding ZnO.",
publisher = "Central and Eastern European Committee for Thermal Analysis and Calorimetry",
journal = "Book of abstracts / 4th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC4), 28-31 August 2017, Chişinău, Moldova",
title = "Non-isothermal degradation of zinc–isophthalate complex with 2,2’-dipyridylamine",
pages = "209",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6702"
}

Zdravković, J. D., Radovanović, L., Poleti, D., Rogan, J., Mészásaros Szécsényi, K., Vulić, P. J.,& Minić, D. M.. (2017). Non-isothermal degradation of zinc–isophthalate complex with 2,2’-dipyridylamine. in Book of abstracts / 4th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC4), 28-31 August 2017, Chişinău, Moldova
Central and Eastern European Committee for Thermal Analysis and Calorimetry., 209.
https://hdl.handle.net/21.15107/rcub_technorep_6702

Zdravković JD, Radovanović L, Poleti D, Rogan J, Mészásaros Szécsényi K, Vulić PJ, Minić DM. Non-isothermal degradation of zinc–isophthalate complex with 2,2’-dipyridylamine. in Book of abstracts / 4th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC4), 28-31 August 2017, Chişinău, Moldova. 2017;:209.
https://hdl.handle.net/21.15107/rcub_technorep_6702 .

Zdravković, Jelena D., Radovanović, Lidija, Poleti, Dejan, Rogan, Jelena, Mészásaros Szécsényi, Katalin, Vulić, Predrag J., Minić, Dragica M., "Non-isothermal degradation of zinc–isophthalate complex with 2,2’-dipyridylamine" in Book of abstracts / 4th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC4), 28-31 August 2017, Chişinău, Moldova (2017):209,
https://hdl.handle.net/21.15107/rcub_technorep_6702 .