Todorović, Milica D.

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  • Todorović, Milica D. (13)
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Author's Bibliography

Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219)

Popović, Daniela; Miladinović, Jelena; Todorović, Milica D.; Miladinović, Zoran P.

(Pleiades Publishing, 2023)

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Miladinović, Zoran P.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6597
AB  - The title of the article should read as follows: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K.
PB  - Pleiades Publishing
T2  - Russian Journal of Physical Chemistry A
T1  - Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219)
IS  - 6
SP  - 1344
VL  - 97
DO  - 10.1134/S0036024423340010
ER  - 
@article{
author = "Popović, Daniela and Miladinović, Jelena and Todorović, Milica D. and Miladinović, Zoran P.",
year = "2023",
abstract = "The title of the article should read as follows: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K.",
publisher = "Pleiades Publishing",
journal = "Russian Journal of Physical Chemistry A",
title = "Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219)",
number = "6",
pages = "1344",
volume = "97",
doi = "10.1134/S0036024423340010"
}
Popović, D., Miladinović, J., Todorović, M. D.,& Miladinović, Z. P.. (2023). Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219). in Russian Journal of Physical Chemistry A
Pleiades Publishing., 97(6), 1344.
https://doi.org/10.1134/S0036024423340010
Popović D, Miladinović J, Todorović MD, Miladinović ZP. Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219). in Russian Journal of Physical Chemistry A. 2023;97(6):1344.
doi:10.1134/S0036024423340010 .
Popović, Daniela, Miladinović, Jelena, Todorović, Milica D., Miladinović, Zoran P., "Erratum to: Solubility in K+–Na+–Mg (2+)– SO (4) (2-) Aqueous Solution at T = 298.15 K (Russian Journal of Physical Chemistry A, (2013), 87, 13, (2181-2186), 10.1134/S0036024413130219)" in Russian Journal of Physical Chemistry A, 97, no. 6 (2023):1344,
https://doi.org/10.1134/S0036024423340010 . .

Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K

Popović, Daniela; Miladinović, Jelena; Miladinović, Zoran P.; Grujić, Snežana; Todorović, Milica D.; Rard, Joseph A.

(Academic Press Ltd- Elsevier Science Ltd, London, 2013)

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran P.
AU  - Grujić, Snežana
AU  - Todorović, Milica D.
AU  - Rard, Joseph A.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2532
AB  - The molality-based osmotic coefficients of aqueous mixtures of KBr and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method at KBr ionic strength fractions y = (0.18328, 0.38241, 0.58031, 0.79186, and 1) and over the ionic strength range (2.5452 to 10.0418) mol . kg (-1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These experiments were performed using glass sample dishes because preliminary experiments showed that some corrosion of our usual gold-plated silver dishes occurred with dissolution of silver, presumably by "pinhole" corrosion at imperfections in the gold layer. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. The present assessment yields mixing parameters for these models. Model parameters for KBr(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with four sets of osmotic coefficients taken from the published literature. For the {yKBr + (1 -y)K2HPO4}(aq) system, the model with five Scatchard mixing terms gave a significantly better representation of the osmotic coefficients than any of the other models and is therefore recommended for calculation of osmotic and activity coefficients.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K
EP  - 161
SP  - 151
VL  - 62
DO  - 10.1016/j.jct.2013.03.003
ER  - 
@article{
author = "Popović, Daniela and Miladinović, Jelena and Miladinović, Zoran P. and Grujić, Snežana and Todorović, Milica D. and Rard, Joseph A.",
year = "2013",
abstract = "The molality-based osmotic coefficients of aqueous mixtures of KBr and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic method at KBr ionic strength fractions y = (0.18328, 0.38241, 0.58031, 0.79186, and 1) and over the ionic strength range (2.5452 to 10.0418) mol . kg (-1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These experiments were performed using glass sample dishes because preliminary experiments showed that some corrosion of our usual gold-plated silver dishes occurred with dissolution of silver, presumably by "pinhole" corrosion at imperfections in the gold layer. These osmotic coefficients were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for this ternary system. The present assessment yields mixing parameters for these models. Model parameters for KBr(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with four sets of osmotic coefficients taken from the published literature. For the {yKBr + (1 -y)K2HPO4}(aq) system, the model with five Scatchard mixing terms gave a significantly better representation of the osmotic coefficients than any of the other models and is therefore recommended for calculation of osmotic and activity coefficients.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K",
pages = "161-151",
volume = "62",
doi = "10.1016/j.jct.2013.03.003"
}
Popović, D., Miladinović, J., Miladinović, Z. P., Grujić, S., Todorović, M. D.,& Rard, J. A.. (2013). Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 62, 151-161.
https://doi.org/10.1016/j.jct.2013.03.003
Popović D, Miladinović J, Miladinović ZP, Grujić S, Todorović MD, Rard JA. Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2013;62:151-161.
doi:10.1016/j.jct.2013.03.003 .
Popović, Daniela, Miladinović, Jelena, Miladinović, Zoran P., Grujić, Snežana, Todorović, Milica D., Rard, Joseph A., "Isopiestic determination of the osmotic and activity coefficients of the {yKBr + (1-y)K2HPO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 62 (2013):151-161,
https://doi.org/10.1016/j.jct.2013.03.003 . .
15
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Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K

Popović, Daniela; Miladinović, Jelena; Miladinović, Zoran P.; Ivošević, Branislav; Todorović, Milica D.; Rard, Joseph A.

(Academic Press Ltd- Elsevier Science Ltd, London, 2012)

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran P.
AU  - Ivošević, Branislav
AU  - Todorović, Milica D.
AU  - Rard, Joseph A.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2112
AB  - The osmotic coefficients of aqueous mixtures of KNO3 and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic vapor pressure method at KNO3 ionic strength fractions y = (0.20581, 0.43631, 0.61099, and 0.83170), over the ionic strength range (2.4958 to 6.0801) mol.kg (1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These measurements include some new isopiestic results for the KNO3(aq) binary system extending slightly into the oversaturated (supersaturated) molality region from (2.1973 to 4.1295) mol.kg (1). Our new experimental results were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for the {yKNO(3) + (1 - y)K2HPO4}(aq) system. The present assessment yields NO3 - HPO42 mixing parameters for these models that are needed for modeling the thermodynamic activities of solute components of natural waters and other complex aqueous electrolyte mixtures. Model parameters for KNO3(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with critically-assessed osmotic coefficients taken from the published literature. Thermodynamic properties of the saturated solution were calculated using published solubilities of KNO3(cr) in water at T = 298.15 K and the evaluated ion-interaction model parameters for KNO3(aq).
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K
EP  - 183
SP  - 172
VL  - 55
DO  - 10.1016/j.jct.2012.06.027
ER  - 
@article{
author = "Popović, Daniela and Miladinović, Jelena and Miladinović, Zoran P. and Ivošević, Branislav and Todorović, Milica D. and Rard, Joseph A.",
year = "2012",
abstract = "The osmotic coefficients of aqueous mixtures of KNO3 and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic vapor pressure method at KNO3 ionic strength fractions y = (0.20581, 0.43631, 0.61099, and 0.83170), over the ionic strength range (2.4958 to 6.0801) mol.kg (1), using KCl(aq) and CaCl2(aq) as the reference standard solutions. These measurements include some new isopiestic results for the KNO3(aq) binary system extending slightly into the oversaturated (supersaturated) molality region from (2.1973 to 4.1295) mol.kg (1). Our new experimental results were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual Pitzer mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There are no previously published isopiestic measurements for the {yKNO(3) + (1 - y)K2HPO4}(aq) system. The present assessment yields NO3 - HPO42 mixing parameters for these models that are needed for modeling the thermodynamic activities of solute components of natural waters and other complex aqueous electrolyte mixtures. Model parameters for KNO3(aq) at T = (298.15 +/- 0.01) K were also evaluated using the present results along with critically-assessed osmotic coefficients taken from the published literature. Thermodynamic properties of the saturated solution were calculated using published solubilities of KNO3(cr) in water at T = 298.15 K and the evaluated ion-interaction model parameters for KNO3(aq).",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K",
pages = "183-172",
volume = "55",
doi = "10.1016/j.jct.2012.06.027"
}
Popović, D., Miladinović, J., Miladinović, Z. P., Ivošević, B., Todorović, M. D.,& Rard, J. A.. (2012). Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 55, 172-183.
https://doi.org/10.1016/j.jct.2012.06.027
Popović D, Miladinović J, Miladinović ZP, Ivošević B, Todorović MD, Rard JA. Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2012;55:172-183.
doi:10.1016/j.jct.2012.06.027 .
Popović, Daniela, Miladinović, Jelena, Miladinović, Zoran P., Ivošević, Branislav, Todorović, Milica D., Rard, Joseph A., "Isopiestic determination of the osmotic and activity coefficients of the {yKNO(3) + (1-y)K2HPO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 55 (2012):172-183,
https://doi.org/10.1016/j.jct.2012.06.027 . .
18
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17

Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K

Popović, Daniela; Miladinović, Jelena; Todorović, Milica D.; Zrilić, Milorad; Rard, Joseph A.

(Academic Press Ltd- Elsevier Science Ltd, London, 2011)

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Zrilić, Milorad
AU  - Rard, Joseph A.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1872
AB  - The osmotic coefficients of aqueous mixtures of KCl and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic vapor pressure method over the range of ionic strengths from (2.3700 to 11.250) mol . kg(-1) using CaCl2(aq) as the reference solution. Our new experimental results were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There is a dearth of previously published isopiestic data for mixtures containing salts of HPO42- (aq) and, consequently, no previous measurements are available for comparison with the present results. The present study yields Cl--HPO42- mixing parameters for these three models that are needed for modeling the thermodynamic activities of solute components of natural waters and other complex aqueous electrolyte mixtures.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K
EP  - 1885
IS  - 12
SP  - 1877
VL  - 43
DO  - 10.1016/j.jct.2011.06.017
ER  - 
@article{
author = "Popović, Daniela and Miladinović, Jelena and Todorović, Milica D. and Zrilić, Milorad and Rard, Joseph A.",
year = "2011",
abstract = "The osmotic coefficients of aqueous mixtures of KCl and K2HPO4 have been measured at T = (298.15 +/- 0.01) K by the isopiestic vapor pressure method over the range of ionic strengths from (2.3700 to 11.250) mol . kg(-1) using CaCl2(aq) as the reference solution. Our new experimental results were modeled with an extended form of Pitzer's ion-interaction model equations, both with the usual mixing terms and with Scatchard's neutral-electrolyte mixing terms, and with the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale. There is a dearth of previously published isopiestic data for mixtures containing salts of HPO42- (aq) and, consequently, no previous measurements are available for comparison with the present results. The present study yields Cl--HPO42- mixing parameters for these three models that are needed for modeling the thermodynamic activities of solute components of natural waters and other complex aqueous electrolyte mixtures.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K",
pages = "1885-1877",
number = "12",
volume = "43",
doi = "10.1016/j.jct.2011.06.017"
}
Popović, D., Miladinović, J., Todorović, M. D., Zrilić, M.,& Rard, J. A.. (2011). Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 43(12), 1877-1885.
https://doi.org/10.1016/j.jct.2011.06.017
Popović D, Miladinović J, Todorović MD, Zrilić M, Rard JA. Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2011;43(12):1877-1885.
doi:10.1016/j.jct.2011.06.017 .
Popović, Daniela, Miladinović, Jelena, Todorović, Milica D., Zrilić, Milorad, Rard, Joseph A., "Isopiestic determination of the osmotic and activity coefficients of the {yKCl + (1-y)K2HPO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 43, no. 12 (2011):1877-1885,
https://doi.org/10.1016/j.jct.2011.06.017 . .
18
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18

Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K

Popović, Daniela; Miladinović, Jelena; Todorović, Milica D.; Zrilić, Milorad; Rard, Joseph A.

(Springer/Plenum Publishers, New York, 2011)

TY  - JOUR
AU  - Popović, Daniela
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Zrilić, Milorad
AU  - Rard, Joseph A.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1964
AB  - The osmotic coefficients of K2HPO4(aq) have been measured at T=298.15 K by the isopiestic vapor pressure method over the range of molalities from 1.3846 mola  lt ...kg(-1) to 13.939 mola  lt ...kg(-1) (oversaturation) with CaCl2(aq) as the reference solution. The molalities and osmotic coefficients of saturated solutions in equilibrium with K(2)HPO(4)a  lt ...xH(2)O(cr) were measured simultaneously by the same method. Available literature osmotic coefficients of K2HPO4(aq) at T=298.15 K, and our new experimental data, were combined and modeled using an extended form of Pitzer's equation and the Clegg-Pitzer-Brimblecombe equation based on the mole-fraction-composition scale. These equations were used to calculate the activity coefficients of K2HPO4(aq) at T=298.15 K.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K
EP  - 920
IS  - 5
SP  - 907
VL  - 40
DO  - 10.1007/s10953-011-9650-1
ER  - 
@article{
author = "Popović, Daniela and Miladinović, Jelena and Todorović, Milica D. and Zrilić, Milorad and Rard, Joseph A.",
year = "2011",
abstract = "The osmotic coefficients of K2HPO4(aq) have been measured at T=298.15 K by the isopiestic vapor pressure method over the range of molalities from 1.3846 mola  lt ...kg(-1) to 13.939 mola  lt ...kg(-1) (oversaturation) with CaCl2(aq) as the reference solution. The molalities and osmotic coefficients of saturated solutions in equilibrium with K(2)HPO(4)a  lt ...xH(2)O(cr) were measured simultaneously by the same method. Available literature osmotic coefficients of K2HPO4(aq) at T=298.15 K, and our new experimental data, were combined and modeled using an extended form of Pitzer's equation and the Clegg-Pitzer-Brimblecombe equation based on the mole-fraction-composition scale. These equations were used to calculate the activity coefficients of K2HPO4(aq) at T=298.15 K.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K",
pages = "920-907",
number = "5",
volume = "40",
doi = "10.1007/s10953-011-9650-1"
}
Popović, D., Miladinović, J., Todorović, M. D., Zrilić, M.,& Rard, J. A.. (2011). Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 40(5), 907-920.
https://doi.org/10.1007/s10953-011-9650-1
Popović D, Miladinović J, Todorović MD, Zrilić M, Rard JA. Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K. in Journal of Solution Chemistry. 2011;40(5):907-920.
doi:10.1007/s10953-011-9650-1 .
Popović, Daniela, Miladinović, Jelena, Todorović, Milica D., Zrilić, Milorad, Rard, Joseph A., "Isopiestic Determination of the Osmotic and Activity Coefficients of K2HPO4(aq), Including Saturated and Supersaturated Solutions, at T=298.15 K" in Journal of Solution Chemistry, 40, no. 5 (2011):907-920,
https://doi.org/10.1007/s10953-011-9650-1 . .
21
15
20

Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007)

Miladinović, Jelena; Ninković, Rozalija; Todorović, Milica D.

(Springer/Plenum Publishers, New York, 2011)

TY  - JOUR
AU  - Miladinović, Jelena
AU  - Ninković, Rozalija
AU  - Todorović, Milica D.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1938
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007)
EP  - 1154
IS  - 6
SP  - 1153
VL  - 40
DO  - 10.1007/s10953-011-9707-1
ER  - 
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica D.",
year = "2011",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007)",
pages = "1154-1153",
number = "6",
volume = "40",
doi = "10.1007/s10953-011-9707-1"
}
Miladinović, J., Ninković, R.,& Todorović, M. D.. (2011). Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007). in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 40(6), 1153-1154.
https://doi.org/10.1007/s10953-011-9707-1
Miladinović J, Ninković R, Todorović MD. Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007). in Journal of Solution Chemistry. 2011;40(6):1153-1154.
doi:10.1007/s10953-011-9707-1 .
Miladinović, Jelena, Ninković, Rozalija, Todorović, Milica D., "Osmotic and Activity Coefficients of {yKCl+(1-y)MgCl2}(aq) at T = 298.15 K (vol 36, pg 1401, 2007)" in Journal of Solution Chemistry, 40, no. 6 (2011):1153-1154,
https://doi.org/10.1007/s10953-011-9707-1 . .

Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K

Miladinović, Jelena; Todorović, Milica D.; Ninković, Rozalija

(Amer Chemical Soc, Washington, 2009)

TY  - JOUR
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Ninković, Rozalija
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1499
AB  - Isopiestic vapor pressure measurements were made for {yZnCl(2) + (1 - y)ZnSO4}(aq) solutions with ZnCl2 ionic strength fractions of y = (0.2640, 0.5042, 0.7533, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. To investigate the influence of hydrolysis on the osmotic coefficients of {yZnCl(2) + (1 - y)ZnSO4}(aq), the ZnCl2(aq) stock solution was prepared without acidification and supression of hydrolysis. Thus obtained osmotic coefficients of the system {yZnCl(2) + (1 - y)ZnSO4}(aq) at the temperature 298.15 K were compared with the previously published results of the isopiestic measurements for the same system with ZnCl2(aq) stock solution that was acidified to avoid precipitation of zinc hydroxide or a hydrous oxy-chloride or hydroxy-chloride, upon dilution. This way the effects of hydrolysis on the osmotic coefficient values for the system {yZnCl(2) + (1 - y)ZnSO4}(aq) could be compared and analyzed.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K
EP  - 530
IS  - 2
SP  - 526
VL  - 54
DO  - 10.1021/je800487w
ER  - 
@article{
author = "Miladinović, Jelena and Todorović, Milica D. and Ninković, Rozalija",
year = "2009",
abstract = "Isopiestic vapor pressure measurements were made for {yZnCl(2) + (1 - y)ZnSO4}(aq) solutions with ZnCl2 ionic strength fractions of y = (0.2640, 0.5042, 0.7533, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. To investigate the influence of hydrolysis on the osmotic coefficients of {yZnCl(2) + (1 - y)ZnSO4}(aq), the ZnCl2(aq) stock solution was prepared without acidification and supression of hydrolysis. Thus obtained osmotic coefficients of the system {yZnCl(2) + (1 - y)ZnSO4}(aq) at the temperature 298.15 K were compared with the previously published results of the isopiestic measurements for the same system with ZnCl2(aq) stock solution that was acidified to avoid precipitation of zinc hydroxide or a hydrous oxy-chloride or hydroxy-chloride, upon dilution. This way the effects of hydrolysis on the osmotic coefficient values for the system {yZnCl(2) + (1 - y)ZnSO4}(aq) could be compared and analyzed.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K",
pages = "530-526",
number = "2",
volume = "54",
doi = "10.1021/je800487w"
}
Miladinović, J., Todorović, M. D.,& Ninković, R.. (2009). Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 54(2), 526-530.
https://doi.org/10.1021/je800487w
Miladinović J, Todorović MD, Ninković R. Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K. in Journal of Chemical and Engineering Data. 2009;54(2):526-530.
doi:10.1021/je800487w .
Miladinović, Jelena, Todorović, Milica D., Ninković, Rozalija, "Influence of Hydrolysis on the Osmotic Coefficients of the System {yZnCl(2) + (1-y)ZnSO4}(aq) at Temperature 298.15 K" in Journal of Chemical and Engineering Data, 54, no. 2 (2009):526-530,
https://doi.org/10.1021/je800487w . .

Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K

Miladinović, Jelena; Ninković, Rozalija; Todorović, Milica D.; Rard, Joseph A.

(Springer/Plenum Publishers, New York, 2008)

TY  - JOUR
AU  - Miladinović, Jelena
AU  - Ninković, Rozalija
AU  - Todorović, Milica D.
AU  - Rard, Joseph A.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1262
AB  - Isopiestic vapor-pressure measurements were made for {yMgCl(2) + (1-y)MgSO4}(aq) solutions with MgCl2 ionic strength fractions of y = (0,0.1997,0.3989,0.5992,0.8008, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements for the mixtures cover the ionic strength range I=0.9794 to 9.4318 mol.kg(-1). In addition, isopiestic measurements were made with NaCl(aq) as reference standard for mixtures of {xNa(2)SO(4) + (1-x)MgSO4}(aq) with the molality fraction x = 0.5000 that correspond to solutions of the evaporite mineral bloedite (astrakanite), Na2Mg(SO4)(2).4H(2)O(cr). The total molalities, m (T)=m(Na2SO4) + m(MgSO4), range from m(T) = 1.4479 to 4.4312 mol.kg(-1) (I=5.0677 to 15.509 mol.kg(-1)), where the uppermost concentration is the highest oversaturation molality that could be achieved by isothermal evaporation of the solvent at 298.15 K. The parameters of an extended ion-interaction (Pitzer) model for MgCl2(aq) at 298.15 K, which were required for an analysis of the {yMgCl(2) + (1-y)MgSO4}(aq) mixture results, were evaluated up to I=12.075 mol.kg(-1) from published isopiestic data together with the six new osmotic coefficients obtained in this study. Osmotic coefficients of {yMgCl(2) + (1-y)MgSO4}(aq) solutions from the present study, along with critically-assessed values from previous studies, were used to evaluate the mixing parameters of the extended ion-interaction model.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K
EP  - 329
IS  - 3
SP  - 307
VL  - 37
DO  - 10.1007/s10953-007-9238-y
ER  - 
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica D. and Rard, Joseph A.",
year = "2008",
abstract = "Isopiestic vapor-pressure measurements were made for {yMgCl(2) + (1-y)MgSO4}(aq) solutions with MgCl2 ionic strength fractions of y = (0,0.1997,0.3989,0.5992,0.8008, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements for the mixtures cover the ionic strength range I=0.9794 to 9.4318 mol.kg(-1). In addition, isopiestic measurements were made with NaCl(aq) as reference standard for mixtures of {xNa(2)SO(4) + (1-x)MgSO4}(aq) with the molality fraction x = 0.5000 that correspond to solutions of the evaporite mineral bloedite (astrakanite), Na2Mg(SO4)(2).4H(2)O(cr). The total molalities, m (T)=m(Na2SO4) + m(MgSO4), range from m(T) = 1.4479 to 4.4312 mol.kg(-1) (I=5.0677 to 15.509 mol.kg(-1)), where the uppermost concentration is the highest oversaturation molality that could be achieved by isothermal evaporation of the solvent at 298.15 K. The parameters of an extended ion-interaction (Pitzer) model for MgCl2(aq) at 298.15 K, which were required for an analysis of the {yMgCl(2) + (1-y)MgSO4}(aq) mixture results, were evaluated up to I=12.075 mol.kg(-1) from published isopiestic data together with the six new osmotic coefficients obtained in this study. Osmotic coefficients of {yMgCl(2) + (1-y)MgSO4}(aq) solutions from the present study, along with critically-assessed values from previous studies, were used to evaluate the mixing parameters of the extended ion-interaction model.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K",
pages = "329-307",
number = "3",
volume = "37",
doi = "10.1007/s10953-007-9238-y"
}
Miladinović, J., Ninković, R., Todorović, M. D.,& Rard, J. A.. (2008). Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 37(3), 307-329.
https://doi.org/10.1007/s10953-007-9238-y
Miladinović J, Ninković R, Todorović MD, Rard JA. Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K. in Journal of Solution Chemistry. 2008;37(3):307-329.
doi:10.1007/s10953-007-9238-y .
Miladinović, Jelena, Ninković, Rozalija, Todorović, Milica D., Rard, Joseph A., "Isopiestic investigation of the osmotic and activity coefficients of {yMgCl(2)+(1-y)MgSO4}(aq) and the osmotic coefficients of Na2SO4 center dot MgSO4(aq) at 298.15 K" in Journal of Solution Chemistry, 37, no. 3 (2008):307-329,
https://doi.org/10.1007/s10953-007-9238-y . .
14
12
14

Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K

Ninković, Rozalija; Miladinović, Jelena; Todorović, Milica D.; Grujić, Snežana; Rard, Joseph A.

(Springer/Plenum Publishers, New York, 2007)

TY  - JOUR
AU  - Ninković, Rozalija
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Grujić, Snežana
AU  - Rard, Joseph A.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1089
AB  - Isopiestic vapor pressure measurements were made for {xZnCl(2)+(1-x)ZnSO4}(aq) solutions with ZnCl2 molality fractions of x=(0,0.3062,0.5730,0.7969, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements cover the water activity range 0.901-0.919  lt = a(w)  lt = 0.978. The experimental osmotic coefficients were used to evaluate the parameters of an extended ion-interaction (Pitzer) model for these mixed electrolyte solutions. A similar analysis was made of the available activity data for ZnCl2(aq) at 298.15 K, while assuming the presence of equilibrium amounts of ZnCl+(aq) ion-pairs, to derive the ion-interaction parameters for the hypothetical pure binary electrolytes (Zn2+,2Cl(-)) and (ZnCl+,Cl-). These parameters are required for the analysis of the mixture results. Although significant concentrations of higher-order zinc chloride complexes may also be present in these solutions, it was possible to represent the osmotic coefficients accurately by explicitly including only the predominant complex ZnCl+(aq) and the completely dissociated ions. The ionic activity coefficients and osmotic coefficients were calculated over the investigated molality range using the evaluated extended Pitzer model parameters.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K
EP  - 435
IS  - 4
SP  - 405
VL  - 36
DO  - 10.1007/s10953-007-9128-3
ER  - 
@article{
author = "Ninković, Rozalija and Miladinović, Jelena and Todorović, Milica D. and Grujić, Snežana and Rard, Joseph A.",
year = "2007",
abstract = "Isopiestic vapor pressure measurements were made for {xZnCl(2)+(1-x)ZnSO4}(aq) solutions with ZnCl2 molality fractions of x=(0,0.3062,0.5730,0.7969, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements cover the water activity range 0.901-0.919  lt = a(w)  lt = 0.978. The experimental osmotic coefficients were used to evaluate the parameters of an extended ion-interaction (Pitzer) model for these mixed electrolyte solutions. A similar analysis was made of the available activity data for ZnCl2(aq) at 298.15 K, while assuming the presence of equilibrium amounts of ZnCl+(aq) ion-pairs, to derive the ion-interaction parameters for the hypothetical pure binary electrolytes (Zn2+,2Cl(-)) and (ZnCl+,Cl-). These parameters are required for the analysis of the mixture results. Although significant concentrations of higher-order zinc chloride complexes may also be present in these solutions, it was possible to represent the osmotic coefficients accurately by explicitly including only the predominant complex ZnCl+(aq) and the completely dissociated ions. The ionic activity coefficients and osmotic coefficients were calculated over the investigated molality range using the evaluated extended Pitzer model parameters.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K",
pages = "435-405",
number = "4",
volume = "36",
doi = "10.1007/s10953-007-9128-3"
}
Ninković, R., Miladinović, J., Todorović, M. D., Grujić, S.,& Rard, J. A.. (2007). Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 36(4), 405-435.
https://doi.org/10.1007/s10953-007-9128-3
Ninković R, Miladinović J, Todorović MD, Grujić S, Rard JA. Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K. in Journal of Solution Chemistry. 2007;36(4):405-435.
doi:10.1007/s10953-007-9128-3 .
Ninković, Rozalija, Miladinović, Jelena, Todorović, Milica D., Grujić, Snežana, Rard, Joseph A., "Osmotic and activity coefficients of the {xZnCl(2)+(1-x)ZnSO4}(aq) system at 298.15 K" in Journal of Solution Chemistry, 36, no. 4 (2007):405-435,
https://doi.org/10.1007/s10953-007-9128-3 . .
11
10
11

Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k

Miladinović, Jelena; Ninković, Rozalija; Todorović, Milica D.

(Springer/Plenum Publishers, New York, 2007)

TY  - JOUR
AU  - Miladinović, Jelena
AU  - Ninković, Rozalija
AU  - Todorović, Milica D.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1143
AB  - Isopiestic vapor-pressure measurements were made at the temperature 298.15 K for aqueous KCl + MgCl2 solutions using KCl(aq) as the reference standard. The measurements for these ternary solutions were made at KCl ionic strength fractions of y=0.0, 0.1989, 0.3996, 0.5993, 0.7925 and 1.0 (with two additional sets at y=0.0, 0.2021, 0.3998, 0.6125, 0.8209 and 1.0) for the ionic strength range from 0.4014 to 6.2790 mol center dot kg(-1). Our results, and those from two previous isopiestic studies, were combined and used with previously determined parameters for KCl(aq) and those determined here for MgCl2(aq) to evaluate mixing parameters for the Clegg-Pitzer-Brimblecombe model. These combined data were also used to determine the mixing parameters of the Scatchard model. Both sets of model parameters are valid for ionic strengths of  lt = 12.8 mol center dot kg(-1), where higher-order electrostatic effects have been included in the Clegg-Pitzer-Brimblecombe mixture model. The activity coefficients for KCl and MgCl2 were calculated from these models and the results for KCl were compared to experimental data from Emf measurements. The Scatchard model interaction parameters were used for calculation of the excess Gibbs energy as a function of the ionic strength and ionic strength fraction of KCl. The Zdanovskii-Robinson-Stokes rule of linearity for mixing of isopiestic solutions was tested.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k
EP  - 1419
IS  - 11-12
SP  - 1401
VL  - 36
DO  - 10.1007/s10953-007-9197-3
ER  - 
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica D.",
year = "2007",
abstract = "Isopiestic vapor-pressure measurements were made at the temperature 298.15 K for aqueous KCl + MgCl2 solutions using KCl(aq) as the reference standard. The measurements for these ternary solutions were made at KCl ionic strength fractions of y=0.0, 0.1989, 0.3996, 0.5993, 0.7925 and 1.0 (with two additional sets at y=0.0, 0.2021, 0.3998, 0.6125, 0.8209 and 1.0) for the ionic strength range from 0.4014 to 6.2790 mol center dot kg(-1). Our results, and those from two previous isopiestic studies, were combined and used with previously determined parameters for KCl(aq) and those determined here for MgCl2(aq) to evaluate mixing parameters for the Clegg-Pitzer-Brimblecombe model. These combined data were also used to determine the mixing parameters of the Scatchard model. Both sets of model parameters are valid for ionic strengths of  lt = 12.8 mol center dot kg(-1), where higher-order electrostatic effects have been included in the Clegg-Pitzer-Brimblecombe mixture model. The activity coefficients for KCl and MgCl2 were calculated from these models and the results for KCl were compared to experimental data from Emf measurements. The Scatchard model interaction parameters were used for calculation of the excess Gibbs energy as a function of the ionic strength and ionic strength fraction of KCl. The Zdanovskii-Robinson-Stokes rule of linearity for mixing of isopiestic solutions was tested.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k",
pages = "1419-1401",
number = "11-12",
volume = "36",
doi = "10.1007/s10953-007-9197-3"
}
Miladinović, J., Ninković, R.,& Todorović, M. D.. (2007). Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 36(11-12), 1401-1419.
https://doi.org/10.1007/s10953-007-9197-3
Miladinović J, Ninković R, Todorović MD. Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k. in Journal of Solution Chemistry. 2007;36(11-12):1401-1419.
doi:10.1007/s10953-007-9197-3 .
Miladinović, Jelena, Ninković, Rozalija, Todorović, Milica D., "Osmotic and activity coefficients of {yKCl+(1-y)MgCl2}(aq) at T=298.15 k" in Journal of Solution Chemistry, 36, no. 11-12 (2007):1401-1419,
https://doi.org/10.1007/s10953-007-9197-3 . .
15
15
15

Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K

Ninković, Rozalija; Miladinović, Jelena; Todorović, Milica D.; Rumyantsev, AV; Božović, Branislava R.

(Amer Chemical Soc, Washington, 2005)

TY  - JOUR
AU  - Ninković, Rozalija
AU  - Miladinović, Jelena
AU  - Todorović, Milica D.
AU  - Rumyantsev, AV
AU  - Božović, Branislava R.
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/817
AB  - The Zdanovskii rule, in simple and modified form, was used for the estimation of supersaturated K2SO4-(aq) osmotic coefficients at T = 298.15 K by treatment of the isopiestic data of the mixed electrolyte solutions. The results were compared with the predictions of the Akerlof-Thomas rule and of weighted averages. Estimated values by the Zdanovskii rule together with the K2SO4(aq) osmotic coefficient experimental data in unsaturated solution were used in fitting the data to the extended Pitzer equation. The reliability of the Zdanovskii rule estimation was tested on the prediction of the osmotic coefficients in several mixed electrolyte solutions containing K2SO4 and having an ionic strength much greater than the ionic strength of saturated K2SO4(aq) and on the osmotic coefficient estimation for supersaturated Na2SO4(aq) at T = 298.15 K.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K
EP  - 741
IS  - 3
SP  - 735
VL  - 50
DO  - 10.1021/je049632h
ER  - 
@article{
author = "Ninković, Rozalija and Miladinović, Jelena and Todorović, Milica D. and Rumyantsev, AV and Božović, Branislava R.",
year = "2005",
abstract = "The Zdanovskii rule, in simple and modified form, was used for the estimation of supersaturated K2SO4-(aq) osmotic coefficients at T = 298.15 K by treatment of the isopiestic data of the mixed electrolyte solutions. The results were compared with the predictions of the Akerlof-Thomas rule and of weighted averages. Estimated values by the Zdanovskii rule together with the K2SO4(aq) osmotic coefficient experimental data in unsaturated solution were used in fitting the data to the extended Pitzer equation. The reliability of the Zdanovskii rule estimation was tested on the prediction of the osmotic coefficients in several mixed electrolyte solutions containing K2SO4 and having an ionic strength much greater than the ionic strength of saturated K2SO4(aq) and on the osmotic coefficient estimation for supersaturated Na2SO4(aq) at T = 298.15 K.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K",
pages = "741-735",
number = "3",
volume = "50",
doi = "10.1021/je049632h"
}
Ninković, R., Miladinović, J., Todorović, M. D., Rumyantsev, A.,& Božović, B. R.. (2005). Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 50(3), 735-741.
https://doi.org/10.1021/je049632h
Ninković R, Miladinović J, Todorović MD, Rumyantsev A, Božović BR. Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K. in Journal of Chemical and Engineering Data. 2005;50(3):735-741.
doi:10.1021/je049632h .
Ninković, Rozalija, Miladinović, Jelena, Todorović, Milica D., Rumyantsev, AV, Božović, Branislava R., "Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K" in Journal of Chemical and Engineering Data, 50, no. 3 (2005):735-741,
https://doi.org/10.1021/je049632h . .
4
4
4

Mathematical model for exergy in the system NaCl-H2O

Ninković, Rozalija; Todorović, Milica D.; Miladinović, Jelena

(Association of Chemical Engineers of Serbia, 2004)

TY  - JOUR
AU  - Ninković, Rozalija
AU  - Todorović, Milica D.
AU  - Miladinović, Jelena
PY  - 2004
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/638
AB  - In this work mathematical models for the exergy and relative enthalpy of the water solution of sodium-chloride and the pure crystalline sodium-chloride where derived. The environment was defined with the temperature 20 °C, pressure 101,325 kPa and with liquid water and crystalline sodium-chloride, both having at the defined environmental conditions the value of exergy equal zero. The obtained mathematical model is valid in the temperature interval from 0 to 170°C and for the all compositions of solution, until to saturation. The derived mathematical model for the exergy is based on the Pitzer's ion interaction equation which satisfactory represents the dependence of the osmotic coefficient and the mean ionic activity coefficient on the composition of solution. The calculated values of exergy using the mathematical model were compared with the appropriate diagram for the exergy constructed using the table values of activity coefficients, osmotic coefficients and partial molar enthalpies.
AB  - Izveden je matematički model za eksergiju i relativnu entalpiju vodenih rastvora natrijum-hlorida i čistog kristalnog natrijum-hlorida. Uzeto je da je okolina na temperaturi 20°C i pritisku 101,325 kPa i da je čine voda u tečnom i natrijum-hlorid u čvrstom agregatnom stanju, koji pod ovim uslovima imaju vrednost eksergije nula. Model se zasniva na Pitzer-ovoj jednačini jon interakcionog tipa za zavisnost koeficijenta aktivnosti i osmotskog koeficijenta od sastava rastvora.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Mathematical model for exergy in the system NaCl-H2O
T1  - Matematički model za eksergiju u sistemu NaCl-H2O
EP  - 5
IS  - 1
SP  - 1
VL  - 58
DO  - 10.2298/HEMIND0401001N
ER  - 
@article{
author = "Ninković, Rozalija and Todorović, Milica D. and Miladinović, Jelena",
year = "2004",
abstract = "In this work mathematical models for the exergy and relative enthalpy of the water solution of sodium-chloride and the pure crystalline sodium-chloride where derived. The environment was defined with the temperature 20 °C, pressure 101,325 kPa and with liquid water and crystalline sodium-chloride, both having at the defined environmental conditions the value of exergy equal zero. The obtained mathematical model is valid in the temperature interval from 0 to 170°C and for the all compositions of solution, until to saturation. The derived mathematical model for the exergy is based on the Pitzer's ion interaction equation which satisfactory represents the dependence of the osmotic coefficient and the mean ionic activity coefficient on the composition of solution. The calculated values of exergy using the mathematical model were compared with the appropriate diagram for the exergy constructed using the table values of activity coefficients, osmotic coefficients and partial molar enthalpies., Izveden je matematički model za eksergiju i relativnu entalpiju vodenih rastvora natrijum-hlorida i čistog kristalnog natrijum-hlorida. Uzeto je da je okolina na temperaturi 20°C i pritisku 101,325 kPa i da je čine voda u tečnom i natrijum-hlorid u čvrstom agregatnom stanju, koji pod ovim uslovima imaju vrednost eksergije nula. Model se zasniva na Pitzer-ovoj jednačini jon interakcionog tipa za zavisnost koeficijenta aktivnosti i osmotskog koeficijenta od sastava rastvora.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Mathematical model for exergy in the system NaCl-H2O, Matematički model za eksergiju u sistemu NaCl-H2O",
pages = "5-1",
number = "1",
volume = "58",
doi = "10.2298/HEMIND0401001N"
}
Ninković, R., Todorović, M. D.,& Miladinović, J.. (2004). Mathematical model for exergy in the system NaCl-H2O. in Hemijska industrija
Association of Chemical Engineers of Serbia., 58(1), 1-5.
https://doi.org/10.2298/HEMIND0401001N
Ninković R, Todorović MD, Miladinović J. Mathematical model for exergy in the system NaCl-H2O. in Hemijska industrija. 2004;58(1):1-5.
doi:10.2298/HEMIND0401001N .
Ninković, Rozalija, Todorović, Milica D., Miladinović, Jelena, "Mathematical model for exergy in the system NaCl-H2O" in Hemijska industrija, 58, no. 1 (2004):1-5,
https://doi.org/10.2298/HEMIND0401001N . .

Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models

Miladinović, Jelena; Ninković, Rozalija; Todorović, Milica D.; Jovanović, Vladislava M.

(Kluwer Academic/Plenum Publ, New York, 2003)

TY  - JOUR
AU  - Miladinović, Jelena
AU  - Ninković, Rozalija
AU  - Todorović, Milica D.
AU  - Jovanović, Vladislava M.
PY  - 2003
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/519
AB  - The available literature data on the osmotic coefficient of ZnSO4(aq) at 25degreesC in the molality range from 0.1 to 4.3 mol-kg(-1) and new experimental data from 1.2 to 2.9 mol-kg(-1), at the same temperature, are presented. Selected values of the osmotic coefficient from all the data are analyzed using the Clegg-Pitzer-Brimblecombe model, the extended Pitzer model, and a semiempirical equation comprising a power series in molality added to the Debye-Huckel limiting law. The extended Pitzer equation and the Clegg-Pitzer-Brimblecombe equations give the best results in fitting the osmotic coefficient data. All three models are used to calculate ZnSO4 activity coefficients at 25degreesC in dilute solutions ( lt 0.1 mol-kg(-1)) for comparison with published values.
PB  - Kluwer Academic/Plenum Publ, New York
T2  - Journal of Solution Chemistry
T1  - Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models
EP  - 383
IS  - 4
SP  - 371
VL  - 32
DO  - 10.1023/A:1023710022173
ER  - 
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica D. and Jovanović, Vladislava M.",
year = "2003",
abstract = "The available literature data on the osmotic coefficient of ZnSO4(aq) at 25degreesC in the molality range from 0.1 to 4.3 mol-kg(-1) and new experimental data from 1.2 to 2.9 mol-kg(-1), at the same temperature, are presented. Selected values of the osmotic coefficient from all the data are analyzed using the Clegg-Pitzer-Brimblecombe model, the extended Pitzer model, and a semiempirical equation comprising a power series in molality added to the Debye-Huckel limiting law. The extended Pitzer equation and the Clegg-Pitzer-Brimblecombe equations give the best results in fitting the osmotic coefficient data. All three models are used to calculate ZnSO4 activity coefficients at 25degreesC in dilute solutions ( lt 0.1 mol-kg(-1)) for comparison with published values.",
publisher = "Kluwer Academic/Plenum Publ, New York",
journal = "Journal of Solution Chemistry",
title = "Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models",
pages = "383-371",
number = "4",
volume = "32",
doi = "10.1023/A:1023710022173"
}
Miladinović, J., Ninković, R., Todorović, M. D.,& Jovanović, V. M.. (2003). Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models. in Journal of Solution Chemistry
Kluwer Academic/Plenum Publ, New York., 32(4), 371-383.
https://doi.org/10.1023/A:1023710022173
Miladinović J, Ninković R, Todorović MD, Jovanović VM. Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models. in Journal of Solution Chemistry. 2003;32(4):371-383.
doi:10.1023/A:1023710022173 .
Miladinović, Jelena, Ninković, Rozalija, Todorović, Milica D., Jovanović, Vladislava M., "Correlation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic models" in Journal of Solution Chemistry, 32, no. 4 (2003):371-383,
https://doi.org/10.1023/A:1023710022173 . .
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