Radoičić, Marija

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97f68eeb-e7eb-4cb0-99e7-9f401575c7e9
  • Radoičić, Marija (20)
  • Radoičić, Marija B. (1)
Projects

Author's Bibliography

Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada

Kovačević, Aleksandar G.; Marković, Darka D.; Radoičić, Marija B.; Radetić, Maja M.

(Beograd : Srpsko hemijsko društvo = Serbian Chemical Society, 2023)

TY  - CONF
AU  - Kovačević, Aleksandar G.
AU  - Marković, Darka D.
AU  - Radoičić, Marija B.
AU  - Radetić, Maja M.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6882
AB  - Efikasno i jeftino čišćenje naftnih mrlja sa vode i tla kao i generisanje ogromnih količina tekstilnog otpada su goreći ekološki problemi koji zahtevaju hitno rešavanje. U pokušaju da se odgovori na oba izazova, proizveden je iglovani netkani sorbent od recikliranih vlakana jute iz industrije tepiha. Ispitan je uticaj površinske mase i debljine sorbenata na sorpcioni kapacitet za naftu u vodi i u nafti bez vode, sposobnost plutanja, sposobnost zadržavanja nafte i mogućnost ponovne upotrebe. Svi sorbenti su položili test plutanja. Površinska masa sorbenata i viskozitet testirane nafte i naftnih derivata (sirova nafta, dizel gorivo i dva motorna ulja) imaju snažan uticaj na sorpcioni kapacitet i sposobnost zadržavanja nafte. Sorbenti uglavnom zadržavaju do 50% svojih početnih sorpcionih kapaciteta nakon 5 ponovljenih ciklusa sorpcije što ukazuje da se mogu višekratno koristiti.
AB  - Efficient and inexpensive cleanup of oil spills on water or land and huge generation of
textile waste are burning environmental issues that are seeking urgent solutions. In an
attempt to address both challenges, needle-punched non-woven sorbents (NWSs) based on
recycled jute fibers from the carpet industry were manufactured. The influence of NWS
area density and thickness on oil sorption capacity in water and oil without water,
buoyancy, oil retention and reusability were studied. All NWSs passed the buoyancy test.
The area density of NWSs and viscosity of tested oils (crude oil, diesel oil and two motor
oils) strongly affect the oil sorption capacity and oil retention. NWSs mainly retain 50% of
their initial oil sorption capacities after 5 repeated sorption cycles indicating that NWSs
could be used several times.
PB  - Beograd : Srpsko hemijsko društvo = Serbian Chemical Society
C3  - Kratki izvodi radova ; Knjiga radova = Book of Abstracts ; Proceedings / 59. savetovanje Srpskog hemijskog društva, Novi Sad 1. i 2. jun 2023. godine = 59th meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023
T1  - Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada
T1  - Oil spills cleanup with non-woven sorbent produced from postindustrial textile waste
SP  - 143
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6882
ER  - 
@conference{
author = "Kovačević, Aleksandar G. and Marković, Darka D. and Radoičić, Marija B. and Radetić, Maja M.",
year = "2023",
abstract = "Efikasno i jeftino čišćenje naftnih mrlja sa vode i tla kao i generisanje ogromnih količina tekstilnog otpada su goreći ekološki problemi koji zahtevaju hitno rešavanje. U pokušaju da se odgovori na oba izazova, proizveden je iglovani netkani sorbent od recikliranih vlakana jute iz industrije tepiha. Ispitan je uticaj površinske mase i debljine sorbenata na sorpcioni kapacitet za naftu u vodi i u nafti bez vode, sposobnost plutanja, sposobnost zadržavanja nafte i mogućnost ponovne upotrebe. Svi sorbenti su položili test plutanja. Površinska masa sorbenata i viskozitet testirane nafte i naftnih derivata (sirova nafta, dizel gorivo i dva motorna ulja) imaju snažan uticaj na sorpcioni kapacitet i sposobnost zadržavanja nafte. Sorbenti uglavnom zadržavaju do 50% svojih početnih sorpcionih kapaciteta nakon 5 ponovljenih ciklusa sorpcije što ukazuje da se mogu višekratno koristiti., Efficient and inexpensive cleanup of oil spills on water or land and huge generation of
textile waste are burning environmental issues that are seeking urgent solutions. In an
attempt to address both challenges, needle-punched non-woven sorbents (NWSs) based on
recycled jute fibers from the carpet industry were manufactured. The influence of NWS
area density and thickness on oil sorption capacity in water and oil without water,
buoyancy, oil retention and reusability were studied. All NWSs passed the buoyancy test.
The area density of NWSs and viscosity of tested oils (crude oil, diesel oil and two motor
oils) strongly affect the oil sorption capacity and oil retention. NWSs mainly retain 50% of
their initial oil sorption capacities after 5 repeated sorption cycles indicating that NWSs
could be used several times.",
publisher = "Beograd : Srpsko hemijsko društvo = Serbian Chemical Society",
journal = "Kratki izvodi radova ; Knjiga radova = Book of Abstracts ; Proceedings / 59. savetovanje Srpskog hemijskog društva, Novi Sad 1. i 2. jun 2023. godine = 59th meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023",
title = "Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada, Oil spills cleanup with non-woven sorbent produced from postindustrial textile waste",
pages = "143",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6882"
}
Kovačević, A. G., Marković, D. D., Radoičić, M. B.,& Radetić, M. M.. (2023). Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada. in Kratki izvodi radova ; Knjiga radova = Book of Abstracts ; Proceedings / 59. savetovanje Srpskog hemijskog društva, Novi Sad 1. i 2. jun 2023. godine = 59th meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023
Beograd : Srpsko hemijsko društvo = Serbian Chemical Society., 143.
https://hdl.handle.net/21.15107/rcub_technorep_6882
Kovačević AG, Marković DD, Radoičić MB, Radetić MM. Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada. in Kratki izvodi radova ; Knjiga radova = Book of Abstracts ; Proceedings / 59. savetovanje Srpskog hemijskog društva, Novi Sad 1. i 2. jun 2023. godine = 59th meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023. 2023;:143.
https://hdl.handle.net/21.15107/rcub_technorep_6882 .
Kovačević, Aleksandar G., Marković, Darka D., Radoičić, Marija B., Radetić, Maja M., "Čišćenje naftnih mrlja sa netkanim sorbentom proizvedenim od post-industrijskog tekstilnog otpada" in Kratki izvodi radova ; Knjiga radova = Book of Abstracts ; Proceedings / 59. savetovanje Srpskog hemijskog društva, Novi Sad 1. i 2. jun 2023. godine = 59th meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 (2023):143,
https://hdl.handle.net/21.15107/rcub_technorep_6882 .

Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton

Radetić, Maja; Marković, Darka; Petkovska, Jovana; Mladenović, Nina; Radoičić, Marija; Vest, Natalie; Palen, Bethany; Jaime, Grunlan; Jordanov, Igor

(2023)

TY  - CONF
AU  - Radetić, Maja
AU  - Marković, Darka
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Radoičić, Marija
AU  - Vest, Natalie
AU  - Palen, Bethany
AU  - Jaime, Grunlan
AU  - Jordanov, Igor
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6866
AB  - The demand for antimicrobial textiles is rapidly
growing particularly in medical sector. In an
effort to develop a simple and efficient
antimicrobial treatment for cotton, layer-bylayer
deposition of chitosan and magnesium
lignosulfonate, followed by in situ synthesis of
silver (Ag) nanoparticles, was accomplished.
Lignin is exploited as a natural reducing and
stabilizing agent1,2, producing Ag nanoparticles
in amounts even larger than those obtained with
sodium borohydride as a strong reducing agent.
The influence of the number of bilayers (4 and
12) and initial concentration of AgNO3 solution
(10 and 20 mM) on antimicrobial activity of
cotton fabric against Gram-negative bacteria E.
coli, Gram-positive bacteria S. aureus, and C.
albicans, yeast was examined. The presence of
evenly scattered Ag nanoparticles all over the
fiber surface is confirmed by FESEM analysis
(Figure 1). The number of bilayers does not
affect the size of nanoparticles (~56 nm), but an
increase of bilayers results in greater Ag
content. The samples treated with 20 mM
AgNO3 solution contain more Ag than those
treated with 10 mM solution. The formation of
metallic Ag nanoparticles is confirmed by XPS
analysis.
Synthesized Ag nanoparticles provide excellent
antibacterial activity against bacteria S. aureus
(99.9 %), independent of the initial
concentration of AgNO3 and number of bilayers.
Larger content of Ag nanoparticles i.e., higher
initial concentration of AgNO3 solution leads to
considerably enhanced antibacterial activity
against E. coli. A similar trend is evident with
the C. albicans yeast, but the desired yeast
reduction of 99 % was not obtained.
C3  - Book of Abstracts / SICT/Plasma Tech/Tribology 2023 Joint Conferences, 26-28 Avril, 2023 - Lisbon, Portugal
T1  - Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton
SP  - 177
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6866
ER  - 
@conference{
author = "Radetić, Maja and Marković, Darka and Petkovska, Jovana and Mladenović, Nina and Radoičić, Marija and Vest, Natalie and Palen, Bethany and Jaime, Grunlan and Jordanov, Igor",
year = "2023",
abstract = "The demand for antimicrobial textiles is rapidly
growing particularly in medical sector. In an
effort to develop a simple and efficient
antimicrobial treatment for cotton, layer-bylayer
deposition of chitosan and magnesium
lignosulfonate, followed by in situ synthesis of
silver (Ag) nanoparticles, was accomplished.
Lignin is exploited as a natural reducing and
stabilizing agent1,2, producing Ag nanoparticles
in amounts even larger than those obtained with
sodium borohydride as a strong reducing agent.
The influence of the number of bilayers (4 and
12) and initial concentration of AgNO3 solution
(10 and 20 mM) on antimicrobial activity of
cotton fabric against Gram-negative bacteria E.
coli, Gram-positive bacteria S. aureus, and C.
albicans, yeast was examined. The presence of
evenly scattered Ag nanoparticles all over the
fiber surface is confirmed by FESEM analysis
(Figure 1). The number of bilayers does not
affect the size of nanoparticles (~56 nm), but an
increase of bilayers results in greater Ag
content. The samples treated with 20 mM
AgNO3 solution contain more Ag than those
treated with 10 mM solution. The formation of
metallic Ag nanoparticles is confirmed by XPS
analysis.
Synthesized Ag nanoparticles provide excellent
antibacterial activity against bacteria S. aureus
(99.9 %), independent of the initial
concentration of AgNO3 and number of bilayers.
Larger content of Ag nanoparticles i.e., higher
initial concentration of AgNO3 solution leads to
considerably enhanced antibacterial activity
against E. coli. A similar trend is evident with
the C. albicans yeast, but the desired yeast
reduction of 99 % was not obtained.",
journal = "Book of Abstracts / SICT/Plasma Tech/Tribology 2023 Joint Conferences, 26-28 Avril, 2023 - Lisbon, Portugal",
title = "Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton",
pages = "177",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6866"
}
Radetić, M., Marković, D., Petkovska, J., Mladenović, N., Radoičić, M., Vest, N., Palen, B., Jaime, G.,& Jordanov, I.. (2023). Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton. in Book of Abstracts / SICT/Plasma Tech/Tribology 2023 Joint Conferences, 26-28 Avril, 2023 - Lisbon, Portugal, 177.
https://hdl.handle.net/21.15107/rcub_technorep_6866
Radetić M, Marković D, Petkovska J, Mladenović N, Radoičić M, Vest N, Palen B, Jaime G, Jordanov I. Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton. in Book of Abstracts / SICT/Plasma Tech/Tribology 2023 Joint Conferences, 26-28 Avril, 2023 - Lisbon, Portugal. 2023;:177.
https://hdl.handle.net/21.15107/rcub_technorep_6866 .
Radetić, Maja, Marković, Darka, Petkovska, Jovana, Mladenović, Nina, Radoičić, Marija, Vest, Natalie, Palen, Bethany, Jaime, Grunlan, Jordanov, Igor, "Multilayer Chitosan/Lignin Nanocoating with Silver Nanoparticles for Antimicrobial Cotton" in Book of Abstracts / SICT/Plasma Tech/Tribology 2023 Joint Conferences, 26-28 Avril, 2023 - Lisbon, Portugal (2023):177,
https://hdl.handle.net/21.15107/rcub_technorep_6866 .

Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles

Marković, Darka; Petkovska, Jovana; Mladenovic, Nina; Radoičić, Marija; Rodriguez-Melendez, Danixa; Ilić-Tomić, Tatjana; Radetić, Maja; Grunlan, Jaime C.; Jordanov, Igor

(John Wiley and Sons Inc., 2023)

TY  - JOUR
AU  - Marković, Darka
AU  - Petkovska, Jovana
AU  - Mladenovic, Nina
AU  - Radoičić, Marija
AU  - Rodriguez-Melendez, Danixa
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6335
AB  - Poor antimicrobial activity and lack of protection against UV irradiation are weaknesses of cotton textiles. In an attempt to impart superior antimicrobial and UV-protective properties to cotton, layer-by-layer deposition of chitosan and magnesium lignosulfonate, and in situ synthesis of silver (Ag) nanoparticles (NPs), was performed. Lignin, in a chitosan/lignin multilayer, simultaneously acts as a UV protective macromolecule and natural reducing and stabilizing agent, allowing formation of Ag NPs. Four bilayers of this coating is sufficient for fabrication of a chitosan/lignin/Ag-NP textile nanocomposite treatment with 50+ UV protection. 100% reduction of Gram-negative bacteria Escherichia coli, gram-positive bacteria Staphylococcus aureus, and yeast Candida albicans can be achieved with a 12-bilayer coating, when 20 mM silver nitrate solution and sodium borohydride are applied. On the other hand, four bilayers impregnated with Ag NPs, using 10 mM silver nitrate solution, provides sufficient antimicrobial activity independent of an added reducing agent. This treatment exhibits no inhibition of human keratinocyte cells growth on the skin, indicating low cytotoxicity.
PB  - John Wiley and Sons Inc.
T2  - Journal of Applied Polymer Science
T1  - Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles
SP  - e53823
DO  - 10.1002/app.53823
ER  - 
@article{
author = "Marković, Darka and Petkovska, Jovana and Mladenovic, Nina and Radoičić, Marija and Rodriguez-Melendez, Danixa and Ilić-Tomić, Tatjana and Radetić, Maja and Grunlan, Jaime C. and Jordanov, Igor",
year = "2023",
abstract = "Poor antimicrobial activity and lack of protection against UV irradiation are weaknesses of cotton textiles. In an attempt to impart superior antimicrobial and UV-protective properties to cotton, layer-by-layer deposition of chitosan and magnesium lignosulfonate, and in situ synthesis of silver (Ag) nanoparticles (NPs), was performed. Lignin, in a chitosan/lignin multilayer, simultaneously acts as a UV protective macromolecule and natural reducing and stabilizing agent, allowing formation of Ag NPs. Four bilayers of this coating is sufficient for fabrication of a chitosan/lignin/Ag-NP textile nanocomposite treatment with 50+ UV protection. 100% reduction of Gram-negative bacteria Escherichia coli, gram-positive bacteria Staphylococcus aureus, and yeast Candida albicans can be achieved with a 12-bilayer coating, when 20 mM silver nitrate solution and sodium borohydride are applied. On the other hand, four bilayers impregnated with Ag NPs, using 10 mM silver nitrate solution, provides sufficient antimicrobial activity independent of an added reducing agent. This treatment exhibits no inhibition of human keratinocyte cells growth on the skin, indicating low cytotoxicity.",
publisher = "John Wiley and Sons Inc.",
journal = "Journal of Applied Polymer Science",
title = "Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles",
pages = "e53823",
doi = "10.1002/app.53823"
}
Marković, D., Petkovska, J., Mladenovic, N., Radoičić, M., Rodriguez-Melendez, D., Ilić-Tomić, T., Radetić, M., Grunlan, J. C.,& Jordanov, I.. (2023). Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles. in Journal of Applied Polymer Science
John Wiley and Sons Inc.., e53823.
https://doi.org/10.1002/app.53823
Marković D, Petkovska J, Mladenovic N, Radoičić M, Rodriguez-Melendez D, Ilić-Tomić T, Radetić M, Grunlan JC, Jordanov I. Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles. in Journal of Applied Polymer Science. 2023;:e53823.
doi:10.1002/app.53823 .
Marković, Darka, Petkovska, Jovana, Mladenovic, Nina, Radoičić, Marija, Rodriguez-Melendez, Danixa, Ilić-Tomić, Tatjana, Radetić, Maja, Grunlan, Jaime C., Jordanov, Igor, "Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles" in Journal of Applied Polymer Science (2023):e53823,
https://doi.org/10.1002/app.53823 . .
5
5

Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation

Kovačević, Aleksandar; Radoičić, Marija; Marković, Darka; Ponjavić, Marijana; Nikodinović-Runić, Jasmina; Radetić, Maja

(Elsevier B.V., 2023)

TY  - JOUR
AU  - Kovačević, Aleksandar
AU  - Radoičić, Marija
AU  - Marković, Darka
AU  - Ponjavić, Marijana
AU  - Nikodinović-Runić, Jasmina
AU  - Radetić, Maja
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6372
AB  - Loose assemblies of cellulose fibers could be employed in the clean-up of oil spills, but the difficulty to separate them from the spill after use makes them impractical. In an effort to tackle this issue, a non-woven sorbent based on recycled jute fibers from the carpet industry was developed. To enhance the porosity and hydrophobicity/oleophilicity of the sorbent, carbonization in an inert atmosphere was carried out. A comparison in oil sorption performance between non-carbonized and carbonized sorbents was made by evaluating the oil capacity in a water medium, buoyancy, oil retention and reusability. Carbonization of sorbent resulted in more than doubled oil sorption capacity independent of oil viscosity. Oil viscosity did not affect the oil sorption capacity of non-carbonized sorbent. Carbonized sorbent showed superior buoyancy in water even after 24 hours, oil retention of approximately 60–80% after 3 hours and only 12–20% decline of oil sorption capacity after five repeated sorption/desorption trials. However, the ability of oiled non-carbonized sorbent to efficiently biodegrade in model compost (up to 45% weight loss after 10 weeks) makes it a sustainable candidate for oil spill clean-up.
PB  - Elsevier B.V.
T2  - Environmental Technology and Innovation
T1  - Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation
SP  - 103170
VL  - 31
DO  - 10.1016/j.eti.2023.103170
ER  - 
@article{
author = "Kovačević, Aleksandar and Radoičić, Marija and Marković, Darka and Ponjavić, Marijana and Nikodinović-Runić, Jasmina and Radetić, Maja",
year = "2023",
abstract = "Loose assemblies of cellulose fibers could be employed in the clean-up of oil spills, but the difficulty to separate them from the spill after use makes them impractical. In an effort to tackle this issue, a non-woven sorbent based on recycled jute fibers from the carpet industry was developed. To enhance the porosity and hydrophobicity/oleophilicity of the sorbent, carbonization in an inert atmosphere was carried out. A comparison in oil sorption performance between non-carbonized and carbonized sorbents was made by evaluating the oil capacity in a water medium, buoyancy, oil retention and reusability. Carbonization of sorbent resulted in more than doubled oil sorption capacity independent of oil viscosity. Oil viscosity did not affect the oil sorption capacity of non-carbonized sorbent. Carbonized sorbent showed superior buoyancy in water even after 24 hours, oil retention of approximately 60–80% after 3 hours and only 12–20% decline of oil sorption capacity after five repeated sorption/desorption trials. However, the ability of oiled non-carbonized sorbent to efficiently biodegrade in model compost (up to 45% weight loss after 10 weeks) makes it a sustainable candidate for oil spill clean-up.",
publisher = "Elsevier B.V.",
journal = "Environmental Technology and Innovation",
title = "Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation",
pages = "103170",
volume = "31",
doi = "10.1016/j.eti.2023.103170"
}
Kovačević, A., Radoičić, M., Marković, D., Ponjavić, M., Nikodinović-Runić, J.,& Radetić, M.. (2023). Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation. in Environmental Technology and Innovation
Elsevier B.V.., 31, 103170.
https://doi.org/10.1016/j.eti.2023.103170
Kovačević A, Radoičić M, Marković D, Ponjavić M, Nikodinović-Runić J, Radetić M. Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation. in Environmental Technology and Innovation. 2023;31:103170.
doi:10.1016/j.eti.2023.103170 .
Kovačević, Aleksandar, Radoičić, Marija, Marković, Darka, Ponjavić, Marijana, Nikodinović-Runić, Jasmina, Radetić, Maja, "Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation" in Environmental Technology and Innovation, 31 (2023):103170,
https://doi.org/10.1016/j.eti.2023.103170 . .
7
5

Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric

Petkovska, Jovana; Mladenović, Nina; Marković, Darka; Radoičić, Marija; Chiang, Hsu-Cheng; Palen, Bethany; Mirakovski, Dejan; Dimova, Vesna; Radetić, Maja; Grunlan, Jaime C.; Jordanov, Igor

(Elsevier Ltd, 2023)

TY  - JOUR
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Marković, Darka
AU  - Radoičić, Marija
AU  - Chiang, Hsu-Cheng
AU  - Palen, Bethany
AU  - Mirakovski, Dejan
AU  - Dimova, Vesna
AU  - Radetić, Maja
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6418
AB  - The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.
PB  - Elsevier Ltd
T2  - Polymer Degradation and Stability
T1  - Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric
SP  - 110406
VL  - 214
DO  - 10.1016/j.polymdegradstab.2023.110406
ER  - 
@article{
author = "Petkovska, Jovana and Mladenović, Nina and Marković, Darka and Radoičić, Marija and Chiang, Hsu-Cheng and Palen, Bethany and Mirakovski, Dejan and Dimova, Vesna and Radetić, Maja and Grunlan, Jaime C. and Jordanov, Igor",
year = "2023",
abstract = "The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.",
publisher = "Elsevier Ltd",
journal = "Polymer Degradation and Stability",
title = "Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric",
pages = "110406",
volume = "214",
doi = "10.1016/j.polymdegradstab.2023.110406"
}
Petkovska, J., Mladenović, N., Marković, D., Radoičić, M., Chiang, H., Palen, B., Mirakovski, D., Dimova, V., Radetić, M., Grunlan, J. C.,& Jordanov, I.. (2023). Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric. in Polymer Degradation and Stability
Elsevier Ltd., 214, 110406.
https://doi.org/10.1016/j.polymdegradstab.2023.110406
Petkovska J, Mladenović N, Marković D, Radoičić M, Chiang H, Palen B, Mirakovski D, Dimova V, Radetić M, Grunlan JC, Jordanov I. Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric. in Polymer Degradation and Stability. 2023;214:110406.
doi:10.1016/j.polymdegradstab.2023.110406 .
Petkovska, Jovana, Mladenović, Nina, Marković, Darka, Radoičić, Marija, Chiang, Hsu-Cheng, Palen, Bethany, Mirakovski, Dejan, Dimova, Vesna, Radetić, Maja, Grunlan, Jaime C., Jordanov, Igor, "Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric" in Polymer Degradation and Stability, 214 (2023):110406,
https://doi.org/10.1016/j.polymdegradstab.2023.110406 . .
6
5

Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract

Krkobabić, Ana; Marković, Darka; Kovačević, Aleksandar; Tadić, Vanja; Radoičić, Marija; Barudžija, Tatjana; Ilic-Tomic, Tatjana; Radetić, Maja

(Korean Fiber Society, 2022)

TY  - JOUR
AU  - Krkobabić, Ana
AU  - Marković, Darka
AU  - Kovačević, Aleksandar
AU  - Tadić, Vanja
AU  - Radoičić, Marija
AU  - Barudžija, Tatjana
AU  - Ilic-Tomic, Tatjana
AU  - Radetić, Maja
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5130
AB  - The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.
PB  - Korean Fiber Society
T2  - Fibers and Polymers
T1  - Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract
EP  - 966
IS  - 4
SP  - 954
VL  - 23
DO  - 10.1007/s12221-022-4639-5
ER  - 
@article{
author = "Krkobabić, Ana and Marković, Darka and Kovačević, Aleksandar and Tadić, Vanja and Radoičić, Marija and Barudžija, Tatjana and Ilic-Tomic, Tatjana and Radetić, Maja",
year = "2022",
abstract = "The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.",
publisher = "Korean Fiber Society",
journal = "Fibers and Polymers",
title = "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract",
pages = "966-954",
number = "4",
volume = "23",
doi = "10.1007/s12221-022-4639-5"
}
Krkobabić, A., Marković, D., Kovačević, A., Tadić, V., Radoičić, M., Barudžija, T., Ilic-Tomic, T.,& Radetić, M.. (2022). Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers
Korean Fiber Society., 23(4), 954-966.
https://doi.org/10.1007/s12221-022-4639-5
Krkobabić A, Marković D, Kovačević A, Tadić V, Radoičić M, Barudžija T, Ilic-Tomic T, Radetić M. Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers. 2022;23(4):954-966.
doi:10.1007/s12221-022-4639-5 .
Krkobabić, Ana, Marković, Darka, Kovačević, Aleksandar, Tadić, Vanja, Radoičić, Marija, Barudžija, Tatjana, Ilic-Tomic, Tatjana, Radetić, Maja, "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract" in Fibers and Polymers, 23, no. 4 (2022):954-966,
https://doi.org/10.1007/s12221-022-4639-5 . .
6
1
4

Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating

Petkovska, Jovana; Mladenović, Nina; Marković, Darka; Radoičić, Marija; Vest, Natalie A.; Palen, Bethany; Radetić, Maja; Grunlan, Jaime C.; Jordanov, Igor

(American Chemical Society, 2022)

TY  - JOUR
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Marković, Darka
AU  - Radoičić, Marija
AU  - Vest, Natalie A.
AU  - Palen, Bethany
AU  - Radetić, Maja
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5161
AB  - Creating multifunctional textiles using chemicals from renewable sources is challenging. In an effort to develop a sustainable and efficient multifunctional cotton treatment, a lignin-based multilayer nanocoating comprising magnesium lignosulfonate, chitosan, and monoammonium phosphate (MAP) was deposited using layer-by-layer assembly. A five bilayer coating adds 15.5 wt % to cotton and imparts fire extinguishing behavior and excellent UV and antimicrobial protection to the fabric. Just a two bilayer coating imparts sufficient self-extinguishing behavior to pass the standard vertical flame test. The combined influence of lignin as a char-forming and UV-protective macromolecule, chitosan as a char-forming biopolymer, and MAP acting as an antimicrobial agent (and a blowing agent and an acid source in an intumescent flame retardant system) results in a very powerful multifunctional textile treatment with very few layers of deposition.
PB  - American Chemical Society
T2  - ACS Applied Polymer Materials
T1  - Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating
EP  - 4537
IS  - 6
SP  - 4528
VL  - 4
DO  - 10.1021/acsapm.2c00520
ER  - 
@article{
author = "Petkovska, Jovana and Mladenović, Nina and Marković, Darka and Radoičić, Marija and Vest, Natalie A. and Palen, Bethany and Radetić, Maja and Grunlan, Jaime C. and Jordanov, Igor",
year = "2022",
abstract = "Creating multifunctional textiles using chemicals from renewable sources is challenging. In an effort to develop a sustainable and efficient multifunctional cotton treatment, a lignin-based multilayer nanocoating comprising magnesium lignosulfonate, chitosan, and monoammonium phosphate (MAP) was deposited using layer-by-layer assembly. A five bilayer coating adds 15.5 wt % to cotton and imparts fire extinguishing behavior and excellent UV and antimicrobial protection to the fabric. Just a two bilayer coating imparts sufficient self-extinguishing behavior to pass the standard vertical flame test. The combined influence of lignin as a char-forming and UV-protective macromolecule, chitosan as a char-forming biopolymer, and MAP acting as an antimicrobial agent (and a blowing agent and an acid source in an intumescent flame retardant system) results in a very powerful multifunctional textile treatment with very few layers of deposition.",
publisher = "American Chemical Society",
journal = "ACS Applied Polymer Materials",
title = "Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating",
pages = "4537-4528",
number = "6",
volume = "4",
doi = "10.1021/acsapm.2c00520"
}
Petkovska, J., Mladenović, N., Marković, D., Radoičić, M., Vest, N. A., Palen, B., Radetić, M., Grunlan, J. C.,& Jordanov, I.. (2022). Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating. in ACS Applied Polymer Materials
American Chemical Society., 4(6), 4528-4537.
https://doi.org/10.1021/acsapm.2c00520
Petkovska J, Mladenović N, Marković D, Radoičić M, Vest NA, Palen B, Radetić M, Grunlan JC, Jordanov I. Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating. in ACS Applied Polymer Materials. 2022;4(6):4528-4537.
doi:10.1021/acsapm.2c00520 .
Petkovska, Jovana, Mladenović, Nina, Marković, Darka, Radoičić, Marija, Vest, Natalie A., Palen, Bethany, Radetić, Maja, Grunlan, Jaime C., Jordanov, Igor, "Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating" in ACS Applied Polymer Materials, 4, no. 6 (2022):4528-4537,
https://doi.org/10.1021/acsapm.2c00520 . .
17
11

Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2

Krkobabić, Ana; Marković, Darka; Tadić, Vanja; Radoičić, Marija; Radetić, Maja

(Beograd : Srpsko hemijsko društvo, 2021)

TY  - CONF
AU  - Krkobabić, Ana
AU  - Marković, Darka
AU  - Tadić, Vanja
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6879
AB  - U ovom radu diskutovana je mogućnost sinteze nanolistića na bazi Cu na pamučnoj tkanini koji bi
pružili željeni nivo antimikrobne aktivnosti. Da bi se obezbedio dovoljan broj karboksilnih grupa za
vezivanje Cu2+
-jona iz rastvora soli prekursora pamučna tkanina je selektivno oksidisana u
dvostepenom procesu sa NaIO4 i NaClO2. Sorbovani Cu2+
-joni su redukovani galnom kiselinom.
FESEM i XRD analize su pokazale da nanolistići CuO organizovani u fine slojeve ravnomerno
pokrivaju površinu vlakana. Što je veća početna koncentracija NaIO4, veći je broj karboksilnih
grupa i posledično količina sintetisanih nanolistića CuO. Razvijeni tekstilni nanokompoziti su
pokazali odličnu antibakterijsku aktivnost prema Gram-negativnoj bakteriji Escherichia Coli i
Gram-pozitivnoj bakteriji Staphylococcus aureus, kao i zadovoljavajuću antifungalnu aktivnost
prema kvascu Candida albicans.
AB  - This study discussed the possibility of synthesizing Cu-based nanosheets on cotton fabric which could provide desired level of antimicrobial activity. In order to ensure a sufficient number of carboxyl groups that could efficiently bind Cu2+-ions from precursor salt solution, cotton fabric was selectively oxidized in two-step process with NaIO4 and NaClO2. Sorbed Cu2+-ions were reduced with gallic acid. FESEM and XRD analyses revealed that CuO nanosheets organized in fine layers evenly covered the surface of cotton fibers. The larger the initial concentration of NaIO4, the larger the number of carboxyl groups and consequently the amounts of synthesized CuO nanosheets. Fabricated textile nanocomposites exhibited excellent antibacterial activity against Gram-negative bacterium Escherichia Coli and Gram-positive bacterium Staphylococcus aureus as well as satisfactory antifungal activity against yeast Candida albicans.
PB  - Beograd : Srpsko hemijsko društvo
C3  - Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021
T1  - Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2
T1  - Antimicrobial activity of CuO nanosheets in situ synthesized on cotton fabric previously oxidized with NaIO4/NaClO2
SP  - 51
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6879
ER  - 
@conference{
author = "Krkobabić, Ana and Marković, Darka and Tadić, Vanja and Radoičić, Marija and Radetić, Maja",
year = "2021",
abstract = "U ovom radu diskutovana je mogućnost sinteze nanolistića na bazi Cu na pamučnoj tkanini koji bi
pružili željeni nivo antimikrobne aktivnosti. Da bi se obezbedio dovoljan broj karboksilnih grupa za
vezivanje Cu2+
-jona iz rastvora soli prekursora pamučna tkanina je selektivno oksidisana u
dvostepenom procesu sa NaIO4 i NaClO2. Sorbovani Cu2+
-joni su redukovani galnom kiselinom.
FESEM i XRD analize su pokazale da nanolistići CuO organizovani u fine slojeve ravnomerno
pokrivaju površinu vlakana. Što je veća početna koncentracija NaIO4, veći je broj karboksilnih
grupa i posledično količina sintetisanih nanolistića CuO. Razvijeni tekstilni nanokompoziti su
pokazali odličnu antibakterijsku aktivnost prema Gram-negativnoj bakteriji Escherichia Coli i
Gram-pozitivnoj bakteriji Staphylococcus aureus, kao i zadovoljavajuću antifungalnu aktivnost
prema kvascu Candida albicans., This study discussed the possibility of synthesizing Cu-based nanosheets on cotton fabric which could provide desired level of antimicrobial activity. In order to ensure a sufficient number of carboxyl groups that could efficiently bind Cu2+-ions from precursor salt solution, cotton fabric was selectively oxidized in two-step process with NaIO4 and NaClO2. Sorbed Cu2+-ions were reduced with gallic acid. FESEM and XRD analyses revealed that CuO nanosheets organized in fine layers evenly covered the surface of cotton fibers. The larger the initial concentration of NaIO4, the larger the number of carboxyl groups and consequently the amounts of synthesized CuO nanosheets. Fabricated textile nanocomposites exhibited excellent antibacterial activity against Gram-negative bacterium Escherichia Coli and Gram-positive bacterium Staphylococcus aureus as well as satisfactory antifungal activity against yeast Candida albicans.",
publisher = "Beograd : Srpsko hemijsko društvo",
journal = "Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021",
title = "Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2, Antimicrobial activity of CuO nanosheets in situ synthesized on cotton fabric previously oxidized with NaIO4/NaClO2",
pages = "51",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6879"
}
Krkobabić, A., Marković, D., Tadić, V., Radoičić, M.,& Radetić, M.. (2021). Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021
Beograd : Srpsko hemijsko društvo., 51.
https://hdl.handle.net/21.15107/rcub_technorep_6879
Krkobabić A, Marković D, Tadić V, Radoičić M, Radetić M. Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. 2021;:51.
https://hdl.handle.net/21.15107/rcub_technorep_6879 .
Krkobabić, Ana, Marković, Darka, Tadić, Vanja, Radoičić, Marija, Radetić, Maja, "Antimikrobna aktivnost nanolistića CuO in situ sintetisanih na pamučnoj tkanini prethodno oksidisanoj sa NaIO4/NaClO2" in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021 (2021):51,
https://hdl.handle.net/21.15107/rcub_technorep_6879 .

Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO

Marković, Darka; Radetić, Maja; Radoičić, Marija

(2021)


                                            

                                            
Marković, D., Radetić, M.,& Radoičić, M.. (2021). Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO. in Matični naučni odbor za materijale i hemijske tehnologije.
https://hdl.handle.net/21.15107/rcub_technorep_6883
Marković D, Radetić M, Radoičić M. Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO. in Matični naučni odbor za materijale i hemijske tehnologije. 2021;.
https://hdl.handle.net/21.15107/rcub_technorep_6883 .
Marković, Darka, Radetić, Maja, Radoičić, Marija, "Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO" in Matični naučni odbor za materijale i hemijske tehnologije (2021),
https://hdl.handle.net/21.15107/rcub_technorep_6883 .

Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles

Marković, Darka; Kovačević, Aleksandar; Tadić, Vanja; Radoičić, Marija; Barudžija, Tanja; Radetić, Maja

(Portugal : University of Minho, 2021)

TY  - CONF
AU  - Marković, Darka
AU  - Kovačević, Aleksandar
AU  - Tadić, Vanja
AU  - Radoičić, Marija
AU  - Barudžija, Tanja
AU  - Radetić, Maja
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6864
AB  - This study discusses the antimicrobial activity of cotton (CO) fabric oxidized with NaIO4/NaClO2
prior to in situ synthesis of Cu-based nanoparticles (NPs). Carboxyl groups generated by oxidation
of cellulose were utilized for efficient binding of Cu2+-ions from the solution of CuSO4 which
were further reduced by extract of Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry
leaves) as a green reducing agent. A number of free carboxyl groups was highly affected by the
initial concentration of NaIO4 solution. Color yield of impregnated fabrics varied with amounts of
synthesized Cu-based NPs. Fabricated samples provided excellent antibacterial activity and controlled
release of Cu2+-ions.
PB  - Portugal : University of Minho
C3  - Book of abstracts / Unfolding the future, 20th World Textile Conference AUTEX 2021, 5 - 9 September 2021, Guimarães, Portugal
T1  - Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles
EP  - 103
SP  - 102
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6864
ER  - 
@conference{
author = "Marković, Darka and Kovačević, Aleksandar and Tadić, Vanja and Radoičić, Marija and Barudžija, Tanja and Radetić, Maja",
year = "2021",
abstract = "This study discusses the antimicrobial activity of cotton (CO) fabric oxidized with NaIO4/NaClO2
prior to in situ synthesis of Cu-based nanoparticles (NPs). Carboxyl groups generated by oxidation
of cellulose were utilized for efficient binding of Cu2+-ions from the solution of CuSO4 which
were further reduced by extract of Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry
leaves) as a green reducing agent. A number of free carboxyl groups was highly affected by the
initial concentration of NaIO4 solution. Color yield of impregnated fabrics varied with amounts of
synthesized Cu-based NPs. Fabricated samples provided excellent antibacterial activity and controlled
release of Cu2+-ions.",
publisher = "Portugal : University of Minho",
journal = "Book of abstracts / Unfolding the future, 20th World Textile Conference AUTEX 2021, 5 - 9 September 2021, Guimarães, Portugal",
title = "Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles",
pages = "103-102",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6864"
}
Marković, D., Kovačević, A., Tadić, V., Radoičić, M., Barudžija, T.,& Radetić, M.. (2021). Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles. in Book of abstracts / Unfolding the future, 20th World Textile Conference AUTEX 2021, 5 - 9 September 2021, Guimarães, Portugal
Portugal : University of Minho., 102-103.
https://hdl.handle.net/21.15107/rcub_technorep_6864
Marković D, Kovačević A, Tadić V, Radoičić M, Barudžija T, Radetić M. Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles. in Book of abstracts / Unfolding the future, 20th World Textile Conference AUTEX 2021, 5 - 9 September 2021, Guimarães, Portugal. 2021;:102-103.
https://hdl.handle.net/21.15107/rcub_technorep_6864 .
Marković, Darka, Kovačević, Aleksandar, Tadić, Vanja, Radoičić, Marija, Barudžija, Tanja, Radetić, Maja, "Аntimicrobial activity of oxidized cotton fabric impregnated with Cu-based nanoparticles" in Book of abstracts / Unfolding the future, 20th World Textile Conference AUTEX 2021, 5 - 9 September 2021, Guimarães, Portugal (2021):102-103,
https://hdl.handle.net/21.15107/rcub_technorep_6864 .

Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid

Marković, Darka; Nunney, Tim; Deeks, Christopher; Radovanović, Željko; Radoičić, Marija; Radetić, Maja

(Meta Basım Press, 2018)

TY  - CONF
AU  - Marković, Darka
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radovanović, Željko
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6495
AB  - This study discusses the possibility of fabrication of antibacterial textile 
nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabric modified 
with oxalic acid. The change in chemical structure of the cotton fibres was assessed by 
FTIR spectroscopy. The presence of Cu-based nanoparticles on the cotton fabric was 
proved by SEM, EDX and AAS analyses. Chemical composition of the fabricated Cu based nanoparticles was evaluated by XPS analysis. Antibacterial activity of the textile 
nanocomposite was tested against Gram-negative bacterium E. coli and Gram-positive 
bacterium S. aureus.
On the basis of the XPS measurements, it was suggested that synthetized nanoparticles 
consisted of metallic Cu/Cu2O and Cu2CO3(OH)2. Fabricated nanocomposite provided 
maximum reduction of both bacterial strains and controlled release of Cu2+
-ions in physiological saline solution which are necessary precondition for infection prevention.
PB  - Meta Basım Press
C3  - 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey
T1  - Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid
EP  - 196
SP  - 189
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6495
ER  - 
@conference{
author = "Marković, Darka and Nunney, Tim and Deeks, Christopher and Radovanović, Željko and Radoičić, Marija and Radetić, Maja",
year = "2018",
abstract = "This study discusses the possibility of fabrication of antibacterial textile 
nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabric modified 
with oxalic acid. The change in chemical structure of the cotton fibres was assessed by 
FTIR spectroscopy. The presence of Cu-based nanoparticles on the cotton fabric was 
proved by SEM, EDX and AAS analyses. Chemical composition of the fabricated Cu based nanoparticles was evaluated by XPS analysis. Antibacterial activity of the textile 
nanocomposite was tested against Gram-negative bacterium E. coli and Gram-positive 
bacterium S. aureus.
On the basis of the XPS measurements, it was suggested that synthetized nanoparticles 
consisted of metallic Cu/Cu2O and Cu2CO3(OH)2. Fabricated nanocomposite provided 
maximum reduction of both bacterial strains and controlled release of Cu2+
-ions in physiological saline solution which are necessary precondition for infection prevention.",
publisher = "Meta Basım Press",
journal = "7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey",
title = "Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid",
pages = "196-189",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6495"
}
Marković, D., Nunney, T., Deeks, C., Radovanović, Ž., Radoičić, M.,& Radetić, M.. (2018). Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid. in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey
Meta Basım Press., 189-196.
https://hdl.handle.net/21.15107/rcub_technorep_6495
Marković D, Nunney T, Deeks C, Radovanović Ž, Radoičić M, Radetić M. Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid. in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey. 2018;:189-196.
https://hdl.handle.net/21.15107/rcub_technorep_6495 .
Marković, Darka, Nunney, Tim, Deeks, Christopher, Radovanović, Željko, Radoičić, Marija, Radetić, Maja, "Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid" in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey (2018):189-196,
https://hdl.handle.net/21.15107/rcub_technorep_6495 .

Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids

Marković, Darka; Nunney, Tim; Deeks, Christopher; Radovanović, Željko; Radoičić, Marija; Radetić, Maja

(Srpsko hemijsko društvo, 2018)

TY  - CONF
AU  - Marković, Darka
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radovanović, Željko
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6552
AB  - U ovom radu je diskutovana mogućnost in situ sinteze nanočestica na bazi Cu na pamučnim
tkaninama prethodno modifikovanim ćilibarnom i limunskom kiselinom u cilju dobijanja
tekstilnih nanokompozita sa antibakterijskom aktivnošću. Utvrđeno je da veći broj
karboksilnih grupa u prekursoru obezbeđuje veći broj slobodnih karboksilnih grupa na
tkanini, a time veću sorpciju Cu2+
-jona iz rastvora CuSO4 i veći sadržaj nanočestica nakon
redukcije. Prisustvo nanočestica na pamučnoj tkanini potvrđeno je SEM analizom, a XPS
analizom je ustanovljeno da se sintetisane nanočestice sastoje iz metalnog Cu/Cu2O i CuO.
Ispitivani nanokompoziti ostvarili su maksimum redukcije bakterija Gram-negativne E. coli i
Gram-pozitivne S. aureus.
PB  - Srpsko hemijsko društvo
C3  - 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
T1  - Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids
EP  - 81
SP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6552
ER  - 
@conference{
author = "Marković, Darka and Nunney, Tim and Deeks, Christopher and Radovanović, Željko and Radoičić, Marija and Radetić, Maja",
year = "2018",
abstract = "U ovom radu je diskutovana mogućnost in situ sinteze nanočestica na bazi Cu na pamučnim
tkaninama prethodno modifikovanim ćilibarnom i limunskom kiselinom u cilju dobijanja
tekstilnih nanokompozita sa antibakterijskom aktivnošću. Utvrđeno je da veći broj
karboksilnih grupa u prekursoru obezbeđuje veći broj slobodnih karboksilnih grupa na
tkanini, a time veću sorpciju Cu2+
-jona iz rastvora CuSO4 i veći sadržaj nanočestica nakon
redukcije. Prisustvo nanočestica na pamučnoj tkanini potvrđeno je SEM analizom, a XPS
analizom je ustanovljeno da se sintetisane nanočestice sastoje iz metalnog Cu/Cu2O i CuO.
Ispitivani nanokompoziti ostvarili su maksimum redukcije bakterija Gram-negativne E. coli i
Gram-pozitivne S. aureus.",
publisher = "Srpsko hemijsko društvo",
journal = "55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova",
title = "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids",
pages = "81-77",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6552"
}
Marković, D., Nunney, T., Deeks, C., Radovanović, Ž., Radoičić, M.,& Radetić, M.. (2018). Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
Srpsko hemijsko društvo., 77-81.
https://hdl.handle.net/21.15107/rcub_technorep_6552
Marković D, Nunney T, Deeks C, Radovanović Ž, Radoičić M, Radetić M. Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova. 2018;:77-81.
https://hdl.handle.net/21.15107/rcub_technorep_6552 .
Marković, Darka, Nunney, Tim, Deeks, Christopher, Radovanović, Željko, Radoičić, Marija, Radetić, Maja, "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids" in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova (2018):77-81,
https://hdl.handle.net/21.15107/rcub_technorep_6552 .

Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles

Marković, Darka; Radoičić, Marija; Radovanović, Željko; Šaponjic, Zoran; Radetić, Maja

(Srpsko hemijsko društvo, 2017)

TY  - CONF
AU  - Marković, Darka
AU  - Radoičić, Marija
AU  - Radovanović, Željko
AU  - Šaponjic, Zoran
AU  - Radetić, Maja
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6553
AB  - U ovom radu je ispitana mogućnost dobijanja kompozitnog tekstilnog materijala na bazi PET
tkanine, polipirola i nanočestica TiO2 sa efikasnom fotokatalitičkom aktivnošću. Prisustvo PPy/TiO2
kompozitnog sloja na površini vlakana je potvrđeno FE-SEM i EDS analizom. Fotokatalitička
aktivnost PET tkanine obrađene polipirolom i nanočesticama TiO2 kao i PET tkanine obrađene
samo nanočesticama TiO2 ispitana je u vodenom rastvoru boje C.I. Acid Orange 7. Rezultati
ispitivanja fotokatalitičke aktivnosti su pokazali da uzorak modifikovan polipirolom i nanočesticama
Beograd, 29. i 30. septembar 2017. 54. savetovanje SHD
127
TiO2 potpuno degradira boju za samo 120 minuta osvetljavanja lampom koja simulira sunčevo
zračenje dok je uzorku modifikovanom nanočesticama TiO2 za to potrebno 24 h. Takođe je utvrđeno
da kompozitni uzorak PET+PPy/TiO2 pokazuje odlična fotokatalitička svojstva u drugom i trećem
ciklusu fotodegradacije. Znatno bolja fotokatalitička aktivnost kompozitnog uzorka u odnosu na
PET tkaninu modifikovanu nanočesticama TiO2 je upravo posledica prisustva polipirola.
PB  - Srpsko hemijsko društvo
C3  - 54. Savetovanje SHD, 29-30. septembar 2017, Beograd, Kratki izvodi i knjiga radova
T1  - Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles
EP  - 127
SP  - 122
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6553
ER  - 
@conference{
author = "Marković, Darka and Radoičić, Marija and Radovanović, Željko and Šaponjic, Zoran and Radetić, Maja",
year = "2017",
abstract = "U ovom radu je ispitana mogućnost dobijanja kompozitnog tekstilnog materijala na bazi PET
tkanine, polipirola i nanočestica TiO2 sa efikasnom fotokatalitičkom aktivnošću. Prisustvo PPy/TiO2
kompozitnog sloja na površini vlakana je potvrđeno FE-SEM i EDS analizom. Fotokatalitička
aktivnost PET tkanine obrađene polipirolom i nanočesticama TiO2 kao i PET tkanine obrađene
samo nanočesticama TiO2 ispitana je u vodenom rastvoru boje C.I. Acid Orange 7. Rezultati
ispitivanja fotokatalitičke aktivnosti su pokazali da uzorak modifikovan polipirolom i nanočesticama
Beograd, 29. i 30. septembar 2017. 54. savetovanje SHD
127
TiO2 potpuno degradira boju za samo 120 minuta osvetljavanja lampom koja simulira sunčevo
zračenje dok je uzorku modifikovanom nanočesticama TiO2 za to potrebno 24 h. Takođe je utvrđeno
da kompozitni uzorak PET+PPy/TiO2 pokazuje odlična fotokatalitička svojstva u drugom i trećem
ciklusu fotodegradacije. Znatno bolja fotokatalitička aktivnost kompozitnog uzorka u odnosu na
PET tkaninu modifikovanu nanočesticama TiO2 je upravo posledica prisustva polipirola.",
publisher = "Srpsko hemijsko društvo",
journal = "54. Savetovanje SHD, 29-30. septembar 2017, Beograd, Kratki izvodi i knjiga radova",
title = "Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles",
pages = "127-122",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6553"
}
Marković, D., Radoičić, M., Radovanović, Ž., Šaponjic, Z.,& Radetić, M.. (2017). Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles. in 54. Savetovanje SHD, 29-30. septembar 2017, Beograd, Kratki izvodi i knjiga radova
Srpsko hemijsko društvo., 122-127.
https://hdl.handle.net/21.15107/rcub_technorep_6553
Marković D, Radoičić M, Radovanović Ž, Šaponjic Z, Radetić M. Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles. in 54. Savetovanje SHD, 29-30. septembar 2017, Beograd, Kratki izvodi i knjiga radova. 2017;:122-127.
https://hdl.handle.net/21.15107/rcub_technorep_6553 .
Marković, Darka, Radoičić, Marija, Radovanović, Željko, Šaponjic, Zoran, Radetić, Maja, "Photocatalytic activity of PET fabric modified with polypyrrole and TiO2 nanoparticles" in 54. Savetovanje SHD, 29-30. septembar 2017, Beograd, Kratki izvodi i knjiga radova (2017):122-127,
https://hdl.handle.net/21.15107/rcub_technorep_6553 .

Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles

Milošević, Milica; Krkobabić, Ana; Lazić, Vesna; Radoičić, Marija; Šaponjić, Zoran; Radetić, Maja

(2016)

TY  - CONF
AU  - Milošević, Milica
AU  - Krkobabić, Ana
AU  - Lazić, Vesna
AU  - Radoičić, Marija
AU  - Šaponjić, Zoran
AU  - Radetić, Maja
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6496
AB  - This study was aimed to elucidate the biodegradation behaviour of cotton and cotton/PET fabrics 
impregnated with Ag/TiO2 nanoparticles in soil. Biodegradation behaviour was assessed according to 
standard test method ASTM 5988-03 and soil burial test, where the extent of biodegradation was 
estimated by the calculation of fabric weight loss. The morphology of fibres affected by biodegradation 
was analysed by SEM. 
The results indicated that Ag/TiO2 nanoparticles inhibit the biodegradation of investigated cotton and 
cotton/PET fabrics. As expected, biodegradation of cotton fabric was considerably more pronounced 
compared to cotton/PET fabric. Larger inhibition of biodegradation of cotton fabrics impregnated with 
Ag/TiO2 nanoparticles compared to impregnated cotton/PET fabrics was not only due to the poor 
biodegradability of PET, but also because of significantly larger content of Ag in the cotton fabric. 
Severe damage of cotton fibres during the biodegradation process was also confirmed by SEM.
C3  - Proceedings 16th World Textile Conference, AUTEX 2016, June 8-10 2016, Ljubljana, Slovenia
T1  - Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles
EP  - 7
SP  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6496
ER  - 
@conference{
author = "Milošević, Milica and Krkobabić, Ana and Lazić, Vesna and Radoičić, Marija and Šaponjić, Zoran and Radetić, Maja",
year = "2016",
abstract = "This study was aimed to elucidate the biodegradation behaviour of cotton and cotton/PET fabrics 
impregnated with Ag/TiO2 nanoparticles in soil. Biodegradation behaviour was assessed according to 
standard test method ASTM 5988-03 and soil burial test, where the extent of biodegradation was 
estimated by the calculation of fabric weight loss. The morphology of fibres affected by biodegradation 
was analysed by SEM. 
The results indicated that Ag/TiO2 nanoparticles inhibit the biodegradation of investigated cotton and 
cotton/PET fabrics. As expected, biodegradation of cotton fabric was considerably more pronounced 
compared to cotton/PET fabric. Larger inhibition of biodegradation of cotton fabrics impregnated with 
Ag/TiO2 nanoparticles compared to impregnated cotton/PET fabrics was not only due to the poor 
biodegradability of PET, but also because of significantly larger content of Ag in the cotton fabric. 
Severe damage of cotton fibres during the biodegradation process was also confirmed by SEM.",
journal = "Proceedings 16th World Textile Conference, AUTEX 2016, June 8-10 2016, Ljubljana, Slovenia",
title = "Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles",
pages = "7-1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6496"
}
Milošević, M., Krkobabić, A., Lazić, V., Radoičić, M., Šaponjić, Z.,& Radetić, M.. (2016). Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles. in Proceedings 16th World Textile Conference, AUTEX 2016, June 8-10 2016, Ljubljana, Slovenia, 1-7.
https://hdl.handle.net/21.15107/rcub_technorep_6496
Milošević M, Krkobabić A, Lazić V, Radoičić M, Šaponjić Z, Radetić M. Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles. in Proceedings 16th World Textile Conference, AUTEX 2016, June 8-10 2016, Ljubljana, Slovenia. 2016;:1-7.
https://hdl.handle.net/21.15107/rcub_technorep_6496 .
Milošević, Milica, Krkobabić, Ana, Lazić, Vesna, Radoičić, Marija, Šaponjić, Zoran, Radetić, Maja, "Biodegradation of cotton and cotton/polyester fabrics impregnated by Ag/TiO2 nanoparticles" in Proceedings 16th World Textile Conference, AUTEX 2016, June 8-10 2016, Ljubljana, Slovenia (2016):1-7,
https://hdl.handle.net/21.15107/rcub_technorep_6496 .

Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles

Milošević, Milica; Radoičić, Marija; Šaponjić, Zoran; Nunney, Tim; Marković, Darka; Nedeljković, Jovan; Jovančić, Petar; Radetić, Maja

(Institute of Textile Machinery and High Performance Material Technology (ITM), 2013)

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Marković, Darka
AU  - Nedeljković, Jovan
AU  - Jovančić, Petar
AU  - Radetić, Maja
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6497
AB  - This study was aimed to highlight the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fibers was proved by XRD, XPS and SEM analyses. Such nanocomposite textile material provides extraordinary antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus and fungus C. albicans. Maximum microbial reduction was maintained after ten washing cycles. Despite good laundering durability, the leaching of silver occurred during washing. Silver release was also detected during the 24 hours long incubation at 37o C in artificial sweat at pH 5.5 and 8.0. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles provided maximum UV protection to polyester fabrics.
PB  - Institute of Textile Machinery and High Performance Material Technology (ITM)
C3  - Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany
T1  - Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles
EP  - 5
SP  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6497
ER  - 
@conference{
author = "Milošević, Milica and Radoičić, Marija and Šaponjić, Zoran and Nunney, Tim and Marković, Darka and Nedeljković, Jovan and Jovančić, Petar and Radetić, Maja",
year = "2013",
abstract = "This study was aimed to highlight the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fibers was proved by XRD, XPS and SEM analyses. Such nanocomposite textile material provides extraordinary antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus and fungus C. albicans. Maximum microbial reduction was maintained after ten washing cycles. Despite good laundering durability, the leaching of silver occurred during washing. Silver release was also detected during the 24 hours long incubation at 37o C in artificial sweat at pH 5.5 and 8.0. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles provided maximum UV protection to polyester fabrics.",
publisher = "Institute of Textile Machinery and High Performance Material Technology (ITM)",
journal = "Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany",
title = "Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles",
pages = "5-1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6497"
}
Milošević, M., Radoičić, M., Šaponjić, Z., Nunney, T., Marković, D., Nedeljković, J., Jovančić, P.,& Radetić, M.. (2013). Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles. in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany
Institute of Textile Machinery and High Performance Material Technology (ITM)., 1-5.
https://hdl.handle.net/21.15107/rcub_technorep_6497
Milošević M, Radoičić M, Šaponjić Z, Nunney T, Marković D, Nedeljković J, Jovančić P, Radetić M. Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles. in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany. 2013;:1-5.
https://hdl.handle.net/21.15107/rcub_technorep_6497 .
Milošević, Milica, Radoičić, Marija, Šaponjić, Zoran, Nunney, Tim, Marković, Darka, Nedeljković, Jovan, Jovančić, Petar, Radetić, Maja, "Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles" in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany (2013):1-5,
https://hdl.handle.net/21.15107/rcub_technorep_6497 .

Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles

Marković, Darka; Šaponjić, Zoran; Radoičić, Marija; Baily, Christopher; Dimitrijević, Suzana; Jovančić, Petar; Nedeljković, Jovan; Radetić, Maja

(Ecole Nationale Supérieure d'Ingénieurs Sud-Alsace, 2011)

TY  - CONF
AU  - Marković, Darka
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
AU  - Baily, Christopher
AU  - Dimitrijević, Suzana
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6493
AB  - The aim of this study was to compare the effects of corona discharge at atmospheric pressure and air RF plasma at low pressure activation of cotton fabrics prior to deposition of colloidal TiO2 nanoparticles in order to enhance antibacterial, UV protective and photocatalytic properties. X-ray photoelectron spectroscopy analysis proved the presence of TiO2 nanoparticles on the surface of cotton fibres. Atomic absorption spectroscopy measurements demonstrated that content of TiO2 in the cotton fabrics pre-treated by corona and RF plasma was 31 % higher than in the fabric that did not undergo any treatment prior to loading of TiO2 nanoparticles. In order to obtain maximum reduction of Gram-negative bacteria E. coli, untreated cotton fabric had to be loaded with colloidal TiO2 nanoparticles twice, but only once following the corona or air RF plasma pre-treatment. Loading of cotton fabrics with TiO2 nanoparticles ensured maximum UV protective rating of 50+. Excellent photocatalytic activity of TiO2 nanoparticles deposited onto cotton fabrics was confirmed by photodegradation of dye methylene blue in aqueous solution under UV illumination.
PB  - Ecole Nationale Supérieure d'Ingénieurs Sud-Alsace
C3  - Proceedings AUTEX 2011 World Textile Conference, 8-10 June 2011, Mulhouse, France
T1  - Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles
EP  - 145
SP  - 141
VL  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6493
ER  - 
@conference{
author = "Marković, Darka and Šaponjić, Zoran and Radoičić, Marija and Baily, Christopher and Dimitrijević, Suzana and Jovančić, Petar and Nedeljković, Jovan and Radetić, Maja",
year = "2011",
abstract = "The aim of this study was to compare the effects of corona discharge at atmospheric pressure and air RF plasma at low pressure activation of cotton fabrics prior to deposition of colloidal TiO2 nanoparticles in order to enhance antibacterial, UV protective and photocatalytic properties. X-ray photoelectron spectroscopy analysis proved the presence of TiO2 nanoparticles on the surface of cotton fibres. Atomic absorption spectroscopy measurements demonstrated that content of TiO2 in the cotton fabrics pre-treated by corona and RF plasma was 31 % higher than in the fabric that did not undergo any treatment prior to loading of TiO2 nanoparticles. In order to obtain maximum reduction of Gram-negative bacteria E. coli, untreated cotton fabric had to be loaded with colloidal TiO2 nanoparticles twice, but only once following the corona or air RF plasma pre-treatment. Loading of cotton fabrics with TiO2 nanoparticles ensured maximum UV protective rating of 50+. Excellent photocatalytic activity of TiO2 nanoparticles deposited onto cotton fabrics was confirmed by photodegradation of dye methylene blue in aqueous solution under UV illumination.",
publisher = "Ecole Nationale Supérieure d'Ingénieurs Sud-Alsace",
journal = "Proceedings AUTEX 2011 World Textile Conference, 8-10 June 2011, Mulhouse, France",
title = "Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles",
pages = "145-141",
volume = "1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6493"
}
Marković, D., Šaponjić, Z., Radoičić, M., Baily, C., Dimitrijević, S., Jovančić, P., Nedeljković, J.,& Radetić, M.. (2011). Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings AUTEX 2011 World Textile Conference, 8-10 June 2011, Mulhouse, France
Ecole Nationale Supérieure d'Ingénieurs Sud-Alsace., 1, 141-145.
https://hdl.handle.net/21.15107/rcub_technorep_6493
Marković D, Šaponjić Z, Radoičić M, Baily C, Dimitrijević S, Jovančić P, Nedeljković J, Radetić M. Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings AUTEX 2011 World Textile Conference, 8-10 June 2011, Mulhouse, France. 2011;1:141-145.
https://hdl.handle.net/21.15107/rcub_technorep_6493 .
Marković, Darka, Šaponjić, Zoran, Radoičić, Marija, Baily, Christopher, Dimitrijević, Suzana, Jovančić, Petar, Nedeljković, Jovan, Radetić, Maja, "Multifunctional Properties of Cotton Fabrics Modified with Corona/Air RF Plasma and Colloidal TiO2 Nanoparticles" in Proceedings AUTEX 2011 World Textile Conference, 8-10 June 2011, Mulhouse, France, 1 (2011):141-145,
https://hdl.handle.net/21.15107/rcub_technorep_6493 .

Polyester Fabrics Modified with Alginates and TiO2 nanoparticles

Mihailović, Darka; Šaponjić, Zoran; Radoičić, Marija; Radetić, Tamara; Dimitrijević, Suzana; Jovančić, Petar; Nedeljković, Jovan; Radetić, Maja

(Kaunas University of Technology, Faculty od Design and Technologies, Department of Textile Technology, 2010)

TY  - CONF
AU  - Mihailović, Darka
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
AU  - Radetić, Tamara
AU  - Dimitrijević, Suzana
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6499
AB  - This study discusses the possibility of engineering the multifunctional nanocomposite textile material based on the polyester fabric modified with alginates and colloidal TiO2 nanoparticles. This material exhibited excellent antibacterial properties against Gram-negative bacterium E. coli, which were preserved after five washing cycles. The deposition of TiO2
nanoparticles onto polyester fabrics ensured maximum UV protection. TiO2 nanoparticles deposited onto the polyester fabric previously coated with alginates provided total 
 photodegradation of methylene blue in aqueous solution after 24 hours of UV illumination.
PB  - Kaunas University of Technology, Faculty od Design and Technologies, Department of Textile Technology
C3  - Proceedings AUTEX 2010 World Textile Conference, 21-23 June 2010, Vilnius, Lithuania
T1  - Polyester Fabrics Modified with Alginates and TiO2 nanoparticles
EP  - 4
SP  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6499
ER  - 
@conference{
author = "Mihailović, Darka and Šaponjić, Zoran and Radoičić, Marija and Radetić, Tamara and Dimitrijević, Suzana and Jovančić, Petar and Nedeljković, Jovan and Radetić, Maja",
year = "2010",
abstract = "This study discusses the possibility of engineering the multifunctional nanocomposite textile material based on the polyester fabric modified with alginates and colloidal TiO2 nanoparticles. This material exhibited excellent antibacterial properties against Gram-negative bacterium E. coli, which were preserved after five washing cycles. The deposition of TiO2
nanoparticles onto polyester fabrics ensured maximum UV protection. TiO2 nanoparticles deposited onto the polyester fabric previously coated with alginates provided total 
 photodegradation of methylene blue in aqueous solution after 24 hours of UV illumination.",
publisher = "Kaunas University of Technology, Faculty od Design and Technologies, Department of Textile Technology",
journal = "Proceedings AUTEX 2010 World Textile Conference, 21-23 June 2010, Vilnius, Lithuania",
title = "Polyester Fabrics Modified with Alginates and TiO2 nanoparticles",
pages = "4-1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6499"
}
Mihailović, D., Šaponjić, Z., Radoičić, M., Radetić, T., Dimitrijević, S., Jovančić, P., Nedeljković, J.,& Radetić, M.. (2010). Polyester Fabrics Modified with Alginates and TiO2 nanoparticles. in Proceedings AUTEX 2010 World Textile Conference, 21-23 June 2010, Vilnius, Lithuania
Kaunas University of Technology, Faculty od Design and Technologies, Department of Textile Technology., 1-4.
https://hdl.handle.net/21.15107/rcub_technorep_6499
Mihailović D, Šaponjić Z, Radoičić M, Radetić T, Dimitrijević S, Jovančić P, Nedeljković J, Radetić M. Polyester Fabrics Modified with Alginates and TiO2 nanoparticles. in Proceedings AUTEX 2010 World Textile Conference, 21-23 June 2010, Vilnius, Lithuania. 2010;:1-4.
https://hdl.handle.net/21.15107/rcub_technorep_6499 .
Mihailović, Darka, Šaponjić, Zoran, Radoičić, Marija, Radetić, Tamara, Dimitrijević, Suzana, Jovančić, Petar, Nedeljković, Jovan, Radetić, Maja, "Polyester Fabrics Modified with Alginates and TiO2 nanoparticles" in Proceedings AUTEX 2010 World Textile Conference, 21-23 June 2010, Vilnius, Lithuania (2010):1-4,
https://hdl.handle.net/21.15107/rcub_technorep_6499 .

Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2

Mihailović, Darka; Šaponjić, Zoran; Radoičić, Marija; Potkonjak, Branislav; Dimitrijević, Suzana; Jovančić, Petar; Nedeljković, Jovan; Radetić, Maja

(Srpsko hemijsko društvo, 2010)

TY  - CONF
AU  - Mihailović, Darka
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
AU  - Potkonjak, Branislav
AU  - Dimitrijević, Suzana
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6562
PB  - Srpsko hemijsko društvo
C3  - 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova
T1  - Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2
EP  - 274
SP  - 271
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6562
ER  - 
@conference{
author = "Mihailović, Darka and Šaponjić, Zoran and Radoičić, Marija and Potkonjak, Branislav and Dimitrijević, Suzana and Jovančić, Petar and Nedeljković, Jovan and Radetić, Maja",
year = "2010",
publisher = "Srpsko hemijsko društvo",
journal = "48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova",
title = "Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2",
pages = "274-271",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6562"
}
Mihailović, D., Šaponjić, Z., Radoičić, M., Potkonjak, B., Dimitrijević, S., Jovančić, P., Nedeljković, J.,& Radetić, M.. (2010). Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2. in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova
Srpsko hemijsko društvo., 271-274.
https://hdl.handle.net/21.15107/rcub_technorep_6562
Mihailović D, Šaponjić Z, Radoičić M, Potkonjak B, Dimitrijević S, Jovančić P, Nedeljković J, Radetić M. Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2. in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova. 2010;:271-274.
https://hdl.handle.net/21.15107/rcub_technorep_6562 .
Mihailović, Darka, Šaponjić, Zoran, Radoičić, Marija, Potkonjak, Branislav, Dimitrijević, Suzana, Jovančić, Petar, Nedeljković, Jovan, Radetić, Maja, "Multifunkcionalna svojstva pamučne tkanine modifikovane koronom i koloidnim nanočesticama TiO2" in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova (2010):271-274,
https://hdl.handle.net/21.15107/rcub_technorep_6562 .

Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama

Stanković, Snežana; Mihailović, Darka; Šaponjic, Zoran; Radoičić, Marija; Puač, Nevena; Jovančić, Petar; Nedeljković, Jovan; Radetić, Maja

(Srpsko hemijsko društvo, 2010)

TY  - CONF
AU  - Stanković, Snežana
AU  - Mihailović, Darka
AU  - Šaponjic, Zoran
AU  - Radoičić, Marija
AU  - Puač, Nevena
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6560
PB  - Srpsko hemijsko društvo
C3  - 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova
T1  - Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama
EP  - 286
SP  - 283
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6560
ER  - 
@conference{
author = "Stanković, Snežana and Mihailović, Darka and Šaponjic, Zoran and Radoičić, Marija and Puač, Nevena and Jovančić, Petar and Nedeljković, Jovan and Radetić, Maja",
year = "2010",
publisher = "Srpsko hemijsko društvo",
journal = "48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova",
title = "Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama",
pages = "286-283",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6560"
}
Stanković, S., Mihailović, D., Šaponjic, Z., Radoičić, M., Puač, N., Jovančić, P., Nedeljković, J.,& Radetić, M.. (2010). Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama. in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova
Srpsko hemijsko društvo., 283-286.
https://hdl.handle.net/21.15107/rcub_technorep_6560
Stanković S, Mihailović D, Šaponjic Z, Radoičić M, Puač N, Jovančić P, Nedeljković J, Radetić M. Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama. in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova. 2010;:283-286.
https://hdl.handle.net/21.15107/rcub_technorep_6560 .
Stanković, Snežana, Mihailović, Darka, Šaponjic, Zoran, Radoičić, Marija, Puač, Nevena, Jovančić, Petar, Nedeljković, Jovan, Radetić, Maja, "Kompresiona svojstva PES tkanine modifikovane RF plazmom i TiO2 nanočesticama" in 48. Savetovanje Srpskog Hemijskog Društva, Novi Sad, 17-18. 04. 2010, Zbornik radova (2010):283-286,
https://hdl.handle.net/21.15107/rcub_technorep_6560 .

Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles

Mihailović, Darka; Radetić, Maja; Radoičić, Marija; Molina, Ricardo; Puač, Nevena; Jovančić, Petar; Nedeljković, Jovan; Šaponjic, Zoran

(Department of Materials, Textiles and Chemical Engineering, 2009)

TY  - CONF
AU  - Mihailović, Darka
AU  - Radetić, Maja
AU  - Radoičić, Marija
AU  - Molina, Ricardo
AU  - Puač, Nevena
AU  - Jovančić, Petar
AU  - Nedeljković, Jovan
AU  - Šaponjic, Zoran
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6501
AB  - This study was aimed to examine the possibility of using RF plasma at low pressure for the surface activation of polyester fabrics in order to improve the binding efficiency of colloidal TiO2 nanoparticles. Colloidal TiO2 nanoparticles were synthesized without stabilizers by acid hydrolysis method. Air and argon were used as plasma gases. Polyester fabrics modified by RF plasma and TiO2 nanoparticles exhibited excellent antibacterial efficiency against E. coli which was preserved after five washing cycles. The presence of TiO2 nanoparticles contributed to a significant increase in UV protection factor (UPF) of fabrics. These values correspond to UPF rating of 50+, which designates the maximum UV protection. Additionally, irradiated polyester fabrics loaded with TiO2 nanoparticles demonstrated satisfactory self-cleaning efficiency.
PB  - Department of Materials, Textiles and Chemical Engineering
C3  - Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium
T1  - Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles
EP  - 218
SP  - 213
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6501
ER  - 
@conference{
author = "Mihailović, Darka and Radetić, Maja and Radoičić, Marija and Molina, Ricardo and Puač, Nevena and Jovančić, Petar and Nedeljković, Jovan and Šaponjic, Zoran",
year = "2009",
abstract = "This study was aimed to examine the possibility of using RF plasma at low pressure for the surface activation of polyester fabrics in order to improve the binding efficiency of colloidal TiO2 nanoparticles. Colloidal TiO2 nanoparticles were synthesized without stabilizers by acid hydrolysis method. Air and argon were used as plasma gases. Polyester fabrics modified by RF plasma and TiO2 nanoparticles exhibited excellent antibacterial efficiency against E. coli which was preserved after five washing cycles. The presence of TiO2 nanoparticles contributed to a significant increase in UV protection factor (UPF) of fabrics. These values correspond to UPF rating of 50+, which designates the maximum UV protection. Additionally, irradiated polyester fabrics loaded with TiO2 nanoparticles demonstrated satisfactory self-cleaning efficiency.",
publisher = "Department of Materials, Textiles and Chemical Engineering",
journal = "Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium",
title = "Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles",
pages = "218-213",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6501"
}
Mihailović, D., Radetić, M., Radoičić, M., Molina, R., Puač, N., Jovančić, P., Nedeljković, J.,& Šaponjic, Z.. (2009). Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium
Department of Materials, Textiles and Chemical Engineering., 213-218.
https://hdl.handle.net/21.15107/rcub_technorep_6501
Mihailović D, Radetić M, Radoičić M, Molina R, Puač N, Jovančić P, Nedeljković J, Šaponjic Z. Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles. in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium. 2009;:213-218.
https://hdl.handle.net/21.15107/rcub_technorep_6501 .
Mihailović, Darka, Radetić, Maja, Radoičić, Marija, Molina, Ricardo, Puač, Nevena, Jovančić, Petar, Nedeljković, Jovan, Šaponjic, Zoran, "Specific Properties of Polyester Fabrics Functionalized by RF Plasma and Colloidal TiO2 Nanoparticles" in Proceedings International Conference:. Latest Advances in High Tech Textiles and Textile-based Materials, 23-25 September, 2009, Ghent, Belgium (2009):213-218,
https://hdl.handle.net/21.15107/rcub_technorep_6501 .

The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide)

Pepić, Dragana; Radoičić, Marija; Nikolić, Marija; Đonlagić, Jasna

(Serbian Chemical Society, Belgrade, 2007)

TY  - JOUR
AU  - Pepić, Dragana
AU  - Radoičić, Marija
AU  - Nikolić, Marija
AU  - Đonlagić, Jasna
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1104
AB  - Novel poly(ester-ether)s based on poly(butylene succinate) (PBS) as the hard segments and 30 mass % of poly(propylene oxide) (PPO) as the soft segments were synthesized with varying amount of the antioxidant (N,N'-diphenyl-p-phenylenediamine, DPPD). The influences of the addition of DPPD and the impact of post-synthetic treatment by precipitation on the molecular structure, thermal and physical properties, as well as on the storage stability of the biodegradable aliphatic copolyesters, were investigated. The structure and composition of the copolymers were determined by means of 1H-NMR spectroscopy. The molecular weight and polydispersity of the poly(ester-ether)s were evaluated from solution viscosity and GPC measurements. The thermal properties and stability were evaluated, respecttively, by means of DSC and non-isothermal thermogravimetry in an inert nitrogen atmosphere. The biodegradability potential of the polymers was studied in hydrolytic and enzymatic degradation tests with Candida cylindracea lipase by monitoring the weight loss of polymer films after incubation. The weight losses of the samples increased with time and were in the range from 1 to 5 mass % after 4 weeks. GPC analysis confirmed that there were changes in the molecular weight of the copolyesters during both hydrolytic and enzymatic degradation tests, leading to the conclusion that the degradation mechanism of poly(butylene succinate)s modified with PPO occurred through surface erosion and bulk degradation.
AB  - U okviru ovog rada sintetisani su novi poli(estar-etri) na bazi poli(butilen sukcinata) (PBS) kao tvrdih segmenata i 30 masenih % poli(propilenoksida) (PPO) ugrađenih u meke segmente, bez i u prisustvu antioksidansa N,N′-difenil-p-fenilendiamina (DPPD). Izučavao se uticaj antioksiodansa DPPD kao i načina izdvajanja polimera, odnosno pretaložavanja na strukturu i veličinu molekula, termička i fizička svojstva kao i na stabilnost biodegradabilnih alifatskih kopoliestara. Struktura i sastav kopoliestara su provereni 1H-NMR spektroskopijom. Veličina molekula i raspodela veličina molekula sintetisanih poli(estar-etara) su određeni viskozimetrijom razblaženih rastvora i GPC analizom. Termička svojstva i termička stabilnost poli(estar-etara) su analizirana DSC i neizotermskom termogravimetrijom u inertnoj atmosferi azota. Biodegradabilni potencijal polimera je izučavan u ogledima hidrolotičke i enzimske degradacije u prisustvu lipaze Candida cylindracea prateći promene u masi polimernih filmova tokom inkubacije. Gubici su rasli sa vremenom i posle 4 nedelje su bili u opsegu od 1 do 5 masenih %. GPC analiza je potvrdila da postoje promene u molarnoj masi uzoraka i u ogledima hidrolitičke i enzimske degradacije na osnovu čega se može zaključiti da se mehanizam degradacije poli(estar-etara) na bazi PPO odvija kroz eroziju površine i degradaciju u masi.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide)
T1  - Uticaj antioksiodansa i načina izdvajanja polimera na svojstva biodegradabilnih poli(butilen sukcinata) modifikovanih poli(propilenoksidom)
EP  - 1531
IS  - 12
SP  - 1515
VL  - 72
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1104
ER  - 
@article{
author = "Pepić, Dragana and Radoičić, Marija and Nikolić, Marija and Đonlagić, Jasna",
year = "2007",
abstract = "Novel poly(ester-ether)s based on poly(butylene succinate) (PBS) as the hard segments and 30 mass % of poly(propylene oxide) (PPO) as the soft segments were synthesized with varying amount of the antioxidant (N,N'-diphenyl-p-phenylenediamine, DPPD). The influences of the addition of DPPD and the impact of post-synthetic treatment by precipitation on the molecular structure, thermal and physical properties, as well as on the storage stability of the biodegradable aliphatic copolyesters, were investigated. The structure and composition of the copolymers were determined by means of 1H-NMR spectroscopy. The molecular weight and polydispersity of the poly(ester-ether)s were evaluated from solution viscosity and GPC measurements. The thermal properties and stability were evaluated, respecttively, by means of DSC and non-isothermal thermogravimetry in an inert nitrogen atmosphere. The biodegradability potential of the polymers was studied in hydrolytic and enzymatic degradation tests with Candida cylindracea lipase by monitoring the weight loss of polymer films after incubation. The weight losses of the samples increased with time and were in the range from 1 to 5 mass % after 4 weeks. GPC analysis confirmed that there were changes in the molecular weight of the copolyesters during both hydrolytic and enzymatic degradation tests, leading to the conclusion that the degradation mechanism of poly(butylene succinate)s modified with PPO occurred through surface erosion and bulk degradation., U okviru ovog rada sintetisani su novi poli(estar-etri) na bazi poli(butilen sukcinata) (PBS) kao tvrdih segmenata i 30 masenih % poli(propilenoksida) (PPO) ugrađenih u meke segmente, bez i u prisustvu antioksidansa N,N′-difenil-p-fenilendiamina (DPPD). Izučavao se uticaj antioksiodansa DPPD kao i načina izdvajanja polimera, odnosno pretaložavanja na strukturu i veličinu molekula, termička i fizička svojstva kao i na stabilnost biodegradabilnih alifatskih kopoliestara. Struktura i sastav kopoliestara su provereni 1H-NMR spektroskopijom. Veličina molekula i raspodela veličina molekula sintetisanih poli(estar-etara) su određeni viskozimetrijom razblaženih rastvora i GPC analizom. Termička svojstva i termička stabilnost poli(estar-etara) su analizirana DSC i neizotermskom termogravimetrijom u inertnoj atmosferi azota. Biodegradabilni potencijal polimera je izučavan u ogledima hidrolotičke i enzimske degradacije u prisustvu lipaze Candida cylindracea prateći promene u masi polimernih filmova tokom inkubacije. Gubici su rasli sa vremenom i posle 4 nedelje su bili u opsegu od 1 do 5 masenih %. GPC analiza je potvrdila da postoje promene u molarnoj masi uzoraka i u ogledima hidrolitičke i enzimske degradacije na osnovu čega se može zaključiti da se mehanizam degradacije poli(estar-etara) na bazi PPO odvija kroz eroziju površine i degradaciju u masi.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide), Uticaj antioksiodansa i načina izdvajanja polimera na svojstva biodegradabilnih poli(butilen sukcinata) modifikovanih poli(propilenoksidom)",
pages = "1531-1515",
number = "12",
volume = "72",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1104"
}
Pepić, D., Radoičić, M., Nikolić, M.,& Đonlagić, J.. (2007). The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide). in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 72(12), 1515-1531.
https://hdl.handle.net/21.15107/rcub_technorep_1104
Pepić D, Radoičić M, Nikolić M, Đonlagić J. The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide). in Journal of the Serbian Chemical Society. 2007;72(12):1515-1531.
https://hdl.handle.net/21.15107/rcub_technorep_1104 .
Pepić, Dragana, Radoičić, Marija, Nikolić, Marija, Đonlagić, Jasna, "The influence of antioxidant and post-synthetic treatment on the properties of biodegradable poly(butylene succinate)s modified with poly(propylene oxide)" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1515-1531,
https://hdl.handle.net/21.15107/rcub_technorep_1104 .
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