TY  - JOUR
AU  - Marković, Darka
AU  - Tseng, Hsiang-Han
AU  - Nunney, Tim
AU  - Radoicić, Marija
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4391
AB  - The objective of this study was to develop novel antimicrobial nanocomposite material based on polypropylene (PP) non-woven fabric, biopolymer alginate and copper oxides nanoparticles. In order to introduce polar groups onto the surface of PP fibers necessary for binding of alginate, non-woven fabric was activated by corona discharge. Carboxylate groups of alginate were further utilized for binding of Cu2+-ions which were reduced with sodium borohydride as a conventional and ascorbic acid as a green reducing agent. Characteristic morphological and chemical changes induced by corona activation and alginate impregnation were confirmed by FTIR, XPS and FESEM analyses. AAS measurements showed that the amounts of generated nanoparticles depend on applied reducing agent and the concentration of precursor salt. XPS analysis suggested that nanoparticles were mixture of copper (I) and (II) oxides. XPS depth profiling gave an exceptional insight into chemical changes within the thin layer on the fiber surface and formation of certain interfaces induced by each treatment. All fabricated nanocomposites provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. The cytotoxicity assay indicated that maximum amount of Cu2+-ions released from synthetized nanocomposite within 24 h was not cytotoxic to human keratinocyte (HaCaT) cells.
PB  - Elsevier, Amsterdam
T2  - Applied Surface Science
T1  - Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles
VL  - 527
DO  - 10.1016/j.apsusc.2020.146829
ER  - 

@article{
author = "Marković, Darka and Tseng, Hsiang-Han and Nunney, Tim and Radoicić, Marija and Ilić-Tomić, Tatjana and Radetić, Maja",
year = "2020",
abstract = "The objective of this study was to develop novel antimicrobial nanocomposite material based on polypropylene (PP) non-woven fabric, biopolymer alginate and copper oxides nanoparticles. In order to introduce polar groups onto the surface of PP fibers necessary for binding of alginate, non-woven fabric was activated by corona discharge. Carboxylate groups of alginate were further utilized for binding of Cu2+-ions which were reduced with sodium borohydride as a conventional and ascorbic acid as a green reducing agent. Characteristic morphological and chemical changes induced by corona activation and alginate impregnation were confirmed by FTIR, XPS and FESEM analyses. AAS measurements showed that the amounts of generated nanoparticles depend on applied reducing agent and the concentration of precursor salt. XPS analysis suggested that nanoparticles were mixture of copper (I) and (II) oxides. XPS depth profiling gave an exceptional insight into chemical changes within the thin layer on the fiber surface and formation of certain interfaces induced by each treatment. All fabricated nanocomposites provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. The cytotoxicity assay indicated that maximum amount of Cu2+-ions released from synthetized nanocomposite within 24 h was not cytotoxic to human keratinocyte (HaCaT) cells.",
publisher = "Elsevier, Amsterdam",
journal = "Applied Surface Science",
title = "Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles",
volume = "527",
doi = "10.1016/j.apsusc.2020.146829"
}

Marković, D., Tseng, H., Nunney, T., Radoicić, M., Ilić-Tomić, T.,& Radetić, M.. (2020). Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles. in Applied Surface Science
Elsevier, Amsterdam., 527.
https://doi.org/10.1016/j.apsusc.2020.146829

Marković D, Tseng H, Nunney T, Radoicić M, Ilić-Tomić T, Radetić M. Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles. in Applied Surface Science. 2020;527.
doi:10.1016/j.apsusc.2020.146829 .

Marković, Darka, Tseng, Hsiang-Han, Nunney, Tim, Radoicić, Marija, Ilić-Tomić, Tatjana, Radetić, Maja, "Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles" in Applied Surface Science, 527 (2020),
https://doi.org/10.1016/j.apsusc.2020.146829 . .

TY  - JOUR
AU  - Marković, Darka
AU  - Ašanin, Jelena
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Mišić, Dušan
AU  - Radetić, Maja
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4106
AB  - This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours.
PB  - Korean Fiber Soc, Seoul
T2  - Fibers and Polymers
T1  - Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles
EP  - 2325
IS  - 11
SP  - 2317
VL  - 20
DO  - 10.1007/s12221-019-9131-5
ER  - 

@article{
author = "Marković, Darka and Ašanin, Jelena and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja",
year = "2019",
abstract = "This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours.",
publisher = "Korean Fiber Soc, Seoul",
journal = "Fibers and Polymers",
title = "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles",
pages = "2325-2317",
number = "11",
volume = "20",
doi = "10.1007/s12221-019-9131-5"
}

Marković, D., Ašanin, J., Nunney, T., Radovanović, Ž., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M.. (2019). Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers
Korean Fiber Soc, Seoul., 20(11), 2317-2325.
https://doi.org/10.1007/s12221-019-9131-5

Marković D, Ašanin J, Nunney T, Radovanović Ž, Radoičić MB, Mitrić M, Mišić D, Radetić M. Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers. 2019;20(11):2317-2325.
doi:10.1007/s12221-019-9131-5 .

Marković, Darka, Ašanin, Jelena, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja, "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles" in Fibers and Polymers, 20, no. 11 (2019):2317-2325,
https://doi.org/10.1007/s12221-019-9131-5 . .

TY  - CONF
AU  - Marković, Darka
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radovanović, Željko
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6495
AB  - This study discusses the possibility of fabrication of antibacterial textile 
nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabric modified 
with oxalic acid. The change in chemical structure of the cotton fibres was assessed by 
FTIR spectroscopy. The presence of Cu-based nanoparticles on the cotton fabric was 
proved by SEM, EDX and AAS analyses. Chemical composition of the fabricated Cu based nanoparticles was evaluated by XPS analysis. Antibacterial activity of the textile 
nanocomposite was tested against Gram-negative bacterium E. coli and Gram-positive 
bacterium S. aureus.
On the basis of the XPS measurements, it was suggested that synthetized nanoparticles 
consisted of metallic Cu/Cu2O and Cu2CO3(OH)2. Fabricated nanocomposite provided 
maximum reduction of both bacterial strains and controlled release of Cu2+
-ions in physiological saline solution which are necessary precondition for infection prevention.
PB  - Meta Basım Press
C3  - 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey
T1  - Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid
EP  - 196
SP  - 189
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6495
ER  - 

@conference{
author = "Marković, Darka and Nunney, Tim and Deeks, Christopher and Radovanović, Željko and Radoičić, Marija and Radetić, Maja",
year = "2018",
abstract = "This study discusses the possibility of fabrication of antibacterial textile 
nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabric modified 
with oxalic acid. The change in chemical structure of the cotton fibres was assessed by 
FTIR spectroscopy. The presence of Cu-based nanoparticles on the cotton fabric was 
proved by SEM, EDX and AAS analyses. Chemical composition of the fabricated Cu based nanoparticles was evaluated by XPS analysis. Antibacterial activity of the textile 
nanocomposite was tested against Gram-negative bacterium E. coli and Gram-positive 
bacterium S. aureus.
On the basis of the XPS measurements, it was suggested that synthetized nanoparticles 
consisted of metallic Cu/Cu2O and Cu2CO3(OH)2. Fabricated nanocomposite provided 
maximum reduction of both bacterial strains and controlled release of Cu2+
-ions in physiological saline solution which are necessary precondition for infection prevention.",
publisher = "Meta Basım Press",
journal = "7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey",
title = "Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid",
pages = "196-189",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6495"
}

Marković, D., Nunney, T., Deeks, C., Radovanović, Ž., Radoičić, M.,& Radetić, M.. (2018). Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid. in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey
Meta Basım Press., 189-196.
https://hdl.handle.net/21.15107/rcub_technorep_6495

Marković D, Nunney T, Deeks C, Radovanović Ž, Radoičić M, Radetić M. Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid. in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey. 2018;:189-196.
https://hdl.handle.net/21.15107/rcub_technorep_6495 .

Marković, Darka, Nunney, Tim, Deeks, Christopher, Radovanović, Željko, Radoičić, Marija, Radetić, Maja, "Antibacterial activity of copper-based nanoparticles synthetized on cotton fabric previously modified with oxalic acid" in 7th International Technical Textile Congress, Proceedings Book, 10-12.10.2018. Izmir, Turkey (2018):189-196,
https://hdl.handle.net/21.15107/rcub_technorep_6495 .

TY  - CONF
AU  - Marković, Darka
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radovanović, Željko
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6552
AB  - U ovom radu je diskutovana mogućnost in situ sinteze nanočestica na bazi Cu na pamučnim
tkaninama prethodno modifikovanim ćilibarnom i limunskom kiselinom u cilju dobijanja
tekstilnih nanokompozita sa antibakterijskom aktivnošću. Utvrđeno je da veći broj
karboksilnih grupa u prekursoru obezbeđuje veći broj slobodnih karboksilnih grupa na
tkanini, a time veću sorpciju Cu2+
-jona iz rastvora CuSO4 i veći sadržaj nanočestica nakon
redukcije. Prisustvo nanočestica na pamučnoj tkanini potvrđeno je SEM analizom, a XPS
analizom je ustanovljeno da se sintetisane nanočestice sastoje iz metalnog Cu/Cu2O i CuO.
Ispitivani nanokompoziti ostvarili su maksimum redukcije bakterija Gram-negativne E. coli i
Gram-pozitivne S. aureus.
PB  - Srpsko hemijsko društvo
C3  - 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
T1  - Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids
EP  - 81
SP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6552
ER  - 

@conference{
author = "Marković, Darka and Nunney, Tim and Deeks, Christopher and Radovanović, Željko and Radoičić, Marija and Radetić, Maja",
year = "2018",
abstract = "U ovom radu je diskutovana mogućnost in situ sinteze nanočestica na bazi Cu na pamučnim
tkaninama prethodno modifikovanim ćilibarnom i limunskom kiselinom u cilju dobijanja
tekstilnih nanokompozita sa antibakterijskom aktivnošću. Utvrđeno je da veći broj
karboksilnih grupa u prekursoru obezbeđuje veći broj slobodnih karboksilnih grupa na
tkanini, a time veću sorpciju Cu2+
-jona iz rastvora CuSO4 i veći sadržaj nanočestica nakon
redukcije. Prisustvo nanočestica na pamučnoj tkanini potvrđeno je SEM analizom, a XPS
analizom je ustanovljeno da se sintetisane nanočestice sastoje iz metalnog Cu/Cu2O i CuO.
Ispitivani nanokompoziti ostvarili su maksimum redukcije bakterija Gram-negativne E. coli i
Gram-pozitivne S. aureus.",
publisher = "Srpsko hemijsko društvo",
journal = "55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova",
title = "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids",
pages = "81-77",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6552"
}

Marković, D., Nunney, T., Deeks, C., Radovanović, Ž., Radoičić, M.,& Radetić, M.. (2018). Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
Srpsko hemijsko društvo., 77-81.
https://hdl.handle.net/21.15107/rcub_technorep_6552

Marković D, Nunney T, Deeks C, Radovanović Ž, Radoičić M, Radetić M. Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova. 2018;:77-81.
https://hdl.handle.net/21.15107/rcub_technorep_6552 .

Marković, Darka, Nunney, Tim, Deeks, Christopher, Radovanović, Željko, Radoičić, Marija, Radetić, Maja, "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics previously modified with succinic and citric acids" in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova (2018):77-81,
https://hdl.handle.net/21.15107/rcub_technorep_6552 .

TY  - CONF
AU  - Marković, Darka
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radovanović, Željko
AU  - Šaponjic, Zoran
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6551
AB  - U ovom radu je ispitana mogućnost in situ sinteze nanočestica Cu2O/CuO na pamučnoj
tkanini prethodno modifikovanoj 1,2,3,4-butantetrakarboksilnom kiselinom (BTCA) različitih
koncentracija sa ciljem postizanja antibakterijske zaštite. Utvrđeno je da se većom
koncentracijom BTCA postiže bolja sorpcija Cu2+
-jona iz rastvora CuSO4 i veći sadržaj
nanočestica nakon redukcije. Prisustvo nanočestica na pamučnoj tkanini dokazano je FESEM
analizom. XPS i XRD analizama je ustanovljeno da sintetisane nanočestice predstavljaju
smešu Cu2O i CuO. Dobijeni tekstilni nanokompoziti obezbeđuju odličnu antibakterijsku
zaštitu prema Gram-negativnoj bakteriji E. coli i Gram-pozitivnoj bakteriji S. aureus koja
zavisi od količine sintetisanih nanočestica Cu2O/CuO.
PB  - Srpsko hemijsko društvo
C3  - 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
T1  - The influence of 1,2,3,4-butantetracarboxylic acid on in situ synthesis of Cu2O/CuO nanoparticles on the cotton fabric and its antibacterial activty
EP  - 87
SP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6551
ER  - 

@conference{
author = "Marković, Darka and Nunney, Tim and Deeks, Christopher and Radovanović, Željko and Šaponjic, Zoran and Radetić, Maja",
year = "2018",
abstract = "U ovom radu je ispitana mogućnost in situ sinteze nanočestica Cu2O/CuO na pamučnoj
tkanini prethodno modifikovanoj 1,2,3,4-butantetrakarboksilnom kiselinom (BTCA) različitih
koncentracija sa ciljem postizanja antibakterijske zaštite. Utvrđeno je da se većom
koncentracijom BTCA postiže bolja sorpcija Cu2+
-jona iz rastvora CuSO4 i veći sadržaj
nanočestica nakon redukcije. Prisustvo nanočestica na pamučnoj tkanini dokazano je FESEM
analizom. XPS i XRD analizama je ustanovljeno da sintetisane nanočestice predstavljaju
smešu Cu2O i CuO. Dobijeni tekstilni nanokompoziti obezbeđuju odličnu antibakterijsku
zaštitu prema Gram-negativnoj bakteriji E. coli i Gram-pozitivnoj bakteriji S. aureus koja
zavisi od količine sintetisanih nanočestica Cu2O/CuO.",
publisher = "Srpsko hemijsko društvo",
journal = "55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova",
title = "The influence of 1,2,3,4-butantetracarboxylic acid on in situ synthesis of Cu2O/CuO nanoparticles on the cotton fabric and its antibacterial activty",
pages = "87-82",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6551"
}

Marković, D., Nunney, T., Deeks, C., Radovanović, Ž., Šaponjic, Z.,& Radetić, M.. (2018). The influence of 1,2,3,4-butantetracarboxylic acid on in situ synthesis of Cu2O/CuO nanoparticles on the cotton fabric and its antibacterial activty. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova
Srpsko hemijsko društvo., 82-87.
https://hdl.handle.net/21.15107/rcub_technorep_6551

Marković D, Nunney T, Deeks C, Radovanović Ž, Šaponjic Z, Radetić M. The influence of 1,2,3,4-butantetracarboxylic acid on in situ synthesis of Cu2O/CuO nanoparticles on the cotton fabric and its antibacterial activty. in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova. 2018;:82-87.
https://hdl.handle.net/21.15107/rcub_technorep_6551 .

Marković, Darka, Nunney, Tim, Deeks, Christopher, Radovanović, Željko, Šaponjic, Zoran, Radetić, Maja, "The influence of 1,2,3,4-butantetracarboxylic acid on in situ synthesis of Cu2O/CuO nanoparticles on the cotton fabric and its antibacterial activty" in 55. Savetovanje SHD, 8-9. jun 2018, Novi Sad, Knjiga radova (2018):82-87,
https://hdl.handle.net/21.15107/rcub_technorep_6551 .

TY  - JOUR
AU  - Marković, Darka
AU  - Deeks, Christopher
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3850
AB  - The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.
PB  - Elsevier Sci Ltd, Oxford
T2  - Carbohydrate Polymers
T1  - Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids
EP  - 182
SP  - 173
VL  - 200
DO  - 10.1016/j.carbpol.2018.08.001
ER  - 

@article{
author = "Marković, Darka and Deeks, Christopher and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Šaponjić, Zoran and Radetić, Maja",
year = "2018",
abstract = "The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Carbohydrate Polymers",
title = "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids",
pages = "182-173",
volume = "200",
doi = "10.1016/j.carbpol.2018.08.001"
}

Marković, D., Deeks, C., Nunney, T., Radovanović, Ž., Radoičić, M. B., Šaponjić, Z.,& Radetić, M.. (2018). Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers
Elsevier Sci Ltd, Oxford., 200, 173-182.
https://doi.org/10.1016/j.carbpol.2018.08.001

Marković D, Deeks C, Nunney T, Radovanović Ž, Radoičić MB, Šaponjić Z, Radetić M. Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers. 2018;200:173-182.
doi:10.1016/j.carbpol.2018.08.001 .

Marković, Darka, Deeks, Christopher, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Šaponjić, Zoran, Radetić, Maja, "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids" in Carbohydrate Polymers, 200 (2018):173-182,
https://doi.org/10.1016/j.carbpol.2018.08.001 . .

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Radetić, Tamara
AU  - Radetić, Maja
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3694
AB  - This study discusses the possibility of in situ photoreduction of Ag+-ions on the surface of titania nanotubes (TNTs) deposited on the cotton and cotton/PET fabrics in the presence of amino acid alanine and methyl alcohol. TNTs were synthetized by hydrothermal method. The proposed interaction between titania, alanine and Ag+-ions was based on the results obtained by FTIR measurements. In order to enhance the binding efficiency between TNTs and fibers, the fabrics were previously impregnated with polyethyleneimine. The presence of TNT/Ag nanocrystals on the surface of fibers was proved by SEM, AAS, XRD and XPS. Larger amount of silver was detected on the cotton fabric. Fabricated TiO2/Ag nanocrystals provided maximum reduction of bacteria E. coli which was preserved after five washing cycles despite significant release of silver. The perspiration fastness tests indicated that silver release did not depend on pH. The presence of TNT/Ag nanocrystals imparted maximum UV protection to fabrics.
PB  - Springer, Dordrecht
T2  - Cellulose
T1  - In situ photoreduction of Ag+-ions on the surface of titania nanotubes deposited on cotton and cotton/PET fabrics
EP  - 1610
IS  - 3
SP  - 1597
VL  - 24
DO  - 10.1007/s10570-017-1207-z
ER  - 

@article{
author = "Milošević, Milica V. and Šaponjić, Zoran and Nunney, Tim and Deeks, Christopher and Radoičić, Marija B. and Mitrić, Miodrag and Radetić, Tamara and Radetić, Maja",
year = "2017",
abstract = "This study discusses the possibility of in situ photoreduction of Ag+-ions on the surface of titania nanotubes (TNTs) deposited on the cotton and cotton/PET fabrics in the presence of amino acid alanine and methyl alcohol. TNTs were synthetized by hydrothermal method. The proposed interaction between titania, alanine and Ag+-ions was based on the results obtained by FTIR measurements. In order to enhance the binding efficiency between TNTs and fibers, the fabrics were previously impregnated with polyethyleneimine. The presence of TNT/Ag nanocrystals on the surface of fibers was proved by SEM, AAS, XRD and XPS. Larger amount of silver was detected on the cotton fabric. Fabricated TiO2/Ag nanocrystals provided maximum reduction of bacteria E. coli which was preserved after five washing cycles despite significant release of silver. The perspiration fastness tests indicated that silver release did not depend on pH. The presence of TNT/Ag nanocrystals imparted maximum UV protection to fabrics.",
publisher = "Springer, Dordrecht",
journal = "Cellulose",
title = "In situ photoreduction of Ag+-ions on the surface of titania nanotubes deposited on cotton and cotton/PET fabrics",
pages = "1610-1597",
number = "3",
volume = "24",
doi = "10.1007/s10570-017-1207-z"
}

Milošević, M. V., Šaponjić, Z., Nunney, T., Deeks, C., Radoičić, M. B., Mitrić, M., Radetić, T.,& Radetić, M.. (2017). In situ photoreduction of Ag+-ions on the surface of titania nanotubes deposited on cotton and cotton/PET fabrics. in Cellulose
Springer, Dordrecht., 24(3), 1597-1610.
https://doi.org/10.1007/s10570-017-1207-z

Milošević MV, Šaponjić Z, Nunney T, Deeks C, Radoičić MB, Mitrić M, Radetić T, Radetić M. In situ photoreduction of Ag+-ions on the surface of titania nanotubes deposited on cotton and cotton/PET fabrics. in Cellulose. 2017;24(3):1597-1610.
doi:10.1007/s10570-017-1207-z .

Milošević, Milica V., Šaponjić, Zoran, Nunney, Tim, Deeks, Christopher, Radoičić, Marija B., Mitrić, Miodrag, Radetić, Tamara, Radetić, Maja, "In situ photoreduction of Ag+-ions on the surface of titania nanotubes deposited on cotton and cotton/PET fabrics" in Cellulose, 24, no. 3 (2017):1597-1610,
https://doi.org/10.1007/s10570-017-1207-z . .

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Deeks, Christopher
AU  - Lazić, Vesna M.
AU  - Mitrić, Miodrag
AU  - Radetić, Tamara
AU  - Radetić, Maja
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2656
AB  - The possibility of in situ photoreduction of Ag+-ions using TiO2 nanoparticles deposited on cotton and cotton/PET fabrics in the presence of amino acid alanine and methyl alcohol has been discussed. The possible interaction between TiO2, alanine and Ag+-ions was evaluated by FTIR analysis. The fabrication of TiO2/Ag nanoparticles on both fabrics was confirmed by SEM, EDX, XRD, XPS and AAS analyses. Cotton and cotton/PET fabrics impregnated with TiO2/Ag nanoparticles provided maximum reduction of Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Although excellent antibacterial activity was preserved after ten washing cycles, a significant amount of silver leached out from the fabrics into the washing bath. The perspiration fastness assessment revealed that smaller amounts of silver were also released from the fabrics into artificial sweat at pH 5.50 and 8.00. In addition, deposited TiO2/Ag nanoparticles imparted maximum UV protection to fabrics.
PB  - Springer, Dordrecht
T2  - Cellulose
T1  - In situ photoreduction of Ag+-ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics
EP  - 3795
IS  - 5
SP  - 3781
VL  - 21
DO  - 10.1007/s10570-014-0373-5
ER  - 

@article{
author = "Milošević, Milica V. and Radoičić, Marija B. and Šaponjić, Zoran and Nunney, Tim and Deeks, Christopher and Lazić, Vesna M. and Mitrić, Miodrag and Radetić, Tamara and Radetić, Maja",
year = "2014",
abstract = "The possibility of in situ photoreduction of Ag+-ions using TiO2 nanoparticles deposited on cotton and cotton/PET fabrics in the presence of amino acid alanine and methyl alcohol has been discussed. The possible interaction between TiO2, alanine and Ag+-ions was evaluated by FTIR analysis. The fabrication of TiO2/Ag nanoparticles on both fabrics was confirmed by SEM, EDX, XRD, XPS and AAS analyses. Cotton and cotton/PET fabrics impregnated with TiO2/Ag nanoparticles provided maximum reduction of Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Although excellent antibacterial activity was preserved after ten washing cycles, a significant amount of silver leached out from the fabrics into the washing bath. The perspiration fastness assessment revealed that smaller amounts of silver were also released from the fabrics into artificial sweat at pH 5.50 and 8.00. In addition, deposited TiO2/Ag nanoparticles imparted maximum UV protection to fabrics.",
publisher = "Springer, Dordrecht",
journal = "Cellulose",
title = "In situ photoreduction of Ag+-ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics",
pages = "3795-3781",
number = "5",
volume = "21",
doi = "10.1007/s10570-014-0373-5"
}

Milošević, M. V., Radoičić, M. B., Šaponjić, Z., Nunney, T., Deeks, C., Lazić, V. M., Mitrić, M., Radetić, T.,& Radetić, M.. (2014). In situ photoreduction of Ag+-ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics. in Cellulose
Springer, Dordrecht., 21(5), 3781-3795.
https://doi.org/10.1007/s10570-014-0373-5

Milošević MV, Radoičić MB, Šaponjić Z, Nunney T, Deeks C, Lazić VM, Mitrić M, Radetić T, Radetić M. In situ photoreduction of Ag+-ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics. in Cellulose. 2014;21(5):3781-3795.
doi:10.1007/s10570-014-0373-5 .

Milošević, Milica V., Radoičić, Marija B., Šaponjić, Zoran, Nunney, Tim, Deeks, Christopher, Lazić, Vesna M., Mitrić, Miodrag, Radetić, Tamara, Radetić, Maja, "In situ photoreduction of Ag+-ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics" in Cellulose, 21, no. 5 (2014):3781-3795,
https://doi.org/10.1007/s10570-014-0373-5 . .

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Marković, Darka
AU  - Nedeljković, Jovan
AU  - Jovančić, Petar
AU  - Radetić, Maja
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6497
AB  - This study was aimed to highlight the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fibers was proved by XRD, XPS and SEM analyses. Such nanocomposite textile material provides extraordinary antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus and fungus C. albicans. Maximum microbial reduction was maintained after ten washing cycles. Despite good laundering durability, the leaching of silver occurred during washing. Silver release was also detected during the 24 hours long incubation at 37o C in artificial sweat at pH 5.5 and 8.0. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles provided maximum UV protection to polyester fabrics.
PB  - Institute of Textile Machinery and High Performance Material Technology (ITM)
C3  - Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany
T1  - Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles
EP  - 5
SP  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6497
ER  - 

@conference{
author = "Milošević, Milica and Radoičić, Marija and Šaponjić, Zoran and Nunney, Tim and Marković, Darka and Nedeljković, Jovan and Jovančić, Petar and Radetić, Maja",
year = "2013",
abstract = "This study was aimed to highlight the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fibers was proved by XRD, XPS and SEM analyses. Such nanocomposite textile material provides extraordinary antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus and fungus C. albicans. Maximum microbial reduction was maintained after ten washing cycles. Despite good laundering durability, the leaching of silver occurred during washing. Silver release was also detected during the 24 hours long incubation at 37o C in artificial sweat at pH 5.5 and 8.0. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles provided maximum UV protection to polyester fabrics.",
publisher = "Institute of Textile Machinery and High Performance Material Technology (ITM)",
journal = "Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany",
title = "Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles",
pages = "5-1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6497"
}

Milošević, M., Radoičić, M., Šaponjić, Z., Nunney, T., Marković, D., Nedeljković, J., Jovančić, P.,& Radetić, M.. (2013). Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles. in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany
Institute of Textile Machinery and High Performance Material Technology (ITM)., 1-5.
https://hdl.handle.net/21.15107/rcub_technorep_6497

Milošević M, Radoičić M, Šaponjić Z, Nunney T, Marković D, Nedeljković J, Jovančić P, Radetić M. Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles. in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany. 2013;:1-5.
https://hdl.handle.net/21.15107/rcub_technorep_6497 .

Milošević, Milica, Radoičić, Marija, Šaponjić, Zoran, Nunney, Tim, Marković, Darka, Nedeljković, Jovan, Jovančić, Petar, Radetić, Maja, "Antimicrobial Activity of Ag Nanoparticles on Polyester Fabrics Generated by Photoreduction Using TiO2 Nanoparticles" in Proceedings AUTEX 2013 World Textile Conference, May 2013, Dresden, Germany (2013):1-5,
https://hdl.handle.net/21.15107/rcub_technorep_6497 .

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Marković, Darka
AU  - Nedeljković, Jovan
AU  - Radetić, Maja
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2472
AB  - This study discusses the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fiber surface was confirmed by XRD, XPS, and SEM analyses. Such nanocomposite textile material provides excellent antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus, and fungus C. albicans. Maximum microbial reduction was preserved even after ten washing cycles. In spite of satisfactory laundering durability, the release of silver occurred during washing. The leaching of silver was also present when the fabrics were exposed to artificial sweat at pH 5.5 and pH 8.0 for 24 h. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles imparted maximum UV protection to polyester fabrics.
PB  - Springer, New York
T2  - Journal of Materials Science
T1  - In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles
EP  - 5455
IS  - 16
SP  - 5447
VL  - 48
DO  - 10.1007/s10853-013-7338-1
ER  - 

@article{
author = "Milošević, Milica V. and Radoičić, Marija B. and Šaponjić, Zoran and Nunney, Tim and Marković, Darka and Nedeljković, Jovan and Radetić, Maja",
year = "2013",
abstract = "This study discusses the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fiber surface was confirmed by XRD, XPS, and SEM analyses. Such nanocomposite textile material provides excellent antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus, and fungus C. albicans. Maximum microbial reduction was preserved even after ten washing cycles. In spite of satisfactory laundering durability, the release of silver occurred during washing. The leaching of silver was also present when the fabrics were exposed to artificial sweat at pH 5.5 and pH 8.0 for 24 h. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles imparted maximum UV protection to polyester fabrics.",
publisher = "Springer, New York",
journal = "Journal of Materials Science",
title = "In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles",
pages = "5455-5447",
number = "16",
volume = "48",
doi = "10.1007/s10853-013-7338-1"
}

Milošević, M. V., Radoičić, M. B., Šaponjić, Z., Nunney, T., Marković, D., Nedeljković, J.,& Radetić, M.. (2013). In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles. in Journal of Materials Science
Springer, New York., 48(16), 5447-5455.
https://doi.org/10.1007/s10853-013-7338-1

Milošević MV, Radoičić MB, Šaponjić Z, Nunney T, Marković D, Nedeljković J, Radetić M. In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles. in Journal of Materials Science. 2013;48(16):5447-5455.
doi:10.1007/s10853-013-7338-1 .

Milošević, Milica V., Radoičić, Marija B., Šaponjić, Zoran, Nunney, Tim, Marković, Darka, Nedeljković, Jovan, Radetić, Maja, "In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles" in Journal of Materials Science, 48, no. 16 (2013):5447-5455,
https://doi.org/10.1007/s10853-013-7338-1 . .