TY  - JOUR
AU  - Pavlović, Miroslav M.
AU  - Pavlović, Miomir
AU  - Ćosović, Vladan
AU  - Bojanić, Vaso
AU  - Nikolić, Nebojša D.
AU  - Aleksić, Radoslav
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5778
AB  - Composites based on polymers with conductive fillers have been gaining more significant roles in a variety of technological domains and they are getting in the research focus of numerous studies as a part of growing research trend. Galvanostatically produced copper powder with high values of specific area was used as filler for synthesis of electroconductive composite materials prepared by the compression molding of mixtures of lignocellulose and electrochemically deposited copper powder. This article is concerned with characterization of these composites. Analysis of the most significant properties of prepared composites and its components included measurements of electrical conductivity, impedance spectroscopy (IS) behavior and structural and morphological analysis. Volume fraction of the copper powder was varied from 2.0-29.8% (v/v). The significant increase of the electrical conductivity can be observed as the copper powder content reaches the percolation threshold (PT). It was shown that PT depends on both particle shape and type of spatial distribution. IS measurements have shown that particle morphology having pronounced grain boundaries has great effect on appearance of electric conductive layers. The packaging effect and more pronounced interpartical contact with copper powder particles lead to "movement" of PT, which for the particles  LT 45 mu m and highest processing pressure of 27 MPa was 7.2% (v/v). IS response of the composites showed existence of electrical conductive layers, each having different resistivity which increases towards interior of the composite.
PB  - Electrochemical Science Group
T2  - International Journal of Electrochemical Science
T1  - Influence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathways
EP  - 8366
IS  - 12
SP  - 8355
VL  - 9
UR  - https://hdl.handle.net/21.15107/rcub_cer_1415
ER  - 

@article{
author = "Pavlović, Miroslav M. and Pavlović, Miomir and Ćosović, Vladan and Bojanić, Vaso and Nikolić, Nebojša D. and Aleksić, Radoslav",
year = "2014",
abstract = "Composites based on polymers with conductive fillers have been gaining more significant roles in a variety of technological domains and they are getting in the research focus of numerous studies as a part of growing research trend. Galvanostatically produced copper powder with high values of specific area was used as filler for synthesis of electroconductive composite materials prepared by the compression molding of mixtures of lignocellulose and electrochemically deposited copper powder. This article is concerned with characterization of these composites. Analysis of the most significant properties of prepared composites and its components included measurements of electrical conductivity, impedance spectroscopy (IS) behavior and structural and morphological analysis. Volume fraction of the copper powder was varied from 2.0-29.8% (v/v). The significant increase of the electrical conductivity can be observed as the copper powder content reaches the percolation threshold (PT). It was shown that PT depends on both particle shape and type of spatial distribution. IS measurements have shown that particle morphology having pronounced grain boundaries has great effect on appearance of electric conductive layers. The packaging effect and more pronounced interpartical contact with copper powder particles lead to "movement" of PT, which for the particles  LT 45 mu m and highest processing pressure of 27 MPa was 7.2% (v/v). IS response of the composites showed existence of electrical conductive layers, each having different resistivity which increases towards interior of the composite.",
publisher = "Electrochemical Science Group",
journal = "International Journal of Electrochemical Science",
title = "Influence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathways",
pages = "8366-8355",
number = "12",
volume = "9",
url = "https://hdl.handle.net/21.15107/rcub_cer_1415"
}

Pavlović, M. M., Pavlović, M., Ćosović, V., Bojanić, V., Nikolić, N. D.,& Aleksić, R.. (2014). Influence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathways. in International Journal of Electrochemical Science
Electrochemical Science Group., 9(12), 8355-8366.
https://hdl.handle.net/21.15107/rcub_cer_1415

Pavlović MM, Pavlović M, Ćosović V, Bojanić V, Nikolić ND, Aleksić R. Influence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathways. in International Journal of Electrochemical Science. 2014;9(12):8355-8366.
https://hdl.handle.net/21.15107/rcub_cer_1415 .

Pavlović, Miroslav M., Pavlović, Miomir, Ćosović, Vladan, Bojanić, Vaso, Nikolić, Nebojša D., Aleksić, Radoslav, "Influence of Electrolytic Copper Powder Particle Morphology on Electrical Conductivity of Lignocellulose Composites and Formation of Conductive Pathways" in International Journal of Electrochemical Science, 9, no. 12 (2014):8355-8366,
https://hdl.handle.net/21.15107/rcub_cer_1415 .

TY  - JOUR
AU  - Pavlović, Miroslav M.
AU  - Ćosović, Vladan
AU  - Pavlović, Miomir
AU  - Bojanić, Vaso
AU  - Nikolić, Nebojša D.
AU  - Aleksić, Radoslav
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5682
AB  - This article is concerned with synthesis and characterization of electroconductive composite materials prepared by the compression molding of mixtures of lignocellulose and electrochemically deposited copper powder under different pressures, and investigation of the influence of particle size on conductivity and percolation threshold of obtained composites. Electrodeposited copper powder content was varied from 2.0-29.8 vol%. Analysis of the most significant properties of individual components and prepared composites included structural and morphological analysis and measurements of hardness and electrical conductivity. Hardness of the investigated composites, as expected, increased with the increase of the processing pressure, as well as lowering the particle size compared to previous work. The significant increase of the electrical conductivity can be observed as the copper powder content reaches the percolation threshold. The packaging effect and more pronounced interpartical contact with smaller, highly porous, highly dendritic particles with high values of specific area lead to "movement" of percolation threshold towards lower filler content, which for the particles  LT 45 mu m and highest processing pressure of 27 MPa was 7.2% (v/v). In the investigated range of electrodeposited copper powder concentrations and applied pressures the increase of the electrical conductivity of composites is as much as fourteen orders of magnitude. It was found that this transition occurs at lower volume fractions than stated in the literature which can be due to the filler with high specific area.
PB  - Esg, Belgrade
T2  - International Journal of Electrochemical Science
T1  - Electrical Conductivity of Lignocellulose Composites Loaded with Electrodeposited Copper Powders. Part II. Influence of Particle Size on Percolation Threshold
EP  - 8893
IS  - 9
SP  - 8883
VL  - 7
UR  - https://hdl.handle.net/21.15107/rcub_cer_1027
ER  - 

@article{
author = "Pavlović, Miroslav M. and Ćosović, Vladan and Pavlović, Miomir and Bojanić, Vaso and Nikolić, Nebojša D. and Aleksić, Radoslav",
year = "2012",
abstract = "This article is concerned with synthesis and characterization of electroconductive composite materials prepared by the compression molding of mixtures of lignocellulose and electrochemically deposited copper powder under different pressures, and investigation of the influence of particle size on conductivity and percolation threshold of obtained composites. Electrodeposited copper powder content was varied from 2.0-29.8 vol%. Analysis of the most significant properties of individual components and prepared composites included structural and morphological analysis and measurements of hardness and electrical conductivity. Hardness of the investigated composites, as expected, increased with the increase of the processing pressure, as well as lowering the particle size compared to previous work. The significant increase of the electrical conductivity can be observed as the copper powder content reaches the percolation threshold. The packaging effect and more pronounced interpartical contact with smaller, highly porous, highly dendritic particles with high values of specific area lead to "movement" of percolation threshold towards lower filler content, which for the particles  LT 45 mu m and highest processing pressure of 27 MPa was 7.2% (v/v). In the investigated range of electrodeposited copper powder concentrations and applied pressures the increase of the electrical conductivity of composites is as much as fourteen orders of magnitude. It was found that this transition occurs at lower volume fractions than stated in the literature which can be due to the filler with high specific area.",
publisher = "Esg, Belgrade",
journal = "International Journal of Electrochemical Science",
title = "Electrical Conductivity of Lignocellulose Composites Loaded with Electrodeposited Copper Powders. Part II. Influence of Particle Size on Percolation Threshold",
pages = "8893-8883",
number = "9",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_cer_1027"
}

Pavlović, M. M., Ćosović, V., Pavlović, M., Bojanić, V., Nikolić, N. D.,& Aleksić, R.. (2012). Electrical Conductivity of Lignocellulose Composites Loaded with Electrodeposited Copper Powders. Part II. Influence of Particle Size on Percolation Threshold. in International Journal of Electrochemical Science
Esg, Belgrade., 7(9), 8883-8893.
https://hdl.handle.net/21.15107/rcub_cer_1027

Pavlović MM, Ćosović V, Pavlović M, Bojanić V, Nikolić ND, Aleksić R. Electrical Conductivity of Lignocellulose Composites Loaded with Electrodeposited Copper Powders. Part II. Influence of Particle Size on Percolation Threshold. in International Journal of Electrochemical Science. 2012;7(9):8883-8893.
https://hdl.handle.net/21.15107/rcub_cer_1027 .

Pavlović, Miroslav M., Ćosović, Vladan, Pavlović, Miomir, Bojanić, Vaso, Nikolić, Nebojša D., Aleksić, Radoslav, "Electrical Conductivity of Lignocellulose Composites Loaded with Electrodeposited Copper Powders. Part II. Influence of Particle Size on Percolation Threshold" in International Journal of Electrochemical Science, 7, no. 9 (2012):8883-8893,
https://hdl.handle.net/21.15107/rcub_cer_1027 .