TY  - JOUR
AU  - Stanković, Srđan
AU  - Kamberović, Željko
AU  - Friedrich, Bernd
AU  - Stopić, Srećko R.
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Schippers, Axel
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5132
AB  - The automotive industry is in the process of transformation from the traditional production of vehicles with engines powered by the combustion of fossil fuels to vehicles powered by electric energy. This revolutionary transformation will generate a growing demand for metallic raw materials that are a crucial part of batteries—nickel and cobalt, among others. Providing enough raw materials for e-mobility in a sustainable way will be a challenge in the years to come. The region of South-Eastern Europe (SEE) and Turkey is relatively rich in lateritic Ni-Co deposits, and this region has the potential to partially replace the import of nickel and cobalt intermediates to the European Union from distant overseas locations. Possibilities for the sustainable sourcing of nickel and cobalt from the SEE region are reviewed in this paper, with an overview of the global demand and production of these metals, lateritic mineral resources of SEE, the current status of production, and the prospective development of nickel and cobalt production in this region.
PB  - MDPI
T2  - Metals
T1  - Options for Hydrometallurgical Treatment of Ni-Co Lateritic Ores for Sustainable Supply of Nickel and Cobalt for European Battery Industry from South-Eastern Europe and Turkey
IS  - 5
SP  - 807
VL  - 12
DO  - 10.3390/met12050807
ER  - 

@article{
author = "Stanković, Srđan and Kamberović, Željko and Friedrich, Bernd and Stopić, Srećko R. and Sokić, Miroslav and Marković, Branislav and Schippers, Axel",
year = "2022",
abstract = "The automotive industry is in the process of transformation from the traditional production of vehicles with engines powered by the combustion of fossil fuels to vehicles powered by electric energy. This revolutionary transformation will generate a growing demand for metallic raw materials that are a crucial part of batteries—nickel and cobalt, among others. Providing enough raw materials for e-mobility in a sustainable way will be a challenge in the years to come. The region of South-Eastern Europe (SEE) and Turkey is relatively rich in lateritic Ni-Co deposits, and this region has the potential to partially replace the import of nickel and cobalt intermediates to the European Union from distant overseas locations. Possibilities for the sustainable sourcing of nickel and cobalt from the SEE region are reviewed in this paper, with an overview of the global demand and production of these metals, lateritic mineral resources of SEE, the current status of production, and the prospective development of nickel and cobalt production in this region.",
publisher = "MDPI",
journal = "Metals",
title = "Options for Hydrometallurgical Treatment of Ni-Co Lateritic Ores for Sustainable Supply of Nickel and Cobalt for European Battery Industry from South-Eastern Europe and Turkey",
number = "5",
pages = "807",
volume = "12",
doi = "10.3390/met12050807"
}

Stanković, S., Kamberović, Ž., Friedrich, B., Stopić, S. R., Sokić, M., Marković, B.,& Schippers, A.. (2022). Options for Hydrometallurgical Treatment of Ni-Co Lateritic Ores for Sustainable Supply of Nickel and Cobalt for European Battery Industry from South-Eastern Europe and Turkey. in Metals
MDPI., 12(5), 807.
https://doi.org/10.3390/met12050807

Stanković S, Kamberović Ž, Friedrich B, Stopić SR, Sokić M, Marković B, Schippers A. Options for Hydrometallurgical Treatment of Ni-Co Lateritic Ores for Sustainable Supply of Nickel and Cobalt for European Battery Industry from South-Eastern Europe and Turkey. in Metals. 2022;12(5):807.
doi:10.3390/met12050807 .

Stanković, Srđan, Kamberović, Željko, Friedrich, Bernd, Stopić, Srećko R., Sokić, Miroslav, Marković, Branislav, Schippers, Axel, "Options for Hydrometallurgical Treatment of Ni-Co Lateritic Ores for Sustainable Supply of Nickel and Cobalt for European Battery Industry from South-Eastern Europe and Turkey" in Metals, 12, no. 5 (2022):807,
https://doi.org/10.3390/met12050807 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Stojanović, Jovica
AU  - Marković, Branislav
AU  - Kamberović, Željko
AU  - Gajić, Nataša
AU  - Radosavljević-Mihajlović, Ana
AU  - Milojkov, Dušan
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5238
AB  - This paper examines the effects of structural-textural characteristics of sulfide minerals on their leaching from polymetallic concentrates with sulfuric acid and hydrogen peroxide solutions. The polymetallic concentrate was obtained by flotation of polymetallic ore from the Rudnik deposit in Serbia. X-ray diffraction (XRD), qualitative and quantitative mineralogical, scanning electron microscopy (SEM/EDX), and chemical analyses were used to characterize the polymetallic concentrate and leach residue. The polymetallic concentrate contained chalcopyrite, galena, sphalerite, pyrrhotite, and quartz. The total content of sulfide minerals was 69.5%, and the occurrence of free sulfide mineral grains was about 60.9%. The comprehensive thermodynamic analysis was done by HSC Chemistry® package 9.9.2.3 to determine optimal experimental leaching conditions. Chalcopyrite, sphalerite, and pyrrhotite oxidized during leaching, and dissolution occurred. The oxidized galena remains in the solid residual as insoluble anglesite. Also, elemental sulfur and unleached minerals of copper, zinc, and iron were found in the leach residues. It was found that the structural assembly of sulfide minerals in the leach residue is very favorable and that undissolved sulfide grains are primarily present in free form. Accordingly, there was no reason to reduce the leaching rate with time. The presence of elemental sulfur and anglesite formed in the leaching process and precipitated on the surface of mineral grains was confirmed by XRD, quantitative and qualitative mineralogical analysis, and SEM/EDX.
PB  - Pleiades journals
T2  - Russian Journal of Non-Ferrous Metals
T1  - Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions
EP  - 472
IS  - 5
SP  - 457
VL  - 63
DO  - 10.3103/S1067821222050091
ER  - 

@article{
author = "Sokić, Miroslav and Stojanović, Jovica and Marković, Branislav and Kamberović, Željko and Gajić, Nataša and Radosavljević-Mihajlović, Ana and Milojkov, Dušan",
year = "2022",
abstract = "This paper examines the effects of structural-textural characteristics of sulfide minerals on their leaching from polymetallic concentrates with sulfuric acid and hydrogen peroxide solutions. The polymetallic concentrate was obtained by flotation of polymetallic ore from the Rudnik deposit in Serbia. X-ray diffraction (XRD), qualitative and quantitative mineralogical, scanning electron microscopy (SEM/EDX), and chemical analyses were used to characterize the polymetallic concentrate and leach residue. The polymetallic concentrate contained chalcopyrite, galena, sphalerite, pyrrhotite, and quartz. The total content of sulfide minerals was 69.5%, and the occurrence of free sulfide mineral grains was about 60.9%. The comprehensive thermodynamic analysis was done by HSC Chemistry® package 9.9.2.3 to determine optimal experimental leaching conditions. Chalcopyrite, sphalerite, and pyrrhotite oxidized during leaching, and dissolution occurred. The oxidized galena remains in the solid residual as insoluble anglesite. Also, elemental sulfur and unleached minerals of copper, zinc, and iron were found in the leach residues. It was found that the structural assembly of sulfide minerals in the leach residue is very favorable and that undissolved sulfide grains are primarily present in free form. Accordingly, there was no reason to reduce the leaching rate with time. The presence of elemental sulfur and anglesite formed in the leaching process and precipitated on the surface of mineral grains was confirmed by XRD, quantitative and qualitative mineralogical analysis, and SEM/EDX.",
publisher = "Pleiades journals",
journal = "Russian Journal of Non-Ferrous Metals",
title = "Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions",
pages = "472-457",
number = "5",
volume = "63",
doi = "10.3103/S1067821222050091"
}

Sokić, M., Stojanović, J., Marković, B., Kamberović, Ž., Gajić, N., Radosavljević-Mihajlović, A.,& Milojkov, D.. (2022). Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions. in Russian Journal of Non-Ferrous Metals
Pleiades journals., 63(5), 457-472.
https://doi.org/10.3103/S1067821222050091

Sokić M, Stojanović J, Marković B, Kamberović Ž, Gajić N, Radosavljević-Mihajlović A, Milojkov D. Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions. in Russian Journal of Non-Ferrous Metals. 2022;63(5):457-472.
doi:10.3103/S1067821222050091 .

Sokić, Miroslav, Stojanović, Jovica, Marković, Branislav, Kamberović, Željko, Gajić, Nataša, Radosavljević-Mihajlović, Ana, Milojkov, Dušan, "Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions" in Russian Journal of Non-Ferrous Metals, 63, no. 5 (2022):457-472,
https://doi.org/10.3103/S1067821222050091 . .

TY  - JOUR
AU  - Petronijević, Nela
AU  - Radovanović, Dragana
AU  - Štulović, Marija
AU  - Sokić, Miroslav
AU  - Jovanović, Gvozden
AU  - Kamberović, Željko
AU  - Stanković, Srđan
AU  - Stopić, Srećko
AU  - Onjia, Antonije
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5244
AB  - Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia (“Nikola Tesla” (EF) and “Kostolac” (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.
PB  - MDPI
T2  - Water (Switzerland)
T1  - Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia
IS  - 20
SP  - 3244
VL  - 14
DO  - 10.3390/w14203244
ER  - 

@article{
author = "Petronijević, Nela and Radovanović, Dragana and Štulović, Marija and Sokić, Miroslav and Jovanović, Gvozden and Kamberović, Željko and Stanković, Srđan and Stopić, Srećko and Onjia, Antonije",
year = "2022",
abstract = "Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia (“Nikola Tesla” (EF) and “Kostolac” (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.",
publisher = "MDPI",
journal = "Water (Switzerland)",
title = "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia",
number = "20",
pages = "3244",
volume = "14",
doi = "10.3390/w14203244"
}

Petronijević, N., Radovanović, D., Štulović, M., Sokić, M., Jovanović, G., Kamberović, Ž., Stanković, S., Stopić, S.,& Onjia, A.. (2022). Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water (Switzerland)
MDPI., 14(20), 3244.
https://doi.org/10.3390/w14203244

Petronijević N, Radovanović D, Štulović M, Sokić M, Jovanović G, Kamberović Ž, Stanković S, Stopić S, Onjia A. Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water (Switzerland). 2022;14(20):3244.
doi:10.3390/w14203244 .

Petronijević, Nela, Radovanović, Dragana, Štulović, Marija, Sokić, Miroslav, Jovanović, Gvozden, Kamberović, Željko, Stanković, Srđan, Stopić, Srećko, Onjia, Antonije, "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia" in Water (Switzerland), 14, no. 20 (2022):3244,
https://doi.org/10.3390/w14203244 . .

TY  - JOUR
AU  - Kamberović, Željko
AU  - Gajić, Nataša
AU  - Korać, Marija
AU  - Jevtić, Sanja
AU  - Sokić, Miroslav
AU  - Stojanovic, Jovica
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4900
AB  - By-products from zinc hydrometallurgy are classified as hazardous waste with strong leaching toxicities. Even though numerous research papers are dedicated to valorizing valuable metals in it, the primary management route is still disposal or partial reuse, such as the Waelz process. Presented experimental research investigates possibilities of sulfidization and further processing as a technologically sustainable route for valuable metals valorization from non-standard jarosite-PbAg sludge. The comprehensive thermodynamic analysis was done by HSC Chemistry(R), through optimizing process parameters, i.e., temperature, sulfur addition, and selection of possible additives. Technological possibility of magnetic separation, flotation, and smelting of sulfidized material was also investigated; the results were below the values that allow practical application, due to the obtained texture of sulfidized jarosite, which does not allow the liberation of minerals. Smelting tests were performed on sulfidized jarosite with sulfur and without and with carbon as additive. By smelting sulfidized jarosite-PbAg sludge with added carbon in sulfidization stage at 1375 degrees C, obtained products were matte, slag, raw lead, and dust in which base, critical, and slag forming components were valorized. Valuable metals were concentrated in smelting products so as to enable further processing, which also could be interesting in the case of treatment of complex, polymetallic, and refractory primary materials, which represent a significant contribution to the circular economy.
T2  - Minerals
T1  - Technologically Sustainable Route for Metals Valorization from Jarosite-PbAg Sludge
IS  - 3
VL  - 11
DO  - 10.3390/min11030255
ER  - 

@article{
author = "Kamberović, Željko and Gajić, Nataša and Korać, Marija and Jevtić, Sanja and Sokić, Miroslav and Stojanovic, Jovica",
year = "2021",
abstract = "By-products from zinc hydrometallurgy are classified as hazardous waste with strong leaching toxicities. Even though numerous research papers are dedicated to valorizing valuable metals in it, the primary management route is still disposal or partial reuse, such as the Waelz process. Presented experimental research investigates possibilities of sulfidization and further processing as a technologically sustainable route for valuable metals valorization from non-standard jarosite-PbAg sludge. The comprehensive thermodynamic analysis was done by HSC Chemistry(R), through optimizing process parameters, i.e., temperature, sulfur addition, and selection of possible additives. Technological possibility of magnetic separation, flotation, and smelting of sulfidized material was also investigated; the results were below the values that allow practical application, due to the obtained texture of sulfidized jarosite, which does not allow the liberation of minerals. Smelting tests were performed on sulfidized jarosite with sulfur and without and with carbon as additive. By smelting sulfidized jarosite-PbAg sludge with added carbon in sulfidization stage at 1375 degrees C, obtained products were matte, slag, raw lead, and dust in which base, critical, and slag forming components were valorized. Valuable metals were concentrated in smelting products so as to enable further processing, which also could be interesting in the case of treatment of complex, polymetallic, and refractory primary materials, which represent a significant contribution to the circular economy.",
journal = "Minerals",
title = "Technologically Sustainable Route for Metals Valorization from Jarosite-PbAg Sludge",
number = "3",
volume = "11",
doi = "10.3390/min11030255"
}

Kamberović, Ž., Gajić, N., Korać, M., Jevtić, S., Sokić, M.,& Stojanovic, J.. (2021). Technologically Sustainable Route for Metals Valorization from Jarosite-PbAg Sludge. in Minerals, 11(3).
https://doi.org/10.3390/min11030255

Kamberović Ž, Gajić N, Korać M, Jevtić S, Sokić M, Stojanovic J. Technologically Sustainable Route for Metals Valorization from Jarosite-PbAg Sludge. in Minerals. 2021;11(3).
doi:10.3390/min11030255 .

Kamberović, Željko, Gajić, Nataša, Korać, Marija, Jevtić, Sanja, Sokić, Miroslav, Stojanovic, Jovica, "Technologically Sustainable Route for Metals Valorization from Jarosite-PbAg Sludge" in Minerals, 11, no. 3 (2021),
https://doi.org/10.3390/min11030255 . .

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Tomić, Nataša
AU  - Bugarcic, Mladen
AU  - Sokić, Miroslav
AU  - Marinković, Aleksandar
AU  - Veličković, Zlate
AU  - Kamberović, Željko
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4966
AB  - A simple sol-gel method and external gelatinization method of hollow alumina spheres synthesis were developed in this study. The spheres were modified with polyethyleneimine (PEI) producing PEI-Al2O3 via (3-glycidyloxypropyl)trimethoxy-silane, GLYMO, linker. Characterization results, obtained using XRD and SEM microscopy revealed spherical geometry with a hollow core of PEI-Al2O3 adsorbent. Introduction of a large number of the amino group, 6.9 mmol g(-1), contributes to achieving high adsorption capacities, q(m), of 95.6, 124.9, 61.3, and 125.9 mg g(-1) for Cd2+, Pb2+, As(V), and DCF, respectively, which is obtained by using the Langmuir model. Thermodynamic studies indicated feasible adsorption and higher spontaneity with temperature increase. The kinetic study conveniently modeled using pseudo-second-order (PSO) and Weber-Morris kinetic model, as well as single resistance mass transfer model, indicated a change of the contribution of diffusional processes during adsorption with a dominance of intra-particle diffusion. The fixed-bed column adsorption data, fitted using Bohart-Adams, Clark, Yoon-Nelson, and Thomas models, showed lower capacity in comparison to batch study, and thus clear potential applicability of PEI-Al2O3 was deduced even at a high loading of feed water.
T2  - Environmental Science and Pollution Research
T1  - Amino-modified hollow alumina spheres: effective adsorbent for Cd2+, Pb2+, As(V), and diclofenac removal
EP  - 27192
IS  - 21
SP  - 27174
VL  - 28
DO  - 10.1007/s11356-020-12157-1
ER  - 

@article{
author = "Nikolić, Vesna and Tomić, Nataša and Bugarcic, Mladen and Sokić, Miroslav and Marinković, Aleksandar and Veličković, Zlate and Kamberović, Željko",
year = "2021",
abstract = "A simple sol-gel method and external gelatinization method of hollow alumina spheres synthesis were developed in this study. The spheres were modified with polyethyleneimine (PEI) producing PEI-Al2O3 via (3-glycidyloxypropyl)trimethoxy-silane, GLYMO, linker. Characterization results, obtained using XRD and SEM microscopy revealed spherical geometry with a hollow core of PEI-Al2O3 adsorbent. Introduction of a large number of the amino group, 6.9 mmol g(-1), contributes to achieving high adsorption capacities, q(m), of 95.6, 124.9, 61.3, and 125.9 mg g(-1) for Cd2+, Pb2+, As(V), and DCF, respectively, which is obtained by using the Langmuir model. Thermodynamic studies indicated feasible adsorption and higher spontaneity with temperature increase. The kinetic study conveniently modeled using pseudo-second-order (PSO) and Weber-Morris kinetic model, as well as single resistance mass transfer model, indicated a change of the contribution of diffusional processes during adsorption with a dominance of intra-particle diffusion. The fixed-bed column adsorption data, fitted using Bohart-Adams, Clark, Yoon-Nelson, and Thomas models, showed lower capacity in comparison to batch study, and thus clear potential applicability of PEI-Al2O3 was deduced even at a high loading of feed water.",
journal = "Environmental Science and Pollution Research",
title = "Amino-modified hollow alumina spheres: effective adsorbent for Cd2+, Pb2+, As(V), and diclofenac removal",
pages = "27192-27174",
number = "21",
volume = "28",
doi = "10.1007/s11356-020-12157-1"
}

Nikolić, V., Tomić, N., Bugarcic, M., Sokić, M., Marinković, A., Veličković, Z.,& Kamberović, Ž.. (2021). Amino-modified hollow alumina spheres: effective adsorbent for Cd2+, Pb2+, As(V), and diclofenac removal. in Environmental Science and Pollution Research, 28(21), 27174-27192.
https://doi.org/10.1007/s11356-020-12157-1

Nikolić V, Tomić N, Bugarcic M, Sokić M, Marinković A, Veličković Z, Kamberović Ž. Amino-modified hollow alumina spheres: effective adsorbent for Cd2+, Pb2+, As(V), and diclofenac removal. in Environmental Science and Pollution Research. 2021;28(21):27174-27192.
doi:10.1007/s11356-020-12157-1 .

Nikolić, Vesna, Tomić, Nataša, Bugarcic, Mladen, Sokić, Miroslav, Marinković, Aleksandar, Veličković, Zlate, Kamberović, Željko, "Amino-modified hollow alumina spheres: effective adsorbent for Cd2+, Pb2+, As(V), and diclofenac removal" in Environmental Science and Pollution Research, 28, no. 21 (2021):27174-27192,
https://doi.org/10.1007/s11356-020-12157-1 . .

TY  - JOUR
AU  - Milojkov, Dusan V.
AU  - Sokić, Miroslav
AU  - Radosavljevic-Mihajlovic, Ana
AU  - Stanic, Vojislav Dj.
AU  - Manojlović, Vaso
AU  - Mutavdzic, Dragosav R.
AU  - Milanovic, Marija
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4796
AB  - Coupled substitution of fluorapatite (FAP) crystal lattice plays an important role in the engineering of optically active nanomaterials. Uniform fluorapatite nanopowders doped with praseodymium (Pr3+) and carbonate (CO32-) ions have been successfully synthesized by precipitation method under room temperature (25 degrees C). The structural, morphological, chemical and optical properties of monophase material were characterized by X-ray diffraction (XRD), Fourier Transform Infrared and Far Infrared Spectroscopy (FTIR and FIR, respectively), Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS), Transmission Electron Microscopy (TEM) and Photoluminescence Spectroscopy (PL). Coupled substitution of FAP crystal lattice with Pr3+ and CO32- reduces the crystallite size with a constant c/a ratio of 1.72. FTIR study showed that synthesized nanopowders were AB-type CO32- substitution, and FIR study revealed new Pr-O vibrations. TEM analysis was found that synthesized nanopowders were composed of irregular spheres in the nanometer range. The fluorescence of FAP nanoparticles was in the violet-blue region of the visible part of the spectrum. When Pr3+ was doped in a lattice, the violet-blue emission becomes sharper due to reabsorption. MCR-ALS analyses of fluorescence spectra indicated the shift of the maximum to the blue color with the increase in the concentration of Pr3+ ions. Additionally, luminescent nanopowders demonstrated significant antibacterial activity against Escherichia coli. As the obtained nanoparticles showed a good absorption of ultraviolet A light and reabsorption of blue-green luminescence, they are suitable for further development of optically active nanomaterials for light filtering. Optically active PrCFAP nanopowders with antibacterial properties may be promising additives for the development of multifunctional cosmetic and health care products.
T2  - Metals
T1  - Influence of Pr3+ and CO32- Ions Coupled Substitution on Structural, Optical and Antibacterial Properties of Fluorapatite Nanopowders Obtained by Precipitation
IS  - 9
VL  - 11
DO  - 10.3390/met11091384
ER  - 

@article{
author = "Milojkov, Dusan V. and Sokić, Miroslav and Radosavljevic-Mihajlovic, Ana and Stanic, Vojislav Dj. and Manojlović, Vaso and Mutavdzic, Dragosav R. and Milanovic, Marija",
year = "2021",
abstract = "Coupled substitution of fluorapatite (FAP) crystal lattice plays an important role in the engineering of optically active nanomaterials. Uniform fluorapatite nanopowders doped with praseodymium (Pr3+) and carbonate (CO32-) ions have been successfully synthesized by precipitation method under room temperature (25 degrees C). The structural, morphological, chemical and optical properties of monophase material were characterized by X-ray diffraction (XRD), Fourier Transform Infrared and Far Infrared Spectroscopy (FTIR and FIR, respectively), Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS), Transmission Electron Microscopy (TEM) and Photoluminescence Spectroscopy (PL). Coupled substitution of FAP crystal lattice with Pr3+ and CO32- reduces the crystallite size with a constant c/a ratio of 1.72. FTIR study showed that synthesized nanopowders were AB-type CO32- substitution, and FIR study revealed new Pr-O vibrations. TEM analysis was found that synthesized nanopowders were composed of irregular spheres in the nanometer range. The fluorescence of FAP nanoparticles was in the violet-blue region of the visible part of the spectrum. When Pr3+ was doped in a lattice, the violet-blue emission becomes sharper due to reabsorption. MCR-ALS analyses of fluorescence spectra indicated the shift of the maximum to the blue color with the increase in the concentration of Pr3+ ions. Additionally, luminescent nanopowders demonstrated significant antibacterial activity against Escherichia coli. As the obtained nanoparticles showed a good absorption of ultraviolet A light and reabsorption of blue-green luminescence, they are suitable for further development of optically active nanomaterials for light filtering. Optically active PrCFAP nanopowders with antibacterial properties may be promising additives for the development of multifunctional cosmetic and health care products.",
journal = "Metals",
title = "Influence of Pr3+ and CO32- Ions Coupled Substitution on Structural, Optical and Antibacterial Properties of Fluorapatite Nanopowders Obtained by Precipitation",
number = "9",
volume = "11",
doi = "10.3390/met11091384"
}

Milojkov, D. V., Sokić, M., Radosavljevic-Mihajlovic, A., Stanic, V. Dj., Manojlović, V., Mutavdzic, D. R.,& Milanovic, M.. (2021). Influence of Pr3+ and CO32- Ions Coupled Substitution on Structural, Optical and Antibacterial Properties of Fluorapatite Nanopowders Obtained by Precipitation. in Metals, 11(9).
https://doi.org/10.3390/met11091384

Milojkov DV, Sokić M, Radosavljevic-Mihajlovic A, Stanic VD, Manojlović V, Mutavdzic DR, Milanovic M. Influence of Pr3+ and CO32- Ions Coupled Substitution on Structural, Optical and Antibacterial Properties of Fluorapatite Nanopowders Obtained by Precipitation. in Metals. 2021;11(9).
doi:10.3390/met11091384 .

Milojkov, Dusan V., Sokić, Miroslav, Radosavljevic-Mihajlovic, Ana, Stanic, Vojislav Dj., Manojlović, Vaso, Mutavdzic, Dragosav R., Milanovic, Marija, "Influence of Pr3+ and CO32- Ions Coupled Substitution on Structural, Optical and Antibacterial Properties of Fluorapatite Nanopowders Obtained by Precipitation" in Metals, 11, no. 9 (2021),
https://doi.org/10.3390/met11091384 . .

TY  - JOUR
AU  - Ranitović, Milisav
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Radovanović, Dragana
AU  - Sokić, Miroslav
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4548
AB  - High flexibility of hydrometallurgical operations as well as economic and environmental acceptability, offer the opportunity to selectively obtain metals in the early stages of the processing. This enables the application of hydrometallurgical operations in processing of ores which, due to their complex composition or low copper content, are not suitable for pyrometallurgical treatment. In contrast to sulfide minerals, leaching of oxide ores does not requires presence of oxidizing agent. This paper presents the results of influence of temperature on the leaching degree of copper from pyritechalcopyrite concentrate by sulfuric acid solution at atmospheric pressure. According to the obtained results, it was found that an increase in the leaching temperature significantly contributes to the increase in the leaching efficiency, where after 6 hours of leaching at 40°C achieved efficiency was 90.6%.
AB  - Visoka fleksibilnost, ekonomičnost i ekološka prihvatljivost hidrometalurških operacija nude mogućnost za selektivno dobijanje metala u ranim fazama tehnološkog procesa. To omogućava primenu hidrometalurških operacija u preradi ruda koje, zbog kompleksnog sastava ili niskog sadržaja metala, nisu pogodne za pirometalurški tretman. Nasuprot sulfidnim mineralima, za luženje oksidnih ruda nije potrebno prisustvo oksidansa. U ovom radu prikazani su rezultati ispitivanja uticaja temperature na stepen izluženja bakra iz piritno-halkopiritnog koncentrata rastvorom sumporne kiseline pri atmosferskom pritisku. Na osnovu dobijenih rezultata utvrđeno je da povećanje temperature luženja značajno doprinosi povećanju efikasnosti izluženja pri čemu nakon 6 sati luženja na 40°C postignuta efikasnost je iznosila 90,6%.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid
T1  - Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline
EP  - 175
IS  - 2
SP  - 172
VL  - 75
DO  - 10.5937/tehnika2002172R
ER  - 

@article{
author = "Ranitović, Milisav and Kamberović, Željko and Korać, Marija and Radovanović, Dragana and Sokić, Miroslav",
year = "2020",
abstract = "High flexibility of hydrometallurgical operations as well as economic and environmental acceptability, offer the opportunity to selectively obtain metals in the early stages of the processing. This enables the application of hydrometallurgical operations in processing of ores which, due to their complex composition or low copper content, are not suitable for pyrometallurgical treatment. In contrast to sulfide minerals, leaching of oxide ores does not requires presence of oxidizing agent. This paper presents the results of influence of temperature on the leaching degree of copper from pyritechalcopyrite concentrate by sulfuric acid solution at atmospheric pressure. According to the obtained results, it was found that an increase in the leaching temperature significantly contributes to the increase in the leaching efficiency, where after 6 hours of leaching at 40°C achieved efficiency was 90.6%., Visoka fleksibilnost, ekonomičnost i ekološka prihvatljivost hidrometalurških operacija nude mogućnost za selektivno dobijanje metala u ranim fazama tehnološkog procesa. To omogućava primenu hidrometalurških operacija u preradi ruda koje, zbog kompleksnog sastava ili niskog sadržaja metala, nisu pogodne za pirometalurški tretman. Nasuprot sulfidnim mineralima, za luženje oksidnih ruda nije potrebno prisustvo oksidansa. U ovom radu prikazani su rezultati ispitivanja uticaja temperature na stepen izluženja bakra iz piritno-halkopiritnog koncentrata rastvorom sumporne kiseline pri atmosferskom pritisku. Na osnovu dobijenih rezultata utvrđeno je da povećanje temperature luženja značajno doprinosi povećanju efikasnosti izluženja pri čemu nakon 6 sati luženja na 40°C postignuta efikasnost je iznosila 90,6%.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid, Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline",
pages = "175-172",
number = "2",
volume = "75",
doi = "10.5937/tehnika2002172R"
}

Ranitović, M., Kamberović, Ž., Korać, M., Radovanović, D.,& Sokić, M.. (2020). Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 75(2), 172-175.
https://doi.org/10.5937/tehnika2002172R

Ranitović M, Kamberović Ž, Korać M, Radovanović D, Sokić M. Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid. in Tehnika. 2020;75(2):172-175.
doi:10.5937/tehnika2002172R .

Ranitović, Milisav, Kamberović, Željko, Korać, Marija, Radovanović, Dragana, Sokić, Miroslav, "Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid" in Tehnika, 75, no. 2 (2020):172-175,
https://doi.org/10.5937/tehnika2002172R . .

TY  - JOUR
AU  - Petronijević, Nela
AU  - Stanković, Srđan
AU  - Radovanović, Dragana
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stopić, Srećko
AU  - Kamberović, Željko
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4485
AB  - Flotation tailings rich in carbonate minerals from the tailings deposit of the copper mine Majdanpek (Serbia) were applied for neutralization of the water taken from the extremely acidic Lake Robule (Bor, Serbia). Tests conducted in Erlenmeyer flasks showed that after neutralization of the lake water to pH 7, over 99% of aluminum (Al), iron (Fe), and copper (Cu) precipitated, as well as 92% of Zn and 98% of Pb. In order to remove residual Mn and Ag, the water was further treated with NaOH. After treatment with NaOH, all concentrations of the metals in the lake water samples were below discharge limits for municipal wastewater according to the national legislation of the Republic of Serbia. The results of this work suggest that mining waste could be used for active neutralization of the acid mine drainage. The use of the mining waste instead of lime could reduce the costs of the active treatment of the acid mine drainage.
PB  - MDPI, Basel
T2  - Metals
T1  - Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)
IS  - 1
VL  - 10
DO  - 10.3390/met10010016
ER  - 

@article{
author = "Petronijević, Nela and Stanković, Srđan and Radovanović, Dragana and Sokić, Miroslav and Marković, Branislav and Stopić, Srećko and Kamberović, Željko",
year = "2020",
abstract = "Flotation tailings rich in carbonate minerals from the tailings deposit of the copper mine Majdanpek (Serbia) were applied for neutralization of the water taken from the extremely acidic Lake Robule (Bor, Serbia). Tests conducted in Erlenmeyer flasks showed that after neutralization of the lake water to pH 7, over 99% of aluminum (Al), iron (Fe), and copper (Cu) precipitated, as well as 92% of Zn and 98% of Pb. In order to remove residual Mn and Ag, the water was further treated with NaOH. After treatment with NaOH, all concentrations of the metals in the lake water samples were below discharge limits for municipal wastewater according to the national legislation of the Republic of Serbia. The results of this work suggest that mining waste could be used for active neutralization of the acid mine drainage. The use of the mining waste instead of lime could reduce the costs of the active treatment of the acid mine drainage.",
publisher = "MDPI, Basel",
journal = "Metals",
title = "Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)",
number = "1",
volume = "10",
doi = "10.3390/met10010016"
}

Petronijević, N., Stanković, S., Radovanović, D., Sokić, M., Marković, B., Stopić, S.,& Kamberović, Ž.. (2020). Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia). in Metals
MDPI, Basel., 10(1).
https://doi.org/10.3390/met10010016

Petronijević N, Stanković S, Radovanović D, Sokić M, Marković B, Stopić S, Kamberović Ž. Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia). in Metals. 2020;10(1).
doi:10.3390/met10010016 .

Petronijević, Nela, Stanković, Srđan, Radovanović, Dragana, Sokić, Miroslav, Marković, Branislav, Stopić, Srećko, Kamberović, Željko, "Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)" in Metals, 10, no. 1 (2020),
https://doi.org/10.3390/met10010016 . .

TY  - JOUR
AU  - Petronijević, Nela
AU  - Alivojvodić, Vesna
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Radovanović, Dragana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4550
AB  - Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, re-utilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.
PB  - Institut za istrazivanja i projektovanja u privredi
T2  - Journal of Applied Engineering Science
T1  - Sustainable mining towards accomplishing circular economy principles
EP  - 499
IS  - 4
SP  - 493
VL  - 18
DO  - 10.5937/jaes0-27460
ER  - 

@article{
author = "Petronijević, Nela and Alivojvodić, Vesna and Sokić, Miroslav and Marković, Branislav and Stanković, Srđan and Radovanović, Dragana",
year = "2020",
abstract = "Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, re-utilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.",
publisher = "Institut za istrazivanja i projektovanja u privredi",
journal = "Journal of Applied Engineering Science",
title = "Sustainable mining towards accomplishing circular economy principles",
pages = "499-493",
number = "4",
volume = "18",
doi = "10.5937/jaes0-27460"
}

Petronijević, N., Alivojvodić, V., Sokić, M., Marković, B., Stanković, S.,& Radovanović, D.. (2020). Sustainable mining towards accomplishing circular economy principles. in Journal of Applied Engineering Science
Institut za istrazivanja i projektovanja u privredi., 18(4), 493-499.
https://doi.org/10.5937/jaes0-27460

Petronijević N, Alivojvodić V, Sokić M, Marković B, Stanković S, Radovanović D. Sustainable mining towards accomplishing circular economy principles. in Journal of Applied Engineering Science. 2020;18(4):493-499.
doi:10.5937/jaes0-27460 .

Petronijević, Nela, Alivojvodić, Vesna, Sokić, Miroslav, Marković, Branislav, Stanković, Srđan, Radovanović, Dragana, "Sustainable mining towards accomplishing circular economy principles" in Journal of Applied Engineering Science, 18, no. 4 (2020):493-499,
https://doi.org/10.5937/jaes0-27460 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Kamberović, Željko
AU  - Stanković, Srđan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4300
AB  - Due to complex mineralogy and/or low content of base metals, some ores and mineral concentrates are not suitable for pyrometallurgical treatment. Therefore, those ores and concentrates have to be treated by application of the hydrometallurgical processes. Lower energy consumption and lower environmental impact are important advantages of hydrometallurgy over pyrometallurgy. Leaching of sulphide minerals requires presence of oxidants in acidic environment. Influence of temperature on leaching degree of copper from chalcopyrite in presence of hydrogen peroxide under atmospheric pressure was investigated in this paper. Results of the chemical and X-ray diffraction analysis of the concentrate and leaching residue were used in order to explain mechanism of the copper leaching from the mineral concentrate.
AB  - Primena hidrometalurških procesa omogućava proizvodnju metala iz ruda i koncentrata koji, zbog kompleksne mineralogije i/ili niskog sadržaja metala, nisu pogodni za pirometaluršku preradu. Pored toga, manja potrošnja energije i manji uticaj na životnu sredinu su važne prednosti hidrometalurgije u odnosu na konvencionalne pirometalurške procese. Prilikom luženja sulfidnih minerala sumpornom kiselinom rastvor za luženje mora sadržati oksidaciono sredstvo za oksidaciju sulfidnog sumpora. U ovom radu je ispitivan uticaj temperature na stepen izluženja bakra iz halkopiritnog koncentrata u prisustvu vodonik-peroksida kao oksidansa pri atmosferskom pritisku. Hemijska i rendgenska difrakciona analiza polaznog koncentrata i čvrstog ostatka nakon luženja su korišćene za određivanje mehanizma procesa luženja bakra iz ispitivanog koncentrata.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Leaching of chalcopyrite concentrate by hydrogen peroxide in sulphuric acid solution
T1  - Luženje halkopiritnog koncentrata rastvorom sumporne kiseline i vodonik-peroksida
EP  - 70
IS  - 1
SP  - 66
VL  - 74
DO  - 10.5937/tehnika1901066S
ER  - 

@article{
author = "Sokić, Miroslav and Marković, Branislav and Kamberović, Željko and Stanković, Srđan",
year = "2019",
abstract = "Due to complex mineralogy and/or low content of base metals, some ores and mineral concentrates are not suitable for pyrometallurgical treatment. Therefore, those ores and concentrates have to be treated by application of the hydrometallurgical processes. Lower energy consumption and lower environmental impact are important advantages of hydrometallurgy over pyrometallurgy. Leaching of sulphide minerals requires presence of oxidants in acidic environment. Influence of temperature on leaching degree of copper from chalcopyrite in presence of hydrogen peroxide under atmospheric pressure was investigated in this paper. Results of the chemical and X-ray diffraction analysis of the concentrate and leaching residue were used in order to explain mechanism of the copper leaching from the mineral concentrate., Primena hidrometalurških procesa omogućava proizvodnju metala iz ruda i koncentrata koji, zbog kompleksne mineralogije i/ili niskog sadržaja metala, nisu pogodni za pirometaluršku preradu. Pored toga, manja potrošnja energije i manji uticaj na životnu sredinu su važne prednosti hidrometalurgije u odnosu na konvencionalne pirometalurške procese. Prilikom luženja sulfidnih minerala sumpornom kiselinom rastvor za luženje mora sadržati oksidaciono sredstvo za oksidaciju sulfidnog sumpora. U ovom radu je ispitivan uticaj temperature na stepen izluženja bakra iz halkopiritnog koncentrata u prisustvu vodonik-peroksida kao oksidansa pri atmosferskom pritisku. Hemijska i rendgenska difrakciona analiza polaznog koncentrata i čvrstog ostatka nakon luženja su korišćene za određivanje mehanizma procesa luženja bakra iz ispitivanog koncentrata.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Leaching of chalcopyrite concentrate by hydrogen peroxide in sulphuric acid solution, Luženje halkopiritnog koncentrata rastvorom sumporne kiseline i vodonik-peroksida",
pages = "70-66",
number = "1",
volume = "74",
doi = "10.5937/tehnika1901066S"
}

Sokić, M., Marković, B., Kamberović, Ž.,& Stanković, S.. (2019). Leaching of chalcopyrite concentrate by hydrogen peroxide in sulphuric acid solution. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 74(1), 66-70.
https://doi.org/10.5937/tehnika1901066S

Sokić M, Marković B, Kamberović Ž, Stanković S. Leaching of chalcopyrite concentrate by hydrogen peroxide in sulphuric acid solution. in Tehnika. 2019;74(1):66-70.
doi:10.5937/tehnika1901066S .

Sokić, Miroslav, Marković, Branislav, Kamberović, Željko, Stanković, Srđan, "Leaching of chalcopyrite concentrate by hydrogen peroxide in sulphuric acid solution" in Tehnika, 74, no. 1 (2019):66-70,
https://doi.org/10.5937/tehnika1901066S . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Karnberović, Željko
AU  - Štrbac, Nada
AU  - Manojlović, Vaso
AU  - Petronijević, Nela
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4112
AB  - In ores, chalcopyrite is usually associated with other sulfide minerals, such as sphalerite, galena, and pyrite, in a dispersed form, with complex mineralogical structures. Concentrates obtained by flotation of such ores are unsuitable for pyrometallurgical processing owing to their poor quality and low metal recovery. This paper presents the leaching of chalcopyrite concentrate from the location "Rudnik, Serbia". The samples from the flotation plant were treated with hydrogen peroxide in sulfuric acid. The influences of temperature, particle size, stirring speed, as well as the concentrations of hydrogen peroxide and sulfuric acid were followed and discussed. Hence, the main objective was to optimize the relevant conditions and to determine the reaction kinetics. It was remarked that the increase in temperature, hydrogen peroxide content, and sulfuric acid concentration, as well as the decrease in particle size and stirring speed, contribute to the dissolution of chalcopyrite. The dissolution kinetics follow a model controlled by diffusion, and the lixiviant diffusion controls the rate of reaction through the sulfur layer. Finally, the main characterization methods used to corroborate the obtained results were X-ray diffraction (XRD) as well as qualitative and quantitative light microscopy of the chalcopyrite concentrate samples and the leach residue.
PB  - MDPI, Basel
T2  - Metals
T1  - Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid
IS  - 11
VL  - 9
DO  - 10.3390/met9111173
ER  - 

@article{
author = "Sokić, Miroslav and Marković, Branislav and Stanković, Srđan and Karnberović, Željko and Štrbac, Nada and Manojlović, Vaso and Petronijević, Nela",
year = "2019",
abstract = "In ores, chalcopyrite is usually associated with other sulfide minerals, such as sphalerite, galena, and pyrite, in a dispersed form, with complex mineralogical structures. Concentrates obtained by flotation of such ores are unsuitable for pyrometallurgical processing owing to their poor quality and low metal recovery. This paper presents the leaching of chalcopyrite concentrate from the location "Rudnik, Serbia". The samples from the flotation plant were treated with hydrogen peroxide in sulfuric acid. The influences of temperature, particle size, stirring speed, as well as the concentrations of hydrogen peroxide and sulfuric acid were followed and discussed. Hence, the main objective was to optimize the relevant conditions and to determine the reaction kinetics. It was remarked that the increase in temperature, hydrogen peroxide content, and sulfuric acid concentration, as well as the decrease in particle size and stirring speed, contribute to the dissolution of chalcopyrite. The dissolution kinetics follow a model controlled by diffusion, and the lixiviant diffusion controls the rate of reaction through the sulfur layer. Finally, the main characterization methods used to corroborate the obtained results were X-ray diffraction (XRD) as well as qualitative and quantitative light microscopy of the chalcopyrite concentrate samples and the leach residue.",
publisher = "MDPI, Basel",
journal = "Metals",
title = "Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid",
number = "11",
volume = "9",
doi = "10.3390/met9111173"
}

Sokić, M., Marković, B., Stanković, S., Karnberović, Ž., Štrbac, N., Manojlović, V.,& Petronijević, N.. (2019). Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid. in Metals
MDPI, Basel., 9(11).
https://doi.org/10.3390/met9111173

Sokić M, Marković B, Stanković S, Karnberović Ž, Štrbac N, Manojlović V, Petronijević N. Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid. in Metals. 2019;9(11).
doi:10.3390/met9111173 .

Sokić, Miroslav, Marković, Branislav, Stanković, Srđan, Karnberović, Željko, Štrbac, Nada, Manojlović, Vaso, Petronijević, Nela, "Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid" in Metals, 9, no. 11 (2019),
https://doi.org/10.3390/met9111173 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Radovanović, Dragana
AU  - Marković, Branislav
AU  - Stojanović, Jovica
AU  - Kamberović, Željko
AU  - Petronijević, Nela
AU  - Stanković, Srđan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4268
AB  - Since commissioning in 1961, the copper mine Majdanpek, a part of the Mining and Smelting Complex Bor (RTB Bor), produced approximately 378 million tons of flotation tailings. Semiquantitative mineralogical analysis of the flotation tailings revealed significant content of carbonate minerals (approximately 20-25 %), indicating high acid neutralization capacity. Also, approximately 70 % of copper is in the form of the oxide mineral cuprite (Cu2O). Copper can be easily leached from cuprite by using sulphuric acid. The RTB Bor copper smelter generates 8.7 m(3)h(-1) of extremely acidic waste effluent (142.4 kgm(-3) of sulphuric acid, pH - 0.464) with relatively high concentrations of dissolved metals and metalloids (Cu, Fe, Zn, Pb and As). The effluent is currently treated with hydrated lime. The present study focused on application of flotation tailings as a neutralizing agent for acidic effluents. Laboratory experiments followed by computer simulation of the industrial process showed that 99% of the acid can be neutralized with flotation tailings in a series of six reactors resulting in the final copper concentration of 1.55 gL(-1). Benefits of the proposed process are: lower environmental impact of the process and reduced costs of neutralization of the acidic effluent from the copper smelter.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Treatment of the acidic effluent from a copper smelter by flotation tailings
EP  - 124
IS  - 2
SP  - 115
VL  - 73
DO  - 10.2298/HEMIND181009010S
ER  - 

@article{
author = "Sokić, Miroslav and Radovanović, Dragana and Marković, Branislav and Stojanović, Jovica and Kamberović, Željko and Petronijević, Nela and Stanković, Srđan",
year = "2019",
abstract = "Since commissioning in 1961, the copper mine Majdanpek, a part of the Mining and Smelting Complex Bor (RTB Bor), produced approximately 378 million tons of flotation tailings. Semiquantitative mineralogical analysis of the flotation tailings revealed significant content of carbonate minerals (approximately 20-25 %), indicating high acid neutralization capacity. Also, approximately 70 % of copper is in the form of the oxide mineral cuprite (Cu2O). Copper can be easily leached from cuprite by using sulphuric acid. The RTB Bor copper smelter generates 8.7 m(3)h(-1) of extremely acidic waste effluent (142.4 kgm(-3) of sulphuric acid, pH - 0.464) with relatively high concentrations of dissolved metals and metalloids (Cu, Fe, Zn, Pb and As). The effluent is currently treated with hydrated lime. The present study focused on application of flotation tailings as a neutralizing agent for acidic effluents. Laboratory experiments followed by computer simulation of the industrial process showed that 99% of the acid can be neutralized with flotation tailings in a series of six reactors resulting in the final copper concentration of 1.55 gL(-1). Benefits of the proposed process are: lower environmental impact of the process and reduced costs of neutralization of the acidic effluent from the copper smelter.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Treatment of the acidic effluent from a copper smelter by flotation tailings",
pages = "124-115",
number = "2",
volume = "73",
doi = "10.2298/HEMIND181009010S"
}

Sokić, M., Radovanović, D., Marković, B., Stojanović, J., Kamberović, Ž., Petronijević, N.,& Stanković, S.. (2019). Treatment of the acidic effluent from a copper smelter by flotation tailings. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 73(2), 115-124.
https://doi.org/10.2298/HEMIND181009010S

Sokić M, Radovanović D, Marković B, Stojanović J, Kamberović Ž, Petronijević N, Stanković S. Treatment of the acidic effluent from a copper smelter by flotation tailings. in Hemijska industrija. 2019;73(2):115-124.
doi:10.2298/HEMIND181009010S .

Sokić, Miroslav, Radovanović, Dragana, Marković, Branislav, Stojanović, Jovica, Kamberović, Željko, Petronijević, Nela, Stanković, Srđan, "Treatment of the acidic effluent from a copper smelter by flotation tailings" in Hemijska industrija, 73, no. 2 (2019):115-124,
https://doi.org/10.2298/HEMIND181009010S . .

TY  - JOUR
AU  - Bugarčić, Mladen
AU  - Milivojević, Milan
AU  - Marinković, Aleksandar
AU  - Marković, Branislav
AU  - Sokić, Miroslav
AU  - Petronijević, Nela
AU  - Stojanović, Jovica
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3882
AB  - This paper aims to determine the potential of volcanic rock found in Etna valley as an adsorbent of heavy metals in anionic form (chromates, arsenates, and selenates). Characterization of the volcanic rock was done with chemical methods (AAS, AES, gravimetric analysis, XRF), physicochemical methods (XRD, FTIR, SEM, DTA, DTG) and physical methods (porosity measurement, Microscopy in transmitted light). Also, equilibrium adsorption capacity was determined. All the results of adsorption capacity were satisfying considering the mineral composition, granulation, and porosity. The removal efficiency of chromates was the biggest (above 30 %) with adsorption capacity of 15.6 mg Cr g(-1). The lowest adsorption efficiency was with the selenates, approximately 18 %.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Application of raw volcanic rock found in etna valley as an adsorbent of chromates, arsenates and selenates
EP  - 144
IS  - 2
SP  - 133
VL  - 24
DO  - 10.30544/366
ER  - 

@article{
author = "Bugarčić, Mladen and Milivojević, Milan and Marinković, Aleksandar and Marković, Branislav and Sokić, Miroslav and Petronijević, Nela and Stojanović, Jovica",
year = "2018",
abstract = "This paper aims to determine the potential of volcanic rock found in Etna valley as an adsorbent of heavy metals in anionic form (chromates, arsenates, and selenates). Characterization of the volcanic rock was done with chemical methods (AAS, AES, gravimetric analysis, XRF), physicochemical methods (XRD, FTIR, SEM, DTA, DTG) and physical methods (porosity measurement, Microscopy in transmitted light). Also, equilibrium adsorption capacity was determined. All the results of adsorption capacity were satisfying considering the mineral composition, granulation, and porosity. The removal efficiency of chromates was the biggest (above 30 %) with adsorption capacity of 15.6 mg Cr g(-1). The lowest adsorption efficiency was with the selenates, approximately 18 %.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Application of raw volcanic rock found in etna valley as an adsorbent of chromates, arsenates and selenates",
pages = "144-133",
number = "2",
volume = "24",
doi = "10.30544/366"
}

Bugarčić, M., Milivojević, M., Marinković, A., Marković, B., Sokić, M., Petronijević, N.,& Stojanović, J.. (2018). Application of raw volcanic rock found in etna valley as an adsorbent of chromates, arsenates and selenates. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 24(2), 133-144.
https://doi.org/10.30544/366

Bugarčić M, Milivojević M, Marinković A, Marković B, Sokić M, Petronijević N, Stojanović J. Application of raw volcanic rock found in etna valley as an adsorbent of chromates, arsenates and selenates. in Metallurgical & Materials Engineering. 2018;24(2):133-144.
doi:10.30544/366 .

Bugarčić, Mladen, Milivojević, Milan, Marinković, Aleksandar, Marković, Branislav, Sokić, Miroslav, Petronijević, Nela, Stojanović, Jovica, "Application of raw volcanic rock found in etna valley as an adsorbent of chromates, arsenates and selenates" in Metallurgical & Materials Engineering, 24, no. 2 (2018):133-144,
https://doi.org/10.30544/366 . .

TY  - JOUR
AU  - Manojlović, Vaso
AU  - Kamberović, Željko
AU  - Gavrilovski, Milorad
AU  - Sokić, Miroslav
AU  - Korać, Marija
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3699
AB  - Simulating the reactions in a complex system can lead to self-sustaining and energy efficient treatment of wastes in recycling promoting manner. In this contribution, the synergic combination of electric arc furnace dust (EAFD), mill scale, and secondary aluminum, in a form of waste foil, was researched aiming to use exothermal energy of reactions and to obtain environmentally favorable products. The secondary aluminum in the form of foil was prepared in different ways in order to develop aluminum surface and to be suitable for aluminothermic reactions. The commercial aluminum powder was used to determine optimal conditions using full factorial experiment design. After that, research was performed on aluminothermic reactions with the aluminum powder obtained from secondary aluminum foils. Results show that the secondary aluminum can be successfully used for a treatment of oxides bearing hazardous wastes in an energy efficient and environmentally friendly manner. The comparative life-cycle assessment revealed several advantages of using the secondary aluminum foil as a reduction agent compared to the conventional recycling of the secondary aluminum foil.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Combustion Science and Technology
T1  - Combustion of Metallurgical Wastes Using Secondary Aluminum Foils
EP  - 1089
IS  - 6
SP  - 1072
VL  - 189
DO  - 10.1080/00102202.2016.1274310
ER  - 

@article{
author = "Manojlović, Vaso and Kamberović, Željko and Gavrilovski, Milorad and Sokić, Miroslav and Korać, Marija",
year = "2017",
abstract = "Simulating the reactions in a complex system can lead to self-sustaining and energy efficient treatment of wastes in recycling promoting manner. In this contribution, the synergic combination of electric arc furnace dust (EAFD), mill scale, and secondary aluminum, in a form of waste foil, was researched aiming to use exothermal energy of reactions and to obtain environmentally favorable products. The secondary aluminum in the form of foil was prepared in different ways in order to develop aluminum surface and to be suitable for aluminothermic reactions. The commercial aluminum powder was used to determine optimal conditions using full factorial experiment design. After that, research was performed on aluminothermic reactions with the aluminum powder obtained from secondary aluminum foils. Results show that the secondary aluminum can be successfully used for a treatment of oxides bearing hazardous wastes in an energy efficient and environmentally friendly manner. The comparative life-cycle assessment revealed several advantages of using the secondary aluminum foil as a reduction agent compared to the conventional recycling of the secondary aluminum foil.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Combustion Science and Technology",
title = "Combustion of Metallurgical Wastes Using Secondary Aluminum Foils",
pages = "1089-1072",
number = "6",
volume = "189",
doi = "10.1080/00102202.2016.1274310"
}

Manojlović, V., Kamberović, Ž., Gavrilovski, M., Sokić, M.,& Korać, M.. (2017). Combustion of Metallurgical Wastes Using Secondary Aluminum Foils. in Combustion Science and Technology
Taylor & Francis Inc, Philadelphia., 189(6), 1072-1089.
https://doi.org/10.1080/00102202.2016.1274310

Manojlović V, Kamberović Ž, Gavrilovski M, Sokić M, Korać M. Combustion of Metallurgical Wastes Using Secondary Aluminum Foils. in Combustion Science and Technology. 2017;189(6):1072-1089.
doi:10.1080/00102202.2016.1274310 .

Manojlović, Vaso, Kamberović, Željko, Gavrilovski, Milorad, Sokić, Miroslav, Korać, Marija, "Combustion of Metallurgical Wastes Using Secondary Aluminum Foils" in Combustion Science and Technology, 189, no. 6 (2017):1072-1089,
https://doi.org/10.1080/00102202.2016.1274310 . .

TY  - JOUR
AU  - Marković, Branislav
AU  - Sokić, Miroslav
AU  - Ilić, Ilija
AU  - Manojlović, Vaso
AU  - Gulišija, Zvonko
AU  - Živković, Dragana
AU  - Štrbac, Nada
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3528
AB  - Modern industrial product design implies presence of many different materials. Consequently, in the recycling process, shredding and separation procedures are applied. However, all materials cannot be completely separated; therefore, there is a contamination in the recycling streams. The quality of the materials streams can be reduced in each of the following recycling steps. These qualitative losses cannot be described by material balance. This paper presents the concept of exergy as a measure of quality losses, and gives the methods for the calculation of the exergy content and the exergy loss. Losses attributed to the recycling or material losses, material contamination losses and dilution requirements can be used as indicators for the materials quality loss as well as for the resource efficiency in the production systems. In this paper, the example of calculations on the steel scrap is presented.
AB  - Dizajn modernih industrijskih proizvoda je takav da oni predstavljaju kompleksne spojeve različitih materijala. Zbog toga se u postupku reciklaže materijala primenjuju procesi usitnjavanja i razdvajanja. Međutim materijali se ne mogu u potpunosti razdvojiti i zbog toga dolazi do kontaminacija u reciklažnim tokovima. Zbog toga se kvalitet materijala može smanjivati u svakom narednom reciklažnom koraku. Ovakvi kvalitativni gubici ne mogu se opisati masenim bilansom, i u radu je prikazan eksergijski koncept kao merilo gubitaka kvaliteta, odnosno dat je metod za izračunavanje eksergijskog sadržaja i eksergijskog gubitka. Gubici pripisani reciklaži ili tačnije materijalni gubici, gubici usled kontaminacije drugim metalima i posledično potreba za razblaživanjem, mogu se koristiti kao indikatori gubitka kvaliteta materijala i efikasnosti korišćenja resursa u proizvodnim sistemima. U radu je dat primer proračuna na čeličnom otpadu.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Exergy concept and its implementation in the recycling of metals
T1  - Eksergijski koncept i njegova primena u recikliranju metala
EP  - 103
IS  - 1
SP  - 100
VL  - 58
DO  - 10.5937/ZasMat1701100M
ER  - 

@article{
author = "Marković, Branislav and Sokić, Miroslav and Ilić, Ilija and Manojlović, Vaso and Gulišija, Zvonko and Živković, Dragana and Štrbac, Nada",
year = "2017",
abstract = "Modern industrial product design implies presence of many different materials. Consequently, in the recycling process, shredding and separation procedures are applied. However, all materials cannot be completely separated; therefore, there is a contamination in the recycling streams. The quality of the materials streams can be reduced in each of the following recycling steps. These qualitative losses cannot be described by material balance. This paper presents the concept of exergy as a measure of quality losses, and gives the methods for the calculation of the exergy content and the exergy loss. Losses attributed to the recycling or material losses, material contamination losses and dilution requirements can be used as indicators for the materials quality loss as well as for the resource efficiency in the production systems. In this paper, the example of calculations on the steel scrap is presented., Dizajn modernih industrijskih proizvoda je takav da oni predstavljaju kompleksne spojeve različitih materijala. Zbog toga se u postupku reciklaže materijala primenjuju procesi usitnjavanja i razdvajanja. Međutim materijali se ne mogu u potpunosti razdvojiti i zbog toga dolazi do kontaminacija u reciklažnim tokovima. Zbog toga se kvalitet materijala može smanjivati u svakom narednom reciklažnom koraku. Ovakvi kvalitativni gubici ne mogu se opisati masenim bilansom, i u radu je prikazan eksergijski koncept kao merilo gubitaka kvaliteta, odnosno dat je metod za izračunavanje eksergijskog sadržaja i eksergijskog gubitka. Gubici pripisani reciklaži ili tačnije materijalni gubici, gubici usled kontaminacije drugim metalima i posledično potreba za razblaživanjem, mogu se koristiti kao indikatori gubitka kvaliteta materijala i efikasnosti korišćenja resursa u proizvodnim sistemima. U radu je dat primer proračuna na čeličnom otpadu.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Exergy concept and its implementation in the recycling of metals, Eksergijski koncept i njegova primena u recikliranju metala",
pages = "103-100",
number = "1",
volume = "58",
doi = "10.5937/ZasMat1701100M"
}

Marković, B., Sokić, M., Ilić, I., Manojlović, V., Gulišija, Z., Živković, D.,& Štrbac, N.. (2017). Exergy concept and its implementation in the recycling of metals. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 58(1), 100-103.
https://doi.org/10.5937/ZasMat1701100M

Marković B, Sokić M, Ilić I, Manojlović V, Gulišija Z, Živković D, Štrbac N. Exergy concept and its implementation in the recycling of metals. in Zaštita materijala. 2017;58(1):100-103.
doi:10.5937/ZasMat1701100M .

Marković, Branislav, Sokić, Miroslav, Ilić, Ilija, Manojlović, Vaso, Gulišija, Zvonko, Živković, Dragana, Štrbac, Nada, "Exergy concept and its implementation in the recycling of metals" in Zaštita materijala, 58, no. 1 (2017):100-103,
https://doi.org/10.5937/ZasMat1701100M . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Stojanović, Jovica
AU  - Marković, Branislav
AU  - Bugarčić, Mladen
AU  - Štrbac, Nada
AU  - Kamberović, Željko
AU  - Manojlović, Vaso
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3654
AB  - In this paper, the influence of structural and textural characteristics of sulfide minerals on their leaching from a polymetallic concentrate by sulfuric acid and sodium nitrate solution is presented. The starting material was Pb-Zn-Cu sulphide polymetallic concentrate enriched during the flotation of a polymetallic ore in the "Rudnik" flotation plant (Rudnik - Serbia). Leaching experiments were carried out in a closed glass reactor, which provides stable hermetic conditions and allows heating at constant temperature. Chemical, XRD, qualitative and quantitative microscopic and SEM/EDX analyses were used to characterizes samples of the polymetallic concentrate and leach residue. It was determined that chalcopyrite, sphalerite, galena, pyrrhotite and quartz were present in the polymetallic concentrate. The content of sulphide minerals was 69.5%, of which 60.9% occurred as liberated grains: 88.3% of chalcopyrite, 59.3% of sphalerite, 25.1% of galena and 51.6% of pirrhotite. The rest of chalcopyrite, sphalerite, galena and pirrhotite grains were in the forms of inclusions, impregnations, and simple and complex intergrowths. During the leaching process by sodium nitrate and sulphuric acid solution, it was shown previously that the leaching rate of sulphide minerals decreased with time while a part of the sulphide minerals remained in the leach residue. After leaching at 80 degrees C for 120 min, the yields were 69.8, 82.7 and 67.1% for Cu, Zn and Fe, respectively. Lead, in the form of insoluble anglesite, remained in the leach residue. In addition to the anglesite, unleached sulfide minerals and quartz, elemental sulfur was found in the solid residue. The content of sulphide minerals was 35% of which 33.7% minerals occur independently. In specific, 54.7% of chalcopyrite, 31.9% of sphalerite, 8.2% of galena and 37.6% of pyrrhotite appear as separate grains with highly corroded surfaces. Therefore, the structural assembly of sulphide grains in the polymetallic concentrate is favourable and it is not the reason for the observed decrease in the leaching rate in the final process stages. The obtained findings may be explained by the presence of elemental sulphur that is formed during the reaction and precipitated at the grain surfaces, thus creating a diffusion barrier for the leach solution.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Effects of structural and textural grain characteristics on leaching of sulphide minerals from a polymetallic concentrate by sodium nitrate and sulphuric acid solution
EP  - 469
IS  - 6
SP  - 461
VL  - 71
DO  - 10.2298/HEMIND161130006S
ER  - 

@article{
author = "Sokić, Miroslav and Stojanović, Jovica and Marković, Branislav and Bugarčić, Mladen and Štrbac, Nada and Kamberović, Željko and Manojlović, Vaso",
year = "2017",
abstract = "In this paper, the influence of structural and textural characteristics of sulfide minerals on their leaching from a polymetallic concentrate by sulfuric acid and sodium nitrate solution is presented. The starting material was Pb-Zn-Cu sulphide polymetallic concentrate enriched during the flotation of a polymetallic ore in the "Rudnik" flotation plant (Rudnik - Serbia). Leaching experiments were carried out in a closed glass reactor, which provides stable hermetic conditions and allows heating at constant temperature. Chemical, XRD, qualitative and quantitative microscopic and SEM/EDX analyses were used to characterizes samples of the polymetallic concentrate and leach residue. It was determined that chalcopyrite, sphalerite, galena, pyrrhotite and quartz were present in the polymetallic concentrate. The content of sulphide minerals was 69.5%, of which 60.9% occurred as liberated grains: 88.3% of chalcopyrite, 59.3% of sphalerite, 25.1% of galena and 51.6% of pirrhotite. The rest of chalcopyrite, sphalerite, galena and pirrhotite grains were in the forms of inclusions, impregnations, and simple and complex intergrowths. During the leaching process by sodium nitrate and sulphuric acid solution, it was shown previously that the leaching rate of sulphide minerals decreased with time while a part of the sulphide minerals remained in the leach residue. After leaching at 80 degrees C for 120 min, the yields were 69.8, 82.7 and 67.1% for Cu, Zn and Fe, respectively. Lead, in the form of insoluble anglesite, remained in the leach residue. In addition to the anglesite, unleached sulfide minerals and quartz, elemental sulfur was found in the solid residue. The content of sulphide minerals was 35% of which 33.7% minerals occur independently. In specific, 54.7% of chalcopyrite, 31.9% of sphalerite, 8.2% of galena and 37.6% of pyrrhotite appear as separate grains with highly corroded surfaces. Therefore, the structural assembly of sulphide grains in the polymetallic concentrate is favourable and it is not the reason for the observed decrease in the leaching rate in the final process stages. The obtained findings may be explained by the presence of elemental sulphur that is formed during the reaction and precipitated at the grain surfaces, thus creating a diffusion barrier for the leach solution.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Effects of structural and textural grain characteristics on leaching of sulphide minerals from a polymetallic concentrate by sodium nitrate and sulphuric acid solution",
pages = "469-461",
number = "6",
volume = "71",
doi = "10.2298/HEMIND161130006S"
}

Sokić, M., Stojanović, J., Marković, B., Bugarčić, M., Štrbac, N., Kamberović, Ž.,& Manojlović, V.. (2017). Effects of structural and textural grain characteristics on leaching of sulphide minerals from a polymetallic concentrate by sodium nitrate and sulphuric acid solution. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 71(6), 461-469.
https://doi.org/10.2298/HEMIND161130006S

Sokić M, Stojanović J, Marković B, Bugarčić M, Štrbac N, Kamberović Ž, Manojlović V. Effects of structural and textural grain characteristics on leaching of sulphide minerals from a polymetallic concentrate by sodium nitrate and sulphuric acid solution. in Hemijska industrija. 2017;71(6):461-469.
doi:10.2298/HEMIND161130006S .

Sokić, Miroslav, Stojanović, Jovica, Marković, Branislav, Bugarčić, Mladen, Štrbac, Nada, Kamberović, Željko, Manojlović, Vaso, "Effects of structural and textural grain characteristics on leaching of sulphide minerals from a polymetallic concentrate by sodium nitrate and sulphuric acid solution" in Hemijska industrija, 71, no. 6 (2017):461-469,
https://doi.org/10.2298/HEMIND161130006S . .

TY  - JOUR
AU  - Ćosović, Aleksandar
AU  - Žák, Tomáš
AU  - Glišić, Sandra
AU  - Sokić, Miroslav
AU  - Lazarević, Slavica
AU  - Ćosović, Vladan
AU  - Orlović, Aleksandar
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3262
AB  - Nano-crystalline nickel ferrite has a broad range of applications due to its favourable magnetic properties. Those characteristics can be significantly influenced by the synthesis pathway including methods conducted in the presence of supercritical alcohols. Nano-crystalline NiFe2O4 powders were obtained in the reaction under subcritical and supercritical conditions of ethanol. Both high pressure synthesis routes resulted in powders with smaller primary particles and higher mesoporosity than co-precipitation method. Upon the annealing treatment the average crystallite size increased while material structure remained uniform, resulting in significantly enhanced magnetic properties, such as coercivity and remanence. It was found that synthesis under supercritical conditions provides higher conversion but also material with larger average crystallite size upon annealing. The time and temperature of annealing stage significantly influenced the morphology and magnetic properties of the obtained powders.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Supercritical Fluids
T1  - Synthesis of nano-crystalline NiFe2O4 powders in subcritical and supercritical ethanol
EP  - 105
SP  - 96
VL  - 113
DO  - 10.1016/j.supflu.2016.03.014
ER  - 

@article{
author = "Ćosović, Aleksandar and Žák, Tomáš and Glišić, Sandra and Sokić, Miroslav and Lazarević, Slavica and Ćosović, Vladan and Orlović, Aleksandar",
year = "2016",
abstract = "Nano-crystalline nickel ferrite has a broad range of applications due to its favourable magnetic properties. Those characteristics can be significantly influenced by the synthesis pathway including methods conducted in the presence of supercritical alcohols. Nano-crystalline NiFe2O4 powders were obtained in the reaction under subcritical and supercritical conditions of ethanol. Both high pressure synthesis routes resulted in powders with smaller primary particles and higher mesoporosity than co-precipitation method. Upon the annealing treatment the average crystallite size increased while material structure remained uniform, resulting in significantly enhanced magnetic properties, such as coercivity and remanence. It was found that synthesis under supercritical conditions provides higher conversion but also material with larger average crystallite size upon annealing. The time and temperature of annealing stage significantly influenced the morphology and magnetic properties of the obtained powders.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Supercritical Fluids",
title = "Synthesis of nano-crystalline NiFe2O4 powders in subcritical and supercritical ethanol",
pages = "105-96",
volume = "113",
doi = "10.1016/j.supflu.2016.03.014"
}

Ćosović, A., Žák, T., Glišić, S., Sokić, M., Lazarević, S., Ćosović, V.,& Orlović, A.. (2016). Synthesis of nano-crystalline NiFe2O4 powders in subcritical and supercritical ethanol. in Journal of Supercritical Fluids
Elsevier Science Bv, Amsterdam., 113, 96-105.
https://doi.org/10.1016/j.supflu.2016.03.014

Ćosović A, Žák T, Glišić S, Sokić M, Lazarević S, Ćosović V, Orlović A. Synthesis of nano-crystalline NiFe2O4 powders in subcritical and supercritical ethanol. in Journal of Supercritical Fluids. 2016;113:96-105.
doi:10.1016/j.supflu.2016.03.014 .

Ćosović, Aleksandar, Žák, Tomáš, Glišić, Sandra, Sokić, Miroslav, Lazarević, Slavica, Ćosović, Vladan, Orlović, Aleksandar, "Synthesis of nano-crystalline NiFe2O4 powders in subcritical and supercritical ethanol" in Journal of Supercritical Fluids, 113 (2016):96-105,
https://doi.org/10.1016/j.supflu.2016.03.014 . .

TY  - JOUR
AU  - Manojlović, Vaso
AU  - Kamberović, Željko
AU  - Sokić, Miroslav
AU  - Gavrilovski, Milorad
AU  - Korać, Marija
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3270
AB  - Electric arc furnace (EAF) dust, together with a mill scale and coke were smelted in a laboratory electric arc furnace. These metallurgical wastes consist of a many different phases and elements, making the reaction process complex. Thermo-chemical analysis of the reactions in metal, slag, and gas phases was done, and used for modeling of the mixture composition and energy consumption required for smelting. Modelling was performed with the software named RikiAlC. The crude ZnO, slag, and metal phase were analyzed using the atomic absorption spectrometry (AAS), the optical emission spectrometry with inductively coupled plasma (ICP-OES), the X-ray diffraction (XRD), the scanning electron microscopy (SEM) equipped with energy dispersive spectrometry (EDS), and reflected and transmitted light microscopy. Also, in order to follow the behavior of this process the exhausted gases were monitored. The synergetic effects of the designed mixture may be recognized in minimizing energy consumption for the smelting process, improving the product yield efficiency, and reducing the negative environmental effects.
PB  - MDPI, Basel
T2  - Metals
T1  - Designing of Synergistic Waste Mixtures for Multiphase Reactive Smelting
IS  - 6
VL  - 6
DO  - 10.3390/met6060138
ER  - 

@article{
author = "Manojlović, Vaso and Kamberović, Željko and Sokić, Miroslav and Gavrilovski, Milorad and Korać, Marija",
year = "2016",
abstract = "Electric arc furnace (EAF) dust, together with a mill scale and coke were smelted in a laboratory electric arc furnace. These metallurgical wastes consist of a many different phases and elements, making the reaction process complex. Thermo-chemical analysis of the reactions in metal, slag, and gas phases was done, and used for modeling of the mixture composition and energy consumption required for smelting. Modelling was performed with the software named RikiAlC. The crude ZnO, slag, and metal phase were analyzed using the atomic absorption spectrometry (AAS), the optical emission spectrometry with inductively coupled plasma (ICP-OES), the X-ray diffraction (XRD), the scanning electron microscopy (SEM) equipped with energy dispersive spectrometry (EDS), and reflected and transmitted light microscopy. Also, in order to follow the behavior of this process the exhausted gases were monitored. The synergetic effects of the designed mixture may be recognized in minimizing energy consumption for the smelting process, improving the product yield efficiency, and reducing the negative environmental effects.",
publisher = "MDPI, Basel",
journal = "Metals",
title = "Designing of Synergistic Waste Mixtures for Multiphase Reactive Smelting",
number = "6",
volume = "6",
doi = "10.3390/met6060138"
}

Manojlović, V., Kamberović, Ž., Sokić, M., Gavrilovski, M.,& Korać, M.. (2016). Designing of Synergistic Waste Mixtures for Multiphase Reactive Smelting. in Metals
MDPI, Basel., 6(6).
https://doi.org/10.3390/met6060138

Manojlović V, Kamberović Ž, Sokić M, Gavrilovski M, Korać M. Designing of Synergistic Waste Mixtures for Multiphase Reactive Smelting. in Metals. 2016;6(6).
doi:10.3390/met6060138 .

Manojlović, Vaso, Kamberović, Željko, Sokić, Miroslav, Gavrilovski, Milorad, Korać, Marija, "Designing of Synergistic Waste Mixtures for Multiphase Reactive Smelting" in Metals, 6, no. 6 (2016),
https://doi.org/10.3390/met6060138 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Matković, Vladislav
AU  - Marković, Branislav
AU  - Manojlović, Vaso
AU  - Štrbac, Nada
AU  - Živković, Dragana
AU  - Kamberović, Željko
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3206
AB  - The results of research on the leaching process of complex sulphide-barite ore were presented in this paper. The leaching process was carried out in a laboratory autoclave by ferric chloride solution. Considering that those minerals are represented in complex structural-textural relationships, it is not possible to extract lead, zinc and copper minerals from ore by flotation methods. The obtained results confirmed possibility of the ore processing directly, by chemical methods. The effect of temperature, time and oxygen partial pressure on the lead, zinc and copper dissolution was studied. The maximal leaching degree was achieved at 100 °C and amount of 91.5 % for Pb, 96.1 % for Zn and 60.7 % for Cu). Leaching at temperatures above 100 °C is impractical.
PB  - Association of Metallurgical Engineers of Serbia
T2  - Metallurgical & Materials Engineering
T1  - Complex sulphide-barite ore leaching in ferric chloride solution
EP  - 89
IS  - 2
SP  - 81
VL  - 22
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3206
ER  - 

@article{
author = "Sokić, Miroslav and Matković, Vladislav and Marković, Branislav and Manojlović, Vaso and Štrbac, Nada and Živković, Dragana and Kamberović, Željko",
year = "2016",
abstract = "The results of research on the leaching process of complex sulphide-barite ore were presented in this paper. The leaching process was carried out in a laboratory autoclave by ferric chloride solution. Considering that those minerals are represented in complex structural-textural relationships, it is not possible to extract lead, zinc and copper minerals from ore by flotation methods. The obtained results confirmed possibility of the ore processing directly, by chemical methods. The effect of temperature, time and oxygen partial pressure on the lead, zinc and copper dissolution was studied. The maximal leaching degree was achieved at 100 °C and amount of 91.5 % for Pb, 96.1 % for Zn and 60.7 % for Cu). Leaching at temperatures above 100 °C is impractical.",
publisher = "Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering",
title = "Complex sulphide-barite ore leaching in ferric chloride solution",
pages = "89-81",
number = "2",
volume = "22",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3206"
}

Sokić, M., Matković, V., Marković, B., Manojlović, V., Štrbac, N., Živković, D.,& Kamberović, Ž.. (2016). Complex sulphide-barite ore leaching in ferric chloride solution. in Metallurgical & Materials Engineering
Association of Metallurgical Engineers of Serbia., 22(2), 81-89.
https://hdl.handle.net/21.15107/rcub_technorep_3206

Sokić M, Matković V, Marković B, Manojlović V, Štrbac N, Živković D, Kamberović Ž. Complex sulphide-barite ore leaching in ferric chloride solution. in Metallurgical & Materials Engineering. 2016;22(2):81-89.
https://hdl.handle.net/21.15107/rcub_technorep_3206 .

Sokić, Miroslav, Matković, Vladislav, Marković, Branislav, Manojlović, Vaso, Štrbac, Nada, Živković, Dragana, Kamberović, Željko, "Complex sulphide-barite ore leaching in ferric chloride solution" in Metallurgical & Materials Engineering, 22, no. 2 (2016):81-89,
https://hdl.handle.net/21.15107/rcub_technorep_3206 .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Matković, Vladislav
AU  - Stojanović, Jovica
AU  - Marković, Branislav
AU  - Manojlović, Vaso
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3310
AB  - Refractory sulphide-barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Kinetics of barite reduction from refractory barite-sulphide ore
EP  - 268
IS  - 4
SP  - 261
VL  - 22
DO  - 10.30544/237
ER  - 

@article{
author = "Sokić, Miroslav and Matković, Vladislav and Stojanović, Jovica and Marković, Branislav and Manojlović, Vaso",
year = "2016",
abstract = "Refractory sulphide-barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Kinetics of barite reduction from refractory barite-sulphide ore",
pages = "268-261",
number = "4",
volume = "22",
doi = "10.30544/237"
}

Sokić, M., Matković, V., Stojanović, J., Marković, B.,& Manojlović, V.. (2016). Kinetics of barite reduction from refractory barite-sulphide ore. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 22(4), 261-268.
https://doi.org/10.30544/237

Sokić M, Matković V, Stojanović J, Marković B, Manojlović V. Kinetics of barite reduction from refractory barite-sulphide ore. in Metallurgical & Materials Engineering. 2016;22(4):261-268.
doi:10.30544/237 .

Sokić, Miroslav, Matković, Vladislav, Stojanović, Jovica, Marković, Branislav, Manojlović, Vaso, "Kinetics of barite reduction from refractory barite-sulphide ore" in Metallurgical & Materials Engineering, 22, no. 4 (2016):261-268,
https://doi.org/10.30544/237 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Ilić, Ilija B.
AU  - Manojlović, Vaso
AU  - Marković, Branislav
AU  - Gulišija, Zvonko
AU  - Pavlović, Milan D.
AU  - Štrbac, Nada
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3331
AB  - The impact of various time-defendant factors on the recycling rate of end-of-life vehicles (ELV) in Republic of Serbia was investigated. Statistical distribution of the frequency of the number of ELV in the year of dismantling depending on the year of production of ELV is designed using the two-parameter Weibull distribution function and MATLAB software, based on a real time data. Obtaining the time-dependence of Weibull parameters, a statistical distribution of frequency of the number of ELV in the coming period in Serbia was simulated. These results in combination with amount of materials in the most abundant cars in Serbia were used to simulate the overall amount of materials, which are available for recycling, in the coming period. These results are essential for automotive recycling industry management, particularly for shredders, dismantlers and metal pre-processors.
PB  - Budapest Tech, Budapest
T2  - Acta Polytechnica Hungarica
T1  - Modeling and Prediction of the end of Life Vehicles Number Distribution in Serbia
EP  - 172
IS  - 4
SP  - 159
VL  - 13
DO  - 10.12700/APH.13.4.2016.4.10
ER  - 

@article{
author = "Sokić, Miroslav and Ilić, Ilija B. and Manojlović, Vaso and Marković, Branislav and Gulišija, Zvonko and Pavlović, Milan D. and Štrbac, Nada",
year = "2016",
abstract = "The impact of various time-defendant factors on the recycling rate of end-of-life vehicles (ELV) in Republic of Serbia was investigated. Statistical distribution of the frequency of the number of ELV in the year of dismantling depending on the year of production of ELV is designed using the two-parameter Weibull distribution function and MATLAB software, based on a real time data. Obtaining the time-dependence of Weibull parameters, a statistical distribution of frequency of the number of ELV in the coming period in Serbia was simulated. These results in combination with amount of materials in the most abundant cars in Serbia were used to simulate the overall amount of materials, which are available for recycling, in the coming period. These results are essential for automotive recycling industry management, particularly for shredders, dismantlers and metal pre-processors.",
publisher = "Budapest Tech, Budapest",
journal = "Acta Polytechnica Hungarica",
title = "Modeling and Prediction of the end of Life Vehicles Number Distribution in Serbia",
pages = "172-159",
number = "4",
volume = "13",
doi = "10.12700/APH.13.4.2016.4.10"
}

Sokić, M., Ilić, I. B., Manojlović, V., Marković, B., Gulišija, Z., Pavlović, M. D.,& Štrbac, N.. (2016). Modeling and Prediction of the end of Life Vehicles Number Distribution in Serbia. in Acta Polytechnica Hungarica
Budapest Tech, Budapest., 13(4), 159-172.
https://doi.org/10.12700/APH.13.4.2016.4.10

Sokić M, Ilić IB, Manojlović V, Marković B, Gulišija Z, Pavlović MD, Štrbac N. Modeling and Prediction of the end of Life Vehicles Number Distribution in Serbia. in Acta Polytechnica Hungarica. 2016;13(4):159-172.
doi:10.12700/APH.13.4.2016.4.10 .

Sokić, Miroslav, Ilić, Ilija B., Manojlović, Vaso, Marković, Branislav, Gulišija, Zvonko, Pavlović, Milan D., Štrbac, Nada, "Modeling and Prediction of the end of Life Vehicles Number Distribution in Serbia" in Acta Polytechnica Hungarica, 13, no. 4 (2016):159-172,
https://doi.org/10.12700/APH.13.4.2016.4.10 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Kamberović, Željko
AU  - Nikolić, Vesna
AU  - Marković, B.
AU  - Korać, Marija
AU  - Anić, Z.
AU  - Gavrilovski, Milorad
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2875
AB  - The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K.
PB  - Hindawi Limited
T2  - Scientific World Journal
T1  - Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts
VL  - 2015
DO  - 10.1155/2015/601970
ER  - 

@article{
author = "Sokić, Miroslav and Kamberović, Željko and Nikolić, Vesna and Marković, B. and Korać, Marija and Anić, Z. and Gavrilovski, Milorad",
year = "2015",
abstract = "The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K.",
publisher = "Hindawi Limited",
journal = "Scientific World Journal",
title = "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts",
volume = "2015",
doi = "10.1155/2015/601970"
}

Sokić, M., Kamberović, Ž., Nikolić, V., Marković, B., Korać, M., Anić, Z.,& Gavrilovski, M.. (2015). Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal
Hindawi Limited., 2015.
https://doi.org/10.1155/2015/601970

Sokić M, Kamberović Ž, Nikolić V, Marković B, Korać M, Anić Z, Gavrilovski M. Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal. 2015;2015.
doi:10.1155/2015/601970 .

Sokić, Miroslav, Kamberović, Željko, Nikolić, Vesna, Marković, B., Korać, Marija, Anić, Z., Gavrilovski, Milorad, "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts" in Scientific World Journal, 2015 (2015),
https://doi.org/10.1155/2015/601970 . .

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Sokić, Miroslav
AU  - Anđić, Zoran
AU  - Tomović, Aleksandar
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2902
AB  - In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Ni-pd/al(2)o(3) catalyst supported on reticulated ceramic foam for dry methane reforming
EP  - 63
IS  - 1
SP  - 57
VL  - 21
DO  - 10.30544/133
ER  - 

@article{
author = "Nikolić, Vesna and Kamberović, Željko and Korać, Marija and Sokić, Miroslav and Anđić, Zoran and Tomović, Aleksandar",
year = "2015",
abstract = "In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Ni-pd/al(2)o(3) catalyst supported on reticulated ceramic foam for dry methane reforming",
pages = "63-57",
number = "1",
volume = "21",
doi = "10.30544/133"
}

Nikolić, V., Kamberović, Ž., Korać, M., Sokić, M., Anđić, Z.,& Tomović, A.. (2015). Ni-pd/al(2)o(3) catalyst supported on reticulated ceramic foam for dry methane reforming. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 21(1), 57-63.
https://doi.org/10.30544/133

Nikolić V, Kamberović Ž, Korać M, Sokić M, Anđić Z, Tomović A. Ni-pd/al(2)o(3) catalyst supported on reticulated ceramic foam for dry methane reforming. in Metallurgical & Materials Engineering. 2015;21(1):57-63.
doi:10.30544/133 .

Nikolić, Vesna, Kamberović, Željko, Korać, Marija, Sokić, Miroslav, Anđić, Zoran, Tomović, Aleksandar, "Ni-pd/al(2)o(3) catalyst supported on reticulated ceramic foam for dry methane reforming" in Metallurgical & Materials Engineering, 21, no. 1 (2015):57-63,
https://doi.org/10.30544/133 . .

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokić, Miroslav
AU  - Gajić, Nataša
AU  - Jovanović, Nikola
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2916
AB  - The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Exploitation properties of ni-pd/al2o3 catalyst supported on ceramic foam
EP  - 282
IS  - 4
SP  - 277
VL  - 21
DO  - 10.30544/74
ER  - 

@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokić, Miroslav and Gajić, Nataša and Jovanović, Nikola",
year = "2015",
abstract = "The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Exploitation properties of ni-pd/al2o3 catalyst supported on ceramic foam",
pages = "282-277",
number = "4",
volume = "21",
doi = "10.30544/74"
}

Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokić, M., Gajić, N.,& Jovanović, N.. (2015). Exploitation properties of ni-pd/al2o3 catalyst supported on ceramic foam. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 21(4), 277-282.
https://doi.org/10.30544/74

Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokić M, Gajić N, Jovanović N. Exploitation properties of ni-pd/al2o3 catalyst supported on ceramic foam. in Metallurgical & Materials Engineering. 2015;21(4):277-282.
doi:10.30544/74 .

Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokić, Miroslav, Gajić, Nataša, Jovanović, Nikola, "Exploitation properties of ni-pd/al2o3 catalyst supported on ceramic foam" in Metallurgical & Materials Engineering, 21, no. 4 (2015):277-282,
https://doi.org/10.30544/74 . .

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Gulišija, Zvonko
AU  - Ilić, Ilija B.
AU  - Marković, Branislav
AU  - Štrbac, Nada
AU  - Živković, Dragana
AU  - Manojlović, Vaso
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2903
AB  - Procedures for copper secondary raw materials processing include two basic stages: pretreatment of the copper waste and its further metallurgical processing. For copper waste pretreatment technology, there are different applied procedures depending on the type of raw material. All operations of pretreatment are influencing the quality of metallurgical processing. For metallurgical processing of raw materials prepared for the purpose of obtaining copper and copper alloys the shaft, flaming and short-drum furnaces, converters and electric furnaces (electric resistant, electric arc and induction furnaces) are used.
AB  - Postupci prerade sekundarnih sirovina bakra uključuju dva osnovna stupnja: pripremu bakarnih otpadaka i njihovu dalju metaluršku preradu. Za pripremu bakarnih otpadaka koriste se različiti postupci u zavisnosti od vrste i kvaliteta sekundarne sirovine. Sve operacije pripreme utiču na kvalitet metalurške prerade, odnosno na kvalitet proizvoda. Za topljenje pripremljenih sekundarnih sirovina u cilju dobijanja legura na bazi bakra koriste se razni agregati: šahtne peći, konvertori, plamene lončaste i koritaste plamene peći, kratke bubnjaste peći i električne peći (elektrolučne, elektrootporne, indukcione).
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Metallurgical processing of copper secondary raw materials
T1  - Metalurška prerada sekundarnih sirovina bakra
EP  - 622
IS  - 4
SP  - 616
VL  - 70
DO  - 10.5937/tehnika1504616S
ER  - 

@article{
author = "Sokić, Miroslav and Gulišija, Zvonko and Ilić, Ilija B. and Marković, Branislav and Štrbac, Nada and Živković, Dragana and Manojlović, Vaso",
year = "2015",
abstract = "Procedures for copper secondary raw materials processing include two basic stages: pretreatment of the copper waste and its further metallurgical processing. For copper waste pretreatment technology, there are different applied procedures depending on the type of raw material. All operations of pretreatment are influencing the quality of metallurgical processing. For metallurgical processing of raw materials prepared for the purpose of obtaining copper and copper alloys the shaft, flaming and short-drum furnaces, converters and electric furnaces (electric resistant, electric arc and induction furnaces) are used., Postupci prerade sekundarnih sirovina bakra uključuju dva osnovna stupnja: pripremu bakarnih otpadaka i njihovu dalju metaluršku preradu. Za pripremu bakarnih otpadaka koriste se različiti postupci u zavisnosti od vrste i kvaliteta sekundarne sirovine. Sve operacije pripreme utiču na kvalitet metalurške prerade, odnosno na kvalitet proizvoda. Za topljenje pripremljenih sekundarnih sirovina u cilju dobijanja legura na bazi bakra koriste se razni agregati: šahtne peći, konvertori, plamene lončaste i koritaste plamene peći, kratke bubnjaste peći i električne peći (elektrolučne, elektrootporne, indukcione).",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Metallurgical processing of copper secondary raw materials, Metalurška prerada sekundarnih sirovina bakra",
pages = "622-616",
number = "4",
volume = "70",
doi = "10.5937/tehnika1504616S"
}

Sokić, M., Gulišija, Z., Ilić, I. B., Marković, B., Štrbac, N., Živković, D.,& Manojlović, V.. (2015). Metallurgical processing of copper secondary raw materials. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 70(4), 616-622.
https://doi.org/10.5937/tehnika1504616S

Sokić M, Gulišija Z, Ilić IB, Marković B, Štrbac N, Živković D, Manojlović V. Metallurgical processing of copper secondary raw materials. in Tehnika. 2015;70(4):616-622.
doi:10.5937/tehnika1504616S .

Sokić, Miroslav, Gulišija, Zvonko, Ilić, Ilija B., Marković, Branislav, Štrbac, Nada, Živković, Dragana, Manojlović, Vaso, "Metallurgical processing of copper secondary raw materials" in Tehnika, 70, no. 4 (2015):616-622,
https://doi.org/10.5937/tehnika1504616S . .