TY  - JOUR
AU  - Veljković, Filip M.
AU  - Dimitrijević, Stevan P.
AU  - Dimitrijević, Silvana B.
AU  - Vurdelja, Borislava D.
AU  - Matović, Branko Z.
AU  - Stoiljković, Milovan M.
AU  - Kamberović, Željko J.
AU  - Veličković, Suzana R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5317
AB  - This work presents the perspective of applying the laser desorption/ionization mass spectrometry (LDI MS) for characterization the anode film of the Ag60Cu26Zn14, Ag58.5Cu31.5Pd10, and Ag63Cu27In10 alloys (at high concentrations of chloride ions in solutions). The reference LDI mass spectra of anode films of pure Ag and Cu have been used for the identification of product corrosion. Knowing the clusters detected in the reference spectra lead to the facilitating identification of the LDI mass spectrum of the sample and reduces the analysis time. The LDI MS analysis of these alloys revealed that the predominant corrosion product are AgCl (from AgnCln+1−/+, n = 1–3), and CuCl (from “superhalogen” CumCln− clusters, m = 1–2, n = 2–6); it also revealed Cu2(OH)3Cl (from Cu2(OH)(H2O)2+) and Cu2O (from Cu(H2O)+, Cu2O doped with chlorine). These results are in accordance with the X-ray diffraction and Raman analysis. The LDI MS spectra of alloys contain the additional peaks formed due to the mutual influences of different metals in the alloys (AgCuCl3− (AgCl-CuCl2−), AgCu2Cl4− (AgCl-CuCl-CuCl2−), and Ag2CuCl4− (AgCl-AgCl-CuCl−), which is consistent with the identified corrosion products. It should be noted that the LDI MS suggest the presence of CuCl2, which can be interpreted as the corrosion products retained in the porous films of alloys, and not detected by the other methods due to a small amount. The future theoretical and experimental studies of metal clusters, significant for metallurgy, can contribute that the LDI MS is becoming a powerful analytical tool for characterization the metal surfaces.
PB  - Elsevier B.V.
T2  - Arabian Journal of Chemistry
T1  - Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system
IS  - 2
SP  - 104461
VL  - 16
DO  - 10.1016/j.arabjc.2022.104461
ER  - 

@article{
author = "Veljković, Filip M. and Dimitrijević, Stevan P. and Dimitrijević, Silvana B. and Vurdelja, Borislava D. and Matović, Branko Z. and Stoiljković, Milovan M. and Kamberović, Željko J. and Veličković, Suzana R.",
year = "2023",
abstract = "This work presents the perspective of applying the laser desorption/ionization mass spectrometry (LDI MS) for characterization the anode film of the Ag60Cu26Zn14, Ag58.5Cu31.5Pd10, and Ag63Cu27In10 alloys (at high concentrations of chloride ions in solutions). The reference LDI mass spectra of anode films of pure Ag and Cu have been used for the identification of product corrosion. Knowing the clusters detected in the reference spectra lead to the facilitating identification of the LDI mass spectrum of the sample and reduces the analysis time. The LDI MS analysis of these alloys revealed that the predominant corrosion product are AgCl (from AgnCln+1−/+, n = 1–3), and CuCl (from “superhalogen” CumCln− clusters, m = 1–2, n = 2–6); it also revealed Cu2(OH)3Cl (from Cu2(OH)(H2O)2+) and Cu2O (from Cu(H2O)+, Cu2O doped with chlorine). These results are in accordance with the X-ray diffraction and Raman analysis. The LDI MS spectra of alloys contain the additional peaks formed due to the mutual influences of different metals in the alloys (AgCuCl3− (AgCl-CuCl2−), AgCu2Cl4− (AgCl-CuCl-CuCl2−), and Ag2CuCl4− (AgCl-AgCl-CuCl−), which is consistent with the identified corrosion products. It should be noted that the LDI MS suggest the presence of CuCl2, which can be interpreted as the corrosion products retained in the porous films of alloys, and not detected by the other methods due to a small amount. The future theoretical and experimental studies of metal clusters, significant for metallurgy, can contribute that the LDI MS is becoming a powerful analytical tool for characterization the metal surfaces.",
publisher = "Elsevier B.V.",
journal = "Arabian Journal of Chemistry",
title = "Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system",
number = "2",
pages = "104461",
volume = "16",
doi = "10.1016/j.arabjc.2022.104461"
}

Veljković, F. M., Dimitrijević, S. P., Dimitrijević, S. B., Vurdelja, B. D., Matović, B. Z., Stoiljković, M. M., Kamberović, Ž. J.,& Veličković, S. R.. (2023). Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system. in Arabian Journal of Chemistry
Elsevier B.V.., 16(2), 104461.
https://doi.org/10.1016/j.arabjc.2022.104461

Veljković FM, Dimitrijević SP, Dimitrijević SB, Vurdelja BD, Matović BZ, Stoiljković MM, Kamberović ŽJ, Veličković SR. Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system. in Arabian Journal of Chemistry. 2023;16(2):104461.
doi:10.1016/j.arabjc.2022.104461 .

Veljković, Filip M., Dimitrijević, Stevan P., Dimitrijević, Silvana B., Vurdelja, Borislava D., Matović, Branko Z., Stoiljković, Milovan M., Kamberović, Željko J., Veličković, Suzana R., "Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system" in Arabian Journal of Chemistry, 16, no. 2 (2023):104461,
https://doi.org/10.1016/j.arabjc.2022.104461 . .

TY  - JOUR
AU  - Dimitrijević, Stevan
AU  - Vurdelja, Borislava D.
AU  - Dimitrijević, Silvana
AU  - Veljković, Filip M.
AU  - Kamberović, Željko
AU  - Veličković, Suzana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4456
AB  - Corrosion products formed on the surface of two silver brazing alloys after the potentiostatic polarization in 3.5% sodium chloride solution were characterized by the standard methods such as, the X-ray diffraction, microRaman spectroscopy, and scanning electron microscopy with energy-dispersive spectroscopy. This paper presents the results of a laser desorption/ionization mass spectrometry (LDI MS) analysis as a new approach to the characterization of corrosion products. The potential of the anodic polarization was 0.5 V versus saturated calomel electrode, and the process duration was 300 s. The corrosion layers on both investigated alloys were similar in composition with cuprous chloride and silver chloride as the main components and had strong indications of cuprous oxide formation. The major difference between these two layers was the existence of zinc hydroxychioride as the corrosion product of Ag-Cu-Zn alloy. Palladium compounds were not found in the case of Ag-Cu-Pd alloy. The results of different methods have shown a good consistency. Complementarity between the used methods was useful in the interpretation of the results for each used method. This study has demonstrated that LDI MS can be used as an efficient additional method together with the traditional ones.
PB  - Walter de Gruyter Gmbh, Berlin
T2  - Corrosion Reviews
T1  - Complementary methods for characterization of the corrosion products on the surface of Ag60Cu26Zn14 and Ag58.5Cu31.5Pd10 brazing alloys
EP  - 125
IS  - 2
SP  - 111
VL  - 38
DO  - 10.1515/corrrev-2019-0067
ER  - 

@article{
author = "Dimitrijević, Stevan and Vurdelja, Borislava D. and Dimitrijević, Silvana and Veljković, Filip M. and Kamberović, Željko and Veličković, Suzana",
year = "2020",
abstract = "Corrosion products formed on the surface of two silver brazing alloys after the potentiostatic polarization in 3.5% sodium chloride solution were characterized by the standard methods such as, the X-ray diffraction, microRaman spectroscopy, and scanning electron microscopy with energy-dispersive spectroscopy. This paper presents the results of a laser desorption/ionization mass spectrometry (LDI MS) analysis as a new approach to the characterization of corrosion products. The potential of the anodic polarization was 0.5 V versus saturated calomel electrode, and the process duration was 300 s. The corrosion layers on both investigated alloys were similar in composition with cuprous chloride and silver chloride as the main components and had strong indications of cuprous oxide formation. The major difference between these two layers was the existence of zinc hydroxychioride as the corrosion product of Ag-Cu-Zn alloy. Palladium compounds were not found in the case of Ag-Cu-Pd alloy. The results of different methods have shown a good consistency. Complementarity between the used methods was useful in the interpretation of the results for each used method. This study has demonstrated that LDI MS can be used as an efficient additional method together with the traditional ones.",
publisher = "Walter de Gruyter Gmbh, Berlin",
journal = "Corrosion Reviews",
title = "Complementary methods for characterization of the corrosion products on the surface of Ag60Cu26Zn14 and Ag58.5Cu31.5Pd10 brazing alloys",
pages = "125-111",
number = "2",
volume = "38",
doi = "10.1515/corrrev-2019-0067"
}

Dimitrijević, S., Vurdelja, B. D., Dimitrijević, S., Veljković, F. M., Kamberović, Ž.,& Veličković, S.. (2020). Complementary methods for characterization of the corrosion products on the surface of Ag60Cu26Zn14 and Ag58.5Cu31.5Pd10 brazing alloys. in Corrosion Reviews
Walter de Gruyter Gmbh, Berlin., 38(2), 111-125.
https://doi.org/10.1515/corrrev-2019-0067

Dimitrijević S, Vurdelja BD, Dimitrijević S, Veljković FM, Kamberović Ž, Veličković S. Complementary methods for characterization of the corrosion products on the surface of Ag60Cu26Zn14 and Ag58.5Cu31.5Pd10 brazing alloys. in Corrosion Reviews. 2020;38(2):111-125.
doi:10.1515/corrrev-2019-0067 .

Dimitrijević, Stevan, Vurdelja, Borislava D., Dimitrijević, Silvana, Veljković, Filip M., Kamberović, Željko, Veličković, Suzana, "Complementary methods for characterization of the corrosion products on the surface of Ag60Cu26Zn14 and Ag58.5Cu31.5Pd10 brazing alloys" in Corrosion Reviews, 38, no. 2 (2020):111-125,
https://doi.org/10.1515/corrrev-2019-0067 . .

TY  - CONF
AU  - Vurdelja, Borislava
AU  - Veljković, Filip
AU  - Rajčić, Boris
AU  - Dimitrijević, Silvana
AU  - Dimitrijević, Stevan
AU  - Kamberović, Željko J.
AU  - Veličković, Suzana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6981
AB  - Precise, direct and fast methods for characterization the anodic films still have to be developed, since the conventional methods cannot be accelerated beyond the certain limits. The present work uses a laser desorption/ionization mass spectrometry (LDI MS) to characterize the chemical composition of anodic film on the Ag60Cu26Zn14 alloy. The positive mode mass spectra, measured from the propan-2-ol solution of corrosion film, shows the formation of three major signals originating from the Ag+, CuCl2CuCl(H2O)+ and Cu(OH)2(CuCl)3+ species. The other ions, such as Cu+, Cu(H2O)+, CuO(H2O)+, AgCl(H2O)+, Cu(ClO)2+, AgCuCl+, Ag2Cl(H2O)3+, have a much lower intensity. It has been noted that the ion species of zinc with chlorine or oxygen where not detected.
PB  - Bor : Mining and Metallurgy Institute
C3  - Proceedings / 50th International October Conference on Mining and Metallurgy - IOC 2018, 30th September - 3rd October 2018 Bor Lake, Serbia
T1  - CHARACTERIZATION OF THE ANODIC FILMS FORMED ON THE Ag60Cu26Zn14 ALLOY BY THE LDI MASS SPECTROMETRY
EP  - 264
SP  - 261
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6981
ER  - 

@conference{
author = "Vurdelja, Borislava and Veljković, Filip and Rajčić, Boris and Dimitrijević, Silvana and Dimitrijević, Stevan and Kamberović, Željko J. and Veličković, Suzana",
year = "2018",
abstract = "Precise, direct and fast methods for characterization the anodic films still have to be developed, since the conventional methods cannot be accelerated beyond the certain limits. The present work uses a laser desorption/ionization mass spectrometry (LDI MS) to characterize the chemical composition of anodic film on the Ag60Cu26Zn14 alloy. The positive mode mass spectra, measured from the propan-2-ol solution of corrosion film, shows the formation of three major signals originating from the Ag+, CuCl2CuCl(H2O)+ and Cu(OH)2(CuCl)3+ species. The other ions, such as Cu+, Cu(H2O)+, CuO(H2O)+, AgCl(H2O)+, Cu(ClO)2+, AgCuCl+, Ag2Cl(H2O)3+, have a much lower intensity. It has been noted that the ion species of zinc with chlorine or oxygen where not detected.",
publisher = "Bor : Mining and Metallurgy Institute",
journal = "Proceedings / 50th International October Conference on Mining and Metallurgy - IOC 2018, 30th September - 3rd October 2018 Bor Lake, Serbia",
title = "CHARACTERIZATION OF THE ANODIC FILMS FORMED ON THE Ag60Cu26Zn14 ALLOY BY THE LDI MASS SPECTROMETRY",
pages = "264-261",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6981"
}

Vurdelja, B., Veljković, F., Rajčić, B., Dimitrijević, S., Dimitrijević, S., Kamberović, Ž. J.,& Veličković, S.. (2018). CHARACTERIZATION OF THE ANODIC FILMS FORMED ON THE Ag60Cu26Zn14 ALLOY BY THE LDI MASS SPECTROMETRY. in Proceedings / 50th International October Conference on Mining and Metallurgy - IOC 2018, 30th September - 3rd October 2018 Bor Lake, Serbia
Bor : Mining and Metallurgy Institute., 261-264.
https://hdl.handle.net/21.15107/rcub_technorep_6981

Vurdelja B, Veljković F, Rajčić B, Dimitrijević S, Dimitrijević S, Kamberović ŽJ, Veličković S. CHARACTERIZATION OF THE ANODIC FILMS FORMED ON THE Ag60Cu26Zn14 ALLOY BY THE LDI MASS SPECTROMETRY. in Proceedings / 50th International October Conference on Mining and Metallurgy - IOC 2018, 30th September - 3rd October 2018 Bor Lake, Serbia. 2018;:261-264.
https://hdl.handle.net/21.15107/rcub_technorep_6981 .

Vurdelja, Borislava, Veljković, Filip, Rajčić, Boris, Dimitrijević, Silvana, Dimitrijević, Stevan, Kamberović, Željko J., Veličković, Suzana, "CHARACTERIZATION OF THE ANODIC FILMS FORMED ON THE Ag60Cu26Zn14 ALLOY BY THE LDI MASS SPECTROMETRY" in Proceedings / 50th International October Conference on Mining and Metallurgy - IOC 2018, 30th September - 3rd October 2018 Bor Lake, Serbia (2018):261-264,
https://hdl.handle.net/21.15107/rcub_technorep_6981 .

TY  - JOUR
AU  - Vurdelja, Borislava D.
AU  - Dimitrijević, Stevan P.
AU  - Dimitrijević, Silvana B.
AU  - Kamberović, Željko J.
AU  - Veličković, Suzana R.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3656
AB  - This work is the first to demonstrate the possibilities of direct analysis of the corrosion film formed on Ag43Cu37Zn20 alloy using laser desorption/ionization (LDI) on a commercial matrix-assisted LDI time of flight mass spectrometry (MS) instrument. In the LDI mass spectra measured from the water solution of the corrosion film, the ion species Zn+, Zn(H2O)(+), AgH+, Cu2H+, Cu2O(OH)+, Cu3O(OH)(+) (high intensity), and Cu(OH)(H2O)(+), ZnCl(OH)(H2O)(+), AgCl+, CuCl+ (low intensity) were identified. The LDI mass spectra of the propan-2-ol solution of the corrosion film contains the ions Zn5Cl(OH)(3)(H2O)(11)(+), Zn5Cl2 (OH)(8) (H2O)(6)(+), and Zn5Cl2 (OH)(H2O)(14)(+). Mass spectra were observed at laser energies in the range of 1340-1860 arbitrary units in positive ion mode. Previously, Raman spectra and X-ray diffraction (XRD) analysis of the same anodic film have shown similar results as LDI MS -that the anodic film contains the mixture of Ag, Cu2O, CuCl, Zn5Cl2(OH)(8) center dot H2O, and beta-Zn(OH) Cl. LDI MS could be a complementary method for XRD and Raman, as demonstrated in this investigation. The LDI MS method greatly reduces the analysis time and amount of the sample compared to traditional methods. For this reason, the LDI MS method can be a useful tool for the fast qualitative screening of corrosion films.
PB  - Walter de Gruyter Gmbh
T2  - Corrosion Reviews
T1  - Characterization of the Ag43Cu37Zn20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry
EP  - 481
IS  - 6
SP  - 473
VL  - 35
DO  - 10.1515/corrrev-2017-0065
ER  - 

@article{
author = "Vurdelja, Borislava D. and Dimitrijević, Stevan P. and Dimitrijević, Silvana B. and Kamberović, Željko J. and Veličković, Suzana R.",
year = "2017",
abstract = "This work is the first to demonstrate the possibilities of direct analysis of the corrosion film formed on Ag43Cu37Zn20 alloy using laser desorption/ionization (LDI) on a commercial matrix-assisted LDI time of flight mass spectrometry (MS) instrument. In the LDI mass spectra measured from the water solution of the corrosion film, the ion species Zn+, Zn(H2O)(+), AgH+, Cu2H+, Cu2O(OH)+, Cu3O(OH)(+) (high intensity), and Cu(OH)(H2O)(+), ZnCl(OH)(H2O)(+), AgCl+, CuCl+ (low intensity) were identified. The LDI mass spectra of the propan-2-ol solution of the corrosion film contains the ions Zn5Cl(OH)(3)(H2O)(11)(+), Zn5Cl2 (OH)(8) (H2O)(6)(+), and Zn5Cl2 (OH)(H2O)(14)(+). Mass spectra were observed at laser energies in the range of 1340-1860 arbitrary units in positive ion mode. Previously, Raman spectra and X-ray diffraction (XRD) analysis of the same anodic film have shown similar results as LDI MS -that the anodic film contains the mixture of Ag, Cu2O, CuCl, Zn5Cl2(OH)(8) center dot H2O, and beta-Zn(OH) Cl. LDI MS could be a complementary method for XRD and Raman, as demonstrated in this investigation. The LDI MS method greatly reduces the analysis time and amount of the sample compared to traditional methods. For this reason, the LDI MS method can be a useful tool for the fast qualitative screening of corrosion films.",
publisher = "Walter de Gruyter Gmbh",
journal = "Corrosion Reviews",
title = "Characterization of the Ag43Cu37Zn20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry",
pages = "481-473",
number = "6",
volume = "35",
doi = "10.1515/corrrev-2017-0065"
}

Vurdelja, B. D., Dimitrijević, S. P., Dimitrijević, S. B., Kamberović, Ž. J.,& Veličković, S. R.. (2017). Characterization of the Ag43Cu37Zn20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry. in Corrosion Reviews
Walter de Gruyter Gmbh., 35(6), 473-481.
https://doi.org/10.1515/corrrev-2017-0065

Vurdelja BD, Dimitrijević SP, Dimitrijević SB, Kamberović ŽJ, Veličković SR. Characterization of the Ag43Cu37Zn20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry. in Corrosion Reviews. 2017;35(6):473-481.
doi:10.1515/corrrev-2017-0065 .

Vurdelja, Borislava D., Dimitrijević, Stevan P., Dimitrijević, Silvana B., Kamberović, Željko J., Veličković, Suzana R., "Characterization of the Ag43Cu37Zn20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry" in Corrosion Reviews, 35, no. 6 (2017):473-481,
https://doi.org/10.1515/corrrev-2017-0065 . .