TY  - JOUR
AU  - Velicić, Zorica
AU  - Rusmirović, Jelena
AU  - Prlainović, Nevena
AU  - Tomić, Nataša
AU  - Veličković, Zlate
AU  - Taleb, Khaled
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4461
AB  - In this work, the optimization of synthesis of terpolymer monolith based on glycidyl methacrylate (GMA), ethylene glycol dimethacrylate (EGDMA) and additional cross-linkers: trimethylolpropanetriacrylate (TMPTA) or triethylene glycol dimethacrylate (TEGDMA) was performed. Moreover, novel vinyl functionalized cross-linkable polymers: ethanolamine (EA)/methacryloyl (MAC) modified poly (methyl methacrylate) (PMMA), and hydrolyzed poly (ethylene-co-vinyl acetate) copolymer (EVOH) modified with MAC either directly or via ethyl malonyl chloride/EA bridging group (m-EVA) were used as cross-linkable polymer to improve mechanical/elastic properties of the obtained monoliths. Optimization procedure, performed applying response surface methodology (RSM), was focused on the production of materials with improved dimensional stability/integrity and porosity with abundance of epoxide groups capable for immobilization of lipase from Candida rugosa (CRL). Structural characterization of the synthesized monoliths was determined using FTIR, Raman and H-1 NMR spectroscopies, while morphology/porosity was determined by SEM technique and image analysis; and mechanical properties by diametral compression testing. The most potential monolith containing m-EVA polymeric cross-linker, i.e. GMA/EGDMA/TEGDMA/m-EVA monolith, was used as CRL carrier in a two-step immobilization process. Enzyme loading and the activity of obtained preparations for various initial enzyme concentrations were monitored after 4 and 48 h of immobilization. The resulting catalysts show high potency in biocatalytic reactions with the highest percentage of retained initial lipase activity of 64.5%.
PB  - Springer, Dordrecht
T2  - Journal of Polymer Research
T1  - The optimization of glycidyl methacrylate based terpolymer monolith synthesis: an effective Candida rugosa lipase immobilization support
IS  - 5
VL  - 27
DO  - 10.1007/s10965-020-02127-z
ER  - 

@article{
author = "Velicić, Zorica and Rusmirović, Jelena and Prlainović, Nevena and Tomić, Nataša and Veličković, Zlate and Taleb, Khaled and Marinković, Aleksandar",
year = "2020",
abstract = "In this work, the optimization of synthesis of terpolymer monolith based on glycidyl methacrylate (GMA), ethylene glycol dimethacrylate (EGDMA) and additional cross-linkers: trimethylolpropanetriacrylate (TMPTA) or triethylene glycol dimethacrylate (TEGDMA) was performed. Moreover, novel vinyl functionalized cross-linkable polymers: ethanolamine (EA)/methacryloyl (MAC) modified poly (methyl methacrylate) (PMMA), and hydrolyzed poly (ethylene-co-vinyl acetate) copolymer (EVOH) modified with MAC either directly or via ethyl malonyl chloride/EA bridging group (m-EVA) were used as cross-linkable polymer to improve mechanical/elastic properties of the obtained monoliths. Optimization procedure, performed applying response surface methodology (RSM), was focused on the production of materials with improved dimensional stability/integrity and porosity with abundance of epoxide groups capable for immobilization of lipase from Candida rugosa (CRL). Structural characterization of the synthesized monoliths was determined using FTIR, Raman and H-1 NMR spectroscopies, while morphology/porosity was determined by SEM technique and image analysis; and mechanical properties by diametral compression testing. The most potential monolith containing m-EVA polymeric cross-linker, i.e. GMA/EGDMA/TEGDMA/m-EVA monolith, was used as CRL carrier in a two-step immobilization process. Enzyme loading and the activity of obtained preparations for various initial enzyme concentrations were monitored after 4 and 48 h of immobilization. The resulting catalysts show high potency in biocatalytic reactions with the highest percentage of retained initial lipase activity of 64.5%.",
publisher = "Springer, Dordrecht",
journal = "Journal of Polymer Research",
title = "The optimization of glycidyl methacrylate based terpolymer monolith synthesis: an effective Candida rugosa lipase immobilization support",
number = "5",
volume = "27",
doi = "10.1007/s10965-020-02127-z"
}

Velicić, Z., Rusmirović, J., Prlainović, N., Tomić, N., Veličković, Z., Taleb, K.,& Marinković, A.. (2020). The optimization of glycidyl methacrylate based terpolymer monolith synthesis: an effective Candida rugosa lipase immobilization support. in Journal of Polymer Research
Springer, Dordrecht., 27(5).
https://doi.org/10.1007/s10965-020-02127-z

Velicić Z, Rusmirović J, Prlainović N, Tomić N, Veličković Z, Taleb K, Marinković A. The optimization of glycidyl methacrylate based terpolymer monolith synthesis: an effective Candida rugosa lipase immobilization support. in Journal of Polymer Research. 2020;27(5).
doi:10.1007/s10965-020-02127-z .

Velicić, Zorica, Rusmirović, Jelena, Prlainović, Nevena, Tomić, Nataša, Veličković, Zlate, Taleb, Khaled, Marinković, Aleksandar, "The optimization of glycidyl methacrylate based terpolymer monolith synthesis: an effective Candida rugosa lipase immobilization support" in Journal of Polymer Research, 27, no. 5 (2020),
https://doi.org/10.1007/s10965-020-02127-z . .

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Veličković, Zlate
AU  - Rusmirović, Jelena
AU  - Rančić, Milica
AU  - Pavlović, Vladimir B.
AU  - Marinković, Aleksandar
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4140
AB  - Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g(-1)) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg(-1) min(-1)). Lower capacity of arsenite, As(III), removal, 68.3 mg g(-1) for NC-MA/L-MG and 17.8 mg g(-1) for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol(-1) for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.
PB  - Elsevier, Amsterdam
T2  - Arabian Journal of Chemistry
T1  - Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size
EP  - 4693
IS  - 8
SP  - 4675
VL  - 12
DO  - 10.1016/j.arabjc.2016.08.006
ER  - 

@article{
author = "Taleb, Khaled and Markovski, Jasmina and Veličković, Zlate and Rusmirović, Jelena and Rančić, Milica and Pavlović, Vladimir B. and Marinković, Aleksandar",
year = "2019",
abstract = "Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g(-1)) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg(-1) min(-1)). Lower capacity of arsenite, As(III), removal, 68.3 mg g(-1) for NC-MA/L-MG and 17.8 mg g(-1) for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol(-1) for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.",
publisher = "Elsevier, Amsterdam",
journal = "Arabian Journal of Chemistry",
title = "Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size",
pages = "4693-4675",
number = "8",
volume = "12",
doi = "10.1016/j.arabjc.2016.08.006"
}

Taleb, K., Markovski, J., Veličković, Z., Rusmirović, J., Rančić, M., Pavlović, V. B.,& Marinković, A.. (2019). Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size. in Arabian Journal of Chemistry
Elsevier, Amsterdam., 12(8), 4675-4693.
https://doi.org/10.1016/j.arabjc.2016.08.006

Taleb K, Markovski J, Veličković Z, Rusmirović J, Rančić M, Pavlović VB, Marinković A. Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size. in Arabian Journal of Chemistry. 2019;12(8):4675-4693.
doi:10.1016/j.arabjc.2016.08.006 .

Taleb, Khaled, Markovski, Jasmina, Veličković, Zlate, Rusmirović, Jelena, Rančić, Milica, Pavlović, Vladimir B., Marinković, Aleksandar, "Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size" in Arabian Journal of Chemistry, 12, no. 8 (2019):4675-4693,
https://doi.org/10.1016/j.arabjc.2016.08.006 . .

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Hristovski, Kiril
AU  - Rajaković-Ognjanović, Vladana
AU  - Onjia, Antonije
AU  - Marinković, Aleksandar
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3186
AB  - To achieve short mass transfer zones that enable arsenic removal under high hydraulic loading rates and short empty bed contact times needed for small point-of-use packed bed applications, hybrid media was developed and tested. Cross-linked macroporous glycidyl methacrylate copolymer support media was synthetized, amino modified and in-situ impregnated by goethite nanoparticles via an oxidative deposition in a hydrophilic/hydrophobic (water/xylene) system. The media properties were characterized via scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDS), X-ray diffraction (XRD), and surface area analysis. Arsenic removal capabilities of the hybrid goethite impregnated media were evaluated by conducting batch sorption tests, developing isotherms and simulating the breakthrough curve with a pore surface diffusion model (PSDM), after being verified by a short bed column (SBC) test. The high porous media (ep ≈ 0.7) contained ∼16% of iron and exhibited Freundlich adsorption capacity parameter of K ≈ 369 (µg g−1)(L µg−1)1/n and Freundlich intensity parameter of 1/n ≈ 0.54. Without engaging in taxing pilot scale testing, the PSDM was able to provide a good prediction of the media's capacity and intraparticle mass transport properties under high hydraulic loading rates.
PB  - Tomsk Polytechnic University
T2  - Resource-Efficient Technologies
T1  - Aminated glycidyl methacrylates as a support media for goethite nanoparticle enabled hybrid sorbents for arsenic removal: From copolymer synthesis to full-scale system modeling
EP  - 22
IS  - 1
SP  - 15
VL  - 2
DO  - 10.1016/j.reffit.2016.04.002
ER  - 

@article{
author = "Taleb, Khaled and Markovski, Jasmina and Hristovski, Kiril and Rajaković-Ognjanović, Vladana and Onjia, Antonije and Marinković, Aleksandar",
year = "2016",
abstract = "To achieve short mass transfer zones that enable arsenic removal under high hydraulic loading rates and short empty bed contact times needed for small point-of-use packed bed applications, hybrid media was developed and tested. Cross-linked macroporous glycidyl methacrylate copolymer support media was synthetized, amino modified and in-situ impregnated by goethite nanoparticles via an oxidative deposition in a hydrophilic/hydrophobic (water/xylene) system. The media properties were characterized via scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDS), X-ray diffraction (XRD), and surface area analysis. Arsenic removal capabilities of the hybrid goethite impregnated media were evaluated by conducting batch sorption tests, developing isotherms and simulating the breakthrough curve with a pore surface diffusion model (PSDM), after being verified by a short bed column (SBC) test. The high porous media (ep ≈ 0.7) contained ∼16% of iron and exhibited Freundlich adsorption capacity parameter of K ≈ 369 (µg g−1)(L µg−1)1/n and Freundlich intensity parameter of 1/n ≈ 0.54. Without engaging in taxing pilot scale testing, the PSDM was able to provide a good prediction of the media's capacity and intraparticle mass transport properties under high hydraulic loading rates.",
publisher = "Tomsk Polytechnic University",
journal = "Resource-Efficient Technologies",
title = "Aminated glycidyl methacrylates as a support media for goethite nanoparticle enabled hybrid sorbents for arsenic removal: From copolymer synthesis to full-scale system modeling",
pages = "22-15",
number = "1",
volume = "2",
doi = "10.1016/j.reffit.2016.04.002"
}

Taleb, K., Markovski, J., Hristovski, K., Rajaković-Ognjanović, V., Onjia, A.,& Marinković, A.. (2016). Aminated glycidyl methacrylates as a support media for goethite nanoparticle enabled hybrid sorbents for arsenic removal: From copolymer synthesis to full-scale system modeling. in Resource-Efficient Technologies
Tomsk Polytechnic University., 2(1), 15-22.
https://doi.org/10.1016/j.reffit.2016.04.002

Taleb K, Markovski J, Hristovski K, Rajaković-Ognjanović V, Onjia A, Marinković A. Aminated glycidyl methacrylates as a support media for goethite nanoparticle enabled hybrid sorbents for arsenic removal: From copolymer synthesis to full-scale system modeling. in Resource-Efficient Technologies. 2016;2(1):15-22.
doi:10.1016/j.reffit.2016.04.002 .

Taleb, Khaled, Markovski, Jasmina, Hristovski, Kiril, Rajaković-Ognjanović, Vladana, Onjia, Antonije, Marinković, Aleksandar, "Aminated glycidyl methacrylates as a support media for goethite nanoparticle enabled hybrid sorbents for arsenic removal: From copolymer synthesis to full-scale system modeling" in Resource-Efficient Technologies, 2, no. 1 (2016):15-22,
https://doi.org/10.1016/j.reffit.2016.04.002 . .

TY  - JOUR
AU  - Taleb, Khaled
AU  - Rusmirović, Jelena
AU  - Rančić, Milica
AU  - Nikolić, Jasmina
AU  - Drmanić, Saša
AU  - Veličković, Zlate
AU  - Marinković, Aleksandar
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3292
AB  - A novel adsorbent, NC-PEG, obtained by modification of nanocellulose (NC) with PEG-6-arm amino polyethylene glycol (PEG-NH2) via maleic anhydride (MA) linker, was used for removal of Cd2+ and Ni2+ from water. A subsequent precipitation of iron oxide (FO) from goethite on NC-PEG was employed to produce NC-PEG/FO adsorbent which was used for As(V) and As(III) removal. In a batch test, the influence of pH, contact time, initial ion concentration and temperature on the adsorption efficiency were studied. The maximum adsorption capacities found for Cd2+ and Ni2+, obtained by the use of Langmuir model, were 37.9 and 32.4 mg g(-1) at 25 degrees C, respectively. Also, high As(V) and As(III) removal capacities of 26.0 and 23.6 mg g(-1) were obtained. The thermodynamic parameters indicated endothermic, feasible and spontaneous nature of the adsorption process. The kinetic study, i.e., fitting by Weber-Morris model predicted that intra-particle diffusion was the rate-controlling step. The ability for multi-cycle reusability of both NC-PEG and NCPEG/FO, represents a positive indicator when considering their possible applications.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide
EP  - 1213
IS  - 10
SP  - 1199
VL  - 81
DO  - 10.2298/JSC160529063T
ER  - 

@article{
author = "Taleb, Khaled and Rusmirović, Jelena and Rančić, Milica and Nikolić, Jasmina and Drmanić, Saša and Veličković, Zlate and Marinković, Aleksandar",
year = "2016",
abstract = "A novel adsorbent, NC-PEG, obtained by modification of nanocellulose (NC) with PEG-6-arm amino polyethylene glycol (PEG-NH2) via maleic anhydride (MA) linker, was used for removal of Cd2+ and Ni2+ from water. A subsequent precipitation of iron oxide (FO) from goethite on NC-PEG was employed to produce NC-PEG/FO adsorbent which was used for As(V) and As(III) removal. In a batch test, the influence of pH, contact time, initial ion concentration and temperature on the adsorption efficiency were studied. The maximum adsorption capacities found for Cd2+ and Ni2+, obtained by the use of Langmuir model, were 37.9 and 32.4 mg g(-1) at 25 degrees C, respectively. Also, high As(V) and As(III) removal capacities of 26.0 and 23.6 mg g(-1) were obtained. The thermodynamic parameters indicated endothermic, feasible and spontaneous nature of the adsorption process. The kinetic study, i.e., fitting by Weber-Morris model predicted that intra-particle diffusion was the rate-controlling step. The ability for multi-cycle reusability of both NC-PEG and NCPEG/FO, represents a positive indicator when considering their possible applications.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide",
pages = "1213-1199",
number = "10",
volume = "81",
doi = "10.2298/JSC160529063T"
}

Taleb, K., Rusmirović, J., Rančić, M., Nikolić, J., Drmanić, S., Veličković, Z.,& Marinković, A.. (2016). Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 81(10), 1199-1213.
https://doi.org/10.2298/JSC160529063T

Taleb K, Rusmirović J, Rančić M, Nikolić J, Drmanić S, Veličković Z, Marinković A. Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide. in Journal of the Serbian Chemical Society. 2016;81(10):1199-1213.
doi:10.2298/JSC160529063T .

Taleb, Khaled, Rusmirović, Jelena, Rančić, Milica, Nikolić, Jasmina, Drmanić, Saša, Veličković, Zlate, Marinković, Aleksandar, "Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide" in Journal of the Serbian Chemical Society, 81, no. 10 (2016):1199-1213,
https://doi.org/10.2298/JSC160529063T . .

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Hristovski, Kiril
AU  - Rajaković-Ognjanović, Vladana
AU  - Marinković, Aleksandar
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3092
PB  - Amer Chemical Soc, Washington
T2  - Abstracts of Papers of the American Chemical Society
T1  - Goethite nanoparticles impregnated cross-linked macroporous polymer for arsenic removal: fullscale system modeling
VL  - 250
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3092
ER  - 

@article{
author = "Taleb, Khaled and Markovski, Jasmina and Hristovski, Kiril and Rajaković-Ognjanović, Vladana and Marinković, Aleksandar",
year = "2015",
publisher = "Amer Chemical Soc, Washington",
journal = "Abstracts of Papers of the American Chemical Society",
title = "Goethite nanoparticles impregnated cross-linked macroporous polymer for arsenic removal: fullscale system modeling",
volume = "250",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3092"
}

Taleb, K., Markovski, J., Hristovski, K., Rajaković-Ognjanović, V.,& Marinković, A.. (2015). Goethite nanoparticles impregnated cross-linked macroporous polymer for arsenic removal: fullscale system modeling. in Abstracts of Papers of the American Chemical Society
Amer Chemical Soc, Washington., 250.
https://hdl.handle.net/21.15107/rcub_technorep_3092

Taleb K, Markovski J, Hristovski K, Rajaković-Ognjanović V, Marinković A. Goethite nanoparticles impregnated cross-linked macroporous polymer for arsenic removal: fullscale system modeling. in Abstracts of Papers of the American Chemical Society. 2015;250.
https://hdl.handle.net/21.15107/rcub_technorep_3092 .

Taleb, Khaled, Markovski, Jasmina, Hristovski, Kiril, Rajaković-Ognjanović, Vladana, Marinković, Aleksandar, "Goethite nanoparticles impregnated cross-linked macroporous polymer for arsenic removal: fullscale system modeling" in Abstracts of Papers of the American Chemical Society, 250 (2015),
https://hdl.handle.net/21.15107/rcub_technorep_3092 .

TY  - JOUR
AU  - Taleb, Khaled
AU  - Markovski, Jasmina
AU  - Milosavljević, Milutin
AU  - Marinović-Cincović, Milena
AU  - Rusmirović, Jelena
AU  - Ristić, Mirjana
AU  - Marinković, Aleksandar
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3151
AB  - Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance
EP  - 78
SP  - 66
VL  - 279
DO  - 10.1016/j.cej.2015.04.147
ER  - 

@article{
author = "Taleb, Khaled and Markovski, Jasmina and Milosavljević, Milutin and Marinović-Cincović, Milena and Rusmirović, Jelena and Ristić, Mirjana and Marinković, Aleksandar",
year = "2015",
abstract = "Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance",
pages = "78-66",
volume = "279",
doi = "10.1016/j.cej.2015.04.147"
}

Taleb, K., Markovski, J., Milosavljević, M., Marinović-Cincović, M., Rusmirović, J., Ristić, M.,& Marinković, A.. (2015). Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 279, 66-78.
https://doi.org/10.1016/j.cej.2015.04.147

Taleb K, Markovski J, Milosavljević M, Marinović-Cincović M, Rusmirović J, Ristić M, Marinković A. Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal. 2015;279:66-78.
doi:10.1016/j.cej.2015.04.147 .

Taleb, Khaled, Markovski, Jasmina, Milosavljević, Milutin, Marinović-Cincović, Milena, Rusmirović, Jelena, Ristić, Mirjana, Marinković, Aleksandar, "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance" in Chemical Engineering Journal, 279 (2015):66-78,
https://doi.org/10.1016/j.cej.2015.04.147 . .