Popović, Maja

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orcid::0000-0002-0659-1732
  • Popović, Maja (8)

Author's Bibliography

Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air

Bjelajac, Anđelika; Petrović, Rada; Popović, Maja; Rakočević, Zlatko Lj.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier Ltd, 2019)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5027
AB  - The ∼60 nm wide and ∼2 μm long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.
PB  - Elsevier Ltd
T2  - Thin Solid Films
T1  - Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air
SP  - 137598
VL  - 692
DO  - 10.1016/j.tsf.2019.137598
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Popović, Maja and Rakočević, Zlatko Lj. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2019",
abstract = "The ∼60 nm wide and ∼2 μm long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.",
publisher = "Elsevier Ltd",
journal = "Thin Solid Films",
title = "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air",
pages = "137598",
volume = "692",
doi = "10.1016/j.tsf.2019.137598"
}
Bjelajac, A., Petrović, R., Popović, M., Rakočević, Z. Lj., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2019). Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films
Elsevier Ltd., 692, 137598.
https://doi.org/10.1016/j.tsf.2019.137598
Bjelajac A, Petrović R, Popović M, Rakočević ZL, Socol G, Mihailescu IN, Janaćković Đ. Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films. 2019;692:137598.
doi:10.1016/j.tsf.2019.137598 .
Bjelajac, Anđelika, Petrović, Rada, Popović, Maja, Rakočević, Zlatko Lj., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air" in Thin Solid Films, 692 (2019):137598,
https://doi.org/10.1016/j.tsf.2019.137598 . .
12
10
13

Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air

Bjelajac, Anđelika; Petrović, Rada; Popović, Maja; Rakočević, Zlatko Lj.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier Science Sa, Lausanne, 2019)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4092
AB  - The similar to 60 nm wide and similar to 2 mu m long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.
PB  - Elsevier Science Sa, Lausanne
T2  - Thin Solid Films
T1  - Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air
SP  - 137598
VL  - 692
DO  - 10.1016/j.tsf.2019.137598
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Popović, Maja and Rakočević, Zlatko Lj. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2019",
abstract = "The similar to 60 nm wide and similar to 2 mu m long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Thin Solid Films",
title = "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air",
pages = "137598",
volume = "692",
doi = "10.1016/j.tsf.2019.137598"
}
Bjelajac, A., Petrović, R., Popović, M., Rakočević, Z. Lj., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2019). Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films
Elsevier Science Sa, Lausanne., 692, 137598.
https://doi.org/10.1016/j.tsf.2019.137598
Bjelajac A, Petrović R, Popović M, Rakočević ZL, Socol G, Mihailescu IN, Janaćković Đ. Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films. 2019;692:137598.
doi:10.1016/j.tsf.2019.137598 .
Bjelajac, Anđelika, Petrović, Rada, Popović, Maja, Rakočević, Zlatko Lj., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air" in Thin Solid Films, 692 (2019):137598,
https://doi.org/10.1016/j.tsf.2019.137598 . .
12
10

Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko Lj.; Horvath, Endre; Kollar, Marton; Nafradi, Balint; Schiller, Andreas; Domanski, Konrad; Forro, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(Elsevier Sci Ltd, Oxford, 2019)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Horvath, Endre
AU  - Kollar, Marton
AU  - Nafradi, Balint
AU  - Schiller, Andreas
AU  - Domanski, Konrad
AU  - Forro, Laszlo
AU  - Pavlović, Vera P.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4251
AB  - Highly ordered, anodically grown TiO2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping ( lt = 2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 +/- 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO2/CH3NH3PbI3 single crystals. The N-TiO2/perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping
EP  - 10020
IS  - 8
SP  - 10013
VL  - 45
DO  - 10.1016/j.ceramint.2019.02.045
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko Lj. and Horvath, Endre and Kollar, Marton and Nafradi, Balint and Schiller, Andreas and Domanski, Konrad and Forro, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
abstract = "Highly ordered, anodically grown TiO2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping ( lt = 2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 +/- 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO2/CH3NH3PbI3 single crystals. The N-TiO2/perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping",
pages = "10020-10013",
number = "8",
volume = "45",
doi = "10.1016/j.ceramint.2019.02.045"
}
Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z. Lj., Horvath, E., Kollar, M., Nafradi, B., Schiller, A., Domanski, K., Forro, L., Pavlović, V. P.,& Janaćković, Đ.. (2019). Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(8), 10013-10020.
https://doi.org/10.1016/j.ceramint.2019.02.045
Vujančević J, Andričević P, Bjelajac A, Đokić V, Popović M, Rakočević ZL, Horvath E, Kollar M, Nafradi B, Schiller A, Domanski K, Forro L, Pavlović VP, Janaćković Đ. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. in Ceramics International. 2019;45(8):10013-10020.
doi:10.1016/j.ceramint.2019.02.045 .
Vujančević, Jelena, Andričević, Pavao, Bjelajac, Anđelika, Đokić, Veljko, Popović, Maja, Rakočević, Zlatko Lj., Horvath, Endre, Kollar, Marton, Nafradi, Balint, Schiller, Andreas, Domanski, Konrad, Forro, Laszlo, Pavlović, Vera P., Janaćković, Đorđe, "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping" in Ceramics International, 45, no. 8 (2019):10013-10020,
https://doi.org/10.1016/j.ceramint.2019.02.045 . .
5
2
2

Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation

Bogdanović, Una; Dimitrijević, Suzana; Škapin, Srečo Davor; Popović, Maja; Rakočević, Zlatko Lj.; Leskovac, Andreja; Petrović, Sandra; Stoiljković, Milovan; Vodnik, Vesna

(Elsevier, Amsterdam, 2018)

TY  - JOUR
AU  - Bogdanović, Una
AU  - Dimitrijević, Suzana
AU  - Škapin, Srečo Davor
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Leskovac, Andreja
AU  - Petrović, Sandra
AU  - Stoiljković, Milovan
AU  - Vodnik, Vesna
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3928
AB  - Copper nanoparticles (Cu NPs) have proven to own excellent antimicrobial efficacy, but the problems of easy oxidation and aggregation limit their practical application. Here, nanocomposite based on polyaniline (PANI) and Cu NPs solved this problem and brought additional physicochemical properties that are markedly advantageous for antimicrobial applications. Current work exploits this potential, to examine its time- and concentration-dependent antimicrobial activity, employing E. coli, S. aureus, and C. albicans as a model microbial species. Regarding the presence of polaronic charge carriers in the fibrous polyaniline network, effects of Cu NPs size and their partially oxidized surfaces (the data were confirmed by HRTEM, FESEM, XRD, Raman and XPS analysis), as well as rapid copper ions release, Cu-PANI nanocomposite showed efficient bactericidal and fungicidal activities at the concentrations  lt = 1 ppm, within the incubation time of 2 h. Beside the quantitative analysis, the high levels of cellular disruption for all tested microbes were evidenced by atomic force microscopy. Moreover, the minimum inhibitory and bactericidal concentrations of the Cu-PANI nanocomposite were lower than those reported for other nanocomposites. Using such low concentrations is recognized as a good way to avoid its toxicity toward the environment. For this purpose, Cu-PANI nanocomposite is tested for its genotoxicity and influence on the oxidative status of the human cells in vitro.
PB  - Elsevier, Amsterdam
T2  - Materials Science & Engineering C-Materials for Biological Applications
T1  - Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation
EP  - 60
SP  - 49
VL  - 93
DO  - 10.1016/j.msec.2018.07.067
ER  - 
@article{
author = "Bogdanović, Una and Dimitrijević, Suzana and Škapin, Srečo Davor and Popović, Maja and Rakočević, Zlatko Lj. and Leskovac, Andreja and Petrović, Sandra and Stoiljković, Milovan and Vodnik, Vesna",
year = "2018",
abstract = "Copper nanoparticles (Cu NPs) have proven to own excellent antimicrobial efficacy, but the problems of easy oxidation and aggregation limit their practical application. Here, nanocomposite based on polyaniline (PANI) and Cu NPs solved this problem and brought additional physicochemical properties that are markedly advantageous for antimicrobial applications. Current work exploits this potential, to examine its time- and concentration-dependent antimicrobial activity, employing E. coli, S. aureus, and C. albicans as a model microbial species. Regarding the presence of polaronic charge carriers in the fibrous polyaniline network, effects of Cu NPs size and their partially oxidized surfaces (the data were confirmed by HRTEM, FESEM, XRD, Raman and XPS analysis), as well as rapid copper ions release, Cu-PANI nanocomposite showed efficient bactericidal and fungicidal activities at the concentrations  lt = 1 ppm, within the incubation time of 2 h. Beside the quantitative analysis, the high levels of cellular disruption for all tested microbes were evidenced by atomic force microscopy. Moreover, the minimum inhibitory and bactericidal concentrations of the Cu-PANI nanocomposite were lower than those reported for other nanocomposites. Using such low concentrations is recognized as a good way to avoid its toxicity toward the environment. For this purpose, Cu-PANI nanocomposite is tested for its genotoxicity and influence on the oxidative status of the human cells in vitro.",
publisher = "Elsevier, Amsterdam",
journal = "Materials Science & Engineering C-Materials for Biological Applications",
title = "Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation",
pages = "60-49",
volume = "93",
doi = "10.1016/j.msec.2018.07.067"
}
Bogdanović, U., Dimitrijević, S., Škapin, S. D., Popović, M., Rakočević, Z. Lj., Leskovac, A., Petrović, S., Stoiljković, M.,& Vodnik, V.. (2018). Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation. in Materials Science & Engineering C-Materials for Biological Applications
Elsevier, Amsterdam., 93, 49-60.
https://doi.org/10.1016/j.msec.2018.07.067
Bogdanović U, Dimitrijević S, Škapin SD, Popović M, Rakočević ZL, Leskovac A, Petrović S, Stoiljković M, Vodnik V. Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation. in Materials Science & Engineering C-Materials for Biological Applications. 2018;93:49-60.
doi:10.1016/j.msec.2018.07.067 .
Bogdanović, Una, Dimitrijević, Suzana, Škapin, Srečo Davor, Popović, Maja, Rakočević, Zlatko Lj., Leskovac, Andreja, Petrović, Sandra, Stoiljković, Milovan, Vodnik, Vesna, "Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation" in Materials Science & Engineering C-Materials for Biological Applications, 93 (2018):49-60,
https://doi.org/10.1016/j.msec.2018.07.067 . .
25
14
24

Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel

Spasojević, Jelena P.; Radosavljević, Aleksandra; Krstić, Jelena I.; Mitrić, Miodrag; Popović, Maja; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina; Kačarević-Popović, Zorica M.

(Wiley, Hoboken, 2017)

TY  - JOUR
AU  - Spasojević, Jelena P.
AU  - Radosavljević, Aleksandra
AU  - Krstić, Jelena I.
AU  - Mitrić, Miodrag
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
AU  - Kačarević-Popović, Zorica M.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3718
AB  - To produce well-defined metal clusters stabilized in protective matrix, poly(N-isopropylacrylamide) (PNi-PAAm) hydrogel with different initial concentration of polymer was used as nanoreactor. The in situ synthesis of well dispersed silver nanoparticles (AgNPs) was performed by gamma irradiation. The obtained AgNPs are spherical in shape with the diameter less than 20 nm. Crystalline properties of nanoparticles such as size, texture coefficient, strain, stress, lattice parameter, d-spacing, and dislocation density have been calculated using XRD data. Results confirm that the changes of lattice parameter of crystalline AgNPs sensitively reflect their state of strain and stress depending on the formation conditions (i.e., on the concentration of PNiPAAm) and on the diameter of AgNPs. The negative lattice strain and compression stress were observed for the smaller AgNPs (lattice contraction), while for the larger AgNPs are positively strained and under tensile stress (lattice expansion). XPS spectra revealed the donor-acceptor type of interaction between carbonyl oxygen from PNiPAAm and AgNPs (positive shift of high BE component of O 1s and negative shift of Ag 3d BE). The greater dislocation density of smaller AgNPs incorporated in more concentrated PNiPAAm, resulted in more binding sites and stronger interaction with polymer.
PB  - Wiley, Hoboken
T2  - Polymer Composites
T1  - Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel
EP  - 1026
IS  - 5
SP  - 1014
VL  - 38
DO  - 10.1002/pc.23665
ER  - 
@article{
author = "Spasojević, Jelena P. and Radosavljević, Aleksandra and Krstić, Jelena I. and Mitrić, Miodrag and Popović, Maja and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina and Kačarević-Popović, Zorica M.",
year = "2017",
abstract = "To produce well-defined metal clusters stabilized in protective matrix, poly(N-isopropylacrylamide) (PNi-PAAm) hydrogel with different initial concentration of polymer was used as nanoreactor. The in situ synthesis of well dispersed silver nanoparticles (AgNPs) was performed by gamma irradiation. The obtained AgNPs are spherical in shape with the diameter less than 20 nm. Crystalline properties of nanoparticles such as size, texture coefficient, strain, stress, lattice parameter, d-spacing, and dislocation density have been calculated using XRD data. Results confirm that the changes of lattice parameter of crystalline AgNPs sensitively reflect their state of strain and stress depending on the formation conditions (i.e., on the concentration of PNiPAAm) and on the diameter of AgNPs. The negative lattice strain and compression stress were observed for the smaller AgNPs (lattice contraction), while for the larger AgNPs are positively strained and under tensile stress (lattice expansion). XPS spectra revealed the donor-acceptor type of interaction between carbonyl oxygen from PNiPAAm and AgNPs (positive shift of high BE component of O 1s and negative shift of Ag 3d BE). The greater dislocation density of smaller AgNPs incorporated in more concentrated PNiPAAm, resulted in more binding sites and stronger interaction with polymer.",
publisher = "Wiley, Hoboken",
journal = "Polymer Composites",
title = "Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel",
pages = "1026-1014",
number = "5",
volume = "38",
doi = "10.1002/pc.23665"
}
Spasojević, J. P., Radosavljević, A., Krstić, J. I., Mitrić, M., Popović, M., Rakočević, Z. Lj., Kalagasidis Krušić, M.,& Kačarević-Popović, Z. M.. (2017). Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel. in Polymer Composites
Wiley, Hoboken., 38(5), 1014-1026.
https://doi.org/10.1002/pc.23665
Spasojević JP, Radosavljević A, Krstić JI, Mitrić M, Popović M, Rakočević ZL, Kalagasidis Krušić M, Kačarević-Popović ZM. Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel. in Polymer Composites. 2017;38(5):1014-1026.
doi:10.1002/pc.23665 .
Spasojević, Jelena P., Radosavljević, Aleksandra, Krstić, Jelena I., Mitrić, Miodrag, Popović, Maja, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, Kačarević-Popović, Zorica M., "Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel" in Polymer Composites, 38, no. 5 (2017):1014-1026,
https://doi.org/10.1002/pc.23665 . .
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Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique

Potočnik, Jelena; Nenadović, Miloš; Jokić, Bojan M.; Popović, Maja; Rakočević, Zlatko Lj.

(2017)

TY  - JOUR
AU  - Potočnik, Jelena
AU  - Nenadović, Miloš
AU  - Jokić, Bojan M.
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5853
AB  - In this work, Glancing Angle Deposition technique was used for obtaining nanostructured nickel thin film with vertical posts on glass substrate which was positioned 75 degrees with respect to the substrate normal and rotated with a suitable constant speed. The obtained nickel thin film was characterized by Scanning Electron Microscopy, Atomic Force Microscopy and X-ray Photoelectron Spectroscopy. It was found that the deposited thin film consists of 94.0 at.% of nickel. Magnetic properties of the deposited thin film were determined by Magneto-Optical Kerr Effect Microscopy. According to the obtained coercivity values, it can be concluded that the nickel thin film shows uniaxial magnetic anisotropy.
T2  - Science of Sintering
T1  - Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique
EP  - 79
IS  - 1
SP  - 73
VL  - 49
DO  - 10.2298/SOS1701073P
ER  - 
@article{
author = "Potočnik, Jelena and Nenadović, Miloš and Jokić, Bojan M. and Popović, Maja and Rakočević, Zlatko Lj.",
year = "2017",
abstract = "In this work, Glancing Angle Deposition technique was used for obtaining nanostructured nickel thin film with vertical posts on glass substrate which was positioned 75 degrees with respect to the substrate normal and rotated with a suitable constant speed. The obtained nickel thin film was characterized by Scanning Electron Microscopy, Atomic Force Microscopy and X-ray Photoelectron Spectroscopy. It was found that the deposited thin film consists of 94.0 at.% of nickel. Magnetic properties of the deposited thin film were determined by Magneto-Optical Kerr Effect Microscopy. According to the obtained coercivity values, it can be concluded that the nickel thin film shows uniaxial magnetic anisotropy.",
journal = "Science of Sintering",
title = "Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique",
pages = "79-73",
number = "1",
volume = "49",
doi = "10.2298/SOS1701073P"
}
Potočnik, J., Nenadović, M., Jokić, B. M., Popović, M.,& Rakočević, Z. Lj.. (2017). Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique. in Science of Sintering, 49(1), 73-79.
https://doi.org/10.2298/SOS1701073P
Potočnik J, Nenadović M, Jokić BM, Popović M, Rakočević ZL. Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique. in Science of Sintering. 2017;49(1):73-79.
doi:10.2298/SOS1701073P .
Potočnik, Jelena, Nenadović, Miloš, Jokić, Bojan M., Popović, Maja, Rakočević, Zlatko Lj., "Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique" in Science of Sintering, 49, no. 1 (2017):73-79,
https://doi.org/10.2298/SOS1701073P . .
1
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Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode

Kalijadis, Ana; Đorđević, Jelena S.; Trtić-Petrović, Tatjana M.; Vukčević, Marija; Popović, Maja; Maksimović, Vesna; Rakočević, Zlatko Lj.; Laušević, Zoran

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - JOUR
AU  - Kalijadis, Ana
AU  - Đorđević, Jelena S.
AU  - Trtić-Petrović, Tatjana M.
AU  - Vukčević, Marija
AU  - Popović, Maja
AU  - Maksimović, Vesna
AU  - Rakočević, Zlatko Lj.
AU  - Laušević, Zoran
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3074
AB  - Boron doped hydrothermal carbon microspheres were synthesized by introducing boric acid into glucose precursor solution to obtain boron concentration from 0.1 to 1 wt. %. Following hydrothermal treatment, samples were thermally treated to 1000 degrees C. For obtained samples structural and surface characterization were performed. Characterization of obtained samples as material for carbon paste electrode was achieved by measurement of the Fe (CN)(6)(3-/4-) redox couple and linuron determination. Catalytic effect of boric acid on hydrothermal reaction induced enlargement of particle size for boron doped samples. Significant reduction of specific surface area for samples with highest boron concentration was observed. Boron was substitutionally incorporated in the structure of doped samples and incorporation up to 0.6 wt. % in precursor solution generates structure ordering, which induces a reduction of surface active sites for oxygen adsorption in a greater extent. It was found that modified structural and surface characteristics are responsible for good electron transfer property of carbon paste electrode based on doped samples with nominal boron concentration range from 0.2 to 0.6 wt. %. However, it has been shown that sample with nominal boron concentration of 0.2 wt. % proved to be most promising candidate as a material for carbon paste electrode.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Carbon
T1  - Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode
EP  - 50
SP  - 42
VL  - 95
DO  - 10.1016/j.carbon.2015.08.016
ER  - 
@article{
author = "Kalijadis, Ana and Đorđević, Jelena S. and Trtić-Petrović, Tatjana M. and Vukčević, Marija and Popović, Maja and Maksimović, Vesna and Rakočević, Zlatko Lj. and Laušević, Zoran",
year = "2015",
abstract = "Boron doped hydrothermal carbon microspheres were synthesized by introducing boric acid into glucose precursor solution to obtain boron concentration from 0.1 to 1 wt. %. Following hydrothermal treatment, samples were thermally treated to 1000 degrees C. For obtained samples structural and surface characterization were performed. Characterization of obtained samples as material for carbon paste electrode was achieved by measurement of the Fe (CN)(6)(3-/4-) redox couple and linuron determination. Catalytic effect of boric acid on hydrothermal reaction induced enlargement of particle size for boron doped samples. Significant reduction of specific surface area for samples with highest boron concentration was observed. Boron was substitutionally incorporated in the structure of doped samples and incorporation up to 0.6 wt. % in precursor solution generates structure ordering, which induces a reduction of surface active sites for oxygen adsorption in a greater extent. It was found that modified structural and surface characteristics are responsible for good electron transfer property of carbon paste electrode based on doped samples with nominal boron concentration range from 0.2 to 0.6 wt. %. However, it has been shown that sample with nominal boron concentration of 0.2 wt. % proved to be most promising candidate as a material for carbon paste electrode.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Carbon",
title = "Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode",
pages = "50-42",
volume = "95",
doi = "10.1016/j.carbon.2015.08.016"
}
Kalijadis, A., Đorđević, J. S., Trtić-Petrović, T. M., Vukčević, M., Popović, M., Maksimović, V., Rakočević, Z. Lj.,& Laušević, Z.. (2015). Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode. in Carbon
Pergamon-Elsevier Science Ltd, Oxford., 95, 42-50.
https://doi.org/10.1016/j.carbon.2015.08.016
Kalijadis A, Đorđević JS, Trtić-Petrović TM, Vukčević M, Popović M, Maksimović V, Rakočević ZL, Laušević Z. Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode. in Carbon. 2015;95:42-50.
doi:10.1016/j.carbon.2015.08.016 .
Kalijadis, Ana, Đorđević, Jelena S., Trtić-Petrović, Tatjana M., Vukčević, Marija, Popović, Maja, Maksimović, Vesna, Rakočević, Zlatko Lj., Laušević, Zoran, "Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode" in Carbon, 95 (2015):42-50,
https://doi.org/10.1016/j.carbon.2015.08.016 . .
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The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles

Jokić, Bojan; Mitrić, Miodrag; Popović, Maja; Sima, L.; Petrescu, S. M.; Petrović, Rada; Janaćković, Đorđe

(Springer, Dordrecht, 2011)

TY  - JOUR
AU  - Jokić, Bojan
AU  - Mitrić, Miodrag
AU  - Popović, Maja
AU  - Sima, L.
AU  - Petrescu, S. M.
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1863
AB  - In this work, the influence of the morphology of hydroxyapatite particles on silicon substitution through hydrothermal synthesis performed under the same conditions was investigated. Spherical- and whisker-like hydroxyapatite particles were obtained starting from calcium-nitrate, sodium dihydrogen phosphate, disodium-ethylenediaminetetraacetic acid and urea (used only for the synthesis of whisker-like particles) dissolved in aqueous solutions. Silicon was introduced into the solution using tetraethylorthosilicate. X-ray diffraction, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and transmission electron microscopy indicate that silicon doping induce different phase compositions and bioactivity of spherical- and whisker-like hydroxyapatite particles obtained under the same hydrothermal conditions. Silicon-substituted, spherical hydroxyapatites particles showed greater phase transformation to silicon-substituted alpha- calcium-phosphate compared with whiskers-like hydroxyapatite particles synthesized with the same amount of added silicon. Metabolic activity assay performed with SaOs2 osteosarcoma cells showed better biocompatibility of annealed biphasic spherical-like particles compared with annealed whiskerlike particles while dried spherical-like particles induce high cytotoxicity effect.
PB  - Springer, Dordrecht
T2  - Journal of Materials Science-Materials in Medicine
T1  - The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles
EP  - 2185
IS  - 10
SP  - 2175
VL  - 22
DO  - 10.1007/s10856-011-4412-6
ER  - 
@article{
author = "Jokić, Bojan and Mitrić, Miodrag and Popović, Maja and Sima, L. and Petrescu, S. M. and Petrović, Rada and Janaćković, Đorđe",
year = "2011",
abstract = "In this work, the influence of the morphology of hydroxyapatite particles on silicon substitution through hydrothermal synthesis performed under the same conditions was investigated. Spherical- and whisker-like hydroxyapatite particles were obtained starting from calcium-nitrate, sodium dihydrogen phosphate, disodium-ethylenediaminetetraacetic acid and urea (used only for the synthesis of whisker-like particles) dissolved in aqueous solutions. Silicon was introduced into the solution using tetraethylorthosilicate. X-ray diffraction, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and transmission electron microscopy indicate that silicon doping induce different phase compositions and bioactivity of spherical- and whisker-like hydroxyapatite particles obtained under the same hydrothermal conditions. Silicon-substituted, spherical hydroxyapatites particles showed greater phase transformation to silicon-substituted alpha- calcium-phosphate compared with whiskers-like hydroxyapatite particles synthesized with the same amount of added silicon. Metabolic activity assay performed with SaOs2 osteosarcoma cells showed better biocompatibility of annealed biphasic spherical-like particles compared with annealed whiskerlike particles while dried spherical-like particles induce high cytotoxicity effect.",
publisher = "Springer, Dordrecht",
journal = "Journal of Materials Science-Materials in Medicine",
title = "The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles",
pages = "2185-2175",
number = "10",
volume = "22",
doi = "10.1007/s10856-011-4412-6"
}
Jokić, B., Mitrić, M., Popović, M., Sima, L., Petrescu, S. M., Petrović, R.,& Janaćković, Đ.. (2011). The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles. in Journal of Materials Science-Materials in Medicine
Springer, Dordrecht., 22(10), 2175-2185.
https://doi.org/10.1007/s10856-011-4412-6
Jokić B, Mitrić M, Popović M, Sima L, Petrescu SM, Petrović R, Janaćković Đ. The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles. in Journal of Materials Science-Materials in Medicine. 2011;22(10):2175-2185.
doi:10.1007/s10856-011-4412-6 .
Jokić, Bojan, Mitrić, Miodrag, Popović, Maja, Sima, L., Petrescu, S. M., Petrović, Rada, Janaćković, Đorđe, "The influence of silicon substitution on the properties of spherical- and whisker-like biphasic alpha-calcium-phosphate/hydroxyapatite particles" in Journal of Materials Science-Materials in Medicine, 22, no. 10 (2011):2175-2185,
https://doi.org/10.1007/s10856-011-4412-6 . .
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