Jegdić, Bore

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Authority KeyName Variants
orcid::0000-0002-3287-3653
  • Jegdić, Bore (33)
Projects
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Investigation and Optimization of the Technological and Functional Performance of the Ventilation Mill in the Thermal Power Plant Kostolac B Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy)
Development of the tribological micro/nano two component and hybrid selflubricating composites Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
The effect of nano- and microconstituents on the synthesis and characteristics of novel composite materials with metal matrix Basic Science Research Program of the Ministry of Education, Science and Technology of Korea [2018R1A2B5A02023190]
Elektrohemijske karakteristike oksidnih i polimernih prevlaka na modifikovanim površinama metala Osvajanje novih tehnologija reparaturnog zavarivanja za interventne remonte termoenergetskih postrojenja
Istraživanje mogućnosti optimizacije rada i revitalizacije habajućih delova ventilacionog mlina termoelektrane Drmno - Kostolac The development of casting technologies under the influence of electromagnetic field and technologies of hot plastic forming of 7000 series aluminium alloys for special purposes
Development of covering and core production technology based on local raw materials for manufacturing of special coated electrodes designed for steel arc welding Design of processing and welding of the high strength Al-Mg alloys for road and railway trasportation applications
Ministry of Education, Science and Technological Development, Republic of Serbia Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]

Author's Bibliography

Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution

Marković, Snežana; Radojković, Bojana; Jegdić, Bore; Jovanović, Aleksandar; Stojanović, Jovica; Trumić, Milan; Manojlović, Vaso

(Inženjersko društvo za koroziju, 2024)

TY  - JOUR
AU  - Marković, Snežana
AU  - Radojković, Bojana
AU  - Jegdić, Bore
AU  - Jovanović, Aleksandar
AU  - Stojanović, Jovica
AU  - Trumić, Milan
AU  - Manojlović, Vaso
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7408
AB  - The corrosion behaviour of three types of alloys (two low-alloy carbon steel and one stainless iron with ~15 wt.% Cr), in a solution which simulates seawater (3% NaCl solution, pH 8.1) was tested. Tested samples are used to make steel (iron) balls applied in mils for grinding copper and other ore. The corrosion tests were performed using three electrochemical methods, at room temperature in the presence of atmospheric oxygen. The linear polarization resistance (LPR) method, electrochemical impedance spectroscopy (EIS) method, and linear sweep voltammetry (LSV) method were applied. Based on measurements by LPR and EIS methods (as non-destructive methods), the value of polarization resistance (Rp) was determined and the general corrosion rate (vcorr) of the examined samples was calculated. The obtained values of the general corrosion rate can be used to calculate the service life of steel (iron) balls under exploitation conditions (seawater). The appearance of the surface after linear sweep voltammetry (LSV) measurement showed the presence of localized corrosion (pits were formed) of the tested samples, especially stainless iron, and the LSV method is not suitable for the determination of the general corrosion rate of tested samples in seawater. This form of corrosion occurs at high anodic polarizations, during performing LSV measurements.
AB  - Ispitivano  je  koroziono  ponašanje  tri  vrste legura(dva  nisko-legirana  ugljenična  čelika  i  jedanuzorakje nerđajuće gvožđe sa ~15% Cr), u rastvoru koji simulira morsku vodu (3% rastvor NaCl, pH 8,1). Ispitani uzorcise koriste za proizvodnju čeličnih kugli koje se primenjuju u mlinovima za mlevenje  bakarnih  i  drugih  ruda. Koroziona  ispitivanja  su  izvedena  primenom  tri  elektrohemijske metode, na sobnoj temperaturi u prisustvu atmosferskog kiseonika. Korišćene su metoda linearne polarizacione   otpornosti   (LPR),   metoda   elektrohemijske   impedansne   spektroskopije   (EIS)   i metoda  linearne  promene  potencijala  (LSV).  Na  osnovu  merenja  LPR  i  EIS  metodama  (kao nerazarajućim  metodama),  određena  je  vrednost  polarizacione  otpornosti  (Rp),   a   zatim   je izračunata vrednost brzine opšte korozije (vkor)  ispitivanih uzoraka.  Dobijene  vrednosti  za  brzinu opšte  korozije  se  mogu  koristiti  za  izračunavanje  veka  trajanja  kugli  u  uslovima  eksploatacije (morska  voda).  Izgled  površine  ispitivanih uzorakanakon  izvođenja  LSV  metode  pokazao  je prisustvo  lokalizovane  korozije  (formirane  su  jamice,  pitovi)  na  ispitivanim uzorcima,  posebno  na nerđajućem gvožđu. Prema tome, LSV metoda nije pogodna za određivanje brzine opšte korozije ispitivanih čelika u morskoj vodi. Ovaj oblik korozije javlja se pri visokim anodnim polarizacijama tokom izvođenja LSV merenja.
PB  - Inženjersko društvo za koroziju
T2  - Zaštita materijala
T1  - Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution
T1  - Koroziono ponašanje čeličnih kuglica za mlevenje sa visokim i niskim sadržajem hroma u rastvoru hlorida
EP  - 53
IS  - 1
SP  - 45
VL  - 65
DO  - 10.62638/zasmat998
ER  - 
@article{
author = "Marković, Snežana and Radojković, Bojana and Jegdić, Bore and Jovanović, Aleksandar and Stojanović, Jovica and Trumić, Milan and Manojlović, Vaso",
year = "2024",
abstract = "The corrosion behaviour of three types of alloys (two low-alloy carbon steel and one stainless iron with ~15 wt.% Cr), in a solution which simulates seawater (3% NaCl solution, pH 8.1) was tested. Tested samples are used to make steel (iron) balls applied in mils for grinding copper and other ore. The corrosion tests were performed using three electrochemical methods, at room temperature in the presence of atmospheric oxygen. The linear polarization resistance (LPR) method, electrochemical impedance spectroscopy (EIS) method, and linear sweep voltammetry (LSV) method were applied. Based on measurements by LPR and EIS methods (as non-destructive methods), the value of polarization resistance (Rp) was determined and the general corrosion rate (vcorr) of the examined samples was calculated. The obtained values of the general corrosion rate can be used to calculate the service life of steel (iron) balls under exploitation conditions (seawater). The appearance of the surface after linear sweep voltammetry (LSV) measurement showed the presence of localized corrosion (pits were formed) of the tested samples, especially stainless iron, and the LSV method is not suitable for the determination of the general corrosion rate of tested samples in seawater. This form of corrosion occurs at high anodic polarizations, during performing LSV measurements., Ispitivano  je  koroziono  ponašanje  tri  vrste legura(dva  nisko-legirana  ugljenična  čelika  i  jedanuzorakje nerđajuće gvožđe sa ~15% Cr), u rastvoru koji simulira morsku vodu (3% rastvor NaCl, pH 8,1). Ispitani uzorcise koriste za proizvodnju čeličnih kugli koje se primenjuju u mlinovima za mlevenje  bakarnih  i  drugih  ruda. Koroziona  ispitivanja  su  izvedena  primenom  tri  elektrohemijske metode, na sobnoj temperaturi u prisustvu atmosferskog kiseonika. Korišćene su metoda linearne polarizacione   otpornosti   (LPR),   metoda   elektrohemijske   impedansne   spektroskopije   (EIS)   i metoda  linearne  promene  potencijala  (LSV).  Na  osnovu  merenja  LPR  i  EIS  metodama  (kao nerazarajućim  metodama),  određena  je  vrednost  polarizacione  otpornosti  (Rp),   a   zatim   je izračunata vrednost brzine opšte korozije (vkor)  ispitivanih uzoraka.  Dobijene  vrednosti  za  brzinu opšte  korozije  se  mogu  koristiti  za  izračunavanje  veka  trajanja  kugli  u  uslovima  eksploatacije (morska  voda).  Izgled  površine  ispitivanih uzorakanakon  izvođenja  LSV  metode  pokazao  je prisustvo  lokalizovane  korozije  (formirane  su  jamice,  pitovi)  na  ispitivanim uzorcima,  posebno  na nerđajućem gvožđu. Prema tome, LSV metoda nije pogodna za određivanje brzine opšte korozije ispitivanih čelika u morskoj vodi. Ovaj oblik korozije javlja se pri visokim anodnim polarizacijama tokom izvođenja LSV merenja.",
publisher = "Inženjersko društvo za koroziju",
journal = "Zaštita materijala",
title = "Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution, Koroziono ponašanje čeličnih kuglica za mlevenje sa visokim i niskim sadržajem hroma u rastvoru hlorida",
pages = "53-45",
number = "1",
volume = "65",
doi = "10.62638/zasmat998"
}
Marković, S., Radojković, B., Jegdić, B., Jovanović, A., Stojanović, J., Trumić, M.,& Manojlović, V.. (2024). Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution. in Zaštita materijala
Inženjersko društvo za koroziju., 65(1), 45-53.
https://doi.org/10.62638/zasmat998
Marković S, Radojković B, Jegdić B, Jovanović A, Stojanović J, Trumić M, Manojlović V. Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution. in Zaštita materijala. 2024;65(1):45-53.
doi:10.62638/zasmat998 .
Marković, Snežana, Radojković, Bojana, Jegdić, Bore, Jovanović, Aleksandar, Stojanović, Jovica, Trumić, Milan, Manojlović, Vaso, "Corrosion behavior of high- and low-chromium steel grinding balls in chloride solution" in Zaštita materijala, 65, no. 1 (2024):45-53,
https://doi.org/10.62638/zasmat998 . .

Corrosion of metal parts in the power plant

Radojković, Bojana; Pejić, Jovanka; Marunkić, Dunja; Simović, Anđela; Eraković Pantović, Sanja; Jegdić, Bore; Bajat, Jelena

(John Wiley and Sons Inc., 2023)

TY  - JOUR
AU  - Radojković, Bojana
AU  - Pejić, Jovanka
AU  - Marunkić, Dunja
AU  - Simović, Anđela
AU  - Eraković Pantović, Sanja
AU  - Jegdić, Bore
AU  - Bajat, Jelena
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6474
AB  - The AISI 304 (X5CrNi19-10) stainless steel is widely used for the production of various metal parts in power plants. A procedure for testing the influence of the dust from a power plant on resistance to general and pitting corrosion of the AISI 304 stainless steel is developed and performed. The quantitative (XRD method) and qualitative (Fourier–transform infrared spectroscopy [FTIR] method) composition of the dust present in the power plant is determined. Applying the Mott–Schottky method, the properties of the passive layer are analyzed, while a degree of chromium depletion of the grain boundary is determined by the electrochemical potentiokinetic reactivation method with double loop method. Values of polarization resistance (linear polarization resistance and electrochemical impedance spectroscopy methods) and the corrosion current density (polarization measurements) indicate that the stainless steel has a higher resistance to general corrosion in the dust solutions than in the etalon solution. Also, based on the measured value of the pitting potential (Epit) and the difference between the values of the pitting potential and the corrosion potential (Epit – Ecorr), it can be seen that stainless steel has a higher resistance to localized types of corrosion, such as pitting corrosion, in dust solutions than in the etalon solution.
PB  - John Wiley and Sons Inc.
T2  - Materials and Corrosion
T1  - Corrosion of metal parts in the power plant
DO  - 10.1002/maco.202313919
ER  - 
@article{
author = "Radojković, Bojana and Pejić, Jovanka and Marunkić, Dunja and Simović, Anđela and Eraković Pantović, Sanja and Jegdić, Bore and Bajat, Jelena",
year = "2023",
abstract = "The AISI 304 (X5CrNi19-10) stainless steel is widely used for the production of various metal parts in power plants. A procedure for testing the influence of the dust from a power plant on resistance to general and pitting corrosion of the AISI 304 stainless steel is developed and performed. The quantitative (XRD method) and qualitative (Fourier–transform infrared spectroscopy [FTIR] method) composition of the dust present in the power plant is determined. Applying the Mott–Schottky method, the properties of the passive layer are analyzed, while a degree of chromium depletion of the grain boundary is determined by the electrochemical potentiokinetic reactivation method with double loop method. Values of polarization resistance (linear polarization resistance and electrochemical impedance spectroscopy methods) and the corrosion current density (polarization measurements) indicate that the stainless steel has a higher resistance to general corrosion in the dust solutions than in the etalon solution. Also, based on the measured value of the pitting potential (Epit) and the difference between the values of the pitting potential and the corrosion potential (Epit – Ecorr), it can be seen that stainless steel has a higher resistance to localized types of corrosion, such as pitting corrosion, in dust solutions than in the etalon solution.",
publisher = "John Wiley and Sons Inc.",
journal = "Materials and Corrosion",
title = "Corrosion of metal parts in the power plant",
doi = "10.1002/maco.202313919"
}
Radojković, B., Pejić, J., Marunkić, D., Simović, A., Eraković Pantović, S., Jegdić, B.,& Bajat, J.. (2023). Corrosion of metal parts in the power plant. in Materials and Corrosion
John Wiley and Sons Inc...
https://doi.org/10.1002/maco.202313919
Radojković B, Pejić J, Marunkić D, Simović A, Eraković Pantović S, Jegdić B, Bajat J. Corrosion of metal parts in the power plant. in Materials and Corrosion. 2023;.
doi:10.1002/maco.202313919 .
Radojković, Bojana, Pejić, Jovanka, Marunkić, Dunja, Simović, Anđela, Eraković Pantović, Sanja, Jegdić, Bore, Bajat, Jelena, "Corrosion of metal parts in the power plant" in Materials and Corrosion (2023),
https://doi.org/10.1002/maco.202313919 . .
1

Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023. https://doi.org/10.1002/maco.202313919

Radojković, Bojana; Pejić, Jovanka; Marunkić, Dunja; Simović, Anđela; Eraković Pantović, Sanja; Jegdić, Bore; Bajat, Jelena

(John Wiley and Sons Inc., 2023)

TY  - DATA
AU  - Radojković, Bojana
AU  - Pejić, Jovanka
AU  - Marunkić, Dunja
AU  - Simović, Anđela
AU  - Eraković Pantović, Sanja
AU  - Jegdić, Bore
AU  - Bajat, Jelena
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6475
AB  - The AISI 304 (X5CrNi19-10) stainless steel is widely used for the production of various metal parts in power plants. A procedure for testing the influence of the dust from a power plant on resistance to general and pitting corrosion of the AISI 304 stainless steel is developed and performed. The quantitative (XRD method) and qualitative (Fourier–transform infrared spectroscopy [FTIR] method) composition of the dust present in the power plant is determined. Applying the Mott–Schottky method, the properties of the passive layer are analyzed, while a degree of chromium depletion of the grain boundary is determined by the electrochemical potentiokinetic reactivation method with double loop method. Values of polarization resistance (linear polarization resistance and electrochemical impedance spectroscopy methods) and the corrosion current density (polarization measurements) indicate that the stainless steel has a higher resistance to general corrosion in the dust solutions than in the etalon solution. Also, based on the measured value of the pitting potential (Epit) and the difference between the values of the pitting potential and the corrosion potential (Epit – Ecorr), it can be seen that stainless steel has a higher resistance to localized types of corrosion, such as pitting corrosion, in dust solutions than in the etalon solution.
PB  - John Wiley and Sons Inc.
T2  - Materials and Corrosion
T1  - Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023.  https://doi.org/10.1002/maco.202313919
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6475
ER  - 
@misc{
author = "Radojković, Bojana and Pejić, Jovanka and Marunkić, Dunja and Simović, Anđela and Eraković Pantović, Sanja and Jegdić, Bore and Bajat, Jelena",
year = "2023",
abstract = "The AISI 304 (X5CrNi19-10) stainless steel is widely used for the production of various metal parts in power plants. A procedure for testing the influence of the dust from a power plant on resistance to general and pitting corrosion of the AISI 304 stainless steel is developed and performed. The quantitative (XRD method) and qualitative (Fourier–transform infrared spectroscopy [FTIR] method) composition of the dust present in the power plant is determined. Applying the Mott–Schottky method, the properties of the passive layer are analyzed, while a degree of chromium depletion of the grain boundary is determined by the electrochemical potentiokinetic reactivation method with double loop method. Values of polarization resistance (linear polarization resistance and electrochemical impedance spectroscopy methods) and the corrosion current density (polarization measurements) indicate that the stainless steel has a higher resistance to general corrosion in the dust solutions than in the etalon solution. Also, based on the measured value of the pitting potential (Epit) and the difference between the values of the pitting potential and the corrosion potential (Epit – Ecorr), it can be seen that stainless steel has a higher resistance to localized types of corrosion, such as pitting corrosion, in dust solutions than in the etalon solution.",
publisher = "John Wiley and Sons Inc.",
journal = "Materials and Corrosion",
title = "Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023.  https://doi.org/10.1002/maco.202313919",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6475"
}
Radojković, B., Pejić, J., Marunkić, D., Simović, A., Eraković Pantović, S., Jegdić, B.,& Bajat, J.. (2023). Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023.  https://doi.org/10.1002/maco.202313919. in Materials and Corrosion
John Wiley and Sons Inc...
https://hdl.handle.net/21.15107/rcub_technorep_6475
Radojković B, Pejić J, Marunkić D, Simović A, Eraković Pantović S, Jegdić B, Bajat J. Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023.  https://doi.org/10.1002/maco.202313919. in Materials and Corrosion. 2023;.
https://hdl.handle.net/21.15107/rcub_technorep_6475 .
Radojković, Bojana, Pejić, Jovanka, Marunkić, Dunja, Simović, Anđela, Eraković Pantović, Sanja, Jegdić, Bore, Bajat, Jelena, "Supplementary material for the article: Radojković, B.; Pejić, J.; Marunkić, D.; Simović, A.; Pantović, S. E.; Jegdić, B.; Bajat, J. Corrosion of Metal Parts in the Power Plant. Materials & Corrosion 2023.  https://doi.org/10.1002/maco.202313919" in Materials and Corrosion (2023),
https://hdl.handle.net/21.15107/rcub_technorep_6475 .

Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution

Pejić, Jovanka; Radojković, Bojana; Marunkić, Dunja; Jegdić, Bore; Stevanović, Sanja; Milošević, Milena; Bajat, Jelena

(John Wiley and Sons Inc, 2022)

TY  - JOUR
AU  - Pejić, Jovanka
AU  - Radojković, Bojana
AU  - Marunkić, Dunja
AU  - Jegdić, Bore
AU  - Stevanović, Sanja
AU  - Milošević, Milena
AU  - Bajat, Jelena
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5171
AB  - The inhibitory effect of cysteine in the presence of selected lanthanide chlorides (LaCl3, NdCl3, and CeCl3) in a neutral 0.1 M NaCl solution was analyzed. The cysteine concentration of 0.3 mM was determined as an optimal one. The resistance to general and pitting corrosion of AA7075-T6 alloy in inhibitive solutions was determined using electrochemical impedance spectroscopy and potentiodynamic polarization measurements. The surface appearance of the aluminum alloy was determined before and after corrosion tests using scanning electron microscopy/energy dispersive spectroscopy, while the presence of an inhibitory layer on the alloy surface was confirmed by X-ray photoelectron spectroscopy analysis and atomic force microscopy. The inhibitory effect of cysteine was significantly higher in the presence of all tested lanthanide chlorides, especially to pitting corrosion. The protective ability of cysteine was increased by lanthanides in the following sequence: Ln < Nd < Ce ions. The inhibitory effect of cysteine in the presence of cerium ions was examined in more detail as cerium ions provided the highest inhibitory effect, both to general and pitting corrosion.
PB  - John Wiley and Sons Inc
T2  - Materials and Corrosion
T1  - Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution
DO  - 10.1002/maco.202213330
ER  - 
@article{
author = "Pejić, Jovanka and Radojković, Bojana and Marunkić, Dunja and Jegdić, Bore and Stevanović, Sanja and Milošević, Milena and Bajat, Jelena",
year = "2022",
abstract = "The inhibitory effect of cysteine in the presence of selected lanthanide chlorides (LaCl3, NdCl3, and CeCl3) in a neutral 0.1 M NaCl solution was analyzed. The cysteine concentration of 0.3 mM was determined as an optimal one. The resistance to general and pitting corrosion of AA7075-T6 alloy in inhibitive solutions was determined using electrochemical impedance spectroscopy and potentiodynamic polarization measurements. The surface appearance of the aluminum alloy was determined before and after corrosion tests using scanning electron microscopy/energy dispersive spectroscopy, while the presence of an inhibitory layer on the alloy surface was confirmed by X-ray photoelectron spectroscopy analysis and atomic force microscopy. The inhibitory effect of cysteine was significantly higher in the presence of all tested lanthanide chlorides, especially to pitting corrosion. The protective ability of cysteine was increased by lanthanides in the following sequence: Ln < Nd < Ce ions. The inhibitory effect of cysteine in the presence of cerium ions was examined in more detail as cerium ions provided the highest inhibitory effect, both to general and pitting corrosion.",
publisher = "John Wiley and Sons Inc",
journal = "Materials and Corrosion",
title = "Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution",
doi = "10.1002/maco.202213330"
}
Pejić, J., Radojković, B., Marunkić, D., Jegdić, B., Stevanović, S., Milošević, M.,& Bajat, J.. (2022). Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution. in Materials and Corrosion
John Wiley and Sons Inc..
https://doi.org/10.1002/maco.202213330
Pejić J, Radojković B, Marunkić D, Jegdić B, Stevanović S, Milošević M, Bajat J. Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution. in Materials and Corrosion. 2022;.
doi:10.1002/maco.202213330 .
Pejić, Jovanka, Radojković, Bojana, Marunkić, Dunja, Jegdić, Bore, Stevanović, Sanja, Milošević, Milena, Bajat, Jelena, "Inhibitory effect of cysteine and lanthanides on AA7075-T6 in neutral NaCl solution" in Materials and Corrosion (2022),
https://doi.org/10.1002/maco.202213330 . .
3
2

Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution

Radojković, Bojana; Marunkić, Dunja; Milošević, Milena; Grubišić, Sonja; Pejić, Jovanka; Jegdić, Bore; Marinković, Aleksandar

(John Wiley and Sons Inc, 2022)

TY  - JOUR
AU  - Radojković, Bojana
AU  - Marunkić, Dunja
AU  - Milošević, Milena
AU  - Grubišić, Sonja
AU  - Pejić, Jovanka
AU  - Jegdić, Bore
AU  - Marinković, Aleksandar
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5134
AB  - Green corrosion inhibitors, Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate, were tested in NaCl solution with the aim to evaluate their inhibitory effect on 7049 aluminum alloy and to propose a mechanism of their inhibitive action. Corrosion properties of the formed inhibitor layer were analyzed using electrochemical impedance spectroscopy, while the pit formation resistance was analyzed using potentiodynamic polarization tests. Morphology of the formed pits was evaluated by scanning electron microscope/energy-dispersive spectroscopy analysis. It was shown that Ce(III) propionate in NaCl solution has a noticeably higher protective ability than Ce(III) chloride and Ce(III) nitrate. The presence of cerium, propionate anions, and Al–O bonds in the inhibitive layer on the 7049 aluminum alloy surface was confirmed by X-ray photoelectron spectroscopy analysis. This indicates the formation of Ce propionate complexes and bonds via oxygen atoms from carboxylate anions with the metal surface. Density-functional theory methods were used for the geometry optimization of possible Ce propionate complexes as corrosion inhibitors.
PB  - John Wiley and Sons Inc
T2  - Materials and Corrosion
T1  - Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution
DO  - 10.1002/maco.202213177
ER  - 
@article{
author = "Radojković, Bojana and Marunkić, Dunja and Milošević, Milena and Grubišić, Sonja and Pejić, Jovanka and Jegdić, Bore and Marinković, Aleksandar",
year = "2022",
abstract = "Green corrosion inhibitors, Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate, were tested in NaCl solution with the aim to evaluate their inhibitory effect on 7049 aluminum alloy and to propose a mechanism of their inhibitive action. Corrosion properties of the formed inhibitor layer were analyzed using electrochemical impedance spectroscopy, while the pit formation resistance was analyzed using potentiodynamic polarization tests. Morphology of the formed pits was evaluated by scanning electron microscope/energy-dispersive spectroscopy analysis. It was shown that Ce(III) propionate in NaCl solution has a noticeably higher protective ability than Ce(III) chloride and Ce(III) nitrate. The presence of cerium, propionate anions, and Al–O bonds in the inhibitive layer on the 7049 aluminum alloy surface was confirmed by X-ray photoelectron spectroscopy analysis. This indicates the formation of Ce propionate complexes and bonds via oxygen atoms from carboxylate anions with the metal surface. Density-functional theory methods were used for the geometry optimization of possible Ce propionate complexes as corrosion inhibitors.",
publisher = "John Wiley and Sons Inc",
journal = "Materials and Corrosion",
title = "Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution",
doi = "10.1002/maco.202213177"
}
Radojković, B., Marunkić, D., Milošević, M., Grubišić, S., Pejić, J., Jegdić, B.,& Marinković, A.. (2022). Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution. in Materials and Corrosion
John Wiley and Sons Inc..
https://doi.org/10.1002/maco.202213177
Radojković B, Marunkić D, Milošević M, Grubišić S, Pejić J, Jegdić B, Marinković A. Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution. in Materials and Corrosion. 2022;.
doi:10.1002/maco.202213177 .
Radojković, Bojana, Marunkić, Dunja, Milošević, Milena, Grubišić, Sonja, Pejić, Jovanka, Jegdić, Bore, Marinković, Aleksandar, "Analysis of the Ce(III) chloride, Ce(III) nitrate, and Ce(III) propionate as corrosion inhibitor of the aluminum alloys in NaCl solution" in Materials and Corrosion (2022),
https://doi.org/10.1002/maco.202213177 . .
5
4

Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution

Marunkić, Dunja; Jegdić, Bore; Pejić, Jovanka; Milošević, Milena; Marinković, Aleksandar; Radojković, Bojana

(John Wiley and Sons Inc, 2022)

TY  - JOUR
AU  - Marunkić, Dunja
AU  - Jegdić, Bore
AU  - Pejić, Jovanka
AU  - Milošević, Milena
AU  - Marinković, Aleksandar
AU  - Radojković, Bojana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5083
AB  - The new environmentally friendly corrosion inhibitor Ce-citrate was analyzed in 0.05 M NaCl solution on the AISI 4130 steel. For comparison, corrosion inhibitor Ce-chloride is tested in the same concentration as Ce-citrate (0.3 mM). Inhibitor efficiencies were determined by applying electrochemical impedance spectroscopy and potentiodynamic polarization measurements. The results of electrochemical measurements, the contact angle measurements, as well as the surface appearance of the specimens after the immersion in the inhibitive NaCl solution for 96 h confirmed that the new environmentally friendly inhibitor (Ce-citrate) has a significantly higher protective ability than the Ce-chloride. The protective ability of Ce-citrate increases over time, according to the proposed mechanism of its action. In the inhibitive layer formed in NaCl solution containing Ce-citrate, XPS analysis revealed the presence of cerium in oxidation states CeIII and CeIV, citrate anions (carboxyl O–C═O group as well as C–OH and C–C and C–H bonds), oxide, hydroxide, and oxyhydroxide of iron (mainly FeOOH and Fe2O3). The mechanism of inhibitory action of Ce-citrate was proposed and analyzed in detail.
PB  - John Wiley and Sons Inc
T2  - Materials and Corrosion
T1  - Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution
DO  - 10.1002/maco.202213079
ER  - 
@article{
author = "Marunkić, Dunja and Jegdić, Bore and Pejić, Jovanka and Milošević, Milena and Marinković, Aleksandar and Radojković, Bojana",
year = "2022",
abstract = "The new environmentally friendly corrosion inhibitor Ce-citrate was analyzed in 0.05 M NaCl solution on the AISI 4130 steel. For comparison, corrosion inhibitor Ce-chloride is tested in the same concentration as Ce-citrate (0.3 mM). Inhibitor efficiencies were determined by applying electrochemical impedance spectroscopy and potentiodynamic polarization measurements. The results of electrochemical measurements, the contact angle measurements, as well as the surface appearance of the specimens after the immersion in the inhibitive NaCl solution for 96 h confirmed that the new environmentally friendly inhibitor (Ce-citrate) has a significantly higher protective ability than the Ce-chloride. The protective ability of Ce-citrate increases over time, according to the proposed mechanism of its action. In the inhibitive layer formed in NaCl solution containing Ce-citrate, XPS analysis revealed the presence of cerium in oxidation states CeIII and CeIV, citrate anions (carboxyl O–C═O group as well as C–OH and C–C and C–H bonds), oxide, hydroxide, and oxyhydroxide of iron (mainly FeOOH and Fe2O3). The mechanism of inhibitory action of Ce-citrate was proposed and analyzed in detail.",
publisher = "John Wiley and Sons Inc",
journal = "Materials and Corrosion",
title = "Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution",
doi = "10.1002/maco.202213079"
}
Marunkić, D., Jegdić, B., Pejić, J., Milošević, M., Marinković, A.,& Radojković, B.. (2022). Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution. in Materials and Corrosion
John Wiley and Sons Inc..
https://doi.org/10.1002/maco.202213079
Marunkić D, Jegdić B, Pejić J, Milošević M, Marinković A, Radojković B. Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution. in Materials and Corrosion. 2022;.
doi:10.1002/maco.202213079 .
Marunkić, Dunja, Jegdić, Bore, Pejić, Jovanka, Milošević, Milena, Marinković, Aleksandar, Radojković, Bojana, "Analysis of inhibitory properties of Ce-citrate as a green corrosion inhibitor of low alloy steel in neutral chloride solution" in Materials and Corrosion (2022),
https://doi.org/10.1002/maco.202213079 . .
5
4

Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint

Radojković, Bojana; Kovačina, Jovanka; Jegdić, Bore; Bobić, Biljana; Alić, Behar; Marunkić, Dunja D.; Simović, Anđela

(Wiley-VCH Verlag Gmbh, Weinheim, 2021)

TY  - JOUR
AU  - Radojković, Bojana
AU  - Kovačina, Jovanka
AU  - Jegdić, Bore
AU  - Bobić, Biljana
AU  - Alić, Behar
AU  - Marunkić, Dunja D.
AU  - Simović, Anđela
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/8
AB  - This study considers the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint in NaCl solution, with and without the presence of several corrosion inhibitors (NaNO3, Ce(NO3)(3), and CeCl3). The degree of sensitization of the welded joint to intergranular corrosion is determined using the electrochemical potentiokinetic reactivation method with a double-loop method. Pitting corrosion tests are performed by the potentiodynamic method. Resistance to general corrosion and the stability of the passive film is assessed based on the results of electrochemical impedance spectroscopy measurements, as well as on the values of the corrosion and passivation current. The main goal of this study is to determine the relation of the welded joint microstructure to general and pitting corrosion in the presence of the corrosion inhibitors. The value of pitting potential for the base metal and weld metal in the presence of the NaNO3 or Ce(NO3)(3) inhibitor is shifted to potentials in the transpassive area. The pitting potential for the heat-affected zone also possesses a noticeable higher value. However, nitrate ions do not increase the general corrosion resistance of any part of the welded joint. CeCl3 does not increase resistance to general or pitting corrosion.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Materials and Corrosion-Werkstoffe Und Korrosion
T1  - Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint
EP  - 707
IS  - 4
SP  - 694
VL  - 72
DO  - 10.1002/maco.202012039
ER  - 
@article{
author = "Radojković, Bojana and Kovačina, Jovanka and Jegdić, Bore and Bobić, Biljana and Alić, Behar and Marunkić, Dunja D. and Simović, Anđela",
year = "2021",
abstract = "This study considers the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint in NaCl solution, with and without the presence of several corrosion inhibitors (NaNO3, Ce(NO3)(3), and CeCl3). The degree of sensitization of the welded joint to intergranular corrosion is determined using the electrochemical potentiokinetic reactivation method with a double-loop method. Pitting corrosion tests are performed by the potentiodynamic method. Resistance to general corrosion and the stability of the passive film is assessed based on the results of electrochemical impedance spectroscopy measurements, as well as on the values of the corrosion and passivation current. The main goal of this study is to determine the relation of the welded joint microstructure to general and pitting corrosion in the presence of the corrosion inhibitors. The value of pitting potential for the base metal and weld metal in the presence of the NaNO3 or Ce(NO3)(3) inhibitor is shifted to potentials in the transpassive area. The pitting potential for the heat-affected zone also possesses a noticeable higher value. However, nitrate ions do not increase the general corrosion resistance of any part of the welded joint. CeCl3 does not increase resistance to general or pitting corrosion.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Materials and Corrosion-Werkstoffe Und Korrosion",
title = "Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint",
pages = "707-694",
number = "4",
volume = "72",
doi = "10.1002/maco.202012039"
}
Radojković, B., Kovačina, J., Jegdić, B., Bobić, B., Alić, B., Marunkić, D. D.,& Simović, A.. (2021). Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint. in Materials and Corrosion-Werkstoffe Und Korrosion
Wiley-VCH Verlag Gmbh, Weinheim., 72(4), 694-707.
https://doi.org/10.1002/maco.202012039
Radojković B, Kovačina J, Jegdić B, Bobić B, Alić B, Marunkić DD, Simović A. Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint. in Materials and Corrosion-Werkstoffe Und Korrosion. 2021;72(4):694-707.
doi:10.1002/maco.202012039 .
Radojković, Bojana, Kovačina, Jovanka, Jegdić, Bore, Bobić, Biljana, Alić, Behar, Marunkić, Dunja D., Simović, Anđela, "Influence of inhibitors on the corrosion behavior of the X5CrNi18 10 stainless steel-welded joint" in Materials and Corrosion-Werkstoffe Und Korrosion, 72, no. 4 (2021):694-707,
https://doi.org/10.1002/maco.202012039 . .
5
3
6

Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6

Kovačina, Jovanka N.; Marunkić, Dunja D.; Simović, Anđela; Radojković, Bojana; Jegdić, Bore; Marinković, Aleksandar

(Belgrade : Military Technical Institute, 2020)

TY  - CONF
AU  - Kovačina, Jovanka N.
AU  - Marunkić, Dunja D.
AU  - Simović, Anđela
AU  - Radojković, Bojana
AU  - Jegdić, Bore
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4409
AB  - Aluminium AA7075 alloy with its low density and good mechanical properties, widely responds to the requirements of aerospace, navy, and defense industries. However, corrosion is the most common problem that affects the reliability and service life of components and constructions based on this alloy. One of the most practical methods for protecting metals from corrosion is the use of inhibitors. Chromates are known as excellent inhibitors but chromate compounds are highly toxic, carcinogenic, and thus hazardous to humans and the environment. The aim of this study was to synthesize an organic eco-friendly compound (cerium-cysteine) and to investigate its inhibitory property on aluminum alloy AA7075-T6. Rare-earth metals are effective and environmentally friendly substances for aluminium protection as well as cysteine that can be found in many proteins and enzymes such as the keratin in hair. The synthesized inhibitor was confirmed and analyzed by FTIR. The survey of samples corrosion resistance was conducted by three electrochemical methods: linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), and polarization measurements (Epit) in a 0.1M NaCl solution at room temperature. Different concentrations of ceriumcysteine were used to find the best efficiency. The best results were then tested for time dependence (up to 72 h). The inhibitory effectiveness of the cerium complex is shown to depend on a variety of factors such as concentration and time dependence.
PB  - Belgrade : Military Technical Institute
C3  - 9th International Scientific Conference od Defensive Technologies OTEH 2020
T1  - Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4409
ER  - 
@conference{
author = "Kovačina, Jovanka N. and Marunkić, Dunja D. and Simović, Anđela and Radojković, Bojana and Jegdić, Bore and Marinković, Aleksandar",
year = "2020",
abstract = "Aluminium AA7075 alloy with its low density and good mechanical properties, widely responds to the requirements of aerospace, navy, and defense industries. However, corrosion is the most common problem that affects the reliability and service life of components and constructions based on this alloy. One of the most practical methods for protecting metals from corrosion is the use of inhibitors. Chromates are known as excellent inhibitors but chromate compounds are highly toxic, carcinogenic, and thus hazardous to humans and the environment. The aim of this study was to synthesize an organic eco-friendly compound (cerium-cysteine) and to investigate its inhibitory property on aluminum alloy AA7075-T6. Rare-earth metals are effective and environmentally friendly substances for aluminium protection as well as cysteine that can be found in many proteins and enzymes such as the keratin in hair. The synthesized inhibitor was confirmed and analyzed by FTIR. The survey of samples corrosion resistance was conducted by three electrochemical methods: linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), and polarization measurements (Epit) in a 0.1M NaCl solution at room temperature. Different concentrations of ceriumcysteine were used to find the best efficiency. The best results were then tested for time dependence (up to 72 h). The inhibitory effectiveness of the cerium complex is shown to depend on a variety of factors such as concentration and time dependence.",
publisher = "Belgrade : Military Technical Institute",
journal = "9th International Scientific Conference od Defensive Technologies OTEH 2020",
title = "Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4409"
}
Kovačina, J. N., Marunkić, D. D., Simović, A., Radojković, B., Jegdić, B.,& Marinković, A.. (2020). Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6. in 9th International Scientific Conference od Defensive Technologies OTEH 2020
Belgrade : Military Technical Institute..
https://hdl.handle.net/21.15107/rcub_technorep_4409
Kovačina JN, Marunkić DD, Simović A, Radojković B, Jegdić B, Marinković A. Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6. in 9th International Scientific Conference od Defensive Technologies OTEH 2020. 2020;.
https://hdl.handle.net/21.15107/rcub_technorep_4409 .
Kovačina, Jovanka N., Marunkić, Dunja D., Simović, Anđela, Radojković, Bojana, Jegdić, Bore, Marinković, Aleksandar, "Cerium-cysteine complex inhibitor for aluminium alloy AA7075-T6" in 9th International Scientific Conference od Defensive Technologies OTEH 2020 (2020),
https://hdl.handle.net/21.15107/rcub_technorep_4409 .

Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole

Jegdić, Bore; Bobić, Biljana; Stevanović, Maja; Mihailović, Marija; Daničić, Dunja; Kovačina, Jovanka; Radojković, Bojana

(Korean Inst Metals Materials, Seoul, 2020)

TY  - JOUR
AU  - Jegdić, Bore
AU  - Bobić, Biljana
AU  - Stevanović, Maja
AU  - Mihailović, Marija
AU  - Daničić, Dunja
AU  - Kovačina, Jovanka
AU  - Radojković, Bojana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4533
AB  - The paper analyses the corrosion behaviour of both naturally and artificially aged AA2024 aluminium alloy in NaCl solution in the presence of the corrosion inhibitor benzotriazole (BTA). The differences between these two aging tempers in terms of resistance to general corrosion are explained as well as the differences in terms of pit formation and pit growth. Based on the values of the polarisation resistance and the corrosion current density, the general corrosion resistance of the alloy is determined in the absence and in the presence of BTA. The resistance to pit formation and pit growth is determined on the basis of the polarisation measurements results. Scanning electron microscopy confirmed the expected differences in the appearance and size of the pits formed in naturally aged and artificially aged alloy. In the presence of the corrosion inhibitor BTA, for both aging tempers of the alloy, the corrosion resistance is significantly higher compared to the resistance in the solution without the inhibitor. The value of the polarisation resistance for both aging tempers increases over time. However, at the same time, the value of the constant phase element increases as well. An explanation for this phenomenon is provided. The calculated average value of the thickness of the adsorbed inhibitor layer on the surface of the aluminium alloy is in accordance with the inhibitor protective ability for both aging tempers. Graphic
PB  - Korean Inst Metals Materials, Seoul
T2  - Metals and Materials International
T1  - Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole
EP  - 1653
IS  - 11
SP  - 1643
VL  - 26
DO  - 10.1007/s12540-019-00451-8
ER  - 
@article{
author = "Jegdić, Bore and Bobić, Biljana and Stevanović, Maja and Mihailović, Marija and Daničić, Dunja and Kovačina, Jovanka and Radojković, Bojana",
year = "2020",
abstract = "The paper analyses the corrosion behaviour of both naturally and artificially aged AA2024 aluminium alloy in NaCl solution in the presence of the corrosion inhibitor benzotriazole (BTA). The differences between these two aging tempers in terms of resistance to general corrosion are explained as well as the differences in terms of pit formation and pit growth. Based on the values of the polarisation resistance and the corrosion current density, the general corrosion resistance of the alloy is determined in the absence and in the presence of BTA. The resistance to pit formation and pit growth is determined on the basis of the polarisation measurements results. Scanning electron microscopy confirmed the expected differences in the appearance and size of the pits formed in naturally aged and artificially aged alloy. In the presence of the corrosion inhibitor BTA, for both aging tempers of the alloy, the corrosion resistance is significantly higher compared to the resistance in the solution without the inhibitor. The value of the polarisation resistance for both aging tempers increases over time. However, at the same time, the value of the constant phase element increases as well. An explanation for this phenomenon is provided. The calculated average value of the thickness of the adsorbed inhibitor layer on the surface of the aluminium alloy is in accordance with the inhibitor protective ability for both aging tempers. Graphic",
publisher = "Korean Inst Metals Materials, Seoul",
journal = "Metals and Materials International",
title = "Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole",
pages = "1653-1643",
number = "11",
volume = "26",
doi = "10.1007/s12540-019-00451-8"
}
Jegdić, B., Bobić, B., Stevanović, M., Mihailović, M., Daničić, D., Kovačina, J.,& Radojković, B.. (2020). Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole. in Metals and Materials International
Korean Inst Metals Materials, Seoul., 26(11), 1643-1653.
https://doi.org/10.1007/s12540-019-00451-8
Jegdić B, Bobić B, Stevanović M, Mihailović M, Daničić D, Kovačina J, Radojković B. Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole. in Metals and Materials International. 2020;26(11):1643-1653.
doi:10.1007/s12540-019-00451-8 .
Jegdić, Bore, Bobić, Biljana, Stevanović, Maja, Mihailović, Marija, Daničić, Dunja, Kovačina, Jovanka, Radojković, Bojana, "Resistance to Pit Formation and Pit Growth for Different Tempers of AA2024 Aluminium Alloy in Presence of Benzotriazole" in Metals and Materials International, 26, no. 11 (2020):1643-1653,
https://doi.org/10.1007/s12540-019-00451-8 . .
3
2
3

The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy

Živković, Ljiljana; Jegdić, Bore; Andrić, Velibor; Rhee, Kyong Yop; Bajat, Jelena; Mišković-Stanković, Vesna

(Elsevier Science Sa, Lausanne, 2019)

TY  - JOUR
AU  - Živković, Ljiljana
AU  - Jegdić, Bore
AU  - Andrić, Velibor
AU  - Rhee, Kyong Yop
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4046
AB  - In this work an attempt was made to produce epoxy coating doped with ceria (CeO2) and/or zirconia (ZrO2) nanoparticles, in single step electrophoretric deposition process. Deposition was carried out on AA6060 cataforetically from epoxy resin suspension containing synthesized stable aqueous colloidal dispersions (sols) of CeO2 and ZrO2. The influence of ceria and zirconia nanoparticles on the physicochemical characteristics of epoxy coatings was evaluated by energy dispersive X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis and adhesion measurements, while their corrosion stability during immersion in 0.5 M NaCl solution was monitored by electrochemical impedance spectroscopy. All ceria and/or zirconia containing coatings showed better corrosion stability and adhesion than pure epoxy coating, while between doped epoxy coatings one with CeO2/ZrO2 exhhibited the greatest values of charge-transfer resistance due to synergetic effect of both types of added nanoparticles.
PB  - Elsevier Science Sa, Lausanne
T2  - Progress in Organic Coatings
T1  - The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy
VL  - 136
DO  - 10.1016/j.porgcoat.2019.105219
ER  - 
@article{
author = "Živković, Ljiljana and Jegdić, Bore and Andrić, Velibor and Rhee, Kyong Yop and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2019",
abstract = "In this work an attempt was made to produce epoxy coating doped with ceria (CeO2) and/or zirconia (ZrO2) nanoparticles, in single step electrophoretric deposition process. Deposition was carried out on AA6060 cataforetically from epoxy resin suspension containing synthesized stable aqueous colloidal dispersions (sols) of CeO2 and ZrO2. The influence of ceria and zirconia nanoparticles on the physicochemical characteristics of epoxy coatings was evaluated by energy dispersive X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis and adhesion measurements, while their corrosion stability during immersion in 0.5 M NaCl solution was monitored by electrochemical impedance spectroscopy. All ceria and/or zirconia containing coatings showed better corrosion stability and adhesion than pure epoxy coating, while between doped epoxy coatings one with CeO2/ZrO2 exhhibited the greatest values of charge-transfer resistance due to synergetic effect of both types of added nanoparticles.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Progress in Organic Coatings",
title = "The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy",
volume = "136",
doi = "10.1016/j.porgcoat.2019.105219"
}
Živković, L., Jegdić, B., Andrić, V., Rhee, K. Y., Bajat, J.,& Mišković-Stanković, V.. (2019). The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy. in Progress in Organic Coatings
Elsevier Science Sa, Lausanne., 136.
https://doi.org/10.1016/j.porgcoat.2019.105219
Živković L, Jegdić B, Andrić V, Rhee KY, Bajat J, Mišković-Stanković V. The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy. in Progress in Organic Coatings. 2019;136.
doi:10.1016/j.porgcoat.2019.105219 .
Živković, Ljiljana, Jegdić, Bore, Andrić, Velibor, Rhee, Kyong Yop, Bajat, Jelena, Mišković-Stanković, Vesna, "The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy" in Progress in Organic Coatings, 136 (2019),
https://doi.org/10.1016/j.porgcoat.2019.105219 . .
21
10
20

Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy

Radetić, Tamara; Popović, Miljana; Jegdić, Bore; Romhanji, Endre

(Wiley-VCH Verlag Gmbh, Weinheim, 2016)

TY  - JOUR
AU  - Radetić, Tamara
AU  - Popović, Miljana
AU  - Jegdić, Bore
AU  - Romhanji, Endre
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3335
AB  - Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Materials and Corrosion-Werkstoffe Und Korrosion
T1  - Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy
EP  - 875
IS  - 8
SP  - 867
VL  - 67
DO  - 10.1002/maco.201508709
ER  - 
@article{
author = "Radetić, Tamara and Popović, Miljana and Jegdić, Bore and Romhanji, Endre",
year = "2016",
abstract = "Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Materials and Corrosion-Werkstoffe Und Korrosion",
title = "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy",
pages = "875-867",
number = "8",
volume = "67",
doi = "10.1002/maco.201508709"
}
Radetić, T., Popović, M., Jegdić, B.,& Romhanji, E.. (2016). Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion
Wiley-VCH Verlag Gmbh, Weinheim., 67(8), 867-875.
https://doi.org/10.1002/maco.201508709
Radetić T, Popović M, Jegdić B, Romhanji E. Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion. 2016;67(8):867-875.
doi:10.1002/maco.201508709 .
Radetić, Tamara, Popović, Miljana, Jegdić, Bore, Romhanji, Endre, "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy" in Materials and Corrosion-Werkstoffe Und Korrosion, 67, no. 8 (2016):867-875,
https://doi.org/10.1002/maco.201508709 . .
6
4
6

Failures of brass condenser tubes

Bobić, Biljana; Jegdić, Bore; Jugović, Branimir; Stevanović, Jasmina; Gligorijević, Bojan; Murariu, Alin

(Society for Structural Integrity and Life, Institute for Material Testing, 2016)

TY  - JOUR
AU  - Bobić, Biljana
AU  - Jegdić, Bore
AU  - Jugović, Branimir
AU  - Stevanović, Jasmina
AU  - Gligorijević, Bojan
AU  - Murariu, Alin
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3171
AB  - Causes of failure of brass condenser tubes (CuZn28Sn1) in a thermal power plant in Serbia are analysed. Results of testing by Fourier transformed infrared spectroscopy (FTIR) have indicated the presence of ammonia and nitrogen compounds on fracture surfaces and on the inner surface of the tubes. These compounds are specific agents that cause stress corrosion cracking (SCC) in brass. Analysis of fracture surfaces using scanning electron microscopy (SEM) has shown the brittle transgranular fracture due to the occurrence of SCC. The resistance of brass condenser tubes to other types of corrosion, such as erosion, general and selective corrosion (dezincification) is also considered. Some procedures are proposed to reduce the risk of SCC in the brass condenser tubes.
PB  - Society for Structural Integrity and Life, Institute for Material Testing
T2  - Structural Integrity and Life
T1  - Failures of brass condenser tubes
EP  - 23
IS  - 1
SP  - 19
VL  - 16
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3171
ER  - 
@article{
author = "Bobić, Biljana and Jegdić, Bore and Jugović, Branimir and Stevanović, Jasmina and Gligorijević, Bojan and Murariu, Alin",
year = "2016",
abstract = "Causes of failure of brass condenser tubes (CuZn28Sn1) in a thermal power plant in Serbia are analysed. Results of testing by Fourier transformed infrared spectroscopy (FTIR) have indicated the presence of ammonia and nitrogen compounds on fracture surfaces and on the inner surface of the tubes. These compounds are specific agents that cause stress corrosion cracking (SCC) in brass. Analysis of fracture surfaces using scanning electron microscopy (SEM) has shown the brittle transgranular fracture due to the occurrence of SCC. The resistance of brass condenser tubes to other types of corrosion, such as erosion, general and selective corrosion (dezincification) is also considered. Some procedures are proposed to reduce the risk of SCC in the brass condenser tubes.",
publisher = "Society for Structural Integrity and Life, Institute for Material Testing",
journal = "Structural Integrity and Life",
title = "Failures of brass condenser tubes",
pages = "23-19",
number = "1",
volume = "16",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3171"
}
Bobić, B., Jegdić, B., Jugović, B., Stevanović, J., Gligorijević, B.,& Murariu, A.. (2016). Failures of brass condenser tubes. in Structural Integrity and Life
Society for Structural Integrity and Life, Institute for Material Testing., 16(1), 19-23.
https://hdl.handle.net/21.15107/rcub_technorep_3171
Bobić B, Jegdić B, Jugović B, Stevanović J, Gligorijević B, Murariu A. Failures of brass condenser tubes. in Structural Integrity and Life. 2016;16(1):19-23.
https://hdl.handle.net/21.15107/rcub_technorep_3171 .
Bobić, Biljana, Jegdić, Bore, Jugović, Branimir, Stevanović, Jasmina, Gligorijević, Bojan, Murariu, Alin, "Failures of brass condenser tubes" in Structural Integrity and Life, 16, no. 1 (2016):19-23,
https://hdl.handle.net/21.15107/rcub_technorep_3171 .
2

Failures of Brass Condenser Tubes

Bobić, Biljana; Jegdić, Bore; Jugović, Branimir; Stevanović, Jasmina; Gligorijević, Bojan; Murariu, Alin

(Institut za ispitivanje materijala, Beograd, 2016)

TY  - JOUR
AU  - Bobić, Biljana
AU  - Jegdić, Bore
AU  - Jugović, Branimir
AU  - Stevanović, Jasmina
AU  - Gligorijević, Bojan
AU  - Murariu, Alin
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3180
AB  - Causes of failure of brass condenser tubes (CuZn28Sn1) in a thermal power plant in Serbia are analysed. Results of testing by Fourier transformed infrared spectroscopy (FTIR) have indicated the presence of ammonia and nitro- gen compounds on fracture surfaces and on the inner surface of the tubes. These compounds are specific agents that cause stress corrosion cracking (SCC) in brass. Analy- sis of fracture surfaces using scanning electron microscopy (SEM) has shown the brittle transgranular fracture due to the occurrence of SCC. The resistance of brass condenser tubes to other types of corrosion, such as erosion, general and selective corrosion (dezincification) is also considered. Some procedures are proposed to reduce the risk of SCC in the brass condenser tubes.
AB  - Analizirani su uzroci pojave loma kondenzatorskih cevi od mesinga CuZn28Sn1 u jednoj termoelektrani u Srbiji. Rezultati ispitivanja metodom Furijeove transformisane infracrvene spektroskopije (FTIR) ukazuju na prisustvo amonijačnih i azotnih jedinjenja na površini loma i na unutrašnjoj površini cevi. Ta jedinjenja su specifični agensi za pojavu naponske korozije mesinga. Analiza površine loma primenom skening elektronske mikroskopije (SEM) pokazala je prisustvo krtog transkistalnog loma nastalog usled pojave naponske korozije. Razmatrana je otpornost cevi od mesinga CuZn28Sn1 prema drugim vidovima koro- zije, kao što su eroziona, opšta i selektivna korozija (decin- kacija). Predloženi su postupci za smanjenje rizika od pojave naponske korozije u kondenzatorskim cevima.
PB  - Institut za ispitivanje materijala, Beograd
T2  - Structural Integrity and Life
T1  - Failures of Brass Condenser Tubes
T1  - Lomovi kondenzatorskih cevi od mesinga
EP  - 23
IS  - 1
SP  - 19
VL  - 16
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3180
ER  - 
@article{
author = "Bobić, Biljana and Jegdić, Bore and Jugović, Branimir and Stevanović, Jasmina and Gligorijević, Bojan and Murariu, Alin",
year = "2016",
abstract = "Causes of failure of brass condenser tubes (CuZn28Sn1) in a thermal power plant in Serbia are analysed. Results of testing by Fourier transformed infrared spectroscopy (FTIR) have indicated the presence of ammonia and nitro- gen compounds on fracture surfaces and on the inner surface of the tubes. These compounds are specific agents that cause stress corrosion cracking (SCC) in brass. Analy- sis of fracture surfaces using scanning electron microscopy (SEM) has shown the brittle transgranular fracture due to the occurrence of SCC. The resistance of brass condenser tubes to other types of corrosion, such as erosion, general and selective corrosion (dezincification) is also considered. Some procedures are proposed to reduce the risk of SCC in the brass condenser tubes., Analizirani su uzroci pojave loma kondenzatorskih cevi od mesinga CuZn28Sn1 u jednoj termoelektrani u Srbiji. Rezultati ispitivanja metodom Furijeove transformisane infracrvene spektroskopije (FTIR) ukazuju na prisustvo amonijačnih i azotnih jedinjenja na površini loma i na unutrašnjoj površini cevi. Ta jedinjenja su specifični agensi za pojavu naponske korozije mesinga. Analiza površine loma primenom skening elektronske mikroskopije (SEM) pokazala je prisustvo krtog transkistalnog loma nastalog usled pojave naponske korozije. Razmatrana je otpornost cevi od mesinga CuZn28Sn1 prema drugim vidovima koro- zije, kao što su eroziona, opšta i selektivna korozija (decin- kacija). Predloženi su postupci za smanjenje rizika od pojave naponske korozije u kondenzatorskim cevima.",
publisher = "Institut za ispitivanje materijala, Beograd",
journal = "Structural Integrity and Life",
title = "Failures of Brass Condenser Tubes, Lomovi kondenzatorskih cevi od mesinga",
pages = "23-19",
number = "1",
volume = "16",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3180"
}
Bobić, B., Jegdić, B., Jugović, B., Stevanović, J., Gligorijević, B.,& Murariu, A.. (2016). Failures of Brass Condenser Tubes. in Structural Integrity and Life
Institut za ispitivanje materijala, Beograd., 16(1), 19-23.
https://hdl.handle.net/21.15107/rcub_technorep_3180
Bobić B, Jegdić B, Jugović B, Stevanović J, Gligorijević B, Murariu A. Failures of Brass Condenser Tubes. in Structural Integrity and Life. 2016;16(1):19-23.
https://hdl.handle.net/21.15107/rcub_technorep_3180 .
Bobić, Biljana, Jegdić, Bore, Jugović, Branimir, Stevanović, Jasmina, Gligorijević, Bojan, Murariu, Alin, "Failures of Brass Condenser Tubes" in Structural Integrity and Life, 16, no. 1 (2016):19-23,
https://hdl.handle.net/21.15107/rcub_technorep_3180 .

Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution

Bobić, Biljana; Bajat, Jelena; Bobić, Ilija; Jegdić, Bore

(Elsevier Science Bv, Amsterdam, 2016)

TY  - JOUR
AU  - Bobić, Biljana
AU  - Bajat, Jelena
AU  - Bobić, Ilija
AU  - Jegdić, Bore
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3271
AB  - The influence of corrosion on the surface appearance and microstructure of particulate ZA27/SiCp composites was examined after 30 d immersion in a sodium chloride solution with the access of atmospheric oxygen. The composites with different contents of SiC micro-particles were synthesized via compo casting. Microstructural studies by means of optical microscopy (OM) and scanning electron microscopy (SEM) showed that corrosion occurred in the composite matrices, preferentially in regions of the. phase, rich in zinc. The corrosion processes did not affect the silicon carbide particles incorporated in the matrix alloy. According to the results of electrochemical polarization measurements, an increase in the content of SiC particles in the composite matrice has led to the lower corrosion resistance in the composites.
PB  - Elsevier Science Bv, Amsterdam
T2  - Transactions of Nonferrous Metals Society of China
T1  - Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution
EP  - 1521
IS  - 6
SP  - 1512
VL  - 26
DO  - 10.1016/S1003-6326(16)64257-7
ER  - 
@article{
author = "Bobić, Biljana and Bajat, Jelena and Bobić, Ilija and Jegdić, Bore",
year = "2016",
abstract = "The influence of corrosion on the surface appearance and microstructure of particulate ZA27/SiCp composites was examined after 30 d immersion in a sodium chloride solution with the access of atmospheric oxygen. The composites with different contents of SiC micro-particles were synthesized via compo casting. Microstructural studies by means of optical microscopy (OM) and scanning electron microscopy (SEM) showed that corrosion occurred in the composite matrices, preferentially in regions of the. phase, rich in zinc. The corrosion processes did not affect the silicon carbide particles incorporated in the matrix alloy. According to the results of electrochemical polarization measurements, an increase in the content of SiC particles in the composite matrice has led to the lower corrosion resistance in the composites.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution",
pages = "1521-1512",
number = "6",
volume = "26",
doi = "10.1016/S1003-6326(16)64257-7"
}
Bobić, B., Bajat, J., Bobić, I.,& Jegdić, B.. (2016). Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution. in Transactions of Nonferrous Metals Society of China
Elsevier Science Bv, Amsterdam., 26(6), 1512-1521.
https://doi.org/10.1016/S1003-6326(16)64257-7
Bobić B, Bajat J, Bobić I, Jegdić B. Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution. in Transactions of Nonferrous Metals Society of China. 2016;26(6):1512-1521.
doi:10.1016/S1003-6326(16)64257-7 .
Bobić, Biljana, Bajat, Jelena, Bobić, Ilija, Jegdić, Bore, "Corrosion influence on surface appearance and microstructure of compo cast ZA27/SiCp composites in sodium chloride solution" in Transactions of Nonferrous Metals Society of China, 26, no. 6 (2016):1512-1521,
https://doi.org/10.1016/S1003-6326(16)64257-7 . .
12
10
12

Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy

Jegdić, Bore; Živković, Ljiljana; Popić, Jovan P.; Rogan, Jelena; Bajat, Jelena; Mišković-Stanković, Vesna

(Wiley-VCH Verlag Gmbh, Weinheim, 2016)

TY  - JOUR
AU  - Jegdić, Bore
AU  - Živković, Ljiljana
AU  - Popić, Jovan P.
AU  - Rogan, Jelena
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3302
AB  - In this study, corrosion protection efficiency of undoped epoxy and epoxy coating doped with cerium on aluminum alloy AA6060 is evaluated over prolonged exposure to 3wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Different amounts of Ce(NO3)(3) are added into the epoxy suspension used for the cataphoretic deposition. Suspension stability is characterized by zeta potential and particle size values. Water content and thermal stability of the coatings were determined by thermogravimetric analysis. Insufficient corrosion stability, very close to that of undoped epoxy, is revealed for the coating with 1mM Ce. Higher cerium doping contributes to a significant increase in corrosion stability (2-3 orders of magnitude greater charge-transfer resistance). Epoxy coating doped with 5mM Ce displays a pronounced self-healing ability and the best corrosion protection and adhesion, owing to evenly distributed cerium precipitates on the aluminum surface. In the case of 10mM Ce-doped coating, the formation of Ce clusters and higher porosity causes a certain lowering of the protective ability. EIS measurements on epoxy coating with artificial defect confirm these findings.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Materials and Corrosion-Werkstoffe Und Korrosion
T1  - Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy
EP  - 1184
IS  - 11
SP  - 1173
VL  - 67
DO  - 10.1002/maco.201608827
ER  - 
@article{
author = "Jegdić, Bore and Živković, Ljiljana and Popić, Jovan P. and Rogan, Jelena and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2016",
abstract = "In this study, corrosion protection efficiency of undoped epoxy and epoxy coating doped with cerium on aluminum alloy AA6060 is evaluated over prolonged exposure to 3wt% NaCl solution by electrochemical impedance spectroscopy (EIS). Different amounts of Ce(NO3)(3) are added into the epoxy suspension used for the cataphoretic deposition. Suspension stability is characterized by zeta potential and particle size values. Water content and thermal stability of the coatings were determined by thermogravimetric analysis. Insufficient corrosion stability, very close to that of undoped epoxy, is revealed for the coating with 1mM Ce. Higher cerium doping contributes to a significant increase in corrosion stability (2-3 orders of magnitude greater charge-transfer resistance). Epoxy coating doped with 5mM Ce displays a pronounced self-healing ability and the best corrosion protection and adhesion, owing to evenly distributed cerium precipitates on the aluminum surface. In the case of 10mM Ce-doped coating, the formation of Ce clusters and higher porosity causes a certain lowering of the protective ability. EIS measurements on epoxy coating with artificial defect confirm these findings.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Materials and Corrosion-Werkstoffe Und Korrosion",
title = "Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy",
pages = "1184-1173",
number = "11",
volume = "67",
doi = "10.1002/maco.201608827"
}
Jegdić, B., Živković, L., Popić, J. P., Rogan, J., Bajat, J.,& Mišković-Stanković, V.. (2016). Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy. in Materials and Corrosion-Werkstoffe Und Korrosion
Wiley-VCH Verlag Gmbh, Weinheim., 67(11), 1173-1184.
https://doi.org/10.1002/maco.201608827
Jegdić B, Živković L, Popić JP, Rogan J, Bajat J, Mišković-Stanković V. Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy. in Materials and Corrosion-Werkstoffe Und Korrosion. 2016;67(11):1173-1184.
doi:10.1002/maco.201608827 .
Jegdić, Bore, Živković, Ljiljana, Popić, Jovan P., Rogan, Jelena, Bajat, Jelena, Mišković-Stanković, Vesna, "Corrosion stability of cerium-doped cataphoretic epoxy coatings on AA6060 alloy" in Materials and Corrosion-Werkstoffe Und Korrosion, 67, no. 11 (2016):1173-1184,
https://doi.org/10.1002/maco.201608827 . .
11
8
11

Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging

Jegdić, Bore; Bobić, Biljana; Pavlović, Miloš K.; Alil, Ana; Putić, Slaviša

(Association of the Chemical Engineers of Serbia, 2015)

TY  - JOUR
AU  - Jegdić, Bore
AU  - Bobić, Biljana
AU  - Pavlović, Miloš K.
AU  - Alil, Ana
AU  - Putić, Slaviša
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2923
AB  - The effect of one-step and a new (short) two-step aging process on the resistance to stress corrosion cracking of an aluminum alloy 7000 series was investigated, using slow strain rate test and fracture mechanics method. The aging level in the tested alloy was evaluated by means of scanning electron microscopy and measurements of electrical resistivity. It was shown that the alloy after the new two-step aging is significantly more resistant to stress corrosion cracking. Values of tensile properties and fracture toughness are similar for both thermal states. Processes that take place at the crack tip have been considered. The effect of the testing solution temperature on the crack growth rate on the plateau was determined. Two values of the apparent activation energy were obtained. These values correspond to different processes that control crack growth rate on the plateau at higher and lower temperatures.
AB  - Ispitivan je uticaj jednostepenog i novog (kratkotrajnog) dvostepenog termičkog taloženja na otpornost prema naponskoj koroziji aluminijumske legure serije 7000, primenom metode male brzine deformacije i metode mehanike loma. Stepen starenja ispitivane legure je procenjen primenom skening elektronske mikroskopije i na osnovu merenja električne otpornosti. Pokazano je da je legura posle novog dvostepenog termičkog starenja znatno otpornija prema naponskoj koroziji. Vrednosti zateznih karakteristika i žilavosti loma su slične za oba termička stanja legure. Razmatrani su procesi koji se odvijaju na vrhu naponsko-korozione prsline. Određen je uticaj temperature rastvora za ispitivanje na brzinu rasta prsline na platou. Određene su dve vrednosti prividne energije aktivacije. Ove vrednosti odgovaraju različitim procesima koji kontrolišu brzinu rasta prsline na platou, na visokim i niskim temperaturama.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging
T1  - Otpornost aluminijumske legure serije 7000 prema naponskoj koroziji posle dvostepenog termičkog taloženja
EP  - 268
IS  - 2
SP  - 261
VL  - 21
DO  - 10.2298/CICEQ140324024J
ER  - 
@article{
author = "Jegdić, Bore and Bobić, Biljana and Pavlović, Miloš K. and Alil, Ana and Putić, Slaviša",
year = "2015",
abstract = "The effect of one-step and a new (short) two-step aging process on the resistance to stress corrosion cracking of an aluminum alloy 7000 series was investigated, using slow strain rate test and fracture mechanics method. The aging level in the tested alloy was evaluated by means of scanning electron microscopy and measurements of electrical resistivity. It was shown that the alloy after the new two-step aging is significantly more resistant to stress corrosion cracking. Values of tensile properties and fracture toughness are similar for both thermal states. Processes that take place at the crack tip have been considered. The effect of the testing solution temperature on the crack growth rate on the plateau was determined. Two values of the apparent activation energy were obtained. These values correspond to different processes that control crack growth rate on the plateau at higher and lower temperatures., Ispitivan je uticaj jednostepenog i novog (kratkotrajnog) dvostepenog termičkog taloženja na otpornost prema naponskoj koroziji aluminijumske legure serije 7000, primenom metode male brzine deformacije i metode mehanike loma. Stepen starenja ispitivane legure je procenjen primenom skening elektronske mikroskopije i na osnovu merenja električne otpornosti. Pokazano je da je legura posle novog dvostepenog termičkog starenja znatno otpornija prema naponskoj koroziji. Vrednosti zateznih karakteristika i žilavosti loma su slične za oba termička stanja legure. Razmatrani su procesi koji se odvijaju na vrhu naponsko-korozione prsline. Određen je uticaj temperature rastvora za ispitivanje na brzinu rasta prsline na platou. Određene su dve vrednosti prividne energije aktivacije. Ove vrednosti odgovaraju različitim procesima koji kontrolišu brzinu rasta prsline na platou, na visokim i niskim temperaturama.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging, Otpornost aluminijumske legure serije 7000 prema naponskoj koroziji posle dvostepenog termičkog taloženja",
pages = "268-261",
number = "2",
volume = "21",
doi = "10.2298/CICEQ140324024J"
}
Jegdić, B., Bobić, B., Pavlović, M. K., Alil, A.,& Putić, S.. (2015). Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 21(2), 261-268.
https://doi.org/10.2298/CICEQ140324024J
Jegdić B, Bobić B, Pavlović MK, Alil A, Putić S. Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging. in Chemical Industry & Chemical Engineering Quarterly. 2015;21(2):261-268.
doi:10.2298/CICEQ140324024J .
Jegdić, Bore, Bobić, Biljana, Pavlović, Miloš K., Alil, Ana, Putić, Slaviša, "Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging" in Chemical Industry & Chemical Engineering Quarterly, 21, no. 2 (2015):261-268,
https://doi.org/10.2298/CICEQ140324024J . .
3
1
3

Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy

Bajat, Jelena; Živković, Ljiljana; Jegdić, Bore; Popić, Jovan P.; Mišković-Stanković, Vesna

(Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria, 2015)

TY  - CONF
AU  - Bajat, Jelena
AU  - Živković, Ljiljana
AU  - Jegdić, Bore
AU  - Popić, Jovan P.
AU  - Mišković-Stanković, Vesna
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2877
AB  - Protective coatings should provide good barrier to ingress of corrosive species, sufficient adhesion to the substrate as well as good compatibility with additional top coats. The presence of pigments and/or functional agents in the coating composition could be beneficial in the corrosion protection. The doping with rare earth elements, like cerium, has shown to enhance the corrosion stability of organic coatings due to their self-healing properties. In this work cerium doped nanometric epoxy primers were deposited cataphoretically with different amounts of cerium nitrate (1, 5 and 10 mM) with the aim of optimizing the cerium content in the epoxy emulsion with respect to adhesion and corrosion stability of deposited primer coating. Cerium-free epoxy coating was also analyzed as a reference. The long term protection was evaluated in the chloride environment (3 wt.%NaCl) using electrochemical impedance spectroscopy (EIS) and polarization measurements. Coatings were also analyzed by scanning electron microscopy (SEM) coupled with EDX, Fourier transform infrared spectroscopy and thermogravimetric measurements. Size and zeta potential of epoxy emulsion were measured by dynamic light scattering and Laser Doppler velocimetry. Adhesion was determined both by a standardized pull-off method and by swelling in N-methyl pyrrolidone. The ceria content, as well as its distribution in the epoxy coating, was determined by SEM cross-sectional analysis. The homogeneity of epoxy coatings was evaluated and related to corrosion stability. The results showed that cerium-doping can promote the formation of compact epoxy coatings with enhanced protectiveness in the early stage of immersion in the corrosive media. Increased barrier properties of epoxy primers suggest good compatibility of ceria particles with polymeric epoxy layer. However, zeta potential measurements indicated that higher amounts than 10 mM Ce(NO3)3 added into the epoxy emulsion resulted in unstable emulsion. The water content in the epoxy coatings and their thermal stability were also determined. In addition, a detailed EIS study was undertaken to follow the evolution of corrosion stability of all samples with time of exposure to corrosive media. It was shown that all examined ceria containing epoxy emulsions resulted with the enhanced adhesion and corrosion stability of epoxy primers. However, the smallest loading of 1 mM showed only improvement during the initial exposure to NaCl solution. EIS and polarization measurements confirmed that higher ceria loadings also provide long term protection in chloride solution.The optimal ceria content in the epoxy emulsion, with respect to adhesion strength, thermal stability and long-term corrosion stability of protective systems was 10 mM.
PB  - Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria
C3  - 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
T1  - Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy
EP  - 44
SP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2877
ER  - 
@conference{
author = "Bajat, Jelena and Živković, Ljiljana and Jegdić, Bore and Popić, Jovan P. and Mišković-Stanković, Vesna",
year = "2015",
abstract = "Protective coatings should provide good barrier to ingress of corrosive species, sufficient adhesion to the substrate as well as good compatibility with additional top coats. The presence of pigments and/or functional agents in the coating composition could be beneficial in the corrosion protection. The doping with rare earth elements, like cerium, has shown to enhance the corrosion stability of organic coatings due to their self-healing properties. In this work cerium doped nanometric epoxy primers were deposited cataphoretically with different amounts of cerium nitrate (1, 5 and 10 mM) with the aim of optimizing the cerium content in the epoxy emulsion with respect to adhesion and corrosion stability of deposited primer coating. Cerium-free epoxy coating was also analyzed as a reference. The long term protection was evaluated in the chloride environment (3 wt.%NaCl) using electrochemical impedance spectroscopy (EIS) and polarization measurements. Coatings were also analyzed by scanning electron microscopy (SEM) coupled with EDX, Fourier transform infrared spectroscopy and thermogravimetric measurements. Size and zeta potential of epoxy emulsion were measured by dynamic light scattering and Laser Doppler velocimetry. Adhesion was determined both by a standardized pull-off method and by swelling in N-methyl pyrrolidone. The ceria content, as well as its distribution in the epoxy coating, was determined by SEM cross-sectional analysis. The homogeneity of epoxy coatings was evaluated and related to corrosion stability. The results showed that cerium-doping can promote the formation of compact epoxy coatings with enhanced protectiveness in the early stage of immersion in the corrosive media. Increased barrier properties of epoxy primers suggest good compatibility of ceria particles with polymeric epoxy layer. However, zeta potential measurements indicated that higher amounts than 10 mM Ce(NO3)3 added into the epoxy emulsion resulted in unstable emulsion. The water content in the epoxy coatings and their thermal stability were also determined. In addition, a detailed EIS study was undertaken to follow the evolution of corrosion stability of all samples with time of exposure to corrosive media. It was shown that all examined ceria containing epoxy emulsions resulted with the enhanced adhesion and corrosion stability of epoxy primers. However, the smallest loading of 1 mM showed only improvement during the initial exposure to NaCl solution. EIS and polarization measurements confirmed that higher ceria loadings also provide long term protection in chloride solution.The optimal ceria content in the epoxy emulsion, with respect to adhesion strength, thermal stability and long-term corrosion stability of protective systems was 10 mM.",
publisher = "Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria",
journal = "5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts",
title = "Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy",
pages = "44-44",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2877"
}
Bajat, J., Živković, L., Jegdić, B., Popić, J. P.,& Mišković-Stanković, V.. (2015). Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy. in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems Bulgarian Academy of Sciences, Sofia, Bulgaria., 44-44.
https://hdl.handle.net/21.15107/rcub_technorep_2877
Bajat J, Živković L, Jegdić B, Popić JP, Mišković-Stanković V. Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy. in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts. 2015;:44-44.
https://hdl.handle.net/21.15107/rcub_technorep_2877 .
Bajat, Jelena, Živković, Ljiljana, Jegdić, Bore, Popić, Jovan P., Mišković-Stanković, Vesna, "Corrosion Stability of Cerium Modified Cataphoretic Epoxy Coatings on Al6060 Alloy" in 5th Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts (2015):44-44,
https://hdl.handle.net/21.15107/rcub_technorep_2877 .

Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment

Živković, Ljiljana; Bajat, Jelena; Popić, Jovan P.; Jegdić, Bore; Stevanović, Sanja; Mišković-Stanković, Vesna

(Elsevier Science Sa, Lausanne, 2015)

TY  - JOUR
AU  - Živković, Ljiljana
AU  - Bajat, Jelena
AU  - Popić, Jovan P.
AU  - Jegdić, Bore
AU  - Stevanović, Sanja
AU  - Mišković-Stanković, Vesna
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3045
AB  - Ce-based conversion coatings (CeCCs) are a promising alternative to toxic chromate coatings on the metal substrates. In this work the CeCCs were electrodeposited on aluminium alloy AA6060 from aqueous solution of Ce(NO3)(3) at different potentials (-0.95 V, -1.2 V and -1.4V). Effect of deposition potential and post-treatment in the phosphate solution on morphology and protective properties of CeCCs with top cataphoretic epoxy coating was studied. To assess the differences between the protective systems, originating from the different CeCCs pre-treatments, electrochemical impedance spectroscopy (EIS), polarization measurements, AFM and SEM/EDS analysis were used. The EIS study was undertaken to follow the evolution of corrosion behaviour of epoxy coating/CeCCs protective systems over prolonged time of exposure to the chloride environment (3 wt.% NaCl). Results suggest significantly improved corrosion stability of epoxy coating on AA6060 with as-deposited CeCCs sub-layers with respect to the same epoxy coatings with phosphate post-treated CeCCs. The far best protective properties, i.e., the greatest value of pore resistance and the lowest value of corrosion current density were provided by the epoxy coating/CeCC protective system with CeCC deposited at -1.2V and without post-treatment.
PB  - Elsevier Science Sa, Lausanne
T2  - Progress in Organic Coatings
T1  - Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment
EP  - 52
SP  - 43
VL  - 79
DO  - 10.1016/j.porgcoat.2014.10.014
ER  - 
@article{
author = "Živković, Ljiljana and Bajat, Jelena and Popić, Jovan P. and Jegdić, Bore and Stevanović, Sanja and Mišković-Stanković, Vesna",
year = "2015",
abstract = "Ce-based conversion coatings (CeCCs) are a promising alternative to toxic chromate coatings on the metal substrates. In this work the CeCCs were electrodeposited on aluminium alloy AA6060 from aqueous solution of Ce(NO3)(3) at different potentials (-0.95 V, -1.2 V and -1.4V). Effect of deposition potential and post-treatment in the phosphate solution on morphology and protective properties of CeCCs with top cataphoretic epoxy coating was studied. To assess the differences between the protective systems, originating from the different CeCCs pre-treatments, electrochemical impedance spectroscopy (EIS), polarization measurements, AFM and SEM/EDS analysis were used. The EIS study was undertaken to follow the evolution of corrosion behaviour of epoxy coating/CeCCs protective systems over prolonged time of exposure to the chloride environment (3 wt.% NaCl). Results suggest significantly improved corrosion stability of epoxy coating on AA6060 with as-deposited CeCCs sub-layers with respect to the same epoxy coatings with phosphate post-treated CeCCs. The far best protective properties, i.e., the greatest value of pore resistance and the lowest value of corrosion current density were provided by the epoxy coating/CeCC protective system with CeCC deposited at -1.2V and without post-treatment.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Progress in Organic Coatings",
title = "Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment",
pages = "52-43",
volume = "79",
doi = "10.1016/j.porgcoat.2014.10.014"
}
Živković, L., Bajat, J., Popić, J. P., Jegdić, B., Stevanović, S.,& Mišković-Stanković, V.. (2015). Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment. in Progress in Organic Coatings
Elsevier Science Sa, Lausanne., 79, 43-52.
https://doi.org/10.1016/j.porgcoat.2014.10.014
Živković L, Bajat J, Popić JP, Jegdić B, Stevanović S, Mišković-Stanković V. Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment. in Progress in Organic Coatings. 2015;79:43-52.
doi:10.1016/j.porgcoat.2014.10.014 .
Živković, Ljiljana, Bajat, Jelena, Popić, Jovan P., Jegdić, Bore, Stevanović, Sanja, Mišković-Stanković, Vesna, "Protective properties of cataphoretic epoxy coating on aluminium alloy AA6060 modified with electrodeposited Ce-based coatings: Effect of post-treatment" in Progress in Organic Coatings, 79 (2015):43-52,
https://doi.org/10.1016/j.porgcoat.2014.10.014 . .
18
13
16

Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening

Jegdić, Bore; Bobić, Biljana; Gligorijević, Bojan; Mišković-Stanković, Vesna

(Engineering Society for Corrosion, Belgrade, Serbia, 2014)

TY  - JOUR
AU  - Jegdić, Bore
AU  - Bobić, Biljana
AU  - Gligorijević, Bojan
AU  - Mišković-Stanković, Vesna
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2602
AB  - Corrosion properties of an aluminium alloy 7000 series were investigated by different electrochemical methods. The alloy was subjected to the one-step and to a new two-step precipitation hardening. Polarization measurements in the 3.5 wt. % NaCl solution have shown a more positive value of the pitting potential (Epit) and a higher corrosion resistance for the two-step aged alloy. The electrochemical impedance spectroscopy (EIS) has also shown that the two-step aged alloy has better corrosion properties (higher value of polarization resistance, Rp, and lower value of double-layer capacitance, Cdl) comparing to the one-step aged alloy.
AB  - Otpornost prema koroziji aluminijumske legure serije 7000 ispitivana je primenom različitih elektrohemijskih metoda. Legura je bila podvrgnuta jednostepenom i novom dvostepenom termičkom taloženju. Polarizaciona merenja u 3,5 mas.% NaCl su pokazala da legura posle dvostepenog termičkog taloženja ima pozitivniju vrednost potencijala pitinga (Epit) i veću otpornost prema koroziji. Spektroskopija elektrohemijske impedancije (SEI) je takođe pokazala da legura posle dvostepenog termičkog taloženja ima bolju otpornost prema koroziji (veću vrednost polarizacione otpornosti, Rp i manju vrednost kapacitivnosti dvojnog sloja, Cdl) u poređenju sa legurom posle jednostepenog termičkog taloženja.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening
T1  - Otpornost prema koroziji aluminijumske legure serije 7000 posle novog dvostepenog termičkog taloženja
EP  - 394
IS  - 4
SP  - 387
VL  - 55
DO  - 10.5937/ZasMat1404387J
ER  - 
@article{
author = "Jegdić, Bore and Bobić, Biljana and Gligorijević, Bojan and Mišković-Stanković, Vesna",
year = "2014",
abstract = "Corrosion properties of an aluminium alloy 7000 series were investigated by different electrochemical methods. The alloy was subjected to the one-step and to a new two-step precipitation hardening. Polarization measurements in the 3.5 wt. % NaCl solution have shown a more positive value of the pitting potential (Epit) and a higher corrosion resistance for the two-step aged alloy. The electrochemical impedance spectroscopy (EIS) has also shown that the two-step aged alloy has better corrosion properties (higher value of polarization resistance, Rp, and lower value of double-layer capacitance, Cdl) comparing to the one-step aged alloy., Otpornost prema koroziji aluminijumske legure serije 7000 ispitivana je primenom različitih elektrohemijskih metoda. Legura je bila podvrgnuta jednostepenom i novom dvostepenom termičkom taloženju. Polarizaciona merenja u 3,5 mas.% NaCl su pokazala da legura posle dvostepenog termičkog taloženja ima pozitivniju vrednost potencijala pitinga (Epit) i veću otpornost prema koroziji. Spektroskopija elektrohemijske impedancije (SEI) je takođe pokazala da legura posle dvostepenog termičkog taloženja ima bolju otpornost prema koroziji (veću vrednost polarizacione otpornosti, Rp i manju vrednost kapacitivnosti dvojnog sloja, Cdl) u poređenju sa legurom posle jednostepenog termičkog taloženja.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening, Otpornost prema koroziji aluminijumske legure serije 7000 posle novog dvostepenog termičkog taloženja",
pages = "394-387",
number = "4",
volume = "55",
doi = "10.5937/ZasMat1404387J"
}
Jegdić, B., Bobić, B., Gligorijević, B.,& Mišković-Stanković, V.. (2014). Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 55(4), 387-394.
https://doi.org/10.5937/ZasMat1404387J
Jegdić B, Bobić B, Gligorijević B, Mišković-Stanković V. Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening. in Zaštita materijala. 2014;55(4):387-394.
doi:10.5937/ZasMat1404387J .
Jegdić, Bore, Bobić, Biljana, Gligorijević, Bojan, Mišković-Stanković, Vesna, "Corrosion properties of an aluminium alloy 7000 series after a new two step precipitation hardening" in Zaštita materijala, 55, no. 4 (2014):387-394,
https://doi.org/10.5937/ZasMat1404387J . .
2

Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential

Živković, Ljiljana; Popić, Jovan P.; Jegdić, Bore; Dohcević-Mitrović, Zorana; Bajat, Jelena; Mišković-Stanković, Vesna

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Živković, Ljiljana
AU  - Popić, Jovan P.
AU  - Jegdić, Bore
AU  - Dohcević-Mitrović, Zorana
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2767
AB  - Among potential replacements for chromates, cerium-based conversion coatings (CeCCs) have been identified as leading candidates, showing a good promise as environmentally compliant corrosion inhibitors on Al alloys. In this work, CeCCs were synthesized on M6060 by electrolytic deposition (ELD), a well-suited method for the fabrication of films with controllable properties, at low processing temperature and cost. The CeCCs were deposited at room temperature from Ce(NO3)(3) solution, applying different cathodic potentials (-1.1, -1.4 and -1.6 V vs. SCE) for different deposition times between 5 and 20 min. Structural, morphological and compositional properties of the films were characterized by X-ray diffraction, Raman spectroscopy and scanning electron microscopy coupled with energy dispersive spectroscopy. Ceria films were nanostructured, exhibiting a cubic fluorite structure. From corrosion perspective, the quality of CeCCs was evaluated in 0.5 M NaCI solution via electrochemical impedance spectroscopy and linear sweep voltammetry. As shown, the coating corrosion quality is the interplay between deposition potential and deposition time. The highest potential led to highly cracked films of poor adherence, even at the shortest deposition time, which disqualified them from any corrosion protection application. The lowest potential (-1.1 V) produced crack-free coatings, but longer times ( gt = 10 min) were needed to provide the protective layer formation. The best corrosion protection offered CeCCs prepared at -1.4 V. The highest R-p (582 k Omega cm(2)) and the smallest CPE (12.6 . 10(-6) s(n) Omega(-1) cm) were obtained at 20 min deposition time. However, from economical point of view, 10 min deposition is a promising choice. These CeCCs also improved pitting corrosion resistance owing to homogeneous microstructure and sufficient thickness.
PB  - Elsevier Science Sa, Lausanne
T2  - Surface & Coatings Technology
T1  - Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential
EP  - 335
SP  - 327
VL  - 240
DO  - 10.1016/j.surfcoat.2013.12.048
ER  - 
@article{
author = "Živković, Ljiljana and Popić, Jovan P. and Jegdić, Bore and Dohcević-Mitrović, Zorana and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2014",
abstract = "Among potential replacements for chromates, cerium-based conversion coatings (CeCCs) have been identified as leading candidates, showing a good promise as environmentally compliant corrosion inhibitors on Al alloys. In this work, CeCCs were synthesized on M6060 by electrolytic deposition (ELD), a well-suited method for the fabrication of films with controllable properties, at low processing temperature and cost. The CeCCs were deposited at room temperature from Ce(NO3)(3) solution, applying different cathodic potentials (-1.1, -1.4 and -1.6 V vs. SCE) for different deposition times between 5 and 20 min. Structural, morphological and compositional properties of the films were characterized by X-ray diffraction, Raman spectroscopy and scanning electron microscopy coupled with energy dispersive spectroscopy. Ceria films were nanostructured, exhibiting a cubic fluorite structure. From corrosion perspective, the quality of CeCCs was evaluated in 0.5 M NaCI solution via electrochemical impedance spectroscopy and linear sweep voltammetry. As shown, the coating corrosion quality is the interplay between deposition potential and deposition time. The highest potential led to highly cracked films of poor adherence, even at the shortest deposition time, which disqualified them from any corrosion protection application. The lowest potential (-1.1 V) produced crack-free coatings, but longer times ( gt = 10 min) were needed to provide the protective layer formation. The best corrosion protection offered CeCCs prepared at -1.4 V. The highest R-p (582 k Omega cm(2)) and the smallest CPE (12.6 . 10(-6) s(n) Omega(-1) cm) were obtained at 20 min deposition time. However, from economical point of view, 10 min deposition is a promising choice. These CeCCs also improved pitting corrosion resistance owing to homogeneous microstructure and sufficient thickness.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Surface & Coatings Technology",
title = "Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential",
pages = "335-327",
volume = "240",
doi = "10.1016/j.surfcoat.2013.12.048"
}
Živković, L., Popić, J. P., Jegdić, B., Dohcević-Mitrović, Z., Bajat, J.,& Mišković-Stanković, V.. (2014). Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential. in Surface & Coatings Technology
Elsevier Science Sa, Lausanne., 240, 327-335.
https://doi.org/10.1016/j.surfcoat.2013.12.048
Živković L, Popić JP, Jegdić B, Dohcević-Mitrović Z, Bajat J, Mišković-Stanković V. Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential. in Surface & Coatings Technology. 2014;240:327-335.
doi:10.1016/j.surfcoat.2013.12.048 .
Živković, Ljiljana, Popić, Jovan P., Jegdić, Bore, Dohcević-Mitrović, Zorana, Bajat, Jelena, Mišković-Stanković, Vesna, "Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: Effect of deposition potential" in Surface & Coatings Technology, 240 (2014):327-335,
https://doi.org/10.1016/j.surfcoat.2013.12.048 . .
29
24
32

Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique

Popić, Jovan P.; Jegdić, Bore; Bajat, Jelena; Mitrić, Miodrag; Mišković-Stanković, Vesna

(Serbian Chemical Society, Belgrade, 2013)

TY  - JOUR
AU  - Popić, Jovan P.
AU  - Jegdić, Bore
AU  - Bajat, Jelena
AU  - Mitrić, Miodrag
AU  - Mišković-Stanković, Vesna
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2314
AB  - In this study, the effect of deposition time and concentration of NaNO2 in the phosphate bath on the surface morphology of iron-phosphate coatings on low carbon steel was investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The composition of ironphosphate coatings was determined using energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), while surface coverage was evaluated by the voltammetric anodic dissolution (VAD) technique in the borate solution. The addition of NaNO2 to the phosphate bath significantly increased the surface coverage since better packed crystals of smaller size, which favour the phosphate nucleation, were obtained. It was also shown that prolonged deposition time increased the surface coverage, coating roughness and crystal size in the lateral direction, altering also the crystal shape from large platelets non-uniformly distributed on the steel surface during the initial time to better packed laminated and needle-like structures during prolonged exposure.
AB  - U ovom radu je, primenom skenirajuće elektronske mikroskopije (SEM) i mikro- skopije međuatomskih sila (AFM), ispitivan uticaj vremena taloženja i koncentracije NaNO2 u rastvoru za fosfatiranje na morfologiju gvožđe-fosfatnih prevlaka na nisko-ugljeničnom čeliku. Sastav gvožđe–fosfatnih prevlaka je određen primenom energetske disperzione atomske analize (EDS) i difrakcijom H-zraka (XRD), dok je pokrivenost površine određivana anodnim rastvaranjem u boratnom rastvoru primenom linearne voltametrije (VAD). Pokazano je da dodatak NaNO2 u rastvoru za fosfatiranje značajno povećava pokrivenost površine čelika, jer se formiraju bolje pakovani kristali, manje veličine. Duže vreme taloženja takođe povećava pokrivenost površine, kao i hrapavost prevlake i širinu kristala. Oblik kristala se tokom dužeg vremena taloženja menja od kristala u obliku većih ploča neuniformno raspoređenih na površini čelika, ka bolje pakovanim laminarnim i igličastim kristalima.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique
T1  - Određivanje pokrivenosti površine čelika gvožđe-fosfatnim prevlakama anodnim rastvaranjem primenom linearne voltametrije
EP  - 114
IS  - 1
SP  - 101
VL  - 78
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2314
ER  - 
@article{
author = "Popić, Jovan P. and Jegdić, Bore and Bajat, Jelena and Mitrić, Miodrag and Mišković-Stanković, Vesna",
year = "2013",
abstract = "In this study, the effect of deposition time and concentration of NaNO2 in the phosphate bath on the surface morphology of iron-phosphate coatings on low carbon steel was investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The composition of ironphosphate coatings was determined using energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), while surface coverage was evaluated by the voltammetric anodic dissolution (VAD) technique in the borate solution. The addition of NaNO2 to the phosphate bath significantly increased the surface coverage since better packed crystals of smaller size, which favour the phosphate nucleation, were obtained. It was also shown that prolonged deposition time increased the surface coverage, coating roughness and crystal size in the lateral direction, altering also the crystal shape from large platelets non-uniformly distributed on the steel surface during the initial time to better packed laminated and needle-like structures during prolonged exposure., U ovom radu je, primenom skenirajuće elektronske mikroskopije (SEM) i mikro- skopije međuatomskih sila (AFM), ispitivan uticaj vremena taloženja i koncentracije NaNO2 u rastvoru za fosfatiranje na morfologiju gvožđe-fosfatnih prevlaka na nisko-ugljeničnom čeliku. Sastav gvožđe–fosfatnih prevlaka je određen primenom energetske disperzione atomske analize (EDS) i difrakcijom H-zraka (XRD), dok je pokrivenost površine određivana anodnim rastvaranjem u boratnom rastvoru primenom linearne voltametrije (VAD). Pokazano je da dodatak NaNO2 u rastvoru za fosfatiranje značajno povećava pokrivenost površine čelika, jer se formiraju bolje pakovani kristali, manje veličine. Duže vreme taloženja takođe povećava pokrivenost površine, kao i hrapavost prevlake i širinu kristala. Oblik kristala se tokom dužeg vremena taloženja menja od kristala u obliku većih ploča neuniformno raspoređenih na površini čelika, ka bolje pakovanim laminarnim i igličastim kristalima.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique, Određivanje pokrivenosti površine čelika gvožđe-fosfatnim prevlakama anodnim rastvaranjem primenom linearne voltametrije",
pages = "114-101",
number = "1",
volume = "78",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2314"
}
Popić, J. P., Jegdić, B., Bajat, J., Mitrić, M.,& Mišković-Stanković, V.. (2013). Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 78(1), 101-114.
https://hdl.handle.net/21.15107/rcub_technorep_2314
Popić JP, Jegdić B, Bajat J, Mitrić M, Mišković-Stanković V. Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique. in Journal of the Serbian Chemical Society. 2013;78(1):101-114.
https://hdl.handle.net/21.15107/rcub_technorep_2314 .
Popić, Jovan P., Jegdić, Bore, Bajat, Jelena, Mitrić, Miodrag, Mišković-Stanković, Vesna, "Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique" in Journal of the Serbian Chemical Society, 78, no. 1 (2013):101-114,
https://hdl.handle.net/21.15107/rcub_technorep_2314 .
3
5

Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method

Jegdić, Bore; Živković, Ljiljana; Popić, Jovan P.; Bajat, Jelena; Mišković-Stanković, Vesna

(Serbian Chemical Society, Belgrade, 2013)

TY  - JOUR
AU  - Jegdić, Bore
AU  - Živković, Ljiljana
AU  - Popić, Jovan P.
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2360
AB  - Dip-immersion is a simple and cost-effective method for the preparation of Ce-based conversion coatings (CeCCs), a promising alternative to toxic chromate coatings, on metal substrates. In this work, CeCCs were prepared on Al-alloy AA6060 from an aqueous solution of cerium chloride at room temperature. The effect of immersion time and post-treatment in phosphate solution on the microstructure and corrosion properties of the coatings was studied. The longer the immersion time was, the thicker but more nonhomogeneous and cracked were the CeCCs. The post-treatment contributed to a sealing of the cracks, as proven by an increase in the corrosion resistance compared with the as-deposited coatings. The CeCCs prepared at longer deposition times and post-treated showed much better corrosion protection than those prepared at shorter deposition times. A detailed electrochemical impedance spectroscopy (EIS) study was undertaken to follow the evolution of the corrosion behaviour of the CeCCs with time of exposure to an aggressive chloride environment (3.5 % NaCl). For the sake of comparison, the EIS properties of bare AA6060 were also investigated. Linear voltammetry was performed to complete the study. The results confirmed the formation of protective CeCCs on the surface of AA6060. However, even CeCCs prepared at longer deposition times and post-treated provided short term protection in the aggressive environment, due to the small thickness of the coating.
AB  - Nanošenje prevlaka potapanjem u rastvor je jednostavna i ekonomski prihvatljiva metoda za pripremu konverzionih prevlaka na bazi cerijuma na metalnim supstratima, koje su dobra zamena za toksične hromatne prevlake. U ovom radu prevlake na bazi cerijuma su nanesene na aluminijumsku leguru AA6060 iz vodenog rastvora cerijum-hlorida na sobnoj temperaturi. Ispitivan je uticaj vremena potapanja i uticaj naknadnog tretmana u fosfatnom rastvoru na mikrostrukturu i zaštitna svojstva dobijenih prevlaka. Dužim potapanjem su dobijene deblje ali nehomogene prevlake. Naknadni tretman je povoljno uticao na zatvaranje prskotina, što je u saglasnosti sa izmerenom većom korozionom otpornošću u poređenju sa prevlakama bez tretmana. Prevlake dobijene dužim nanošenjem su pokazale bolju korozionu zaštitu od prevlaka dobijenih kraćim nanošenjem. Koroziona stabilnost prevlaka je ispitivana u agresivnoj hloridnoj sredini (3,5 % NaCl) metodama spektroskopije elektrohemijske impedancije (SEI) i linearne voltametrije. Detaljno je praćeno koroziono ponašanje prevlaka sa vremenom delovanja korozionog agensa. Poređenja radi, SEI analiza je sprovedena i za leguru AA6060 bez prevlake. Rezultati istraživanja potvrđuju da dobijene prevlake na bazi cerijuma predstavljaju dobru korozionu zaštitu leguri AA6060. Međutim, čak i kvalitetnija prevlaka (20 min potapanja i naknadno tretirana u fosfatnom rastvoru) obezbeđuje leguri kratkoročnu zaštitu u agresivnoj sredini usled svoje male debljine.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method
T1  - Elektrohemijske metode za ispitivanje korozione stabilnosti prevlaka na bazi cerijuma dobijenih potapanjem na leguri AA6060
EP  - 1011
IS  - 7
SP  - 997
VL  - 78
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2360
ER  - 
@article{
author = "Jegdić, Bore and Živković, Ljiljana and Popić, Jovan P. and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2013",
abstract = "Dip-immersion is a simple and cost-effective method for the preparation of Ce-based conversion coatings (CeCCs), a promising alternative to toxic chromate coatings, on metal substrates. In this work, CeCCs were prepared on Al-alloy AA6060 from an aqueous solution of cerium chloride at room temperature. The effect of immersion time and post-treatment in phosphate solution on the microstructure and corrosion properties of the coatings was studied. The longer the immersion time was, the thicker but more nonhomogeneous and cracked were the CeCCs. The post-treatment contributed to a sealing of the cracks, as proven by an increase in the corrosion resistance compared with the as-deposited coatings. The CeCCs prepared at longer deposition times and post-treated showed much better corrosion protection than those prepared at shorter deposition times. A detailed electrochemical impedance spectroscopy (EIS) study was undertaken to follow the evolution of the corrosion behaviour of the CeCCs with time of exposure to an aggressive chloride environment (3.5 % NaCl). For the sake of comparison, the EIS properties of bare AA6060 were also investigated. Linear voltammetry was performed to complete the study. The results confirmed the formation of protective CeCCs on the surface of AA6060. However, even CeCCs prepared at longer deposition times and post-treated provided short term protection in the aggressive environment, due to the small thickness of the coating., Nanošenje prevlaka potapanjem u rastvor je jednostavna i ekonomski prihvatljiva metoda za pripremu konverzionih prevlaka na bazi cerijuma na metalnim supstratima, koje su dobra zamena za toksične hromatne prevlake. U ovom radu prevlake na bazi cerijuma su nanesene na aluminijumsku leguru AA6060 iz vodenog rastvora cerijum-hlorida na sobnoj temperaturi. Ispitivan je uticaj vremena potapanja i uticaj naknadnog tretmana u fosfatnom rastvoru na mikrostrukturu i zaštitna svojstva dobijenih prevlaka. Dužim potapanjem su dobijene deblje ali nehomogene prevlake. Naknadni tretman je povoljno uticao na zatvaranje prskotina, što je u saglasnosti sa izmerenom većom korozionom otpornošću u poređenju sa prevlakama bez tretmana. Prevlake dobijene dužim nanošenjem su pokazale bolju korozionu zaštitu od prevlaka dobijenih kraćim nanošenjem. Koroziona stabilnost prevlaka je ispitivana u agresivnoj hloridnoj sredini (3,5 % NaCl) metodama spektroskopije elektrohemijske impedancije (SEI) i linearne voltametrije. Detaljno je praćeno koroziono ponašanje prevlaka sa vremenom delovanja korozionog agensa. Poređenja radi, SEI analiza je sprovedena i za leguru AA6060 bez prevlake. Rezultati istraživanja potvrđuju da dobijene prevlake na bazi cerijuma predstavljaju dobru korozionu zaštitu leguri AA6060. Međutim, čak i kvalitetnija prevlaka (20 min potapanja i naknadno tretirana u fosfatnom rastvoru) obezbeđuje leguri kratkoročnu zaštitu u agresivnoj sredini usled svoje male debljine.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method, Elektrohemijske metode za ispitivanje korozione stabilnosti prevlaka na bazi cerijuma dobijenih potapanjem na leguri AA6060",
pages = "1011-997",
number = "7",
volume = "78",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2360"
}
Jegdić, B., Živković, L., Popić, J. P., Bajat, J.,& Mišković-Stanković, V.. (2013). Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 78(7), 997-1011.
https://hdl.handle.net/21.15107/rcub_technorep_2360
Jegdić B, Živković L, Popić JP, Bajat J, Mišković-Stanković V. Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method. in Journal of the Serbian Chemical Society. 2013;78(7):997-1011.
https://hdl.handle.net/21.15107/rcub_technorep_2360 .
Jegdić, Bore, Živković, Ljiljana, Popić, Jovan P., Bajat, Jelena, Mišković-Stanković, Vesna, "Electrochemical methods for corrosion testing of Ce-based coatings prepared on AA6060 alloy by the dip immersion method" in Journal of the Serbian Chemical Society, 78, no. 7 (2013):997-1011,
https://hdl.handle.net/21.15107/rcub_technorep_2360 .
6

Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution

Bobić, Biljana; Bajat, Jelena; Aćimović-Pavlović, Zagorka; Bobić, Ilija; Jegdić, Bore

(Elsevier Science Bv, Amsterdam, 2013)

TY  - JOUR
AU  - Bobić, Biljana
AU  - Bajat, Jelena
AU  - Aćimović-Pavlović, Zagorka
AU  - Bobić, Ilija
AU  - Jegdić, Bore
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2473
AB  - The influence of corrosion on the microstructure of thixoformed and heat-treated ZA27 alloys was investigated. The microstructure of ZA27 alloy was affected by heat treatment. The process of electrochemical corrosion occurs in both ZA27 alloys through the area of eta phase. According to the results of immersion test and electrochemical measurements, the corrosion rate of the thixoformed ZA27 alloy is at least 50% lower than that of the thixoformed and thermally processed alloy. This indicates the unfavourable influence of applied heat treatment (T4 regime) on the corrosion resistance of the thixoformed ZA27 alloy.
PB  - Elsevier Science Bv, Amsterdam
T2  - Transactions of Nonferrous Metals Society of China
T1  - Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution
EP  - 941
IS  - 4
SP  - 931
VL  - 23
DO  - 10.1016/S1003-6326(13)62550-9
ER  - 
@article{
author = "Bobić, Biljana and Bajat, Jelena and Aćimović-Pavlović, Zagorka and Bobić, Ilija and Jegdić, Bore",
year = "2013",
abstract = "The influence of corrosion on the microstructure of thixoformed and heat-treated ZA27 alloys was investigated. The microstructure of ZA27 alloy was affected by heat treatment. The process of electrochemical corrosion occurs in both ZA27 alloys through the area of eta phase. According to the results of immersion test and electrochemical measurements, the corrosion rate of the thixoformed ZA27 alloy is at least 50% lower than that of the thixoformed and thermally processed alloy. This indicates the unfavourable influence of applied heat treatment (T4 regime) on the corrosion resistance of the thixoformed ZA27 alloy.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution",
pages = "941-931",
number = "4",
volume = "23",
doi = "10.1016/S1003-6326(13)62550-9"
}
Bobić, B., Bajat, J., Aćimović-Pavlović, Z., Bobić, I.,& Jegdić, B.. (2013). Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution. in Transactions of Nonferrous Metals Society of China
Elsevier Science Bv, Amsterdam., 23(4), 931-941.
https://doi.org/10.1016/S1003-6326(13)62550-9
Bobić B, Bajat J, Aćimović-Pavlović Z, Bobić I, Jegdić B. Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution. in Transactions of Nonferrous Metals Society of China. 2013;23(4):931-941.
doi:10.1016/S1003-6326(13)62550-9 .
Bobić, Biljana, Bajat, Jelena, Aćimović-Pavlović, Zagorka, Bobić, Ilija, Jegdić, Bore, "Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution" in Transactions of Nonferrous Metals Society of China, 23, no. 4 (2013):931-941,
https://doi.org/10.1016/S1003-6326(13)62550-9 . .
10
8
14

The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060

Živković, Ljiljana; Jegdić, Bore; Popić, Jovan P.; Bajat, Jelena; Mišković-Stanković, Vesna

(Elsevier Science Sa, Lausanne, 2013)

TY  - JOUR
AU  - Živković, Ljiljana
AU  - Jegdić, Bore
AU  - Popić, Jovan P.
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2388
AB  - Cerium-based conversion coatings (CeCCs) are one of the most prospective alternatives to the widely used chromate conversion coatings (CCCs) due to their anticorrosion efficiency, environmentally friendly nature and low cost. In this work, the CeCCs on AA6060 were prepared by immersion into aqueous cerium salt solutions at room temperature, and subsequently post-treated in heated phosphate solution. The effect of counter ion (nitrate and chloride) on the coating properties was studied testing CeCCs as sole or conversion layers for the top polyester coating. Since the 60 mu m thick polyester coating was applied, an artificial defect of 0.8 mm hole was introduced to faster assess the differences between pretreatments. The system with CCC pretreatment was used as reference. Corrosion properties were investigated in 0.5 M NaCl solution by electrochemical impedance spectroscopy while the adhesion strength was measured by NMPR (N-methyl-2-pyrrolidone) and pull-off tests. As shown, the post-treated chloride-based CeCC offered better protection than crack-free thin nitrate-based CeCC, when used as sole coatings. On the other hand, it was brought to evidence that in combination with top powder polyester coating, the CeCC deposited from nitrate solution exhibited better protection compared to protective system pretreated with chloride-based one. Excellent polyester coating adhesion was found independently on aluminium surface pretreatment.
PB  - Elsevier Science Sa, Lausanne
T2  - Progress in Organic Coatings
T1  - The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060
EP  - 1395
IS  - 10
SP  - 1387
VL  - 76
DO  - 10.1016/j.porgcoat.2013.04.017
ER  - 
@article{
author = "Živković, Ljiljana and Jegdić, Bore and Popić, Jovan P. and Bajat, Jelena and Mišković-Stanković, Vesna",
year = "2013",
abstract = "Cerium-based conversion coatings (CeCCs) are one of the most prospective alternatives to the widely used chromate conversion coatings (CCCs) due to their anticorrosion efficiency, environmentally friendly nature and low cost. In this work, the CeCCs on AA6060 were prepared by immersion into aqueous cerium salt solutions at room temperature, and subsequently post-treated in heated phosphate solution. The effect of counter ion (nitrate and chloride) on the coating properties was studied testing CeCCs as sole or conversion layers for the top polyester coating. Since the 60 mu m thick polyester coating was applied, an artificial defect of 0.8 mm hole was introduced to faster assess the differences between pretreatments. The system with CCC pretreatment was used as reference. Corrosion properties were investigated in 0.5 M NaCl solution by electrochemical impedance spectroscopy while the adhesion strength was measured by NMPR (N-methyl-2-pyrrolidone) and pull-off tests. As shown, the post-treated chloride-based CeCC offered better protection than crack-free thin nitrate-based CeCC, when used as sole coatings. On the other hand, it was brought to evidence that in combination with top powder polyester coating, the CeCC deposited from nitrate solution exhibited better protection compared to protective system pretreated with chloride-based one. Excellent polyester coating adhesion was found independently on aluminium surface pretreatment.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Progress in Organic Coatings",
title = "The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060",
pages = "1395-1387",
number = "10",
volume = "76",
doi = "10.1016/j.porgcoat.2013.04.017"
}
Živković, L., Jegdić, B., Popić, J. P., Bajat, J.,& Mišković-Stanković, V.. (2013). The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060. in Progress in Organic Coatings
Elsevier Science Sa, Lausanne., 76(10), 1387-1395.
https://doi.org/10.1016/j.porgcoat.2013.04.017
Živković L, Jegdić B, Popić JP, Bajat J, Mišković-Stanković V. The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060. in Progress in Organic Coatings. 2013;76(10):1387-1395.
doi:10.1016/j.porgcoat.2013.04.017 .
Živković, Ljiljana, Jegdić, Bore, Popić, Jovan P., Bajat, Jelena, Mišković-Stanković, Vesna, "The influence of Ce-based coatings as pretreatments on corrosion stability of top powder polyester coating on AA6060" in Progress in Organic Coatings, 76, no. 10 (2013):1387-1395,
https://doi.org/10.1016/j.porgcoat.2013.04.017 . .
15
12

Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods

Jegdić, Bore; Alil, Ana; Bobić, Biljana; Radosavljević, Miroslav; Mišković-Stanković, Vesna

(Military Technical Institute, 2012)

TY  - CONF
AU  - Jegdić, Bore
AU  - Alil, Ana
AU  - Bobić, Biljana
AU  - Radosavljević, Miroslav
AU  - Mišković-Stanković, Vesna
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6092
AB  - Abstract: The corrosion tendency in the 7000 series aluminium alloys changes depending on the content of alloying
elements, thermal and thermo-mechanical treatments, etc. An alloy of this type applied in the production of weapons
and military equipment has been investigated by applying different electrochemical methods. A degree of the
precipitation hardening (aging) of the alloy has been evaluated by measuring its electrical resistivity. The corrosion
potential measurements (Ecorr.) gave information about the distribution of the alloying elements between the solid
solution and the precipitation phases. The polarization measurements, performed in the 0.5 M NaCl solution, have
shown a more positive value of the pitting potential (Epit.) and a greater corrosion resistance for the two-step aged
alloy. The electrochemical impedance spectroscopy (EIS) has also shown that the two-step aged alloy has better
corrosion properties (a higher value of polarization resistance, Rp, and a lower value of capacitance, Cdl) comparing to
the one-step aged alloy. These results enable a deeper insight into the effects of both heat treatment and alloying
elements, primarily copper, on the corrosion resistance of the tested alloy.
PB  - Military Technical Institute
C3  - 5th International Scientific Conference on Defensive Technologies
T1  - Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods
EP  - 593
SP  - 588
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6092
ER  - 
@conference{
author = "Jegdić, Bore and Alil, Ana and Bobić, Biljana and Radosavljević, Miroslav and Mišković-Stanković, Vesna",
year = "2012",
abstract = "Abstract: The corrosion tendency in the 7000 series aluminium alloys changes depending on the content of alloying
elements, thermal and thermo-mechanical treatments, etc. An alloy of this type applied in the production of weapons
and military equipment has been investigated by applying different electrochemical methods. A degree of the
precipitation hardening (aging) of the alloy has been evaluated by measuring its electrical resistivity. The corrosion
potential measurements (Ecorr.) gave information about the distribution of the alloying elements between the solid
solution and the precipitation phases. The polarization measurements, performed in the 0.5 M NaCl solution, have
shown a more positive value of the pitting potential (Epit.) and a greater corrosion resistance for the two-step aged
alloy. The electrochemical impedance spectroscopy (EIS) has also shown that the two-step aged alloy has better
corrosion properties (a higher value of polarization resistance, Rp, and a lower value of capacitance, Cdl) comparing to
the one-step aged alloy. These results enable a deeper insight into the effects of both heat treatment and alloying
elements, primarily copper, on the corrosion resistance of the tested alloy.",
publisher = "Military Technical Institute",
journal = "5th International Scientific Conference on Defensive Technologies",
title = "Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods",
pages = "593-588",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6092"
}
Jegdić, B., Alil, A., Bobić, B., Radosavljević, M.,& Mišković-Stanković, V.. (2012). Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods. in 5th International Scientific Conference on Defensive Technologies
Military Technical Institute., 588-593.
https://hdl.handle.net/21.15107/rcub_technorep_6092
Jegdić B, Alil A, Bobić B, Radosavljević M, Mišković-Stanković V. Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods. in 5th International Scientific Conference on Defensive Technologies. 2012;:588-593.
https://hdl.handle.net/21.15107/rcub_technorep_6092 .
Jegdić, Bore, Alil, Ana, Bobić, Biljana, Radosavljević, Miroslav, Mišković-Stanković, Vesna, "Corrosion Testing of an Al-Zn-Mg-Cu Alloy After Different Heat Treatment Regimes by the Application of Electrochemical Methods" in 5th International Scientific Conference on Defensive Technologies (2012):588-593,
https://hdl.handle.net/21.15107/rcub_technorep_6092 .