Jovanović, Dušan M.

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  • Jovanović, Dušan M. (6)
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Author's Bibliography

Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide

Pajnik, Jelena; Radetić, Maja; Stojanović, Dušica; Janković-Častvan, Ivona; Tadić, Vanja; Stanković, Miroslav; Jovanović, Dušan M.; Žižović, Irena

(Elsevier Science Bv, Amsterdam, 2018)

TY  - JOUR
AU  - Pajnik, Jelena
AU  - Radetić, Maja
AU  - Stojanović, Dušica
AU  - Janković-Častvan, Ivona
AU  - Tadić, Vanja
AU  - Stanković, Miroslav
AU  - Jovanović, Dušan M.
AU  - Žižović, Irena
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4035
AB  - This study discusses the possibility of supercritical solvent impregnation of polypropylene and polyamide fabrics as well as cellulose acetate in the form of beads and films with pyrethrum extract in order to fabricate functionalized materials with repellent properties. Impregnation experiments were performed at temperature of 40 degrees C and pressures of 10 and 20 MPa in supercritical carbon dioxide. The time of impregnation was varied from 0.5 to 18 h. Loadings of pyrethrum extract into polypropylene fabrics and cellulose acetate films higher than 30% were attainable at 10 MPa. In the case of polyamide fabrics and cellulose acetate beads, the pressure of 20 MPa was needed for obtaining the loadings higher than 11%. Pyrethrum extract release study revealed different capabilities of the tested materials for the repellent release, implying a variety of their possible applications. The impregnated solids were characterized by SEM, DSC, FTIR, Mercury intrusion porosimetry analyses and HPLC analyses.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Supercritical Fluids
T1  - Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide
EP  - 81
SP  - 70
VL  - 136
DO  - 10.1016/j.supflu.2018.02.014
ER  - 
@article{
author = "Pajnik, Jelena and Radetić, Maja and Stojanović, Dušica and Janković-Častvan, Ivona and Tadić, Vanja and Stanković, Miroslav and Jovanović, Dušan M. and Žižović, Irena",
year = "2018",
abstract = "This study discusses the possibility of supercritical solvent impregnation of polypropylene and polyamide fabrics as well as cellulose acetate in the form of beads and films with pyrethrum extract in order to fabricate functionalized materials with repellent properties. Impregnation experiments were performed at temperature of 40 degrees C and pressures of 10 and 20 MPa in supercritical carbon dioxide. The time of impregnation was varied from 0.5 to 18 h. Loadings of pyrethrum extract into polypropylene fabrics and cellulose acetate films higher than 30% were attainable at 10 MPa. In the case of polyamide fabrics and cellulose acetate beads, the pressure of 20 MPa was needed for obtaining the loadings higher than 11%. Pyrethrum extract release study revealed different capabilities of the tested materials for the repellent release, implying a variety of their possible applications. The impregnated solids were characterized by SEM, DSC, FTIR, Mercury intrusion porosimetry analyses and HPLC analyses.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Supercritical Fluids",
title = "Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide",
pages = "81-70",
volume = "136",
doi = "10.1016/j.supflu.2018.02.014"
}
Pajnik, J., Radetić, M., Stojanović, D., Janković-Častvan, I., Tadić, V., Stanković, M., Jovanović, D. M.,& Žižović, I.. (2018). Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide. in Journal of Supercritical Fluids
Elsevier Science Bv, Amsterdam., 136, 70-81.
https://doi.org/10.1016/j.supflu.2018.02.014
Pajnik J, Radetić M, Stojanović D, Janković-Častvan I, Tadić V, Stanković M, Jovanović DM, Žižović I. Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide. in Journal of Supercritical Fluids. 2018;136:70-81.
doi:10.1016/j.supflu.2018.02.014 .
Pajnik, Jelena, Radetić, Maja, Stojanović, Dušica, Janković-Častvan, Ivona, Tadić, Vanja, Stanković, Miroslav, Jovanović, Dušan M., Žižović, Irena, "Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide" in Journal of Supercritical Fluids, 136 (2018):70-81,
https://doi.org/10.1016/j.supflu.2018.02.014 . .
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Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes

Dostanić, Jasmina; Mijin, Dušan; Ušćumlić, Gordana; Jovanović, Dušan M.; Zlatar, Matija; Lončarević, Davor

(Pergamon-Elsevier Science Ltd, Oxford, 2014)

TY  - JOUR
AU  - Dostanić, Jasmina
AU  - Mijin, Dušan
AU  - Ušćumlić, Gordana
AU  - Jovanović, Dušan M.
AU  - Zlatar, Matija
AU  - Lončarević, Davor
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2842
AB  - A series of 5-(4-substituted arylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridone dyes was synthesized and the structure of the dyes was confirmed by UV-Vis, FT-IR, H-1 NMR and C-13 NMR spectroscopic techniques. The azo-hydrazone tautomeric equilibrium was found to depend on the substituents as well as on the acidity and basicity of the media. Ionization constant, pK(a), of the dyes was determined by UV-Vis spectroscopy and correlated with the Hammett substituent constants, sigma(p) and sigma(I). The interpretation of the effect of different substituent in phenyl ring of arylazo pyridone dyes on their spectroscopic and structural properties was based on quantum chemical calculations performed by the density functional theory (DET/M06-2X) method. The DFT calculations confirmed the existence of two forms in water solution: hydrazone form in acidic and neutral media and anionic form in basic media. The different contribution of azo and hydrazone canonical forms of anionic form is observed for dyes with electron-donating and dyes with electron-withdrawing groups. The dependence of absorption spectra and determined pK(a) values to the substituent type seems to be mostly due to azo/hydrazone canonical structure ratio in their anionic form.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
T1  - Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes
EP  - 45
SP  - 37
VL  - 123
DO  - 10.1016/j.saa.2013.12.064
ER  - 
@article{
author = "Dostanić, Jasmina and Mijin, Dušan and Ušćumlić, Gordana and Jovanović, Dušan M. and Zlatar, Matija and Lončarević, Davor",
year = "2014",
abstract = "A series of 5-(4-substituted arylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridone dyes was synthesized and the structure of the dyes was confirmed by UV-Vis, FT-IR, H-1 NMR and C-13 NMR spectroscopic techniques. The azo-hydrazone tautomeric equilibrium was found to depend on the substituents as well as on the acidity and basicity of the media. Ionization constant, pK(a), of the dyes was determined by UV-Vis spectroscopy and correlated with the Hammett substituent constants, sigma(p) and sigma(I). The interpretation of the effect of different substituent in phenyl ring of arylazo pyridone dyes on their spectroscopic and structural properties was based on quantum chemical calculations performed by the density functional theory (DET/M06-2X) method. The DFT calculations confirmed the existence of two forms in water solution: hydrazone form in acidic and neutral media and anionic form in basic media. The different contribution of azo and hydrazone canonical forms of anionic form is observed for dyes with electron-donating and dyes with electron-withdrawing groups. The dependence of absorption spectra and determined pK(a) values to the substituent type seems to be mostly due to azo/hydrazone canonical structure ratio in their anionic form.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy",
title = "Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes",
pages = "45-37",
volume = "123",
doi = "10.1016/j.saa.2013.12.064"
}
Dostanić, J., Mijin, D., Ušćumlić, G., Jovanović, D. M., Zlatar, M.,& Lončarević, D.. (2014). Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes. in Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
Pergamon-Elsevier Science Ltd, Oxford., 123, 37-45.
https://doi.org/10.1016/j.saa.2013.12.064
Dostanić J, Mijin D, Ušćumlić G, Jovanović DM, Zlatar M, Lončarević D. Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes. in Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. 2014;123:37-45.
doi:10.1016/j.saa.2013.12.064 .
Dostanić, Jasmina, Mijin, Dušan, Ušćumlić, Gordana, Jovanović, Dušan M., Zlatar, Matija, Lončarević, Davor, "Spectroscopic and quantum chemical investigations of substituent effects on the azo-hydrazone tautomerism and acid-base properties of arylazo pyridone dyes" in Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 123 (2014):37-45,
https://doi.org/10.1016/j.saa.2013.12.064 . .
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Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite

Marinović, Sanja; Milutinović Nikolić, Aleksandra; Nastasović, Aleksandra; Žunić, Marija; Vuković, Zorica; Antonovic, Dusan G; Jovanović, Dušan M.

(Serbian Chemical Society, 2014)

TY  - JOUR
AU  - Marinović, Sanja
AU  - Milutinović Nikolić, Aleksandra
AU  - Nastasović, Aleksandra
AU  - Žunić, Marija
AU  - Vuković, Zorica
AU  - Antonovic, Dusan G
AU  - Jovanović, Dušan M.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5796
AB  - Macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite was prepared by radical suspension copolymerization. Nanocomposite was functionalized with diethylenetriamine (DETA), by ring-opening reaction of the pendant epoxy groups. Functionalization was performed in order to enable phenol derivatives sorption. This new, not sufficiently investigated material, with developed porous structure was denoted CP-S-A-DETA. In this study, the influence of temperature on 4-nitrophenol (4NP) sorption on CP-S-A-DETA was investigated. The chemisorption was estimated as dominant process since activation energy of sorption of 4NP of 54.8 kJ mol(-1) was obtained. After determining the optimal sorption conditions for 4NP, the sorption of 2-nitrophenol (2NP) and 2-chloro-4-nitrophenol (2Cl4NP) on CP-S-A-DETA was investigated with respect to pH, initial concentration and contact time. The 2NP sorption was seldom tested, while according to our knowledge, the 2Cl4NP sorption was not investigated. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model for all derivatives.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite
EP  - 1261
IS  - 10
SP  - 1249
VL  - 79
DO  - 10.2298/JSC140206043M
ER  - 
@article{
author = "Marinović, Sanja and Milutinović Nikolić, Aleksandra and Nastasović, Aleksandra and Žunić, Marija and Vuković, Zorica and Antonovic, Dusan G and Jovanović, Dušan M.",
year = "2014",
abstract = "Macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite was prepared by radical suspension copolymerization. Nanocomposite was functionalized with diethylenetriamine (DETA), by ring-opening reaction of the pendant epoxy groups. Functionalization was performed in order to enable phenol derivatives sorption. This new, not sufficiently investigated material, with developed porous structure was denoted CP-S-A-DETA. In this study, the influence of temperature on 4-nitrophenol (4NP) sorption on CP-S-A-DETA was investigated. The chemisorption was estimated as dominant process since activation energy of sorption of 4NP of 54.8 kJ mol(-1) was obtained. After determining the optimal sorption conditions for 4NP, the sorption of 2-nitrophenol (2NP) and 2-chloro-4-nitrophenol (2Cl4NP) on CP-S-A-DETA was investigated with respect to pH, initial concentration and contact time. The 2NP sorption was seldom tested, while according to our knowledge, the 2Cl4NP sorption was not investigated. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model for all derivatives.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite",
pages = "1261-1249",
number = "10",
volume = "79",
doi = "10.2298/JSC140206043M"
}
Marinović, S., Milutinović Nikolić, A., Nastasović, A., Žunić, M., Vuković, Z., Antonovic, D. G.,& Jovanović, D. M.. (2014). Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 79(10), 1249-1261.
https://doi.org/10.2298/JSC140206043M
Marinović S, Milutinović Nikolić A, Nastasović A, Žunić M, Vuković Z, Antonovic DG, Jovanović DM. Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite. in Journal of the Serbian Chemical Society. 2014;79(10):1249-1261.
doi:10.2298/JSC140206043M .
Marinović, Sanja, Milutinović Nikolić, Aleksandra, Nastasović, Aleksandra, Žunić, Marija, Vuković, Zorica, Antonovic, Dusan G, Jovanović, Dušan M., "Sorption of different phenol derivatives on a functionalized macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite" in Journal of the Serbian Chemical Society, 79, no. 10 (2014):1249-1261,
https://doi.org/10.2298/JSC140206043M . .
3
2
2

Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology

Dostanić, Jasmina; Lončarević, Davor; Rožić, Ljiljana; Petrović, Srđan; Mijin, Dušan; Jovanović, Dušan M.

(Desalination Publ, Hopkinton, 2013)

TY  - JOUR
AU  - Dostanić, Jasmina
AU  - Lončarević, Davor
AU  - Rožić, Ljiljana
AU  - Petrović, Srđan
AU  - Mijin, Dušan
AU  - Jovanović, Dušan M.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2517
AB  - Response surface methodology (RSM) and central composite design have been applied to describe and optimize photocatalytic degradation of azo pyridone dye using TiO2, H2O2, and simulated sun light. The mutual interactions between three independent variables, viz. H2O2 concentration, irradiation time, and TiO2 content were obtained. The results revealed that the most influential variables under selected reaction conditions were irradiation time and TiO2 content. The optimized conditions for the photocatalytic degradation of azo pyridone dye were as follows: H2O2 concentration: 130.5 mg/L, irradiation time: 54.8 min, and TiO2 content: 2.48 g/L. Under these conditions, the maximum decolorization efficiency of 96.43% was achieved. This experimental value was in good agreement with the predicted one, which proved the validity of the model. Operation cost analysis indicated that irradiation time had the major influence on total process cost. The RSM based on the central composite design was shown to be a successful technique for the optimization of the decolorization efficiency of azo pyridone dye and can be very helpful in improving the process economic feasibility. TOC analysis showed that the dye could be effectively mineralized during photocatalytic degradation.
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology
EP  - 2812
IS  - 13-15
SP  - 2802
VL  - 51
DO  - 10.1080/19443994.2012.750699
ER  - 
@article{
author = "Dostanić, Jasmina and Lončarević, Davor and Rožić, Ljiljana and Petrović, Srđan and Mijin, Dušan and Jovanović, Dušan M.",
year = "2013",
abstract = "Response surface methodology (RSM) and central composite design have been applied to describe and optimize photocatalytic degradation of azo pyridone dye using TiO2, H2O2, and simulated sun light. The mutual interactions between three independent variables, viz. H2O2 concentration, irradiation time, and TiO2 content were obtained. The results revealed that the most influential variables under selected reaction conditions were irradiation time and TiO2 content. The optimized conditions for the photocatalytic degradation of azo pyridone dye were as follows: H2O2 concentration: 130.5 mg/L, irradiation time: 54.8 min, and TiO2 content: 2.48 g/L. Under these conditions, the maximum decolorization efficiency of 96.43% was achieved. This experimental value was in good agreement with the predicted one, which proved the validity of the model. Operation cost analysis indicated that irradiation time had the major influence on total process cost. The RSM based on the central composite design was shown to be a successful technique for the optimization of the decolorization efficiency of azo pyridone dye and can be very helpful in improving the process economic feasibility. TOC analysis showed that the dye could be effectively mineralized during photocatalytic degradation.",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology",
pages = "2812-2802",
number = "13-15",
volume = "51",
doi = "10.1080/19443994.2012.750699"
}
Dostanić, J., Lončarević, D., Rožić, L., Petrović, S., Mijin, D.,& Jovanović, D. M.. (2013). Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 51(13-15), 2802-2812.
https://doi.org/10.1080/19443994.2012.750699
Dostanić J, Lončarević D, Rožić L, Petrović S, Mijin D, Jovanović DM. Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology. in Desalination and Water Treatment. 2013;51(13-15):2802-2812.
doi:10.1080/19443994.2012.750699 .
Dostanić, Jasmina, Lončarević, Davor, Rožić, Ljiljana, Petrović, Srđan, Mijin, Dušan, Jovanović, Dušan M., "Photocatalytic degradation of azo pyridone dye: Optimization using response surface methodology" in Desalination and Water Treatment, 51, no. 13-15 (2013):2802-2812,
https://doi.org/10.1080/19443994.2012.750699 . .
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28

Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst

Dokic, Marko; Kesic, Zeljka; Krstić, Jugoslav; Jovanović, Dušan M.; Skala, Dejan

(Elsevier Sci Ltd, Oxford, 2012)

TY  - JOUR
AU  - Dokic, Marko
AU  - Kesic, Zeljka
AU  - Krstić, Jugoslav
AU  - Jovanović, Dušan M.
AU  - Skala, Dejan
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5672
AB  - A difficulty of biodiesel synthesis based on alkaline catalysts obviously exists if free fatty acids (FFAs) content in vegetable oil is above 0.5 wt.%. In this study, the ferric sulfate supported on silica (Fe-2(SO4)(3)/SiO2) was synthesized, activated (at different temperature: 120-600 degrees C) and tested for heterogeneous esterification of FFA (oleic acid) present in sunflower oil (5 wt.%). The catalyst samples were characterized by BET, TG/DTG, XRD and FTIR analyses. Obtained results showed that catalyst activated at 500 degrees C for 2 h in air atmosphere gave the maximal conversion of oleic acid (similar to 97%). Repeated use of catalyst without additional catalyst treatment or re-activation indicated that catalyst posses desired stability and activity. A pseudo-homogeneous kinetic model was proposed with good agreement between calculated and experimental data.
PB  - Elsevier Sci Ltd, Oxford
T2  - Fuel
T1  - Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst
EP  - 602
SP  - 595
VL  - 97
DO  - 10.1016/j.fuel.2012.03.039
ER  - 
@article{
author = "Dokic, Marko and Kesic, Zeljka and Krstić, Jugoslav and Jovanović, Dušan M. and Skala, Dejan",
year = "2012",
abstract = "A difficulty of biodiesel synthesis based on alkaline catalysts obviously exists if free fatty acids (FFAs) content in vegetable oil is above 0.5 wt.%. In this study, the ferric sulfate supported on silica (Fe-2(SO4)(3)/SiO2) was synthesized, activated (at different temperature: 120-600 degrees C) and tested for heterogeneous esterification of FFA (oleic acid) present in sunflower oil (5 wt.%). The catalyst samples were characterized by BET, TG/DTG, XRD and FTIR analyses. Obtained results showed that catalyst activated at 500 degrees C for 2 h in air atmosphere gave the maximal conversion of oleic acid (similar to 97%). Repeated use of catalyst without additional catalyst treatment or re-activation indicated that catalyst posses desired stability and activity. A pseudo-homogeneous kinetic model was proposed with good agreement between calculated and experimental data.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Fuel",
title = "Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst",
pages = "602-595",
volume = "97",
doi = "10.1016/j.fuel.2012.03.039"
}
Dokic, M., Kesic, Z., Krstić, J., Jovanović, D. M.,& Skala, D.. (2012). Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst. in Fuel
Elsevier Sci Ltd, Oxford., 97, 595-602.
https://doi.org/10.1016/j.fuel.2012.03.039
Dokic M, Kesic Z, Krstić J, Jovanović DM, Skala D. Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst. in Fuel. 2012;97:595-602.
doi:10.1016/j.fuel.2012.03.039 .
Dokic, Marko, Kesic, Zeljka, Krstić, Jugoslav, Jovanović, Dušan M., Skala, Dejan, "Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst" in Fuel, 97 (2012):595-602,
https://doi.org/10.1016/j.fuel.2012.03.039 . .
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Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight

Dostanić, Jasmina; Lončarević, Davor; Banković, Predrag; Cvetković, Olga; Jovanović, Dušan M.; Mijin, Dušan

(Taylor & Francis Inc, Philadelphia, 2011)

TY  - JOUR
AU  - Dostanić, Jasmina
AU  - Lončarević, Davor
AU  - Banković, Predrag
AU  - Cvetković, Olga
AU  - Jovanović, Dušan M.
AU  - Mijin, Dušan
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1924
AB  - Photocatalytic degradation of synthesized azo pyridone dye (5-(4-sulpho phenylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridone), in aqueous solutions by simulated sunlight in the presence of commercial TiO2, Aeroxide P25, was studied. The reaction kinetics analysis showed that photodegradation exhibits pseudo first-order kinetics according to Langmuir-Hinshelwood model. The effects of various process parameters on the photocatalytic degradation were investigated. The optimal catalyst content and pH were determined. A decrease in the reaction rate was observed upon the increase of the initial dye concentration. Degradation of the dye was enhanced by hydrogen peroxide, but it was inhibited by ethanol. The influence of temperature was studied, and the energy of activation was determined. According to total organic carbon (TOC) analysis, 54% of TOC remained when 100% of the dye was decolorized. Although the intermediates were not determined in this study, the TOC results clearly indicate their presence during the reaction. In addition, photocatalytic degradation of simulated dyehouse effluents, containing tested azo pyridone dye and associated auxiliary chemicals was investigated.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine
T1  - Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight
EP  - 79
IS  - 1
SP  - 70
VL  - 46
DO  - 10.1080/10934529.2011.526905
ER  - 
@article{
author = "Dostanić, Jasmina and Lončarević, Davor and Banković, Predrag and Cvetković, Olga and Jovanović, Dušan M. and Mijin, Dušan",
year = "2011",
abstract = "Photocatalytic degradation of synthesized azo pyridone dye (5-(4-sulpho phenylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridone), in aqueous solutions by simulated sunlight in the presence of commercial TiO2, Aeroxide P25, was studied. The reaction kinetics analysis showed that photodegradation exhibits pseudo first-order kinetics according to Langmuir-Hinshelwood model. The effects of various process parameters on the photocatalytic degradation were investigated. The optimal catalyst content and pH were determined. A decrease in the reaction rate was observed upon the increase of the initial dye concentration. Degradation of the dye was enhanced by hydrogen peroxide, but it was inhibited by ethanol. The influence of temperature was studied, and the energy of activation was determined. According to total organic carbon (TOC) analysis, 54% of TOC remained when 100% of the dye was decolorized. Although the intermediates were not determined in this study, the TOC results clearly indicate their presence during the reaction. In addition, photocatalytic degradation of simulated dyehouse effluents, containing tested azo pyridone dye and associated auxiliary chemicals was investigated.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine",
title = "Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight",
pages = "79-70",
number = "1",
volume = "46",
doi = "10.1080/10934529.2011.526905"
}
Dostanić, J., Lončarević, D., Banković, P., Cvetković, O., Jovanović, D. M.,& Mijin, D.. (2011). Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight. in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine
Taylor & Francis Inc, Philadelphia., 46(1), 70-79.
https://doi.org/10.1080/10934529.2011.526905
Dostanić J, Lončarević D, Banković P, Cvetković O, Jovanović DM, Mijin D. Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight. in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine. 2011;46(1):70-79.
doi:10.1080/10934529.2011.526905 .
Dostanić, Jasmina, Lončarević, Davor, Banković, Predrag, Cvetković, Olga, Jovanović, Dušan M., Mijin, Dušan, "Influence of process parameters on the photodegradation of synthesized azo pyridone dye in TiO2 water suspension under simulated sunlight" in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine, 46, no. 1 (2011):70-79,
https://doi.org/10.1080/10934529.2011.526905 . .
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