@article{
author = "Milovanović, Željka and Lazarević, Slavica and Janković-Častvan, Ivona and Radovanović, Željko and Cvetković, Slobodan and Janaćković, Đorđe and Petrović, Rada",
year = "2023",
abstract = "The sepiolite/ZrO2 composites were prepared by sepiolite (Sep) modification with zirconium propoxide in toluene at room temperature for 24 h (Sep–ZrI) or 95 °C for 4 h (sample Sep–ZrII). The efficiency of the obtained composites for the removal of phosphate from aqueous solutions at initial pH = 4 and pH = 8 was investigated. Characterization of the samples shows that synthesis at a higher temperature for a shorter time provides a slightly higher content of amorphous Zr phase, which is deposited on the sepiolite fibers as a thin layer and agglomerated nanoparticles. Compared to Sep, the composites have a lower point of zero charge and higher specific surface area and pore volume. The adsorption kinetics follow the pseudo second-order model. The adsorption capacities of the composites are approximately the same at both initial pH and higher at initial pH = 4 than at pH = 8. The XPS and ATR-FTIR of Sep–ZrI before and after adsorption identifies the formation of inner-sphere complexes as the mechanism of phosphate adsorption. The slow release during desorption with NaOH solution confirms the strong bonds of the phosphates with the surface of the composites.",
publisher = "MDPI",
journal = "Water",
title = "The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism",
number = "13",
pages = "2376",
volume = "15",
doi = "10.3390/w15132376"
}