Sekulić, Zoran

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orcid::0000-0002-6858-9304
  • Sekulić, Zoran (6)
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Author's Bibliography

Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia

Crnković, Dragan; Sekulić, Zoran; Antonović, Dušan; Marinković, Aleksandar; Popović, Slađana; Nikolić, Jasmina; Drmanić, Saša

(Hard, Olsztyn 5, 2020)

TY  - JOUR
AU  - Crnković, Dragan
AU  - Sekulić, Zoran
AU  - Antonović, Dušan
AU  - Marinković, Aleksandar
AU  - Popović, Slađana
AU  - Nikolić, Jasmina
AU  - Drmanić, Saša
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4460
AB  - This study focussed on a comprehensive investigation on the state of pollution and identification of potential sources of contamination of some river sediments in Serbia by polycyclic aromatic hydrocarbons (PAHs), and is the basis for setting up further monitoring programs. The sediment quality of the Danube River (km 1433-845) and its tributaries in Serbia, including the Sava River (km 202-1), were analysed with respect to PAHs and total organic carbon (TOC). We found that total PAH concentration in the sediments from the Danube and its tributaries (10.0-4140 mu g kg(-1)) was lower than total PAH concentration in Sava River sediments (265.1-11272 mu g kg(-1)). Principal component analysis showed that concentrations of benzo[a]anthracene, chrysene, pyrene, fluoranthene, indeno[1,2,3- cd]pyrene, benzo[a] pyrene, benzo[b]fluoranthene and benzo[k]fluoranthene in the sediments were correlated with TOC. The diagnostic ratios anthracene/(anthracene+phenanthrene) and fluoranthene/(fluoranthene+ pyrene) were calculated to evaluate the emission sources of the PAHs. Therefore, these ratios indicated the predominantly pyrogenic source of the PAHs in the sediments. Results have also shown that river sediments in the Danube and Sava rivers and their tributaries were not recently polluted with PAHs, excluding only one location - S4, downstream of Sabac and characterized by heavily polluted sediment.
PB  - Hard, Olsztyn 5
T2  - Polish Journal of Environmental Studies
T1  - Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia
EP  - 2110
IS  - 3
SP  - 2101
VL  - 29
DO  - 10.15244/pjoes/111319
ER  - 
@article{
author = "Crnković, Dragan and Sekulić, Zoran and Antonović, Dušan and Marinković, Aleksandar and Popović, Slađana and Nikolić, Jasmina and Drmanić, Saša",
year = "2020",
abstract = "This study focussed on a comprehensive investigation on the state of pollution and identification of potential sources of contamination of some river sediments in Serbia by polycyclic aromatic hydrocarbons (PAHs), and is the basis for setting up further monitoring programs. The sediment quality of the Danube River (km 1433-845) and its tributaries in Serbia, including the Sava River (km 202-1), were analysed with respect to PAHs and total organic carbon (TOC). We found that total PAH concentration in the sediments from the Danube and its tributaries (10.0-4140 mu g kg(-1)) was lower than total PAH concentration in Sava River sediments (265.1-11272 mu g kg(-1)). Principal component analysis showed that concentrations of benzo[a]anthracene, chrysene, pyrene, fluoranthene, indeno[1,2,3- cd]pyrene, benzo[a] pyrene, benzo[b]fluoranthene and benzo[k]fluoranthene in the sediments were correlated with TOC. The diagnostic ratios anthracene/(anthracene+phenanthrene) and fluoranthene/(fluoranthene+ pyrene) were calculated to evaluate the emission sources of the PAHs. Therefore, these ratios indicated the predominantly pyrogenic source of the PAHs in the sediments. Results have also shown that river sediments in the Danube and Sava rivers and their tributaries were not recently polluted with PAHs, excluding only one location - S4, downstream of Sabac and characterized by heavily polluted sediment.",
publisher = "Hard, Olsztyn 5",
journal = "Polish Journal of Environmental Studies",
title = "Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia",
pages = "2110-2101",
number = "3",
volume = "29",
doi = "10.15244/pjoes/111319"
}
Crnković, D., Sekulić, Z., Antonović, D., Marinković, A., Popović, S., Nikolić, J.,& Drmanić, S.. (2020). Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia. in Polish Journal of Environmental Studies
Hard, Olsztyn 5., 29(3), 2101-2110.
https://doi.org/10.15244/pjoes/111319
Crnković D, Sekulić Z, Antonović D, Marinković A, Popović S, Nikolić J, Drmanić S. Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia. in Polish Journal of Environmental Studies. 2020;29(3):2101-2110.
doi:10.15244/pjoes/111319 .
Crnković, Dragan, Sekulić, Zoran, Antonović, Dušan, Marinković, Aleksandar, Popović, Slađana, Nikolić, Jasmina, Drmanić, Saša, "Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia" in Polish Journal of Environmental Studies, 29, no. 3 (2020):2101-2110,
https://doi.org/10.15244/pjoes/111319 . .
15
4
11

The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach

Sekulić, Zoran; Antanasijević, Davor; Stevanović, Slavica; Trivunac, Katarina

(Springer International Publishing Ag, Cham, 2019)

TY  - JOUR
AU  - Sekulić, Zoran
AU  - Antanasijević, Davor
AU  - Stevanović, Slavica
AU  - Trivunac, Katarina
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4323
AB  - Membrane filtration techniques are distinguished among methods for wastewater treatment and fully correspond to the requirements of the green concept of chemistry and production. The limiting factor for greater application of these methods is the phenomenon of fouling and the decline of the permeate flux. In this study, polynomial neural network based on group method data handling (GMDH) algorithm was applied to predict the performance of the complexation-microfiltration process for the removal of Pb(II), Zn(II), and Cd(II) from synthetic wastewater. The influence of working parameters such as pH, initial concentration of metal ions, type of complexing agent, and pressure on flux was experimentally determined. The data obtained were used as input parameters for the GMDH model as well as for the multiple linear regression (MLR) model. Root mean square error (RMSE), mean absolute error (MAE), and mean absolute percent error (MAPE) were used for evaluation purposes. Results showed that the developed model has excellent performance in flux prediction with R-2 of 0.9648.
PB  - Springer International Publishing Ag, Cham
T2  - Water Air and Soil Pollution
T1  - The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach
IS  - 1
VL  - 230
DO  - 10.1007/s11270-018-4072-y
ER  - 
@article{
author = "Sekulić, Zoran and Antanasijević, Davor and Stevanović, Slavica and Trivunac, Katarina",
year = "2019",
abstract = "Membrane filtration techniques are distinguished among methods for wastewater treatment and fully correspond to the requirements of the green concept of chemistry and production. The limiting factor for greater application of these methods is the phenomenon of fouling and the decline of the permeate flux. In this study, polynomial neural network based on group method data handling (GMDH) algorithm was applied to predict the performance of the complexation-microfiltration process for the removal of Pb(II), Zn(II), and Cd(II) from synthetic wastewater. The influence of working parameters such as pH, initial concentration of metal ions, type of complexing agent, and pressure on flux was experimentally determined. The data obtained were used as input parameters for the GMDH model as well as for the multiple linear regression (MLR) model. Root mean square error (RMSE), mean absolute error (MAE), and mean absolute percent error (MAPE) were used for evaluation purposes. Results showed that the developed model has excellent performance in flux prediction with R-2 of 0.9648.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Water Air and Soil Pollution",
title = "The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach",
number = "1",
volume = "230",
doi = "10.1007/s11270-018-4072-y"
}
Sekulić, Z., Antanasijević, D., Stevanović, S.,& Trivunac, K.. (2019). The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach. in Water Air and Soil Pollution
Springer International Publishing Ag, Cham., 230(1).
https://doi.org/10.1007/s11270-018-4072-y
Sekulić Z, Antanasijević D, Stevanović S, Trivunac K. The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach. in Water Air and Soil Pollution. 2019;230(1).
doi:10.1007/s11270-018-4072-y .
Sekulić, Zoran, Antanasijević, Davor, Stevanović, Slavica, Trivunac, Katarina, "The Prediction of Heavy Metal Permeate Flux in Complexation-Microfiltration Process: Polynomial Neural Network Approach" in Water Air and Soil Pollution, 230, no. 1 (2019),
https://doi.org/10.1007/s11270-018-4072-y . .
10
4
8

Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process

Sekulić, Zoran; Antanasijević, Davor; Stevanović, S.; Trivunac, Katarina

(Springer, New York, 2017)

TY  - JOUR
AU  - Sekulić, Zoran
AU  - Antanasijević, Davor
AU  - Stevanović, S.
AU  - Trivunac, Katarina
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3722
AB  - Complexation-microfiltration process for removal of heavy metal ions such as lead, cadmium and zinc from water had been investigated. Two soluble derivates of cellulose was selected as complexing agents. The dependence of the removal efficiency from the operating parameters (pH value, pressure, concentration of metal ion, concentration of complexing agent and type of counter ion) was established. Two approaches of preparation of input data and two different artificial neural network architectures, general regression neural network and back-propagation neural network have been used for modeling of experimental data. The extrapolation ability of selected architectures, i.e., the prediction of rejection coefficient with inputs beyond the calibration range of original model, was also determined. The predictions were successful, and after evaluation of performances, the models that were developed gave relatively good results of mean absolute percentage error from 4 to 14% and R-squared from 0.717 to 0.852 for general regression neural network and from 0.897 to 0.955 for back-propagation neural network.
PB  - Springer, New York
T2  - International Journal of Environmental Science and Technology
T1  - Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process
EP  - 1396
IS  - 7
SP  - 1383
VL  - 14
DO  - 10.1007/s13762-017-1248-8
ER  - 
@article{
author = "Sekulić, Zoran and Antanasijević, Davor and Stevanović, S. and Trivunac, Katarina",
year = "2017",
abstract = "Complexation-microfiltration process for removal of heavy metal ions such as lead, cadmium and zinc from water had been investigated. Two soluble derivates of cellulose was selected as complexing agents. The dependence of the removal efficiency from the operating parameters (pH value, pressure, concentration of metal ion, concentration of complexing agent and type of counter ion) was established. Two approaches of preparation of input data and two different artificial neural network architectures, general regression neural network and back-propagation neural network have been used for modeling of experimental data. The extrapolation ability of selected architectures, i.e., the prediction of rejection coefficient with inputs beyond the calibration range of original model, was also determined. The predictions were successful, and after evaluation of performances, the models that were developed gave relatively good results of mean absolute percentage error from 4 to 14% and R-squared from 0.717 to 0.852 for general regression neural network and from 0.897 to 0.955 for back-propagation neural network.",
publisher = "Springer, New York",
journal = "International Journal of Environmental Science and Technology",
title = "Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process",
pages = "1396-1383",
number = "7",
volume = "14",
doi = "10.1007/s13762-017-1248-8"
}
Sekulić, Z., Antanasijević, D., Stevanović, S.,& Trivunac, K.. (2017). Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process. in International Journal of Environmental Science and Technology
Springer, New York., 14(7), 1383-1396.
https://doi.org/10.1007/s13762-017-1248-8
Sekulić Z, Antanasijević D, Stevanović S, Trivunac K. Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process. in International Journal of Environmental Science and Technology. 2017;14(7):1383-1396.
doi:10.1007/s13762-017-1248-8 .
Sekulić, Zoran, Antanasijević, Davor, Stevanović, S., Trivunac, Katarina, "Application of artificial neural networks for estimating Cd, Zn, Pb removal efficiency from wastewater using complexation-microfiltration process" in International Journal of Environmental Science and Technology, 14, no. 7 (2017):1383-1396,
https://doi.org/10.1007/s13762-017-1248-8 . .
12
7
13

Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade

Deljanin, Isidora; Antanasijević, Davor; Urošević-Aničić, M.; Tomašević, M.; Sekulić, Zoran; Perić-Grujić, Aleksandra; Ristić, M.

(Association of the Chemical Engineers of Serbia, 2015)

TY  - JOUR
AU  - Deljanin, Isidora
AU  - Antanasijević, Davor
AU  - Urošević-Aničić, M.
AU  - Tomašević, M.
AU  - Sekulić, Zoran
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, M.
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2909
AB  - In this study, airborne particulates (PM10) and leaves of horse chestnut were collected at selected urban sites in Belgrade, Serbia, in years 2006, 2009 and 2012. All samples were analysed for trace element concentrations of As, Cd, Cr, Ni and Pb. It was found that, during the study period, the differences among PM10 mass trace element concentrations were not considerable, and that the measured mass and trace elements concentrations were below the Serbian and EU legislation limits. The highest values of trace element concentrations in leaves were observed in year 2012, with the exception of Pb. Lead concentration had a decreasing trend during the whole studied period, in both PM10 and tree leaves. Since leaded gasoline was banned in 2011, a possible reason could be an increasing number of vehicles using unleaded kind along the previous years. Although trace elements in horse chestnut leaves were accumulated only during the summer season, horse chestnut leaves showed good response to changes in trace element atmospheric concentrations. However, seasonal variability was evident in trace element source apportionment due to the lack of stationary heating system influence. The principal component analysis showed that during the studied period, one of the major sources of the measured elements was fossil fuel combustion.
AB  - U ovom radu određivane su koncentracije elemenata u tragovima, As, Cd, Cr, Ni i Pb u česticama iz vazduha (PM10) i listovima divljeg kestena sakupljenim na odabranim lokacijama u centru Beograda, tokom 2006., 2009., i 2012. godine. Utvrđeno je da razlike u koncentracijama elemenata u tragovima u uzorcima PM10 nisu bile značajne, i da su, tokom posmatranog perioda, bile ispod dozvoljenih granica propisanih od strane Republike Srbije i Evropske Unije. Najviše koncentracije ispitivanih elemenata u listovima su zabeležene u 2012. godini, osim u slučaju olova. Koncentracija olova je imala opadajući trend, i u česticama i u listovima, tokom celog ispitivanog perioda, verovatno zbog povećanja broja vozila koja koriste bezolovni benzin, s obzirom na to da je upotreba olovnog benzina zabranjena početkom 2011. godine. Iako se elementi u tragovima u listovima divljeg kestena akumuliraju samo tokom letnjeg perioda, koncentracije ispitivanih elemenata u listovima su bile u korelaciji sa promenama koncentracija elemenata u vazduhu. Ipak, uočljiva je sezonska varijacija koncentracija elemenata usled nedostatka uticaja stacionarnog grejanja tokom leta. Analiza glavnih komponenti je pokazala da je, tokom posmatranog perioda, jedan od glavnih izvora ispitivanih elemenata bilo sagorevanje fosilnih goriva.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade
T1  - Koncentracije odabranih elemenata u tragovima u vazduhu i u listovima divljeg kestena u Beogradu
EP  - 178
IS  - 1-2
SP  - 169
VL  - 21
DO  - 10.2298/CICEQ131216019D
ER  - 
@article{
author = "Deljanin, Isidora and Antanasijević, Davor and Urošević-Aničić, M. and Tomašević, M. and Sekulić, Zoran and Perić-Grujić, Aleksandra and Ristić, M.",
year = "2015",
abstract = "In this study, airborne particulates (PM10) and leaves of horse chestnut were collected at selected urban sites in Belgrade, Serbia, in years 2006, 2009 and 2012. All samples were analysed for trace element concentrations of As, Cd, Cr, Ni and Pb. It was found that, during the study period, the differences among PM10 mass trace element concentrations were not considerable, and that the measured mass and trace elements concentrations were below the Serbian and EU legislation limits. The highest values of trace element concentrations in leaves were observed in year 2012, with the exception of Pb. Lead concentration had a decreasing trend during the whole studied period, in both PM10 and tree leaves. Since leaded gasoline was banned in 2011, a possible reason could be an increasing number of vehicles using unleaded kind along the previous years. Although trace elements in horse chestnut leaves were accumulated only during the summer season, horse chestnut leaves showed good response to changes in trace element atmospheric concentrations. However, seasonal variability was evident in trace element source apportionment due to the lack of stationary heating system influence. The principal component analysis showed that during the studied period, one of the major sources of the measured elements was fossil fuel combustion., U ovom radu određivane su koncentracije elemenata u tragovima, As, Cd, Cr, Ni i Pb u česticama iz vazduha (PM10) i listovima divljeg kestena sakupljenim na odabranim lokacijama u centru Beograda, tokom 2006., 2009., i 2012. godine. Utvrđeno je da razlike u koncentracijama elemenata u tragovima u uzorcima PM10 nisu bile značajne, i da su, tokom posmatranog perioda, bile ispod dozvoljenih granica propisanih od strane Republike Srbije i Evropske Unije. Najviše koncentracije ispitivanih elemenata u listovima su zabeležene u 2012. godini, osim u slučaju olova. Koncentracija olova je imala opadajući trend, i u česticama i u listovima, tokom celog ispitivanog perioda, verovatno zbog povećanja broja vozila koja koriste bezolovni benzin, s obzirom na to da je upotreba olovnog benzina zabranjena početkom 2011. godine. Iako se elementi u tragovima u listovima divljeg kestena akumuliraju samo tokom letnjeg perioda, koncentracije ispitivanih elemenata u listovima su bile u korelaciji sa promenama koncentracija elemenata u vazduhu. Ipak, uočljiva je sezonska varijacija koncentracija elemenata usled nedostatka uticaja stacionarnog grejanja tokom leta. Analiza glavnih komponenti je pokazala da je, tokom posmatranog perioda, jedan od glavnih izvora ispitivanih elemenata bilo sagorevanje fosilnih goriva.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade, Koncentracije odabranih elemenata u tragovima u vazduhu i u listovima divljeg kestena u Beogradu",
pages = "178-169",
number = "1-2",
volume = "21",
doi = "10.2298/CICEQ131216019D"
}
Deljanin, I., Antanasijević, D., Urošević-Aničić, M., Tomašević, M., Sekulić, Z., Perić-Grujić, A.,& Ristić, M.. (2015). Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 21(1-2), 169-178.
https://doi.org/10.2298/CICEQ131216019D
Deljanin I, Antanasijević D, Urošević-Aničić M, Tomašević M, Sekulić Z, Perić-Grujić A, Ristić M. Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade. in Chemical Industry & Chemical Engineering Quarterly. 2015;21(1-2):169-178.
doi:10.2298/CICEQ131216019D .
Deljanin, Isidora, Antanasijević, Davor, Urošević-Aničić, M., Tomašević, M., Sekulić, Zoran, Perić-Grujić, Aleksandra, Ristić, M., "Selected trace element concentrations in ambient air and in horse chestnut leaves in Belgrade" in Chemical Industry & Chemical Engineering Quarterly, 21, no. 1-2 (2015):169-178,
https://doi.org/10.2298/CICEQ131216019D . .
1

Traffic-related trace element concentrations in PM10 and horse chestnut leaves

Deljanin, Isidora; Antanasijević, Davor; Aničić Urošević, Mira; Tomašević, Milica; Sekulić, Zoran; Perić-Grujić, Aleksandra; Ristić, Mirjana

(Belgrade : Public Health Institute, 2013)

TY  - CONF
AU  - Deljanin, Isidora
AU  - Antanasijević, Davor
AU  - Aničić Urošević, Mira
AU  - Tomašević, Milica
AU  - Sekulić, Zoran
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7339
AB  - Urban environment is heavily impacted by airborne particulates originated from fossil fuel
combustion, traffic, industry and other anthropogenic activities. Trace elements, attached to PM10,
can be toxic and may have dangerousimpacts on human health. The assessment of the trace element
content of PM10 gives important information for development of risk assessment strategies. In the
past decades, biomonitoring of air quality using plantshas been widely usedto detect and monitor
trace and other element atmospheric contamination (Bargagli 1998; Markert, 1993).Previousstudies
have shown that horse chestnut leaves could be valuabletools for monitoring trace elementsin the
atmosphere (Aničić, 2011; Šućur, 2010; Tomašević, 2011). The objective of this study was to
obtain data of the temporal variability of PM10 mass concentrations and traffic-related trace
element contentin PM10 and tree leaves samples collected from year 2006 to 2012. It was a
transition period when gasoline with lead-alkyl additives was replaced with unleaded kind, with the
complete ban of the leaded gasoline in the beginning of 2011.
PB  - Belgrade : Public Health Institute
C3  - Abstracts of Keynote Invited Lectures and Contributed Papers / The Fourth International WeBIOPATR Workshop & Conference Particulate Matter: Research and Management, WeBIOPATR2013, Belgrade, October 2nd-4th, 2013
T1  - Traffic-related trace element concentrations in PM10 and horse chestnut leaves
SP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7339
ER  - 
@conference{
author = "Deljanin, Isidora and Antanasijević, Davor and Aničić Urošević, Mira and Tomašević, Milica and Sekulić, Zoran and Perić-Grujić, Aleksandra and Ristić, Mirjana",
year = "2013",
abstract = "Urban environment is heavily impacted by airborne particulates originated from fossil fuel
combustion, traffic, industry and other anthropogenic activities. Trace elements, attached to PM10,
can be toxic and may have dangerousimpacts on human health. The assessment of the trace element
content of PM10 gives important information for development of risk assessment strategies. In the
past decades, biomonitoring of air quality using plantshas been widely usedto detect and monitor
trace and other element atmospheric contamination (Bargagli 1998; Markert, 1993).Previousstudies
have shown that horse chestnut leaves could be valuabletools for monitoring trace elementsin the
atmosphere (Aničić, 2011; Šućur, 2010; Tomašević, 2011). The objective of this study was to
obtain data of the temporal variability of PM10 mass concentrations and traffic-related trace
element contentin PM10 and tree leaves samples collected from year 2006 to 2012. It was a
transition period when gasoline with lead-alkyl additives was replaced with unleaded kind, with the
complete ban of the leaded gasoline in the beginning of 2011.",
publisher = "Belgrade : Public Health Institute",
journal = "Abstracts of Keynote Invited Lectures and Contributed Papers / The Fourth International WeBIOPATR Workshop & Conference Particulate Matter: Research and Management, WeBIOPATR2013, Belgrade, October 2nd-4th, 2013",
title = "Traffic-related trace element concentrations in PM10 and horse chestnut leaves",
pages = "52",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7339"
}
Deljanin, I., Antanasijević, D., Aničić Urošević, M., Tomašević, M., Sekulić, Z., Perić-Grujić, A.,& Ristić, M.. (2013). Traffic-related trace element concentrations in PM10 and horse chestnut leaves. in Abstracts of Keynote Invited Lectures and Contributed Papers / The Fourth International WeBIOPATR Workshop & Conference Particulate Matter: Research and Management, WeBIOPATR2013, Belgrade, October 2nd-4th, 2013
Belgrade : Public Health Institute., 52.
https://hdl.handle.net/21.15107/rcub_technorep_7339
Deljanin I, Antanasijević D, Aničić Urošević M, Tomašević M, Sekulić Z, Perić-Grujić A, Ristić M. Traffic-related trace element concentrations in PM10 and horse chestnut leaves. in Abstracts of Keynote Invited Lectures and Contributed Papers / The Fourth International WeBIOPATR Workshop & Conference Particulate Matter: Research and Management, WeBIOPATR2013, Belgrade, October 2nd-4th, 2013. 2013;:52.
https://hdl.handle.net/21.15107/rcub_technorep_7339 .
Deljanin, Isidora, Antanasijević, Davor, Aničić Urošević, Mira, Tomašević, Milica, Sekulić, Zoran, Perić-Grujić, Aleksandra, Ristić, Mirjana, "Traffic-related trace element concentrations in PM10 and horse chestnut leaves" in Abstracts of Keynote Invited Lectures and Contributed Papers / The Fourth International WeBIOPATR Workshop & Conference Particulate Matter: Research and Management, WeBIOPATR2013, Belgrade, October 2nd-4th, 2013 (2013):52,
https://hdl.handle.net/21.15107/rcub_technorep_7339 .

Zinc removal from wastewater by a complexation-microfiltration process

Trivunac, Katarina; Sekulić, Zoran; Stevanović, Slavica

(Serbian Chemical Society, Belgrade, 2012)

TY  - JOUR
AU  - Trivunac, Katarina
AU  - Sekulić, Zoran
AU  - Stevanović, Slavica
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2088
AB  - Due to its wide industrial applications, zinc has become an important contaminant in aquatic environments since it is a toxic heavy metal and some of its compounds, such as zinc arsenate and zinc cyanide, may be extremely hazardous. Therefore, there is a growing need to develop simple methods capable of separating and recovering trace zinc from environmental waters. Nowadays, ultra- and microfiltration methods for trace metals removal from waters by the addition of a water-soluble polymer into the aqueous solutions have become a significant area of research. The choice of water-soluble macroligands remains important for the development of this technology. Sodium carboxymethyl cellulose (Na-CMC) was selected as the complexing agent. The microfiltration experiments were performed in a stirred dead-end cell. Versapor membranes were used to separate the formed polymer-metal complex. The concentration of heavy metal ions after microfiltration in aqueous solution was determined using atomic absorption spectroscopy (AAS). The effects of the amount of complexing agent, pH value, type of anion, ionic strength and operating pressure on the flux (J) and rejection coefficient (R) were investigated. Experimental results indicate a considerable influence of the pH, ionic strength and type of anion on the rejection coefficient, while the effect of the amount of the complexing agent was relatively insignificant. The Na-CMC used in the research proved very effective, which is supported by the high rejection coefficients obtained (99%).
AB  - Kao rezultat njegove široke industrijske primene, cink i njegova jedinjenja su postali značajne zagađujuće materije vodenih resursa. Zbog toga je postalo neophodno razvijati nove metode za njihovo uklanjanje, koje bi bile efikasne, jednostavne i neškodljive po životnu sredinu. Među njima, metoda membranske filtracije se pokazala kao veoma uspešna za uklanjanje različitih zagađujućih materija, posebno u kombinaciji sa makromolekulima. Veliki broj istraživanja usmeren je na izbor selektivnog i specifičnog makromolekula. U radu je proučavan kompleksirajuće-filtracioni proces za uklanjanje jona cinka pomoću natrijum-karboksimetil celuloze. Mikrofiltracija je vršena u ćeliji sa mešanjem. Separacija formiranih kompleksa je vršena na Versapor mikrofiltracionim membranama. Koncentracija jona metala posle mikrofiltracije je određena atomskom apsorpcionom spektroskopijom. Ispitani su uticaji količine kompleksirajućeg sredstva, pH vrednosti rastvora, radnog pritiska, jonske jačine i anjona na fluks i koeficijent zadržavanja. Eksperimentalni rezultati su pokazali značajan uticaj pH, jonske jačine i anjona na koeficijent zadržavanja, dok koncentracija kompleksirajućeg sredstva nije imala značajan uticaj na proces. Natrijum karboksimetil celuloza se pokazala kao uspešno sredstvo za uklanjanje jona cinka što se može zaključiti na osnovu postignutog veoma visokog koeficijenta zadržavanja jona cinka od 99 %.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Zinc removal from wastewater by a complexation-microfiltration process
T1  - Uklanjanje cinka iz otpadnih voda kompleksirajuće-mikrofiltracionim procesom
EP  - 1670
IS  - 11
SP  - 1661
VL  - 77
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2088
ER  - 
@article{
author = "Trivunac, Katarina and Sekulić, Zoran and Stevanović, Slavica",
year = "2012",
abstract = "Due to its wide industrial applications, zinc has become an important contaminant in aquatic environments since it is a toxic heavy metal and some of its compounds, such as zinc arsenate and zinc cyanide, may be extremely hazardous. Therefore, there is a growing need to develop simple methods capable of separating and recovering trace zinc from environmental waters. Nowadays, ultra- and microfiltration methods for trace metals removal from waters by the addition of a water-soluble polymer into the aqueous solutions have become a significant area of research. The choice of water-soluble macroligands remains important for the development of this technology. Sodium carboxymethyl cellulose (Na-CMC) was selected as the complexing agent. The microfiltration experiments were performed in a stirred dead-end cell. Versapor membranes were used to separate the formed polymer-metal complex. The concentration of heavy metal ions after microfiltration in aqueous solution was determined using atomic absorption spectroscopy (AAS). The effects of the amount of complexing agent, pH value, type of anion, ionic strength and operating pressure on the flux (J) and rejection coefficient (R) were investigated. Experimental results indicate a considerable influence of the pH, ionic strength and type of anion on the rejection coefficient, while the effect of the amount of the complexing agent was relatively insignificant. The Na-CMC used in the research proved very effective, which is supported by the high rejection coefficients obtained (99%)., Kao rezultat njegove široke industrijske primene, cink i njegova jedinjenja su postali značajne zagađujuće materije vodenih resursa. Zbog toga je postalo neophodno razvijati nove metode za njihovo uklanjanje, koje bi bile efikasne, jednostavne i neškodljive po životnu sredinu. Među njima, metoda membranske filtracije se pokazala kao veoma uspešna za uklanjanje različitih zagađujućih materija, posebno u kombinaciji sa makromolekulima. Veliki broj istraživanja usmeren je na izbor selektivnog i specifičnog makromolekula. U radu je proučavan kompleksirajuće-filtracioni proces za uklanjanje jona cinka pomoću natrijum-karboksimetil celuloze. Mikrofiltracija je vršena u ćeliji sa mešanjem. Separacija formiranih kompleksa je vršena na Versapor mikrofiltracionim membranama. Koncentracija jona metala posle mikrofiltracije je određena atomskom apsorpcionom spektroskopijom. Ispitani su uticaji količine kompleksirajućeg sredstva, pH vrednosti rastvora, radnog pritiska, jonske jačine i anjona na fluks i koeficijent zadržavanja. Eksperimentalni rezultati su pokazali značajan uticaj pH, jonske jačine i anjona na koeficijent zadržavanja, dok koncentracija kompleksirajućeg sredstva nije imala značajan uticaj na proces. Natrijum karboksimetil celuloza se pokazala kao uspešno sredstvo za uklanjanje jona cinka što se može zaključiti na osnovu postignutog veoma visokog koeficijenta zadržavanja jona cinka od 99 %.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Zinc removal from wastewater by a complexation-microfiltration process, Uklanjanje cinka iz otpadnih voda kompleksirajuće-mikrofiltracionim procesom",
pages = "1670-1661",
number = "11",
volume = "77",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2088"
}
Trivunac, K., Sekulić, Z.,& Stevanović, S.. (2012). Zinc removal from wastewater by a complexation-microfiltration process. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 77(11), 1661-1670.
https://hdl.handle.net/21.15107/rcub_technorep_2088
Trivunac K, Sekulić Z, Stevanović S. Zinc removal from wastewater by a complexation-microfiltration process. in Journal of the Serbian Chemical Society. 2012;77(11):1661-1670.
https://hdl.handle.net/21.15107/rcub_technorep_2088 .
Trivunac, Katarina, Sekulić, Zoran, Stevanović, Slavica, "Zinc removal from wastewater by a complexation-microfiltration process" in Journal of the Serbian Chemical Society, 77, no. 11 (2012):1661-1670,
https://hdl.handle.net/21.15107/rcub_technorep_2088 .
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