Mirković, Miljana

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  • Mirković, Miljana (2)

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Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin

Mladenović Nikolić, Nataša; Knežević, Sanja; Ivanović, Marija; Mirković, Miljana; Maletić, Marina; Kljajević, Ljiljana; Trivunac, Katarina

(Skopje : Society of Chemists and Technologists of Macedonia, 2023)

TY  - CONF
AU  - Mladenović Nikolić, Nataša
AU  - Knežević, Sanja
AU  - Ivanović, Marija
AU  - Mirković, Miljana
AU  - Maletić, Marina
AU  - Kljajević, Ljiljana
AU  - Trivunac, Katarina
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6641
AB  - The aim of this paper is to show the possibility of using waste materials, blends of (wood ash, fly ash, from thermal power plant, and metakaolin) for the production of alkali activated materials that can be used to purify wastewater from different kinds of pollutants such as heavy metals. Heavy metals are toxic, especially cadmium, so they must be removed from wastewater to prevent or minimize contact with the environment and humans. The synthesis of the alkali activated materials was performed by mixing solid precursors with a liquid alkali activator. Two- and three-component systems of wood ash, fly ash and metakaolin (wood ash/fly ash, wood ash/metakaolin, fly ash/metakaolin and wood ash/fly ash/metakaolin) were used as precursor materials. The alkali activator solution was a mixture of sodium silicate solution and sodium hydroxide solution of concentrations (6M and 12M). The characterization of alkali activated materials was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS). XRD measurements of investigated samples showed a characteristic halo between 18 and 35º 2 with a dominant crystal phase of quartz. FTIR spectroscopy showed that the main vibration band of all investigated samples appeared between 1037-996 cm-1, and corresponds to Si-O-Si/Si-O-Al bands. SEM/EDS analysis was used to determine the microstructure of the samples. The adsorption efficiency of the investigated alkali activated materials for removing cadmium ions from aqueous solution was tested under different conditions: initial concentration of cadmium ions in the range of 20-100 mg/l, pH values from 3 to 7 and mass of adsorbents from 0.02-0.05 g.
PB  - Skopje : Society of Chemists and Technologists of Macedonia
C3  - Book of abstracts / 26th Congress of SCTM with international participation 20–23 September 2023 Metropol Lake Resort Ohrid, R. Macedonia
T1  - Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin
SP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6641
ER  - 
@conference{
author = "Mladenović Nikolić, Nataša and Knežević, Sanja and Ivanović, Marija and Mirković, Miljana and Maletić, Marina and Kljajević, Ljiljana and Trivunac, Katarina",
year = "2023",
abstract = "The aim of this paper is to show the possibility of using waste materials, blends of (wood ash, fly ash, from thermal power plant, and metakaolin) for the production of alkali activated materials that can be used to purify wastewater from different kinds of pollutants such as heavy metals. Heavy metals are toxic, especially cadmium, so they must be removed from wastewater to prevent or minimize contact with the environment and humans. The synthesis of the alkali activated materials was performed by mixing solid precursors with a liquid alkali activator. Two- and three-component systems of wood ash, fly ash and metakaolin (wood ash/fly ash, wood ash/metakaolin, fly ash/metakaolin and wood ash/fly ash/metakaolin) were used as precursor materials. The alkali activator solution was a mixture of sodium silicate solution and sodium hydroxide solution of concentrations (6M and 12M). The characterization of alkali activated materials was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS). XRD measurements of investigated samples showed a characteristic halo between 18 and 35º 2 with a dominant crystal phase of quartz. FTIR spectroscopy showed that the main vibration band of all investigated samples appeared between 1037-996 cm-1, and corresponds to Si-O-Si/Si-O-Al bands. SEM/EDS analysis was used to determine the microstructure of the samples. The adsorption efficiency of the investigated alkali activated materials for removing cadmium ions from aqueous solution was tested under different conditions: initial concentration of cadmium ions in the range of 20-100 mg/l, pH values from 3 to 7 and mass of adsorbents from 0.02-0.05 g.",
publisher = "Skopje : Society of Chemists and Technologists of Macedonia",
journal = "Book of abstracts / 26th Congress of SCTM with international participation 20–23 September 2023 Metropol Lake Resort Ohrid, R. Macedonia",
title = "Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin",
pages = "29",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6641"
}
Mladenović Nikolić, N., Knežević, S., Ivanović, M., Mirković, M., Maletić, M., Kljajević, L.,& Trivunac, K.. (2023). Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin. in Book of abstracts / 26th Congress of SCTM with international participation 20–23 September 2023 Metropol Lake Resort Ohrid, R. Macedonia
Skopje : Society of Chemists and Technologists of Macedonia., 29.
https://hdl.handle.net/21.15107/rcub_technorep_6641
Mladenović Nikolić N, Knežević S, Ivanović M, Mirković M, Maletić M, Kljajević L, Trivunac K. Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin. in Book of abstracts / 26th Congress of SCTM with international participation 20–23 September 2023 Metropol Lake Resort Ohrid, R. Macedonia. 2023;:29.
https://hdl.handle.net/21.15107/rcub_technorep_6641 .
Mladenović Nikolić, Nataša, Knežević, Sanja, Ivanović, Marija, Mirković, Miljana, Maletić, Marina, Kljajević, Ljiljana, Trivunac, Katarina, "Structural Characteristics and Adsorption Properties of Alkali Activated Blends Ashes/Metakaolin" in Book of abstracts / 26th Congress of SCTM with international participation 20–23 September 2023 Metropol Lake Resort Ohrid, R. Macedonia (2023):29,
https://hdl.handle.net/21.15107/rcub_technorep_6641 .

Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite

Janićijević, Aleksandra; Filipović, Suzana; Sknepnek, Aleksandra; Vlahović, Branislav; Đorđević, Nenad; Kovačević, Danijela; Mirković, Miljana; Petronijević, Ivan; Živković, Predrag; Rogan, Jelena; Pavlović, Vladimir B.

(MDPI, 2023)

TY  - JOUR
AU  - Janićijević, Aleksandra
AU  - Filipović, Suzana
AU  - Sknepnek, Aleksandra
AU  - Vlahović, Branislav
AU  - Đorđević, Nenad
AU  - Kovačević, Danijela
AU  - Mirković, Miljana
AU  - Petronijević, Ivan
AU  - Živković, Predrag
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6805
AB  - In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe3O4, and a mixture of BaTiO3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe3O4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.
PB  - MDPI
T2  - Polymers
T1  - Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite
IS  - 20
SP  - 4080
VL  - 15
DO  - 10.3390/polym15204080
ER  - 
@article{
author = "Janićijević, Aleksandra and Filipović, Suzana and Sknepnek, Aleksandra and Vlahović, Branislav and Đorđević, Nenad and Kovačević, Danijela and Mirković, Miljana and Petronijević, Ivan and Živković, Predrag and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2023",
abstract = "In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe3O4, and a mixture of BaTiO3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe3O4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.",
publisher = "MDPI",
journal = "Polymers",
title = "Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite",
number = "20",
pages = "4080",
volume = "15",
doi = "10.3390/polym15204080"
}
Janićijević, A., Filipović, S., Sknepnek, A., Vlahović, B., Đorđević, N., Kovačević, D., Mirković, M., Petronijević, I., Živković, P., Rogan, J.,& Pavlović, V. B.. (2023). Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite. in Polymers
MDPI., 15(20), 4080.
https://doi.org/10.3390/polym15204080
Janićijević A, Filipović S, Sknepnek A, Vlahović B, Đorđević N, Kovačević D, Mirković M, Petronijević I, Živković P, Rogan J, Pavlović VB. Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite. in Polymers. 2023;15(20):4080.
doi:10.3390/polym15204080 .
Janićijević, Aleksandra, Filipović, Suzana, Sknepnek, Aleksandra, Vlahović, Branislav, Đorđević, Nenad, Kovačević, Danijela, Mirković, Miljana, Petronijević, Ivan, Živković, Predrag, Rogan, Jelena, Pavlović, Vladimir B., "Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite" in Polymers, 15, no. 20 (2023):4080,
https://doi.org/10.3390/polym15204080 . .
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