Pejić, Biljana

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Authority KeyName Variants
orcid::0000-0003-0694-6529
  • Pejić, Biljana (40)
  • Pejić, Biljana M. (3)
Projects
Functionalization, characterization and application of cellulose and cellulose derivatives SIW4SE - Serbian Industrial Waste towards Sustainable Environment: Resource of Strategic Elements and Removal Agent for Pollutants
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy) Razvoj biološki-aktivnih polisaharidnih vlakana i materijala kao veštačkih depoa proteina male molekulske mase za različite medicinske namene (u terapijama hormonskih poremećaja, virusnih infekcija, neuroloških i malignih oboljenja, ortopediji i stomatologiji
Physics and Chemistry with Ion Beams 41001
Investigation of the effect of parameters of synthesis and processing on dielectric, optical and magnetic properties, both bulk and surface of crystal and polymeric systems Diagnostics and Optimization of Plasma Sources Important for Applications
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200032 (Institute of Field and Vegetable Crops, Novi Sad)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200117 (University of Novi Sad, Faculty of Agriculture) ITES Odzaci (Serbia)
Ministry of Science and Environmental Protection of the Republic Serbia (Project TR-6713B) is gratefully acknowledged. Ministry of Science of the Republic SerbiaMinistry of Science, Serbia [TR-6713B]
Projekat Ministarstva nauke Republike Srbije, br. TR-6713 Projekat Ministarstva nauke Republike Srbije, br. TR-6713B

Author's Bibliography

Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater

Vukčević, Marija; Maletić, Marina; Pejić, Biljana; Kalijadis, Ana; Kostić, Mirjana; Trivunac, Katarina; Perić Grujić, Aleksandra

(MDPI, 2024)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Pejić, Biljana
AU  - Kalijadis, Ana
AU  - Kostić, Mirjana
AU  - Trivunac, Katarina
AU  - Perić Grujić, Aleksandra
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7448
AB  - In an attempt to reuse fibrous textile waste and, at the same time, to address dye pollution
in textile wastewater, waste cotton-based yarn was utilized as a cheap and sustainable adsorbent, as
well as a row material for carbon adsorbent production. Unmodified yarn and cotton-based carbon
adsorbents were used as adsorbents for dye removal from water. Cotton and cotton/polyester yarn
samples underwent thermal modification through carbonization followed by chemical activation
with KOH. Various techniques, including scanning electron microscopy, Fourier transform infrared
spectroscopy, nitrogen adsorption–desorption isotherms, and surface charge determination, were
employed to analyze the morphological and surface characteristics of the cotton-based adsorbents.
Adsorption properties were evaluated by testing the removal of selected cationic and anionic dyes
from water. The impact of temperature, initial pH and concentration of the dye solution, and
contact time on adsorption were investigated, and experimentally obtained data were analyzed using
theoretical models. While carbonization alone did not significantly enhance adsorption properties,
activated samples exhibited high efficacy in removing both cationic and anionic dyes from water.
Despite the negative influence of the polyester component in the carbon precursor on the efficiency
of activated samples in removing methyl orange, the results indicated that activated cotton and
cotton/polyester yarn could be used to prepare highly efficient adsorbents for the rapid removal of
methylene blue from real wastewater samples.
PB  - MDPI
T2  - Sustainability
T1  - Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater
IS  - 9
SP  - 3660
VL  - 16
DO  - 10.3390/su16093660
ER  - 
@article{
author = "Vukčević, Marija and Maletić, Marina and Pejić, Biljana and Kalijadis, Ana and Kostić, Mirjana and Trivunac, Katarina and Perić Grujić, Aleksandra",
year = "2024",
abstract = "In an attempt to reuse fibrous textile waste and, at the same time, to address dye pollution
in textile wastewater, waste cotton-based yarn was utilized as a cheap and sustainable adsorbent, as
well as a row material for carbon adsorbent production. Unmodified yarn and cotton-based carbon
adsorbents were used as adsorbents for dye removal from water. Cotton and cotton/polyester yarn
samples underwent thermal modification through carbonization followed by chemical activation
with KOH. Various techniques, including scanning electron microscopy, Fourier transform infrared
spectroscopy, nitrogen adsorption–desorption isotherms, and surface charge determination, were
employed to analyze the morphological and surface characteristics of the cotton-based adsorbents.
Adsorption properties were evaluated by testing the removal of selected cationic and anionic dyes
from water. The impact of temperature, initial pH and concentration of the dye solution, and
contact time on adsorption were investigated, and experimentally obtained data were analyzed using
theoretical models. While carbonization alone did not significantly enhance adsorption properties,
activated samples exhibited high efficacy in removing both cationic and anionic dyes from water.
Despite the negative influence of the polyester component in the carbon precursor on the efficiency
of activated samples in removing methyl orange, the results indicated that activated cotton and
cotton/polyester yarn could be used to prepare highly efficient adsorbents for the rapid removal of
methylene blue from real wastewater samples.",
publisher = "MDPI",
journal = "Sustainability",
title = "Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater",
number = "9",
pages = "3660",
volume = "16",
doi = "10.3390/su16093660"
}
Vukčević, M., Maletić, M., Pejić, B., Kalijadis, A., Kostić, M., Trivunac, K.,& Perić Grujić, A.. (2024). Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater. in Sustainability
MDPI., 16(9), 3660.
https://doi.org/10.3390/su16093660
Vukčević M, Maletić M, Pejić B, Kalijadis A, Kostić M, Trivunac K, Perić Grujić A. Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater. in Sustainability. 2024;16(9):3660.
doi:10.3390/su16093660 .
Vukčević, Marija, Maletić, Marina, Pejić, Biljana, Kalijadis, Ana, Kostić, Mirjana, Trivunac, Katarina, Perić Grujić, Aleksandra, "Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater" in Sustainability, 16, no. 9 (2024):3660,
https://doi.org/10.3390/su16093660 . .

The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers

Pejić, Biljana M.; Vukčević, Marija M.; Lazić, Biljana D.; Janjić, Svjetlana D.; Kostić, Mirjana

(2023)

TY  - JOUR
AU  - Pejić, Biljana M.
AU  - Vukčević, Marija M.
AU  - Lazić, Biljana D.
AU  - Janjić, Svjetlana D.
AU  - Kostić, Mirjana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5924
AB  - In this study, waste flax fibers with different levels of cellulosic and noncellulosic components were obtained by oxidative and alkali treatments and used to assess the influence of the fiber’s structural and chemical properties on the biosorption of lead ions. Scanning electron microscopy was used for the characterization of the flax fibers’ surface morphology, while the physicochemical properties of the fibers’ surface were determined by the streaming potential method, and Fourier transform infrared spectroscopy. Alkaline treatment decreased, while oxidative increased the crystallinity index of flax fibers by approximately 10%, due to the changes in the content of cellulosic components. Adsorption of lead ions was studied in detail, including kinetics, isotherms, and thermodynamic parameters analysis. It was shown that the amount and distribution of oxygen-containing groups, originating from cellulosic components, have the highest influence on the adsorption capacity of flax fibers, increasing Langmuir adsorption capacity from 12.76 mg g−1 for untreated to 21.9 and 79.9 mg g−1 for alkali-treated and oxidized fibers, respectively. Obtained negative values of ∆GӨ (−4.874 to −0.807 kJ mol−1) and ∆HӨ (−42.81 to −13.65 kJ mol−1) indicated that the adsorption of lead ions onto flax fibers is a spontaneous and endothermic process, which occurs through electrostatic attraction and ion-exchange. The results presented in this work demonstrate that the waste flax fibers of suitable chemical composition may be used as sustainable and renewable low-cost biosorbents.
T2  - JOURNAL OF NATURAL FIBERS
T1  - The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers
IS  - 1
SP  - 2140325
VL  - 20
DO  - 10.1080/15440478.2022.2140325
ER  - 
@article{
author = "Pejić, Biljana M. and Vukčević, Marija M. and Lazić, Biljana D. and Janjić, Svjetlana D. and Kostić, Mirjana",
year = "2023",
abstract = "In this study, waste flax fibers with different levels of cellulosic and noncellulosic components were obtained by oxidative and alkali treatments and used to assess the influence of the fiber’s structural and chemical properties on the biosorption of lead ions. Scanning electron microscopy was used for the characterization of the flax fibers’ surface morphology, while the physicochemical properties of the fibers’ surface were determined by the streaming potential method, and Fourier transform infrared spectroscopy. Alkaline treatment decreased, while oxidative increased the crystallinity index of flax fibers by approximately 10%, due to the changes in the content of cellulosic components. Adsorption of lead ions was studied in detail, including kinetics, isotherms, and thermodynamic parameters analysis. It was shown that the amount and distribution of oxygen-containing groups, originating from cellulosic components, have the highest influence on the adsorption capacity of flax fibers, increasing Langmuir adsorption capacity from 12.76 mg g−1 for untreated to 21.9 and 79.9 mg g−1 for alkali-treated and oxidized fibers, respectively. Obtained negative values of ∆GӨ (−4.874 to −0.807 kJ mol−1) and ∆HӨ (−42.81 to −13.65 kJ mol−1) indicated that the adsorption of lead ions onto flax fibers is a spontaneous and endothermic process, which occurs through electrostatic attraction and ion-exchange. The results presented in this work demonstrate that the waste flax fibers of suitable chemical composition may be used as sustainable and renewable low-cost biosorbents.",
journal = "JOURNAL OF NATURAL FIBERS",
title = "The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers",
number = "1",
pages = "2140325",
volume = "20",
doi = "10.1080/15440478.2022.2140325"
}
Pejić, B. M., Vukčević, M. M., Lazić, B. D., Janjić, S. D.,& Kostić, M.. (2023). The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers. in JOURNAL OF NATURAL FIBERS, 20(1), 2140325.
https://doi.org/10.1080/15440478.2022.2140325
Pejić BM, Vukčević MM, Lazić BD, Janjić SD, Kostić M. The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers. in JOURNAL OF NATURAL FIBERS. 2023;20(1):2140325.
doi:10.1080/15440478.2022.2140325 .
Pejić, Biljana M., Vukčević, Marija M., Lazić, Biljana D., Janjić, Svjetlana D., Kostić, Mirjana, "The Role of Cellulosic and Noncellulosic Functional Groups in the Biosorption of Lead Ions by Waste Flax Fibers" in JOURNAL OF NATURAL FIBERS, 20, no. 1 (2023):2140325,
https://doi.org/10.1080/15440478.2022.2140325 . .
4
4

WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES

Trivunac, Katarina; Vukčević, Marija; Maletić, Marina; Karić, Nataša; Pejić, Biljana; Perić-Grujić, Aleksandra

(SAVEZ INŽENJERA I TEHNIČARA TEKSTILACA SRBIJE, 2023)

TY  - JOUR
AU  - Trivunac, Katarina
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Karić, Nataša
AU  - Pejić, Biljana
AU  - Perić-Grujić, Aleksandra
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6379
AB  - This study aims to investigate the effect of alkalization and chemical coupling methods on the surface
and adsorption properties of waste cotton and cotton/polyester yarns. The simple and cheap alkali treatment was
performed using 10% and 18% NaOH solution, while the chemical coupling method involved combining cotton
and cotton/polyester yarns and fly ash, using sodium carboxymethyl cellulose and sodium alginate as binders.
Morphological and surface characteristics of unmodified and modified cotton and cotton/polyester yarns were
analyzed by scanning electron microscopy and Fourier transform infrared spectroscopy, while adsorption properties were assessed by the removal of lead and cadmium ions from aqueous solution. It was found that chemical
modification with 18% NaOH solution positively affected the adsorption properties of only cotton yarns, increasing the removal efficiency of lead ions up to 75%. On the other hand, modification with fly ash improves the adsorption properties of both, cotton and cotton/polyester yarns, increasing the efficiency in removing lead ions by
using sodium carboxymethyl cellulose, and cadmium ions by using alginate as a binder. Using the chemical coupling method, effective adsorbents are obtained starting from waste yarn, which gives it added value, the amount
of non-degradable waste material can be reduced and the criteria of a cleaner environment and circular economy
can be met.
PB  - SAVEZ INŽENJERA I TEHNIČARA TEKSTILACA SRBIJE
T2  - Tekstilna industrija
T1  - WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES
EP  - 10
IS  - 1
SP  - 4
VL  - 71
DO  - 10.5937/TEKSTIND2301004T
ER  - 
@article{
author = "Trivunac, Katarina and Vukčević, Marija and Maletić, Marina and Karić, Nataša and Pejić, Biljana and Perić-Grujić, Aleksandra",
year = "2023",
abstract = "This study aims to investigate the effect of alkalization and chemical coupling methods on the surface
and adsorption properties of waste cotton and cotton/polyester yarns. The simple and cheap alkali treatment was
performed using 10% and 18% NaOH solution, while the chemical coupling method involved combining cotton
and cotton/polyester yarns and fly ash, using sodium carboxymethyl cellulose and sodium alginate as binders.
Morphological and surface characteristics of unmodified and modified cotton and cotton/polyester yarns were
analyzed by scanning electron microscopy and Fourier transform infrared spectroscopy, while adsorption properties were assessed by the removal of lead and cadmium ions from aqueous solution. It was found that chemical
modification with 18% NaOH solution positively affected the adsorption properties of only cotton yarns, increasing the removal efficiency of lead ions up to 75%. On the other hand, modification with fly ash improves the adsorption properties of both, cotton and cotton/polyester yarns, increasing the efficiency in removing lead ions by
using sodium carboxymethyl cellulose, and cadmium ions by using alginate as a binder. Using the chemical coupling method, effective adsorbents are obtained starting from waste yarn, which gives it added value, the amount
of non-degradable waste material can be reduced and the criteria of a cleaner environment and circular economy
can be met.",
publisher = "SAVEZ INŽENJERA I TEHNIČARA TEKSTILACA SRBIJE",
journal = "Tekstilna industrija",
title = "WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES",
pages = "10-4",
number = "1",
volume = "71",
doi = "10.5937/TEKSTIND2301004T"
}
Trivunac, K., Vukčević, M., Maletić, M., Karić, N., Pejić, B.,& Perić-Grujić, A.. (2023). WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES. in Tekstilna industrija
SAVEZ INŽENJERA I TEHNIČARA TEKSTILACA SRBIJE., 71(1), 4-10.
https://doi.org/10.5937/TEKSTIND2301004T
Trivunac K, Vukčević M, Maletić M, Karić N, Pejić B, Perić-Grujić A. WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES. in Tekstilna industrija. 2023;71(1):4-10.
doi:10.5937/TEKSTIND2301004T .
Trivunac, Katarina, Vukčević, Marija, Maletić, Marina, Karić, Nataša, Pejić, Biljana, Perić-Grujić, Aleksandra, "WASTE MATERIALS AS ADSORBENTS FOR HEAVY METALS REMOVAL FROM WATER: COMPARATIVE ANALYSIS OF MODIFICATION TECHNIQUES" in Tekstilna industrija, 71, no. 1 (2023):4-10,
https://doi.org/10.5937/TEKSTIND2301004T . .
1

Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties

Vukčević, Marija; Maletić, Marina; Pejić, Biljana; Karić, Nataša; Trivunac, Katarina; Perić-Grujić, Aleksandra

(Serbian Chemical Society, 2023)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Pejić, Biljana
AU  - Karić, Nataša
AU  - Trivunac, Katarina
AU  - Perić-Grujić, Aleksandra
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6380
AB  - Waste hemp and flax fibers, and cotton and cotton/polyester yarns,
available in large quantities from the textile industry, were used as cheap and
effective sorbents for the removal of methylene blue from wastewater. Waste
fibers and yarns were characterized by scanning electron microscopy, Fourier
transform infrared spectroscopy, iodine sorption, water retention, and point of
zero charge, as well as through the determination of crystallinity index and
degree of surface crystallinity. Adsorption of methylene blue was optimized by
examining the influence of contact time, initial concentration, temperature, and
pH value. It was found that the more ordered structure of cotton and
cotton/polyester yarns leads to lower adsorption capacities and better agreement
with pseudo-second order kinetic and Langmuir isotherm model, while the more
heterogeneous structure of flax and hemp fibers show higher capacities for
methylene blue adsorption, better described by the pseudo-first order kinetic and
Freundlich isotherm model. Based on the obtained results, waste lignocellulosic
fibers and yarns can be utilized for the discoloration of wastewater, thereby
solving the problem of waste generated in the textile industry.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties
DO  - 10.2298/JSC221213015V
ER  - 
@article{
author = "Vukčević, Marija and Maletić, Marina and Pejić, Biljana and Karić, Nataša and Trivunac, Katarina and Perić-Grujić, Aleksandra",
year = "2023",
abstract = "Waste hemp and flax fibers, and cotton and cotton/polyester yarns,
available in large quantities from the textile industry, were used as cheap and
effective sorbents for the removal of methylene blue from wastewater. Waste
fibers and yarns were characterized by scanning electron microscopy, Fourier
transform infrared spectroscopy, iodine sorption, water retention, and point of
zero charge, as well as through the determination of crystallinity index and
degree of surface crystallinity. Adsorption of methylene blue was optimized by
examining the influence of contact time, initial concentration, temperature, and
pH value. It was found that the more ordered structure of cotton and
cotton/polyester yarns leads to lower adsorption capacities and better agreement
with pseudo-second order kinetic and Langmuir isotherm model, while the more
heterogeneous structure of flax and hemp fibers show higher capacities for
methylene blue adsorption, better described by the pseudo-first order kinetic and
Freundlich isotherm model. Based on the obtained results, waste lignocellulosic
fibers and yarns can be utilized for the discoloration of wastewater, thereby
solving the problem of waste generated in the textile industry.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties",
doi = "10.2298/JSC221213015V"
}
Vukčević, M., Maletić, M., Pejić, B., Karić, N., Trivunac, K.,& Perić-Grujić, A.. (2023). Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties. in Journal of the Serbian Chemical Society
Serbian Chemical Society..
https://doi.org/10.2298/JSC221213015V
Vukčević M, Maletić M, Pejić B, Karić N, Trivunac K, Perić-Grujić A. Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties. in Journal of the Serbian Chemical Society. 2023;.
doi:10.2298/JSC221213015V .
Vukčević, Marija, Maletić, Marina, Pejić, Biljana, Karić, Nataša, Trivunac, Katarina, Perić-Grujić, Aleksandra, "Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties" in Journal of the Serbian Chemical Society (2023),
https://doi.org/10.2298/JSC221213015V . .
1

Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties

Vukčević, Marija M.; Maletić, Marina M.; Pejić, Biljana M.; Karić, Nataša V.; Trivunac, Katarina V.; Perić-Grujić, Aleksandra A.

(Serbian Chemical Society, 2023)

TY  - JOUR
AU  - Vukčević, Marija M.
AU  - Maletić, Marina M.
AU  - Pejić, Biljana M.
AU  - Karić, Nataša V.
AU  - Trivunac, Katarina V.
AU  - Perić-Grujić, Aleksandra A.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6586
AB  - Waste hemp and flax fibers, and cotton and cotton/polyester yarns, available in large quantities from the textile industry, were used as cheap and effective sorbents for the removal of methylene blue from wastewater. Waste fibers and yarns were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, iodine sorption, water retention, and point of zero charge, as well as through the determination of crystallinity index and degree of surface crystallinity. The adsorption of methylene blue was optimized by examining the influence of contact time, initial concentration, temperature, and pH value. It was found that the more ordered structure of cotton and cotton/polyester yarns leads to lower adsorption capacities and better agreement with pseudo-second order kinetic and Langmuir isotherm model, while the more heterogeneous structure of flax and hemp fibers shows higher capacities for methylene blue adsorption, better described by the pseudo-first order kinetic and Freundlich isotherm model. Based on the obtained results, waste lignocellulosic fibers and yarns can be used for the discoloration of wastewater, thereby solving the problem of waste generated in the textile industry.
AB  - Отпадна влакна конопље и лана и пређе памука и памук/полиестра, добијена као
отпад из текстилне индустрије, коришћена су као јефтини и ефикасни сорбенти за уклањање метиленског плавог из отпадних вода. Узорци влакана и пређе су окарактерисани
скенирајућом електронском микроскопијом, инфрацрвеном спектроскопијом са Фуријеовом трансформацијом, сорпцијом јода, задржавањем воде, тачком нултог наелектрисања, као и одређивањем индекса кристаличности и степена површинске кристаличности. У циљу оптимизације адсорпције метиленско плавог испитан је утицај времена
контакта, почетне концентрације, температуре и pH вредности на ефикасност адсорпције. Показано је да пређа памука и памук/полиестера са већим уделом кристалних
области у структури има нижи адсорпциони капацитет и боље се слаже са кинетичким
моделом псеудо-другог реда и Лангмировом адсорпционом изотермом. С друге стране,
влакна лана и конопље се одликују већим уделом аморфних области и нецелулозних
компоненти у структури и показују већи капацитет адсорпције и боље слагање са кинетичким моделом псеудо-првог реда као и са Фројндлиховом адсорпционом изотермом.
На основу добијених резултата показано је да се отпадна лигноцелулозна влакна и пређа
могу користити за обезбојавање отпадних вода, чиме се решава проблем отпада који
настаје у текстилној индустрији и задовољавају све строжији захтеви у области заштите
животне средине.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties
T1  - ОТПАДНА ВЛАКНА КОНОПЉЕ И ЛАНА И ПРЕЂЕ ПАМУКА И ПАМУК/ПОЛИЕСТЕРА
ЗА УКЛАЊАЊЕ МЕТИЛЕНСКО ПЛАВОГ ИЗ ОТПАДНЕ ВОДЕ: УПОРЕДНА АНАЛИЗА
АДСОРПЦИОНИХ КАРАКТЕРИСТИКА
EP  - 683
IS  - 6
SP  - 669
VL  - 88
DO  - 10.2298/JSC221213015V
ER  - 
@article{
author = "Vukčević, Marija M. and Maletić, Marina M. and Pejić, Biljana M. and Karić, Nataša V. and Trivunac, Katarina V. and Perić-Grujić, Aleksandra A.",
year = "2023",
abstract = "Waste hemp and flax fibers, and cotton and cotton/polyester yarns, available in large quantities from the textile industry, were used as cheap and effective sorbents for the removal of methylene blue from wastewater. Waste fibers and yarns were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, iodine sorption, water retention, and point of zero charge, as well as through the determination of crystallinity index and degree of surface crystallinity. The adsorption of methylene blue was optimized by examining the influence of contact time, initial concentration, temperature, and pH value. It was found that the more ordered structure of cotton and cotton/polyester yarns leads to lower adsorption capacities and better agreement with pseudo-second order kinetic and Langmuir isotherm model, while the more heterogeneous structure of flax and hemp fibers shows higher capacities for methylene blue adsorption, better described by the pseudo-first order kinetic and Freundlich isotherm model. Based on the obtained results, waste lignocellulosic fibers and yarns can be used for the discoloration of wastewater, thereby solving the problem of waste generated in the textile industry., Отпадна влакна конопље и лана и пређе памука и памук/полиестра, добијена као
отпад из текстилне индустрије, коришћена су као јефтини и ефикасни сорбенти за уклањање метиленског плавог из отпадних вода. Узорци влакана и пређе су окарактерисани
скенирајућом електронском микроскопијом, инфрацрвеном спектроскопијом са Фуријеовом трансформацијом, сорпцијом јода, задржавањем воде, тачком нултог наелектрисања, као и одређивањем индекса кристаличности и степена површинске кристаличности. У циљу оптимизације адсорпције метиленско плавог испитан је утицај времена
контакта, почетне концентрације, температуре и pH вредности на ефикасност адсорпције. Показано је да пређа памука и памук/полиестера са већим уделом кристалних
области у структури има нижи адсорпциони капацитет и боље се слаже са кинетичким
моделом псеудо-другог реда и Лангмировом адсорпционом изотермом. С друге стране,
влакна лана и конопље се одликују већим уделом аморфних области и нецелулозних
компоненти у структури и показују већи капацитет адсорпције и боље слагање са кинетичким моделом псеудо-првог реда као и са Фројндлиховом адсорпционом изотермом.
На основу добијених резултата показано је да се отпадна лигноцелулозна влакна и пређа
могу користити за обезбојавање отпадних вода, чиме се решава проблем отпада који
настаје у текстилној индустрији и задовољавају све строжији захтеви у области заштите
животне средине.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties, ОТПАДНА ВЛАКНА КОНОПЉЕ И ЛАНА И ПРЕЂЕ ПАМУКА И ПАМУК/ПОЛИЕСТЕРА
ЗА УКЛАЊАЊЕ МЕТИЛЕНСКО ПЛАВОГ ИЗ ОТПАДНЕ ВОДЕ: УПОРЕДНА АНАЛИЗА
АДСОРПЦИОНИХ КАРАКТЕРИСТИКА",
pages = "683-669",
number = "6",
volume = "88",
doi = "10.2298/JSC221213015V"
}
Vukčević, M. M., Maletić, M. M., Pejić, B. M., Karić, N. V., Trivunac, K. V.,& Perić-Grujić, A. A.. (2023). Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 88(6), 669-683.
https://doi.org/10.2298/JSC221213015V
Vukčević MM, Maletić MM, Pejić BM, Karić NV, Trivunac KV, Perić-Grujić AA. Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties. in Journal of the Serbian Chemical Society. 2023;88(6):669-683.
doi:10.2298/JSC221213015V .
Vukčević, Marija M., Maletić, Marina M., Pejić, Biljana M., Karić, Nataša V., Trivunac, Katarina V., Perić-Grujić, Aleksandra A., "Waste hemp and flax fibers and cotton and cotton/polyester yarns for removal of methylene blue from wastewater: Comparative study of adsorption properties" in Journal of the Serbian Chemical Society, 88, no. 6 (2023):669-683,
https://doi.org/10.2298/JSC221213015V . .
1

Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification

Vukčević, Marija; Pejić, Biljana; Maletić, Marina; Trivunac, Katarina; Kostić, Mirjana

(Belgrade : Union of Engineers and Textile Technicians of Serbia, 2023)

TY  - CONF
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Maletić, Marina
AU  - Trivunac, Katarina
AU  - Kostić, Mirjana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6639
AB  - Frequent changes in clothing fashion trends and the furniture industry have led to the excessive consumption of textiles to meet human needs. This leads to an increase in the production and finishing of textile materials, and the generation of large amounts of waste, making the textile industry one of the main polluters of the environment nowadays. Therefore, there are concerns about the reckless disposal of chemical and solid textile waste (natural or synthetic yarns, fibers, pieces of clothing, etc.) which can cause serious soil, water, and air pollution. To reduce the amount of waste generated in the industry, and preserve the environment and human health, it is necessary to apply modern trends of sustainable development. These trends imply the simultaneous satisfaction of the principles of ecological efficiency, social responsibility, and economic profitability. In this way, waste from the textile industry becomes a resource of the circular economy system with the aim of realizing sustainable development. In this work, waste materials of lignocellulosic, cellulosic, and synthetic origin were used as biosorbents for the purification of water polluted by organic and inorganic pollutants. This kind of waste utilization represents a special way of recycling, which is one of the most important links in the chain of sustainable development.
AB  - Česte promene modnih trendova u odevnoj industriji, kao i industriji nameštaja, dovode do prekomerne potrošnje tekstila. Ovo direktno utiče na povećanje proizvodnje i dorade tekstilnih materijala, kao i stvaranja velike količine otpada, što tekstilnu industriju čini jednim od najvećih zagađivača životne sredine. Poseban problem predstavlja odlaganje hemijskog i čvrstog tekstilnog otpada (prirodna i sintetička prediva, vlakna, komadi odeće itd.) koji mogu izazvati ozbiljno zagađenje zemljišta, vode i vazduha. U cilju smanjenja količine otpada koji se generiše u industriji, a samim tim i očuvanja životne sredine i zdravlja ljudi, primenjuju se moderni trendovi održivog razvoja, koji podrazumeva istovremeno zadovoljenje principa ekološke efikasnosti, društvene odgovornosti i ekonomske isplativosti. Na taj način otpad iz tekstilne industrije postaje resurs sistema cirkularne ekonomije sa ciljem realizacije održivog razvoja. U ovom radu, otpadni materijali lignoceluloznog, celuloznog i sintetičkog porekla korišćeni su kao biosorbenti za prečišćavanje vode zagađene organskim i neorganskim polutantima. Ovakvo korišćenje otpada predstavlja specijalni vid reciklaže koja je jedna od najvažnijih karika u lancu održivog razvoja.
PB  - Belgrade : Union of Engineers and Textile Technicians of Serbia
C3  - Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September
T1  - Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification
T1  - Doprinos cirkularnoj ekonomiji kroz korišćenje vlaknastog tekstilnog otpada kao biosorbenata za prečIšćavanje vode
EP  - 26
SP  - 17
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6639
ER  - 
@conference{
author = "Vukčević, Marija and Pejić, Biljana and Maletić, Marina and Trivunac, Katarina and Kostić, Mirjana",
year = "2023",
abstract = "Frequent changes in clothing fashion trends and the furniture industry have led to the excessive consumption of textiles to meet human needs. This leads to an increase in the production and finishing of textile materials, and the generation of large amounts of waste, making the textile industry one of the main polluters of the environment nowadays. Therefore, there are concerns about the reckless disposal of chemical and solid textile waste (natural or synthetic yarns, fibers, pieces of clothing, etc.) which can cause serious soil, water, and air pollution. To reduce the amount of waste generated in the industry, and preserve the environment and human health, it is necessary to apply modern trends of sustainable development. These trends imply the simultaneous satisfaction of the principles of ecological efficiency, social responsibility, and economic profitability. In this way, waste from the textile industry becomes a resource of the circular economy system with the aim of realizing sustainable development. In this work, waste materials of lignocellulosic, cellulosic, and synthetic origin were used as biosorbents for the purification of water polluted by organic and inorganic pollutants. This kind of waste utilization represents a special way of recycling, which is one of the most important links in the chain of sustainable development., Česte promene modnih trendova u odevnoj industriji, kao i industriji nameštaja, dovode do prekomerne potrošnje tekstila. Ovo direktno utiče na povećanje proizvodnje i dorade tekstilnih materijala, kao i stvaranja velike količine otpada, što tekstilnu industriju čini jednim od najvećih zagađivača životne sredine. Poseban problem predstavlja odlaganje hemijskog i čvrstog tekstilnog otpada (prirodna i sintetička prediva, vlakna, komadi odeće itd.) koji mogu izazvati ozbiljno zagađenje zemljišta, vode i vazduha. U cilju smanjenja količine otpada koji se generiše u industriji, a samim tim i očuvanja životne sredine i zdravlja ljudi, primenjuju se moderni trendovi održivog razvoja, koji podrazumeva istovremeno zadovoljenje principa ekološke efikasnosti, društvene odgovornosti i ekonomske isplativosti. Na taj način otpad iz tekstilne industrije postaje resurs sistema cirkularne ekonomije sa ciljem realizacije održivog razvoja. U ovom radu, otpadni materijali lignoceluloznog, celuloznog i sintetičkog porekla korišćeni su kao biosorbenti za prečišćavanje vode zagađene organskim i neorganskim polutantima. Ovakvo korišćenje otpada predstavlja specijalni vid reciklaže koja je jedna od najvažnijih karika u lancu održivog razvoja.",
publisher = "Belgrade : Union of Engineers and Textile Technicians of Serbia",
journal = "Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September",
title = "Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification, Doprinos cirkularnoj ekonomiji kroz korišćenje vlaknastog tekstilnog otpada kao biosorbenata za prečIšćavanje vode",
pages = "26-17",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6639"
}
Vukčević, M., Pejić, B., Maletić, M., Trivunac, K.,& Kostić, M.. (2023). Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification. in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September
Belgrade : Union of Engineers and Textile Technicians of Serbia., 17-26.
https://hdl.handle.net/21.15107/rcub_technorep_6639
Vukčević M, Pejić B, Maletić M, Trivunac K, Kostić M. Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification. in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September. 2023;:17-26.
https://hdl.handle.net/21.15107/rcub_technorep_6639 .
Vukčević, Marija, Pejić, Biljana, Maletić, Marina, Trivunac, Katarina, Kostić, Mirjana, "Contribution to the circular economy through the utilization of fibrous textile waste as biosorbents for water purification" in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September (2023):17-26,
https://hdl.handle.net/21.15107/rcub_technorep_6639 .

ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN

Maletić, Marina; Vukčević, Marija; Pejić, Biljana; Kostić, Mirjana; Perić Grujić, Aleksandra

(Belgrade : Union of Engineers and Textile Technicians of Serbia, 2023)

TY  - CONF
AU  - Maletić, Marina
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Kostić, Mirjana
AU  - Perić Grujić, Aleksandra
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6642
AB  - In an attempt to reuse fibrous textile waste, and at the same time to reduce its quantity, waste cotton-based yarn was used as a cheap and sustainable precursor for carbon adsorbents production. Cotton and cotton/polyester yarn samples were carbonized using hydrothermal and classical carbonization and activated using KOH as activating agent. Nitrogen adsorption-desorption isotherms, scanning electron microscopy, Fourier transform infrared spectroscopy, and Boehm titration methods were used to analyze the structural and surface properties of obtained carbon samples. The adsorption properties of cotton-based carbon materials were tested through the adsorption of selected organic dyes from water. The influence of contact time, initial concentration, and pH value of adsorbate solution on adsorption was examined and experimental data were processed by theoretical models. It was found that the adsorption properties of carbonized samples were negatively affected by the presence of a polyester component in the precursor structure. Nevertheless, the cotton-based carbon adsorbents obtained by carbonization, and subsequent activation proved to be highly efficient adsorbents for organic dye removal from water.
AB  - U cilju iskorišćenja vlaknastog tekstilnog otpada, kao i smanjenja njegove količine, otpadna prediva na bazi pamuka su korišćena kao jeftina sirovina za proizvodnju ugljeničnih materijala. Pamučno predivo, kao i predivo mešavine pamuka i poliestra, karbonizovani su primenom klasične ili hidrotermalne karbonizacije, i naknadno aktivirani u prisustvu KOH kao aktivirajućeg agensa. Strukturne i površinske karakteristike dobijenih ugljeničnih materijala ispitane su analizom adsorpciono-desorpcionih izotermi azota i rezultata Bemovih titracija, kao i skenirajućom elektronskom mikroskopijom i infracrvenom spektroskopijom sa Furijeovom transformacijom. Adsorpcija odabranih organskih boja iz vodenih rastvora je korišćenja za ispitivanje adsorpcionih karakteristika, a ispitan je i uticaj vremena kontakta, početne koncentracije i pH vrednosti rastvora adsorbata na adsorpcione kapacitete ugljeničnih adsorbenata. Pokazano je da prisustvo poliestarske komponente u strukturi prekursora ima negativan uticaj na adsorpcione karakteristike materijala dobijenih samo karbonizacijom. S druge strane, svi uzorci ugljeničnih materijala dobijeni karbonizacijom pređa na bazi pamuka i naknadnom aktivacijom pokazuju visoku efikasnost u uklanjanju boja iz vode.
PB  - Belgrade : Union of Engineers and Textile Technicians of Serbia
C3  - Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September
T1  - ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN
T1  - ADSORPCIJA ORGANSKIH BOJA NA UGLJENIČNIM ADSORBENTIMA DOBIJENIM OD OTPADNOG PREDIVA PAMUKA I PAMUK/POLIESTRA
EP  - 402
SP  - 394
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6642
ER  - 
@conference{
author = "Maletić, Marina and Vukčević, Marija and Pejić, Biljana and Kostić, Mirjana and Perić Grujić, Aleksandra",
year = "2023",
abstract = "In an attempt to reuse fibrous textile waste, and at the same time to reduce its quantity, waste cotton-based yarn was used as a cheap and sustainable precursor for carbon adsorbents production. Cotton and cotton/polyester yarn samples were carbonized using hydrothermal and classical carbonization and activated using KOH as activating agent. Nitrogen adsorption-desorption isotherms, scanning electron microscopy, Fourier transform infrared spectroscopy, and Boehm titration methods were used to analyze the structural and surface properties of obtained carbon samples. The adsorption properties of cotton-based carbon materials were tested through the adsorption of selected organic dyes from water. The influence of contact time, initial concentration, and pH value of adsorbate solution on adsorption was examined and experimental data were processed by theoretical models. It was found that the adsorption properties of carbonized samples were negatively affected by the presence of a polyester component in the precursor structure. Nevertheless, the cotton-based carbon adsorbents obtained by carbonization, and subsequent activation proved to be highly efficient adsorbents for organic dye removal from water., U cilju iskorišćenja vlaknastog tekstilnog otpada, kao i smanjenja njegove količine, otpadna prediva na bazi pamuka su korišćena kao jeftina sirovina za proizvodnju ugljeničnih materijala. Pamučno predivo, kao i predivo mešavine pamuka i poliestra, karbonizovani su primenom klasične ili hidrotermalne karbonizacije, i naknadno aktivirani u prisustvu KOH kao aktivirajućeg agensa. Strukturne i površinske karakteristike dobijenih ugljeničnih materijala ispitane su analizom adsorpciono-desorpcionih izotermi azota i rezultata Bemovih titracija, kao i skenirajućom elektronskom mikroskopijom i infracrvenom spektroskopijom sa Furijeovom transformacijom. Adsorpcija odabranih organskih boja iz vodenih rastvora je korišćenja za ispitivanje adsorpcionih karakteristika, a ispitan je i uticaj vremena kontakta, početne koncentracije i pH vrednosti rastvora adsorbata na adsorpcione kapacitete ugljeničnih adsorbenata. Pokazano je da prisustvo poliestarske komponente u strukturi prekursora ima negativan uticaj na adsorpcione karakteristike materijala dobijenih samo karbonizacijom. S druge strane, svi uzorci ugljeničnih materijala dobijeni karbonizacijom pređa na bazi pamuka i naknadnom aktivacijom pokazuju visoku efikasnost u uklanjanju boja iz vode.",
publisher = "Belgrade : Union of Engineers and Textile Technicians of Serbia",
journal = "Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September",
title = "ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN, ADSORPCIJA ORGANSKIH BOJA NA UGLJENIČNIM ADSORBENTIMA DOBIJENIM OD OTPADNOG PREDIVA PAMUKA I PAMUK/POLIESTRA",
pages = "402-394",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6642"
}
Maletić, M., Vukčević, M., Pejić, B., Kostić, M.,& Perić Grujić, A.. (2023). ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN. in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September
Belgrade : Union of Engineers and Textile Technicians of Serbia., 394-402.
https://hdl.handle.net/21.15107/rcub_technorep_6642
Maletić M, Vukčević M, Pejić B, Kostić M, Perić Grujić A. ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN. in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September. 2023;:394-402.
https://hdl.handle.net/21.15107/rcub_technorep_6642 .
Maletić, Marina, Vukčević, Marija, Pejić, Biljana, Kostić, Mirjana, Perić Grujić, Aleksandra, "ORGANIC DYES ADSORPTION ON CARBON ADSORBENTS DERIVED FROM WASTE COTTON AND COTTON/POLYESTER YARN" in Proceedings / VI International Scientific Conference Contemporary Trends and Innovations in the Textile Industry, CT&ITI, Belgrade, 14-15th September (2023):394-402,
https://hdl.handle.net/21.15107/rcub_technorep_6642 .

CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS

Vukčević, Marija; Maletić, Marina; Karić, Nataša; Pejić, Biljana; Trivunac, Katarina; Perić Grujić, Aleksandra

(Savez inženjera i tehničara tekstilaca Srbije, 2023)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Karić, Nataša
AU  - Pejić, Biljana
AU  - Trivunac, Katarina
AU  - Perić Grujić, Aleksandra
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6813
AB  - In an attempt to reuse fibrous textile waste, and at the same time to reduce its quantity, waste hemp and
flax fibers, and cotton yarn were used as cheap and sustainable adsorbents for the removal of pharmaceuticals
from water. In order to improve their adsorption properties, waste fibers, and yarn samples were modified using
18% NaOH solution. Morphology, surface chemistry, and structural characteristics were examined through scanning
electron microscopy, Fourier transform infrared spectroscopy, degree of surface crystallinity, and crystallinity
index. Adsorption properties were analyzed through the determination of iodine sorption and water retention, as
well as, the adsorption of selected sedatives. Modification with 18% NaOH increased the content of amorphous
areas in examined fibers and yarn samples, improving their adsorption characteristics. Utilization of both unmodified
and modified samples enables fast and highly efficient removal (adsorption efficiency ranging from 75 to
100%) of sedatives from water, making waste hemp and flax fibers and cotton yarn samples promising adsorbents
for water treatment.
AB  - U cilju smanjenja količine vlaknastog tekstilnog otpada, kao i njegove ponovne upotrebe, u ovom
radu je ispitana mogućnost primene otpadnih vlakana konoplje i lana i pamučnog prediva, kao jeftinih i održivih adsorbenata za uklanjanje lekova iz vode. Izvršena je hemijska modifikacija otpadnih vlakana i prediva 18%
rastvorom NaOH, da bi se poboljšala adsorpciona svojstva materijala. Morfologija, hemija površine i strukturne
karakteristike korišćenih materijala ispitane su skenirajućom elektronskom mikroskopijom, infracrvenom spektroskopijom sa Furijeovom transformacijom, kao i određivanjem stepena površinske kristaliničnosti i indeksa
kristalnosti. Adsorpciona svojstva su analizirana kroz vrednosti sorpcije joda i sposobnosti zadržavanja vode,
kao i određivanjem adsorpcionih kapaciteta ispitivanih materijala za uklanjanje odabranih sedativa. Primenjeni alkalni tretman dovodi do povećanja sadržaja amorfnih oblasti u ispitivanim uzorcima vlakana i prediva,
poboljšavajući njihove adsorpcione karakteristike. Dobijeni rezultati su pokazali da primena nemodifikovanih
i modifikovanih otpadnih vlakana konoplje i lana i pamučnog prediva omogućava brzo i visoko efikasno uklanjanje (efikasnost adsorpcije u opsegu 75 - 100%) sedativa iz vode.
PB  - Savez inženjera i tehničara tekstilaca Srbije
T2  - Tekstilna industrija
T1  - CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS
T1  - UTICAJ STRUKTURE I HEMIJSKOG SASTAVA CELULOZNOG OTPADA NA ADSORPCIJU FARMACEUTIKA
EP  - 12
IS  - 3
SP  - 4
VL  - 71
DO  - 10.5937/tekstind2303004V
ER  - 
@article{
author = "Vukčević, Marija and Maletić, Marina and Karić, Nataša and Pejić, Biljana and Trivunac, Katarina and Perić Grujić, Aleksandra",
year = "2023",
abstract = "In an attempt to reuse fibrous textile waste, and at the same time to reduce its quantity, waste hemp and
flax fibers, and cotton yarn were used as cheap and sustainable adsorbents for the removal of pharmaceuticals
from water. In order to improve their adsorption properties, waste fibers, and yarn samples were modified using
18% NaOH solution. Morphology, surface chemistry, and structural characteristics were examined through scanning
electron microscopy, Fourier transform infrared spectroscopy, degree of surface crystallinity, and crystallinity
index. Adsorption properties were analyzed through the determination of iodine sorption and water retention, as
well as, the adsorption of selected sedatives. Modification with 18% NaOH increased the content of amorphous
areas in examined fibers and yarn samples, improving their adsorption characteristics. Utilization of both unmodified
and modified samples enables fast and highly efficient removal (adsorption efficiency ranging from 75 to
100%) of sedatives from water, making waste hemp and flax fibers and cotton yarn samples promising adsorbents
for water treatment., U cilju smanjenja količine vlaknastog tekstilnog otpada, kao i njegove ponovne upotrebe, u ovom
radu je ispitana mogućnost primene otpadnih vlakana konoplje i lana i pamučnog prediva, kao jeftinih i održivih adsorbenata za uklanjanje lekova iz vode. Izvršena je hemijska modifikacija otpadnih vlakana i prediva 18%
rastvorom NaOH, da bi se poboljšala adsorpciona svojstva materijala. Morfologija, hemija površine i strukturne
karakteristike korišćenih materijala ispitane su skenirajućom elektronskom mikroskopijom, infracrvenom spektroskopijom sa Furijeovom transformacijom, kao i određivanjem stepena površinske kristaliničnosti i indeksa
kristalnosti. Adsorpciona svojstva su analizirana kroz vrednosti sorpcije joda i sposobnosti zadržavanja vode,
kao i određivanjem adsorpcionih kapaciteta ispitivanih materijala za uklanjanje odabranih sedativa. Primenjeni alkalni tretman dovodi do povećanja sadržaja amorfnih oblasti u ispitivanim uzorcima vlakana i prediva,
poboljšavajući njihove adsorpcione karakteristike. Dobijeni rezultati su pokazali da primena nemodifikovanih
i modifikovanih otpadnih vlakana konoplje i lana i pamučnog prediva omogućava brzo i visoko efikasno uklanjanje (efikasnost adsorpcije u opsegu 75 - 100%) sedativa iz vode.",
publisher = "Savez inženjera i tehničara tekstilaca Srbije",
journal = "Tekstilna industrija",
title = "CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS, UTICAJ STRUKTURE I HEMIJSKOG SASTAVA CELULOZNOG OTPADA NA ADSORPCIJU FARMACEUTIKA",
pages = "12-4",
number = "3",
volume = "71",
doi = "10.5937/tekstind2303004V"
}
Vukčević, M., Maletić, M., Karić, N., Pejić, B., Trivunac, K.,& Perić Grujić, A.. (2023). CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS. in Tekstilna industrija
Savez inženjera i tehničara tekstilaca Srbije., 71(3), 4-12.
https://doi.org/10.5937/tekstind2303004V
Vukčević M, Maletić M, Karić N, Pejić B, Trivunac K, Perić Grujić A. CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS. in Tekstilna industrija. 2023;71(3):4-12.
doi:10.5937/tekstind2303004V .
Vukčević, Marija, Maletić, Marina, Karić, Nataša, Pejić, Biljana, Trivunac, Katarina, Perić Grujić, Aleksandra, "CELLULOSE-BASED WASTE STRUCTURE AND CHEMICAL COMPOSITION IMPACT ON THE ADSORPTION OF PHARMACEUTICALS" in Tekstilna industrija, 71, no. 3 (2023):4-12,
https://doi.org/10.5937/tekstind2303004V . .
1

HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS

Pejić, Biljana; Vukčević, Marija; Kalijadis, Ana; Kostić, Mirjana

(Union of engineers and textile tehnicians of Serbia, Belgrade, Serbia,, 2022)

TY  - CONF
AU  - Pejić, Biljana
AU  - Vukčević, Marija
AU  - Kalijadis, Ana
AU  - Kostić, Mirjana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6085
AB  - This paper attempts to summarize the historical facts about the
cultivation and use of hemp in the world, and especially in Serbia, with a special
emphasis on the research and new application brought by the renaissance of hemp
production at the end of the 20th century. Hemp (Cannabis Sativa L.) as one of the
oldest cultivated plants represents a renewable and sustainable source of fibers, mainly
for textile production. Due to their specific chemical composition, structure and
properties, such as high specific strength, non-toxic, biocompatible and biodegradable
nature, hemp fibers become ideal candidates for a wide range of applications. Being
lignocellulosic, hemp can be used alone, or as combined with different kinds of polymers
to provide a wide range of useful composites in textiles, construction, automotive
industry, and soil conservation. Also, hemp fibers have proven to be efficient biosorbents
and suitable precursors for the production of low-cost carbon materials for adsorption
applications.
AB  - U ovom radu su sumirane istorijske činjenice o gajenju i upotrebi
konoplje u Srbiji i svetu, sa posebnim osvrtom na istraživanja i nove primene sa
renesansom konoplje krajem 20. veka. Konoplja (Canabis Sativa L) je jedna od
najstarijih gajenih biljaka, i predstavlja obnovljiv i održiv izvor vlakana, uglavnom za
tekstilnu industriju. Zbog svog specifičnog hemijskog sastava, strukture i svojstava, kao
što su visoka specifična čvrstoća, netoksičnost, biokompatibilnost i biorazgradivost,
vlakna konoplje imaju visok potencijal za primenu u različitim oblastima. Sama, ili kao
kompozit u kombinaciji sa različitim vrstama polimera, konoplja nalazi primenu u
oblastima tekstila, građevinarstva, automobilske industrije, očuvanja životne sredine.
Takođe, vlakna konoplje su se pokazala kao efikasni biosorbenti i pogodni prekursori za
proizvodnju jeftinih ugljeničnih adsorbenata za prečišćavanje vode od organskih i
neorganskih zagađujućih materija.
PB  - Union of engineers and textile tehnicians of Serbia, Belgrade, Serbia,
C3  - V Međunarodna konferencija „Savremeni trendovi i inovacije u tekstilnoj industriji“
T1  - HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS
EP  - 12
SP  - 3
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6085
ER  - 
@conference{
author = "Pejić, Biljana and Vukčević, Marija and Kalijadis, Ana and Kostić, Mirjana",
year = "2022",
abstract = "This paper attempts to summarize the historical facts about the
cultivation and use of hemp in the world, and especially in Serbia, with a special
emphasis on the research and new application brought by the renaissance of hemp
production at the end of the 20th century. Hemp (Cannabis Sativa L.) as one of the
oldest cultivated plants represents a renewable and sustainable source of fibers, mainly
for textile production. Due to their specific chemical composition, structure and
properties, such as high specific strength, non-toxic, biocompatible and biodegradable
nature, hemp fibers become ideal candidates for a wide range of applications. Being
lignocellulosic, hemp can be used alone, or as combined with different kinds of polymers
to provide a wide range of useful composites in textiles, construction, automotive
industry, and soil conservation. Also, hemp fibers have proven to be efficient biosorbents
and suitable precursors for the production of low-cost carbon materials for adsorption
applications., U ovom radu su sumirane istorijske činjenice o gajenju i upotrebi
konoplje u Srbiji i svetu, sa posebnim osvrtom na istraživanja i nove primene sa
renesansom konoplje krajem 20. veka. Konoplja (Canabis Sativa L) je jedna od
najstarijih gajenih biljaka, i predstavlja obnovljiv i održiv izvor vlakana, uglavnom za
tekstilnu industriju. Zbog svog specifičnog hemijskog sastava, strukture i svojstava, kao
što su visoka specifična čvrstoća, netoksičnost, biokompatibilnost i biorazgradivost,
vlakna konoplje imaju visok potencijal za primenu u različitim oblastima. Sama, ili kao
kompozit u kombinaciji sa različitim vrstama polimera, konoplja nalazi primenu u
oblastima tekstila, građevinarstva, automobilske industrije, očuvanja životne sredine.
Takođe, vlakna konoplje su se pokazala kao efikasni biosorbenti i pogodni prekursori za
proizvodnju jeftinih ugljeničnih adsorbenata za prečišćavanje vode od organskih i
neorganskih zagađujućih materija.",
publisher = "Union of engineers and textile tehnicians of Serbia, Belgrade, Serbia,",
journal = "V Međunarodna konferencija „Savremeni trendovi i inovacije u tekstilnoj industriji“",
title = "HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS",
pages = "12-3",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6085"
}
Pejić, B., Vukčević, M., Kalijadis, A.,& Kostić, M.. (2022). HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS. in V Međunarodna konferencija „Savremeni trendovi i inovacije u tekstilnoj industriji“
Union of engineers and textile tehnicians of Serbia, Belgrade, Serbia,., 3-12.
https://hdl.handle.net/21.15107/rcub_technorep_6085
Pejić B, Vukčević M, Kalijadis A, Kostić M. HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS. in V Međunarodna konferencija „Savremeni trendovi i inovacije u tekstilnoj industriji“. 2022;:3-12.
https://hdl.handle.net/21.15107/rcub_technorep_6085 .
Pejić, Biljana, Vukčević, Marija, Kalijadis, Ana, Kostić, Mirjana, "HEMP FIBERS AGAIN IN SERBIA: OLD FIBERS – NEW APPLICATIONS" in V Međunarodna konferencija „Savremeni trendovi i inovacije u tekstilnoj industriji“ (2022):3-12,
https://hdl.handle.net/21.15107/rcub_technorep_6085 .

The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions

Bajić, Ivana; Pejić, Borivoj; Sikora, Vladimir; Kostić, Mirjana; Ivanovska, Aleksandra; Pejić, Biljana; Vojnov, Bojan

(MDPI, 2022)

TY  - JOUR
AU  - Bajić, Ivana
AU  - Pejić, Borivoj
AU  - Sikora, Vladimir
AU  - Kostić, Mirjana
AU  - Ivanovska, Aleksandra
AU  - Pejić, Biljana
AU  - Vojnov, Bojan
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5972
AB  - The study was aimed at determining the most suitable irrigation schedule program for hemp grown for fibers by using evaporation from the free water surface (Eo), measured by a Class A pan and related crop plant coefficient (Kc). The experiment, carried out in Vojvodina, a northern part of the Republic of Serbia, included three irrigation regimes: I1, I2, and I3 corresponding, respectively, to daily evaporation from an open water surface (Eo), two interrow spacings: RS1 (12.5 cm) and RS2 (25 cm), and topped (T) and not topped (NT) variants. The Kc values used for the calculation of daily evapotranspiration (ETd) were 0.42 for April and May and 1.00 (I1), 0.80 (I2), and 0.60 (I3) from June to the harvest. In addition, the nonirrigated (Io) control variant was also included in the trial. The dioecious fiber hemp variety Marina was used for the trials. Irrigation was carried out by a drip irrigation system and was scheduled based on the water budget method. It started when readily available water (RAW) in the soil layer of 0.4 m was completely depleted by the plants. In the first year of the study, irrigation did not influence the yield of hemp fiber, but in the second one, the best result was achieved for the irrigation variant I1. Interrow spacing did not have a statistically significant effect on both the hemp fiber yield and the quality. The topping of plants significantly decreased the yield of hemp, and it is not recommended when the hemp is cultivated for fibers. The quality of the hemp fibers was not influenced by irrigation, inter-row spacing, and topping. The rate of hemp evapotranspiration was in an interval of 312 mm (ETa) to 520 mm (ETm). The highest values of IWUE and ETWUE in both years and the bark yield in the first year were detected for the I3 irrigation variant, which suggested that the crop plant coefficient (Kc) of 0.6 could be recommended for the correction of Eo values in the calculation of the daily evapotranspiration of hemp (ETd) from June to August. The yield response factor (Ky) with values of 0.22 and 0.60 for the total growing season reveals that, in rainy years, hemp for fiber production could be grown without irrigation in the temperate climate of the Vojvodina region. However, such years are rare. Without doubt, irrigation of fiber hemp is recommended in the mentioned region in order to obtain high yields of good quality product.
PB  - MDPI
T2  - Agriculture
T1  - The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions
IS  - 11
SP  - 1923
VL  - 12
DO  - 10.3390/agriculture12111923
ER  - 
@article{
author = "Bajić, Ivana and Pejić, Borivoj and Sikora, Vladimir and Kostić, Mirjana and Ivanovska, Aleksandra and Pejić, Biljana and Vojnov, Bojan",
year = "2022",
abstract = "The study was aimed at determining the most suitable irrigation schedule program for hemp grown for fibers by using evaporation from the free water surface (Eo), measured by a Class A pan and related crop plant coefficient (Kc). The experiment, carried out in Vojvodina, a northern part of the Republic of Serbia, included three irrigation regimes: I1, I2, and I3 corresponding, respectively, to daily evaporation from an open water surface (Eo), two interrow spacings: RS1 (12.5 cm) and RS2 (25 cm), and topped (T) and not topped (NT) variants. The Kc values used for the calculation of daily evapotranspiration (ETd) were 0.42 for April and May and 1.00 (I1), 0.80 (I2), and 0.60 (I3) from June to the harvest. In addition, the nonirrigated (Io) control variant was also included in the trial. The dioecious fiber hemp variety Marina was used for the trials. Irrigation was carried out by a drip irrigation system and was scheduled based on the water budget method. It started when readily available water (RAW) in the soil layer of 0.4 m was completely depleted by the plants. In the first year of the study, irrigation did not influence the yield of hemp fiber, but in the second one, the best result was achieved for the irrigation variant I1. Interrow spacing did not have a statistically significant effect on both the hemp fiber yield and the quality. The topping of plants significantly decreased the yield of hemp, and it is not recommended when the hemp is cultivated for fibers. The quality of the hemp fibers was not influenced by irrigation, inter-row spacing, and topping. The rate of hemp evapotranspiration was in an interval of 312 mm (ETa) to 520 mm (ETm). The highest values of IWUE and ETWUE in both years and the bark yield in the first year were detected for the I3 irrigation variant, which suggested that the crop plant coefficient (Kc) of 0.6 could be recommended for the correction of Eo values in the calculation of the daily evapotranspiration of hemp (ETd) from June to August. The yield response factor (Ky) with values of 0.22 and 0.60 for the total growing season reveals that, in rainy years, hemp for fiber production could be grown without irrigation in the temperate climate of the Vojvodina region. However, such years are rare. Without doubt, irrigation of fiber hemp is recommended in the mentioned region in order to obtain high yields of good quality product.",
publisher = "MDPI",
journal = "Agriculture",
title = "The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions",
number = "11",
pages = "1923",
volume = "12",
doi = "10.3390/agriculture12111923"
}
Bajić, I., Pejić, B., Sikora, V., Kostić, M., Ivanovska, A., Pejić, B.,& Vojnov, B.. (2022). The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions. in Agriculture
MDPI., 12(11), 1923.
https://doi.org/10.3390/agriculture12111923
Bajić I, Pejić B, Sikora V, Kostić M, Ivanovska A, Pejić B, Vojnov B. The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions. in Agriculture. 2022;12(11):1923.
doi:10.3390/agriculture12111923 .
Bajić, Ivana, Pejić, Borivoj, Sikora, Vladimir, Kostić, Mirjana, Ivanovska, Aleksandra, Pejić, Biljana, Vojnov, Bojan, "The Effects of Irrigation, Topping, and Interrow Spacing on the Yield and Quality of Hemp (Cannabis sativa L.) Fibers in Temperate Climatic Conditions" in Agriculture, 12, no. 11 (2022):1923,
https://doi.org/10.3390/agriculture12111923 . .
1
2

Modification of cellulose-based waste materials for removal of methylene blue from wastewater

Vukčević, Marija; Maletić, Marina; Karić, Nataša; Pejić, Biljana; Trivunac, Katarina; Perić-Grujić, Aleksandra

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Karić, Nataša
AU  - Pejić, Biljana
AU  - Trivunac, Katarina
AU  - Perić-Grujić, Aleksandra
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6061
AB  - Different natural fibers and yarns (hemp, flax, and cotton), obtained as a waste from textile industry,
were used for the removal of methylene blue from aqueous solution. In attempt to increase the
adsorption efficiency, examined fibers and yarn were modified by sodium hydroxide solution.
Characterization of examined samples was performed by scanning electron microscopy and Fourier
transform infrared spectroscopy. It was shown that applied modification caused the differences in the
distribution of hemicelluloses in the structure of examined fibers and fibers in yarn, inducing the
changes in morphology and surface chemistry. These changes slightly improved the adsorption
properties of hemp fibers, while in the case of cotton yarn modification had a negative effect on
methylene blue adsorption. Nevertheless, adsorption efficiency of these waste fibers and yarns highly
increase with the pH of the solution, enabling their utilization for methylene blue removal from
wastewaters.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Modification of cellulose-based waste materials for removal of methylene blue from wastewater
EP  - 476
IS  - 473
VL  - 2
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6061
ER  - 
@conference{
author = "Vukčević, Marija and Maletić, Marina and Karić, Nataša and Pejić, Biljana and Trivunac, Katarina and Perić-Grujić, Aleksandra",
year = "2022",
abstract = "Different natural fibers and yarns (hemp, flax, and cotton), obtained as a waste from textile industry,
were used for the removal of methylene blue from aqueous solution. In attempt to increase the
adsorption efficiency, examined fibers and yarn were modified by sodium hydroxide solution.
Characterization of examined samples was performed by scanning electron microscopy and Fourier
transform infrared spectroscopy. It was shown that applied modification caused the differences in the
distribution of hemicelluloses in the structure of examined fibers and fibers in yarn, inducing the
changes in morphology and surface chemistry. These changes slightly improved the adsorption
properties of hemp fibers, while in the case of cotton yarn modification had a negative effect on
methylene blue adsorption. Nevertheless, adsorption efficiency of these waste fibers and yarns highly
increase with the pH of the solution, enabling their utilization for methylene blue removal from
wastewaters.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Modification of cellulose-based waste materials for removal of methylene blue from wastewater",
pages = "476",
number = "473",
volume = "2",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6061"
}
Vukčević, M., Maletić, M., Karić, N., Pejić, B., Trivunac, K.,& Perić-Grujić, A.. (2022). Modification of cellulose-based waste materials for removal of methylene blue from wastewater. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Belgrade : Society of Physical Chemists of Serbia., 2(473).
https://hdl.handle.net/21.15107/rcub_technorep_6061
Vukčević M, Maletić M, Karić N, Pejić B, Trivunac K, Perić-Grujić A. Modification of cellulose-based waste materials for removal of methylene blue from wastewater. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2022;2(473):null-476.
https://hdl.handle.net/21.15107/rcub_technorep_6061 .
Vukčević, Marija, Maletić, Marina, Karić, Nataša, Pejić, Biljana, Trivunac, Katarina, Perić-Grujić, Aleksandra, "Modification of cellulose-based waste materials for removal of methylene blue from wastewater" in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, 2, no. 473 (2022),
https://hdl.handle.net/21.15107/rcub_technorep_6061 .

Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra

Mihajlović, Snežana; Maletić, Marina; Pejić, Biljana; Ristić, Mirjana; Perić-Grujić, Aleksandra; Trivunac, Katarina; Vukčević, Marija

(Akademija tehničkih strukovnih studija Beograd, 2021)

TY  - CONF
AU  - Mihajlović, Snežana
AU  - Maletić, Marina
AU  - Pejić, Biljana
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
AU  - Trivunac, Katarina
AU  - Vukčević, Marija
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6306
AB  - U ovom radu je ispitana mogućnost korišćenja otpadnih pamučnih pređa kao adsorbenta
za uklanjanje olova i hroma iz vode, čime bi se obezbedilo ponovno korišćenje tekstilnog otpada i
smanjenje troškova njegovog odlaganja. Karakterizacija pamučne pređe (CY) i mešavine
pamuk/poliestar (CY/PES) izvršena je skenirajućom elektronskom mikroskopijom, infracrvenom
spektroskopijom sa Furijeovom transformacijom, ispitivanjem sorpcije joda i zadržavanja vode,
kao i određivanjem izoelektrične tačke. Dobijeni rezultati su pokazali da prisustvo poliestarske
komponente u strukturi CY/PES dovodi do smanjenja poroznosti površine pređe, kao i do povećanja
površinske i strukturne kristaličnosti. Ove promene u strukturnim i površinskim karakteristikama
imaju za posledicu nešto niži adsorpcioni kapacitet pređe CY/PES u poređenju sa pamučnom
pređom. Obe pređe, CY i CY/PES, pokazuju relativno brzu adsorpciju jona olova i hroma, koja
prati zakon kinetike pseudo-drugog reda, dok se ravnotežni adsorpcioni podaci mogu opisati
modelom Lengmirove izoterme. Pokazano je da se obe ispitane pređe mogu primeniti kao jeftini
adsorbenti za efikasno uklanjanje jona olova i hroma iz vode, istovremeno zadovoljavajući zahteve
čistije životne sredine i cirkularne ekonomije.
PB  - Akademija tehničkih strukovnih studija Beograd
C3  - Šesti naučno-stručni skup Politehnika, Zbornik radova
T1  - Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra
EP  - 123
SP  - 118
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6306
ER  - 
@conference{
author = "Mihajlović, Snežana and Maletić, Marina and Pejić, Biljana and Ristić, Mirjana and Perić-Grujić, Aleksandra and Trivunac, Katarina and Vukčević, Marija",
year = "2021",
abstract = "U ovom radu je ispitana mogućnost korišćenja otpadnih pamučnih pređa kao adsorbenta
za uklanjanje olova i hroma iz vode, čime bi se obezbedilo ponovno korišćenje tekstilnog otpada i
smanjenje troškova njegovog odlaganja. Karakterizacija pamučne pređe (CY) i mešavine
pamuk/poliestar (CY/PES) izvršena je skenirajućom elektronskom mikroskopijom, infracrvenom
spektroskopijom sa Furijeovom transformacijom, ispitivanjem sorpcije joda i zadržavanja vode,
kao i određivanjem izoelektrične tačke. Dobijeni rezultati su pokazali da prisustvo poliestarske
komponente u strukturi CY/PES dovodi do smanjenja poroznosti površine pređe, kao i do povećanja
površinske i strukturne kristaličnosti. Ove promene u strukturnim i površinskim karakteristikama
imaju za posledicu nešto niži adsorpcioni kapacitet pređe CY/PES u poređenju sa pamučnom
pređom. Obe pređe, CY i CY/PES, pokazuju relativno brzu adsorpciju jona olova i hroma, koja
prati zakon kinetike pseudo-drugog reda, dok se ravnotežni adsorpcioni podaci mogu opisati
modelom Lengmirove izoterme. Pokazano je da se obe ispitane pređe mogu primeniti kao jeftini
adsorbenti za efikasno uklanjanje jona olova i hroma iz vode, istovremeno zadovoljavajući zahteve
čistije životne sredine i cirkularne ekonomije.",
publisher = "Akademija tehničkih strukovnih studija Beograd",
journal = "Šesti naučno-stručni skup Politehnika, Zbornik radova",
title = "Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra",
pages = "123-118",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6306"
}
Mihajlović, S., Maletić, M., Pejić, B., Ristić, M., Perić-Grujić, A., Trivunac, K.,& Vukčević, M.. (2021). Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra. in Šesti naučno-stručni skup Politehnika, Zbornik radova
Akademija tehničkih strukovnih studija Beograd., 118-123.
https://hdl.handle.net/21.15107/rcub_technorep_6306
Mihajlović S, Maletić M, Pejić B, Ristić M, Perić-Grujić A, Trivunac K, Vukčević M. Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra. in Šesti naučno-stručni skup Politehnika, Zbornik radova. 2021;:118-123.
https://hdl.handle.net/21.15107/rcub_technorep_6306 .
Mihajlović, Snežana, Maletić, Marina, Pejić, Biljana, Ristić, Mirjana, Perić-Grujić, Aleksandra, Trivunac, Katarina, Vukčević, Marija, "Uklanjanje hroma i olova iz vode korišćenjem otpadnih pređa pamuka i mešavine pamuka i poliestra" in Šesti naučno-stručni skup Politehnika, Zbornik radova (2021):118-123,
https://hdl.handle.net/21.15107/rcub_technorep_6306 .

Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater

Mihajlović, Snežana; Vukčević, Marija; Maletić, Marina; Pejić, Biljana; Perić-Grujić, Aleksandra; Ristić, Mirjana; Trivunac, Katarina

(Society of Physical Chemists of Serbia, 2021)

TY  - CONF
AU  - Mihajlović, Snežana
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Pejić, Biljana
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
AU  - Trivunac, Katarina
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6330
AB  - Waste cotton/polyester yarn was used for the removal of Pb(II), Cd(II), Cr(III) and As(V) ions from aqueous solution. In attempt to increase the adsorption efficiency, cotton/polyester yarn was modified by sodium hydroxide solution. Characterization of examined yarns was performed by scanning electron microscopy, Fourier transform infrared spectroscopy and streaming potential method for determination of the isoelectric point. It was shown that applied treatments slightly affected the surface acidity due to increased availability of ester groups and changes in cellulose-derived groups. These changes in surface chemistry of modified cotton/polyester yarns did not improve their adsorption capacity for Cd(II), Cr(III) and As(V) ions. However, both unmodified and modified waste cotton/polyester yarns could be used for efficient removal of lead ions from wastewater.
PB  - Society of Physical Chemists of Serbia
C3  - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Proceedings
T1  - Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater
EP  - 631
SP  - 628
VL  - 2
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6330
ER  - 
@conference{
author = "Mihajlović, Snežana and Vukčević, Marija and Maletić, Marina and Pejić, Biljana and Perić-Grujić, Aleksandra and Ristić, Mirjana and Trivunac, Katarina",
year = "2021",
abstract = "Waste cotton/polyester yarn was used for the removal of Pb(II), Cd(II), Cr(III) and As(V) ions from aqueous solution. In attempt to increase the adsorption efficiency, cotton/polyester yarn was modified by sodium hydroxide solution. Characterization of examined yarns was performed by scanning electron microscopy, Fourier transform infrared spectroscopy and streaming potential method for determination of the isoelectric point. It was shown that applied treatments slightly affected the surface acidity due to increased availability of ester groups and changes in cellulose-derived groups. These changes in surface chemistry of modified cotton/polyester yarns did not improve their adsorption capacity for Cd(II), Cr(III) and As(V) ions. However, both unmodified and modified waste cotton/polyester yarns could be used for efficient removal of lead ions from wastewater.",
publisher = "Society of Physical Chemists of Serbia",
journal = "15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Proceedings",
title = "Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater",
pages = "631-628",
volume = "2",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6330"
}
Mihajlović, S., Vukčević, M., Maletić, M., Pejić, B., Perić-Grujić, A., Ristić, M.,& Trivunac, K.. (2021). Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater. in 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Proceedings
Society of Physical Chemists of Serbia., 2, 628-631.
https://hdl.handle.net/21.15107/rcub_technorep_6330
Mihajlović S, Vukčević M, Maletić M, Pejić B, Perić-Grujić A, Ristić M, Trivunac K. Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater. in 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Proceedings. 2021;2:628-631.
https://hdl.handle.net/21.15107/rcub_technorep_6330 .
Mihajlović, Snežana, Vukčević, Marija, Maletić, Marina, Pejić, Biljana, Perić-Grujić, Aleksandra, Ristić, Mirjana, Trivunac, Katarina, "Waste cotton polyester yarn as an adsorbent for the removal of heavy metals from wastewater" in 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Proceedings, 2 (2021):628-631,
https://hdl.handle.net/21.15107/rcub_technorep_6330 .

Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.)

Pejić, Biljana; Kramar, Ana; Obradović, Bratislav M.; Kuraica, Milorad M.; Žekić, Andrijana; Kostić, Mirjana

(Elsevier Sci Ltd, Oxford, 2020)

TY  - JOUR
AU  - Pejić, Biljana
AU  - Kramar, Ana
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Žekić, Andrijana
AU  - Kostić, Mirjana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4493
AB  - Hemp fibers with different amount of hemicelluloses and lignin were subjected to atmospheric pressure dielectric barrier discharge under different conditions (40 W and 80 W power of discharge, const. time 120 s) in order to study influence of plasma treatment on their structure and sorption properties. Wettability of plasma treated samples, compared with precursors, increased due to the changes in hemp fiber surface chemistry confirmed by ATR FTIR spectroscopy and increased roughness as a consequence of intensive surface etching, observed by SEM. After plasma treatment, wettability was the highest for hemp fibers with lower content of hemicelluloses (increase up to 9 times), while wettability of raw hemp fibers and fibers with lower content of lignin increased about 5 and 2 times, respectively. This investigation shows that plasma can be successfully used for improvement of raw hemp fibers wettability, even to substitute the chemical treatment for some applications of hemp.
PB  - Elsevier Sci Ltd, Oxford
T2  - Carbohydrate Polymers
T1  - Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.)
VL  - 236
DO  - 10.1016/j.carbpol.2020.116000
ER  - 
@article{
author = "Pejić, Biljana and Kramar, Ana and Obradović, Bratislav M. and Kuraica, Milorad M. and Žekić, Andrijana and Kostić, Mirjana",
year = "2020",
abstract = "Hemp fibers with different amount of hemicelluloses and lignin were subjected to atmospheric pressure dielectric barrier discharge under different conditions (40 W and 80 W power of discharge, const. time 120 s) in order to study influence of plasma treatment on their structure and sorption properties. Wettability of plasma treated samples, compared with precursors, increased due to the changes in hemp fiber surface chemistry confirmed by ATR FTIR spectroscopy and increased roughness as a consequence of intensive surface etching, observed by SEM. After plasma treatment, wettability was the highest for hemp fibers with lower content of hemicelluloses (increase up to 9 times), while wettability of raw hemp fibers and fibers with lower content of lignin increased about 5 and 2 times, respectively. This investigation shows that plasma can be successfully used for improvement of raw hemp fibers wettability, even to substitute the chemical treatment for some applications of hemp.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Carbohydrate Polymers",
title = "Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.)",
volume = "236",
doi = "10.1016/j.carbpol.2020.116000"
}
Pejić, B., Kramar, A., Obradović, B. M., Kuraica, M. M., Žekić, A.,& Kostić, M.. (2020). Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.). in Carbohydrate Polymers
Elsevier Sci Ltd, Oxford., 236.
https://doi.org/10.1016/j.carbpol.2020.116000
Pejić B, Kramar A, Obradović BM, Kuraica MM, Žekić A, Kostić M. Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.). in Carbohydrate Polymers. 2020;236.
doi:10.1016/j.carbpol.2020.116000 .
Pejić, Biljana, Kramar, Ana, Obradović, Bratislav M., Kuraica, Milorad M., Žekić, Andrijana, Kostić, Mirjana, "Effect of plasma treatment on chemical composition, structure and sorption properties of lignocellulosic hemp fibers (Cannabis sativa L.)" in Carbohydrate Polymers, 236 (2020),
https://doi.org/10.1016/j.carbpol.2020.116000 . .
46
14
38

Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions

Mihajlović, Snežana; Vukčević, Marija; Pejić, Biljana; Perić-Grujić, Aleksandra; Ristić, Mirjana

(Springer Heidelberg, Heidelberg, 2020)

TY  - JOUR
AU  - Mihajlović, Snežana
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4509
AB  - In this study, waste cotton yarn was used for the removal of Pb (II), Cd (II), Cr (III), and As (V) from aqueous solution. Adsorption of heavy metal ions was tested from single ion solutions, while competitive studies were performed using two- and four-ion mixtures. In order to change the structure of the material, cotton yarn was modified by sodium hydroxide solution. The surface of raw and modified cotton yarn were characterized using scanning electron microscopy, Fourier transform infrared spectroscopy, and streaming potential method for determination of an isoelectric point. Sorption studies were performed on the basis of pH, kinetics, isotherms, and desorption results. It has been shown that waste cotton yarn modification, typically, does not improve the sorption capacity of the material and that the unmodified material could be used for the removal of examined heavy metal ions. Selectivity was in order Pb  gt  Cd  gt  Cr  gt  As. Desorption studies have indicated to the possible reusability of the sorbent only in the case of Pb removal. A potential application of spent waste sorbent for the soil quality improvement has been considered.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions
EP  - 35781
IS  - 28
SP  - 35769
VL  - 27
DO  - 10.1007/s11356-020-09811-z
ER  - 
@article{
author = "Mihajlović, Snežana and Vukčević, Marija and Pejić, Biljana and Perić-Grujić, Aleksandra and Ristić, Mirjana",
year = "2020",
abstract = "In this study, waste cotton yarn was used for the removal of Pb (II), Cd (II), Cr (III), and As (V) from aqueous solution. Adsorption of heavy metal ions was tested from single ion solutions, while competitive studies were performed using two- and four-ion mixtures. In order to change the structure of the material, cotton yarn was modified by sodium hydroxide solution. The surface of raw and modified cotton yarn were characterized using scanning electron microscopy, Fourier transform infrared spectroscopy, and streaming potential method for determination of an isoelectric point. Sorption studies were performed on the basis of pH, kinetics, isotherms, and desorption results. It has been shown that waste cotton yarn modification, typically, does not improve the sorption capacity of the material and that the unmodified material could be used for the removal of examined heavy metal ions. Selectivity was in order Pb  gt  Cd  gt  Cr  gt  As. Desorption studies have indicated to the possible reusability of the sorbent only in the case of Pb removal. A potential application of spent waste sorbent for the soil quality improvement has been considered.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions",
pages = "35781-35769",
number = "28",
volume = "27",
doi = "10.1007/s11356-020-09811-z"
}
Mihajlović, S., Vukčević, M., Pejić, B., Perić-Grujić, A.,& Ristić, M.. (2020). Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 27(28), 35769-35781.
https://doi.org/10.1007/s11356-020-09811-z
Mihajlović S, Vukčević M, Pejić B, Perić-Grujić A, Ristić M. Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions. in Environmental Science and Pollution Research. 2020;27(28):35769-35781.
doi:10.1007/s11356-020-09811-z .
Mihajlović, Snežana, Vukčević, Marija, Pejić, Biljana, Perić-Grujić, Aleksandra, Ristić, Mirjana, "Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions" in Environmental Science and Pollution Research, 27, no. 28 (2020):35769-35781,
https://doi.org/10.1007/s11356-020-09811-z . .
13
5
15

Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications

Kostić, Mirjana; Pejić, Biljana; Vukčević, Marija

(Pessac : Presses Universitaires de Bordeaux, 2019)

TY  - CHAP
AU  - Kostić, Mirjana
AU  - Pejić, Biljana
AU  - Vukčević, Marija
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7023
PB  - Pessac : Presses Universitaires de Bordeaux
T2  - Chimie pour la transformation durable de la ressource lignocellulosique
T1  - Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications
EP  - 69
SP  - 27
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7023
ER  - 
@inbook{
author = "Kostić, Mirjana and Pejić, Biljana and Vukčević, Marija",
year = "2019",
publisher = "Pessac : Presses Universitaires de Bordeaux",
journal = "Chimie pour la transformation durable de la ressource lignocellulosique",
booktitle = "Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications",
pages = "69-27",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7023"
}
Kostić, M., Pejić, B.,& Vukčević, M.. (2019). Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications. in Chimie pour la transformation durable de la ressource lignocellulosique
Pessac : Presses Universitaires de Bordeaux., 27-69.
https://hdl.handle.net/21.15107/rcub_technorep_7023
Kostić M, Pejić B, Vukčević M. Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications. in Chimie pour la transformation durable de la ressource lignocellulosique. 2019;:27-69.
https://hdl.handle.net/21.15107/rcub_technorep_7023 .
Kostić, Mirjana, Pejić, Biljana, Vukčević, Marija, "Cellulose provenant de fibres libériennes et autres fibres textiles - nouvelles applications" in Chimie pour la transformation durable de la ressource lignocellulosique (2019):27-69,
https://hdl.handle.net/21.15107/rcub_technorep_7023 .

Cellulose fibers: Trends in production and applications

Kostić, Mirjana; Pejić, Biljana; Milanović, Jovana; Kramar, Ana

(Union of Textile Engineers and Technicians of Serbia, Belgrade, 2018)

TY  - JOUR
AU  - Kostić, Mirjana
AU  - Pejić, Biljana
AU  - Milanović, Jovana
AU  - Kramar, Ana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3830
AB  - The paper gives an overview of the current state in the field of natural and chemical cellulose fibers, as well as future prospects of these fibers. While there is a strong expansion of the synthetic fibers industry, world production and consumption of natural and chemical cellulosic fibers were stabilized at certain level with small oscillation in the last few years. Cotton production reaches average level at 25 mil.ton, flax production at 0.8 mil. ton, hemp production at 0.07 mil.ton and jute production at 3.3 mil.ton, while chemical cellulosic fiber production reaches average level at 6 mil.ton. It is expected that cellulose fibers only for clothing, will be in demand up to 40 mil.ton in the year 2050 due to growing market of hydrophylic fibers and tendency to develop production of natural, light, renewable and biodegradable fibers. In this regard, bast fibers, such as flax, hemp, jute, ramie, etc., isolated from plants that cause little or no detrimental effect on the ecosystem, acquire enormous significance. Their modification and conversion into novel value-added products have been discussed.
AB  - U radu je prikazano sadašnje stanje u oblasti prirodnih i hemijskih celuloznih vlakana, kao i očekivanja vezana za ova vlakna. U poređenju sa ekspanzivnim razvojem sintetizovanih vlakana, svetska proizvodnja i potrošnja prirodnih i hemijskih celuloznih vlakana se stabilizovala na određenom nivou: proizvodnja pamuka oko 25 mil.tona, lana 0,8 mil.tona, konoplje oko 0,07 mil.tona, jute oko 3,3 mil.tona, a hemijskih celuloznih vlakana na nivou od oko 6 mil.tona. Očekuje se da će do 2050.god, zahvaljujući rastućem tržištu hidrofilnih vlakana i tendenciji ka razvoju proizvodnje lakih, prirodnih, obnovljivih i biorazgradivih vlakana, potrebe za ovim vlaknima, samo u oblasti odevnog tekstila, dostići nivo od oko 40 mil.tona. Posebno je analiziran potencijal vlakna iz like (lan, konoplja, juta, ramija), njihovo modifikovanje i konverzija u nove proizvode visoke dodate vrednosti, s obzirom da biljke iz kojih se ova vlakna izoluju, kao i sam proces njihove prerade, nemaju negativni uticaj na ekosistem.
PB  - Union of Textile Engineers and Technicians of Serbia, Belgrade
T2  - Tekstilna industrija
T1  - Cellulose fibers: Trends in production and applications
T1  - Celulozna vlakna - trendovi u proizvodnji i primeni
EP  - 24
IS  - 4
SP  - 16
VL  - 66
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3830
ER  - 
@article{
author = "Kostić, Mirjana and Pejić, Biljana and Milanović, Jovana and Kramar, Ana",
year = "2018",
abstract = "The paper gives an overview of the current state in the field of natural and chemical cellulose fibers, as well as future prospects of these fibers. While there is a strong expansion of the synthetic fibers industry, world production and consumption of natural and chemical cellulosic fibers were stabilized at certain level with small oscillation in the last few years. Cotton production reaches average level at 25 mil.ton, flax production at 0.8 mil. ton, hemp production at 0.07 mil.ton and jute production at 3.3 mil.ton, while chemical cellulosic fiber production reaches average level at 6 mil.ton. It is expected that cellulose fibers only for clothing, will be in demand up to 40 mil.ton in the year 2050 due to growing market of hydrophylic fibers and tendency to develop production of natural, light, renewable and biodegradable fibers. In this regard, bast fibers, such as flax, hemp, jute, ramie, etc., isolated from plants that cause little or no detrimental effect on the ecosystem, acquire enormous significance. Their modification and conversion into novel value-added products have been discussed., U radu je prikazano sadašnje stanje u oblasti prirodnih i hemijskih celuloznih vlakana, kao i očekivanja vezana za ova vlakna. U poređenju sa ekspanzivnim razvojem sintetizovanih vlakana, svetska proizvodnja i potrošnja prirodnih i hemijskih celuloznih vlakana se stabilizovala na određenom nivou: proizvodnja pamuka oko 25 mil.tona, lana 0,8 mil.tona, konoplje oko 0,07 mil.tona, jute oko 3,3 mil.tona, a hemijskih celuloznih vlakana na nivou od oko 6 mil.tona. Očekuje se da će do 2050.god, zahvaljujući rastućem tržištu hidrofilnih vlakana i tendenciji ka razvoju proizvodnje lakih, prirodnih, obnovljivih i biorazgradivih vlakana, potrebe za ovim vlaknima, samo u oblasti odevnog tekstila, dostići nivo od oko 40 mil.tona. Posebno je analiziran potencijal vlakna iz like (lan, konoplja, juta, ramija), njihovo modifikovanje i konverzija u nove proizvode visoke dodate vrednosti, s obzirom da biljke iz kojih se ova vlakna izoluju, kao i sam proces njihove prerade, nemaju negativni uticaj na ekosistem.",
publisher = "Union of Textile Engineers and Technicians of Serbia, Belgrade",
journal = "Tekstilna industrija",
title = "Cellulose fibers: Trends in production and applications, Celulozna vlakna - trendovi u proizvodnji i primeni",
pages = "24-16",
number = "4",
volume = "66",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3830"
}
Kostić, M., Pejić, B., Milanović, J.,& Kramar, A.. (2018). Cellulose fibers: Trends in production and applications. in Tekstilna industrija
Union of Textile Engineers and Technicians of Serbia, Belgrade., 66(4), 16-24.
https://hdl.handle.net/21.15107/rcub_technorep_3830
Kostić M, Pejić B, Milanović J, Kramar A. Cellulose fibers: Trends in production and applications. in Tekstilna industrija. 2018;66(4):16-24.
https://hdl.handle.net/21.15107/rcub_technorep_3830 .
Kostić, Mirjana, Pejić, Biljana, Milanović, Jovana, Kramar, Ana, "Cellulose fibers: Trends in production and applications" in Tekstilna industrija, 66, no. 4 (2018):16-24,
https://hdl.handle.net/21.15107/rcub_technorep_3830 .

Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions

Milivojević, Milan; Pejić, Biljana; Vukčević, Marija; Kostić, Mirjana

(Engineering Society for Corrosion, Belgrade, Serbia, 2018)

TY  - JOUR
AU  - Milivojević, Milan
AU  - Pejić, Biljana
AU  - Vukčević, Marija
AU  - Kostić, Mirjana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3833
AB  - In this paper the possibility of implementing the new biosorbent composed of chemically modified short hemp fibers impregnated with alginate gel for adsorption of lead(II) and zinc (II) ions was investigated. Waste hemp fibers, alkaly treated, were used as an alginate carrier in order to improve the mechanical stability of alginate. Morphological characteristics of obtained alginate-hemp composite were investigated by scanning electron microscopy (SEM), while the Fourier transform infrared spectroscopy (FT-IR) was used for examination of surface chemistry. Alginate immobilization on the hemp fibers surface leads to the morphological changes, by decreasing the roughness of short hemp fibers. FT-IR analysis showed that surface chemistry was changed after alginate immobilization, primarily by increasing the amount of carboxyl groups. The presence of surface groups characteristic for hemp fibers, on the surface of biocomposite, indicate that the surface of hemp fibers is not completely covered by alginate. Adsorption characteristics of alginate-hemp biosorbent were examined through the adsorption of lead and zinc ions, and compared with the adsorption characteristics of alkali treated hemp fibers. Biosorption of lead and zinc ions onto both hemp fibers and alginate-hemp composite, represent fast process since 80 % of initial ions amount were adsorbed in first five minutes. Obtained adsorption data were analyzed by Lagergren pseudo-first and pseudo-second order kinetic models, as well as intraparticle diffusion model. It was found that biosorption of lead and zinc ions on alkali treated hemp fibers and alginate-hemp composite obey the pseudo-second order adsorption kinetics, indicating that adsorption/binding of ions is mediated by chemical forces rather than physical forces of attraction. This observation was confirmed by results of FT-IR analysis of alginate composite surface before and after ions adsorption. It was found that lead and zinc ions predominantly bind on carboxyl and hydroxyl groups through the ion-exchange and surface complexation. New biosorbent demonstrated effective removal of the ions, with the possibility of further process optimization in order to increase the adsorption capacity and rate of metal ions removal.
AB  - U ovom radu ispitana je mogućnost primene novog biosorbenta, na bazi kratkih hemijski modifikovanih vlakana konoplje impregniranih alginatnim gelom, za adsorpciju jona olova(II) i cinka(II). Biosorbent na bazi alginata i alkalno tretiranih vlakana konoplje okarakterisan je sa aspekta strukture i morfologije primenom skenirajuće elektronske mikroskopije (SEM) i prirode funkcionalnih grupa korišćenjem infracrvene spektroskopije sa Furijeovim transformacijama (FT-IR). Adsorpcione karakteristike ovog kompozita, ispitivane su praćenjem kinetike adsorpcije jona olova i cinka, i upoređene su sa adsorpcionim karakteristikama alkalno tretiranih vlakana konoplje. Podaci dobijeni tokom adsorpcije, testirani su korišćenjem Lagergrenovog modela pseudo-prvog reda i pseudo-drugog reda, kao i modela intračestične difuzije. Slaganje modelnih i eksperimentalnih podataka pokazuje da adsorpcioni proces prati kinetiku pseudo-drugog reda, što upućuje na zaključak da tokom adsorpcije jona olova i cinka na površini ispitivanih uzoraka konoplje i kompozita alginat-konoplja, preovladava mehanizam hemisorpcije. Ova zapažanja su potvrđena i rezultatima FT-IR analize, koji pokazuju da se joni teških metala vezuju na karboksilnim, i delimično hidroksilnim grupama prisutnim na površini ispitivanog biokompozita. Na osnovu dobijenih rezultata zaključuje se da se novi biosorbent može uspešno koristiti, kao jeftin i efikasan adsorbent za uklanjanje jona teških metala iz vode.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions
T1  - Novi biosorbent na bazi vlakna konoplje (Cannabis sativa) i Ca-alginata za uklanjanje jona olova i cinka
EP  - 76
IS  - 1
SP  - 67
VL  - 59
DO  - 10.5937/ZasMat1801069M
ER  - 
@article{
author = "Milivojević, Milan and Pejić, Biljana and Vukčević, Marija and Kostić, Mirjana",
year = "2018",
abstract = "In this paper the possibility of implementing the new biosorbent composed of chemically modified short hemp fibers impregnated with alginate gel for adsorption of lead(II) and zinc (II) ions was investigated. Waste hemp fibers, alkaly treated, were used as an alginate carrier in order to improve the mechanical stability of alginate. Morphological characteristics of obtained alginate-hemp composite were investigated by scanning electron microscopy (SEM), while the Fourier transform infrared spectroscopy (FT-IR) was used for examination of surface chemistry. Alginate immobilization on the hemp fibers surface leads to the morphological changes, by decreasing the roughness of short hemp fibers. FT-IR analysis showed that surface chemistry was changed after alginate immobilization, primarily by increasing the amount of carboxyl groups. The presence of surface groups characteristic for hemp fibers, on the surface of biocomposite, indicate that the surface of hemp fibers is not completely covered by alginate. Adsorption characteristics of alginate-hemp biosorbent were examined through the adsorption of lead and zinc ions, and compared with the adsorption characteristics of alkali treated hemp fibers. Biosorption of lead and zinc ions onto both hemp fibers and alginate-hemp composite, represent fast process since 80 % of initial ions amount were adsorbed in first five minutes. Obtained adsorption data were analyzed by Lagergren pseudo-first and pseudo-second order kinetic models, as well as intraparticle diffusion model. It was found that biosorption of lead and zinc ions on alkali treated hemp fibers and alginate-hemp composite obey the pseudo-second order adsorption kinetics, indicating that adsorption/binding of ions is mediated by chemical forces rather than physical forces of attraction. This observation was confirmed by results of FT-IR analysis of alginate composite surface before and after ions adsorption. It was found that lead and zinc ions predominantly bind on carboxyl and hydroxyl groups through the ion-exchange and surface complexation. New biosorbent demonstrated effective removal of the ions, with the possibility of further process optimization in order to increase the adsorption capacity and rate of metal ions removal., U ovom radu ispitana je mogućnost primene novog biosorbenta, na bazi kratkih hemijski modifikovanih vlakana konoplje impregniranih alginatnim gelom, za adsorpciju jona olova(II) i cinka(II). Biosorbent na bazi alginata i alkalno tretiranih vlakana konoplje okarakterisan je sa aspekta strukture i morfologije primenom skenirajuće elektronske mikroskopije (SEM) i prirode funkcionalnih grupa korišćenjem infracrvene spektroskopije sa Furijeovim transformacijama (FT-IR). Adsorpcione karakteristike ovog kompozita, ispitivane su praćenjem kinetike adsorpcije jona olova i cinka, i upoređene su sa adsorpcionim karakteristikama alkalno tretiranih vlakana konoplje. Podaci dobijeni tokom adsorpcije, testirani su korišćenjem Lagergrenovog modela pseudo-prvog reda i pseudo-drugog reda, kao i modela intračestične difuzije. Slaganje modelnih i eksperimentalnih podataka pokazuje da adsorpcioni proces prati kinetiku pseudo-drugog reda, što upućuje na zaključak da tokom adsorpcije jona olova i cinka na površini ispitivanih uzoraka konoplje i kompozita alginat-konoplja, preovladava mehanizam hemisorpcije. Ova zapažanja su potvrđena i rezultatima FT-IR analize, koji pokazuju da se joni teških metala vezuju na karboksilnim, i delimično hidroksilnim grupama prisutnim na površini ispitivanog biokompozita. Na osnovu dobijenih rezultata zaključuje se da se novi biosorbent može uspešno koristiti, kao jeftin i efikasan adsorbent za uklanjanje jona teških metala iz vode.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions, Novi biosorbent na bazi vlakna konoplje (Cannabis sativa) i Ca-alginata za uklanjanje jona olova i cinka",
pages = "76-67",
number = "1",
volume = "59",
doi = "10.5937/ZasMat1801069M"
}
Milivojević, M., Pejić, B., Vukčević, M.,& Kostić, M.. (2018). Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 59(1), 67-76.
https://doi.org/10.5937/ZasMat1801069M
Milivojević M, Pejić B, Vukčević M, Kostić M. Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions. in Zaštita materijala. 2018;59(1):67-76.
doi:10.5937/ZasMat1801069M .
Milivojević, Milan, Pejić, Biljana, Vukčević, Marija, Kostić, Mirjana, "Hemp fibers (Cannabis sativa) impregnated by Ca-alginate gel as a novel biosorbent for the removal of Pb(II) and Zn(II) ions" in Zaštita materijala, 59, no. 1 (2018):67-76,
https://doi.org/10.5937/ZasMat1801069M . .
1

Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.)

Lazić, Biljana D.; Pejić, Biljana; Kramar, Ana; Vukčević, Marija; Mihajlovski, Katarina; Rusmirović, Jelena; Kostić, Mirjana

(Springer, Dordrecht, 2018)

TY  - JOUR
AU  - Lazić, Biljana D.
AU  - Pejić, Biljana
AU  - Kramar, Ana
AU  - Vukčević, Marija
AU  - Mihajlovski, Katarina
AU  - Rusmirović, Jelena
AU  - Kostić, Mirjana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3973
AB  - In this work, alkali and oxidative treatments were employed to obtain flax fibers with different content of hemicelluloses and lignin, in order to study the influence of chemical composition on structure and sorption properties of flax fibers. The flax fibers were characterized using FTIR spectroscopy and FESEM microscopy, and by determination of chemical composition, carboxyl group content, electrokinetic and sorption properties. Adsorption of silver ions was used to evaluate flax fiber sorption properties, but also to obtain antimicrobial fibers whose antimicrobial activity was tested against Gram-negative bacteria Escherichia coli, Gram-positive bacteria Staphylococcus aureus and fungi Candida albicans. The progressive removal of hemicelluloses or lignin influenced the sorption properties through the increased liberation of elementary fibers and accessibility of functional surface groups of flax fibers. Removal of hemicelluloses led to increase of iodine sorption without significant change in functional groups content and electrokinetic properties. On the other hand, lignin removal led to an increase of functional groups content, namely carboxyl groups, which in turn influenced better moisture and silver ions sorption. Flax fibers with incorporated silver exhibit fair antimicrobial activity against Gram (-) E. coli, Gram (+) S. aureus and fungi C. albicans.
PB  - Springer, Dordrecht
T2  - Cellulose
T1  - Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.)
EP  - 709
IS  - 1
SP  - 697
VL  - 25
DO  - 10.1007/s10570-017-1575-4
ER  - 
@article{
author = "Lazić, Biljana D. and Pejić, Biljana and Kramar, Ana and Vukčević, Marija and Mihajlovski, Katarina and Rusmirović, Jelena and Kostić, Mirjana",
year = "2018",
abstract = "In this work, alkali and oxidative treatments were employed to obtain flax fibers with different content of hemicelluloses and lignin, in order to study the influence of chemical composition on structure and sorption properties of flax fibers. The flax fibers were characterized using FTIR spectroscopy and FESEM microscopy, and by determination of chemical composition, carboxyl group content, electrokinetic and sorption properties. Adsorption of silver ions was used to evaluate flax fiber sorption properties, but also to obtain antimicrobial fibers whose antimicrobial activity was tested against Gram-negative bacteria Escherichia coli, Gram-positive bacteria Staphylococcus aureus and fungi Candida albicans. The progressive removal of hemicelluloses or lignin influenced the sorption properties through the increased liberation of elementary fibers and accessibility of functional surface groups of flax fibers. Removal of hemicelluloses led to increase of iodine sorption without significant change in functional groups content and electrokinetic properties. On the other hand, lignin removal led to an increase of functional groups content, namely carboxyl groups, which in turn influenced better moisture and silver ions sorption. Flax fibers with incorporated silver exhibit fair antimicrobial activity against Gram (-) E. coli, Gram (+) S. aureus and fungi C. albicans.",
publisher = "Springer, Dordrecht",
journal = "Cellulose",
title = "Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.)",
pages = "709-697",
number = "1",
volume = "25",
doi = "10.1007/s10570-017-1575-4"
}
Lazić, B. D., Pejić, B., Kramar, A., Vukčević, M., Mihajlovski, K., Rusmirović, J.,& Kostić, M.. (2018). Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.). in Cellulose
Springer, Dordrecht., 25(1), 697-709.
https://doi.org/10.1007/s10570-017-1575-4
Lazić BD, Pejić B, Kramar A, Vukčević M, Mihajlovski K, Rusmirović J, Kostić M. Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.). in Cellulose. 2018;25(1):697-709.
doi:10.1007/s10570-017-1575-4 .
Lazić, Biljana D., Pejić, Biljana, Kramar, Ana, Vukčević, Marija, Mihajlovski, Katarina, Rusmirović, Jelena, Kostić, Mirjana, "Influence of hemicelluloses and lignin content on structure and sorption properties of flax fibers (Linum usitatissimum L.)" in Cellulose, 25, no. 1 (2018):697-709,
https://doi.org/10.1007/s10570-017-1575-4 . .
53
32
54

SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU

Asanović, Koviljka A.; Kostić, Mirjana M.; Cerović, Dragana D.; Mihailović, Tatjana V.; Kramar, Ana D.; Pejić, Biljana M.

(Beograd : Visoka tekstilna strukovna škola za dizajn, tehnologiju i menadžment, 2018)

TY  - CONF
AU  - Asanović, Koviljka A.
AU  - Kostić, Mirjana M.
AU  - Cerović, Dragana D.
AU  - Mihailović, Tatjana V.
AU  - Kramar, Ana D.
AU  - Pejić, Biljana M.
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6930
AB  - U radu je ukazano na značaj poznavanja elektrofizičkih svojstava tekstilnih materijala. Dat je pregled metoda za određivanje električne otpornosti tekstilnih materijala, sa akcentom na metode razvijene na Katedri za tekstilno inženjerstvo Tehnološko-metalurškog fakulteta Univerziteta u Beogradu. Istaknut je značaj određivanja električne otpornosti vlakana i pređa u smislu pružanja informacija o sklonosti tekstilnih materijala ka generisanju statičkog naelektrisanja u procesu proizvodnje, a tkanina, pletenina i netkanih tekstilnih 
materijala sa aspekta karakterisanja gotovih tekstilnih proizvoda u pogledu stvaranja statičkog naelektrisanja i njegovog uticaja na upotrebna svojstva gotovih proizvoda. U radu je dat i prikaz metoda za kontrolu i sniženje statičkog naelektrisanja na tekstilnom materijalu.
AB  - In this work, the importance of knowing the electrophysical properties of textile materials was pointed out. A review of the methods for determining the electrical resistance of textile materials is given, with emphasis on methods developed at the Department of Textile Engineering of the Faculty of Technology and Metallurgy, University of Belgrade. Determining the electrical resistance of fibers and yarns plays a role in providing information on the tendency of textile materials to generate static electricity in the production process. Determining the electrical resistance of woven, knitted and nonwoven fabrics allows us to predict whether these textile products would generate static electricity, and the impact it would have on the usability of finished 
products. This work also presents a review of methods for controlling and decreasing static electricity in textile materials.
PB  - Beograd : Visoka tekstilna strukovna škola za dizajn, tehnologiju i menadžment
C3  - Zbornik radova / VI naučno stručni skup sa međunarodnim učešćem "Tendencije razvoja u tekstilnoj industriji - Dizajn, Tehnologija, Menadžment", Beograd, 27. Jun 2018
T1  - SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU
T1  - TENDENCY OF TEXTILE MATERIALS TO GENERATE STATIC ELECTRICITY: METHODS FOR CHARACTERISATION AND CONTROL
EP  - 12
SP  - 5
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6930
ER  - 
@conference{
author = "Asanović, Koviljka A. and Kostić, Mirjana M. and Cerović, Dragana D. and Mihailović, Tatjana V. and Kramar, Ana D. and Pejić, Biljana M.",
year = "2018",
abstract = "U radu je ukazano na značaj poznavanja elektrofizičkih svojstava tekstilnih materijala. Dat je pregled metoda za određivanje električne otpornosti tekstilnih materijala, sa akcentom na metode razvijene na Katedri za tekstilno inženjerstvo Tehnološko-metalurškog fakulteta Univerziteta u Beogradu. Istaknut je značaj određivanja električne otpornosti vlakana i pređa u smislu pružanja informacija o sklonosti tekstilnih materijala ka generisanju statičkog naelektrisanja u procesu proizvodnje, a tkanina, pletenina i netkanih tekstilnih 
materijala sa aspekta karakterisanja gotovih tekstilnih proizvoda u pogledu stvaranja statičkog naelektrisanja i njegovog uticaja na upotrebna svojstva gotovih proizvoda. U radu je dat i prikaz metoda za kontrolu i sniženje statičkog naelektrisanja na tekstilnom materijalu., In this work, the importance of knowing the electrophysical properties of textile materials was pointed out. A review of the methods for determining the electrical resistance of textile materials is given, with emphasis on methods developed at the Department of Textile Engineering of the Faculty of Technology and Metallurgy, University of Belgrade. Determining the electrical resistance of fibers and yarns plays a role in providing information on the tendency of textile materials to generate static electricity in the production process. Determining the electrical resistance of woven, knitted and nonwoven fabrics allows us to predict whether these textile products would generate static electricity, and the impact it would have on the usability of finished 
products. This work also presents a review of methods for controlling and decreasing static electricity in textile materials.",
publisher = "Beograd : Visoka tekstilna strukovna škola za dizajn, tehnologiju i menadžment",
journal = "Zbornik radova / VI naučno stručni skup sa međunarodnim učešćem "Tendencije razvoja u tekstilnoj industriji - Dizajn, Tehnologija, Menadžment", Beograd, 27. Jun 2018",
title = "SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU, TENDENCY OF TEXTILE MATERIALS TO GENERATE STATIC ELECTRICITY: METHODS FOR CHARACTERISATION AND CONTROL",
pages = "12-5",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6930"
}
Asanović, K. A., Kostić, M. M., Cerović, D. D., Mihailović, T. V., Kramar, A. D.,& Pejić, B. M.. (2018). SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU. in Zbornik radova / VI naučno stručni skup sa međunarodnim učešćem "Tendencije razvoja u tekstilnoj industriji - Dizajn, Tehnologija, Menadžment", Beograd, 27. Jun 2018
Beograd : Visoka tekstilna strukovna škola za dizajn, tehnologiju i menadžment., 5-12.
https://hdl.handle.net/21.15107/rcub_technorep_6930
Asanović KA, Kostić MM, Cerović DD, Mihailović TV, Kramar AD, Pejić BM. SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU. in Zbornik radova / VI naučno stručni skup sa međunarodnim učešćem "Tendencije razvoja u tekstilnoj industriji - Dizajn, Tehnologija, Menadžment", Beograd, 27. Jun 2018. 2018;:5-12.
https://hdl.handle.net/21.15107/rcub_technorep_6930 .
Asanović, Koviljka A., Kostić, Mirjana M., Cerović, Dragana D., Mihailović, Tatjana V., Kramar, Ana D., Pejić, Biljana M., "SKLONOSTI TEKSTILNIH MATERIJALA KA STATIČKOM NAELEKTRISANJU: METODE ZA KARAKTERIZACIJU I KONTROLU" in Zbornik radova / VI naučno stručni skup sa međunarodnim učešćem "Tendencije razvoja u tekstilnoj industriji - Dizajn, Tehnologija, Menadžment", Beograd, 27. Jun 2018 (2018):5-12,
https://hdl.handle.net/21.15107/rcub_technorep_6930 .

Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon

Vukčević, Marija; Pejić, Biljana; Pajić-Lijaković, Ivana; Kalijadis, Ana; Kostić, Mirjana; Laušević, Zoran; Laušević, Mila

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Pajić-Lijaković, Ivana
AU  - Kalijadis, Ana
AU  - Kostić, Mirjana
AU  - Laušević, Zoran
AU  - Laušević, Mila
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3641
AB  - Waste hemp (Cannabis sativa) fibers were used as sustainable and renewable raw materials for production of low-cost biocarbon sorbent for heavy metals removal. Carbon precursors of different chemical composition were obtained by oxidative and alkaline treatments of hemp fibers. Influence of lignocellulosic precursor chemical composition on hemp fibers-based biocarbon (HFB) characteristics was examined by BET surface area measurement, scanning electron microscopy and mass titration. It was found that lignin content and polymorphic transformation of cellulose increase the SBET of microporous HFBs, while hemicelluloses induce more homogeneous distribution of adsorption active sites. Heavy metal ions adsorption onto HFBs is primarily influenced by the amount of surface oxygen groups, while specific surface area plays a secondary role. Equilibrium data obtained for lead ions adsorption were analyzed by different nonlinear adsorption isotherms, and the best fitting model was chosen using standard deviation and Akaike information criterion (AIC
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon
EP  - 1431
IS  - 12
SP  - 1417
VL  - 82
DO  - 10.2298/JSC170310080V
ER  - 
@article{
author = "Vukčević, Marija and Pejić, Biljana and Pajić-Lijaković, Ivana and Kalijadis, Ana and Kostić, Mirjana and Laušević, Zoran and Laušević, Mila",
year = "2017",
abstract = "Waste hemp (Cannabis sativa) fibers were used as sustainable and renewable raw materials for production of low-cost biocarbon sorbent for heavy metals removal. Carbon precursors of different chemical composition were obtained by oxidative and alkaline treatments of hemp fibers. Influence of lignocellulosic precursor chemical composition on hemp fibers-based biocarbon (HFB) characteristics was examined by BET surface area measurement, scanning electron microscopy and mass titration. It was found that lignin content and polymorphic transformation of cellulose increase the SBET of microporous HFBs, while hemicelluloses induce more homogeneous distribution of adsorption active sites. Heavy metal ions adsorption onto HFBs is primarily influenced by the amount of surface oxygen groups, while specific surface area plays a secondary role. Equilibrium data obtained for lead ions adsorption were analyzed by different nonlinear adsorption isotherms, and the best fitting model was chosen using standard deviation and Akaike information criterion (AIC",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon",
pages = "1431-1417",
number = "12",
volume = "82",
doi = "10.2298/JSC170310080V"
}
Vukčević, M., Pejić, B., Pajić-Lijaković, I., Kalijadis, A., Kostić, M., Laušević, Z.,& Laušević, M.. (2017). Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(12), 1417-1431.
https://doi.org/10.2298/JSC170310080V
Vukčević M, Pejić B, Pajić-Lijaković I, Kalijadis A, Kostić M, Laušević Z, Laušević M. Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon. in Journal of the Serbian Chemical Society. 2017;82(12):1417-1431.
doi:10.2298/JSC170310080V .
Vukčević, Marija, Pejić, Biljana, Pajić-Lijaković, Ivana, Kalijadis, Ana, Kostić, Mirjana, Laušević, Zoran, Laušević, Mila, "Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1417-1431,
https://doi.org/10.2298/JSC170310080V . .
7
1
5

Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production

Pejić, Biljana; Vukčević, Marija; Kalijadis, Ana; Laušević, Zoran; Laušević, Mila; Kostić, Mirjana

(Union of Textile Engineers and Technicians of Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Pejić, Biljana
AU  - Vukčević, Marija
AU  - Kalijadis, Ana
AU  - Laušević, Zoran
AU  - Laušević, Mila
AU  - Kostić, Mirjana
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2932
AB  - Short and entangled hemp fibers, obtained as a waste from textile industry, were used as effici­ent biosorbent and low-cost precursor for carbon sorbent production. In order to obtain the biosorbents with better sorption properties, short hemp fibers were chemically modified. Also, chemical modification were used in order to attain the appropriate specific structure of hemp fibers based carbon precursor, that promote the formation of the required porosity and surface chemistry of the biocarbon to facilitate adsorption. Used hemp fibers based sorbents were characterized through the specific surface area, amount of surface functional gro­ups and pH of the point of zero charge. Sorption efficiency of hemp fibers based sorbents were tested through the adsorption of cadmium from water solution. Adsorption data will be used for development of filters based on hemp fibers and carbonized hemp fibers forpurification of water polluted with heavy metals.
AB  - Kratka i zamršena vlakna konoplje, dobijena kao otpad u tekstilnoj industriji, korišćena su kao biosorbenti i jeftina sirovina za proizvodnju ugljeničnih sorbenata. Hemijsko modifikovanje vlakana konoplje izvršeno je u cilju poboljšanja sorpcionih svojstava biosorbenta, i optimizacije hemijskog sastava i strukture prekursora za dobijanje efikasnih ugljeničnih sorbenata. Karakterizacija biosorbenata i ugljeničnih sorbenata izvršena je određivanjem specifične površine i količine funkcionalnih grupaprisutnih na njihovojpovršini, kao i određivanjem pH vrednosti tačke nultog naelektrisanja. Efikasnost dobijenih sorbenata ispitana je adsorpci- jom jona kadmijuma iz vodenog rastvora. Vrednosti dobijene ispitivanjem kinetike adsorpcije jona kadmijuma, kao i vrednosti ravnotežnih sorpcionih kapaciteta, biće iskorišćeni u svrhu razvoja filtera za prečišćavanje otpadnih voda, na bazi hemijski modifikovanih i karbonizovanih vlakana konoplje.
PB  - Union of Textile Engineers and Technicians of Serbia, Belgrade
T2  - Tekstilna industrija
T1  - Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production
T1  - Vlakna konoplje (Cannabis sativa) kao biosorbenti i sirovine za proizvodnju ugljeničnih sorbenata
EP  - 46
IS  - 1
SP  - 41
VL  - 63
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2932
ER  - 
@article{
author = "Pejić, Biljana and Vukčević, Marija and Kalijadis, Ana and Laušević, Zoran and Laušević, Mila and Kostić, Mirjana",
year = "2015",
abstract = "Short and entangled hemp fibers, obtained as a waste from textile industry, were used as effici­ent biosorbent and low-cost precursor for carbon sorbent production. In order to obtain the biosorbents with better sorption properties, short hemp fibers were chemically modified. Also, chemical modification were used in order to attain the appropriate specific structure of hemp fibers based carbon precursor, that promote the formation of the required porosity and surface chemistry of the biocarbon to facilitate adsorption. Used hemp fibers based sorbents were characterized through the specific surface area, amount of surface functional gro­ups and pH of the point of zero charge. Sorption efficiency of hemp fibers based sorbents were tested through the adsorption of cadmium from water solution. Adsorption data will be used for development of filters based on hemp fibers and carbonized hemp fibers forpurification of water polluted with heavy metals., Kratka i zamršena vlakna konoplje, dobijena kao otpad u tekstilnoj industriji, korišćena su kao biosorbenti i jeftina sirovina za proizvodnju ugljeničnih sorbenata. Hemijsko modifikovanje vlakana konoplje izvršeno je u cilju poboljšanja sorpcionih svojstava biosorbenta, i optimizacije hemijskog sastava i strukture prekursora za dobijanje efikasnih ugljeničnih sorbenata. Karakterizacija biosorbenata i ugljeničnih sorbenata izvršena je određivanjem specifične površine i količine funkcionalnih grupaprisutnih na njihovojpovršini, kao i određivanjem pH vrednosti tačke nultog naelektrisanja. Efikasnost dobijenih sorbenata ispitana je adsorpci- jom jona kadmijuma iz vodenog rastvora. Vrednosti dobijene ispitivanjem kinetike adsorpcije jona kadmijuma, kao i vrednosti ravnotežnih sorpcionih kapaciteta, biće iskorišćeni u svrhu razvoja filtera za prečišćavanje otpadnih voda, na bazi hemijski modifikovanih i karbonizovanih vlakana konoplje.",
publisher = "Union of Textile Engineers and Technicians of Serbia, Belgrade",
journal = "Tekstilna industrija",
title = "Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production, Vlakna konoplje (Cannabis sativa) kao biosorbenti i sirovine za proizvodnju ugljeničnih sorbenata",
pages = "46-41",
number = "1",
volume = "63",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2932"
}
Pejić, B., Vukčević, M., Kalijadis, A., Laušević, Z., Laušević, M.,& Kostić, M.. (2015). Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production. in Tekstilna industrija
Union of Textile Engineers and Technicians of Serbia, Belgrade., 63(1), 41-46.
https://hdl.handle.net/21.15107/rcub_technorep_2932
Pejić B, Vukčević M, Kalijadis A, Laušević Z, Laušević M, Kostić M. Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production. in Tekstilna industrija. 2015;63(1):41-46.
https://hdl.handle.net/21.15107/rcub_technorep_2932 .
Pejić, Biljana, Vukčević, Marija, Kalijadis, Ana, Laušević, Zoran, Laušević, Mila, Kostić, Mirjana, "Hemp (Cannabis sativa) fibers as biosorbents and precursor for carbon sorbent production" in Tekstilna industrija, 63, no. 1 (2015):41-46,
https://hdl.handle.net/21.15107/rcub_technorep_2932 .

Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection

Vukčević, Marija; Pejić, Biljana; Kalijadis, Ana; Laušević, Zoran; Laušević, Mila; Kostić, Mirjana

(Union of Textile Engineers and Technicians of Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Kalijadis, Ana
AU  - Laušević, Zoran
AU  - Laušević, Mila
AU  - Kostić, Mirjana
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2933
AB  - By varying the parameters of carbonization and activation, different samples of hemp fibers based activated carbon were obtained. Optimal production conditions were selected based on the adsorption properties of activated hemp fibers toward pesticides. Therefore, the influence of production conditions on the specific surface area, measured by dynamic method, and adsorption characteristics of activated hemp fibers toward different pesticides (acetamiprid, dimethoate, carbofuran and atrazine) was examined. Decrease of pesticide concentration, as a consequence of the adsorption, was determined by liquid chromatography-tandem mass spectrometry technique. Based on obtained results, an efficient pesticides sorbent can be produced using: carbonization temperature of 1000 oC, activated agent/carbon material ratio of 2/1 and activation temperature of 900 oC. Additionally, activated hemp fibers impregnated with silver proved to be suitable for water disinfection due to the strong antimicrobial activity against Escherichia coli, Staphylococcus aureus and Candida albicans.
AB  - Variranjem parametara karbonizacije i aktivacije dobijeni su uzorci aktiviranih ugljeničnih materijala na bazi vlakana konoplje, a optimalni parametri dobijanja izabrani su na osnovu efikasnosti uklanjanja pesticida iz vodenih rastvora. Ispitan je uticaj parametara dobijanja, kako na specifičnu površinu aktiviranih vlakana konoplje, merenu dinamičkom metodom, tako i na efikasnost dobijenih uzoraka u adsorpciji pesticida: acetamiprida, dimetoata, karbofurana i atrazina. Koncentracija pesticida u rastvoru određivana je metodom tečne hromatografije u kombinaciji sa tandem masenom spektrometrijom. Kao optimalni parametri za dobijanje efikasnih sorbenata za uklanjanje pesticida odabrani su: temperatura karbonizacije od 1000oC, odnos aktivacioni agens: karbonizovani materijal - 2:1 i temperatura aktivacije od 900oC. Takođe, aktivirana vlakna konoplje impregnisana srebrom pokazuju jako antimikrobno dejstvo na smešu Escherichia coli, Staphylococcus aureus i Candida albicans, pa se ovi materijali mogu koristiti i za dezinfekciju zagađene vode.
PB  - Union of Textile Engineers and Technicians of Serbia, Belgrade
T2  - Tekstilna industrija
T1  - Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection
T1  - Adsorpcija pesticida i dezinfekcija vode aktiviranim ugljeničnim materijalima na bazi vlakana konoplje
EP  - 20
IS  - 1
SP  - 15
VL  - 63
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2933
ER  - 
@article{
author = "Vukčević, Marija and Pejić, Biljana and Kalijadis, Ana and Laušević, Zoran and Laušević, Mila and Kostić, Mirjana",
year = "2015",
abstract = "By varying the parameters of carbonization and activation, different samples of hemp fibers based activated carbon were obtained. Optimal production conditions were selected based on the adsorption properties of activated hemp fibers toward pesticides. Therefore, the influence of production conditions on the specific surface area, measured by dynamic method, and adsorption characteristics of activated hemp fibers toward different pesticides (acetamiprid, dimethoate, carbofuran and atrazine) was examined. Decrease of pesticide concentration, as a consequence of the adsorption, was determined by liquid chromatography-tandem mass spectrometry technique. Based on obtained results, an efficient pesticides sorbent can be produced using: carbonization temperature of 1000 oC, activated agent/carbon material ratio of 2/1 and activation temperature of 900 oC. Additionally, activated hemp fibers impregnated with silver proved to be suitable for water disinfection due to the strong antimicrobial activity against Escherichia coli, Staphylococcus aureus and Candida albicans., Variranjem parametara karbonizacije i aktivacije dobijeni su uzorci aktiviranih ugljeničnih materijala na bazi vlakana konoplje, a optimalni parametri dobijanja izabrani su na osnovu efikasnosti uklanjanja pesticida iz vodenih rastvora. Ispitan je uticaj parametara dobijanja, kako na specifičnu površinu aktiviranih vlakana konoplje, merenu dinamičkom metodom, tako i na efikasnost dobijenih uzoraka u adsorpciji pesticida: acetamiprida, dimetoata, karbofurana i atrazina. Koncentracija pesticida u rastvoru određivana je metodom tečne hromatografije u kombinaciji sa tandem masenom spektrometrijom. Kao optimalni parametri za dobijanje efikasnih sorbenata za uklanjanje pesticida odabrani su: temperatura karbonizacije od 1000oC, odnos aktivacioni agens: karbonizovani materijal - 2:1 i temperatura aktivacije od 900oC. Takođe, aktivirana vlakna konoplje impregnisana srebrom pokazuju jako antimikrobno dejstvo na smešu Escherichia coli, Staphylococcus aureus i Candida albicans, pa se ovi materijali mogu koristiti i za dezinfekciju zagađene vode.",
publisher = "Union of Textile Engineers and Technicians of Serbia, Belgrade",
journal = "Tekstilna industrija",
title = "Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection, Adsorpcija pesticida i dezinfekcija vode aktiviranim ugljeničnim materijalima na bazi vlakana konoplje",
pages = "20-15",
number = "1",
volume = "63",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2933"
}
Vukčević, M., Pejić, B., Kalijadis, A., Laušević, Z., Laušević, M.,& Kostić, M.. (2015). Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection. in Tekstilna industrija
Union of Textile Engineers and Technicians of Serbia, Belgrade., 63(1), 15-20.
https://hdl.handle.net/21.15107/rcub_technorep_2933
Vukčević M, Pejić B, Kalijadis A, Laušević Z, Laušević M, Kostić M. Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection. in Tekstilna industrija. 2015;63(1):15-20.
https://hdl.handle.net/21.15107/rcub_technorep_2933 .
Vukčević, Marija, Pejić, Biljana, Kalijadis, Ana, Laušević, Zoran, Laušević, Mila, Kostić, Mirjana, "Activated carbon materials derived from hemp fibers in pesticide adsorption and water disinfection" in Tekstilna industrija, 63, no. 1 (2015):15-20,
https://hdl.handle.net/21.15107/rcub_technorep_2933 .

Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility

Pejić, Biljana; Medović-Baralić, Adela; Kojić, Zvezdana; Škundrić, Petar; Kostić, Mirjana

(Korean Fiber Soc, Seoul, 2015)

TY  - JOUR
AU  - Pejić, Biljana
AU  - Medović-Baralić, Adela
AU  - Kojić, Zvezdana
AU  - Škundrić, Petar
AU  - Kostić, Mirjana
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2983
AB  - Oxidized cellulose has a long history of safe and effective use in medical applications. In this paper, research has been directed towards obtaining hormone-active cellulose fibers in the form of an artificial insulin depot, and examination of its biocompatibility regarding cytotoxicity, sensitization, and irritation. The procedure of obtaining the fibrous insulin depot is based on the modification of cotton fibers with sodium periodate, followed by chemisorption of insulin from insulin aqueous solutions. In order to optimize the insulin chemisorption process, the influence of the fiber structure parameters, i.e. the aldehyde group content and iodine sorption value (ISV) on the chemisorption capacity was examined. The obtained artificial depot, containing approximate to 55 mg insulin/g of fibers, has been characterized in vitro by investigation of the desorption kinetics of the insulin from the fibrous depot. It has been shown that insulin is controllably released in quantities of 1.3-1.6 mg of insulin during 24 hours, in the course of 20 days. The results of biocompatibility tests have shown that the examined artificial depot neither shows irritating effects nor provokes sensitizing or cytotoxic effects. Therefore, these materials are acceptable for use in a direct contact with tissue of a living organism.
PB  - Korean Fiber Soc, Seoul
T2  - Fibers and Polymers
T1  - Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility
EP  - 1004
IS  - 5
SP  - 997
VL  - 16
DO  - 10.1007/s12221-015-0997-6
ER  - 
@article{
author = "Pejić, Biljana and Medović-Baralić, Adela and Kojić, Zvezdana and Škundrić, Petar and Kostić, Mirjana",
year = "2015",
abstract = "Oxidized cellulose has a long history of safe and effective use in medical applications. In this paper, research has been directed towards obtaining hormone-active cellulose fibers in the form of an artificial insulin depot, and examination of its biocompatibility regarding cytotoxicity, sensitization, and irritation. The procedure of obtaining the fibrous insulin depot is based on the modification of cotton fibers with sodium periodate, followed by chemisorption of insulin from insulin aqueous solutions. In order to optimize the insulin chemisorption process, the influence of the fiber structure parameters, i.e. the aldehyde group content and iodine sorption value (ISV) on the chemisorption capacity was examined. The obtained artificial depot, containing approximate to 55 mg insulin/g of fibers, has been characterized in vitro by investigation of the desorption kinetics of the insulin from the fibrous depot. It has been shown that insulin is controllably released in quantities of 1.3-1.6 mg of insulin during 24 hours, in the course of 20 days. The results of biocompatibility tests have shown that the examined artificial depot neither shows irritating effects nor provokes sensitizing or cytotoxic effects. Therefore, these materials are acceptable for use in a direct contact with tissue of a living organism.",
publisher = "Korean Fiber Soc, Seoul",
journal = "Fibers and Polymers",
title = "Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility",
pages = "1004-997",
number = "5",
volume = "16",
doi = "10.1007/s12221-015-0997-6"
}
Pejić, B., Medović-Baralić, A., Kojić, Z., Škundrić, P.,& Kostić, M.. (2015). Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility. in Fibers and Polymers
Korean Fiber Soc, Seoul., 16(5), 997-1004.
https://doi.org/10.1007/s12221-015-0997-6
Pejić B, Medović-Baralić A, Kojić Z, Škundrić P, Kostić M. Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility. in Fibers and Polymers. 2015;16(5):997-1004.
doi:10.1007/s12221-015-0997-6 .
Pejić, Biljana, Medović-Baralić, Adela, Kojić, Zvezdana, Škundrić, Petar, Kostić, Mirjana, "Oxidized Cotton as a Substrate for the Preparation of Hormone-Active Fibers-Characterization, Efficiency and Biocompatibility" in Fibers and Polymers, 16, no. 5 (2015):997-1004,
https://doi.org/10.1007/s12221-015-0997-6 . .
2
3
3

Hemp Fibers: Old Fibers - New Applications

Kostić, Mirjana; Vukčević, Marija; Pejić, Biljana; Kalijadis, Ana

(2014)

TY  - CHAP
AU  - Kostić, Mirjana
AU  - Vukčević, Marija
AU  - Pejić, Biljana
AU  - Kalijadis, Ana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2581
AB  - Hemp (Cannabis sativa) was most likely the first plant cultivated by mankind for its textile use. Currently, the interest in hemp is focused on its use as a raw material for the production of environmentally friendly clothes, technical textiles and composite materials. The increased production of hemp fibers in textile industry brings the considerable amount of waste in the form of short and entangled fibers. The cost of waste disposal can be minimized by recycling the waste in the way of producing useful lowcost products. Following the general trend of finding low-cost and easily available adsorbent, waste short and entangled hemp fibers were utilized as a heavy metal biosorbents. Due to the specific structure and heterogenous chemical composition (cellulose, hemicelluloses, lignin, pectin), short hemp fibers as biosorbent offer an effective way to decrease Pb2+, Cd2+ and Zn2+ ion concentration in wastewaters. The influence of hemp fiber chemical composition on their heavy metal ions sorption potential, were assessed by evaluating the water and metal ions uptake capacities of differently modified hemp fibers. The process of heavy metal ions biosorption on short hemp fibers was clarified by mathematical model development. Proposed mathematical model provides a better insight into phenomena of different ions transport through porous fiber matrices, and possibility of optimization of the complex process of biosorption. This is from great importance in the case of using short hemp fibers as filter material for removing the heavy metal ions from polluted water. Furthermore, there is a growing interest in using different type of waste biomass for production of carbon materials as a sorbents for water purification. From that aspect, short and entangled hemp fibers were used as low-cost precursor for production of carbon materials. Chemical modification of hemp fibers, prior to carbonization, affects the specific surface area, amount of surface oxygen groups and morphology of carbonized hemp fibers. Furthermore, activation of carbonized materials with potassium hydroxide improves sorption properties of carbonized hemp fibers by increasing the specific surface area (up to 2192 m2/g) and amount of surface oxygen groups. Due to the good adsorption properties toward heavy metals and pesticides, carbonized and activated hemp fibers were successfully used as a sorbent for the purification of water polluted with pesticides and heavy metals. Also, activated hemp fiber sorbent used for analyte preconcentration in the solid-phase extraction procedure (SPE) for pesticide analysis in water samples, showed even higher efficiency in pesticides preconcentration than expensive commercial cartridges. Sorption process of heavy metal ions and structural parameters of carbonized hemp fibers were described by upgrading already proposed mathematical model. A good agreement between model prediction and the experimental data indicates that the proposed mathematical model can be used for optimization of heavy metal ions adsorption process by correlating the model parameters to the carbonized hemp fibers performances.
T2  - Textiles: History, Properties and Performance and Applications
T1  - Hemp Fibers: Old Fibers - New Applications
EP  - 446
SP  - 399
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2581
ER  - 
@inbook{
author = "Kostić, Mirjana and Vukčević, Marija and Pejić, Biljana and Kalijadis, Ana",
year = "2014",
abstract = "Hemp (Cannabis sativa) was most likely the first plant cultivated by mankind for its textile use. Currently, the interest in hemp is focused on its use as a raw material for the production of environmentally friendly clothes, technical textiles and composite materials. The increased production of hemp fibers in textile industry brings the considerable amount of waste in the form of short and entangled fibers. The cost of waste disposal can be minimized by recycling the waste in the way of producing useful lowcost products. Following the general trend of finding low-cost and easily available adsorbent, waste short and entangled hemp fibers were utilized as a heavy metal biosorbents. Due to the specific structure and heterogenous chemical composition (cellulose, hemicelluloses, lignin, pectin), short hemp fibers as biosorbent offer an effective way to decrease Pb2+, Cd2+ and Zn2+ ion concentration in wastewaters. The influence of hemp fiber chemical composition on their heavy metal ions sorption potential, were assessed by evaluating the water and metal ions uptake capacities of differently modified hemp fibers. The process of heavy metal ions biosorption on short hemp fibers was clarified by mathematical model development. Proposed mathematical model provides a better insight into phenomena of different ions transport through porous fiber matrices, and possibility of optimization of the complex process of biosorption. This is from great importance in the case of using short hemp fibers as filter material for removing the heavy metal ions from polluted water. Furthermore, there is a growing interest in using different type of waste biomass for production of carbon materials as a sorbents for water purification. From that aspect, short and entangled hemp fibers were used as low-cost precursor for production of carbon materials. Chemical modification of hemp fibers, prior to carbonization, affects the specific surface area, amount of surface oxygen groups and morphology of carbonized hemp fibers. Furthermore, activation of carbonized materials with potassium hydroxide improves sorption properties of carbonized hemp fibers by increasing the specific surface area (up to 2192 m2/g) and amount of surface oxygen groups. Due to the good adsorption properties toward heavy metals and pesticides, carbonized and activated hemp fibers were successfully used as a sorbent for the purification of water polluted with pesticides and heavy metals. Also, activated hemp fiber sorbent used for analyte preconcentration in the solid-phase extraction procedure (SPE) for pesticide analysis in water samples, showed even higher efficiency in pesticides preconcentration than expensive commercial cartridges. Sorption process of heavy metal ions and structural parameters of carbonized hemp fibers were described by upgrading already proposed mathematical model. A good agreement between model prediction and the experimental data indicates that the proposed mathematical model can be used for optimization of heavy metal ions adsorption process by correlating the model parameters to the carbonized hemp fibers performances.",
journal = "Textiles: History, Properties and Performance and Applications",
booktitle = "Hemp Fibers: Old Fibers - New Applications",
pages = "446-399",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2581"
}
Kostić, M., Vukčević, M., Pejić, B.,& Kalijadis, A.. (2014). Hemp Fibers: Old Fibers - New Applications. in Textiles: History, Properties and Performance and Applications, 399-446.
https://hdl.handle.net/21.15107/rcub_technorep_2581
Kostić M, Vukčević M, Pejić B, Kalijadis A. Hemp Fibers: Old Fibers - New Applications. in Textiles: History, Properties and Performance and Applications. 2014;:399-446.
https://hdl.handle.net/21.15107/rcub_technorep_2581 .
Kostić, Mirjana, Vukčević, Marija, Pejić, Biljana, Kalijadis, Ana, "Hemp Fibers: Old Fibers - New Applications" in Textiles: History, Properties and Performance and Applications (2014):399-446,
https://hdl.handle.net/21.15107/rcub_technorep_2581 .
13