TY  - JOUR
AU  - Buha Marković, Jovana Z.
AU  - Marinković, Ana D.
AU  - Savić, Jasmina Z.
AU  - Mladenović, Milica R.
AU  - Erić, Milić D.
AU  - Marković, Zoran J.
AU  - Ristić, Mirjana Đ.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6369
AB  - Emission factors (EFs) of gaseous pollutants, particulate matter, certain harmful trace elements, and polycyclic aromatic hydrocarbons (PAHs) from three thermal power plants (TPPs) and semi-industrial fluidized bed boiler (FBB) were compared. EFs of particulate matter, trace elements (except Cd and Pb), benzo[a]pyrene, and benzo[b]fluoranthene exceed the upper limits specified in the EMEP inventory guidebook for all combustion facilities. The comparison of trace elements and PAHs content in fly ashes (FAs) from lignite and coal waste combustion in TPPs and FBB, respectively, as well as the potential environmental impact of FAs disposal, was performed by employing a set of ecological indicators such as crustal enrichment factor, risk assessment code, risk indices for trace elements, and benzo[a]pyrene equivalent concentration for PAHs. Sequential analysis shows that the trace elements portion is the lowest for water-soluble and exchangeable fractions. The highest enrichment levels in FAs are noticed for As and Hg. Based on toxic trace elements content, FAs from TPPs represent a very high ecological risk, whereas fly ash from FBB poses a moderate ecological risk but has the highest benzo[a]pyrene equivalent concentration, indicating its increased carcinogenic potential. Lead isotope ratios for Serbian coals and FAs can contribute to a lead pollution global database.
PB  - MDPI
T2  - Toxics
T1  - Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling
IS  - 4
SP  - 396
VL  - 11
DO  - 10.3390/toxics11040396
ER  - 

@article{
author = "Buha Marković, Jovana Z. and Marinković, Ana D. and Savić, Jasmina Z. and Mladenović, Milica R. and Erić, Milić D. and Marković, Zoran J. and Ristić, Mirjana Đ.",
year = "2023",
abstract = "Emission factors (EFs) of gaseous pollutants, particulate matter, certain harmful trace elements, and polycyclic aromatic hydrocarbons (PAHs) from three thermal power plants (TPPs) and semi-industrial fluidized bed boiler (FBB) were compared. EFs of particulate matter, trace elements (except Cd and Pb), benzo[a]pyrene, and benzo[b]fluoranthene exceed the upper limits specified in the EMEP inventory guidebook for all combustion facilities. The comparison of trace elements and PAHs content in fly ashes (FAs) from lignite and coal waste combustion in TPPs and FBB, respectively, as well as the potential environmental impact of FAs disposal, was performed by employing a set of ecological indicators such as crustal enrichment factor, risk assessment code, risk indices for trace elements, and benzo[a]pyrene equivalent concentration for PAHs. Sequential analysis shows that the trace elements portion is the lowest for water-soluble and exchangeable fractions. The highest enrichment levels in FAs are noticed for As and Hg. Based on toxic trace elements content, FAs from TPPs represent a very high ecological risk, whereas fly ash from FBB poses a moderate ecological risk but has the highest benzo[a]pyrene equivalent concentration, indicating its increased carcinogenic potential. Lead isotope ratios for Serbian coals and FAs can contribute to a lead pollution global database.",
publisher = "MDPI",
journal = "Toxics",
title = "Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling",
number = "4",
pages = "396",
volume = "11",
doi = "10.3390/toxics11040396"
}

Buha Marković, J. Z., Marinković, A. D., Savić, J. Z., Mladenović, M. R., Erić, M. D., Marković, Z. J.,& Ristić, M. Đ.. (2023). Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling. in Toxics
MDPI., 11(4), 396.
https://doi.org/10.3390/toxics11040396

Buha Marković JZ, Marinković AD, Savić JZ, Mladenović MR, Erić MD, Marković ZJ, Ristić MĐ. Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling. in Toxics. 2023;11(4):396.
doi:10.3390/toxics11040396 .

Buha Marković, Jovana Z., Marinković, Ana D., Savić, Jasmina Z., Mladenović, Milica R., Erić, Milić D., Marković, Zoran J., Ristić, Mirjana Đ., "Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling" in Toxics, 11, no. 4 (2023):396,
https://doi.org/10.3390/toxics11040396 . .

TY  - JOUR
AU  - Buha Marković, Jovana Z.
AU  - Marinković, Ana D.
AU  - Savić, Jasmina Z.
AU  - Krstić, Aleksandar D.
AU  - Savić, Andrija B.
AU  - Ristić, Mirjana Đ.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7026
AB  - Lignite and coal waste used as feed fuels in thermal power plants
(TPPs) and semi-industrial fluidized bed boiler (FBB), as well as their representative fly ashes (FAs), were examined. Fly ashes were compared employing
anions and cations content in correspondent water extracts, trace elements and
polycyclic aromatic hydrocarbon concentrations, as well as health risk assessments of substances known to be of concern for public health. Fluoride and sulfate contents in water extracted FAs are far below the legislation limits for
waste, classifying all investigated FAs as non-hazardous. Among investigated
trace elements, Cd content is the lowest, while Mn content is the highest. The
highest enrichment ratios are noticed for As, Pb, Hg, Cu, V and Cr. The results
indicate that total PAHs content is elevated in FA from the combustion of coal
waste (AFB), with fluoranthene prevailing. The cancer risk of As and the non-
-cancer risk of As and Ni in some FAs surpass their respective permissible
limits. The incremental lifetime cancer risk of an adult population indicates a
potential PAHs risk in AFB, whereas all other fly ashes are within safe limits.
AB  - U ovom radu, ispitivana su goriva (lignit i otpadni ugalj) koja se koriste u termoelektranama i poluindustrijskom postrojenju sa fluidizovanim slojem, kao i leteći
pepeli dobijeni njihovim sagorevanjem. Leteći pepeli su upoređeni na osnovu: sadržaja anjona i katjona u njihovim vodenim ekstraktima, koncentracije elemenata u
tragovima i policikličnih aromatičnih ugljovodonika (PAH), kao i procene zdravstvenog rizika koji potiče od prethodno pomenutih potencijalno opasnih supstanci.
Sadržaj fluorida i sulfata u vodenim ekstraktima letećih pepela daleko je ispod
zakonski dozvoljenih granica za otpad, na osnovu čega se mogu svrstati u bezopasne. Od
ispitivanih elemenata u tragovima, sadržaj Cd je najniži, dok je koncentracija Mn
najviša. Najveće obogaćenje pepela u odnosu na odgovarajući ugalj, primećeno je za As,
Pb, Hg, Cu, V i Cr. Na osnovu dobijenih rezultata pokazano je da je ukupni sadržaj PAH
najveći za leteći pepeo dobijen sagorevanjem otpadnog uglja. Među ispitivanim PAH,
najvišu koncentraciju ima fluoranten. Rizici koji potiču od arsena (među kancerogenim elementima), kao i arsena i nikla (među nekancerogenim elementima), premašuju dozvoljene granične vrednosti. Vrednost procenjenog rizika od raka kod odrasle
populacije u slučaju PAH, pokazuje da za leteći pepeo dobijen sagorevanjem otpadnog
uglja postoji potencijalni rizik, dok su vrednosti za ostale pepele unutar dozvoljenih
granica.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion
T1  - Procena rizika za potencijalno opasne supstance iz letećih pepela dobijenih sagorevanjem uglja i otpadnog uglja
EP  - 1173
IS  - 11
SP  - 1161
VL  - 88
DO  - 10.2298/JSC220130048M
ER  - 

@article{
author = "Buha Marković, Jovana Z. and Marinković, Ana D. and Savić, Jasmina Z. and Krstić, Aleksandar D. and Savić, Andrija B. and Ristić, Mirjana Đ.",
year = "2023",
abstract = "Lignite and coal waste used as feed fuels in thermal power plants
(TPPs) and semi-industrial fluidized bed boiler (FBB), as well as their representative fly ashes (FAs), were examined. Fly ashes were compared employing
anions and cations content in correspondent water extracts, trace elements and
polycyclic aromatic hydrocarbon concentrations, as well as health risk assessments of substances known to be of concern for public health. Fluoride and sulfate contents in water extracted FAs are far below the legislation limits for
waste, classifying all investigated FAs as non-hazardous. Among investigated
trace elements, Cd content is the lowest, while Mn content is the highest. The
highest enrichment ratios are noticed for As, Pb, Hg, Cu, V and Cr. The results
indicate that total PAHs content is elevated in FA from the combustion of coal
waste (AFB), with fluoranthene prevailing. The cancer risk of As and the non-
-cancer risk of As and Ni in some FAs surpass their respective permissible
limits. The incremental lifetime cancer risk of an adult population indicates a
potential PAHs risk in AFB, whereas all other fly ashes are within safe limits., U ovom radu, ispitivana su goriva (lignit i otpadni ugalj) koja se koriste u termoelektranama i poluindustrijskom postrojenju sa fluidizovanim slojem, kao i leteći
pepeli dobijeni njihovim sagorevanjem. Leteći pepeli su upoređeni na osnovu: sadržaja anjona i katjona u njihovim vodenim ekstraktima, koncentracije elemenata u
tragovima i policikličnih aromatičnih ugljovodonika (PAH), kao i procene zdravstvenog rizika koji potiče od prethodno pomenutih potencijalno opasnih supstanci.
Sadržaj fluorida i sulfata u vodenim ekstraktima letećih pepela daleko je ispod
zakonski dozvoljenih granica za otpad, na osnovu čega se mogu svrstati u bezopasne. Od
ispitivanih elemenata u tragovima, sadržaj Cd je najniži, dok je koncentracija Mn
najviša. Najveće obogaćenje pepela u odnosu na odgovarajući ugalj, primećeno je za As,
Pb, Hg, Cu, V i Cr. Na osnovu dobijenih rezultata pokazano je da je ukupni sadržaj PAH
najveći za leteći pepeo dobijen sagorevanjem otpadnog uglja. Među ispitivanim PAH,
najvišu koncentraciju ima fluoranten. Rizici koji potiču od arsena (među kancerogenim elementima), kao i arsena i nikla (među nekancerogenim elementima), premašuju dozvoljene granične vrednosti. Vrednost procenjenog rizika od raka kod odrasle
populacije u slučaju PAH, pokazuje da za leteći pepeo dobijen sagorevanjem otpadnog
uglja postoji potencijalni rizik, dok su vrednosti za ostale pepele unutar dozvoljenih
granica.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion, Procena rizika za potencijalno opasne supstance iz letećih pepela dobijenih sagorevanjem uglja i otpadnog uglja",
pages = "1173-1161",
number = "11",
volume = "88",
doi = "10.2298/JSC220130048M"
}

Buha Marković, J. Z., Marinković, A. D., Savić, J. Z., Krstić, A. D., Savić, A. B.,& Ristić, M. Đ.. (2023). Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 88(11), 1161-1173.
https://doi.org/10.2298/JSC220130048M

Buha Marković JZ, Marinković AD, Savić JZ, Krstić AD, Savić AB, Ristić MĐ. Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion. in Journal of the Serbian Chemical Society. 2023;88(11):1161-1173.
doi:10.2298/JSC220130048M .

Buha Marković, Jovana Z., Marinković, Ana D., Savić, Jasmina Z., Krstić, Aleksandar D., Savić, Andrija B., Ristić, Mirjana Đ., "Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion" in Journal of the Serbian Chemical Society, 88, no. 11 (2023):1161-1173,
https://doi.org/10.2298/JSC220130048M . .