Gabrijel, Marijan Z.

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Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices

Radović, Ivona; Kijevčanin, Mirjana; Gabrijel, Marijan Z.; Šerbanović, Slobodan P.; Đorđević, Bojan D.

(Versita, Warsaw, 2008)

TY  - JOUR
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
AU  - Gabrijel, Marijan Z.
AU  - Šerbanović, Slobodan P.
AU  - Đorđević, Bojan D.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1299
AB  - The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.
PB  - Versita, Warsaw
T2  - Chemical Papers
T1  - Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices
EP  - 312
IS  - 3
SP  - 302
VL  - 62
DO  - 10.2478/s11696-008-0027-x
ER  - 
@article{
author = "Radović, Ivona and Kijevčanin, Mirjana and Gabrijel, Marijan Z. and Šerbanović, Slobodan P. and Đorđević, Bojan D.",
year = "2008",
abstract = "The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.",
publisher = "Versita, Warsaw",
journal = "Chemical Papers",
title = "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices",
pages = "312-302",
number = "3",
volume = "62",
doi = "10.2478/s11696-008-0027-x"
}
Radović, I., Kijevčanin, M., Gabrijel, M. Z., Šerbanović, S. P.,& Đorđević, B. D.. (2008). Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers
Versita, Warsaw., 62(3), 302-312.
https://doi.org/10.2478/s11696-008-0027-x
Radović I, Kijevčanin M, Gabrijel MZ, Šerbanović SP, Đorđević BD. Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers. 2008;62(3):302-312.
doi:10.2478/s11696-008-0027-x .
Radović, Ivona, Kijevčanin, Mirjana, Gabrijel, Marijan Z., Šerbanović, Slobodan P., Đorđević, Bojan D., "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices" in Chemical Papers, 62, no. 3 (2008):302-312,
https://doi.org/10.2478/s11696-008-0027-x . .
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