Tošić, Mihajlo B.

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5aa38815-0026-45fc-a84c-43abf644f3c2
  • Tošić, Mihajlo B. (18)
  • Tošić, Mihajlo (1)
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Author's Bibliography

Dissolution behavior of a polyphosphate glass in simulated body fluid

Nikolić, Jelena D.; Tošić, Mihajlo B.; Grujić, Snežana; Živanović, Vladimir D.; Đošić, Marija; Matijašević, Srđan D.; Smiljanić, Sonja

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Nikolić, Jelena D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Đošić, Marija
AU  - Matijašević, Srđan D.
AU  - Smiljanić, Sonja
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3708
AB  - In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Dissolution behavior of a polyphosphate glass in simulated body fluid
EP  - 342
IS  - 3
SP  - 329
VL  - 82
DO  - 10.2298/JSC161031009N
ER  - 
@article{
author = "Nikolić, Jelena D. and Tošić, Mihajlo B. and Grujić, Snežana and Živanović, Vladimir D. and Đošić, Marija and Matijašević, Srđan D. and Smiljanić, Sonja",
year = "2017",
abstract = "In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Dissolution behavior of a polyphosphate glass in simulated body fluid",
pages = "342-329",
number = "3",
volume = "82",
doi = "10.2298/JSC161031009N"
}
Nikolić, J. D., Tošić, M. B., Grujić, S., Živanović, V. D., Đošić, M., Matijašević, S. D.,& Smiljanić, S.. (2017). Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(3), 329-342.
https://doi.org/10.2298/JSC161031009N
Nikolić JD, Tošić MB, Grujić S, Živanović VD, Đošić M, Matijašević SD, Smiljanić S. Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society. 2017;82(3):329-342.
doi:10.2298/JSC161031009N .
Nikolić, Jelena D., Tošić, Mihajlo B., Grujić, Snežana, Živanović, Vladimir D., Đošić, Marija, Matijašević, Srđan D., Smiljanić, Sonja, "Dissolution behavior of a polyphosphate glass in simulated body fluid" in Journal of the Serbian Chemical Society, 82, no. 3 (2017):329-342,
https://doi.org/10.2298/JSC161031009N . .
1
2

Effect of la2o3 on the structure and the properties of strontium borate glasses

Smiljanić, Sonja; Grujić, Snežana; Tošić, Mihajlo B.; Živanović, Vladimir D.; Matijašević, Srđan D.; Nikolić, Jelena D.; Topalović, Vladimir S.

(Savez hemijskih inženjera, Beograd, 2016)

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
AU  - Topalović, Vladimir S.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3451
AB  - The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Effect of la2o3 on the structure and the properties of strontium borate glasses
EP  - 115
IS  - 1
SP  - 111
VL  - 22
DO  - 10.2298/CICEQ150213031S
ER  - 
@article{
author = "Smiljanić, Sonja and Grujić, Snežana and Tošić, Mihajlo B. and Živanović, Vladimir D. and Matijašević, Srđan D. and Nikolić, Jelena D. and Topalović, Vladimir S.",
year = "2016",
abstract = "The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Effect of la2o3 on the structure and the properties of strontium borate glasses",
pages = "115-111",
number = "1",
volume = "22",
doi = "10.2298/CICEQ150213031S"
}
Smiljanić, S., Grujić, S., Tošić, M. B., Živanović, V. D., Matijašević, S. D., Nikolić, J. D.,& Topalović, V. S.. (2016). Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry & Chemical Engineering Quarterly
Savez hemijskih inženjera, Beograd., 22(1), 111-115.
https://doi.org/10.2298/CICEQ150213031S
Smiljanić S, Grujić S, Tošić MB, Živanović VD, Matijašević SD, Nikolić JD, Topalović VS. Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry & Chemical Engineering Quarterly. 2016;22(1):111-115.
doi:10.2298/CICEQ150213031S .
Smiljanić, Sonja, Grujić, Snežana, Tošić, Mihajlo B., Živanović, Vladimir D., Matijašević, Srđan D., Nikolić, Jelena D., Topalović, Vladimir S., "Effect of la2o3 on the structure and the properties of strontium borate glasses" in Chemical Industry & Chemical Engineering Quarterly, 22, no. 1 (2016):111-115,
https://doi.org/10.2298/CICEQ150213031S . .
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9
16

DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass

Živanović, Vladimir D.; Tošić, Mihajlo B.; Grujić, Snežana; Matijašević, Srđan D.; Stojanović, Jovica; Nikolić, J. D.; Smiljanić, Sonja

(Springer, Dordrecht, 2015)

TY  - JOUR
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Matijašević, Srđan D.
AU  - Stojanović, Jovica
AU  - Nikolić, J. D.
AU  - Smiljanić, Sonja
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3034
AB  - In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass
EP  - 1661
IS  - 3
SP  - 1653
VL  - 119
DO  - 10.1007/s10973-015-4390-x
ER  - 
@article{
author = "Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Matijašević, Srđan D. and Stojanović, Jovica and Nikolić, J. D. and Smiljanić, Sonja",
year = "2015",
abstract = "In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass",
pages = "1661-1653",
number = "3",
volume = "119",
doi = "10.1007/s10973-015-4390-x"
}
Živanović, V. D., Tošić, M. B., Grujić, S., Matijašević, S. D., Stojanović, J., Nikolić, J. D.,& Smiljanić, S.. (2015). DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 119(3), 1653-1661.
https://doi.org/10.1007/s10973-015-4390-x
Živanović VD, Tošić MB, Grujić S, Matijašević SD, Stojanović J, Nikolić JD, Smiljanić S. DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry. 2015;119(3):1653-1661.
doi:10.1007/s10973-015-4390-x .
Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, J. D., Smiljanić, Sonja, "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass" in Journal of Thermal Analysis and Calorimetry, 119, no. 3 (2015):1653-1661,
https://doi.org/10.1007/s10973-015-4390-x . .
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4
4

Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3

Smiljanić, Sonja; Grujić, Snežana; Tošić, Mihajlo B.; Živanović, Vladimir D.; Stojanović, Jovica; Matijašević, Srđan D.; Nikolić, Jelena D.

(Elsevier Sci Ltd, Oxford, 2014)

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan D.
AU  - Nikolić, Jelena D.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2800
AB  - Glasses with a constant B2O3 and an increasing La2O3 content in the system La2O3-SrO-B2O3 were obtained by the usual melt quenching procedure. The crystallization and sinterability of the glasses were investigated by hot stage microscopy (HSM), differential thermal analysis (DTA), X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). XRD analysis of the bulk samples evidenced the formation of the crystalline phases: La2SrB10O19, SrB6O10 and SrLaBO4. XRD and TEM/SAED analyses showed a polymorphic crystallization of the glass sample containing 14.3 mol% La2O3 with precipitation of the La2SrB10O19 phase. SEM analysis confirmed the surface crystallization mechanism of this sample. The kinetics of crystallization of the same sample was examined by DTA and the activation energy of crystal growth was calculated by the Kissinger model to be E-a=458 +/- 63 kJ mol(-1).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3
EP  - 305
IS  - 1
SP  - 297
VL  - 40
DO  - 10.1016/j.ceramint.2013.06.002
ER  - 
@article{
author = "Smiljanić, Sonja and Grujić, Snežana and Tošić, Mihajlo B. and Živanović, Vladimir D. and Stojanović, Jovica and Matijašević, Srđan D. and Nikolić, Jelena D.",
year = "2014",
abstract = "Glasses with a constant B2O3 and an increasing La2O3 content in the system La2O3-SrO-B2O3 were obtained by the usual melt quenching procedure. The crystallization and sinterability of the glasses were investigated by hot stage microscopy (HSM), differential thermal analysis (DTA), X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). XRD analysis of the bulk samples evidenced the formation of the crystalline phases: La2SrB10O19, SrB6O10 and SrLaBO4. XRD and TEM/SAED analyses showed a polymorphic crystallization of the glass sample containing 14.3 mol% La2O3 with precipitation of the La2SrB10O19 phase. SEM analysis confirmed the surface crystallization mechanism of this sample. The kinetics of crystallization of the same sample was examined by DTA and the activation energy of crystal growth was calculated by the Kissinger model to be E-a=458 +/- 63 kJ mol(-1).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3",
pages = "305-297",
number = "1",
volume = "40",
doi = "10.1016/j.ceramint.2013.06.002"
}
Smiljanić, S., Grujić, S., Tošić, M. B., Živanović, V. D., Stojanović, J., Matijašević, S. D.,& Nikolić, J. D.. (2014). Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3. in Ceramics International
Elsevier Sci Ltd, Oxford., 40(1), 297-305.
https://doi.org/10.1016/j.ceramint.2013.06.002
Smiljanić S, Grujić S, Tošić MB, Živanović VD, Stojanović J, Matijašević SD, Nikolić JD. Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3. in Ceramics International. 2014;40(1):297-305.
doi:10.1016/j.ceramint.2013.06.002 .
Smiljanić, Sonja, Grujić, Snežana, Tošić, Mihajlo B., Živanović, Vladimir D., Stojanović, Jovica, Matijašević, Srđan D., Nikolić, Jelena D., "Crystallization and sinterability of glass-ceramics in the system La2O3-SrO-B2O3" in Ceramics International, 40, no. 1 (2014):297-305,
https://doi.org/10.1016/j.ceramint.2013.06.002 . .
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Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system

Nikolić, Jelena D.; Smiljanić, Sonja; Matijašević, Srđan D.; Živanović, Vladimir D.; Tošić, Mihajlo B.; Grujić, Snežana; Stojanović, Jovica

(University of Novi Sad, 2013)

TY  - JOUR
AU  - Nikolić, Jelena D.
AU  - Smiljanić, Sonja
AU  - Matijašević, Srđan D.
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Stojanović, Jovica
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2333
AB  - The results of preparation and structural characterization of glass-ceramics from the system Li2O-Al2O3-GeO2-P2O5 are shown in this paper. The crystallization behaviour of the selected glass was examined under non-isothermal and isothermal crystallization conditions. DTA, XRD and SEM methods were employed for analyses. It was confirmed that this glass crystallizes by the volume crystallization mechanism. The results also showed that the glass crystallize by primary crystallization. As a primary phase the LiGe2(PO4)3 is formed and the traces of GeO2 as a secondary one is present. The crystallization process occurred at a high homogeneous nucleation rate and the spherical morphology of crystal growth. By applying the Kissinger relation the activation energy of crystal growth Ea = 462 kJ/mol was determined.
PB  - University of Novi Sad
T2  - Processing and Application of Ceramics
T1  - Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system
EP  - 151
IS  - 4
SP  - 147
VL  - 7
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2333
ER  - 
@article{
author = "Nikolić, Jelena D. and Smiljanić, Sonja and Matijašević, Srđan D. and Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Stojanović, Jovica",
year = "2013",
abstract = "The results of preparation and structural characterization of glass-ceramics from the system Li2O-Al2O3-GeO2-P2O5 are shown in this paper. The crystallization behaviour of the selected glass was examined under non-isothermal and isothermal crystallization conditions. DTA, XRD and SEM methods were employed for analyses. It was confirmed that this glass crystallizes by the volume crystallization mechanism. The results also showed that the glass crystallize by primary crystallization. As a primary phase the LiGe2(PO4)3 is formed and the traces of GeO2 as a secondary one is present. The crystallization process occurred at a high homogeneous nucleation rate and the spherical morphology of crystal growth. By applying the Kissinger relation the activation energy of crystal growth Ea = 462 kJ/mol was determined.",
publisher = "University of Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system",
pages = "151-147",
number = "4",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2333"
}
Nikolić, J. D., Smiljanić, S., Matijašević, S. D., Živanović, V. D., Tošić, M. B., Grujić, S.,& Stojanović, J.. (2013). Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system. in Processing and Application of Ceramics
University of Novi Sad., 7(4), 147-151.
https://hdl.handle.net/21.15107/rcub_technorep_2333
Nikolić JD, Smiljanić S, Matijašević SD, Živanović VD, Tošić MB, Grujić S, Stojanović J. Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system. in Processing and Application of Ceramics. 2013;7(4):147-151.
https://hdl.handle.net/21.15107/rcub_technorep_2333 .
Nikolić, Jelena D., Smiljanić, Sonja, Matijašević, Srđan D., Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Stojanović, Jovica, "Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system" in Processing and Application of Ceramics, 7, no. 4 (2013):147-151,
https://hdl.handle.net/21.15107/rcub_technorep_2333 .
8

Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions

Tošić, Mihajlo B.; Nikolić, J. D.; Grujić, Snežana; Živanović, Vladimir D.; Zildžović, Snežana; Matijašević, Srđan D.; Ždrale, Sonja V.

(Elsevier, Amsterdam, 2013)

TY  - JOUR
AU  - Tošić, Mihajlo B.
AU  - Nikolić, J. D.
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Zildžović, Snežana
AU  - Matijašević, Srđan D.
AU  - Ždrale, Sonja V.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2540
AB  - The dissolution behavior of a polyphosphate glass with a molar ratio [M2O + MO]/P2O5 gt 1 in distilled water under static condition was studied. The leaching tests were performed with glass powder samples (0.1-0.65 mm) at T=15-50 degrees C for times up to 720 h. The mass loss of the samples, the changes of pH and the concentration of elements (P, K, Ca, Mg, Zn and Mn) in solution were determined. The effects of temperature, time and particle size were analyzed. The results of the tests showed a complex dissolution behavior of this glass. The selective dissolution of the glass components was determined. The mechanism of formation and the structure of dissolved glass layer were investigated. The effects of cations on the mechanisms and kinetics of dissolution of the polyphosphate glass are presented. The activation energy of dissolution, Ea, was determined to be 39 +/- 5 kJ/mol.
PB  - Elsevier, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions
EP  - 194
SP  - 185
VL  - 362
DO  - 10.1016/j.jnoncrysol.2012.11.024
ER  - 
@article{
author = "Tošić, Mihajlo B. and Nikolić, J. D. and Grujić, Snežana and Živanović, Vladimir D. and Zildžović, Snežana and Matijašević, Srđan D. and Ždrale, Sonja V.",
year = "2013",
abstract = "The dissolution behavior of a polyphosphate glass with a molar ratio [M2O + MO]/P2O5 gt 1 in distilled water under static condition was studied. The leaching tests were performed with glass powder samples (0.1-0.65 mm) at T=15-50 degrees C for times up to 720 h. The mass loss of the samples, the changes of pH and the concentration of elements (P, K, Ca, Mg, Zn and Mn) in solution were determined. The effects of temperature, time and particle size were analyzed. The results of the tests showed a complex dissolution behavior of this glass. The selective dissolution of the glass components was determined. The mechanism of formation and the structure of dissolved glass layer were investigated. The effects of cations on the mechanisms and kinetics of dissolution of the polyphosphate glass are presented. The activation energy of dissolution, Ea, was determined to be 39 +/- 5 kJ/mol.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions",
pages = "194-185",
volume = "362",
doi = "10.1016/j.jnoncrysol.2012.11.024"
}
Tošić, M. B., Nikolić, J. D., Grujić, S., Živanović, V. D., Zildžović, S., Matijašević, S. D.,& Ždrale, S. V.. (2013). Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions. in Journal of Non-Crystalline Solids
Elsevier, Amsterdam., 362, 185-194.
https://doi.org/10.1016/j.jnoncrysol.2012.11.024
Tošić MB, Nikolić JD, Grujić S, Živanović VD, Zildžović S, Matijašević SD, Ždrale SV. Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions. in Journal of Non-Crystalline Solids. 2013;362:185-194.
doi:10.1016/j.jnoncrysol.2012.11.024 .
Tošić, Mihajlo B., Nikolić, J. D., Grujić, Snežana, Živanović, Vladimir D., Zildžović, Snežana, Matijašević, Srđan D., Ždrale, Sonja V., "Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions" in Journal of Non-Crystalline Solids, 362 (2013):185-194,
https://doi.org/10.1016/j.jnoncrysol.2012.11.024 . .
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The crystallization of potassium germanate glass with high content of niobium oxide

Matijašević, Srđan D.; Tošić, Mihajlo B.; Stojanović, Jovica; Grujić, Snežana; Živanović, Vladimir D.; Nikolić, Jelena D.; Đošić, Marija

(University of Chemistry and Technology, Prague, 2012)

TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Tošić, Mihajlo B.
AU  - Stojanović, Jovica
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Nikolić, Jelena D.
AU  - Đošić, Marija
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1981
AB  - Potassium germanate glass with molar ratio [GeO2]/[K2O] = 1.2 and Nb2O5 content of 34 mol% have been synthesized by a melt-quenching method. The crystallization behavior under non-isothermal and isothermal crystallization conditions was investigated. The results showed that this glass exposed complex primary crystallization. In the temperature range  lt  800 degrees C primary phase is K3.8Nb5Ge3O20.4, while K6Nb6Ge4O26 appeared as primary phase at temperatures  gt  800 degrees C. K10Nb22Ge4O68 and metastable KNbO3 and K4Nb6O17 were formed as secondary phases. The crystallization commenced at T  gt  640 degrees C with high homogeneous nucleation rate and spherulite crystal growth morphology. DTA curves recorded for powder samples particle size  lt  0.1 mm revealed three exothermic peaks and three endothermic peaks within temperature range of T = 640-940 degrees C, while the DTA curves recorded for powder samples particle size  gt  0.1 mm showed two exothermic peaks and two endothermic peaks within temperature range of T = 640-1020 degrees C. The analysis of the dominant crystallization mechanism of powder glass sample and kinetics of crystallization is presented.
PB  - University of Chemistry and Technology, Prague
T2  - Ceramics - Silikaty
T1  - The crystallization of potassium germanate glass with high content of niobium oxide
EP  - 68
IS  - 1
SP  - 61
VL  - 56
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1981
ER  - 
@article{
author = "Matijašević, Srđan D. and Tošić, Mihajlo B. and Stojanović, Jovica and Grujić, Snežana and Živanović, Vladimir D. and Nikolić, Jelena D. and Đošić, Marija",
year = "2012",
abstract = "Potassium germanate glass with molar ratio [GeO2]/[K2O] = 1.2 and Nb2O5 content of 34 mol% have been synthesized by a melt-quenching method. The crystallization behavior under non-isothermal and isothermal crystallization conditions was investigated. The results showed that this glass exposed complex primary crystallization. In the temperature range  lt  800 degrees C primary phase is K3.8Nb5Ge3O20.4, while K6Nb6Ge4O26 appeared as primary phase at temperatures  gt  800 degrees C. K10Nb22Ge4O68 and metastable KNbO3 and K4Nb6O17 were formed as secondary phases. The crystallization commenced at T  gt  640 degrees C with high homogeneous nucleation rate and spherulite crystal growth morphology. DTA curves recorded for powder samples particle size  lt  0.1 mm revealed three exothermic peaks and three endothermic peaks within temperature range of T = 640-940 degrees C, while the DTA curves recorded for powder samples particle size  gt  0.1 mm showed two exothermic peaks and two endothermic peaks within temperature range of T = 640-1020 degrees C. The analysis of the dominant crystallization mechanism of powder glass sample and kinetics of crystallization is presented.",
publisher = "University of Chemistry and Technology, Prague",
journal = "Ceramics - Silikaty",
title = "The crystallization of potassium germanate glass with high content of niobium oxide",
pages = "68-61",
number = "1",
volume = "56",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1981"
}
Matijašević, S. D., Tošić, M. B., Stojanović, J., Grujić, S., Živanović, V. D., Nikolić, J. D.,& Đošić, M.. (2012). The crystallization of potassium germanate glass with high content of niobium oxide. in Ceramics - Silikaty
University of Chemistry and Technology, Prague., 56(1), 61-68.
https://hdl.handle.net/21.15107/rcub_technorep_1981
Matijašević SD, Tošić MB, Stojanović J, Grujić S, Živanović VD, Nikolić JD, Đošić M. The crystallization of potassium germanate glass with high content of niobium oxide. in Ceramics - Silikaty. 2012;56(1):61-68.
https://hdl.handle.net/21.15107/rcub_technorep_1981 .
Matijašević, Srđan D., Tošić, Mihajlo B., Stojanović, Jovica, Grujić, Snežana, Živanović, Vladimir D., Nikolić, Jelena D., Đošić, Marija, "The crystallization of potassium germanate glass with high content of niobium oxide" in Ceramics - Silikaty, 56, no. 1 (2012):61-68,
https://hdl.handle.net/21.15107/rcub_technorep_1981 .
2

Secondary measures for reduction of NOx emission in glass melting process

Nikolić, Jelena; Tošić, Mihajlo B.; Živanović, Vladimir D.; Matijašević, Srđan D.; Zildžović, Snežana; Grujić, Snežana; Ždrale, Sonja V.

(Savez inženjera i tehničara Srbije, Beograd, 2012)

TY  - JOUR
AU  - Nikolić, Jelena
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
AU  - Ždrale, Sonja V.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2025
AB  - In this paper the new methods for reduction of NOx emission from glass melting furnaces were presented. The secondary measures are focused on development of different methods for elimination of nitrogen oxide from the smoke gasses. The main characteristics of the selective catalytic reduction process (SCR), selective non catalytic reduction process (SNCR) and 3R process were presented and some advantages and limitations of these processes were analyzed.
AB  - U ovom radu su prikazani novi postupci smanjenja emisije NOx iz peći za topljenje stakla. Zbog visokih temperatura do kojih se zagreva vazduh neophodan za sagorevanje dolazi do visoke emisije oksida NOx iz staklarskih peći. Sekundarne mere usmerene su na razvoj postupaka za uklanjanje azotnih oksida iz dimnih gasova. Dat je prikaz selektivno nekatalitičkog, selektivno katalitičkog redukcionog i 3R postupka kao i njihove prednosti i nedostaci.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Secondary measures for reduction of NOx emission in glass melting process
T1  - Sekundarni postupci smanjenja emisije oksida azota u procesu topljenja stakla
EP  - 556
IS  - 4
SP  - 553
VL  - 67
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2025
ER  - 
@article{
author = "Nikolić, Jelena and Tošić, Mihajlo B. and Živanović, Vladimir D. and Matijašević, Srđan D. and Zildžović, Snežana and Grujić, Snežana and Ždrale, Sonja V.",
year = "2012",
abstract = "In this paper the new methods for reduction of NOx emission from glass melting furnaces were presented. The secondary measures are focused on development of different methods for elimination of nitrogen oxide from the smoke gasses. The main characteristics of the selective catalytic reduction process (SCR), selective non catalytic reduction process (SNCR) and 3R process were presented and some advantages and limitations of these processes were analyzed., U ovom radu su prikazani novi postupci smanjenja emisije NOx iz peći za topljenje stakla. Zbog visokih temperatura do kojih se zagreva vazduh neophodan za sagorevanje dolazi do visoke emisije oksida NOx iz staklarskih peći. Sekundarne mere usmerene su na razvoj postupaka za uklanjanje azotnih oksida iz dimnih gasova. Dat je prikaz selektivno nekatalitičkog, selektivno katalitičkog redukcionog i 3R postupka kao i njihove prednosti i nedostaci.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Secondary measures for reduction of NOx emission in glass melting process, Sekundarni postupci smanjenja emisije oksida azota u procesu topljenja stakla",
pages = "556-553",
number = "4",
volume = "67",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2025"
}
Nikolić, J., Tošić, M. B., Živanović, V. D., Matijašević, S. D., Zildžović, S., Grujić, S.,& Ždrale, S. V.. (2012). Secondary measures for reduction of NOx emission in glass melting process. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 67(4), 553-556.
https://hdl.handle.net/21.15107/rcub_technorep_2025
Nikolić J, Tošić MB, Živanović VD, Matijašević SD, Zildžović S, Grujić S, Ždrale SV. Secondary measures for reduction of NOx emission in glass melting process. in Tehnika. 2012;67(4):553-556.
https://hdl.handle.net/21.15107/rcub_technorep_2025 .
Nikolić, Jelena, Tošić, Mihajlo B., Živanović, Vladimir D., Matijašević, Srđan D., Zildžović, Snežana, Grujić, Snežana, Ždrale, Sonja V., "Secondary measures for reduction of NOx emission in glass melting process" in Tehnika, 67, no. 4 (2012):553-556,
https://hdl.handle.net/21.15107/rcub_technorep_2025 .

Application of controlled release glass in the production of French marigold (Tagetes patula L.)

Vujošević, Ana; Lakić, Nada; Tošić, Mihajlo B.; Nikolić, Jelena; Živanović, Vladimir D.; Matijašević, Srđan D.; Zildžović, Snežana; Grujić, Snežana; Ždrale, Sonja V.

(Institute of field and vegetable crops, Novi Sad, 2012)

TY  - JOUR
AU  - Vujošević, Ana
AU  - Lakić, Nada
AU  - Tošić, Mihajlo B.
AU  - Nikolić, Jelena
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
AU  - Ždrale, Sonja V.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2062
AB  - This paper investigates the possibility and justification of controlled release glass application as a new ecological material in the production of plants-seedlings of French marigold (Tagetes patula L.). During the investigation its influence on the development of the produced plants-seedlings was monitored. The seedlings were produced in poly-propylene containers (speedling system) and poly-propylene pots (pot system). The trial was conducted in the greenhouse at the Faculty of Agriculture in Belgrade during 2011. In the course of seedling production the glass granulation of  lt  0.5 mm was added in the following doses: 0, 1, 2, 3, and 4 g/l. The results of the research show a positive effect of controlled release glass application in the production of French marigold seedlings, since high quality seedlings were produced justifying its application. The best effect on the analyzed parameters of plant-seedling development was found when substrate was applied in the dose of 1 g/l.
AB  - U radu je ispitivana mogućnost i opravdanost primene stakla sa kontrolisanim otpuštanjem hranljivih elemenata kao novog ekološkog materijala u proizvodnji biljaka-rasada kadifice (Tagetes patula L.). Tokom istraživanja praćen je njegov uticaj na razvijenost proizvedenih biljaka-rasada. Biljke-rasada proizvedene su u polistirenskim kontejnerima (speedling system) i polipropilenskim saksijama (pot system). Istraživanja su sprovedena u stakleniku Poljoprivrednog fakulteta u Beogradu tokom 2011. U toku proizvodnje rasada dodavano je ispitivano staklo granulacije  lt  0,5 mm u dozama 0-4 g/l. Rezultati istraživanja ukazuju na pozitivan efekat primenjenog stakla sa kontrolisanim otpuštanjem jona u proizvodnji biljaka-rasada kadifice. Njegovom primenom dobija se rasad bolje razvijenosti, te je njegova upotreba opravdana. Najbolji efekat na ispitivane parametre razvijenosti biljaka-rasada imala je doza od 1 g/l supstrata.
PB  - Institute of field and vegetable crops, Novi Sad
T2  - Ratarstvo i povrtarstvo
T1  - Application of controlled release glass in the production of French marigold (Tagetes patula L.)
T1  - Primena stakla sa kontrolisanim otpuštanjem hranljivih elemenata u proizvodnji rasada kadifice (Tagetes patula L.)
EP  - 16
IS  - 1
SP  - 12
VL  - 49
DO  - 10.5937/ratpov49-1137
ER  - 
@article{
author = "Vujošević, Ana and Lakić, Nada and Tošić, Mihajlo B. and Nikolić, Jelena and Živanović, Vladimir D. and Matijašević, Srđan D. and Zildžović, Snežana and Grujić, Snežana and Ždrale, Sonja V.",
year = "2012",
abstract = "This paper investigates the possibility and justification of controlled release glass application as a new ecological material in the production of plants-seedlings of French marigold (Tagetes patula L.). During the investigation its influence on the development of the produced plants-seedlings was monitored. The seedlings were produced in poly-propylene containers (speedling system) and poly-propylene pots (pot system). The trial was conducted in the greenhouse at the Faculty of Agriculture in Belgrade during 2011. In the course of seedling production the glass granulation of  lt  0.5 mm was added in the following doses: 0, 1, 2, 3, and 4 g/l. The results of the research show a positive effect of controlled release glass application in the production of French marigold seedlings, since high quality seedlings were produced justifying its application. The best effect on the analyzed parameters of plant-seedling development was found when substrate was applied in the dose of 1 g/l., U radu je ispitivana mogućnost i opravdanost primene stakla sa kontrolisanim otpuštanjem hranljivih elemenata kao novog ekološkog materijala u proizvodnji biljaka-rasada kadifice (Tagetes patula L.). Tokom istraživanja praćen je njegov uticaj na razvijenost proizvedenih biljaka-rasada. Biljke-rasada proizvedene su u polistirenskim kontejnerima (speedling system) i polipropilenskim saksijama (pot system). Istraživanja su sprovedena u stakleniku Poljoprivrednog fakulteta u Beogradu tokom 2011. U toku proizvodnje rasada dodavano je ispitivano staklo granulacije  lt  0,5 mm u dozama 0-4 g/l. Rezultati istraživanja ukazuju na pozitivan efekat primenjenog stakla sa kontrolisanim otpuštanjem jona u proizvodnji biljaka-rasada kadifice. Njegovom primenom dobija se rasad bolje razvijenosti, te je njegova upotreba opravdana. Najbolji efekat na ispitivane parametre razvijenosti biljaka-rasada imala je doza od 1 g/l supstrata.",
publisher = "Institute of field and vegetable crops, Novi Sad",
journal = "Ratarstvo i povrtarstvo",
title = "Application of controlled release glass in the production of French marigold (Tagetes patula L.), Primena stakla sa kontrolisanim otpuštanjem hranljivih elemenata u proizvodnji rasada kadifice (Tagetes patula L.)",
pages = "16-12",
number = "1",
volume = "49",
doi = "10.5937/ratpov49-1137"
}
Vujošević, A., Lakić, N., Tošić, M. B., Nikolić, J., Živanović, V. D., Matijašević, S. D., Zildžović, S., Grujić, S.,& Ždrale, S. V.. (2012). Application of controlled release glass in the production of French marigold (Tagetes patula L.). in Ratarstvo i povrtarstvo
Institute of field and vegetable crops, Novi Sad., 49(1), 12-16.
https://doi.org/10.5937/ratpov49-1137
Vujošević A, Lakić N, Tošić MB, Nikolić J, Živanović VD, Matijašević SD, Zildžović S, Grujić S, Ždrale SV. Application of controlled release glass in the production of French marigold (Tagetes patula L.). in Ratarstvo i povrtarstvo. 2012;49(1):12-16.
doi:10.5937/ratpov49-1137 .
Vujošević, Ana, Lakić, Nada, Tošić, Mihajlo B., Nikolić, Jelena, Živanović, Vladimir D., Matijašević, Srđan D., Zildžović, Snežana, Grujić, Snežana, Ždrale, Sonja V., "Application of controlled release glass in the production of French marigold (Tagetes patula L.)" in Ratarstvo i povrtarstvo, 49, no. 1 (2012):12-16,
https://doi.org/10.5937/ratpov49-1137 . .

The effect of K2O on the crystallization of niobium germanate glasses

Matijašević, Srđan D.; Tošić, Mihajlo B.; Grujić, Snežana; Stojanović, Jovica; Živanović, Vladimir D.; Nikolić, J. D.

(International Institute for the Science of Sintering, Beograd, 2011)

TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Stojanović, Jovica
AU  - Živanović, Vladimir D.
AU  - Nikolić, J. D.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1832
AB  - The effect of K2O content on the crystallization of niobium germanate glasses with 22.7- 24.27 wt% of GeO2 and 54.59-57.48 wt% of Nb2O5 was examined. The glasses crystallize by primary crystallization and the formed crystalline phases were K6Nb6Ge4O26, K3.8Nb5Ge3O20.4 and KNbO3. Increasing the K2O content caused a decrease in the GeO2 content of the primary phases. The effect of the K2O content on the kinetics of primary crystallization was analyzed. It was demonstrated that an increase of the K2O content decreased the activation energy of crystal growth at first of the crystallization peaks (Ec1). At second crystallization peaks the activation energies of crystal growth increased (Ec2).
AB  - Ispitan je uticaj sadržaja K2O na kristalizaciju niobijum germanatnih stakala sa 22,7-24,27 mas % GeO2 i 54,59-57,48 mas % Nb2O5. Ova stakla kristališu primarnom kristalizacijom i stvaraju se kristalne faze K6Nb6Ge4O26, K3.8Nb5Ge3O20.4 i KNbO3. Povećanje sadržaja K2O prouzrokuje smanjenje sadržaja GeO2 u primarnim fazama. Analiziran je uticaj sadržaja K2O na kinetiku primarne kristalizacije. Pokazano je da povećanje sadržaja K2O smanjuje energiju aktivacije rasta kristala na prvom kristalizacionom piku (Ec1). Na drugom kristalizacionom piku energije aktivacije rasta kristala se povećavaju (Ec2).
PB  - International Institute for the Science of Sintering, Beograd
T2  - Science of Sintering
T1  - The effect of K2O on the crystallization of niobium germanate glasses
EP  - 53
IS  - 1
SP  - 47
VL  - 43
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1832
ER  - 
@article{
author = "Matijašević, Srđan D. and Tošić, Mihajlo B. and Grujić, Snežana and Stojanović, Jovica and Živanović, Vladimir D. and Nikolić, J. D.",
year = "2011",
abstract = "The effect of K2O content on the crystallization of niobium germanate glasses with 22.7- 24.27 wt% of GeO2 and 54.59-57.48 wt% of Nb2O5 was examined. The glasses crystallize by primary crystallization and the formed crystalline phases were K6Nb6Ge4O26, K3.8Nb5Ge3O20.4 and KNbO3. Increasing the K2O content caused a decrease in the GeO2 content of the primary phases. The effect of the K2O content on the kinetics of primary crystallization was analyzed. It was demonstrated that an increase of the K2O content decreased the activation energy of crystal growth at first of the crystallization peaks (Ec1). At second crystallization peaks the activation energies of crystal growth increased (Ec2)., Ispitan je uticaj sadržaja K2O na kristalizaciju niobijum germanatnih stakala sa 22,7-24,27 mas % GeO2 i 54,59-57,48 mas % Nb2O5. Ova stakla kristališu primarnom kristalizacijom i stvaraju se kristalne faze K6Nb6Ge4O26, K3.8Nb5Ge3O20.4 i KNbO3. Povećanje sadržaja K2O prouzrokuje smanjenje sadržaja GeO2 u primarnim fazama. Analiziran je uticaj sadržaja K2O na kinetiku primarne kristalizacije. Pokazano je da povećanje sadržaja K2O smanjuje energiju aktivacije rasta kristala na prvom kristalizacionom piku (Ec1). Na drugom kristalizacionom piku energije aktivacije rasta kristala se povećavaju (Ec2).",
publisher = "International Institute for the Science of Sintering, Beograd",
journal = "Science of Sintering",
title = "The effect of K2O on the crystallization of niobium germanate glasses",
pages = "53-47",
number = "1",
volume = "43",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1832"
}
Matijašević, S. D., Tošić, M. B., Grujić, S., Stojanović, J., Živanović, V. D.,& Nikolić, J. D.. (2011). The effect of K2O on the crystallization of niobium germanate glasses. in Science of Sintering
International Institute for the Science of Sintering, Beograd., 43(1), 47-53.
https://hdl.handle.net/21.15107/rcub_technorep_1832
Matijašević SD, Tošić MB, Grujić S, Stojanović J, Živanović VD, Nikolić JD. The effect of K2O on the crystallization of niobium germanate glasses. in Science of Sintering. 2011;43(1):47-53.
https://hdl.handle.net/21.15107/rcub_technorep_1832 .
Matijašević, Srđan D., Tošić, Mihajlo B., Grujić, Snežana, Stojanović, Jovica, Živanović, Vladimir D., Nikolić, J. D., "The effect of K2O on the crystallization of niobium germanate glasses" in Science of Sintering, 43, no. 1 (2011):47-53,
https://hdl.handle.net/21.15107/rcub_technorep_1832 .
2
4

Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2

Matijašević, Srđan D.; Živanović, Vladimir D.; Tošić, Mihajlo B.; Grujić, Snežana; Stojanović, Jovica; Nikolić, Jelena D.; Ždrale, Sonja V.

(University of Novi Sad, 2011)

TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Stojanović, Jovica
AU  - Nikolić, Jelena D.
AU  - Ždrale, Sonja V.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1821
AB  - This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.
PB  - University of Novi Sad
T2  - Processing and Application of Ceramics
T1  - Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2
EP  - 227
IS  - 4
SP  - 223
VL  - 5
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1821
ER  - 
@article{
author = "Matijašević, Srđan D. and Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Stojanović, Jovica and Nikolić, Jelena D. and Ždrale, Sonja V.",
year = "2011",
abstract = "This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.",
publisher = "University of Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2",
pages = "227-223",
number = "4",
volume = "5",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1821"
}
Matijašević, S. D., Živanović, V. D., Tošić, M. B., Grujić, S., Stojanović, J., Nikolić, J. D.,& Ždrale, S. V.. (2011). Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics
University of Novi Sad., 5(4), 223-227.
https://hdl.handle.net/21.15107/rcub_technorep_1821
Matijašević SD, Živanović VD, Tošić MB, Grujić S, Stojanović J, Nikolić JD, Ždrale SV. Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics. 2011;5(4):223-227.
https://hdl.handle.net/21.15107/rcub_technorep_1821 .
Matijašević, Srđan D., Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Stojanović, Jovica, Nikolić, Jelena D., Ždrale, Sonja V., "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2" in Processing and Application of Ceramics, 5, no. 4 (2011):223-227,
https://hdl.handle.net/21.15107/rcub_technorep_1821 .

Measures and methods for NOx reduction from glass-melting furnaces

Nikolić, Jelena D.; Tošić, Mihajlo B.; Živanović, Vladimir D.; Matijašević, Srđan D.; Živanović, Deana B.; Grujić, Snežana; Ždrale, Sonja V.

(Savez inženjera i tehničara Srbije, Beograd, 2011)

TY  - JOUR
AU  - Nikolić, Jelena D.
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan D.
AU  - Živanović, Deana B.
AU  - Grujić, Snežana
AU  - Ždrale, Sonja V.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1828
AB  - The nitrogen oxides emitted to atmosphere effect significantly on formation of photochemical smog, acidic rains and destroying of ozone shell of the earth. Therefore, the regulations for limited emission of nitrogen oxides to atmosphere become very strict. Glass manufacturing is a high-temperature, energy-intensive activity, because of the high temperature NOx emissions are extremely high. NOx emissions could be reduced by primary process modifications measures end secondary post-combustion measures. Primary process modifications are usually based on the following techniques: stoichiometric combustion and advanced burners systems, staged combustion (air- or fuelstaged), recircylation of flue gasses.
AB  - Razvojem tehnike i tehnologije javlja se potreba za većom proizvodnjom energije. Iako se danas uvode u upotrebu i drugi izvori energije, još uvek je najzastupljenije dobijanje energije u procesu sagorevanja goriva. Zbog visokih temperatura koje nastaju pri sagorevanje dolazi do velike emisije NOx oksida. U ovom radu opisane su mere i metode kojima je moguće smanjiti emisiju NOx u procesima dobijanja stakla.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Measures and methods for NOx reduction from glass-melting furnaces
T1  - Mere i metode za smanjenja emisije oksida azota iz peći za topljenje stakla
EP  - 398
IS  - 3
SP  - 393
VL  - 66
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1828
ER  - 
@article{
author = "Nikolić, Jelena D. and Tošić, Mihajlo B. and Živanović, Vladimir D. and Matijašević, Srđan D. and Živanović, Deana B. and Grujić, Snežana and Ždrale, Sonja V.",
year = "2011",
abstract = "The nitrogen oxides emitted to atmosphere effect significantly on formation of photochemical smog, acidic rains and destroying of ozone shell of the earth. Therefore, the regulations for limited emission of nitrogen oxides to atmosphere become very strict. Glass manufacturing is a high-temperature, energy-intensive activity, because of the high temperature NOx emissions are extremely high. NOx emissions could be reduced by primary process modifications measures end secondary post-combustion measures. Primary process modifications are usually based on the following techniques: stoichiometric combustion and advanced burners systems, staged combustion (air- or fuelstaged), recircylation of flue gasses., Razvojem tehnike i tehnologije javlja se potreba za većom proizvodnjom energije. Iako se danas uvode u upotrebu i drugi izvori energije, još uvek je najzastupljenije dobijanje energije u procesu sagorevanja goriva. Zbog visokih temperatura koje nastaju pri sagorevanje dolazi do velike emisije NOx oksida. U ovom radu opisane su mere i metode kojima je moguće smanjiti emisiju NOx u procesima dobijanja stakla.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Measures and methods for NOx reduction from glass-melting furnaces, Mere i metode za smanjenja emisije oksida azota iz peći za topljenje stakla",
pages = "398-393",
number = "3",
volume = "66",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1828"
}
Nikolić, J. D., Tošić, M. B., Živanović, V. D., Matijašević, S. D., Živanović, D. B., Grujić, S.,& Ždrale, S. V.. (2011). Measures and methods for NOx reduction from glass-melting furnaces. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 66(3), 393-398.
https://hdl.handle.net/21.15107/rcub_technorep_1828
Nikolić JD, Tošić MB, Živanović VD, Matijašević SD, Živanović DB, Grujić S, Ždrale SV. Measures and methods for NOx reduction from glass-melting furnaces. in Tehnika. 2011;66(3):393-398.
https://hdl.handle.net/21.15107/rcub_technorep_1828 .
Nikolić, Jelena D., Tošić, Mihajlo B., Živanović, Vladimir D., Matijašević, Srđan D., Živanović, Deana B., Grujić, Snežana, Ždrale, Sonja V., "Measures and methods for NOx reduction from glass-melting furnaces" in Tehnika, 66, no. 3 (2011):393-398,
https://hdl.handle.net/21.15107/rcub_technorep_1828 .

Crystal growth of K2TiGe3O9 in the glass

Grujić, Snežana; Blagojević, Nikola S.; Tošić, Mihajlo B.; Živanović, Vladimir D.; Acimović-Pavlović, Zagorka

(Serbian Chemical Society, Belgrade, 2010)

TY  - JOUR
AU  - Grujić, Snežana
AU  - Blagojević, Nikola S.
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Acimović-Pavlović, Zagorka
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1595
AB  - The kinetics and mechanism of isothermal crystal growth of K2TiGe3O9 from a glass of the same stoichiometric composition were studied. The crystal growth rate, U, in the range 1x10-11-1.27x10-10 m s-1 was experimentally determined in the temperature interval 540-600°C. In the range of high under-cooling, Δt, 435-375°C, spherical crystals growing at (374±19) kJ mol-1 was observed.
AB  - Pod izotermskim uslovima proučavana je kinetika i mehanizam rasta K2TiGe3O9 kristala iz stakla istog stehiometrijskog sastava. U intervalu temperature 540-600°C eksperimentalno su određene brzine rasta kristala, U, 1x10-11-1.27x10-10 m s-1. Pokazano je da se u oblasti visokih pothlađenja, Δt, 435-375°C, rast sfernih kristala ove faze odvija po mehanizmu zavojne dislokacije. Dobijena je energija aktivacije rasta kristala GD=(374±19) kJ mol-1.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Crystal growth of K2TiGe3O9 in the glass
T1  - Rast kristala K2TiGe3O9 u staklu
EP  - 1604
IS  - 11
SP  - 1595
VL  - 75
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1595
ER  - 
@article{
author = "Grujić, Snežana and Blagojević, Nikola S. and Tošić, Mihajlo B. and Živanović, Vladimir D. and Acimović-Pavlović, Zagorka",
year = "2010",
abstract = "The kinetics and mechanism of isothermal crystal growth of K2TiGe3O9 from a glass of the same stoichiometric composition were studied. The crystal growth rate, U, in the range 1x10-11-1.27x10-10 m s-1 was experimentally determined in the temperature interval 540-600°C. In the range of high under-cooling, Δt, 435-375°C, spherical crystals growing at (374±19) kJ mol-1 was observed., Pod izotermskim uslovima proučavana je kinetika i mehanizam rasta K2TiGe3O9 kristala iz stakla istog stehiometrijskog sastava. U intervalu temperature 540-600°C eksperimentalno su određene brzine rasta kristala, U, 1x10-11-1.27x10-10 m s-1. Pokazano je da se u oblasti visokih pothlađenja, Δt, 435-375°C, rast sfernih kristala ove faze odvija po mehanizmu zavojne dislokacije. Dobijena je energija aktivacije rasta kristala GD=(374±19) kJ mol-1.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Crystal growth of K2TiGe3O9 in the glass, Rast kristala K2TiGe3O9 u staklu",
pages = "1604-1595",
number = "11",
volume = "75",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1595"
}
Grujić, S., Blagojević, N. S., Tošić, M. B., Živanović, V. D.,& Acimović-Pavlović, Z.. (2010). Crystal growth of K2TiGe3O9 in the glass. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 75(11), 1595-1604.
https://hdl.handle.net/21.15107/rcub_technorep_1595
Grujić S, Blagojević NS, Tošić MB, Živanović VD, Acimović-Pavlović Z. Crystal growth of K2TiGe3O9 in the glass. in Journal of the Serbian Chemical Society. 2010;75(11):1595-1604.
https://hdl.handle.net/21.15107/rcub_technorep_1595 .
Grujić, Snežana, Blagojević, Nikola S., Tošić, Mihajlo B., Živanović, Vladimir D., Acimović-Pavlović, Zagorka, "Crystal growth of K2TiGe3O9 in the glass" in Journal of the Serbian Chemical Society, 75, no. 11 (2010):1595-1604,
https://hdl.handle.net/21.15107/rcub_technorep_1595 .
1

The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions

Tošić, Mihajlo B.; Grujić, Snežana; Živanović, Vladimir D.; Nikolić, J. D.; Matijašević, Srđan D.

(Elsevier, Amsterdam, 2010)

TY  - JOUR
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Živanović, Vladimir D.
AU  - Nikolić, J. D.
AU  - Matijašević, Srđan D.
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1653
AB  - The nucleation of germanate K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions was studied by the DTA method. The temperature ranges of nucleation and crystal growth of this glass partly overlap. The influence of the mass of the glass sample as well as, the time and temperature of the pre-DTA heat treatment on the DTA parameters T-p, (delta T)(p), and Delta T-p was investigated. A complex behavior of these parameters was evidenced. It was shown that for fixed temperatures, increasing the annealing time of the pre-DTA heat treatment resulted in a decrease in the temperature of the DTA peak (T-p). The curve of the dependence of DTA peak heights (delta T)(p) on time showed a maximum and the parameter Delta T-p continually increased with increasing time. The influence of the temperature of the pre-DTA heat treatment on the DTA parameters showed that for annealing times t gt t(ind), the dependences of T-p(-1) and Delta T-p vs. T corresponded to the dependence of Ion Tin the case when the regions of I and U partly overlapped. As shown, in this case. the change of (delta T)(p) vs. T is not convenient for an analysis of the nucleation behavior of the glass.
PB  - Elsevier, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions
EP  - 1391
IS  - 28-30
SP  - 1385
VL  - 356
DO  - 10.1016/j.jnoncrysol.2010.05.047
ER  - 
@article{
author = "Tošić, Mihajlo B. and Grujić, Snežana and Živanović, Vladimir D. and Nikolić, J. D. and Matijašević, Srđan D.",
year = "2010",
abstract = "The nucleation of germanate K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions was studied by the DTA method. The temperature ranges of nucleation and crystal growth of this glass partly overlap. The influence of the mass of the glass sample as well as, the time and temperature of the pre-DTA heat treatment on the DTA parameters T-p, (delta T)(p), and Delta T-p was investigated. A complex behavior of these parameters was evidenced. It was shown that for fixed temperatures, increasing the annealing time of the pre-DTA heat treatment resulted in a decrease in the temperature of the DTA peak (T-p). The curve of the dependence of DTA peak heights (delta T)(p) on time showed a maximum and the parameter Delta T-p continually increased with increasing time. The influence of the temperature of the pre-DTA heat treatment on the DTA parameters showed that for annealing times t gt t(ind), the dependences of T-p(-1) and Delta T-p vs. T corresponded to the dependence of Ion Tin the case when the regions of I and U partly overlapped. As shown, in this case. the change of (delta T)(p) vs. T is not convenient for an analysis of the nucleation behavior of the glass.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions",
pages = "1391-1385",
number = "28-30",
volume = "356",
doi = "10.1016/j.jnoncrysol.2010.05.047"
}
Tošić, M. B., Grujić, S., Živanović, V. D., Nikolić, J. D.,& Matijašević, S. D.. (2010). The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions. in Journal of Non-Crystalline Solids
Elsevier, Amsterdam., 356(28-30), 1385-1391.
https://doi.org/10.1016/j.jnoncrysol.2010.05.047
Tošić MB, Grujić S, Živanović VD, Nikolić JD, Matijašević SD. The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions. in Journal of Non-Crystalline Solids. 2010;356(28-30):1385-1391.
doi:10.1016/j.jnoncrysol.2010.05.047 .
Tošić, Mihajlo B., Grujić, Snežana, Živanović, Vladimir D., Nikolić, J. D., Matijašević, Srđan D., "The nucleation of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal conditions" in Journal of Non-Crystalline Solids, 356, no. 28-30 (2010):1385-1391,
https://doi.org/10.1016/j.jnoncrysol.2010.05.047 . .
2
1
2

The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt

Grujić, Snežana; Blagojević, Nikola S.; Tošić, Mihajlo B.; Živanović, Vladimir D.; Nikolić, Jelena D.

(University of Chemistry and Technology, Prague, 2009)

TY  - JOUR
AU  - Grujić, Snežana
AU  - Blagojević, Nikola S.
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Nikolić, Jelena D.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1358
AB  - The nucleation of K2TiGe3O9 crystals in an undercooled melt of stoichiometric composition was studied. Volume nucleation with spherical morphology of the growing crystals was determined. The nucleation range is in the temperature interval 540-630 degrees C. A maximum of the steady state nucleation rate of I-max = 1.4 x 10(15) m(-3).s(-1) was determined at the temperature T-n(max) = 582 degrees C. The temperature and time dependence of the nucleation rate was analyzed and it was shown that such a nucleation behavior was the result of a low thermodynamic and kinetic barrier. The results showed that the temperature intervals of nucleation and crystal growth of this undercooled melt partly overlapped.
PB  - University of Chemistry and Technology, Prague
T2  - Ceramics - Silikaty
T1  - The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt
EP  - 136
IS  - 2
SP  - 128
VL  - 53
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1358
ER  - 
@article{
author = "Grujić, Snežana and Blagojević, Nikola S. and Tošić, Mihajlo B. and Živanović, Vladimir D. and Nikolić, Jelena D.",
year = "2009",
abstract = "The nucleation of K2TiGe3O9 crystals in an undercooled melt of stoichiometric composition was studied. Volume nucleation with spherical morphology of the growing crystals was determined. The nucleation range is in the temperature interval 540-630 degrees C. A maximum of the steady state nucleation rate of I-max = 1.4 x 10(15) m(-3).s(-1) was determined at the temperature T-n(max) = 582 degrees C. The temperature and time dependence of the nucleation rate was analyzed and it was shown that such a nucleation behavior was the result of a low thermodynamic and kinetic barrier. The results showed that the temperature intervals of nucleation and crystal growth of this undercooled melt partly overlapped.",
publisher = "University of Chemistry and Technology, Prague",
journal = "Ceramics - Silikaty",
title = "The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt",
pages = "136-128",
number = "2",
volume = "53",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1358"
}
Grujić, S., Blagojević, N. S., Tošić, M. B., Živanović, V. D.,& Nikolić, J. D.. (2009). The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt. in Ceramics - Silikaty
University of Chemistry and Technology, Prague., 53(2), 128-136.
https://hdl.handle.net/21.15107/rcub_technorep_1358
Grujić S, Blagojević NS, Tošić MB, Živanović VD, Nikolić JD. The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt. in Ceramics - Silikaty. 2009;53(2):128-136.
https://hdl.handle.net/21.15107/rcub_technorep_1358 .
Grujić, Snežana, Blagojević, Nikola S., Tošić, Mihajlo B., Živanović, Vladimir D., Nikolić, Jelena D., "The nucleation behavior of k2o center dot tio2 center dot 3geo(2) undercooled melt" in Ceramics - Silikaty, 53, no. 2 (2009):128-136,
https://hdl.handle.net/21.15107/rcub_technorep_1358 .
4
5

Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass

Živanović, Vladimir D.; Grujić, Snežana; Tošić, Mihajlo B.; Blagojević, Nikola S.; Nikolić, J. D.

(Springer, Dordrecht, 2009)

TY  - JOUR
AU  - Živanović, Vladimir D.
AU  - Grujić, Snežana
AU  - Tošić, Mihajlo B.
AU  - Blagojević, Nikola S.
AU  - Nikolić, J. D.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1515
AB  - The crystallization of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal condition was studied. In powdered glass with particle sizes less than 0.15 mm, surface crystallization was dominant and an activation energy of crystal growth of E-a,E-s = 327 +/- 50 kJ mol(-1) was calculated. In the size range 0.15 to 0.45 mm, both surface and volume crystallization occurred. For particle sizes  gt 0.45 mm, volume crystallization dominated with spherulitic morphology of the crystals growth and E-a,E-v = 359 +/- 64 kJ mol(-1) was calculated.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass
EP  - 432
IS  - 2
SP  - 427
VL  - 96
DO  - 10.1007/s10973-008-9335-1
ER  - 
@article{
author = "Živanović, Vladimir D. and Grujić, Snežana and Tošić, Mihajlo B. and Blagojević, Nikola S. and Nikolić, J. D.",
year = "2009",
abstract = "The crystallization of K2O center dot TiO2 center dot 3GeO(2) glass under non-isothermal condition was studied. In powdered glass with particle sizes less than 0.15 mm, surface crystallization was dominant and an activation energy of crystal growth of E-a,E-s = 327 +/- 50 kJ mol(-1) was calculated. In the size range 0.15 to 0.45 mm, both surface and volume crystallization occurred. For particle sizes  gt 0.45 mm, volume crystallization dominated with spherulitic morphology of the crystals growth and E-a,E-v = 359 +/- 64 kJ mol(-1) was calculated.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass",
pages = "432-427",
number = "2",
volume = "96",
doi = "10.1007/s10973-008-9335-1"
}
Živanović, V. D., Grujić, S., Tošić, M. B., Blagojević, N. S.,& Nikolić, J. D.. (2009). Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 96(2), 427-432.
https://doi.org/10.1007/s10973-008-9335-1
Živanović VD, Grujić S, Tošić MB, Blagojević NS, Nikolić JD. Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass. in Journal of Thermal Analysis and Calorimetry. 2009;96(2):427-432.
doi:10.1007/s10973-008-9335-1 .
Živanović, Vladimir D., Grujić, Snežana, Tošić, Mihajlo B., Blagojević, Nikola S., Nikolić, J. D., "Non-isothermal crystallization of k2o center dot tio2 center dot 3geo(2) glass" in Journal of Thermal Analysis and Calorimetry, 96, no. 2 (2009):427-432,
https://doi.org/10.1007/s10973-008-9335-1 . .
2
2
2

A study of the primary crystallization of a mixed anion silicate glass

Tošić, Mihajlo B.; Živanović, Vladimir D.; Grujić, Snežana; Stojanović, Jovica; Nikolić, J. D.

(Elsevier Science Bv, Amsterdam, 2008)

TY  - JOUR
AU  - Tošić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Grujić, Snežana
AU  - Stojanović, Jovica
AU  - Nikolić, J. D.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1242
AB  - This paper presents the results of a study of the primary crystallization of a multicomponent mixed anion silicate glass. The primary phase, leucite, and the secondary phase, diopside, were formed by surface crystallization, while the secondary phase, phlogopite, was formed by volume crystallization. The influence of the particle size of glass powder samples in the range 0-1 mm on the temperature of the DTA crystallization peak, T-p, the height of the peak, (delta T)(p), and the parameter T-p(2)/(Delta T)(p) was studied. The behaviors of the parameters (delta T)(p) and T-p(2)/(Delta T)(p). depend only on the change in the surface-to-volume nuclei ratio, as is the P case with polymorphic crystallization. However, the particle size ranges in which the surface, volume and mixed crystallization mechanism dominate are considerably narrower for this glass. The influence of the duration of a pre-DTA heat treatment on the parameters T-p, (delta T)(p), and Delta T-p for fixed temperatures in the range T = 550-750 degrees C was investigated. The T-p of the samples thermally treated for different times, at fixed temperatures, decreased up to t = 5 h and then increased to a value close to that of an as-quenched sample, after which the value remained constant. The curves of (delta T)(p), and Delta T-p as a function of time for fixed temperatures show a maximum. The influence of the temperature of the pre-DTA heat treatment on the parameters T-p (delta T)(p), and Delta T-p, for fixed times of t = 1-5 h was also investigated. On increasing the pre-DTA heat treatment time, the curves changed significantly. The curves for 3 and 5 h in the temperature range 580-660 degrees C were similar to the nucleation curve, which indicated that the volume nucleation process proceeded in this temperature range. The behavior of these parameters, as a result of the simultaneous action of different nucleation mechanisms and crystal growth differ from those previously reported for the case of polymorphic crystallization.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - A study of the primary crystallization of a mixed anion silicate glass
EP  - 3704
IS  - 31
SP  - 3694
VL  - 354
DO  - 10.1016/j.jnoncrysol.2008.04.011
ER  - 
@article{
author = "Tošić, Mihajlo B. and Živanović, Vladimir D. and Grujić, Snežana and Stojanović, Jovica and Nikolić, J. D.",
year = "2008",
abstract = "This paper presents the results of a study of the primary crystallization of a multicomponent mixed anion silicate glass. The primary phase, leucite, and the secondary phase, diopside, were formed by surface crystallization, while the secondary phase, phlogopite, was formed by volume crystallization. The influence of the particle size of glass powder samples in the range 0-1 mm on the temperature of the DTA crystallization peak, T-p, the height of the peak, (delta T)(p), and the parameter T-p(2)/(Delta T)(p) was studied. The behaviors of the parameters (delta T)(p) and T-p(2)/(Delta T)(p). depend only on the change in the surface-to-volume nuclei ratio, as is the P case with polymorphic crystallization. However, the particle size ranges in which the surface, volume and mixed crystallization mechanism dominate are considerably narrower for this glass. The influence of the duration of a pre-DTA heat treatment on the parameters T-p, (delta T)(p), and Delta T-p for fixed temperatures in the range T = 550-750 degrees C was investigated. The T-p of the samples thermally treated for different times, at fixed temperatures, decreased up to t = 5 h and then increased to a value close to that of an as-quenched sample, after which the value remained constant. The curves of (delta T)(p), and Delta T-p as a function of time for fixed temperatures show a maximum. The influence of the temperature of the pre-DTA heat treatment on the parameters T-p (delta T)(p), and Delta T-p, for fixed times of t = 1-5 h was also investigated. On increasing the pre-DTA heat treatment time, the curves changed significantly. The curves for 3 and 5 h in the temperature range 580-660 degrees C were similar to the nucleation curve, which indicated that the volume nucleation process proceeded in this temperature range. The behavior of these parameters, as a result of the simultaneous action of different nucleation mechanisms and crystal growth differ from those previously reported for the case of polymorphic crystallization.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "A study of the primary crystallization of a mixed anion silicate glass",
pages = "3704-3694",
number = "31",
volume = "354",
doi = "10.1016/j.jnoncrysol.2008.04.011"
}
Tošić, M. B., Živanović, V. D., Grujić, S., Stojanović, J.,& Nikolić, J. D.. (2008). A study of the primary crystallization of a mixed anion silicate glass. in Journal of Non-Crystalline Solids
Elsevier Science Bv, Amsterdam., 354(31), 3694-3704.
https://doi.org/10.1016/j.jnoncrysol.2008.04.011
Tošić MB, Živanović VD, Grujić S, Stojanović J, Nikolić JD. A study of the primary crystallization of a mixed anion silicate glass. in Journal of Non-Crystalline Solids. 2008;354(31):3694-3704.
doi:10.1016/j.jnoncrysol.2008.04.011 .
Tošić, Mihajlo B., Živanović, Vladimir D., Grujić, Snežana, Stojanović, Jovica, Nikolić, J. D., "A study of the primary crystallization of a mixed anion silicate glass" in Journal of Non-Crystalline Solids, 354, no. 31 (2008):3694-3704,
https://doi.org/10.1016/j.jnoncrysol.2008.04.011 . .
5
5
6

The crystallisation of calcium phosphate glass containing vanadium oxide

Živanović, Vladimir D.; Tošić, Mihajlo B.; Blagojević, Nikola S.; Grujić, Snežana; Mitrović, Mico M.

(University of Chemistry and Technology, Prague, 2007)

TY  - JOUR
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Blagojević, Nikola S.
AU  - Grujić, Snežana
AU  - Mitrović, Mico M.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1033
AB  - The crystallisation behaviour of calcium phosphate glass containing vanadium oxide was studied. Glass with a molar ratio of [CaO]/[P2O5] = 1.13 and a V2O5 content of 8 mol.% was prepared for the experiments. The crystallisation of bulk glass samples was performed tinder isothermal conditions at T = 650-820 degrees C. The surface crystallisation mechanism of studied glass with dendritic growth of the primary alpha-Ca2P2O7 phase was observed. In all crystallised samples, beta-Ca2P2O7 and VP2O7 appeared as the secondary phases. In the investigated temperature range, crystal growth rates 9 x 10(-9) - 2.14 x 10(-6) m/s were determined. The temperature dependence of the crystal growth rate makes possible to calculate activation energy E-a = 407 +/- 30 kJ/mol of crystallization. The experimental data were compared with those estimated by using a theoretical model of the crystal growth rate and good agreement between the results was found.
PB  - University of Chemistry and Technology, Prague
T2  - Ceramics - Silikaty
T1  - The crystallisation of calcium phosphate glass containing vanadium oxide
EP  - 118
IS  - 2
SP  - 112
VL  - 51
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1033
ER  - 
@article{
author = "Živanović, Vladimir D. and Tošić, Mihajlo B. and Blagojević, Nikola S. and Grujić, Snežana and Mitrović, Mico M.",
year = "2007",
abstract = "The crystallisation behaviour of calcium phosphate glass containing vanadium oxide was studied. Glass with a molar ratio of [CaO]/[P2O5] = 1.13 and a V2O5 content of 8 mol.% was prepared for the experiments. The crystallisation of bulk glass samples was performed tinder isothermal conditions at T = 650-820 degrees C. The surface crystallisation mechanism of studied glass with dendritic growth of the primary alpha-Ca2P2O7 phase was observed. In all crystallised samples, beta-Ca2P2O7 and VP2O7 appeared as the secondary phases. In the investigated temperature range, crystal growth rates 9 x 10(-9) - 2.14 x 10(-6) m/s were determined. The temperature dependence of the crystal growth rate makes possible to calculate activation energy E-a = 407 +/- 30 kJ/mol of crystallization. The experimental data were compared with those estimated by using a theoretical model of the crystal growth rate and good agreement between the results was found.",
publisher = "University of Chemistry and Technology, Prague",
journal = "Ceramics - Silikaty",
title = "The crystallisation of calcium phosphate glass containing vanadium oxide",
pages = "118-112",
number = "2",
volume = "51",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1033"
}
Živanović, V. D., Tošić, M. B., Blagojević, N. S., Grujić, S.,& Mitrović, M. M.. (2007). The crystallisation of calcium phosphate glass containing vanadium oxide. in Ceramics - Silikaty
University of Chemistry and Technology, Prague., 51(2), 112-118.
https://hdl.handle.net/21.15107/rcub_technorep_1033
Živanović VD, Tošić MB, Blagojević NS, Grujić S, Mitrović MM. The crystallisation of calcium phosphate glass containing vanadium oxide. in Ceramics - Silikaty. 2007;51(2):112-118.
https://hdl.handle.net/21.15107/rcub_technorep_1033 .
Živanović, Vladimir D., Tošić, Mihajlo B., Blagojević, Nikola S., Grujić, Snežana, Mitrović, Mico M., "The crystallisation of calcium phosphate glass containing vanadium oxide" in Ceramics - Silikaty, 51, no. 2 (2007):112-118,
https://hdl.handle.net/21.15107/rcub_technorep_1033 .
2
3

Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass

Grujić, Snežana; Blagojević, Nikola; Tošić, Mihajlo; Živanović, Vladimir

(Institute of Chemical Technology, 2005)

TY  - JOUR
AU  - Grujić, Snežana
AU  - Blagojević, Nikola
AU  - Tošić, Mihajlo
AU  - Živanović, Vladimir
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5480
AB  - Structure and crystallization of K 2 O·TiO 2 ·3GeO 2 glass have been investigated by means of Fourier transform infrared spectroscopy (FTIR), differential thermal analysis (DTA), differential scanning calorimetry (DSC), x-ray diffraction analysis (XRD), and scanning electron microscopy (SEM). XRD analysis of crystallized glass reveals the presence of crystalline K 2 O TiO 2 3GeO 2 indicating the same composition of crystalline and parent glass. For glass particle size > 0.15 mm volume crystallization is dominant crystallization mechanism. SEM investigation of the crystallized glass confirmed volume crystallization of spherical nuclei.
AB  - Struktura a vlastnosti K2O·TiO2·3GeO2 skel byly zkoumány infraèervenou spektrometrií s Fourierovou transformací (FTIR), diferenèní termickou analýzou (DTA), diferenèní skenovací kalorimetrií (DSC), RTG difrakèní analýzou (XRD) a skenovací elektronovou mikroskopií (SEM). RTG analýza zkrystalovaných skel odhalila pøítomnost krystalického K2O·TiO2·3GeO2 ukazující totožné složení krystalické a skelné fáze. Dominujícím mechanismem krystalizace èástic skla
vìtších než 0,15 mm je objemová krystalizace sférických nukleí, která byla rovnìž potvrzena SEM analýzou.
PB  - Institute of Chemical Technology
T2  - Ceramics - Silikaty
T1  - Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass
T1  - Strukturní a krystalizaèní charakteristiky k2o·tio2·3geo2 skel
EP  - 282
IS  - 4
SP  - 278
VL  - 49
UR  - https://hdl.handle.net/21.15107/rcub_technorep_5480
ER  - 
@article{
author = "Grujić, Snežana and Blagojević, Nikola and Tošić, Mihajlo and Živanović, Vladimir",
year = "2005",
abstract = "Structure and crystallization of K 2 O·TiO 2 ·3GeO 2 glass have been investigated by means of Fourier transform infrared spectroscopy (FTIR), differential thermal analysis (DTA), differential scanning calorimetry (DSC), x-ray diffraction analysis (XRD), and scanning electron microscopy (SEM). XRD analysis of crystallized glass reveals the presence of crystalline K 2 O TiO 2 3GeO 2 indicating the same composition of crystalline and parent glass. For glass particle size > 0.15 mm volume crystallization is dominant crystallization mechanism. SEM investigation of the crystallized glass confirmed volume crystallization of spherical nuclei., Struktura a vlastnosti K2O·TiO2·3GeO2 skel byly zkoumány infraèervenou spektrometrií s Fourierovou transformací (FTIR), diferenèní termickou analýzou (DTA), diferenèní skenovací kalorimetrií (DSC), RTG difrakèní analýzou (XRD) a skenovací elektronovou mikroskopií (SEM). RTG analýza zkrystalovaných skel odhalila pøítomnost krystalického K2O·TiO2·3GeO2 ukazující totožné složení krystalické a skelné fáze. Dominujícím mechanismem krystalizace èástic skla
vìtších než 0,15 mm je objemová krystalizace sférických nukleí, která byla rovnìž potvrzena SEM analýzou.",
publisher = "Institute of Chemical Technology",
journal = "Ceramics - Silikaty",
title = "Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass, Strukturní a krystalizaèní charakteristiky k2o·tio2·3geo2 skel",
pages = "282-278",
number = "4",
volume = "49",
url = "https://hdl.handle.net/21.15107/rcub_technorep_5480"
}
Grujić, S., Blagojević, N., Tošić, M.,& Živanović, V.. (2005). Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass. in Ceramics - Silikaty
Institute of Chemical Technology., 49(4), 278-282.
https://hdl.handle.net/21.15107/rcub_technorep_5480
Grujić S, Blagojević N, Tošić M, Živanović V. Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass. in Ceramics - Silikaty. 2005;49(4):278-282.
https://hdl.handle.net/21.15107/rcub_technorep_5480 .
Grujić, Snežana, Blagojević, Nikola, Tošić, Mihajlo, Živanović, Vladimir, "Structural and crystallization characteristics of K 2 O· TiO 2 ·3GeO 2 glass" in Ceramics - Silikaty, 49, no. 4 (2005):278-282,
https://hdl.handle.net/21.15107/rcub_technorep_5480 .