Crini, Grégorio

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  • Crini, Grégorio (5)
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Author's Bibliography

Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment

Karić, Nataša; Maia, Alexandra S.; Teodorović, Ana; Atanasova, Nataša; Langergraber, Guenter; Crini, Grégorio; Ribeiro, Ana R.L.; Đolić, Maja

(Elsevier B.V., 2022)

TY  - JOUR
AU  - Karić, Nataša
AU  - Maia, Alexandra S.
AU  - Teodorović, Ana
AU  - Atanasova, Nataša
AU  - Langergraber, Guenter
AU  - Crini, Grégorio
AU  - Ribeiro, Ana R.L.
AU  - Đolić, Maja
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5094
AB  - The conventional waste management practices dispose or incinerate agricultural and forestry waste, contributing to the environmental pollution while misusing biomass, a valuable resource with a great potential of reuse. In fact, cultivation of agricultural crops and harvesting generate an abundant amount of waste (e.g., stones, shells, straw) that can be used for wastewater treatment. Waste biomass may be used as: (i) an adsorbent in its original, raw form, following ambient drying and grinding; (ii) modified bio-based sorbents; or (iii) a source material for the synthesis of activated carbon adsorbents through carbonization. Despite the numerous publications in this field examining the removal of a wide range of target pollutants (metals, metalloids, dyes, pesticides, as well as emerging contaminants) by several materials, more realistic studies are still required to evaluate the potential to remove residual compounds in complex matrices, by testing natural matrices, i.e., environmental samples without spiking the target compounds. This perspective paper highlights how an integrated-engineering approach may help solving environmental-pollution issues related to water, solid waste, and air pollution. Chiefly, the application of locally produced bio-waste as an adsorbent for wastewater treatment tackles water contamination, decreases the overall amount of agricultural waste, and reduces the potential gas emissions caused by waste transportation, treatment and/or disposal.
PB  - Elsevier B.V.
T2  - Chemical Engineering Journal Advances
T1  - Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment
SP  - 100239
VL  - 9
DO  - 10.1016/j.ceja.2021.100239
ER  - 
@article{
author = "Karić, Nataša and Maia, Alexandra S. and Teodorović, Ana and Atanasova, Nataša and Langergraber, Guenter and Crini, Grégorio and Ribeiro, Ana R.L. and Đolić, Maja",
year = "2022",
abstract = "The conventional waste management practices dispose or incinerate agricultural and forestry waste, contributing to the environmental pollution while misusing biomass, a valuable resource with a great potential of reuse. In fact, cultivation of agricultural crops and harvesting generate an abundant amount of waste (e.g., stones, shells, straw) that can be used for wastewater treatment. Waste biomass may be used as: (i) an adsorbent in its original, raw form, following ambient drying and grinding; (ii) modified bio-based sorbents; or (iii) a source material for the synthesis of activated carbon adsorbents through carbonization. Despite the numerous publications in this field examining the removal of a wide range of target pollutants (metals, metalloids, dyes, pesticides, as well as emerging contaminants) by several materials, more realistic studies are still required to evaluate the potential to remove residual compounds in complex matrices, by testing natural matrices, i.e., environmental samples without spiking the target compounds. This perspective paper highlights how an integrated-engineering approach may help solving environmental-pollution issues related to water, solid waste, and air pollution. Chiefly, the application of locally produced bio-waste as an adsorbent for wastewater treatment tackles water contamination, decreases the overall amount of agricultural waste, and reduces the potential gas emissions caused by waste transportation, treatment and/or disposal.",
publisher = "Elsevier B.V.",
journal = "Chemical Engineering Journal Advances",
title = "Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment",
pages = "100239",
volume = "9",
doi = "10.1016/j.ceja.2021.100239"
}
Karić, N., Maia, A. S., Teodorović, A., Atanasova, N., Langergraber, G., Crini, G., Ribeiro, A. R.L.,& Đolić, M.. (2022). Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment. in Chemical Engineering Journal Advances
Elsevier B.V.., 9, 100239.
https://doi.org/10.1016/j.ceja.2021.100239
Karić N, Maia AS, Teodorović A, Atanasova N, Langergraber G, Crini G, Ribeiro AR, Đolić M. Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment. in Chemical Engineering Journal Advances. 2022;9:100239.
doi:10.1016/j.ceja.2021.100239 .
Karić, Nataša, Maia, Alexandra S., Teodorović, Ana, Atanasova, Nataša, Langergraber, Guenter, Crini, Grégorio, Ribeiro, Ana R.L., Đolić, Maja, "Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment" in Chemical Engineering Journal Advances, 9 (2022):100239,
https://doi.org/10.1016/j.ceja.2021.100239 . .
5
139
126

Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review

Mongioví, Chiara; Morin-Crini, Nadia; Placet, Vincent; Bradu, Corina; Ribeiro, Ana Rita Lado; Ivanovska, Aleksandra; Kostić, Mirjana; Martel, Bernard; Cosentino, Cesare; Torri, Giangiacomo; Rizzi, Vito; Gubitosa, Jennifer; Fini, Paola; Cosma, Pinalysa; Lichtfouse, Eric; Lacalamita, Dario; Mesto, Ernesto; Schingaro, Emanuela; De Vietro, Nicoletta; Crini, Grégorio

(Singapore : Springer Nature, 2022)

TY  - CHAP
AU  - Mongioví, Chiara
AU  - Morin-Crini, Nadia
AU  - Placet, Vincent
AU  - Bradu, Corina
AU  - Ribeiro, Ana Rita Lado
AU  - Ivanovska, Aleksandra
AU  - Kostić, Mirjana
AU  - Martel, Bernard
AU  - Cosentino, Cesare
AU  - Torri, Giangiacomo
AU  - Rizzi, Vito
AU  - Gubitosa, Jennifer
AU  - Fini, Paola
AU  - Cosma, Pinalysa
AU  - Lichtfouse, Eric
AU  - Lacalamita, Dario
AU  - Mesto, Ernesto
AU  - Schingaro, Emanuela
AU  - De Vietro, Nicoletta
AU  - Crini, Grégorio
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6328
AB  - Treatment of wastewater pollution is a critical issue in the context of growing population and industrialization. Actual treatment methods are expensive and not fully effective and rely on fossil fuel-derived chemicals, thus calling for alternative adsorption methods on natural materials such as hemp. Industrial hemp (Cannabis sativa Linn) is a high-yielding annual industrial crop harvested for its fiber from the stem and its oil from the seeds. Hemp is a multi-purpose plant with great potential because of its many uses, such as building materials, textiles, paper, food and beverage, automotive, cosmetics, and medicine. Wastewater treatment is another innovative application. Indeed, the past decade has shown an explosion in the study of hemp-based materials for the biosorption of metal ions from effluents, demonstrating that industrial hemp is one of the most promising materials for environmental applications. Hemp products can be used as biosorbents in granular or felt forms or to prepare non-conventional activated carbons, both used in biosorption-oriented processes. In this chapter, after a brief description of biosorption, the use of different types of hemp-based materials that can be used as pollutant biosorbents is described.
PB  - Singapore : Springer Nature
T2  - Cannabis/Hemp for Sustainable Agriculture and Materials
T1  - Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review
EP  - 295
SP  - 239
DO  - 10.1007/978-981-16-8778-5_9
ER  - 
@inbook{
author = "Mongioví, Chiara and Morin-Crini, Nadia and Placet, Vincent and Bradu, Corina and Ribeiro, Ana Rita Lado and Ivanovska, Aleksandra and Kostić, Mirjana and Martel, Bernard and Cosentino, Cesare and Torri, Giangiacomo and Rizzi, Vito and Gubitosa, Jennifer and Fini, Paola and Cosma, Pinalysa and Lichtfouse, Eric and Lacalamita, Dario and Mesto, Ernesto and Schingaro, Emanuela and De Vietro, Nicoletta and Crini, Grégorio",
year = "2022",
abstract = "Treatment of wastewater pollution is a critical issue in the context of growing population and industrialization. Actual treatment methods are expensive and not fully effective and rely on fossil fuel-derived chemicals, thus calling for alternative adsorption methods on natural materials such as hemp. Industrial hemp (Cannabis sativa Linn) is a high-yielding annual industrial crop harvested for its fiber from the stem and its oil from the seeds. Hemp is a multi-purpose plant with great potential because of its many uses, such as building materials, textiles, paper, food and beverage, automotive, cosmetics, and medicine. Wastewater treatment is another innovative application. Indeed, the past decade has shown an explosion in the study of hemp-based materials for the biosorption of metal ions from effluents, demonstrating that industrial hemp is one of the most promising materials for environmental applications. Hemp products can be used as biosorbents in granular or felt forms or to prepare non-conventional activated carbons, both used in biosorption-oriented processes. In this chapter, after a brief description of biosorption, the use of different types of hemp-based materials that can be used as pollutant biosorbents is described.",
publisher = "Singapore : Springer Nature",
journal = "Cannabis/Hemp for Sustainable Agriculture and Materials",
booktitle = "Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review",
pages = "295-239",
doi = "10.1007/978-981-16-8778-5_9"
}
Mongioví, C., Morin-Crini, N., Placet, V., Bradu, C., Ribeiro, A. R. L., Ivanovska, A., Kostić, M., Martel, B., Cosentino, C., Torri, G., Rizzi, V., Gubitosa, J., Fini, P., Cosma, P., Lichtfouse, E., Lacalamita, D., Mesto, E., Schingaro, E., De Vietro, N.,& Crini, G.. (2022). Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review. in Cannabis/Hemp for Sustainable Agriculture and Materials
Singapore : Springer Nature., 239-295.
https://doi.org/10.1007/978-981-16-8778-5_9
Mongioví C, Morin-Crini N, Placet V, Bradu C, Ribeiro ARL, Ivanovska A, Kostić M, Martel B, Cosentino C, Torri G, Rizzi V, Gubitosa J, Fini P, Cosma P, Lichtfouse E, Lacalamita D, Mesto E, Schingaro E, De Vietro N, Crini G. Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review. in Cannabis/Hemp for Sustainable Agriculture and Materials. 2022;:239-295.
doi:10.1007/978-981-16-8778-5_9 .
Mongioví, Chiara, Morin-Crini, Nadia, Placet, Vincent, Bradu, Corina, Ribeiro, Ana Rita Lado, Ivanovska, Aleksandra, Kostić, Mirjana, Martel, Bernard, Cosentino, Cesare, Torri, Giangiacomo, Rizzi, Vito, Gubitosa, Jennifer, Fini, Paola, Cosma, Pinalysa, Lichtfouse, Eric, Lacalamita, Dario, Mesto, Ernesto, Schingaro, Emanuela, De Vietro, Nicoletta, Crini, Grégorio, "Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review" in Cannabis/Hemp for Sustainable Agriculture and Materials (2022):239-295,
https://doi.org/10.1007/978-981-16-8778-5_9 . .
3
4

Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling

Mongioví, Chiara; Lacalamita, Dario; Morin-Crini, Nadia; Gabrion, Xavier; Placet, Vincent; Ribeiro, Ana Rita Lado; Ivanovska, Aleksandra; Kostić, Mirjana; Bradu, Corina; Staelens, Jean-Noël; Martel, Bernard; Raschetti, Marina; Crini, Grégorio

(Elsevier B.V., 2022)

TY  - JOUR
AU  - Mongioví, Chiara
AU  - Lacalamita, Dario
AU  - Morin-Crini, Nadia
AU  - Gabrion, Xavier
AU  - Placet, Vincent
AU  - Ribeiro, Ana Rita Lado
AU  - Ivanovska, Aleksandra
AU  - Kostić, Mirjana
AU  - Bradu, Corina
AU  - Staelens, Jean-Noël
AU  - Martel, Bernard
AU  - Raschetti, Marina
AU  - Crini, Grégorio
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5391
AB  - In this study, a series of hemp shives (chènevotte) with different chemical compositions and properties, namely a raw (SHI-R), a washed with water (SHI-W), three samples chemically modified with KOH (SHI-OH), Na2CO3 (SHI-C) or H3PO4 (SHI-H), and a hemp shives sample prepared by grafting of carboxylic groups (SHI-BTCA), were used as adsorbents for the removal of copper present in aqueous solutions. This article presents the abatements and kinetics obtained using batch experiments and their modeling. The results first showed that the quantity of copper removed depended on the used shives and the copper initial concentration. At the same experimental conditions, SHI-C and SHI-BTCA samples possessed similar performances which are significantly higher than those of other studied hemp shives. Copper adsorption reached equilibrium after 60 min of contact time and was independent of concentration in the range 5–150 mg/L for SHI-C and SHI-BTCA. According to the better Chi-squared values, the experimental data were better simulated by the non-linear kinetic model in the order: Lagergren < Elovich < Ho and McKay < Weber and Morris < Boyd for SHI-C and Boyd < Ho and McKay < Weber and Morris < Lagergren < Elovich for SHI-BTCA. The analysis of data indicated that chemisorption is the main mechanism for binding copper onto SHI-BTCA, while physisorption (diffusion) is the main interaction for copper adsorption onto SHI-C. The adsorption-oriented process using hemp shives could be an advantageous approach for recovering copper from metal industry effluents due to the simplicity of the process, its efficiency to treat both diluted and concentrated copper solutions, and the low-cost, non-toxic to humans and the environment, ecological character, and facile use of hemp shives.
PB  - Elsevier B.V.
T2  - Arabian Journal of Chemistry
T1  - Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling
IS  - 4
SP  - 103742
VL  - 15
DO  - 10.1016/j.arabjc.2022.103742
ER  - 
@article{
author = "Mongioví, Chiara and Lacalamita, Dario and Morin-Crini, Nadia and Gabrion, Xavier and Placet, Vincent and Ribeiro, Ana Rita Lado and Ivanovska, Aleksandra and Kostić, Mirjana and Bradu, Corina and Staelens, Jean-Noël and Martel, Bernard and Raschetti, Marina and Crini, Grégorio",
year = "2022",
abstract = "In this study, a series of hemp shives (chènevotte) with different chemical compositions and properties, namely a raw (SHI-R), a washed with water (SHI-W), three samples chemically modified with KOH (SHI-OH), Na2CO3 (SHI-C) or H3PO4 (SHI-H), and a hemp shives sample prepared by grafting of carboxylic groups (SHI-BTCA), were used as adsorbents for the removal of copper present in aqueous solutions. This article presents the abatements and kinetics obtained using batch experiments and their modeling. The results first showed that the quantity of copper removed depended on the used shives and the copper initial concentration. At the same experimental conditions, SHI-C and SHI-BTCA samples possessed similar performances which are significantly higher than those of other studied hemp shives. Copper adsorption reached equilibrium after 60 min of contact time and was independent of concentration in the range 5–150 mg/L for SHI-C and SHI-BTCA. According to the better Chi-squared values, the experimental data were better simulated by the non-linear kinetic model in the order: Lagergren < Elovich < Ho and McKay < Weber and Morris < Boyd for SHI-C and Boyd < Ho and McKay < Weber and Morris < Lagergren < Elovich for SHI-BTCA. The analysis of data indicated that chemisorption is the main mechanism for binding copper onto SHI-BTCA, while physisorption (diffusion) is the main interaction for copper adsorption onto SHI-C. The adsorption-oriented process using hemp shives could be an advantageous approach for recovering copper from metal industry effluents due to the simplicity of the process, its efficiency to treat both diluted and concentrated copper solutions, and the low-cost, non-toxic to humans and the environment, ecological character, and facile use of hemp shives.",
publisher = "Elsevier B.V.",
journal = "Arabian Journal of Chemistry",
title = "Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling",
number = "4",
pages = "103742",
volume = "15",
doi = "10.1016/j.arabjc.2022.103742"
}
Mongioví, C., Lacalamita, D., Morin-Crini, N., Gabrion, X., Placet, V., Ribeiro, A. R. L., Ivanovska, A., Kostić, M., Bradu, C., Staelens, J., Martel, B., Raschetti, M.,& Crini, G.. (2022). Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling. in Arabian Journal of Chemistry
Elsevier B.V.., 15(4), 103742.
https://doi.org/10.1016/j.arabjc.2022.103742
Mongioví C, Lacalamita D, Morin-Crini N, Gabrion X, Placet V, Ribeiro ARL, Ivanovska A, Kostić M, Bradu C, Staelens J, Martel B, Raschetti M, Crini G. Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling. in Arabian Journal of Chemistry. 2022;15(4):103742.
doi:10.1016/j.arabjc.2022.103742 .
Mongioví, Chiara, Lacalamita, Dario, Morin-Crini, Nadia, Gabrion, Xavier, Placet, Vincent, Ribeiro, Ana Rita Lado, Ivanovska, Aleksandra, Kostić, Mirjana, Bradu, Corina, Staelens, Jean-Noël, Martel, Bernard, Raschetti, Marina, Crini, Grégorio, "Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling" in Arabian Journal of Chemistry, 15, no. 4 (2022):103742,
https://doi.org/10.1016/j.arabjc.2022.103742 . .
8
9

Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques

Mongioví, Chiara; Crini, Grégorio; Gabrion, Xavier; Placet, Vincent; Blondeau-Patissier, Virginie; Krystianiak, Anna; Durand, Sylvie; Beaugrand, Johnny; Dorlando, Angelina; Rivard, Camille; Gautier, Landrot; Ribeiro, Ana Rita Lado; Lacalamita, Dario; Martel, Bernard; Staelens, Jean-Noël; Ivanovska, Aleksandra; Kostić, Mirjana; Heintz, Olivier; Bradu, Corina; Raschetti, Marina; Morin-Crini, Nadia

(Elsevier B.V., 2022)

TY  - JOUR
AU  - Mongioví, Chiara
AU  - Crini, Grégorio
AU  - Gabrion, Xavier
AU  - Placet, Vincent
AU  - Blondeau-Patissier, Virginie
AU  - Krystianiak, Anna
AU  - Durand, Sylvie
AU  - Beaugrand, Johnny
AU  - Dorlando, Angelina
AU  - Rivard, Camille
AU  - Gautier, Landrot
AU  - Ribeiro, Ana Rita Lado
AU  - Lacalamita, Dario
AU  - Martel, Bernard
AU  - Staelens, Jean-Noël
AU  - Ivanovska, Aleksandra
AU  - Kostić, Mirjana
AU  - Heintz, Olivier
AU  - Bradu, Corina
AU  - Raschetti, Marina
AU  - Morin-Crini, Nadia
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5970
AB  - Hemp-based materials have been recently proposed as adsorbents for metals present in aqueous solutions using adsorption-oriented processes. This study aims to reveal the adsorption mechanism of materials prepared from hemp shives as co-products of the hemp industry, namely sodium carbonate-activated (SHI-C) and polycarboxylic agent-grafted (SHI-BTCA) hemp shives. The interactions between copper and two hemp-based materials were characterized by different microscopic and spectroscopic techniques such as energy-disperse X-ray (EDX) spectroscopy, computed nano-tomography (nano-CT), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and X-ray absorption near-edge structure (XANES) spectroscopy. The results showed remarkable different mechanisms for copper adsorption onto the SHI-C and SHI-BTCA hemp shives. Namely, copper surface adsorption and diffusion in the structure of the SHI-C material were predominant, whereas the adsorption of copper onto SHI-BTCA was due to a chemisorption phenomenon and ion-exchange involving the adsorbent carboxylate groups. The combination of the abovementioned complementary microscopic and spectroscopic techniques allowed us to characterize and distinguish the type of interactions involved in the liquid-solid adsorption phenomena.
PB  - Elsevier B.V.
T2  - Chemical Engineering Journal Advances
T1  - Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques
SP  - 100282
VL  - 10
DO  - 10.1016/j.ceja.2022.100282
ER  - 
@article{
author = "Mongioví, Chiara and Crini, Grégorio and Gabrion, Xavier and Placet, Vincent and Blondeau-Patissier, Virginie and Krystianiak, Anna and Durand, Sylvie and Beaugrand, Johnny and Dorlando, Angelina and Rivard, Camille and Gautier, Landrot and Ribeiro, Ana Rita Lado and Lacalamita, Dario and Martel, Bernard and Staelens, Jean-Noël and Ivanovska, Aleksandra and Kostić, Mirjana and Heintz, Olivier and Bradu, Corina and Raschetti, Marina and Morin-Crini, Nadia",
year = "2022",
abstract = "Hemp-based materials have been recently proposed as adsorbents for metals present in aqueous solutions using adsorption-oriented processes. This study aims to reveal the adsorption mechanism of materials prepared from hemp shives as co-products of the hemp industry, namely sodium carbonate-activated (SHI-C) and polycarboxylic agent-grafted (SHI-BTCA) hemp shives. The interactions between copper and two hemp-based materials were characterized by different microscopic and spectroscopic techniques such as energy-disperse X-ray (EDX) spectroscopy, computed nano-tomography (nano-CT), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and X-ray absorption near-edge structure (XANES) spectroscopy. The results showed remarkable different mechanisms for copper adsorption onto the SHI-C and SHI-BTCA hemp shives. Namely, copper surface adsorption and diffusion in the structure of the SHI-C material were predominant, whereas the adsorption of copper onto SHI-BTCA was due to a chemisorption phenomenon and ion-exchange involving the adsorbent carboxylate groups. The combination of the abovementioned complementary microscopic and spectroscopic techniques allowed us to characterize and distinguish the type of interactions involved in the liquid-solid adsorption phenomena.",
publisher = "Elsevier B.V.",
journal = "Chemical Engineering Journal Advances",
title = "Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques",
pages = "100282",
volume = "10",
doi = "10.1016/j.ceja.2022.100282"
}
Mongioví, C., Crini, G., Gabrion, X., Placet, V., Blondeau-Patissier, V., Krystianiak, A., Durand, S., Beaugrand, J., Dorlando, A., Rivard, C., Gautier, L., Ribeiro, A. R. L., Lacalamita, D., Martel, B., Staelens, J., Ivanovska, A., Kostić, M., Heintz, O., Bradu, C., Raschetti, M.,& Morin-Crini, N.. (2022). Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques. in Chemical Engineering Journal Advances
Elsevier B.V.., 10, 100282.
https://doi.org/10.1016/j.ceja.2022.100282
Mongioví C, Crini G, Gabrion X, Placet V, Blondeau-Patissier V, Krystianiak A, Durand S, Beaugrand J, Dorlando A, Rivard C, Gautier L, Ribeiro ARL, Lacalamita D, Martel B, Staelens J, Ivanovska A, Kostić M, Heintz O, Bradu C, Raschetti M, Morin-Crini N. Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques. in Chemical Engineering Journal Advances. 2022;10:100282.
doi:10.1016/j.ceja.2022.100282 .
Mongioví, Chiara, Crini, Grégorio, Gabrion, Xavier, Placet, Vincent, Blondeau-Patissier, Virginie, Krystianiak, Anna, Durand, Sylvie, Beaugrand, Johnny, Dorlando, Angelina, Rivard, Camille, Gautier, Landrot, Ribeiro, Ana Rita Lado, Lacalamita, Dario, Martel, Bernard, Staelens, Jean-Noël, Ivanovska, Aleksandra, Kostić, Mirjana, Heintz, Olivier, Bradu, Corina, Raschetti, Marina, Morin-Crini, Nadia, "Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques" in Chemical Engineering Journal Advances, 10 (2022):100282,
https://doi.org/10.1016/j.ceja.2022.100282 . .
7
24
21

Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples

Mongioví, Chiara; Lacalamita, Dario; Morin-Crini, Nadia; Gabrion, Xavier; Ivanovska, Aleksandra; Sala, Federico; Placet, Vincent; Rizzi, Vito; Gubitosa, Jennifer; Mesto, Ernesto; Ribeiro, Ana Rita Lado; Fini, Paola; De Vietro, Nicoletta; Schingaro, Emanuela; Kostić, Mirjana; Cosentino, Cesare; Cosma, Pinalysa; Bradu, Corina; Chanet, Gilles; Crini, Grégorio

(MDPI AG, 2021)

TY  - JOUR
AU  - Mongioví, Chiara
AU  - Lacalamita, Dario
AU  - Morin-Crini, Nadia
AU  - Gabrion, Xavier
AU  - Ivanovska, Aleksandra
AU  - Sala, Federico
AU  - Placet, Vincent
AU  - Rizzi, Vito
AU  - Gubitosa, Jennifer
AU  - Mesto, Ernesto
AU  - Ribeiro, Ana Rita Lado
AU  - Fini, Paola
AU  - De Vietro, Nicoletta
AU  - Schingaro, Emanuela
AU  - Kostić, Mirjana
AU  - Cosentino, Cesare
AU  - Cosma, Pinalysa
AU  - Bradu, Corina
AU  - Chanet, Gilles
AU  - Crini, Grégorio
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5971
AB  - FINEAU (2021–2024) is a trans-disciplinary research project involving French, Serbian, Italian, Portuguese and Romanian colleagues, a French agricultural cooperative and two surface-treatment industries, intending to propose chènevotte, a co-product of the hemp industry, as an adsorbent for the removal of pollutants from polycontaminated wastewater. The first objective of FINEAU was to prepare and characterize chènevotte-based materials. In this study, the impact of water washing and treatments (KOH, Na2CO3 and H3PO4) on the composition and structure of chènevotte (also called hemp shives) was evaluated using chemical analysis, X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, X-ray computed nanotomography (nano-CT), attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy, solid state NMR spectroscopy and thermogravimetric analysis. The results showed that all these techniques are complementary and useful to characterize the structure and morphology of the samples. Before any chemical treatment, the presence of impurities with a compact unfibrillated structure on the surfaces of chènevotte samples was found. Data indicated an increase in the crystallinity index and significant changes in the chemical composition of each sample after treatment as well as in surface morphology and roughness. The most significant changes were observed in alkaline-treated samples, especially those treated with KOH.
PB  - MDPI AG
T2  - Molecules
T1  - Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples
IS  - 15
SP  - 4574
VL  - 26
DO  - 10.3390/molecules26154574
ER  - 
@article{
author = "Mongioví, Chiara and Lacalamita, Dario and Morin-Crini, Nadia and Gabrion, Xavier and Ivanovska, Aleksandra and Sala, Federico and Placet, Vincent and Rizzi, Vito and Gubitosa, Jennifer and Mesto, Ernesto and Ribeiro, Ana Rita Lado and Fini, Paola and De Vietro, Nicoletta and Schingaro, Emanuela and Kostić, Mirjana and Cosentino, Cesare and Cosma, Pinalysa and Bradu, Corina and Chanet, Gilles and Crini, Grégorio",
year = "2021",
abstract = "FINEAU (2021–2024) is a trans-disciplinary research project involving French, Serbian, Italian, Portuguese and Romanian colleagues, a French agricultural cooperative and two surface-treatment industries, intending to propose chènevotte, a co-product of the hemp industry, as an adsorbent for the removal of pollutants from polycontaminated wastewater. The first objective of FINEAU was to prepare and characterize chènevotte-based materials. In this study, the impact of water washing and treatments (KOH, Na2CO3 and H3PO4) on the composition and structure of chènevotte (also called hemp shives) was evaluated using chemical analysis, X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, X-ray computed nanotomography (nano-CT), attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy, solid state NMR spectroscopy and thermogravimetric analysis. The results showed that all these techniques are complementary and useful to characterize the structure and morphology of the samples. Before any chemical treatment, the presence of impurities with a compact unfibrillated structure on the surfaces of chènevotte samples was found. Data indicated an increase in the crystallinity index and significant changes in the chemical composition of each sample after treatment as well as in surface morphology and roughness. The most significant changes were observed in alkaline-treated samples, especially those treated with KOH.",
publisher = "MDPI AG",
journal = "Molecules",
title = "Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples",
number = "15",
pages = "4574",
volume = "26",
doi = "10.3390/molecules26154574"
}
Mongioví, C., Lacalamita, D., Morin-Crini, N., Gabrion, X., Ivanovska, A., Sala, F., Placet, V., Rizzi, V., Gubitosa, J., Mesto, E., Ribeiro, A. R. L., Fini, P., De Vietro, N., Schingaro, E., Kostić, M., Cosentino, C., Cosma, P., Bradu, C., Chanet, G.,& Crini, G.. (2021). Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples. in Molecules
MDPI AG., 26(15), 4574.
https://doi.org/10.3390/molecules26154574
Mongioví C, Lacalamita D, Morin-Crini N, Gabrion X, Ivanovska A, Sala F, Placet V, Rizzi V, Gubitosa J, Mesto E, Ribeiro ARL, Fini P, De Vietro N, Schingaro E, Kostić M, Cosentino C, Cosma P, Bradu C, Chanet G, Crini G. Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples. in Molecules. 2021;26(15):4574.
doi:10.3390/molecules26154574 .
Mongioví, Chiara, Lacalamita, Dario, Morin-Crini, Nadia, Gabrion, Xavier, Ivanovska, Aleksandra, Sala, Federico, Placet, Vincent, Rizzi, Vito, Gubitosa, Jennifer, Mesto, Ernesto, Ribeiro, Ana Rita Lado, Fini, Paola, De Vietro, Nicoletta, Schingaro, Emanuela, Kostić, Mirjana, Cosentino, Cesare, Cosma, Pinalysa, Bradu, Corina, Chanet, Gilles, Crini, Grégorio, "Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for pollutant removal. Part i: Chemical, microscopic, spectroscopic and thermogravimetric characterization of raw and modified samples" in Molecules, 26, no. 15 (2021):4574,
https://doi.org/10.3390/molecules26154574 . .
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