Simić, Zoran

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orcid::0000-0001-8258-5492
  • Simić, Zoran (7)
  • Simić, Zoran V. (7)
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Author's Bibliography

High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling

Grozdanić, Nikola; Simić, Zoran; Kijevčanin, Mirjana; Radović, Ivona

(American Chemical Society, 2024)

TY  - JOUR
AU  - Grozdanić, Nikola
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7150
AB  - Terpenes usually found in plants have a wide range of applications, especially as additives in various types of fuels, and most recently in the aviation industry, where they can be blended with jet fuels or kerosene. In this work, the densities of pure terpenes (1R)-(+)-α-pinene, (1S)-(−)-β-pinene, and linalool were measured over the temperature range T = (293.15 to 413.15) K and at high pressures p = (0.1 to 60) MPa. The experimental density data were fitted by the modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was less than 0.02%, the percentage maximum deviation was less than 0.2%, and the average percentage deviation was less than 0.02% for all three measured terpenes. The obtained parameters were used to determine isothermal compressibility (κT), isobaric thermal expansivity (αp), internal pressure (pint), and the difference between specific heat capacity at constant pressure (cp) and constant volume (cv). Furthermore, the PC-SAFT model was applied for liquid density prediction at high pressures. Derived thermodynamic properties such as isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all of the studied compounds.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling
EP  - 863
IS  - 3
SP  - 854
VL  - 69
DO  - 10.1021/acs.jced.3c00582
ER  - 
@article{
author = "Grozdanić, Nikola and Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2024",
abstract = "Terpenes usually found in plants have a wide range of applications, especially as additives in various types of fuels, and most recently in the aviation industry, where they can be blended with jet fuels or kerosene. In this work, the densities of pure terpenes (1R)-(+)-α-pinene, (1S)-(−)-β-pinene, and linalool were measured over the temperature range T = (293.15 to 413.15) K and at high pressures p = (0.1 to 60) MPa. The experimental density data were fitted by the modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was less than 0.02%, the percentage maximum deviation was less than 0.2%, and the average percentage deviation was less than 0.02% for all three measured terpenes. The obtained parameters were used to determine isothermal compressibility (κT), isobaric thermal expansivity (αp), internal pressure (pint), and the difference between specific heat capacity at constant pressure (cp) and constant volume (cv). Furthermore, the PC-SAFT model was applied for liquid density prediction at high pressures. Derived thermodynamic properties such as isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all of the studied compounds.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling",
pages = "863-854",
number = "3",
volume = "69",
doi = "10.1021/acs.jced.3c00582"
}
Grozdanić, N., Simić, Z., Kijevčanin, M.,& Radović, I.. (2024). High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling. in Journal of Chemical and Engineering Data
American Chemical Society., 69(3), 854-863.
https://doi.org/10.1021/acs.jced.3c00582
Grozdanić N, Simić Z, Kijevčanin M, Radović I. High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling. in Journal of Chemical and Engineering Data. 2024;69(3):854-863.
doi:10.1021/acs.jced.3c00582 .
Grozdanić, Nikola, Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling" in Journal of Chemical and Engineering Data, 69, no. 3 (2024):854-863,
https://doi.org/10.1021/acs.jced.3c00582 . .

Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure

Simić, Zoran V.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.

(American Chemical Society, 2024)

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7342
AB  - This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure
DO  - 10.1021/acs.jced.3c00708
ER  - 
@article{
author = "Simić, Zoran V. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2024",
abstract = "This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure",
doi = "10.1021/acs.jced.3c00708"
}
Simić, Z. V., Radović, I. R.,& Kijevčanin, M. Lj.. (2024). Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. in Journal of Chemical and Engineering Data
American Chemical Society..
https://doi.org/10.1021/acs.jced.3c00708
Simić ZV, Radović IR, Kijevčanin ML. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. in Journal of Chemical and Engineering Data. 2024;.
doi:10.1021/acs.jced.3c00708 .
Simić, Zoran V., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure" in Journal of Chemical and Engineering Data (2024),
https://doi.org/10.1021/acs.jced.3c00708 . .

Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708

Simić, Zoran V.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.

(American Chemical Society, 2024)

TY  - DATA
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7343
AB  - This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7343
ER  - 
@misc{
author = "Simić, Zoran V. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2024",
abstract = "This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7343"
}
Simić, Z. V., Radović, I. R.,& Kijevčanin, M. Lj.. (2024). Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data
American Chemical Society..
https://hdl.handle.net/21.15107/rcub_technorep_7343
Simić ZV, Radović IR, Kijevčanin ML. Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data. 2024;.
https://hdl.handle.net/21.15107/rcub_technorep_7343 .
Simić, Zoran V., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708" in Journal of Chemical and Engineering Data (2024),
https://hdl.handle.net/21.15107/rcub_technorep_7343 .

Waste to Energy: Food Waste Valorisation toward Biofuel Production

Ivaniš, Gorica R.; Simić, Zoran V.; Miškov Panić, Sofija P.; Kijevčanin, Mirjana Lj.; Radović, Ivona R.

(Ca'Foscari University of Venice, 2023)

TY  - CONF
AU  - Ivaniš, Gorica R.
AU  - Simić, Zoran V.
AU  - Miškov Panić, Sofija P.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7396
AB  - The uncontrolled and excessive use of fossil fuels is one of the main culprits for global warming due to the emission of greenhouse gases. Therefore, intensive work has been done to reduce the use of such fuels by replacing/adding biodiesel in transport sector since the use of biodiesel decreases the net emission of greenhouse gases by about 76 % than when using petroleum diesel (Ivaniš et al., 2016). On the other hand, the modern consumer lifestyle has led to the accumulation of large amounts of waste that additionally pollutes the soil and water, which indicates the necessity of a global transition from a linear to a circular economy where waste represents raw material. The disposal of used cooking oil is a huge problem because it is usually poured down drains, which leads to clogging of kitchen pipes and local sewage. Consequently, waste cooking oil drastically reduces the efficiency of wastewater treatment plants and is extremely harmful to the aquatic ecosystem. The reuse of used cooking oil in food is not recommended so other forms of recycling such as biodiesel production are preferred. Biodiesel is obtained by the transesterification reaction of vegetable oils with short-chain alcohol in the presence of a catalyst, and glycerine is produced as a side product. By applying heterogeneously catalysed transesterification reaction, such as the use of CaO as catalyst, the generation of waste during the purification of products is avoided. Eggshells are solid organic waste that is generally discarded without prior treatment, making it a hazardous waste. It is considered that the eggshell mainly (about 96 %) consists of CaCO₃, which offers the possibility of its revalorisation through CaO production (Waheed et al., 2020). As part of our research, waste hen’s eggshell was collected and annealed at 830 ̊C producing CaO, which was used as a catalyst in the biodiesel synthesis from used cooking oil. The thermodynamic and transport properties of the obtained biodiesel and crude glycerine were determined at wide ranges of temperature and pressure, which is relevant for their further use [1]. The measured properties of the obtained biodiesel meet the limits prescribed by the standard for biodiesel EN14214 which confirms that it can be used in diesel engines and heating applications. The obtained raw glycerine can be mixed with biomass residues and used in the production of pellets. In this way, the problem of accumulation of waste in the form of eggshells, used cooking oil and crude glycerine is solved and their revalorisation is carried out, which is fully in accordance with the postulates of the circular economy. Furthermore, biodiesel, as an environmentally friendly alternative to petroleum diesel, was obtained.
PB  - Ca'Foscari University of Venice
C3  - Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
T1  - Waste to Energy: Food Waste Valorisation toward Biofuel Production
SP  - 315
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7396
ER  - 
@conference{
author = "Ivaniš, Gorica R. and Simić, Zoran V. and Miškov Panić, Sofija P. and Kijevčanin, Mirjana Lj. and Radović, Ivona R.",
year = "2023",
abstract = "The uncontrolled and excessive use of fossil fuels is one of the main culprits for global warming due to the emission of greenhouse gases. Therefore, intensive work has been done to reduce the use of such fuels by replacing/adding biodiesel in transport sector since the use of biodiesel decreases the net emission of greenhouse gases by about 76 % than when using petroleum diesel (Ivaniš et al., 2016). On the other hand, the modern consumer lifestyle has led to the accumulation of large amounts of waste that additionally pollutes the soil and water, which indicates the necessity of a global transition from a linear to a circular economy where waste represents raw material. The disposal of used cooking oil is a huge problem because it is usually poured down drains, which leads to clogging of kitchen pipes and local sewage. Consequently, waste cooking oil drastically reduces the efficiency of wastewater treatment plants and is extremely harmful to the aquatic ecosystem. The reuse of used cooking oil in food is not recommended so other forms of recycling such as biodiesel production are preferred. Biodiesel is obtained by the transesterification reaction of vegetable oils with short-chain alcohol in the presence of a catalyst, and glycerine is produced as a side product. By applying heterogeneously catalysed transesterification reaction, such as the use of CaO as catalyst, the generation of waste during the purification of products is avoided. Eggshells are solid organic waste that is generally discarded without prior treatment, making it a hazardous waste. It is considered that the eggshell mainly (about 96 %) consists of CaCO₃, which offers the possibility of its revalorisation through CaO production (Waheed et al., 2020). As part of our research, waste hen’s eggshell was collected and annealed at 830 ̊C producing CaO, which was used as a catalyst in the biodiesel synthesis from used cooking oil. The thermodynamic and transport properties of the obtained biodiesel and crude glycerine were determined at wide ranges of temperature and pressure, which is relevant for their further use [1]. The measured properties of the obtained biodiesel meet the limits prescribed by the standard for biodiesel EN14214 which confirms that it can be used in diesel engines and heating applications. The obtained raw glycerine can be mixed with biomass residues and used in the production of pellets. In this way, the problem of accumulation of waste in the form of eggshells, used cooking oil and crude glycerine is solved and their revalorisation is carried out, which is fully in accordance with the postulates of the circular economy. Furthermore, biodiesel, as an environmentally friendly alternative to petroleum diesel, was obtained.",
publisher = "Ca'Foscari University of Venice",
journal = "Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy",
title = "Waste to Energy: Food Waste Valorisation toward Biofuel Production",
pages = "315",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7396"
}
Ivaniš, G. R., Simić, Z. V., Miškov Panić, S. P., Kijevčanin, M. Lj.,& Radović, I. R.. (2023). Waste to Energy: Food Waste Valorisation toward Biofuel Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
Ca'Foscari University of Venice., 315.
https://hdl.handle.net/21.15107/rcub_technorep_7396
Ivaniš GR, Simić ZV, Miškov Panić SP, Kijevčanin ML, Radović IR. Waste to Energy: Food Waste Valorisation toward Biofuel Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy. 2023;:315.
https://hdl.handle.net/21.15107/rcub_technorep_7396 .
Ivaniš, Gorica R., Simić, Zoran V., Miškov Panić, Sofija P., Kijevčanin, Mirjana Lj., Radović, Ivona R., "Waste to Energy: Food Waste Valorisation toward Biofuel Production" in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy (2023):315,
https://hdl.handle.net/21.15107/rcub_technorep_7396 .

Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production

Simić, Zoran V.; Ivaniš, Gorica R.; Miškov Panić, Sofija P.; Kijevčanin, Mirjana Lj.; Radović, Ivona R.

(Ca'Foscari University of Venice, 2023)

TY  - CONF
AU  - Simić, Zoran V.
AU  - Ivaniš, Gorica R.
AU  - Miškov Panić, Sofija P.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7395
AB  - The negative impact of the use of fossil fuels on the environment has led to an increase in research in the field of renewable energy sources and intensified the production of biodiesel. The latter has caused the accumulation of a large amount of waste glycerol, since about 1 kg of crude glycerol is obtained for 10 kg of biodiesel. Crude glycerol is traditionally considered a low-value waste because of impurities and variable composition and its disposal was limited due to the harmful effects on the environment. To reuse this by-product of the transesterification reaction, in most cases it needs to be refined. However, crude glycerol purification requires additional costs while at the same time the glycerol market is already saturated and, consequently, the price of crude glycerol continues to decline. To avoid the accumulation of waste glycerol and pollution of the environment, it is necessary to find some applications for the raw glycerol obtained from the industrial production of biodiesel (Groesbeck et al., 2008).
Crude glycerol can be integrated with waste biomass, such as agricultural waste and wood residues, to improve its properties as a fuel. During the production of pellets, raw glycerol serves as a binder, which increases the yield and durability of pellets during storage and transportation. Additionally, it serves as a lubricant reducing the energy required for palletisation. It has been shown that when burning pellets with additional raw glycerol, a significantly lower amount of NOx is released than in the case of classic wood pellets (Zhang et al., 2022).
In this study, we investigated the possibility of adding waste crude glycerol to waste agro-industrial biomass in the production of enriched pellets. By applying the basic principles of the circular economy, the glycerol used for the purposes of this research was obtained from the transesterification reaction between used edible oil and short-chain alcohol, with the presence of a catalyst obtained from the waste shell of chicken egg. The characterization of the mixtures of different agricultural biomass and agro-industrial waste with different mass fraction of crude glycerol was performed. Standard analyses for determining the quality of pellets (such as calorific value, ash content, etc.) were performed to examine the possibility of using the enriched pellets obtained in this way in existing boilers designed for the use of commercial pellets.
PB  - Ca'Foscari University of Venice
C3  - Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
T1  - Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production
SP  - 327
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7395
ER  - 
@conference{
author = "Simić, Zoran V. and Ivaniš, Gorica R. and Miškov Panić, Sofija P. and Kijevčanin, Mirjana Lj. and Radović, Ivona R.",
year = "2023",
abstract = "The negative impact of the use of fossil fuels on the environment has led to an increase in research in the field of renewable energy sources and intensified the production of biodiesel. The latter has caused the accumulation of a large amount of waste glycerol, since about 1 kg of crude glycerol is obtained for 10 kg of biodiesel. Crude glycerol is traditionally considered a low-value waste because of impurities and variable composition and its disposal was limited due to the harmful effects on the environment. To reuse this by-product of the transesterification reaction, in most cases it needs to be refined. However, crude glycerol purification requires additional costs while at the same time the glycerol market is already saturated and, consequently, the price of crude glycerol continues to decline. To avoid the accumulation of waste glycerol and pollution of the environment, it is necessary to find some applications for the raw glycerol obtained from the industrial production of biodiesel (Groesbeck et al., 2008).
Crude glycerol can be integrated with waste biomass, such as agricultural waste and wood residues, to improve its properties as a fuel. During the production of pellets, raw glycerol serves as a binder, which increases the yield and durability of pellets during storage and transportation. Additionally, it serves as a lubricant reducing the energy required for palletisation. It has been shown that when burning pellets with additional raw glycerol, a significantly lower amount of NOx is released than in the case of classic wood pellets (Zhang et al., 2022).
In this study, we investigated the possibility of adding waste crude glycerol to waste agro-industrial biomass in the production of enriched pellets. By applying the basic principles of the circular economy, the glycerol used for the purposes of this research was obtained from the transesterification reaction between used edible oil and short-chain alcohol, with the presence of a catalyst obtained from the waste shell of chicken egg. The characterization of the mixtures of different agricultural biomass and agro-industrial waste with different mass fraction of crude glycerol was performed. Standard analyses for determining the quality of pellets (such as calorific value, ash content, etc.) were performed to examine the possibility of using the enriched pellets obtained in this way in existing boilers designed for the use of commercial pellets.",
publisher = "Ca'Foscari University of Venice",
journal = "Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy",
title = "Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production",
pages = "327",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7395"
}
Simić, Z. V., Ivaniš, G. R., Miškov Panić, S. P., Kijevčanin, M. Lj.,& Radović, I. R.. (2023). Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
Ca'Foscari University of Venice., 327.
https://hdl.handle.net/21.15107/rcub_technorep_7395
Simić ZV, Ivaniš GR, Miškov Panić SP, Kijevčanin ML, Radović IR. Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy. 2023;:327.
https://hdl.handle.net/21.15107/rcub_technorep_7395 .
Simić, Zoran V., Ivaniš, Gorica R., Miškov Panić, Sofija P., Kijevčanin, Mirjana Lj., Radović, Ivona R., "Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production" in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy (2023):327,
https://hdl.handle.net/21.15107/rcub_technorep_7395 .

Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling

Simić, Zoran V.; Radović, Ivona R.; Stijepović, Mirko Z.; Kijevčanin, Mirjana Lj.

(Elsevier B.V., 2023)

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Stijepović, Mirko Z.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6030
AB  - The aim of this study was to examine the possibility of using a green organic solvent, dimethyl adipate (DMA), as a separation agent in the extraction of different alcohols from aqueous solutions. For that purpose, the liquid–liquid equilibria (LLE) of four ternary systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {water + methanol + dimethyl adipate (DMA)}, {water + ethanol + DMA}, {water + 1-propanol + DMA}, {water + 2-propanol + DMA}. Phase diagrams for these four ternary systems were obtained by determining a binodal curve and tie-lines data using a visual cloud-point method, but also gas chromatography. Distribution coefficients and separation factors were calculated for the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. In addition, the experimental ternary LLE data were correlated with the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The obtained results showed that DMA is a suitable candidate for the extraction of methanol, ethanol, 1-propanol, and 2-propanol from water. With some alcohols, this potential is more noticeable than with others. The potential of DMA as a separation agent is increasing in the following sequence: methanol < ethanol < 2-propanol < 1-propanol, and that also could be noticed from the selectivity values that also increase in this sequence. The UNIQUAC model proved as successful in correlating the LLE data.
PB  - Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling
SP  - 121542
VL  - 377
DO  - 10.1016/j.molliq.2023.121542
ER  - 
@article{
author = "Simić, Zoran V. and Radović, Ivona R. and Stijepović, Mirko Z. and Kijevčanin, Mirjana Lj.",
year = "2023",
abstract = "The aim of this study was to examine the possibility of using a green organic solvent, dimethyl adipate (DMA), as a separation agent in the extraction of different alcohols from aqueous solutions. For that purpose, the liquid–liquid equilibria (LLE) of four ternary systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {water + methanol + dimethyl adipate (DMA)}, {water + ethanol + DMA}, {water + 1-propanol + DMA}, {water + 2-propanol + DMA}. Phase diagrams for these four ternary systems were obtained by determining a binodal curve and tie-lines data using a visual cloud-point method, but also gas chromatography. Distribution coefficients and separation factors were calculated for the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. In addition, the experimental ternary LLE data were correlated with the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The obtained results showed that DMA is a suitable candidate for the extraction of methanol, ethanol, 1-propanol, and 2-propanol from water. With some alcohols, this potential is more noticeable than with others. The potential of DMA as a separation agent is increasing in the following sequence: methanol < ethanol < 2-propanol < 1-propanol, and that also could be noticed from the selectivity values that also increase in this sequence. The UNIQUAC model proved as successful in correlating the LLE data.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling",
pages = "121542",
volume = "377",
doi = "10.1016/j.molliq.2023.121542"
}
Simić, Z. V., Radović, I. R., Stijepović, M. Z.,& Kijevčanin, M. Lj.. (2023). Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling. in Journal of Molecular Liquids
Elsevier B.V.., 377, 121542.
https://doi.org/10.1016/j.molliq.2023.121542
Simić ZV, Radović IR, Stijepović MZ, Kijevčanin ML. Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling. in Journal of Molecular Liquids. 2023;377:121542.
doi:10.1016/j.molliq.2023.121542 .
Simić, Zoran V., Radović, Ivona R., Stijepović, Mirko Z., Kijevčanin, Mirjana Lj., "Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling" in Journal of Molecular Liquids, 377 (2023):121542,
https://doi.org/10.1016/j.molliq.2023.121542 . .
2

Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova

Simić, Zoran; Radović, Ivona; Kijevčanin, Mirjana

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku, 2023)

TY  - CONF
AU  - Simić, Zoran
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6940
AB  - U ovom radu su prikazani podaci o ravnoteži tečnost-tečnost za trokomponentnu smešu voda
+ aceton + dimetil ftalat na T = 298 K i atmosferskom pritisku. Zbog povećanja potrošnje energije
na globalnom nivou, potrebno je ispitati nove mogućnosti zamene klasičnih energetski intenzivnih
procesa separacije koji bi bili zasnovani na ravnoteži tečnost-tečnost. Ekstrakcija tečnost-tečnost je
isplativa, efikasna i iznad svega, metoda separacije koja je prihvatljiva za prirodu u industrijskim
procesima Ovaj postupak bi takođe uključivao zamenu standardnih industrijskih rastvarača sa
ekološki štetnim karakteristikama novim, zelenim rastvaračima. Dimetil ftalat je dobar kandidat
kao zeleni rastvarač jer je relativno netoksičan, dobijen iz obnovljivih izvora i biorazgradiv. Termodinamički
podaci o ravnoteži tečnost-tečnost kako što su binodalna kriva i ravnotežne linije za
odgovarajući sistem su neophodni za projektovanje procesa separacije kao i za bolju percepciju
ponašanja višekomponentnih sistema i poboljšanje termodinamičkog modelovanja i predviđanja
fazne ravnoteže.
AB  - This paper presents liquid-liquid equilibrium data for the ternary mixture of water + acetone + dimethyl phthalate at T = 298 K and atmospheric pressure. Due to the increase in energy consumption on a global level, it is necessary to examine new possibilities of replacing the classic energy-intensive separation processes that would be based on liquid-liquid extraction. Liquid-liquid
extraction is a cost-effective, efficient and, above all, environmentally friendly separation method in
industrial processes. This procedure would also involve the replacement of standard industrial solvents with environmentally harmful characteristics with new, green solvents. Dimethyl phthalate is a good candidate as a green solvent because it is relatively non-toxic, renewable and biodegradable.
Thermodynamic liquid-liquid equilibrium data such as the binodal curve and tie lines for the
corresponding system are necessary for the design of the separation process as well as for a better perception of the behaviour of multicomponent systems and the improvement of thermodynamic modelling and prediction of phase equilibrium.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings
T1  - Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova
T1  - Determination of liquid-liquid equilibrium data of ternary systems for the treatment of industrial wastewater streams
SP  - 91
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6940
ER  - 
@conference{
author = "Simić, Zoran and Radović, Ivona and Kijevčanin, Mirjana",
year = "2023",
abstract = "U ovom radu su prikazani podaci o ravnoteži tečnost-tečnost za trokomponentnu smešu voda
+ aceton + dimetil ftalat na T = 298 K i atmosferskom pritisku. Zbog povećanja potrošnje energije
na globalnom nivou, potrebno je ispitati nove mogućnosti zamene klasičnih energetski intenzivnih
procesa separacije koji bi bili zasnovani na ravnoteži tečnost-tečnost. Ekstrakcija tečnost-tečnost je
isplativa, efikasna i iznad svega, metoda separacije koja je prihvatljiva za prirodu u industrijskim
procesima Ovaj postupak bi takođe uključivao zamenu standardnih industrijskih rastvarača sa
ekološki štetnim karakteristikama novim, zelenim rastvaračima. Dimetil ftalat je dobar kandidat
kao zeleni rastvarač jer je relativno netoksičan, dobijen iz obnovljivih izvora i biorazgradiv. Termodinamički
podaci o ravnoteži tečnost-tečnost kako što su binodalna kriva i ravnotežne linije za
odgovarajući sistem su neophodni za projektovanje procesa separacije kao i za bolju percepciju
ponašanja višekomponentnih sistema i poboljšanje termodinamičkog modelovanja i predviđanja
fazne ravnoteže., This paper presents liquid-liquid equilibrium data for the ternary mixture of water + acetone + dimethyl phthalate at T = 298 K and atmospheric pressure. Due to the increase in energy consumption on a global level, it is necessary to examine new possibilities of replacing the classic energy-intensive separation processes that would be based on liquid-liquid extraction. Liquid-liquid
extraction is a cost-effective, efficient and, above all, environmentally friendly separation method in
industrial processes. This procedure would also involve the replacement of standard industrial solvents with environmentally harmful characteristics with new, green solvents. Dimethyl phthalate is a good candidate as a green solvent because it is relatively non-toxic, renewable and biodegradable.
Thermodynamic liquid-liquid equilibrium data such as the binodal curve and tie lines for the
corresponding system are necessary for the design of the separation process as well as for a better perception of the behaviour of multicomponent systems and the improvement of thermodynamic modelling and prediction of phase equilibrium.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings",
title = "Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova, Determination of liquid-liquid equilibrium data of ternary systems for the treatment of industrial wastewater streams",
pages = "91",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6940"
}
Simić, Z., Radović, I.,& Kijevčanin, M.. (2023). Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova. in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 91.
https://hdl.handle.net/21.15107/rcub_technorep_6940
Simić Z, Radović I, Kijevčanin M. Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova. in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings. 2023;:91.
https://hdl.handle.net/21.15107/rcub_technorep_6940 .
Simić, Zoran, Radović, Ivona, Kijevčanin, Mirjana, "Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova" in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings (2023):91,
https://hdl.handle.net/21.15107/rcub_technorep_6940 .

Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures

Simić, Zoran; Ivaniš, Gorica; Radović, Ivona; Kijevčanin, Mirjana

(Lublin : Publishing House of The University of Life Sciences, 2022)

TY  - CONF
AU  - Simić, Zoran
AU  - Ivaniš, Gorica
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7394
UR  - https://conference-doctoral.up.lublin.pl/2022-volume/
AB  - Due to the global trend of decreasing fossil energy sources consumption, there is a tendency, among other things, to explore possibilities of using biomass to obtain biofuels and value-added chemicals. In order to design processes as optimally as possible, it is necessary to know the thermodynamic properties of biomass components. One of the components that have been gaining in importance lately are furfural and furfuryl alcohol. The thermodynamic and transport properties such as density, speed of sound, refractive index and viscosity, of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressure up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation. The thermodynamic properties of these components are of great importance in their further potential application.
PB  - Lublin : Publishing House of The University of Life Sciences
C3  - 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022
T1  - Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures
SP  - T029
DO  - 10.24326/ICDSUPL1.T029
ER  - 
@conference{
author = "Simić, Zoran and Ivaniš, Gorica and Radović, Ivona and Kijevčanin, Mirjana",
year = "2022",
abstract = "Due to the global trend of decreasing fossil energy sources consumption, there is a tendency, among other things, to explore possibilities of using biomass to obtain biofuels and value-added chemicals. In order to design processes as optimally as possible, it is necessary to know the thermodynamic properties of biomass components. One of the components that have been gaining in importance lately are furfural and furfuryl alcohol. The thermodynamic and transport properties such as density, speed of sound, refractive index and viscosity, of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressure up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation. The thermodynamic properties of these components are of great importance in their further potential application.",
publisher = "Lublin : Publishing House of The University of Life Sciences",
journal = "1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022",
title = "Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures",
pages = "T029",
doi = "10.24326/ICDSUPL1.T029"
}
Simić, Z., Ivaniš, G., Radović, I.,& Kijevčanin, M.. (2022). Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures. in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022
Lublin : Publishing House of The University of Life Sciences., T029.
https://doi.org/10.24326/ICDSUPL1.T029
Simić Z, Ivaniš G, Radović I, Kijevčanin M. Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures. in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022. 2022;:T029.
doi:10.24326/ICDSUPL1.T029 .
Simić, Zoran, Ivaniš, Gorica, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures" in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022 (2022):T029,
https://doi.org/10.24326/ICDSUPL1.T029 . .

Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost

Simić, Zoran; Kijevčanin, Mirjana; Radović, Ivona

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku, 2022)

TY  - CONF
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7388
AB  - Zbog globalnog trenda povećanja zagađenosti životne okoline teži se ka tome da se u različitim granama hemijske industrije implementiraju zeleni rastvarači, koji bi zamenili štetne industrijske rastvarače. Kako bi se ispitale mogućnosti upotrebe zelenih rastvarača, mogućnosti adekvatne zamene i projektovanje procesa, neophodno je poznavanje termodinamičkih podataka kao što su podaci za ravnotežu tečnost-tečnost (LLE), odgovarajuću binodalnu krivu i ravnotežne linije. Podaci o rastvorljivosti komponenata su od velikog značaja za procese separacije (naročito ekstrakciju) koji se primenjuju u hemijskoj industriji. Ravnotežne linije predstavljaju veoma bitan termodinamički podatak koji se, u zavisnosti od same prirode komponenti koje ulaze u sastav smeše, u velikom procentu dobijaju hromatografskom analizom. S obzirom da je hromatografska analiza metoda koju ne može svaka laboratorija da priušti, kako zbog visoke cene aparata tako i zbog visokih troškova korišćenja, u ovom radu biće prikazane neke od alternativnih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. Na primeru ternarnog sistema voda+dimetil adipat+2-propanol biće prikazano određivanje ravnotežnih linija preko indeksa refrakcije i preko gustine smeše. Ove analitičke metode često se koriste u različitim granama industrije. Na osnovu dobijenih rezultata izvršeno je medjusobno poredjenje rezultata dobijenih preko ove tri metode.
AB  - Due to the global trend of increasing environmental pollution, green solvents are being implemented in various branches of the chemical industry to, which would replace standard industrial solvents with harmful characteristics. In order to examine the possibilities of using green solvents, the possibility of appropriate replacement and process design, it is necessary to determine thermodynamic data such as liquid-liquid equilibria, i.e. tie lines in liquid- liquid extraction (LLE), and the corresponding binodal curve. Solubility of components are of great importance for the separation processes (especially for extraction) applied in the chemical industry. Tie lines are a very important thermodynamic data, which are mostly determined by chromatographic analysis depending on the nature of the components in the mixture. Tie lines are mostly determined by chromatographic analysis. Chromatographic analysis is one of the methods that not every laboratory can afford, due to the high cost of the apparatus and high operational costs. In this paper some of the alternative methods for determining tie lines in liquid-liquid equilibria are presented. On the example of the ternary system water+dimethyl adipate+2-propanol, the determination of tie lines via the refractive index and the density of the mixture are shown. These analytical methods are often used in various branches of industry. Based on the obtained results, a mutual comparison of the results obtained through these three methods is performed.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd
T1  - Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost
T1  - Analysis of different possibilities for determining tie lines in liquid-liquid equilibria
EP  - 323
SP  - 319
DO  - 10.24094/ptk.022.319
ER  - 
@conference{
author = "Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2022",
abstract = "Zbog globalnog trenda povećanja zagađenosti životne okoline teži se ka tome da se u različitim granama hemijske industrije implementiraju zeleni rastvarači, koji bi zamenili štetne industrijske rastvarače. Kako bi se ispitale mogućnosti upotrebe zelenih rastvarača, mogućnosti adekvatne zamene i projektovanje procesa, neophodno je poznavanje termodinamičkih podataka kao što su podaci za ravnotežu tečnost-tečnost (LLE), odgovarajuću binodalnu krivu i ravnotežne linije. Podaci o rastvorljivosti komponenata su od velikog značaja za procese separacije (naročito ekstrakciju) koji se primenjuju u hemijskoj industriji. Ravnotežne linije predstavljaju veoma bitan termodinamički podatak koji se, u zavisnosti od same prirode komponenti koje ulaze u sastav smeše, u velikom procentu dobijaju hromatografskom analizom. S obzirom da je hromatografska analiza metoda koju ne može svaka laboratorija da priušti, kako zbog visoke cene aparata tako i zbog visokih troškova korišćenja, u ovom radu biće prikazane neke od alternativnih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. Na primeru ternarnog sistema voda+dimetil adipat+2-propanol biće prikazano određivanje ravnotežnih linija preko indeksa refrakcije i preko gustine smeše. Ove analitičke metode često se koriste u različitim granama industrije. Na osnovu dobijenih rezultata izvršeno je medjusobno poredjenje rezultata dobijenih preko ove tri metode., Due to the global trend of increasing environmental pollution, green solvents are being implemented in various branches of the chemical industry to, which would replace standard industrial solvents with harmful characteristics. In order to examine the possibilities of using green solvents, the possibility of appropriate replacement and process design, it is necessary to determine thermodynamic data such as liquid-liquid equilibria, i.e. tie lines in liquid- liquid extraction (LLE), and the corresponding binodal curve. Solubility of components are of great importance for the separation processes (especially for extraction) applied in the chemical industry. Tie lines are a very important thermodynamic data, which are mostly determined by chromatographic analysis depending on the nature of the components in the mixture. Tie lines are mostly determined by chromatographic analysis. Chromatographic analysis is one of the methods that not every laboratory can afford, due to the high cost of the apparatus and high operational costs. In this paper some of the alternative methods for determining tie lines in liquid-liquid equilibria are presented. On the example of the ternary system water+dimethyl adipate+2-propanol, the determination of tie lines via the refractive index and the density of the mixture are shown. These analytical methods are often used in various branches of industry. Based on the obtained results, a mutual comparison of the results obtained through these three methods is performed.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd",
title = "Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost, Analysis of different possibilities for determining tie lines in liquid-liquid equilibria",
pages = "323-319",
doi = "10.24094/ptk.022.319"
}
Simić, Z., Kijevčanin, M.,& Radović, I.. (2022). Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 319-323.
https://doi.org/10.24094/ptk.022.319
Simić Z, Kijevčanin M, Radović I. Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd. 2022;:319-323.
doi:10.24094/ptk.022.319 .
Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost" in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd (2022):319-323,
https://doi.org/10.24094/ptk.022.319 . .

Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku

Simić, Zoran; Miletić, Ksenija; Grozdanić, Nikola; Radović, Ivona; Kijevčanin, Mirjana

(Beograd : Srpsko hemijsko društvo = Serbian Chemical Society, 2021)

TY  - CONF
AU  - Simić, Zoran
AU  - Miletić, Ksenija
AU  - Grozdanić, Nikola
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7398
AB  - U cilju smanjenja zagađenja na globalnom nivou poslednjih godina aktuelna je tema zamene fosilnih goriva nekim novim biogorivima. Terpeni, koji su sastavni delovi biljaka, mogu se koristiti u ove svrhe kao dodatak standardnim gorivima. Neke od termodinamičkih svojstva pod uslovima visokog pritiska i određnih temperatura su od velike važnosti za efikasnost motora. U ovom radu su dobijene gustine linalola, alfa-pinena i beta-pinena u temperaturnom intervalu 293.15-413.15 K i na pritiscima do 60 MPa. Na osnovu ovih rezultata utvrđeno je da s porastom temperature pri konstantnom pritisku gustina navedenih terpena opada, dok sa povećanjem pritiska pri konstantnoj temperaturi gustina raste.
AB  - In order to reduce pollution at the global level in recent years, the main topic is replacing fossil fuels with some new biofuels. Terpenes, which are integral parts of plants, can be used for these purposes as an addition to standard petroelum fuels. Some of thermodynamic properties under high pressure conditions and moderate temperatures are of significant importance for engine efficiency. In this work, the densities of linalool, αpinene and β-pinene were obtained in the temperature range 293.15-413.15 K and at pressures up to 60 MPa. Based on these results, it was found that with increasing temperature at constant pressure the density of these terpenes decreases, while with increasing pressure at constant temperature the density increases.
PB  - Beograd : Srpsko hemijsko društvo = Serbian Chemical Society
C3  - Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021
T1  - Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku
T1  - Experimental determination of linalool, α-pinene and β-pinene densities at high pressure
EP  - 127
SP  - 121
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7398
ER  - 
@conference{
author = "Simić, Zoran and Miletić, Ksenija and Grozdanić, Nikola and Radović, Ivona and Kijevčanin, Mirjana",
year = "2021",
abstract = "U cilju smanjenja zagađenja na globalnom nivou poslednjih godina aktuelna je tema zamene fosilnih goriva nekim novim biogorivima. Terpeni, koji su sastavni delovi biljaka, mogu se koristiti u ove svrhe kao dodatak standardnim gorivima. Neke od termodinamičkih svojstva pod uslovima visokog pritiska i određnih temperatura su od velike važnosti za efikasnost motora. U ovom radu su dobijene gustine linalola, alfa-pinena i beta-pinena u temperaturnom intervalu 293.15-413.15 K i na pritiscima do 60 MPa. Na osnovu ovih rezultata utvrđeno je da s porastom temperature pri konstantnom pritisku gustina navedenih terpena opada, dok sa povećanjem pritiska pri konstantnoj temperaturi gustina raste., In order to reduce pollution at the global level in recent years, the main topic is replacing fossil fuels with some new biofuels. Terpenes, which are integral parts of plants, can be used for these purposes as an addition to standard petroelum fuels. Some of thermodynamic properties under high pressure conditions and moderate temperatures are of significant importance for engine efficiency. In this work, the densities of linalool, αpinene and β-pinene were obtained in the temperature range 293.15-413.15 K and at pressures up to 60 MPa. Based on these results, it was found that with increasing temperature at constant pressure the density of these terpenes decreases, while with increasing pressure at constant temperature the density increases.",
publisher = "Beograd : Srpsko hemijsko društvo = Serbian Chemical Society",
journal = "Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021",
title = "Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku, Experimental determination of linalool, α-pinene and β-pinene densities at high pressure",
pages = "127-121",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7398"
}
Simić, Z., Miletić, K., Grozdanić, N., Radović, I.,& Kijevčanin, M.. (2021). Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021
Beograd : Srpsko hemijsko društvo = Serbian Chemical Society., 121-127.
https://hdl.handle.net/21.15107/rcub_technorep_7398
Simić Z, Miletić K, Grozdanić N, Radović I, Kijevčanin M. Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021. 2021;:121-127.
https://hdl.handle.net/21.15107/rcub_technorep_7398 .
Simić, Zoran, Miletić, Ksenija, Grozdanić, Nikola, Radović, Ivona, Kijevčanin, Mirjana, "Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku" in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021 (2021):121-127,
https://hdl.handle.net/21.15107/rcub_technorep_7398 .

Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures

Simić, Zoran V.; Kijevčanin, Mirjana Lj.; Radović, Ivona R.; Grilc, Miha; Ivaniš, Gorica R.

(MDPI, 2021)

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
AU  - Grilc, Miha
AU  - Ivaniš, Gorica R.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5933
AB  - The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range T = (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.
PB  - MDPI
T2  - Energies
T1  - Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures
IS  - 22
SP  - 7769
VL  - 14
DO  - 10.3390/en14227769
ER  - 
@article{
author = "Simić, Zoran V. and Kijevčanin, Mirjana Lj. and Radović, Ivona R. and Grilc, Miha and Ivaniš, Gorica R.",
year = "2021",
abstract = "The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range T = (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.",
publisher = "MDPI",
journal = "Energies",
title = "Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures",
number = "22",
pages = "7769",
volume = "14",
doi = "10.3390/en14227769"
}
Simić, Z. V., Kijevčanin, M. Lj., Radović, I. R., Grilc, M.,& Ivaniš, G. R.. (2021). Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures. in Energies
MDPI., 14(22), 7769.
https://doi.org/10.3390/en14227769
Simić ZV, Kijevčanin ML, Radović IR, Grilc M, Ivaniš GR. Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures. in Energies. 2021;14(22):7769.
doi:10.3390/en14227769 .
Simić, Zoran V., Kijevčanin, Mirjana Lj., Radović, Ivona R., Grilc, Miha, Ivaniš, Gorica R., "Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures" in Energies, 14, no. 22 (2021):7769,
https://doi.org/10.3390/en14227769 . .
9
8

Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima

Simić, Zoran; Kijevčanin, Mirjana; Radović, Ivona

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku, 2021)

TY  - CONF
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7389
AB  - Zbog globalnog trenda povećanja potrošnje energenata, kao i njihove cene, teži se ka tome da
se ispitaju nove mogućnosti zamene klasičnih energetski zahtevnih separacionih procesa zasnovanih
na isparavanju lakše isparljivih komponenata, na procese separacije zasnovanih na ravnoteži tečnost-tečnost (LLE), odnosno na ekstrakciji komponenata iz tečnih rastvora. Pored toga što bi ovaj
postupak podrazumevao smanjenu upotrebu različitih izvora energije, on bi uključio i zamenu standardnih industrijskih rastvarača sa karakteristikama štetnim po životnu sredinu, novim, zelenim
rastvaračima. U ovom radu biće prikazan način korišćenja ravnoteže tečnost-tečnost na separacione
procese, na primeru ternarnog sitema voda + i-propanol + dimetil adipat, a kroz određivanje binodalnih krivih i ravnotežnih linija na atmosferskom pritisku i temperaturi od 298.15K.
AB  - Due to the global trend of increasing energy consumption, as well as their prices, the aim is to examine the possibilities of replacing energy-intensive classical separation processes based on eva-poration of more volatile components, to separation processes based on liquid-liquid equilibria (LLE), i.e. extraction of components from liquid solutions. Beside that this procedure would involve the reduced use of various energy sources, it would also include the replacement of standard indus-trial solvents with harmful characteristics for the environment, new green solvents. This paper will show the method of using liquid-liquid equilibrium on the example of the ternary system water + i-propanol + dimethyl adipate through the determination of binodal curves and tie lines at atmospheric pressure and temperature of 298.15 K.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad
T1  - Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima
T1  - Liquid-liquid equilibrium of the ternary water solutions system in separation processes
EP  - 144
SP  - 141
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7389
ER  - 
@conference{
author = "Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2021",
abstract = "Zbog globalnog trenda povećanja potrošnje energenata, kao i njihove cene, teži se ka tome da
se ispitaju nove mogućnosti zamene klasičnih energetski zahtevnih separacionih procesa zasnovanih
na isparavanju lakše isparljivih komponenata, na procese separacije zasnovanih na ravnoteži tečnost-tečnost (LLE), odnosno na ekstrakciji komponenata iz tečnih rastvora. Pored toga što bi ovaj
postupak podrazumevao smanjenu upotrebu različitih izvora energije, on bi uključio i zamenu standardnih industrijskih rastvarača sa karakteristikama štetnim po životnu sredinu, novim, zelenim
rastvaračima. U ovom radu biće prikazan način korišćenja ravnoteže tečnost-tečnost na separacione
procese, na primeru ternarnog sitema voda + i-propanol + dimetil adipat, a kroz određivanje binodalnih krivih i ravnotežnih linija na atmosferskom pritisku i temperaturi od 298.15K., Due to the global trend of increasing energy consumption, as well as their prices, the aim is to examine the possibilities of replacing energy-intensive classical separation processes based on eva-poration of more volatile components, to separation processes based on liquid-liquid equilibria (LLE), i.e. extraction of components from liquid solutions. Beside that this procedure would involve the reduced use of various energy sources, it would also include the replacement of standard indus-trial solvents with harmful characteristics for the environment, new green solvents. This paper will show the method of using liquid-liquid equilibrium on the example of the ternary system water + i-propanol + dimethyl adipate through the determination of binodal curves and tie lines at atmospheric pressure and temperature of 298.15 K.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad",
title = "Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima, Liquid-liquid equilibrium of the ternary water solutions system in separation processes",
pages = "144-141",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7389"
}
Simić, Z., Kijevčanin, M.,& Radović, I.. (2021). Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima. in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 141-144.
https://hdl.handle.net/21.15107/rcub_technorep_7389
Simić Z, Kijevčanin M, Radović I. Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima. in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad. 2021;:141-144.
https://hdl.handle.net/21.15107/rcub_technorep_7389 .
Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima" in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad (2021):141-144,
https://hdl.handle.net/21.15107/rcub_technorep_7389 .

Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure

Aissa, Mohamed A.; Radović, Ivona; Simić, Zoran V.; Kijevčanin, Mirjana

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Aissa, Mohamed A.
AU  - Radović, Ivona
AU  - Simić, Zoran V.
AU  - Kijevčanin, Mirjana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4402
AB  - Densities, viscosities, speeds of sound and refractive indices have beenmeasured for the ternary systemethyl oleate+ n-hexadecane+1-butanol, and for the corresponding binaries ethyl oleate+1-butanol and ethyl oleate+ n-hexadecane, in the temperature range fromT=(293.15 to 343.15) K and at atmospheric pressure. Experimental data were employed to calculate some derived thermodynamic parameters, i.e. excess molar volumes (V-E), viscosity deviations (Delta eta.) and deviations in refractive index (.nD). Additionally, molar excess Gibbs free energies of activation of viscous flow (Delta G*(E)) and deviations in isentropic compressibility (Delta kappa(s)) were calculated. A graphical representation of excess molar volumes and refractive indices show positive deviation from ideal behavior for both binary systems whereas deviation in viscosity shows negative nature for the ethyl oleate + n-hexadecane system and an inversion sign for ethyl oleate +1-butanol binary system. A negative deviation in isentropic compressibility was confirmed for the systems ethyl oleate +1-butanol while positive deviation was observed in ethyl oleate + n-hexadecane system. It can be concluded that dispersive forces predominate between the components in binary systems and the observed behavior seems to suggest that the properties obtained for the ternary mixture are dominated by the binary effects. The viscosities of the binary systems were modeled by UNIFAC-VISCO, ASOG-VISCO, Teja-Rice and McAllister models. The results showed that McAllister's multibodymodel is suitable to describe viscosities for binary systemswithmaximumpercentage deviations less than 0.5%.
PB  - Elsevier, Amsterdam
T2  - Journal of Molecular Liquids
T1  - Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure
VL  - 317
DO  - 10.1016/j.molliq.2020.114186
ER  - 
@article{
author = "Aissa, Mohamed A. and Radović, Ivona and Simić, Zoran V. and Kijevčanin, Mirjana",
year = "2020",
abstract = "Densities, viscosities, speeds of sound and refractive indices have beenmeasured for the ternary systemethyl oleate+ n-hexadecane+1-butanol, and for the corresponding binaries ethyl oleate+1-butanol and ethyl oleate+ n-hexadecane, in the temperature range fromT=(293.15 to 343.15) K and at atmospheric pressure. Experimental data were employed to calculate some derived thermodynamic parameters, i.e. excess molar volumes (V-E), viscosity deviations (Delta eta.) and deviations in refractive index (.nD). Additionally, molar excess Gibbs free energies of activation of viscous flow (Delta G*(E)) and deviations in isentropic compressibility (Delta kappa(s)) were calculated. A graphical representation of excess molar volumes and refractive indices show positive deviation from ideal behavior for both binary systems whereas deviation in viscosity shows negative nature for the ethyl oleate + n-hexadecane system and an inversion sign for ethyl oleate +1-butanol binary system. A negative deviation in isentropic compressibility was confirmed for the systems ethyl oleate +1-butanol while positive deviation was observed in ethyl oleate + n-hexadecane system. It can be concluded that dispersive forces predominate between the components in binary systems and the observed behavior seems to suggest that the properties obtained for the ternary mixture are dominated by the binary effects. The viscosities of the binary systems were modeled by UNIFAC-VISCO, ASOG-VISCO, Teja-Rice and McAllister models. The results showed that McAllister's multibodymodel is suitable to describe viscosities for binary systemswithmaximumpercentage deviations less than 0.5%.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Molecular Liquids",
title = "Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure",
volume = "317",
doi = "10.1016/j.molliq.2020.114186"
}
Aissa, M. A., Radović, I., Simić, Z. V.,& Kijevčanin, M.. (2020). Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure. in Journal of Molecular Liquids
Elsevier, Amsterdam., 317.
https://doi.org/10.1016/j.molliq.2020.114186
Aissa MA, Radović I, Simić ZV, Kijevčanin M. Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure. in Journal of Molecular Liquids. 2020;317.
doi:10.1016/j.molliq.2020.114186 .
Aissa, Mohamed A., Radović, Ivona, Simić, Zoran V., Kijevčanin, Mirjana, "Thermodynamic and transport properties of ternary mixture (ethyl oleate plus n-hexadecane+1-butanol) and its binary constituents (ethyl oleate+1-butanol and ethyl oleate plus n-hexadecane) at different temperatures and atmospheric pressure" in Journal of Molecular Liquids, 317 (2020),
https://doi.org/10.1016/j.molliq.2020.114186 . .
7
8

Primena instrumentalnih metoda na analizu uzoraka vode

Simić, Zoran

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku, 2019)

TY  - CONF
AU  - Simić, Zoran
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7390
AB  - Zagađenje vode je veliki problem čovečanstva. Kako bi se sprečila kontaminacija vodenih
sistema neophodno je kontrolisati količinu zagađujućih materija u njima i ispoštovati uredbe o graničnim vrednostima takvih polutanata za različite vrste voda. Primenom određenih instrumentalnih
metoda, kao što su hromatografija , spektrofotometrija i druge, moguće je analizirati uzorke vode i
odrediti tačnu koncentraciju zagađujućih materija u njima i na taj način sprečiti kontaminaciju vodenih tokova ili ispitati kvalitet i sastav vode. U ovom radu su navedeni analiti, prema pravilniku o
graničnim vrednostima, kojima je potrebno odrediti koncentraciju u uzorcima vode i objašnjeno je
kojim instrumentalnim tehnikama i na koji način se mogu analizirati specifčni realni uzorci različitih
tipova vode.
AB  - Water pollution is a major problem for mankind. In order to prevent contamination of aquatic systems, it is necessary to control the amount of pollutants in them and to comply with the regulations on the limit values for such pollutants in the different types of water. By using certain instrumental methods, such as chromatography, spectrophotometry and others, it is possible to analyze water samples and determine the exact concentration of pollutants in them, thus preventing water contamination or checking the quality and composition of water. In this paper, analytics which need to determine the concentration in water samples are given, according to the regulations on limit values and is explained by which instrumental techniques and how the specific real samples of different types of water can be analyzed.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova = Proceedings / 32. međunarodni kongres o procesnoj industriji, PROCESING '19, Beograd, 30. i 31. maj 2019
T1  - Primena instrumentalnih metoda na analizu uzoraka vode
T1  - Application of instrumental methods in analysis of water samples
SP  - 307
VL  - 314
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7390
ER  - 
@conference{
author = "Simić, Zoran",
year = "2019",
abstract = "Zagađenje vode je veliki problem čovečanstva. Kako bi se sprečila kontaminacija vodenih
sistema neophodno je kontrolisati količinu zagađujućih materija u njima i ispoštovati uredbe o graničnim vrednostima takvih polutanata za različite vrste voda. Primenom određenih instrumentalnih
metoda, kao što su hromatografija , spektrofotometrija i druge, moguće je analizirati uzorke vode i
odrediti tačnu koncentraciju zagađujućih materija u njima i na taj način sprečiti kontaminaciju vodenih tokova ili ispitati kvalitet i sastav vode. U ovom radu su navedeni analiti, prema pravilniku o
graničnim vrednostima, kojima je potrebno odrediti koncentraciju u uzorcima vode i objašnjeno je
kojim instrumentalnim tehnikama i na koji način se mogu analizirati specifčni realni uzorci različitih
tipova vode., Water pollution is a major problem for mankind. In order to prevent contamination of aquatic systems, it is necessary to control the amount of pollutants in them and to comply with the regulations on the limit values for such pollutants in the different types of water. By using certain instrumental methods, such as chromatography, spectrophotometry and others, it is possible to analyze water samples and determine the exact concentration of pollutants in them, thus preventing water contamination or checking the quality and composition of water. In this paper, analytics which need to determine the concentration in water samples are given, according to the regulations on limit values and is explained by which instrumental techniques and how the specific real samples of different types of water can be analyzed.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova = Proceedings / 32. međunarodni kongres o procesnoj industriji, PROCESING '19, Beograd, 30. i 31. maj 2019",
title = "Primena instrumentalnih metoda na analizu uzoraka vode, Application of instrumental methods in analysis of water samples",
pages = "307",
volume = "314",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7390"
}
Simić, Z.. (2019). Primena instrumentalnih metoda na analizu uzoraka vode. in Zbornik radova = Proceedings / 32. međunarodni kongres o procesnoj industriji, PROCESING '19, Beograd, 30. i 31. maj 2019
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 314, 307.
https://hdl.handle.net/21.15107/rcub_technorep_7390
Simić Z. Primena instrumentalnih metoda na analizu uzoraka vode. in Zbornik radova = Proceedings / 32. međunarodni kongres o procesnoj industriji, PROCESING '19, Beograd, 30. i 31. maj 2019. 2019;314:307.
https://hdl.handle.net/21.15107/rcub_technorep_7390 .
Simić, Zoran, "Primena instrumentalnih metoda na analizu uzoraka vode" in Zbornik radova = Proceedings / 32. međunarodni kongres o procesnoj industriji, PROCESING '19, Beograd, 30. i 31. maj 2019, 314 (2019):307,
https://hdl.handle.net/21.15107/rcub_technorep_7390 .