TY  - JOUR
AU  - Nikolić, Svetlana
AU  - Vujačić, Vesna
AU  - Vidović, Milka
AU  - Mojović, Ljiljana
AU  - Nikolić, Branislav
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2943
AB  - The river Veliki Lug originates under the Kosmaj, flows through the municipalities and settlements Sopot and Mladenovac, and flows into the river Kubršnica near village Ratari in the Smederevska Palanka municipality. Waters of the river Veliki Lug are polluted by industrial and sanitary waste waters as well as waters from many landfills at the coastal area. Before Mladenovac the waters of river Veliki Lug belong to the II water class, but after Mladenovac they belong to the IV water class. It is necessary to construct treatment plants for waste waters and sewer systems and also to remediate landfills at the coastal area.
AB  - Reka Veliki Lug izvire ispod Kosmaja, protiče kroz opštine i naselja Sopot i Mladenovac, a uliva se u Kubršnicu kod sela Ratari u opštini Smederevska Palanka. Vode reke Veliki Lug zagađuju se industrijskim i komunalnim otpadnim vodama kao i ocednim vodama sa brojnih deponija na priobalju. Pre Mladenovca vode ove reke pripadaju II klasi, ali posle Mladenovca već IV klasi voda. Neminovna je realizacija izgradnje postrojenja za prečišćavanje svih otpadnih voda, kanalizacionih sistema i saniranje deponija na priobalju, u skladu sa zakonskim regulativama.
PB  - Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd
T2  - Ecologica
T1  - The quality of the Veliki Lug river from Mladenovac to the mouth in Kubršnica in the municipality of Smederevska palanka
T1  - Kvalitet vode reke Veliki Lug posle Mladenovca do ušća u Kubršnicu na teritoriji opštine Smederevska palanka
EP  - 178
IS  - 78
SP  - 175
VL  - 22
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2943
ER  - 

@article{
author = "Nikolić, Svetlana and Vujačić, Vesna and Vidović, Milka and Mojović, Ljiljana and Nikolić, Branislav",
year = "2015",
abstract = "The river Veliki Lug originates under the Kosmaj, flows through the municipalities and settlements Sopot and Mladenovac, and flows into the river Kubršnica near village Ratari in the Smederevska Palanka municipality. Waters of the river Veliki Lug are polluted by industrial and sanitary waste waters as well as waters from many landfills at the coastal area. Before Mladenovac the waters of river Veliki Lug belong to the II water class, but after Mladenovac they belong to the IV water class. It is necessary to construct treatment plants for waste waters and sewer systems and also to remediate landfills at the coastal area., Reka Veliki Lug izvire ispod Kosmaja, protiče kroz opštine i naselja Sopot i Mladenovac, a uliva se u Kubršnicu kod sela Ratari u opštini Smederevska Palanka. Vode reke Veliki Lug zagađuju se industrijskim i komunalnim otpadnim vodama kao i ocednim vodama sa brojnih deponija na priobalju. Pre Mladenovca vode ove reke pripadaju II klasi, ali posle Mladenovca već IV klasi voda. Neminovna je realizacija izgradnje postrojenja za prečišćavanje svih otpadnih voda, kanalizacionih sistema i saniranje deponija na priobalju, u skladu sa zakonskim regulativama.",
publisher = "Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd",
journal = "Ecologica",
title = "The quality of the Veliki Lug river from Mladenovac to the mouth in Kubršnica in the municipality of Smederevska palanka, Kvalitet vode reke Veliki Lug posle Mladenovca do ušća u Kubršnicu na teritoriji opštine Smederevska palanka",
pages = "178-175",
number = "78",
volume = "22",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2943"
}

Nikolić, S., Vujačić, V., Vidović, M., Mojović, L.,& Nikolić, B.. (2015). The quality of the Veliki Lug river from Mladenovac to the mouth in Kubršnica in the municipality of Smederevska palanka. in Ecologica
Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd., 22(78), 175-178.
https://hdl.handle.net/21.15107/rcub_technorep_2943

Nikolić S, Vujačić V, Vidović M, Mojović L, Nikolić B. The quality of the Veliki Lug river from Mladenovac to the mouth in Kubršnica in the municipality of Smederevska palanka. in Ecologica. 2015;22(78):175-178.
https://hdl.handle.net/21.15107/rcub_technorep_2943 .

Nikolić, Svetlana, Vujačić, Vesna, Vidović, Milka, Mojović, Ljiljana, Nikolić, Branislav, "The quality of the Veliki Lug river from Mladenovac to the mouth in Kubršnica in the municipality of Smederevska palanka" in Ecologica, 22, no. 78 (2015):175-178,
https://hdl.handle.net/21.15107/rcub_technorep_2943 .

TY  - JOUR
AU  - Nikolić, Branislav
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Marinković, Dalibor
AU  - Popović, Zoran
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2026
AB  - In the process of refining raw materials and metal production in the metallurgical industry and mining are allocated a number of different secondary materials to be deposited. In the enrichment of the ore by flotation, in addition to metals concentrate, flotation tailings are allocated, which is stored in permanent landfill. When solving the problems of processing of deposited material, landfill rehabilitation and revitalization of the affected land should be accounted more related effects in defining the feasibility of investment projects.
AB  - U procesima prerade sirovina i proizvodnje metala izdvaja se više različitih materijala koji se deponuju. Pri obogaćivanju ruda u flotacijama, pored koncentrata metala, izdvaja se i otpadna flotaciona jalovina koja se skladišti na trajne deponije. Pri rešavanju problematike prerade deponovanih materijala, saniranja deponija i revitalizacije zemljišta trebalo bi obračunati i više pratećih efekata pri definisanju opravdanosti investicionih radova.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Following the ecological and economic effects of mining and metallurgical landfills
T1  - Prateći ekološko-ekonomski efekti metalurških i rudarskih deponija
EP  - 60
IS  - 1
SP  - 57
VL  - 67
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2026
ER  - 

@article{
author = "Nikolić, Branislav and Nikolić, Vesna and Kamberović, Željko and Marinković, Dalibor and Popović, Zoran",
year = "2012",
abstract = "In the process of refining raw materials and metal production in the metallurgical industry and mining are allocated a number of different secondary materials to be deposited. In the enrichment of the ore by flotation, in addition to metals concentrate, flotation tailings are allocated, which is stored in permanent landfill. When solving the problems of processing of deposited material, landfill rehabilitation and revitalization of the affected land should be accounted more related effects in defining the feasibility of investment projects., U procesima prerade sirovina i proizvodnje metala izdvaja se više različitih materijala koji se deponuju. Pri obogaćivanju ruda u flotacijama, pored koncentrata metala, izdvaja se i otpadna flotaciona jalovina koja se skladišti na trajne deponije. Pri rešavanju problematike prerade deponovanih materijala, saniranja deponija i revitalizacije zemljišta trebalo bi obračunati i više pratećih efekata pri definisanju opravdanosti investicionih radova.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Following the ecological and economic effects of mining and metallurgical landfills, Prateći ekološko-ekonomski efekti metalurških i rudarskih deponija",
pages = "60-57",
number = "1",
volume = "67",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2026"
}

Nikolić, B., Nikolić, V., Kamberović, Ž., Marinković, D.,& Popović, Z.. (2012). Following the ecological and economic effects of mining and metallurgical landfills. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 67(1), 57-60.
https://hdl.handle.net/21.15107/rcub_technorep_2026

Nikolić B, Nikolić V, Kamberović Ž, Marinković D, Popović Z. Following the ecological and economic effects of mining and metallurgical landfills. in Tehnika. 2012;67(1):57-60.
https://hdl.handle.net/21.15107/rcub_technorep_2026 .

Nikolić, Branislav, Nikolić, Vesna, Kamberović, Željko, Marinković, Dalibor, Popović, Zoran, "Following the ecological and economic effects of mining and metallurgical landfills" in Tehnika, 67, no. 1 (2012):57-60,
https://hdl.handle.net/21.15107/rcub_technorep_2026 .

TY  - JOUR
AU  - Nikolić, Svetlana
AU  - Mojović, Ljiljana
AU  - Nikolić, Branislav
AU  - Sekulić, Ljubomir
AU  - Milovanović, Dragana
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1793
AB  - Analysis of water quality of the rivers Veliki Lug and Kubršnica, in the area after the bridge for Jagnjilo ie. after the territory of Mladenovac municipality till its flow into the river Jasenica on the territory of Smederevska Palanka municipality, was done in the period September-November 2010. The water samples were taken and analyzed on four measuring points along the river flow. Physicochemical analysis showed that waters of these rivers belong to IV water class on all four measuring points. The concentration of some parameters such as: nitrites, ammonium ion, phosphates, KMnO4 consumption, oxygen, COD, BOD5 and iron exceeded the maximum permissible concentration even for IV water class on some measuring points. Results of microbiological analysis showed that the Most Probable Number (MPN) in 1 l was 240,000 on all measuring points which classify these waters into IV water class, except in November when the MPN decreased to 96,000 which corresponds to II water class. Also, identified pathogen bacteria indicate dominant fecal contamination from households and agricultural farms.
AB  - U periodu septembar-novembar 2010. godine izvršeno je ispitivanje kvaliteta vode reka Veliki Lug i Kubršnica, u delu posle mosta za Jagnjilo tj. posle teritorije opštine Mladenovac do ušća u Jasenicu, na teritoriji opštine Smederevska Palanka. Izvršene su fizičko-hemijske i mikrobiološke analize uzoraka vode na četiri merna mesta duž rečnog toka. Fizičko-hemijske analize pokazale su da vode ovih reka na sva četiri mesta pripadaju IV klasi boniteta. Na pojedinim mernim mestima, vrednosti fizičko-hemijskih parametara kao što su: nitriti, amonijum jon, fosfati, utrošak KMnO4, rastvoreni kiseonik, HPK, BPK5 i gvožđe, su bile iznad maksimalno dozvoljenih vrednosti (MDK) čak i za IV klasu voda. Rezultati mikrobioloških analiza pokazuju da je na svim mernim mestima najverovatniji broj koliformnih bakterija (MPN) u 1l iznosio 240.000 što svrstava ove vode u IV klasu boniteta, osim u novembru kada je taj broj opao na 96.000 što odgovara II klasi boniteta. Takođe, identifikovane patogene bakterijske vrste ukazuju na dominantno fekalno zagađenje domaćinstava i poljoprivrednih farmi.
PB  - Jugoslovensko društvo za odvodnjavanje i navodnjavanje, Beograd
T2  - Vodoprivreda
T1  - Pollutants and the quality of rivers Veliki Lug and Kubršnica on the territory of Smederevska Palanka municipality
T1  - Zagađivači i kvalitet vode reka Veliki Lug i Kubršnica na teritoriji opštine Smederevska Palanka
EP  - 265
IS  - 4-6
SP  - 259
VL  - 43
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1793
ER  - 

@article{
author = "Nikolić, Svetlana and Mojović, Ljiljana and Nikolić, Branislav and Sekulić, Ljubomir and Milovanović, Dragana",
year = "2011",
abstract = "Analysis of water quality of the rivers Veliki Lug and Kubršnica, in the area after the bridge for Jagnjilo ie. after the territory of Mladenovac municipality till its flow into the river Jasenica on the territory of Smederevska Palanka municipality, was done in the period September-November 2010. The water samples were taken and analyzed on four measuring points along the river flow. Physicochemical analysis showed that waters of these rivers belong to IV water class on all four measuring points. The concentration of some parameters such as: nitrites, ammonium ion, phosphates, KMnO4 consumption, oxygen, COD, BOD5 and iron exceeded the maximum permissible concentration even for IV water class on some measuring points. Results of microbiological analysis showed that the Most Probable Number (MPN) in 1 l was 240,000 on all measuring points which classify these waters into IV water class, except in November when the MPN decreased to 96,000 which corresponds to II water class. Also, identified pathogen bacteria indicate dominant fecal contamination from households and agricultural farms., U periodu septembar-novembar 2010. godine izvršeno je ispitivanje kvaliteta vode reka Veliki Lug i Kubršnica, u delu posle mosta za Jagnjilo tj. posle teritorije opštine Mladenovac do ušća u Jasenicu, na teritoriji opštine Smederevska Palanka. Izvršene su fizičko-hemijske i mikrobiološke analize uzoraka vode na četiri merna mesta duž rečnog toka. Fizičko-hemijske analize pokazale su da vode ovih reka na sva četiri mesta pripadaju IV klasi boniteta. Na pojedinim mernim mestima, vrednosti fizičko-hemijskih parametara kao što su: nitriti, amonijum jon, fosfati, utrošak KMnO4, rastvoreni kiseonik, HPK, BPK5 i gvožđe, su bile iznad maksimalno dozvoljenih vrednosti (MDK) čak i za IV klasu voda. Rezultati mikrobioloških analiza pokazuju da je na svim mernim mestima najverovatniji broj koliformnih bakterija (MPN) u 1l iznosio 240.000 što svrstava ove vode u IV klasu boniteta, osim u novembru kada je taj broj opao na 96.000 što odgovara II klasi boniteta. Takođe, identifikovane patogene bakterijske vrste ukazuju na dominantno fekalno zagađenje domaćinstava i poljoprivrednih farmi.",
publisher = "Jugoslovensko društvo za odvodnjavanje i navodnjavanje, Beograd",
journal = "Vodoprivreda",
title = "Pollutants and the quality of rivers Veliki Lug and Kubršnica on the territory of Smederevska Palanka municipality, Zagađivači i kvalitet vode reka Veliki Lug i Kubršnica na teritoriji opštine Smederevska Palanka",
pages = "265-259",
number = "4-6",
volume = "43",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1793"
}

Nikolić, S., Mojović, L., Nikolić, B., Sekulić, L.,& Milovanović, D.. (2011). Pollutants and the quality of rivers Veliki Lug and Kubršnica on the territory of Smederevska Palanka municipality. in Vodoprivreda
Jugoslovensko društvo za odvodnjavanje i navodnjavanje, Beograd., 43(4-6), 259-265.
https://hdl.handle.net/21.15107/rcub_technorep_1793

Nikolić S, Mojović L, Nikolić B, Sekulić L, Milovanović D. Pollutants and the quality of rivers Veliki Lug and Kubršnica on the territory of Smederevska Palanka municipality. in Vodoprivreda. 2011;43(4-6):259-265.
https://hdl.handle.net/21.15107/rcub_technorep_1793 .

Nikolić, Svetlana, Mojović, Ljiljana, Nikolić, Branislav, Sekulić, Ljubomir, Milovanović, Dragana, "Pollutants and the quality of rivers Veliki Lug and Kubršnica on the territory of Smederevska Palanka municipality" in Vodoprivreda, 43, no. 4-6 (2011):259-265,
https://hdl.handle.net/21.15107/rcub_technorep_1793 .

TY  - CONF
AU  - Jovanović, Željka
AU  - Panić, Vladimir
AU  - Nikolić, Branislav
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1557
AB  - The potential use of Ag/poly(N-vinyl-2-pyrrolidone) (PVP) nanocomposites is in wound dressings or soft tissue implants, where Ag nanoparticles (AgNPs) serve as the antimicrobial agent. Ag/PVP nanocomposites were electrochemically synthesized, by the electrochemical reduction of Ag+ ions into the AgNPs in the PVP aqueous solution and within the crosslinked PVP matrix, forming the non-crosslinked and crosslinked Ag/PVP nanocomposite, respectively. The synthesis of AgNPs was performed in an electrochemical cell with Pt working and counter electrodes and the saturated calomel electrode (SCE) as the reference. The non-crosslinked Ag/PVP nanocomposite was obtained by galvanostatic reduction of Ag+ ions from the aqueous solution consisted of 0.10 M KNO3, 3.9 mM AgNO3 and 10 wt. % PVP. The crosslinked Ag/PVP nanocomposite was obtained by in situ potentiostatic reduction of Ag+ ions within PVP hydrogel, previously prepared by -irradiation of the 10 wt. % PVP aqueous solution. Hydrogels were swollen in two different aqueous solutions ((a) 3.9 mM AgNO3, (b) 3.9 mM AgNO3 + 0.10 M KNO3) for 24 h. Ag/PVP nanocomposite systems were characterized by UV-Vis spectroscopy, FTIR, TEM, XRD, Z-sizer analysis and cyclic voltammetry.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
T1  - The electrochemical synthesis of different Ag/PVP nanocomposites
EP  - 155
SP  - 155
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1557
ER  - 

@conference{
author = "Jovanović, Željka and Panić, Vladimir and Nikolić, Branislav and Mišković-Stanković, Vesna",
year = "2010",
abstract = "The potential use of Ag/poly(N-vinyl-2-pyrrolidone) (PVP) nanocomposites is in wound dressings or soft tissue implants, where Ag nanoparticles (AgNPs) serve as the antimicrobial agent. Ag/PVP nanocomposites were electrochemically synthesized, by the electrochemical reduction of Ag+ ions into the AgNPs in the PVP aqueous solution and within the crosslinked PVP matrix, forming the non-crosslinked and crosslinked Ag/PVP nanocomposite, respectively. The synthesis of AgNPs was performed in an electrochemical cell with Pt working and counter electrodes and the saturated calomel electrode (SCE) as the reference. The non-crosslinked Ag/PVP nanocomposite was obtained by galvanostatic reduction of Ag+ ions from the aqueous solution consisted of 0.10 M KNO3, 3.9 mM AgNO3 and 10 wt. % PVP. The crosslinked Ag/PVP nanocomposite was obtained by in situ potentiostatic reduction of Ag+ ions within PVP hydrogel, previously prepared by -irradiation of the 10 wt. % PVP aqueous solution. Hydrogels were swollen in two different aqueous solutions ((a) 3.9 mM AgNO3, (b) 3.9 mM AgNO3 + 0.10 M KNO3) for 24 h. Ag/PVP nanocomposite systems were characterized by UV-Vis spectroscopy, FTIR, TEM, XRD, Z-sizer analysis and cyclic voltammetry.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra",
title = "The electrochemical synthesis of different Ag/PVP nanocomposites",
pages = "155-155",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1557"
}

Jovanović, Ž., Panić, V., Nikolić, B.,& Mišković-Stanković, V.. (2010). The electrochemical synthesis of different Ag/PVP nanocomposites. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
Serbian Chemical Society, Belgrade., 155-155.
https://hdl.handle.net/21.15107/rcub_technorep_1557

Jovanović Ž, Panić V, Nikolić B, Mišković-Stanković V. The electrochemical synthesis of different Ag/PVP nanocomposites. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra. 2010;:155-155.
https://hdl.handle.net/21.15107/rcub_technorep_1557 .

Jovanović, Željka, Panić, Vladimir, Nikolić, Branislav, Mišković-Stanković, Vesna, "The electrochemical synthesis of different Ag/PVP nanocomposites" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra (2010):155-155,
https://hdl.handle.net/21.15107/rcub_technorep_1557 .

TY  - CONF
AU  - Panić, Vladimir
AU  - Mišković-Stanković, Vesna
AU  - Jovanović, Branislav
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1555
AB  - Titanium oxide is applied as a photocatalyst in organic synthesis and for waste water treatment and outdoor air purification. In this work, photoelectrochemical (PEC) activity of titanium oxide coating on titanium substrate, prepared by the sol–gel procedure from the oxide sol obtained by forced hydrolysis of chloride was investigated. Electrochemical and PEC parameters at photoelectrode change intensively upon UV illumination when organic compounds (alcohols, aldehydes, acids, etc.) are present in the electrolyte (H2SO4), which proves coating activity for their oxidation. Electrochemical impedance (EIS) characteristics of the coating are found to be sensitive to the photoelectrode potential and UV light. EIS characteristics are discussed on the basis of the values of parameters of equivalent electrical circuit used to fit experimental impedance data.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
T1  - Photovoltaics of sol-gel processed titanium oxide coating
EP  - 88
SP  - 88
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1555
ER  - 

@conference{
author = "Panić, Vladimir and Mišković-Stanković, Vesna and Jovanović, Branislav and Milonjić, Slobodan K. and Nikolić, Branislav",
year = "2010",
abstract = "Titanium oxide is applied as a photocatalyst in organic synthesis and for waste water treatment and outdoor air purification. In this work, photoelectrochemical (PEC) activity of titanium oxide coating on titanium substrate, prepared by the sol–gel procedure from the oxide sol obtained by forced hydrolysis of chloride was investigated. Electrochemical and PEC parameters at photoelectrode change intensively upon UV illumination when organic compounds (alcohols, aldehydes, acids, etc.) are present in the electrolyte (H2SO4), which proves coating activity for their oxidation. Electrochemical impedance (EIS) characteristics of the coating are found to be sensitive to the photoelectrode potential and UV light. EIS characteristics are discussed on the basis of the values of parameters of equivalent electrical circuit used to fit experimental impedance data.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra",
title = "Photovoltaics of sol-gel processed titanium oxide coating",
pages = "88-88",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1555"
}

Panić, V., Mišković-Stanković, V., Jovanović, B., Milonjić, S. K.,& Nikolić, B.. (2010). Photovoltaics of sol-gel processed titanium oxide coating. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra
Serbian Chemical Society, Belgrade., 88-88.
https://hdl.handle.net/21.15107/rcub_technorep_1555

Panić V, Mišković-Stanković V, Jovanović B, Milonjić SK, Nikolić B. Photovoltaics of sol-gel processed titanium oxide coating. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra. 2010;:88-88.
https://hdl.handle.net/21.15107/rcub_technorep_1555 .

Panić, Vladimir, Mišković-Stanković, Vesna, Jovanović, Branislav, Milonjić, Slobodan K., Nikolić, Branislav, "Photovoltaics of sol-gel processed titanium oxide coating" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstra (2010):88-88,
https://hdl.handle.net/21.15107/rcub_technorep_1555 .

TY  - CONF
AU  - Jovanović, Željka
AU  - Panić, Vladimir
AU  - Krklješ, Aleksandra
AU  - Kačarević-Popović, Zorica M.
AU  - Nikolić, Branislav
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1554
AB  - Hydrogel nanocomposites of silver nanoparticles (AgNPs) and crosslinked poly(N-vinyl-2-pyrrolidone) (PVP) were synthesized in situ by a novel electrochemical method. PVPhydrogels, crosslinked by gamma-irradiation, were swollen in the solution containing0.1 M KNO3 and 3.9 mM AgNO3. PVP polymer matrix nanocavities were used asnanoreactors for AgNPs synthesis. The reduction of silver cations was performed usingtwo-Pt-electrode electrochemical cell. The polarity of the electrodes was changed on thehalf of the implementation time, enabling the Ag+ ions reduction in the bulk. Cyclicvoltammetry (CV) was performed in a three-electrode electrochemical cell, using thesaturated calomel electrode (SCE) as a reference. Ag/PVP nanocomposites werescanned by CV immediately after the synthesis and after drying followed by reswelling in0.1 M KNO3. Ag/PVP was compared with CVs of the following systems: Pt electrode in0.1 M KNO3; Pt/PVP system in 0.1 M KNO3; Ag/Pt system in 0.1 M KNO3 + 3.9 mMAgNO3 solution.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
T1  - Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite
EP  - 32
SP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1554
ER  - 

@conference{
author = "Jovanović, Željka and Panić, Vladimir and Krklješ, Aleksandra and Kačarević-Popović, Zorica M. and Nikolić, Branislav and Mišković-Stanković, Vesna",
year = "2010",
abstract = "Hydrogel nanocomposites of silver nanoparticles (AgNPs) and crosslinked poly(N-vinyl-2-pyrrolidone) (PVP) were synthesized in situ by a novel electrochemical method. PVPhydrogels, crosslinked by gamma-irradiation, were swollen in the solution containing0.1 M KNO3 and 3.9 mM AgNO3. PVP polymer matrix nanocavities were used asnanoreactors for AgNPs synthesis. The reduction of silver cations was performed usingtwo-Pt-electrode electrochemical cell. The polarity of the electrodes was changed on thehalf of the implementation time, enabling the Ag+ ions reduction in the bulk. Cyclicvoltammetry (CV) was performed in a three-electrode electrochemical cell, using thesaturated calomel electrode (SCE) as a reference. Ag/PVP nanocomposites werescanned by CV immediately after the synthesis and after drying followed by reswelling in0.1 M KNO3. Ag/PVP was compared with CVs of the following systems: Pt electrode in0.1 M KNO3; Pt/PVP system in 0.1 M KNO3; Ag/Pt system in 0.1 M KNO3 + 3.9 mMAgNO3 solution.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings",
title = "Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite",
pages = "32-29",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1554"
}

Jovanović, Ž., Panić, V., Krklješ, A., Kačarević-Popović, Z. M., Nikolić, B.,& Mišković-Stanković, V.. (2010). Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
Serbian Chemical Society, Belgrade., 29-32.
https://hdl.handle.net/21.15107/rcub_technorep_1554

Jovanović Ž, Panić V, Krklješ A, Kačarević-Popović ZM, Nikolić B, Mišković-Stanković V. Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings. 2010;:29-32.
https://hdl.handle.net/21.15107/rcub_technorep_1554 .

Jovanović, Željka, Panić, Vladimir, Krklješ, Aleksandra, Kačarević-Popović, Zorica M., Nikolić, Branislav, Mišković-Stanković, Vesna, "Cyclic voltammetry study of electrochemically synthesized Ag/PVP nanocomposite" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings (2010):29-32,
https://hdl.handle.net/21.15107/rcub_technorep_1554 .

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Nikolić, Branislav
AU  - Barać, Milan
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1370
AB  - Besides lead as basic metal, flotation lead concentrates contain several accompanied metals, such as: copper, zinc, iron, antimony, silver, gold, bismuth and arsenic. Raw lead and slag are obtained by agglomeration roasting of concentrates and then reduction smelting of agglomerates in blust furnaces. Iron and zinc go from concentrates to the blust furnaces slag and copper, antimony, silver, gold, bismuth and arsenic mostly pass into raw lead which will be refined later. The process of raw lead refining consists of the following steps: - copper is separated from lead by the effect of sulphur and copper drosses are obtained, - antimony and arsenic are separated by the effect of caustic soda and saltpeter and alkali As-Sb drosses are obtained, - silver, gold and bismuth are separated from lead by special treatments in which alkali deposits are not formed. Copper drosses are refined by alkali treatment in reverberatory furnaces and raw lead, Pb-Cu matte and speiss are obtained, as well as waste slag which goes to the deposit. As-Sb drosses are refined in short drum furnaces and raw lead and Pb-Sb alloy are obtained, as well as waste slag which goes to the deposits. Waste alkali-lead slags which deposit in the direct vicinity of Ibar, contain the following components: - small particle of lead and antimony, as well as oxide of these metals, - sodium, arsenic and bismuth oxides, - copper, sodium and lead sulfides. Reverberatory furnaces slags contain: 8-16% Pb, 5-15% Na, 10-15% Cu, and short drum furnaces slags contain: 1-5% Pb, 20-28% Na, 1-5% Sb, 1-4% As. Both these slags are hygroscopic, they decompose gradually, spill and pollute the waters of Ibar through surface waters during rainfall. The solution of the problems of these slags lies in more technological-ecological and investment-developing proceedings and that is necessary in keeping with law regulations. .
AB  - Pored olova kao osnovnog metala, flotacioni koncentrati olova sadrže više pratećih metala od kojih su značajni sledeći: bakar, cink, železo, antimon, srebro, zlato, bizmut i arsen. Aglomeracionim prženjem koncentrata, a zatim redukcionim topljenjem aglomerata u šahtnim pećima, dobija se sirovo olovo i šljaka. Železo i cink iz koncentrata prelaze u šljaku šahtnih peći koja se deponuje, a bakar, antimon, srebro, zlato, bizmut i arsen, uglavnom prelaze u sirovo olovo, koje se zatim rafiniše. Rafinacija sirovog olova vrši se u više tehnoloških operacija, prema sledećem redosledu: - bakar se iz olova uklanja pomoću sumpora pri čemu se dobijaju bakarni šlikeri i prašine, - antimon i arsen se uklanjaju pomoću sode i šalitre pri čemu se dobijaju alkalni As-Sb šlikeri, - srebro, zlato i bizmut se uklanjaju iz olova specifičnim postupcima u kojima se ne izdvajaju alkalne deponije. Bakarni šlikeri se prerađuju alkalnim postupkom u plamenim pećima pri čemu se dobijaju sirovo olovo, Pb-Cu kamen i špajza, ali i otpadna šljaka koja se deponuje. As-Sb šliker se prerađuje u kratko-bubnjastim pećima pri čemu se dobijaju sirovo olovo, Pb-Sb legura i otpadna šljaka koja se deponuje. Otpadne alkalno-olovne šljake deponuju se u neposrednoj blizini Ibra, a sadrže sledeće: - sitne čestice metalnog olova i antimona, kao okside ovih metala, - okside natrijuma, arsena i bizmuta, - sulfide bakra, natrijuma i olova. Šljake plamenih peći sadrže: 8-16 % Pb, 5-15 % Na, 10-15 % Cu, a šljaka kratko-bubnjastih peći: 1-5 % Pb, 20-28 % Na, 1-5 % Sb, 1-4 % As. Obe šljake su higroskopne, vremenom se raspadaju, rasipaju, a pri atmosferski padavinama, preko površinskih voda, zagađuju vode Ibra. Rešenje problematike ovih šljaka sastoji iz više tehnološko-ekoloških investiciono-razvojnih zahvata, a što je neophodno u skladu sa zakonskim regulativama. .
PB  - Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd
T2  - Ecologica
T1  - Alkali-lead deposits of lead refinery 'Trepča' and their influence on Ibar's waters
T1  - Alkalno-olovne deponije rafinerije olova 'Trepča' i njihov uticaj na vode Ibra
EP  - 414
IS  - 55
SP  - 409
VL  - 16
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1370
ER  - 

@article{
author = "Nikolić, Vesna and Kamberović, Željko and Nikolić, Branislav and Barać, Milan",
year = "2009",
abstract = "Besides lead as basic metal, flotation lead concentrates contain several accompanied metals, such as: copper, zinc, iron, antimony, silver, gold, bismuth and arsenic. Raw lead and slag are obtained by agglomeration roasting of concentrates and then reduction smelting of agglomerates in blust furnaces. Iron and zinc go from concentrates to the blust furnaces slag and copper, antimony, silver, gold, bismuth and arsenic mostly pass into raw lead which will be refined later. The process of raw lead refining consists of the following steps: - copper is separated from lead by the effect of sulphur and copper drosses are obtained, - antimony and arsenic are separated by the effect of caustic soda and saltpeter and alkali As-Sb drosses are obtained, - silver, gold and bismuth are separated from lead by special treatments in which alkali deposits are not formed. Copper drosses are refined by alkali treatment in reverberatory furnaces and raw lead, Pb-Cu matte and speiss are obtained, as well as waste slag which goes to the deposit. As-Sb drosses are refined in short drum furnaces and raw lead and Pb-Sb alloy are obtained, as well as waste slag which goes to the deposits. Waste alkali-lead slags which deposit in the direct vicinity of Ibar, contain the following components: - small particle of lead and antimony, as well as oxide of these metals, - sodium, arsenic and bismuth oxides, - copper, sodium and lead sulfides. Reverberatory furnaces slags contain: 8-16% Pb, 5-15% Na, 10-15% Cu, and short drum furnaces slags contain: 1-5% Pb, 20-28% Na, 1-5% Sb, 1-4% As. Both these slags are hygroscopic, they decompose gradually, spill and pollute the waters of Ibar through surface waters during rainfall. The solution of the problems of these slags lies in more technological-ecological and investment-developing proceedings and that is necessary in keeping with law regulations. ., Pored olova kao osnovnog metala, flotacioni koncentrati olova sadrže više pratećih metala od kojih su značajni sledeći: bakar, cink, železo, antimon, srebro, zlato, bizmut i arsen. Aglomeracionim prženjem koncentrata, a zatim redukcionim topljenjem aglomerata u šahtnim pećima, dobija se sirovo olovo i šljaka. Železo i cink iz koncentrata prelaze u šljaku šahtnih peći koja se deponuje, a bakar, antimon, srebro, zlato, bizmut i arsen, uglavnom prelaze u sirovo olovo, koje se zatim rafiniše. Rafinacija sirovog olova vrši se u više tehnoloških operacija, prema sledećem redosledu: - bakar se iz olova uklanja pomoću sumpora pri čemu se dobijaju bakarni šlikeri i prašine, - antimon i arsen se uklanjaju pomoću sode i šalitre pri čemu se dobijaju alkalni As-Sb šlikeri, - srebro, zlato i bizmut se uklanjaju iz olova specifičnim postupcima u kojima se ne izdvajaju alkalne deponije. Bakarni šlikeri se prerađuju alkalnim postupkom u plamenim pećima pri čemu se dobijaju sirovo olovo, Pb-Cu kamen i špajza, ali i otpadna šljaka koja se deponuje. As-Sb šliker se prerađuje u kratko-bubnjastim pećima pri čemu se dobijaju sirovo olovo, Pb-Sb legura i otpadna šljaka koja se deponuje. Otpadne alkalno-olovne šljake deponuju se u neposrednoj blizini Ibra, a sadrže sledeće: - sitne čestice metalnog olova i antimona, kao okside ovih metala, - okside natrijuma, arsena i bizmuta, - sulfide bakra, natrijuma i olova. Šljake plamenih peći sadrže: 8-16 % Pb, 5-15 % Na, 10-15 % Cu, a šljaka kratko-bubnjastih peći: 1-5 % Pb, 20-28 % Na, 1-5 % Sb, 1-4 % As. Obe šljake su higroskopne, vremenom se raspadaju, rasipaju, a pri atmosferski padavinama, preko površinskih voda, zagađuju vode Ibra. Rešenje problematike ovih šljaka sastoji iz više tehnološko-ekoloških investiciono-razvojnih zahvata, a što je neophodno u skladu sa zakonskim regulativama. .",
publisher = "Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd",
journal = "Ecologica",
title = "Alkali-lead deposits of lead refinery 'Trepča' and their influence on Ibar's waters, Alkalno-olovne deponije rafinerije olova 'Trepča' i njihov uticaj na vode Ibra",
pages = "414-409",
number = "55",
volume = "16",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1370"
}

Nikolić, V., Kamberović, Ž., Nikolić, B.,& Barać, M.. (2009). Alkali-lead deposits of lead refinery 'Trepča' and their influence on Ibar's waters. in Ecologica
Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd., 16(55), 409-414.
https://hdl.handle.net/21.15107/rcub_technorep_1370

Nikolić V, Kamberović Ž, Nikolić B, Barać M. Alkali-lead deposits of lead refinery 'Trepča' and their influence on Ibar's waters. in Ecologica. 2009;16(55):409-414.
https://hdl.handle.net/21.15107/rcub_technorep_1370 .

Nikolić, Vesna, Kamberović, Željko, Nikolić, Branislav, Barać, Milan, "Alkali-lead deposits of lead refinery 'Trepča' and their influence on Ibar's waters" in Ecologica, 16, no. 55 (2009):409-414,
https://hdl.handle.net/21.15107/rcub_technorep_1370 .

TY  - JOUR
AU  - Nikolić, Branislav
AU  - Živković, Dragana
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1073
AB  - Lead ores and concentrates always have significant content of silver and copper. During the process of lead bullion refining these two metals are separated and concentrated into the intermediates which have special technological treatments of processing. Copper intermediates always have high content of silver, therefore the value of present silver effects on techno-economic justification of processing certain copper intermediate. The value of commercial silver and copper products significantly effects on financial affairs of lead Refinery and Smeltery.
AB  - Rude i koncentrati olova uvek imaju značajan sadržaj srebra i bakra, a u procesu rafinacije sirovog olova ova dva metala se izdvajaju i koncentrišu u međuprodukte koji imaju specifične tehnološke postupke prerade. Međuprodukti bakra uvek imaju visok sadržaj srebra, pa vrednost prisutnog srebra često diriguje tehno-ekonomsku opravdanost procesa prerade konkretnog međuprodukta bakra. Vrednost komercijalnih proizvoda srebra i bakra bitno utiču na finansijsko poslovanje Topionice i Rafinerije olova.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika - Rudarstvo, geologija i metalurgija
T1  - Silver in copper intermediates of lead refinery 'Trepča'
T1  - Srebro u bakarnim međuproduktima rafinerije olova 'Trepča'
EP  - 5
IS  - 3
SP  - 1
VL  - 58
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1073
ER  - 

@article{
author = "Nikolić, Branislav and Živković, Dragana and Nikolić, Vesna and Kamberović, Željko",
year = "2007",
abstract = "Lead ores and concentrates always have significant content of silver and copper. During the process of lead bullion refining these two metals are separated and concentrated into the intermediates which have special technological treatments of processing. Copper intermediates always have high content of silver, therefore the value of present silver effects on techno-economic justification of processing certain copper intermediate. The value of commercial silver and copper products significantly effects on financial affairs of lead Refinery and Smeltery., Rude i koncentrati olova uvek imaju značajan sadržaj srebra i bakra, a u procesu rafinacije sirovog olova ova dva metala se izdvajaju i koncentrišu u međuprodukte koji imaju specifične tehnološke postupke prerade. Međuprodukti bakra uvek imaju visok sadržaj srebra, pa vrednost prisutnog srebra često diriguje tehno-ekonomsku opravdanost procesa prerade konkretnog međuprodukta bakra. Vrednost komercijalnih proizvoda srebra i bakra bitno utiču na finansijsko poslovanje Topionice i Rafinerije olova.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika - Rudarstvo, geologija i metalurgija",
title = "Silver in copper intermediates of lead refinery 'Trepča', Srebro u bakarnim međuproduktima rafinerije olova 'Trepča'",
pages = "5-1",
number = "3",
volume = "58",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1073"
}

Nikolić, B., Živković, D., Nikolić, V.,& Kamberović, Ž.. (2007). Silver in copper intermediates of lead refinery 'Trepča'. in Tehnika - Rudarstvo, geologija i metalurgija
Savez inženjera i tehničara Srbije, Beograd., 58(3), 1-5.
https://hdl.handle.net/21.15107/rcub_technorep_1073

Nikolić B, Živković D, Nikolić V, Kamberović Ž. Silver in copper intermediates of lead refinery 'Trepča'. in Tehnika - Rudarstvo, geologija i metalurgija. 2007;58(3):1-5.
https://hdl.handle.net/21.15107/rcub_technorep_1073 .

Nikolić, Branislav, Živković, Dragana, Nikolić, Vesna, Kamberović, Željko, "Silver in copper intermediates of lead refinery 'Trepča'" in Tehnika - Rudarstvo, geologija i metalurgija, 58, no. 3 (2007):1-5,
https://hdl.handle.net/21.15107/rcub_technorep_1073 .

TY  - JOUR
AU  - Nikolić, Branislav
AU  - Kamberović, Željko
AU  - Nikolić, Vesna
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/956
AB  - In Serbia there were several polimetal ores deposits from which silver was exploited during ancient times and middle ages. Large silver production in middle ages, during Nemanjić dynasty, contributed to development and power of Serbia. In that time Novo Brdo was one of the largest European cities. After the arrival of Turks and after many wars, exploitation of mines gradually was decreasing in Serbia, and at the beginning of XVIII century completely stopped.
AB  - U Srbiji ima više nalazišta polimetalnih ruda iz kojih se eksploatisalo srebro u starom i srednjem veku. Visoka proizvodnja srebra u srednjem veku, u doba dinastije Nemanjića, dosta je doprinela razvoju i moći tadašnje Srbije. U to vreme Novo Brdo je bio jedan od većih evropskih gradova. Nakon dolaska Turaka i čestih ratova, eksploatacija rudnika u Srbiji postepeno opada i početkom XVIII veka potpuno prestaje.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika - Rudarstvo, geologija i metalurgija
T1  - Silver in medieval Serbia
T1  - Srebro u srednjovekovnoj Srbiji
EP  - 18
IS  - 3
SP  - 15
VL  - 57
UR  - https://hdl.handle.net/21.15107/rcub_technorep_956
ER  - 

@article{
author = "Nikolić, Branislav and Kamberović, Željko and Nikolić, Vesna",
year = "2006",
abstract = "In Serbia there were several polimetal ores deposits from which silver was exploited during ancient times and middle ages. Large silver production in middle ages, during Nemanjić dynasty, contributed to development and power of Serbia. In that time Novo Brdo was one of the largest European cities. After the arrival of Turks and after many wars, exploitation of mines gradually was decreasing in Serbia, and at the beginning of XVIII century completely stopped., U Srbiji ima više nalazišta polimetalnih ruda iz kojih se eksploatisalo srebro u starom i srednjem veku. Visoka proizvodnja srebra u srednjem veku, u doba dinastije Nemanjića, dosta je doprinela razvoju i moći tadašnje Srbije. U to vreme Novo Brdo je bio jedan od većih evropskih gradova. Nakon dolaska Turaka i čestih ratova, eksploatacija rudnika u Srbiji postepeno opada i početkom XVIII veka potpuno prestaje.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika - Rudarstvo, geologija i metalurgija",
title = "Silver in medieval Serbia, Srebro u srednjovekovnoj Srbiji",
pages = "18-15",
number = "3",
volume = "57",
url = "https://hdl.handle.net/21.15107/rcub_technorep_956"
}

Nikolić, B., Kamberović, Ž.,& Nikolić, V.. (2006). Silver in medieval Serbia. in Tehnika - Rudarstvo, geologija i metalurgija
Savez inženjera i tehničara Srbije, Beograd., 57(3), 15-18.
https://hdl.handle.net/21.15107/rcub_technorep_956

Nikolić B, Kamberović Ž, Nikolić V. Silver in medieval Serbia. in Tehnika - Rudarstvo, geologija i metalurgija. 2006;57(3):15-18.
https://hdl.handle.net/21.15107/rcub_technorep_956 .

Nikolić, Branislav, Kamberović, Željko, Nikolić, Vesna, "Silver in medieval Serbia" in Tehnika - Rudarstvo, geologija i metalurgija, 57, no. 3 (2006):15-18,
https://hdl.handle.net/21.15107/rcub_technorep_956 .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, Branislav
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/946
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
AB  - Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
T1  - Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom
EP  - 1186
IS  - 11
SP  - 1173
VL  - 71
UR  - https://hdl.handle.net/21.15107/rcub_technorep_946
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, Branislav",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass., Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route, Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom",
pages = "1186-1173",
number = "11",
volume = "71",
url = "https://hdl.handle.net/21.15107/rcub_technorep_946"
}

Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 71(11), 1173-1186.
https://hdl.handle.net/21.15107/rcub_technorep_946

Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić B. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
https://hdl.handle.net/21.15107/rcub_technorep_946 .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, Branislav, "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://hdl.handle.net/21.15107/rcub_technorep_946 .

TY  - JOUR
AU  - Nikolić, Branislav
AU  - Sokić, Miroslav
AU  - Kamberović, Željko
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/743
AB  - From all the state-of-the-art technologies of processing lead concentrates industrial applications have found KIVCET CS and Boliden TBRC processes. In the paper, mentioned technological procedures are described with special accent on defining of smelting mechanism in KIVCET furnace. In bath cases smelting process is defined with ratic oxygen-concentrate, with which is determined content of lead in slag content of sulphur in bullion, distribution of side elements and amount of dust. Application of KIVCET CS and Boliden TBRC processes of processing of lead concentrates in industrial conditions confirmed their advantages comparing classical way of processing by reduction in shaft furnace.
AB  - Od savremenih postupaka prerade olovnih koncentrata značajniju industrijsku primenu su našli KIVCET CS i Boliden TBRC postupci. U ovom radu su opisani pomenuti tehnološki postupci, sa posebnim osvrtom na definisanje mehanizma topljenja u KIVCET peći. U oba slučaja je proces topljenja definisan odnosom kiseonik-koncentrat, čime je određen i sadržaj olova u šljaci, sadržaj sumpora u buljonu, distribucija sporednih elemenata i količina stvorene prašine. Primena KIVCET CS i Boliden TBRC postupaka prerade olovnih koncentrata u industrijskim uslovima je potvrdila njihove prednosti u odnosu na klasičan način prerade redukcionim topljenjem u šahtnoj peći.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika - Rudarstvo, geologija i metalurgija
T1  - KIVCET and Boliden TBRC technologies of processing of lead concentrates
T1  - KIVCET-CS i Boliden TBRC postupci prerade koncentrata olova
EP  - 20
IS  - 2
SP  - 13
VL  - 56
UR  - https://hdl.handle.net/21.15107/rcub_technorep_743
ER  - 

@article{
author = "Nikolić, Branislav and Sokić, Miroslav and Kamberović, Željko",
year = "2005",
abstract = "From all the state-of-the-art technologies of processing lead concentrates industrial applications have found KIVCET CS and Boliden TBRC processes. In the paper, mentioned technological procedures are described with special accent on defining of smelting mechanism in KIVCET furnace. In bath cases smelting process is defined with ratic oxygen-concentrate, with which is determined content of lead in slag content of sulphur in bullion, distribution of side elements and amount of dust. Application of KIVCET CS and Boliden TBRC processes of processing of lead concentrates in industrial conditions confirmed their advantages comparing classical way of processing by reduction in shaft furnace., Od savremenih postupaka prerade olovnih koncentrata značajniju industrijsku primenu su našli KIVCET CS i Boliden TBRC postupci. U ovom radu su opisani pomenuti tehnološki postupci, sa posebnim osvrtom na definisanje mehanizma topljenja u KIVCET peći. U oba slučaja je proces topljenja definisan odnosom kiseonik-koncentrat, čime je određen i sadržaj olova u šljaci, sadržaj sumpora u buljonu, distribucija sporednih elemenata i količina stvorene prašine. Primena KIVCET CS i Boliden TBRC postupaka prerade olovnih koncentrata u industrijskim uslovima je potvrdila njihove prednosti u odnosu na klasičan način prerade redukcionim topljenjem u šahtnoj peći.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika - Rudarstvo, geologija i metalurgija",
title = "KIVCET and Boliden TBRC technologies of processing of lead concentrates, KIVCET-CS i Boliden TBRC postupci prerade koncentrata olova",
pages = "20-13",
number = "2",
volume = "56",
url = "https://hdl.handle.net/21.15107/rcub_technorep_743"
}

Nikolić, B., Sokić, M.,& Kamberović, Ž.. (2005). KIVCET and Boliden TBRC technologies of processing of lead concentrates. in Tehnika - Rudarstvo, geologija i metalurgija
Savez inženjera i tehničara Srbije, Beograd., 56(2), 13-20.
https://hdl.handle.net/21.15107/rcub_technorep_743

Nikolić B, Sokić M, Kamberović Ž. KIVCET and Boliden TBRC technologies of processing of lead concentrates. in Tehnika - Rudarstvo, geologija i metalurgija. 2005;56(2):13-20.
https://hdl.handle.net/21.15107/rcub_technorep_743 .

Nikolić, Branislav, Sokić, Miroslav, Kamberović, Željko, "KIVCET and Boliden TBRC technologies of processing of lead concentrates" in Tehnika - Rudarstvo, geologija i metalurgija, 56, no. 2 (2005):13-20,
https://hdl.handle.net/21.15107/rcub_technorep_743 .

TY  - JOUR
AU  - Panić, V
AU  - Vidaković, Tanja
AU  - Gojković, Snežana Lj.
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/527
AB  - Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000(R) (BP) and Vulcan(R) XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 degreesC. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 degreesC, while the lowintensity peak at 2theta position that corresponds to the most intensive peak of the rutile structure was registered at 450 degreesC. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g(-1) of composite was registered for RuOxHy supported on BP and calcined at 300 degreesC while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOXHy composite is highly porous while BP-supported one is more compact.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
EP  - 3813
IS  - 25-26
SP  - 3805
VL  - 48
DO  - 10.1016/S0013-4686(03)00514-0
ER  - 

@article{
author = "Panić, V and Vidaković, Tanja and Gojković, Snežana Lj. and Dekanski, Aleksandar and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000(R) (BP) and Vulcan(R) XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 degreesC. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 degreesC, while the lowintensity peak at 2theta position that corresponds to the most intensive peak of the rutile structure was registered at 450 degreesC. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g(-1) of composite was registered for RuOxHy supported on BP and calcined at 300 degreesC while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOXHy composite is highly porous while BP-supported one is more compact.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol",
pages = "3813-3805",
number = "25-26",
volume = "48",
doi = "10.1016/S0013-4686(03)00514-0"
}

Panić, V., Vidaković, T., Gojković, S. Lj., Dekanski, A., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 48(25-26), 3805-3813.
https://doi.org/10.1016/S0013-4686(03)00514-0

Panić V, Vidaković T, Gojković SL, Dekanski A, Milonjić SK, Nikolić BŽ. The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta. 2003;48(25-26):3805-3813.
doi:10.1016/S0013-4686(03)00514-0 .

Panić, V, Vidaković, Tanja, Gojković, Snežana Lj., Dekanski, Aleksandar, Milonjić, Slobodan K., Nikolić, Branislav Ž., "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol" in Electrochimica Acta, 48, no. 25-26 (2003):3805-3813,
https://doi.org/10.1016/S0013-4686(03)00514-0 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/585
AB  - In order to understand the role of TiO2 in the deactivation mechanism of an active RuO2–TiO2 coating, an additional TiO2 layer was introduced in the support coating interphase of regular Ti//[RuO2–TiO2 anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2–TiO2 coatings, which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot obtained by electrochemical impedance spectroscopy, for a regular RuO2–TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed. The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TiO2 layer at different position within RuO2–TiO2 coating.
AB  - U cilju ispitivanja uloge titan-oksida u deaktivaciji RuO2–TiO2 prevlake na titanskoj podlozi, ispitivane su osobine anoda sa dodatnim slojem TiO2 u međufazi podloga prevlaka, odnosno na površini prevlake. Elektrohemijsko ponašanje ovih upoređeno je sa ponašanjem anoda sa uobičajenom RuO2–TiO2 prevlakom, kao i sa onima koje su bile podvrgnute ubrzanom testu stabilnosti. Pojava polukruga u visoko-frekventnoj oblasti u dijagramima u kompleksnoj ravni, koja je registrovana spektroskopijom elektrohemijske impedancije za uobičajene RuO2–TiO2 prevlake, a koja je posledica obogaćivanja prevlake sa TiO2 tokom njene deaktivacije, nije uočena kod anoda sa dodatim TiO2 slojem. Dodati TiO2 slojevi povećavaju omsku otpornost prevlake i utiču na impedancijsko ponašanje pri niskim frekvencijama. Za analizu impedancijskog ponašanja prevlaka sa dodatim TiO2 slojevima kao i uobičajenih RuO2–TiO2 prevlaka koje su deaktivirane korišćena su slična ekvivalentna električna kola.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure
T1  - Uloga koncentracionog profila titan-oksida u elektrohemijskom ponašanju RuO2-TiO2 prevlaka dobijenih sol-gel postupkom
EP  - 988
IS  - 12
SP  - 979
VL  - 68
UR  - https://hdl.handle.net/21.15107/rcub_technorep_585
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "In order to understand the role of TiO2 in the deactivation mechanism of an active RuO2–TiO2 coating, an additional TiO2 layer was introduced in the support coating interphase of regular Ti//[RuO2–TiO2 anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2–TiO2 coatings, which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot obtained by electrochemical impedance spectroscopy, for a regular RuO2–TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed. The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TiO2 layer at different position within RuO2–TiO2 coating., U cilju ispitivanja uloge titan-oksida u deaktivaciji RuO2–TiO2 prevlake na titanskoj podlozi, ispitivane su osobine anoda sa dodatnim slojem TiO2 u međufazi podloga prevlaka, odnosno na površini prevlake. Elektrohemijsko ponašanje ovih upoređeno je sa ponašanjem anoda sa uobičajenom RuO2–TiO2 prevlakom, kao i sa onima koje su bile podvrgnute ubrzanom testu stabilnosti. Pojava polukruga u visoko-frekventnoj oblasti u dijagramima u kompleksnoj ravni, koja je registrovana spektroskopijom elektrohemijske impedancije za uobičajene RuO2–TiO2 prevlake, a koja je posledica obogaćivanja prevlake sa TiO2 tokom njene deaktivacije, nije uočena kod anoda sa dodatim TiO2 slojem. Dodati TiO2 slojevi povećavaju omsku otpornost prevlake i utiču na impedancijsko ponašanje pri niskim frekvencijama. Za analizu impedancijskog ponašanja prevlaka sa dodatim TiO2 slojevima kao i uobičajenih RuO2–TiO2 prevlaka koje su deaktivirane korišćena su slična ekvivalentna električna kola.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure, Uloga koncentracionog profila titan-oksida u elektrohemijskom ponašanju RuO2-TiO2 prevlaka dobijenih sol-gel postupkom",
pages = "988-979",
number = "12",
volume = "68",
url = "https://hdl.handle.net/21.15107/rcub_technorep_585"
}

Panić, V., Dekanski, A., Mišković-Stanković, V., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 68(12), 979-988.
https://hdl.handle.net/21.15107/rcub_technorep_585

Panić V, Dekanski A, Mišković-Stanković V, Milonjić SK, Nikolić BŽ. The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2003;68(12):979-988.
https://hdl.handle.net/21.15107/rcub_technorep_585 .

Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Milonjić, Slobodan K., Nikolić, Branislav Ž., "The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure" in Journal of the Serbian Chemical Society, 68, no. 12 (2003):979-988,
https://hdl.handle.net/21.15107/rcub_technorep_585 .

TY  - JOUR
AU  - Mitrović, Dejan
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, Radoslav
AU  - Nikolić, Branislav
PY  - 2001
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5356
AB  - The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller.
AB  - U radu je ispitivan uticaj metanola, etanola, 1-propanola i 2-propanola, dodatih u disperznu sredinu RuO2-TiO2 smeše solova, na elektrohemijski aktivnu površinu i elektrokatalitičku aktivnost za reakciju izdvajanja hlora (RIH) RuO2-TiO2/Ti elektroda dobijenih sol-gel postupkom. Elektrohemijski aktivna površina ispitivana je metodom ciklične voltametrije, dok je aktivnost za RIH ispitivana polarizacionim merenjima. Takođe je i ubrzanim testom stabilnosti ispitivana postojanost dobijenih oksidnih prevlaka. Utvrđeno je da osobine dobijenih anoda zavise od broja ugljenikovih atoma u molekulu dodatog alkohola i vremena proteklog od pripreme smeše alkohola i solova do nanošenja smeše na titanski nosač. Uočeno je da dodatak alkohola prouzrokuje povećanje aktivnosti anoda za RIH u odnosu na anode dobijene bez dodavanja alkohola. Istovremeno, anode dobijene dodavanjem alkohola su manje stabilne od anoda dobijenih bez dodavanja alkohola.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes
T1  - Uticaj sastava disperzne sredine oksidnih solova na elektrokatalitičku aktivnost RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom
EP  - 857
IS  - 11-12
SP  - 847
VL  - 66
DO  - 10.2298/jsc0112847m
UR  - https://hdl.handle.net/21.15107/rcub_cer_26
ER  - 

@article{
author = "Mitrović, Dejan and Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, Branislav",
year = "2001",
abstract = "The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller., U radu je ispitivan uticaj metanola, etanola, 1-propanola i 2-propanola, dodatih u disperznu sredinu RuO2-TiO2 smeše solova, na elektrohemijski aktivnu površinu i elektrokatalitičku aktivnost za reakciju izdvajanja hlora (RIH) RuO2-TiO2/Ti elektroda dobijenih sol-gel postupkom. Elektrohemijski aktivna površina ispitivana je metodom ciklične voltametrije, dok je aktivnost za RIH ispitivana polarizacionim merenjima. Takođe je i ubrzanim testom stabilnosti ispitivana postojanost dobijenih oksidnih prevlaka. Utvrđeno je da osobine dobijenih anoda zavise od broja ugljenikovih atoma u molekulu dodatog alkohola i vremena proteklog od pripreme smeše alkohola i solova do nanošenja smeše na titanski nosač. Uočeno je da dodatak alkohola prouzrokuje povećanje aktivnosti anoda za RIH u odnosu na anode dobijene bez dodavanja alkohola. Istovremeno, anode dobijene dodavanjem alkohola su manje stabilne od anoda dobijenih bez dodavanja alkohola.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes, Uticaj sastava disperzne sredine oksidnih solova na elektrokatalitičku aktivnost RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom",
pages = "857-847",
number = "11-12",
volume = "66",
doi = "10.2298/jsc0112847m",
url = "https://hdl.handle.net/21.15107/rcub_cer_26"
}

Mitrović, D., Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B.. (2001). The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 66(11-12), 847-857.
https://doi.org/10.2298/jsc0112847m
https://hdl.handle.net/21.15107/rcub_cer_26

Mitrović D, Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić B. The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society. 2001;66(11-12):847-857.
doi:10.2298/jsc0112847m
https://hdl.handle.net/21.15107/rcub_cer_26 .

Mitrović, Dejan, Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, Branislav, "The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes" in Journal of the Serbian Chemical Society, 66, no. 11-12 (2001):847-857,
https://doi.org/10.2298/jsc0112847m .,
https://hdl.handle.net/21.15107/rcub_cer_26 .