Marković, Bojana

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  • Marković, Bojana (1)
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Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design

Tadić, Tamara; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra; Ilić, Mila; Vuković, Zorica; Onjia, Antonije

(Zvornik : Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Vuković, Zorica
AU  - Onjia, Antonije
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7050
AB  - In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. The obtained macroporous
copolymer was syntesized via suspension copolymerization and was characterized by Fourier
transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The
parameters which affect sorption efficiency of the lindane were: pH, sorption time (tsor), ion
strength (ion), rpm, and dose of sorbent. These variables were optimized by the experimental
design which include Plackett-Burman Design (PBD) and Central Composite Design (CCD).
After screening step by the PBD, the optimum conditions were obtained by the CCD where the
values were investigated in two levels. The design of experiment showed that the ion strength
and dose of sorbent were the most significant parameters, while the other variables do not have
such an effect on sorption efficiency. Accordingly, the optimum conditions to reach the maximum
recovery were: pH 8, 180 min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/l dose of
sorbent. The results showed that the studied copolymer could be an efficient sorbent for trace
lindane in water with recoveries above 80 %.
PB  - Zvornik : Faculty of Technology
C3  - Book of Abstracts / VIII International Congress "Engineering, Environment and Materials in Process Industry", Jahorina, March 20-23, 2023
T1  - Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design
SP  - 124
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7050
ER  - 
@conference{
author = "Tadić, Tamara and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Ilić, Mila and Vuković, Zorica and Onjia, Antonije",
year = "2023",
abstract = "In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. The obtained macroporous
copolymer was syntesized via suspension copolymerization and was characterized by Fourier
transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The
parameters which affect sorption efficiency of the lindane were: pH, sorption time (tsor), ion
strength (ion), rpm, and dose of sorbent. These variables were optimized by the experimental
design which include Plackett-Burman Design (PBD) and Central Composite Design (CCD).
After screening step by the PBD, the optimum conditions were obtained by the CCD where the
values were investigated in two levels. The design of experiment showed that the ion strength
and dose of sorbent were the most significant parameters, while the other variables do not have
such an effect on sorption efficiency. Accordingly, the optimum conditions to reach the maximum
recovery were: pH 8, 180 min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/l dose of
sorbent. The results showed that the studied copolymer could be an efficient sorbent for trace
lindane in water with recoveries above 80 %.",
publisher = "Zvornik : Faculty of Technology",
journal = "Book of Abstracts / VIII International Congress "Engineering, Environment and Materials in Process Industry", Jahorina, March 20-23, 2023",
title = "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design",
pages = "124",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7050"
}
Tadić, T., Bulatović, S., Marković, B., Nastasović, A., Ilić, M., Vuković, Z.,& Onjia, A.. (2023). Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Book of Abstracts / VIII International Congress "Engineering, Environment and Materials in Process Industry", Jahorina, March 20-23, 2023
Zvornik : Faculty of Technology., 124.
https://hdl.handle.net/21.15107/rcub_technorep_7050
Tadić T, Bulatović S, Marković B, Nastasović A, Ilić M, Vuković Z, Onjia A. Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Book of Abstracts / VIII International Congress "Engineering, Environment and Materials in Process Industry", Jahorina, March 20-23, 2023. 2023;:124.
https://hdl.handle.net/21.15107/rcub_technorep_7050 .
Tadić, Tamara, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Ilić, Mila, Vuković, Zorica, Onjia, Antonije, "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design" in Book of Abstracts / VIII International Congress "Engineering, Environment and Materials in Process Industry", Jahorina, March 20-23, 2023 (2023):124,
https://hdl.handle.net/21.15107/rcub_technorep_7050 .