TY  - JOUR
AU  - Milovanović, Jelena
AU  - Rajić, Nevenka
AU  - Romero, Antonio A.
AU  - Li, Hangkong
AU  - Shih, Kaimin
AU  - Tschentscher, Roman
AU  - Luque, Rafael
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3233
AB  - The depolymerization of biolignin (BL), eucalyptus (EL), and hardwood lignins (HL) to simple aromatics was studied by a microwave assisted approach using NiO/H-ZSM-S zeolites as catalysts. The catalysts prepared by the mechanochemical dry milling (MCDM) method contained bunsenite nano NiO particles with an average size of 67 mu m at a concentration of 1-4.8 wt % NiO. Yields and composition of the obtained bio-oils are highly dependent on lignin type as well as on the content of NiO. The highest bio-oil yield (about 20 wt %) was obtained using 3.5 wt % NiO and HL as the feedstock. A number of relevant findings based depolymerization experiments are provided which pointed to different monomeric products (mostly S-derived) that could be produced in different proportions depending on the source of investigated lignin and content of the NiO at H-ZSM-5.
PB  - Amer Chemical Soc, Washington
T2  - ACS Sustainable Chemistry & Engineering
T1  - Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites
EP  - 4313
IS  - 8
SP  - 4305
VL  - 4
DO  - 10.1021/acssuschemeng.6b00825
ER  - 

@article{
author = "Milovanović, Jelena and Rajić, Nevenka and Romero, Antonio A. and Li, Hangkong and Shih, Kaimin and Tschentscher, Roman and Luque, Rafael",
year = "2016",
abstract = "The depolymerization of biolignin (BL), eucalyptus (EL), and hardwood lignins (HL) to simple aromatics was studied by a microwave assisted approach using NiO/H-ZSM-S zeolites as catalysts. The catalysts prepared by the mechanochemical dry milling (MCDM) method contained bunsenite nano NiO particles with an average size of 67 mu m at a concentration of 1-4.8 wt % NiO. Yields and composition of the obtained bio-oils are highly dependent on lignin type as well as on the content of NiO. The highest bio-oil yield (about 20 wt %) was obtained using 3.5 wt % NiO and HL as the feedstock. A number of relevant findings based depolymerization experiments are provided which pointed to different monomeric products (mostly S-derived) that could be produced in different proportions depending on the source of investigated lignin and content of the NiO at H-ZSM-5.",
publisher = "Amer Chemical Soc, Washington",
journal = "ACS Sustainable Chemistry & Engineering",
title = "Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites",
pages = "4313-4305",
number = "8",
volume = "4",
doi = "10.1021/acssuschemeng.6b00825"
}

Milovanović, J., Rajić, N., Romero, A. A., Li, H., Shih, K., Tschentscher, R.,& Luque, R.. (2016). Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites. in ACS Sustainable Chemistry & Engineering
Amer Chemical Soc, Washington., 4(8), 4305-4313.
https://doi.org/10.1021/acssuschemeng.6b00825

Milovanović J, Rajić N, Romero AA, Li H, Shih K, Tschentscher R, Luque R. Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites. in ACS Sustainable Chemistry & Engineering. 2016;4(8):4305-4313.
doi:10.1021/acssuschemeng.6b00825 .

Milovanović, Jelena, Rajić, Nevenka, Romero, Antonio A., Li, Hangkong, Shih, Kaimin, Tschentscher, Roman, Luque, Rafael, "Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites" in ACS Sustainable Chemistry & Engineering, 4, no. 8 (2016):4305-4313,
https://doi.org/10.1021/acssuschemeng.6b00825 . .