EUREKA E!4141

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EUREKA E!4141

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Publications

Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite

Lazarević, Slavica; Janković-Častvan, Ivona; Potkonjak, Branislav; Janaćković, Đorđe; Petrović, Rada

(Elsevier Science Sa, Lausanne, 2012)

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Potkonjak, Branislav
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2237
AB  - The efficiency of iron-functionalized sepiolite for the removal of Co2+ ions from aqueous solutions was determined under different experimental conditions, using the batch method. The ionization constants of the surface functional groups of the sepiolite-iron system, determined from potentiometric titration data, were pK(a1)(int) = 6.7 +/- 0.1 and pK(a2)(int) = 10.2 +/- 0.1. The sorption experiments were performed as a function of initial metal concentration, initial pH value, and the equilibration time. The equilibrium process was well described by the Langmuir isotherm model. The pseudo-second order kinetic model provides the best correlation of the experimental kinetic data. The iron-sepiolite system had a noticeably higher Co2+ sorption capacity than the natural sepiolite sample as a result of higher specific sorption and a higher ion exchange capacity.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering and Processing-Process Intensification
T1  - Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite
EP  - 47
SP  - 40
VL  - 55
DO  - 10.1016/j.cep.2012.01.004
ER  - 
@article{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Potkonjak, Branislav and Janaćković, Đorđe and Petrović, Rada",
year = "2012",
abstract = "The efficiency of iron-functionalized sepiolite for the removal of Co2+ ions from aqueous solutions was determined under different experimental conditions, using the batch method. The ionization constants of the surface functional groups of the sepiolite-iron system, determined from potentiometric titration data, were pK(a1)(int) = 6.7 +/- 0.1 and pK(a2)(int) = 10.2 +/- 0.1. The sorption experiments were performed as a function of initial metal concentration, initial pH value, and the equilibration time. The equilibrium process was well described by the Langmuir isotherm model. The pseudo-second order kinetic model provides the best correlation of the experimental kinetic data. The iron-sepiolite system had a noticeably higher Co2+ sorption capacity than the natural sepiolite sample as a result of higher specific sorption and a higher ion exchange capacity.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering and Processing-Process Intensification",
title = "Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite",
pages = "47-40",
volume = "55",
doi = "10.1016/j.cep.2012.01.004"
}
Lazarević, S., Janković-Častvan, I., Potkonjak, B., Janaćković, Đ.,& Petrović, R.. (2012). Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite. in Chemical Engineering and Processing-Process Intensification
Elsevier Science Sa, Lausanne., 55, 40-47.
https://doi.org/10.1016/j.cep.2012.01.004
Lazarević S, Janković-Častvan I, Potkonjak B, Janaćković Đ, Petrović R. Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite. in Chemical Engineering and Processing-Process Intensification. 2012;55:40-47.
doi:10.1016/j.cep.2012.01.004 .
Lazarević, Slavica, Janković-Častvan, Ivona, Potkonjak, Branislav, Janaćković, Đorđe, Petrović, Rada, "Removal of Co2+ ions from aqueous solutions using iron-functionalized sepiolite" in Chemical Engineering and Processing-Process Intensification, 55 (2012):40-47,
https://doi.org/10.1016/j.cep.2012.01.004 . .
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Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process

Petrović, Rada; Tanasković, N.; Đokić, Veljko; Radovanović, Željko; Janković-Častvan, Ivona; Stamenković, Ivan; Janaćković, Đorđe

(Elsevier, Amsterdam, 2012)

TY  - JOUR
AU  - Petrović, Rada
AU  - Tanasković, N.
AU  - Đokić, Veljko
AU  - Radovanović, Željko
AU  - Janković-Častvan, Ivona
AU  - Stamenković, Ivan
AU  - Janaćković, Đorđe
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2193
AB  - Titania powders were synthesized by nonhydrolitic sol-gel process starting from titanium(IV)-chloride, titanium(IV)-isopropoxide and carbon-tetrachloride. Gelation was performed in solvothermal conditions, at 140 degrees C or 160 degrees C. The obtained gels were then dried and calcined at 500 degrees C or 750 degrees C. Dry gels and powders obtained by their calcination at 500 degrees C contained only anatase, and the degree of crystallinity increased notably on passing from the dry gels to the powders. The crystallite size of dry gels and powders obtained at 500 degrees C increased slightly with increasing temperature of the gelation. The powder obtained at the higher gelation temperature had a larger specific surface area (52.8 m(2) g(-1)) and a smaller maximum pore diameter (12.3 nm). When the calcination temperature was increased to 750 degrees C, the obtained powders contained both anatase and rutile. The rutile content in the powders is related to the degree of crystallinity of the dry gels: with a lower level of dry gel crystallinity, the rutile content in the powders becomes higher, indicating that the temperature of the anatase - gt  rutile transformation decreases with decreasing the size of anatase crystallites. The photocatalytic activity of the powders obtained by gel calcination at 500 degrees C, tested by measuring the photocatalytic degradation of the azo dye CI Reactive orange 16, was sufficiently high and attained the photocatalytic activity of the broadly accepted commercial powder P-25 produced by Degussa. The photocatalytic activity of the powders obtained by calcination at 750 degrees C was low, but showed a tendency to increase with higher anatase content in the powders.
PB  - Elsevier, Amsterdam
T2  - Powder Technology
T1  - Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process
EP  - 243
SP  - 239
VL  - 219
DO  - 10.1016/j.powtec.2011.12.049
ER  - 
@article{
author = "Petrović, Rada and Tanasković, N. and Đokić, Veljko and Radovanović, Željko and Janković-Častvan, Ivona and Stamenković, Ivan and Janaćković, Đorđe",
year = "2012",
abstract = "Titania powders were synthesized by nonhydrolitic sol-gel process starting from titanium(IV)-chloride, titanium(IV)-isopropoxide and carbon-tetrachloride. Gelation was performed in solvothermal conditions, at 140 degrees C or 160 degrees C. The obtained gels were then dried and calcined at 500 degrees C or 750 degrees C. Dry gels and powders obtained by their calcination at 500 degrees C contained only anatase, and the degree of crystallinity increased notably on passing from the dry gels to the powders. The crystallite size of dry gels and powders obtained at 500 degrees C increased slightly with increasing temperature of the gelation. The powder obtained at the higher gelation temperature had a larger specific surface area (52.8 m(2) g(-1)) and a smaller maximum pore diameter (12.3 nm). When the calcination temperature was increased to 750 degrees C, the obtained powders contained both anatase and rutile. The rutile content in the powders is related to the degree of crystallinity of the dry gels: with a lower level of dry gel crystallinity, the rutile content in the powders becomes higher, indicating that the temperature of the anatase - gt  rutile transformation decreases with decreasing the size of anatase crystallites. The photocatalytic activity of the powders obtained by gel calcination at 500 degrees C, tested by measuring the photocatalytic degradation of the azo dye CI Reactive orange 16, was sufficiently high and attained the photocatalytic activity of the broadly accepted commercial powder P-25 produced by Degussa. The photocatalytic activity of the powders obtained by calcination at 750 degrees C was low, but showed a tendency to increase with higher anatase content in the powders.",
publisher = "Elsevier, Amsterdam",
journal = "Powder Technology",
title = "Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process",
pages = "243-239",
volume = "219",
doi = "10.1016/j.powtec.2011.12.049"
}
Petrović, R., Tanasković, N., Đokić, V., Radovanović, Ž., Janković-Častvan, I., Stamenković, I.,& Janaćković, Đ.. (2012). Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process. in Powder Technology
Elsevier, Amsterdam., 219, 239-243.
https://doi.org/10.1016/j.powtec.2011.12.049
Petrović R, Tanasković N, Đokić V, Radovanović Ž, Janković-Častvan I, Stamenković I, Janaćković Đ. Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process. in Powder Technology. 2012;219:239-243.
doi:10.1016/j.powtec.2011.12.049 .
Petrović, Rada, Tanasković, N., Đokić, Veljko, Radovanović, Željko, Janković-Častvan, Ivona, Stamenković, Ivan, Janaćković, Đorđe, "Influence of the gelation and calcination temperatures on physical parameters and photocatalytic activity of mesoporous titania powders synthesized by the nonhydrolytic sol-gel process" in Powder Technology, 219 (2012):239-243,
https://doi.org/10.1016/j.powtec.2011.12.049 . .
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12

Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study

Lazarević, Slavica; Janković-Častvan, Ivona; Radovanović, Željko; Potkonjak, Branislav; Janaćković, Đorđe; Petrović, Rada

(Serbian Chemical Society, Belgrade, 2011)

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Radovanović, Željko
AU  - Potkonjak, Branislav
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1805
AB  - The efficiency of natural sepiolite for the removal of Cu2+ and Co2+ from aqueous solution was determined using the batch method. The sorption experiments were performed as a function of the initial metal concentration, the equilibration time and temperature. Thermodynamic parameters, such as enthalpy, free energy and entropy, were calculated from the temperature dependent sorption isotherms and these values showed that the sorption of the investigated metals onto sepiolite was endothermic. The pseudo-second order kinetic model provides the best correlation of the experimental kinetic data.
AB  - U radu je ispitana efikasnost uklanjanja jona bakra i kobalta iz vodenih rastvora na prirodnom sepiolitu primenom metode uravnotežavanja posebnih proba. Ispitan je uticaj početnih koncentracija Cu2+ i Co2+, kao i vremena uravnotežavanja i temperature na proces sorpcije. Vrednosti termodinamičkih parametara sorpcije (promene entalpije, promene entropije, promene slobodne energije sorpcije), određene na osnovu zavisnosti sorpcionog kapaciteta od temperature, ukazuju na to da je proces sorpcije Cu2+ i Co2+ na sepiolitu endoterman. Poređenjem eksperimentalih rezultata sa kinetičkim modelima utvrđeno je da se kinetika sorpcije Cu2+ i Co2+ na sepiolitu može opisati kinetičkim modelom pseudo-drugog reda.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study
T1  - Sorpcija jona bakra i kobalta iz vodenih rastvora na sepiolitu, ispitivanje ravnoteže, kinetike i termodinamike sorpcije
EP  - 112
IS  - 1
SP  - 101
VL  - 76
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1805
ER  - 
@article{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Radovanović, Željko and Potkonjak, Branislav and Janaćković, Đorđe and Petrović, Rada",
year = "2011",
abstract = "The efficiency of natural sepiolite for the removal of Cu2+ and Co2+ from aqueous solution was determined using the batch method. The sorption experiments were performed as a function of the initial metal concentration, the equilibration time and temperature. Thermodynamic parameters, such as enthalpy, free energy and entropy, were calculated from the temperature dependent sorption isotherms and these values showed that the sorption of the investigated metals onto sepiolite was endothermic. The pseudo-second order kinetic model provides the best correlation of the experimental kinetic data., U radu je ispitana efikasnost uklanjanja jona bakra i kobalta iz vodenih rastvora na prirodnom sepiolitu primenom metode uravnotežavanja posebnih proba. Ispitan je uticaj početnih koncentracija Cu2+ i Co2+, kao i vremena uravnotežavanja i temperature na proces sorpcije. Vrednosti termodinamičkih parametara sorpcije (promene entalpije, promene entropije, promene slobodne energije sorpcije), određene na osnovu zavisnosti sorpcionog kapaciteta od temperature, ukazuju na to da je proces sorpcije Cu2+ i Co2+ na sepiolitu endoterman. Poređenjem eksperimentalih rezultata sa kinetičkim modelima utvrđeno je da se kinetika sorpcije Cu2+ i Co2+ na sepiolitu može opisati kinetičkim modelom pseudo-drugog reda.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study, Sorpcija jona bakra i kobalta iz vodenih rastvora na sepiolitu, ispitivanje ravnoteže, kinetike i termodinamike sorpcije",
pages = "112-101",
number = "1",
volume = "76",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1805"
}
Lazarević, S., Janković-Častvan, I., Radovanović, Ž., Potkonjak, B., Janaćković, Đ.,& Petrović, R.. (2011). Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 76(1), 101-112.
https://hdl.handle.net/21.15107/rcub_technorep_1805
Lazarević S, Janković-Častvan I, Radovanović Ž, Potkonjak B, Janaćković Đ, Petrović R. Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study. in Journal of the Serbian Chemical Society. 2011;76(1):101-112.
https://hdl.handle.net/21.15107/rcub_technorep_1805 .
Lazarević, Slavica, Janković-Častvan, Ivona, Radovanović, Željko, Potkonjak, Branislav, Janaćković, Đorđe, Petrović, Rada, "Sorption of Cu2+ and Co2+ from aqueous solutions onto sepiolite: An equilibrium, kinetic and thermodynamic study" in Journal of the Serbian Chemical Society, 76, no. 1 (2011):101-112,
https://hdl.handle.net/21.15107/rcub_technorep_1805 .
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13

Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography

Lazarević, Slavica; Janković-Častvan, Ivona; Onjia, Antonije; Krstić, Jugoslav; Janaćković, Đorđe; Petrović, Rada

(Amer Chemical Soc, Washington, 2011)

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Onjia, Antonije
AU  - Krstić, Jugoslav
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1850
AB  - Inverse gas chromatography at infinite and finite surface coverages was applied to evaluate the surface properties of an iron-modified sepiolite sorbent, Fe-sepiolite. The adsorptions of different nonpolar and polar probes were measured in the infinite-dilution regime, in the temperature range 483-513 K. For the organic probes used, the thermodynamic parameters (free energy, enthalpy, and entropy) of adsorption and the dispersive and specific components of the free energy of adsorption were determined and are discussed in terms of specific reactions that can occur on the adsorbent surface. Following the approach of Gutmann (The Donor Acceptor Approach to Molecular Interactions; Plenum Press: New York, 1978), acid/base surface characteristics were determined. The adsorption isotherms of n-hexane, benzene, chloroform, and tetrahydrofuran were used to estimate the specific surface areas, isosteric heats of adsorption, and adsorption energy distributions for the adsorption of organic molecules.
PB  - Amer Chemical Soc, Washington
T2  - Industrial & Engineering Chemistry Research
T1  - Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography
EP  - 11475
IS  - 20
SP  - 11467
VL  - 50
DO  - 10.1021/ie200595n
ER  - 
@article{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Onjia, Antonije and Krstić, Jugoslav and Janaćković, Đorđe and Petrović, Rada",
year = "2011",
abstract = "Inverse gas chromatography at infinite and finite surface coverages was applied to evaluate the surface properties of an iron-modified sepiolite sorbent, Fe-sepiolite. The adsorptions of different nonpolar and polar probes were measured in the infinite-dilution regime, in the temperature range 483-513 K. For the organic probes used, the thermodynamic parameters (free energy, enthalpy, and entropy) of adsorption and the dispersive and specific components of the free energy of adsorption were determined and are discussed in terms of specific reactions that can occur on the adsorbent surface. Following the approach of Gutmann (The Donor Acceptor Approach to Molecular Interactions; Plenum Press: New York, 1978), acid/base surface characteristics were determined. The adsorption isotherms of n-hexane, benzene, chloroform, and tetrahydrofuran were used to estimate the specific surface areas, isosteric heats of adsorption, and adsorption energy distributions for the adsorption of organic molecules.",
publisher = "Amer Chemical Soc, Washington",
journal = "Industrial & Engineering Chemistry Research",
title = "Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography",
pages = "11475-11467",
number = "20",
volume = "50",
doi = "10.1021/ie200595n"
}
Lazarević, S., Janković-Častvan, I., Onjia, A., Krstić, J., Janaćković, Đ.,& Petrović, R.. (2011). Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography. in Industrial & Engineering Chemistry Research
Amer Chemical Soc, Washington., 50(20), 11467-11475.
https://doi.org/10.1021/ie200595n
Lazarević S, Janković-Častvan I, Onjia A, Krstić J, Janaćković Đ, Petrović R. Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography. in Industrial & Engineering Chemistry Research. 2011;50(20):11467-11475.
doi:10.1021/ie200595n .
Lazarević, Slavica, Janković-Častvan, Ivona, Onjia, Antonije, Krstić, Jugoslav, Janaćković, Đorđe, Petrović, Rada, "Surface Characterization of Iron-Modified Sepiolite by Inverse Gas Chromatography" in Industrial & Engineering Chemistry Research, 50, no. 20 (2011):11467-11475,
https://doi.org/10.1021/ie200595n . .
9
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11

Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study

Lazarević, Slavica; Janković-Častvan, Ivona; Đokić, Veljko; Radovanović, Željko; Janaćković, Đorđe; Petrović, Rada

(Amer Chemical Soc, Washington, 2010)

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Đokić, Veljko
AU  - Radovanović, Željko
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1717
AB  - Sepiolite was used for the synthesis of the sepiolite-iron oxide system to obtain a sorbent suitable for the removal of Ni2+ from aqueous solution. The modified material, Fe-sepiolite, was characterized by X-ray diffraction analysis, Fourier transform infrared spectroscopy, differential thermal/thermogravimetric analysis, and point of zero charge (pH(pzc)) determination. The sorption experiments were performed as a function of the initial metal concentration, equilibration time, and temperature using the batch method. The Fe-sepiolite had a higher sorption capacity than the natural sepiolite sample due to a higher specific sorption and a higher ion exchange with Mg2+ ions from the sepiolite surface. Thermodynamic parameters, such as enthalpy, Gibbs energy, and entropy, were calculated from the temperature-dependent sorption isotherms, and these values showed that the sorption of Ni2+ onto sepiolites was endothermic. Pseudo-second-order kinetic models provide the best correlation of the experimental kinetic data.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study
EP  - 5689
IS  - 12
SP  - 5681
VL  - 55
DO  - 10.1021/je100639k
ER  - 
@article{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Đokić, Veljko and Radovanović, Željko and Janaćković, Đorđe and Petrović, Rada",
year = "2010",
abstract = "Sepiolite was used for the synthesis of the sepiolite-iron oxide system to obtain a sorbent suitable for the removal of Ni2+ from aqueous solution. The modified material, Fe-sepiolite, was characterized by X-ray diffraction analysis, Fourier transform infrared spectroscopy, differential thermal/thermogravimetric analysis, and point of zero charge (pH(pzc)) determination. The sorption experiments were performed as a function of the initial metal concentration, equilibration time, and temperature using the batch method. The Fe-sepiolite had a higher sorption capacity than the natural sepiolite sample due to a higher specific sorption and a higher ion exchange with Mg2+ ions from the sepiolite surface. Thermodynamic parameters, such as enthalpy, Gibbs energy, and entropy, were calculated from the temperature-dependent sorption isotherms, and these values showed that the sorption of Ni2+ onto sepiolites was endothermic. Pseudo-second-order kinetic models provide the best correlation of the experimental kinetic data.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study",
pages = "5689-5681",
number = "12",
volume = "55",
doi = "10.1021/je100639k"
}
Lazarević, S., Janković-Častvan, I., Đokić, V., Radovanović, Ž., Janaćković, Đ.,& Petrović, R.. (2010). Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 55(12), 5681-5689.
https://doi.org/10.1021/je100639k
Lazarević S, Janković-Častvan I, Đokić V, Radovanović Ž, Janaćković Đ, Petrović R. Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study. in Journal of Chemical and Engineering Data. 2010;55(12):5681-5689.
doi:10.1021/je100639k .
Lazarević, Slavica, Janković-Častvan, Ivona, Đokić, Veljko, Radovanović, Željko, Janaćković, Đorđe, Petrović, Rada, "Iron-Modified Sepiolite for Ni2+ Sorption from Aqueous Solution: An Equilibrium, Kinetic, and Thermodynamic Study" in Journal of Chemical and Engineering Data, 55, no. 12 (2010):5681-5689,
https://doi.org/10.1021/je100639k . .
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48

Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage

Lazarević, Slavica; Radovanović, Željko; Veljović, Đorđe; Onjia, Antonije; Janaćković, Đorđe; Petrović, Rada

(Elsevier Science Bv, Amsterdam, 2009)

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Radovanović, Željko
AU  - Veljović, Đorđe
AU  - Onjia, Antonije
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1472
AB  - The adsorption properties of sepiolite from Andrici, Serbia, were studied by inverse gas chromatography at zero and finite surface coverage between 483 and 513 K. The thermodynamic parameters (free energy, enthalpy, entropy) of adsorption, as well as the dispersive and specific components of the free energy of adsorption and the acid/base of the solid were calculated from the IGC data at zero coverage. The K-D/K-A ratio indicated basis character. The adsorption isotherms were used to estimate the specific surface area, isosteric heat of adsorption and the adsorption energy distribution for the adsorption of organic molecules.
PB  - Elsevier Science Bv, Amsterdam
T2  - Applied Clay Science
T1  - Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage
EP  - 48
IS  - 1
SP  - 41
VL  - 43
DO  - 10.1016/j.clay.2008.07.013
ER  - 
@article{
author = "Lazarević, Slavica and Radovanović, Željko and Veljović, Đorđe and Onjia, Antonije and Janaćković, Đorđe and Petrović, Rada",
year = "2009",
abstract = "The adsorption properties of sepiolite from Andrici, Serbia, were studied by inverse gas chromatography at zero and finite surface coverage between 483 and 513 K. The thermodynamic parameters (free energy, enthalpy, entropy) of adsorption, as well as the dispersive and specific components of the free energy of adsorption and the acid/base of the solid were calculated from the IGC data at zero coverage. The K-D/K-A ratio indicated basis character. The adsorption isotherms were used to estimate the specific surface area, isosteric heat of adsorption and the adsorption energy distribution for the adsorption of organic molecules.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Applied Clay Science",
title = "Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage",
pages = "48-41",
number = "1",
volume = "43",
doi = "10.1016/j.clay.2008.07.013"
}
Lazarević, S., Radovanović, Ž., Veljović, Đ., Onjia, A., Janaćković, Đ.,& Petrović, R.. (2009). Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage. in Applied Clay Science
Elsevier Science Bv, Amsterdam., 43(1), 41-48.
https://doi.org/10.1016/j.clay.2008.07.013
Lazarević S, Radovanović Ž, Veljović Đ, Onjia A, Janaćković Đ, Petrović R. Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage. in Applied Clay Science. 2009;43(1):41-48.
doi:10.1016/j.clay.2008.07.013 .
Lazarević, Slavica, Radovanović, Željko, Veljović, Đorđe, Onjia, Antonije, Janaćković, Đorđe, Petrović, Rada, "Characterization of sepiolite by inverse gas chromatography at infinite and finite surface coverage" in Applied Clay Science, 43, no. 1 (2009):41-48,
https://doi.org/10.1016/j.clay.2008.07.013 . .
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