TY  - JOUR
AU  - Abduarahman, Muna Abdualatif
AU  - Vuksanović, Marija M.
AU  - Milošević, Milena
AU  - Egelja, Adela
AU  - Savić, Andrija
AU  - Veličković, Zlate
AU  - Marinković, Aleksandar
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7322
AB  - This study aimed to investigate the adsorption of As(V), phosphate, and textile dye Acid Green 25 (AG-25) on layered double hydroxides Mn-Fe_LDH and corresponding membranes (wCell/Mn-Fe_LDH). The wCell membrane, derived from waste tobacco boxes, was formed by cross-linking of epoxy and amino modified cellulose fibers with epoxy modified Mn-Fe_LDH and lysine as cross-linker. Structural and morphological analyses were conducted for Mn-Fe_LDH and wCell/Mn-Fe_LDH. The batch system explored pH, contact time, temperature, and initial concentration effects on wCell/Mn-Fe_LDH adsorption efficiency. Adsorption capacities of 82.71, 106.9, and 130.3 mg g−1 were achieved for As(V), phosphate, and AG-25, respectively, indicating effective anionic species removal. Kinetic analysis suggested intraparticle diffusion as the rate-limiting step. Thermodynamic parameters and ionic strength effects indicated a physisorption mechanism for AG-25 and surface complexation for As(V) and phosphate. Biodegradation experiments after five adsorption/desorption cycles revealed the membrane’s decomposition, with phosphate’s strong bonding releasing essential elements valuable for soil fertilization. Effluent wastewater treatment demonstrated low environmental impact through the formation of insoluble As(V) salts and photocatalytic dye degradation.
PB  - Springer
T2  - Journal of Polymers and the Environment
T1  - Mn-Fe Layered Double Hydroxide Modified Cellulose-Based Membrane for Sustainable Anionic Pollutant Removal
DO  - 10.1007/s10924-024-03192-x
ER  - 

@article{
author = "Abduarahman, Muna Abdualatif and Vuksanović, Marija M. and Milošević, Milena and Egelja, Adela and Savić, Andrija and Veličković, Zlate and Marinković, Aleksandar",
year = "2024",
abstract = "This study aimed to investigate the adsorption of As(V), phosphate, and textile dye Acid Green 25 (AG-25) on layered double hydroxides Mn-Fe_LDH and corresponding membranes (wCell/Mn-Fe_LDH). The wCell membrane, derived from waste tobacco boxes, was formed by cross-linking of epoxy and amino modified cellulose fibers with epoxy modified Mn-Fe_LDH and lysine as cross-linker. Structural and morphological analyses were conducted for Mn-Fe_LDH and wCell/Mn-Fe_LDH. The batch system explored pH, contact time, temperature, and initial concentration effects on wCell/Mn-Fe_LDH adsorption efficiency. Adsorption capacities of 82.71, 106.9, and 130.3 mg g−1 were achieved for As(V), phosphate, and AG-25, respectively, indicating effective anionic species removal. Kinetic analysis suggested intraparticle diffusion as the rate-limiting step. Thermodynamic parameters and ionic strength effects indicated a physisorption mechanism for AG-25 and surface complexation for As(V) and phosphate. Biodegradation experiments after five adsorption/desorption cycles revealed the membrane’s decomposition, with phosphate’s strong bonding releasing essential elements valuable for soil fertilization. Effluent wastewater treatment demonstrated low environmental impact through the formation of insoluble As(V) salts and photocatalytic dye degradation.",
publisher = "Springer",
journal = "Journal of Polymers and the Environment",
title = "Mn-Fe Layered Double Hydroxide Modified Cellulose-Based Membrane for Sustainable Anionic Pollutant Removal",
doi = "10.1007/s10924-024-03192-x"
}

Abduarahman, M. A., Vuksanović, M. M., Milošević, M., Egelja, A., Savić, A., Veličković, Z.,& Marinković, A.. (2024). Mn-Fe Layered Double Hydroxide Modified Cellulose-Based Membrane for Sustainable Anionic Pollutant Removal. in Journal of Polymers and the Environment
Springer..
https://doi.org/10.1007/s10924-024-03192-x

Abduarahman MA, Vuksanović MM, Milošević M, Egelja A, Savić A, Veličković Z, Marinković A. Mn-Fe Layered Double Hydroxide Modified Cellulose-Based Membrane for Sustainable Anionic Pollutant Removal. in Journal of Polymers and the Environment. 2024;.
doi:10.1007/s10924-024-03192-x .

Abduarahman, Muna Abdualatif, Vuksanović, Marija M., Milošević, Milena, Egelja, Adela, Savić, Andrija, Veličković, Zlate, Marinković, Aleksandar, "Mn-Fe Layered Double Hydroxide Modified Cellulose-Based Membrane for Sustainable Anionic Pollutant Removal" in Journal of Polymers and the Environment (2024),
https://doi.org/10.1007/s10924-024-03192-x . .

TY  - DATA
AU  - Abduarahman, Muna Abdualatif
AU  - Vuksanović, Marija M.
AU  - Milošević, Milena
AU  - Egelja, Adela
AU  - Savić, Andrija
AU  - Veličković, Zlate
AU  - Marinković, Aleksandar
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7333
AB  - This study aimed to investigate the adsorption of As(V), phosphate, and textile dye Acid Green 25 (AG-25) on layered double hydroxides Mn-Fe_LDH and corresponding membranes (wCell/Mn-Fe_LDH). The wCell membrane, derived from waste tobacco boxes, was formed by cross-linking of epoxy and amino modified cellulose fibers with epoxy modified Mn-Fe_LDH and lysine as cross-linker. Structural and morphological analyses were conducted for Mn-Fe_LDH and wCell/Mn-Fe_LDH. The batch system explored pH, contact time, temperature, and initial concentration effects on wCell/Mn-Fe_LDH adsorption efficiency. Adsorption capacities of 82.71, 106.9, and 130.3 mg g−1 were achieved for As(V), phosphate, and AG-25, respectively, indicating effective anionic species removal. Kinetic analysis suggested intraparticle diffusion as the rate-limiting step. Thermodynamic parameters and ionic strength effects indicated a physisorption mechanism for AG-25 and surface complexation for As(V) and phosphate. Biodegradation experiments after five adsorption/desorption cycles revealed the membrane’s decomposition, with phosphate’s strong bonding releasing essential elements valuable for soil fertilization. Effluent wastewater treatment demonstrated low environmental impact through the formation of insoluble As(V) salts and photocatalytic dye degradation.
PB  - Springer
T2  - Journal of Polymers and the Environment
T1  - Supplementary material for the article: Abduarahman, M. A.; Vuksanović, M. M.; Milošević, M.; Egelja, A.; Savić, A.; Veličković, Z. ; Marinković, A. Mn-Fe Layered Double Hydroxide Modified CelluloseBased Membrane for Sustainable Anionic Pollutant Removal. Journal of Polymers and the Environment 2024. https://doi.org/10.1007/s10924-024-03192-x
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7333
ER  - 

@misc{
author = "Abduarahman, Muna Abdualatif and Vuksanović, Marija M. and Milošević, Milena and Egelja, Adela and Savić, Andrija and Veličković, Zlate and Marinković, Aleksandar",
year = "2024",
abstract = "This study aimed to investigate the adsorption of As(V), phosphate, and textile dye Acid Green 25 (AG-25) on layered double hydroxides Mn-Fe_LDH and corresponding membranes (wCell/Mn-Fe_LDH). The wCell membrane, derived from waste tobacco boxes, was formed by cross-linking of epoxy and amino modified cellulose fibers with epoxy modified Mn-Fe_LDH and lysine as cross-linker. Structural and morphological analyses were conducted for Mn-Fe_LDH and wCell/Mn-Fe_LDH. The batch system explored pH, contact time, temperature, and initial concentration effects on wCell/Mn-Fe_LDH adsorption efficiency. Adsorption capacities of 82.71, 106.9, and 130.3 mg g−1 were achieved for As(V), phosphate, and AG-25, respectively, indicating effective anionic species removal. Kinetic analysis suggested intraparticle diffusion as the rate-limiting step. Thermodynamic parameters and ionic strength effects indicated a physisorption mechanism for AG-25 and surface complexation for As(V) and phosphate. Biodegradation experiments after five adsorption/desorption cycles revealed the membrane’s decomposition, with phosphate’s strong bonding releasing essential elements valuable for soil fertilization. Effluent wastewater treatment demonstrated low environmental impact through the formation of insoluble As(V) salts and photocatalytic dye degradation.",
publisher = "Springer",
journal = "Journal of Polymers and the Environment",
title = "Supplementary material for the article: Abduarahman, M. A.; Vuksanović, M. M.; Milošević, M.; Egelja, A.; Savić, A.; Veličković, Z. ; Marinković, A. Mn-Fe Layered Double Hydroxide Modified CelluloseBased Membrane for Sustainable Anionic Pollutant Removal. Journal of Polymers and the Environment 2024. https://doi.org/10.1007/s10924-024-03192-x",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7333"
}

Abduarahman, M. A., Vuksanović, M. M., Milošević, M., Egelja, A., Savić, A., Veličković, Z.,& Marinković, A.. (2024). Supplementary material for the article: Abduarahman, M. A.; Vuksanović, M. M.; Milošević, M.; Egelja, A.; Savić, A.; Veličković, Z. ; Marinković, A. Mn-Fe Layered Double Hydroxide Modified CelluloseBased Membrane for Sustainable Anionic Pollutant Removal. Journal of Polymers and the Environment 2024. https://doi.org/10.1007/s10924-024-03192-x. in Journal of Polymers and the Environment
Springer..
https://hdl.handle.net/21.15107/rcub_technorep_7333

Abduarahman MA, Vuksanović MM, Milošević M, Egelja A, Savić A, Veličković Z, Marinković A. Supplementary material for the article: Abduarahman, M. A.; Vuksanović, M. M.; Milošević, M.; Egelja, A.; Savić, A.; Veličković, Z. ; Marinković, A. Mn-Fe Layered Double Hydroxide Modified CelluloseBased Membrane for Sustainable Anionic Pollutant Removal. Journal of Polymers and the Environment 2024. https://doi.org/10.1007/s10924-024-03192-x. in Journal of Polymers and the Environment. 2024;.
https://hdl.handle.net/21.15107/rcub_technorep_7333 .

Abduarahman, Muna Abdualatif, Vuksanović, Marija M., Milošević, Milena, Egelja, Adela, Savić, Andrija, Veličković, Zlate, Marinković, Aleksandar, "Supplementary material for the article: Abduarahman, M. A.; Vuksanović, M. M.; Milošević, M.; Egelja, A.; Savić, A.; Veličković, Z. ; Marinković, A. Mn-Fe Layered Double Hydroxide Modified CelluloseBased Membrane for Sustainable Anionic Pollutant Removal. Journal of Polymers and the Environment 2024. https://doi.org/10.1007/s10924-024-03192-x" in Journal of Polymers and the Environment (2024),
https://hdl.handle.net/21.15107/rcub_technorep_7333 .

TY  - JOUR
AU  - Knežević, Nataša
AU  - Milanović, Jovana
AU  - Veličković, Zlate
AU  - Milošević, Milena
AU  - Vuksanović, Marija M.
AU  - Onjia, Antonije
AU  - Marinković, Aleksandar
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6531
AB  - Oxidized cotton linters, TOCell, were used as an adsorbent or derived membrane there from by linters
cross-linking with citric acid. The adsorption/desorption study of Pb2+, methylene blue (MB), and crystal
violet (CV) removal, was performed. Adsorption data fitting, obtained using the Langmuir model, gave
116 mg g 1 (Pb2+), 179 mg g 1 (MB) and 482 mg g 1 (CV) at 25 ℃ for TOCell linters, while 101 mg g 1
(Pb2+), 165 mg g 1 (MB) and 426 mg g 1 (CV) for TOCell membrane. After desorption dyes were subjected
to photocatalytic degradation while lead was transformed into stable lead phthalate (LP), and further
used as filler in composites based on unsaturated polyester resins (UPR). UPR was synthesized from
waste polyethylene terephthalate (PET). Structural characterization was performed using FTIR, SEM,
and NMR methods. Composites loaded with acryloyl modified kraft lignin (A-KfL) and/or LP was tested
for tensile strength, Vickers microhardness, and fire resistance (UL-94 V method). The best mechanical
and fireproofing properties were obtained at 15 wt.% A-KfL and 40 wt.% Al(OH)3 addition. The results
of the toxicity leaching test (TCLP) confirmed the environmentally safe stabilization of desorbed pollutant
in the UPR matrix. Application of environmentally friendly membranes, susceptible to easy biodegradation, had low negative effects to the environment.
PB  - Elsevier B.V.
T2  - Journal of Industrial and Engineering Chemistry
T1  - A closed cycle of sustainable development: Effective removal and desorption of lead and dyes using an oxidized cellulose membrane
EP  - 536
SP  - 520
VL  - 126
DO  - 10.1016/j.jiec.2023.06.041
ER  - 

@article{
author = "Knežević, Nataša and Milanović, Jovana and Veličković, Zlate and Milošević, Milena and Vuksanović, Marija M. and Onjia, Antonije and Marinković, Aleksandar",
year = "2023",
abstract = "Oxidized cotton linters, TOCell, were used as an adsorbent or derived membrane there from by linters
cross-linking with citric acid. The adsorption/desorption study of Pb2+, methylene blue (MB), and crystal
violet (CV) removal, was performed. Adsorption data fitting, obtained using the Langmuir model, gave
116 mg g 1 (Pb2+), 179 mg g 1 (MB) and 482 mg g 1 (CV) at 25 ℃ for TOCell linters, while 101 mg g 1
(Pb2+), 165 mg g 1 (MB) and 426 mg g 1 (CV) for TOCell membrane. After desorption dyes were subjected
to photocatalytic degradation while lead was transformed into stable lead phthalate (LP), and further
used as filler in composites based on unsaturated polyester resins (UPR). UPR was synthesized from
waste polyethylene terephthalate (PET). Structural characterization was performed using FTIR, SEM,
and NMR methods. Composites loaded with acryloyl modified kraft lignin (A-KfL) and/or LP was tested
for tensile strength, Vickers microhardness, and fire resistance (UL-94 V method). The best mechanical
and fireproofing properties were obtained at 15 wt.% A-KfL and 40 wt.% Al(OH)3 addition. The results
of the toxicity leaching test (TCLP) confirmed the environmentally safe stabilization of desorbed pollutant
in the UPR matrix. Application of environmentally friendly membranes, susceptible to easy biodegradation, had low negative effects to the environment.",
publisher = "Elsevier B.V.",
journal = "Journal of Industrial and Engineering Chemistry",
title = "A closed cycle of sustainable development: Effective removal and desorption of lead and dyes using an oxidized cellulose membrane",
pages = "536-520",
volume = "126",
doi = "10.1016/j.jiec.2023.06.041"
}

Knežević, N., Milanović, J., Veličković, Z., Milošević, M., Vuksanović, M. M., Onjia, A.,& Marinković, A.. (2023). A closed cycle of sustainable development: Effective removal and desorption of lead and dyes using an oxidized cellulose membrane. in Journal of Industrial and Engineering Chemistry
Elsevier B.V.., 126, 520-536.
https://doi.org/10.1016/j.jiec.2023.06.041

Knežević N, Milanović J, Veličković Z, Milošević M, Vuksanović MM, Onjia A, Marinković A. A closed cycle of sustainable development: Effective removal and desorption of lead and dyes using an oxidized cellulose membrane. in Journal of Industrial and Engineering Chemistry. 2023;126:520-536.
doi:10.1016/j.jiec.2023.06.041 .

Knežević, Nataša, Milanović, Jovana, Veličković, Zlate, Milošević, Milena, Vuksanović, Marija M., Onjia, Antonije, Marinković, Aleksandar, "A closed cycle of sustainable development: Effective removal and desorption of lead and dyes using an oxidized cellulose membrane" in Journal of Industrial and Engineering Chemistry, 126 (2023):520-536,
https://doi.org/10.1016/j.jiec.2023.06.041 . .

TY  - JOUR
AU  - Salih, Rabab
AU  - Veličković, Zlate
AU  - Milošević, Milena
AU  - Pavlović, Vera P.
AU  - Cvijetić, Ilija
AU  - Sofrenić, Ivana V.
AU  - Gržetić, Jelena D.
AU  - Marinković, Aleksandar
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5275
AB  - Multifunctional lignin bio-based adsorbent, b-LMS, was obtained via inverse copolymerization in the suspension of acryloyl modified kraft lignin (KfL-AA) and bio-based trimethylolpropane triacrylate (bio-TMPTA). Morphological and structural characterization of KfL-AA and b-LMS was performed using BET, FTIR, Raman, NMR, TGA, SEM, and XPS techniques. The b-LMS microspheres with 253 ± 42 μm diameters, 69.4 m2 g−1 surface area, and 59% porosity efficiently adsorb Malachite Green (MG), Tartrazine (T), and Methyl Red (MR) dye. The influence of pH, pollutant concentration, temperature, and time on the removal efficiency was studied in a batch mode. Favorable and spontaneous processes with high adsorption capacities e.g. 116.8 mg g−1 for MG, 86.8 mg g−1 for T, and 68.6 mg g−1 for MR indicate the significant adsorptive potential of b-LMS. Results from diffusional and single mass transfer resistance studies indicate that pore diffusion is a rate-limiting step. Theoretical calculations confirmed a higher affinity of b-LMS to cationic dye MG compared with an anionic and neutral one, i.e. T and MR, respectively. The data fitting from a flow system, using semi-empirical equations and Pore Surface Diffusion Modelling (PSDM) provided breakthrough point determination. The results from the desorption and competitive adsorption study proved the exceptional performance of b-LMS. Moreover, sulfation of b-LMS, i.e.production of b-LMS-OSO3H, introduced high-affinity sulfate groups with respect to cationic dye and cations. Developed methodology implements the principle of sustainable development and offers concept whose results contribute to the minimization of environmental pollution.
PB  - Academic Press
T2  - Journal of Environmental Management
T1  - Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study
SP  - 116838
VL  - 326
DO  - 10.1016/j.jenvman.2022.116838
ER  - 

@article{
author = "Salih, Rabab and Veličković, Zlate and Milošević, Milena and Pavlović, Vera P. and Cvijetić, Ilija and Sofrenić, Ivana V. and Gržetić, Jelena D. and Marinković, Aleksandar",
year = "2023",
abstract = "Multifunctional lignin bio-based adsorbent, b-LMS, was obtained via inverse copolymerization in the suspension of acryloyl modified kraft lignin (KfL-AA) and bio-based trimethylolpropane triacrylate (bio-TMPTA). Morphological and structural characterization of KfL-AA and b-LMS was performed using BET, FTIR, Raman, NMR, TGA, SEM, and XPS techniques. The b-LMS microspheres with 253 ± 42 μm diameters, 69.4 m2 g−1 surface area, and 59% porosity efficiently adsorb Malachite Green (MG), Tartrazine (T), and Methyl Red (MR) dye. The influence of pH, pollutant concentration, temperature, and time on the removal efficiency was studied in a batch mode. Favorable and spontaneous processes with high adsorption capacities e.g. 116.8 mg g−1 for MG, 86.8 mg g−1 for T, and 68.6 mg g−1 for MR indicate the significant adsorptive potential of b-LMS. Results from diffusional and single mass transfer resistance studies indicate that pore diffusion is a rate-limiting step. Theoretical calculations confirmed a higher affinity of b-LMS to cationic dye MG compared with an anionic and neutral one, i.e. T and MR, respectively. The data fitting from a flow system, using semi-empirical equations and Pore Surface Diffusion Modelling (PSDM) provided breakthrough point determination. The results from the desorption and competitive adsorption study proved the exceptional performance of b-LMS. Moreover, sulfation of b-LMS, i.e.production of b-LMS-OSO3H, introduced high-affinity sulfate groups with respect to cationic dye and cations. Developed methodology implements the principle of sustainable development and offers concept whose results contribute to the minimization of environmental pollution.",
publisher = "Academic Press",
journal = "Journal of Environmental Management",
title = "Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study",
pages = "116838",
volume = "326",
doi = "10.1016/j.jenvman.2022.116838"
}

Salih, R., Veličković, Z., Milošević, M., Pavlović, V. P., Cvijetić, I., Sofrenić, I. V., Gržetić, J. D.,& Marinković, A.. (2023). Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study. in Journal of Environmental Management
Academic Press., 326, 116838.
https://doi.org/10.1016/j.jenvman.2022.116838

Salih R, Veličković Z, Milošević M, Pavlović VP, Cvijetić I, Sofrenić IV, Gržetić JD, Marinković A. Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study. in Journal of Environmental Management. 2023;326:116838.
doi:10.1016/j.jenvman.2022.116838 .

Salih, Rabab, Veličković, Zlate, Milošević, Milena, Pavlović, Vera P., Cvijetić, Ilija, Sofrenić, Ivana V., Gržetić, Jelena D., Marinković, Aleksandar, "Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study" in Journal of Environmental Management, 326 (2023):116838,
https://doi.org/10.1016/j.jenvman.2022.116838 . .

TY  - JOUR
AU  - Stojisavljević, Predrag
AU  - Vulović, Nikolina
AU  - Veličković, Zlate
AU  - Mijin, Dušan
AU  - Stupar, Stevan
AU  - Dinić, Denis
AU  - Ivanković, Negovan
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6596
AB  - Adsorption of carbamate pesticide Methomyl by Co-Beta Zeolite particles prepared by wet ion-exchange method from aqueous solutions was studied. The effect of zeolite and pesticide concentrations, pH value, and sintering temperature on pesticide removal from an aqueous solution was studied. The change of methomyl concentration during the adsorption was followed using the UV-Visible spectrophotometer. Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDS) revealed the modified zeolite morphology and elemental structure. The change of the adsorbent surface before and after dye removal was observed using the Fourier Transformation-infrared spectroscopy (FT-IR). The adsorption kinetics follows the pseudo-second-order kinetics model, and at optimal condition adsorption rate is k1 = 0.0166 g mg-1 min-1. The Langmuir, Freundlich, Temkin and Dubinin-Radushkovich adsorption isotherm models were used to describe the adsorption process. Thermodynamic parameters were also determined using experimental data. The thermodynamic study indicates that during pesticide adsorption is, chemisorption and physisorption are present at the same.
PB  - International Institute for the Science of Sintering (IISS)
T2  - Science of Sintering
T1  - Investigation on the Adsorption of the Carbamate Pesticide Methomyl from Aqueous Solution using Modified Co-Beta Zeolite Particles
EP  - 287
IS  - 2
SP  - 269
VL  - 55
DO  - 10.2298/SOS220618004S
ER  - 

@article{
author = "Stojisavljević, Predrag and Vulović, Nikolina and Veličković, Zlate and Mijin, Dušan and Stupar, Stevan and Dinić, Denis and Ivanković, Negovan",
year = "2023",
abstract = "Adsorption of carbamate pesticide Methomyl by Co-Beta Zeolite particles prepared by wet ion-exchange method from aqueous solutions was studied. The effect of zeolite and pesticide concentrations, pH value, and sintering temperature on pesticide removal from an aqueous solution was studied. The change of methomyl concentration during the adsorption was followed using the UV-Visible spectrophotometer. Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDS) revealed the modified zeolite morphology and elemental structure. The change of the adsorbent surface before and after dye removal was observed using the Fourier Transformation-infrared spectroscopy (FT-IR). The adsorption kinetics follows the pseudo-second-order kinetics model, and at optimal condition adsorption rate is k1 = 0.0166 g mg-1 min-1. The Langmuir, Freundlich, Temkin and Dubinin-Radushkovich adsorption isotherm models were used to describe the adsorption process. Thermodynamic parameters were also determined using experimental data. The thermodynamic study indicates that during pesticide adsorption is, chemisorption and physisorption are present at the same.",
publisher = "International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "Investigation on the Adsorption of the Carbamate Pesticide Methomyl from Aqueous Solution using Modified Co-Beta Zeolite Particles",
pages = "287-269",
number = "2",
volume = "55",
doi = "10.2298/SOS220618004S"
}

Stojisavljević, P., Vulović, N., Veličković, Z., Mijin, D., Stupar, S., Dinić, D.,& Ivanković, N.. (2023). Investigation on the Adsorption of the Carbamate Pesticide Methomyl from Aqueous Solution using Modified Co-Beta Zeolite Particles. in Science of Sintering
International Institute for the Science of Sintering (IISS)., 55(2), 269-287.
https://doi.org/10.2298/SOS220618004S

Stojisavljević P, Vulović N, Veličković Z, Mijin D, Stupar S, Dinić D, Ivanković N. Investigation on the Adsorption of the Carbamate Pesticide Methomyl from Aqueous Solution using Modified Co-Beta Zeolite Particles. in Science of Sintering. 2023;55(2):269-287.
doi:10.2298/SOS220618004S .

Stojisavljević, Predrag, Vulović, Nikolina, Veličković, Zlate, Mijin, Dušan, Stupar, Stevan, Dinić, Denis, Ivanković, Negovan, "Investigation on the Adsorption of the Carbamate Pesticide Methomyl from Aqueous Solution using Modified Co-Beta Zeolite Particles" in Science of Sintering, 55, no. 2 (2023):269-287,
https://doi.org/10.2298/SOS220618004S . .

TY  - JOUR
AU  - Popović, Ana L.
AU  - Veličković, Zlate
AU  - Radovanović, Željko
AU  - Đolić, Maja
AU  - Pavlović, Vladimir
AU  - Marinković, Aleksandar D.
AU  - Grzetić, Jelena D.
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5155
AB  - Highly effective lignin-based microspheres were prepared by inverse copolymerization of lignin (kraft) from suspension, with poly(ethylene imine) and amino-functionalized magnetite nanoparticles (A-LMS_Fe3O4) or manganese(IV)oxide nanoparticles (A-LMS_MnO2). The XRD, FTIR, SEM, BET, TEM techniques, including the porosity determination, were performed to analyze morphological and structural properties of synthesized microspheres. The effect of pH, the adsorbent dosage, temperature and contact duration on a batch-mode adsorption efficiency of arsenate and chromate (oxy)anions removal was tested. Spontaneous adsorption was found to be feasible, reaching the adsorption capacities of Cr(VI) (62.9 mg g-1), As(V) (47.8 mg g-1) by A-LMS_Fe3O4, and of Cr(VI) (73.9 mg g-1), As(V) (62.5 mg g-1) using A-LMS_MnO2 adsorbent. Fast removal rates were confirmed via kinetic study, using pseudo-second order, the Weber-Morris and the single resistance mass-transfer model, with a limiting step of the diffusion transport through pores. The correlation of fixed-bed-column results with Bohart-Adams, Thomas, Yoon-Nelson and Dose Response models displayed that breakthrough behavior was influenced by flow rate and the inlet concentration. Significant potential of produced bio-adsorbent is further confirmed by the pore surface diffusion modeling, desorption study and adsorption from multi-component system using artificial water.
PB  - Elsevier Ltd.
T2  - Journal of Environmental Chemical Engineering
T1  - Hybrid amino-terminated lignin microspheres loaded with magnetite and manganese oxide nanoparticles: An effective hazardous oxyanions adsorbent
IS  - 3
SP  - 108009
VL  - 10
DO  - 10.1016/j.jece.2022.108009
ER  - 

@article{
author = "Popović, Ana L. and Veličković, Zlate and Radovanović, Željko and Đolić, Maja and Pavlović, Vladimir and Marinković, Aleksandar D. and Grzetić, Jelena D.",
year = "2022",
abstract = "Highly effective lignin-based microspheres were prepared by inverse copolymerization of lignin (kraft) from suspension, with poly(ethylene imine) and amino-functionalized magnetite nanoparticles (A-LMS_Fe3O4) or manganese(IV)oxide nanoparticles (A-LMS_MnO2). The XRD, FTIR, SEM, BET, TEM techniques, including the porosity determination, were performed to analyze morphological and structural properties of synthesized microspheres. The effect of pH, the adsorbent dosage, temperature and contact duration on a batch-mode adsorption efficiency of arsenate and chromate (oxy)anions removal was tested. Spontaneous adsorption was found to be feasible, reaching the adsorption capacities of Cr(VI) (62.9 mg g-1), As(V) (47.8 mg g-1) by A-LMS_Fe3O4, and of Cr(VI) (73.9 mg g-1), As(V) (62.5 mg g-1) using A-LMS_MnO2 adsorbent. Fast removal rates were confirmed via kinetic study, using pseudo-second order, the Weber-Morris and the single resistance mass-transfer model, with a limiting step of the diffusion transport through pores. The correlation of fixed-bed-column results with Bohart-Adams, Thomas, Yoon-Nelson and Dose Response models displayed that breakthrough behavior was influenced by flow rate and the inlet concentration. Significant potential of produced bio-adsorbent is further confirmed by the pore surface diffusion modeling, desorption study and adsorption from multi-component system using artificial water.",
publisher = "Elsevier Ltd.",
journal = "Journal of Environmental Chemical Engineering",
title = "Hybrid amino-terminated lignin microspheres loaded with magnetite and manganese oxide nanoparticles: An effective hazardous oxyanions adsorbent",
number = "3",
pages = "108009",
volume = "10",
doi = "10.1016/j.jece.2022.108009"
}

Popović, A. L., Veličković, Z., Radovanović, Ž., Đolić, M., Pavlović, V., Marinković, A. D.,& Grzetić, J. D.. (2022). Hybrid amino-terminated lignin microspheres loaded with magnetite and manganese oxide nanoparticles: An effective hazardous oxyanions adsorbent. in Journal of Environmental Chemical Engineering
Elsevier Ltd.., 10(3), 108009.
https://doi.org/10.1016/j.jece.2022.108009

Popović AL, Veličković Z, Radovanović Ž, Đolić M, Pavlović V, Marinković AD, Grzetić JD. Hybrid amino-terminated lignin microspheres loaded with magnetite and manganese oxide nanoparticles: An effective hazardous oxyanions adsorbent. in Journal of Environmental Chemical Engineering. 2022;10(3):108009.
doi:10.1016/j.jece.2022.108009 .

Popović, Ana L., Veličković, Zlate, Radovanović, Željko, Đolić, Maja, Pavlović, Vladimir, Marinković, Aleksandar D., Grzetić, Jelena D., "Hybrid amino-terminated lignin microspheres loaded with magnetite and manganese oxide nanoparticles: An effective hazardous oxyanions adsorbent" in Journal of Environmental Chemical Engineering, 10, no. 3 (2022):108009,
https://doi.org/10.1016/j.jece.2022.108009 . .