Synthesis, processing and applications of nanostructured multifunctional materials with defined properties

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info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS//

Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (en)
Синтеза, развој технологија добијања и примена наноструктурних мултифункционалних материјала дефинисаних својстава (sr)
Sinteza, razvoj tehnologija dobijanja i primena nanostrukturnih multifunkcionalnih materijala definisanih svojstava (sr_RS)
Authors

Publications

C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application

Bjelajac, Anđelika; Petrović, Rada; Stan, George E.; Socol, Gabriel; Mihailescu, Andreea; Mihailescu, Ion N.; Veltruska, Katerina; Matolin, Vladimir; Siketic, Zdravko; Provatas, George; Jaksic, Milko; Janaćković, Đorđe

(2022)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Andreea
AU  - Mihailescu, Ion N.
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketic, Zdravko
AU  - Provatas, George
AU  - Jaksic, Milko
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4996
AB  - Anodization was used to obtain a nanotubular TiO2 photoanode on F-SnO2 glass. Subsequent annealing in the CH4 atmosphere promoted the C-doping and improved the crystallinity of the TiO2 nanotubes. The pulsed laser deposition was applied to cover the nanotubes with Bi2O3, serving as a hole transport material. X-ray photoelectron spectroscopy analyses of the doped samples reveal a shift in the valence band's maximum position towards lower binding energy as compared to those observed for the undoped samples (annealed in the air). The doping positively affects the absorption by shifting the absorption edge to 567 nm. I-V measurements under illumination show that the C-doping of TiO2 increases the current density following the absorbance results. The highest open circuit voltage was reached for the samples with the 300 degrees C-deposited Bi2O3 layer, pointing to better quality of the p-n junction, hence of the contact between Bi2O3 and TiO2. This in situ annealing provided the formation of close contact between Bi2O3 and TiO2, which enabled a faster charge transport as compared to the contact obtained with no annealing or even with post annealing.
T2  - Ceramics International
T1  - C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application
EP  - 4657
IS  - 4
SP  - 4649
VL  - 48
DO  - 10.1016/j.ceramint.2021.10.251
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Stan, George E. and Socol, Gabriel and Mihailescu, Andreea and Mihailescu, Ion N. and Veltruska, Katerina and Matolin, Vladimir and Siketic, Zdravko and Provatas, George and Jaksic, Milko and Janaćković, Đorđe",
year = "2022",
abstract = "Anodization was used to obtain a nanotubular TiO2 photoanode on F-SnO2 glass. Subsequent annealing in the CH4 atmosphere promoted the C-doping and improved the crystallinity of the TiO2 nanotubes. The pulsed laser deposition was applied to cover the nanotubes with Bi2O3, serving as a hole transport material. X-ray photoelectron spectroscopy analyses of the doped samples reveal a shift in the valence band's maximum position towards lower binding energy as compared to those observed for the undoped samples (annealed in the air). The doping positively affects the absorption by shifting the absorption edge to 567 nm. I-V measurements under illumination show that the C-doping of TiO2 increases the current density following the absorbance results. The highest open circuit voltage was reached for the samples with the 300 degrees C-deposited Bi2O3 layer, pointing to better quality of the p-n junction, hence of the contact between Bi2O3 and TiO2. This in situ annealing provided the formation of close contact between Bi2O3 and TiO2, which enabled a faster charge transport as compared to the contact obtained with no annealing or even with post annealing.",
journal = "Ceramics International",
title = "C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application",
pages = "4657-4649",
number = "4",
volume = "48",
doi = "10.1016/j.ceramint.2021.10.251"
}
Bjelajac, A., Petrović, R., Stan, G. E., Socol, G., Mihailescu, A., Mihailescu, I. N., Veltruska, K., Matolin, V., Siketic, Z., Provatas, G., Jaksic, M.,& Janaćković, Đ.. (2022). C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application. in Ceramics International, 48(4), 4649-4657.
https://doi.org/10.1016/j.ceramint.2021.10.251
Bjelajac A, Petrović R, Stan GE, Socol G, Mihailescu A, Mihailescu IN, Veltruska K, Matolin V, Siketic Z, Provatas G, Jaksic M, Janaćković Đ. C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application. in Ceramics International. 2022;48(4):4649-4657.
doi:10.1016/j.ceramint.2021.10.251 .
Bjelajac, Anđelika, Petrović, Rada, Stan, George E., Socol, Gabriel, Mihailescu, Andreea, Mihailescu, Ion N., Veltruska, Katerina, Matolin, Vladimir, Siketic, Zdravko, Provatas, George, Jaksic, Milko, Janaćković, Đorđe, "C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application" in Ceramics International, 48, no. 4 (2022):4649-4657,
https://doi.org/10.1016/j.ceramint.2021.10.251 . .
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The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process

Glišić, Sandra; Orlović, Aleksandar

(2021)

TY  - JOUR
AU  - Glišić, Sandra
AU  - Orlović, Aleksandar
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4849
AB  - Over the years, the hydrotreating process has been considerably improved in order to facilitate the production of environmentally friendly diesel fuels by reducing sulphur and aromatics concentrations, as mandated by contemporary emissions regulations. In this study, different kinetic models for the hydrodearomatisation reaction and the influence of reaction rate on performance of the industrial trickle bed reactor for hydrotreating of gas oil and light cycle oil fractions were analysed. The impact on reactor temperature, catalyst wetting efficiency, and conversion of sulphur and aromatics were determined. The results of simulations were compared with experimental data from an industrial test run and the best model for the observed process is proposed. Reactor performance and overall efficiency of the process is strongly dependent on the kinetics of hydrodearomatisaton with respect to aromatics conversion but even more so with respect to the temperature increase in the reactor, which affects all key catalytic reaction parameters, catalyst wetting efficiency, and thus the sulphur conversion. Based on the obtained simulation results, it could be concluded that reactor performance is strongly dependent on the hydrodearomatisation reaction. The best predictions of outlet temperature as well as sulphur and aromatic conversion (deviation from the experimental value 0.87 K, 0.01% and 2.57%, respectively) are achieved with the Langmuir-Hinshelwood kinetic model proposed by Owusu-Boakye.
T2  - Energies
T1  - The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process
IS  - 15
VL  - 14
DO  - 10.3390/en14154616
ER  - 
@article{
author = "Glišić, Sandra and Orlović, Aleksandar",
year = "2021",
abstract = "Over the years, the hydrotreating process has been considerably improved in order to facilitate the production of environmentally friendly diesel fuels by reducing sulphur and aromatics concentrations, as mandated by contemporary emissions regulations. In this study, different kinetic models for the hydrodearomatisation reaction and the influence of reaction rate on performance of the industrial trickle bed reactor for hydrotreating of gas oil and light cycle oil fractions were analysed. The impact on reactor temperature, catalyst wetting efficiency, and conversion of sulphur and aromatics were determined. The results of simulations were compared with experimental data from an industrial test run and the best model for the observed process is proposed. Reactor performance and overall efficiency of the process is strongly dependent on the kinetics of hydrodearomatisaton with respect to aromatics conversion but even more so with respect to the temperature increase in the reactor, which affects all key catalytic reaction parameters, catalyst wetting efficiency, and thus the sulphur conversion. Based on the obtained simulation results, it could be concluded that reactor performance is strongly dependent on the hydrodearomatisation reaction. The best predictions of outlet temperature as well as sulphur and aromatic conversion (deviation from the experimental value 0.87 K, 0.01% and 2.57%, respectively) are achieved with the Langmuir-Hinshelwood kinetic model proposed by Owusu-Boakye.",
journal = "Energies",
title = "The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process",
number = "15",
volume = "14",
doi = "10.3390/en14154616"
}
Glišić, S.,& Orlović, A.. (2021). The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process. in Energies, 14(15).
https://doi.org/10.3390/en14154616
Glišić S, Orlović A. The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process. in Energies. 2021;14(15).
doi:10.3390/en14154616 .
Glišić, Sandra, Orlović, Aleksandar, "The Influence of Hydrodearomatisation Reaction Kinetics on the Modelling of Sulphur and Aromatics Removal from Diesel Fuel in an Industrial Hydrotreating Process" in Energies, 14, no. 15 (2021),
https://doi.org/10.3390/en14154616 . .
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Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene

Prokić-Vidojević, Dragana; Glišić, Sandra; Krstić, Jugoslav B.; Orlović, Aleksandar

(2021)

TY  - JOUR
AU  - Prokić-Vidojević, Dragana
AU  - Glišić, Sandra
AU  - Krstić, Jugoslav B.
AU  - Orlović, Aleksandar
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4860
AB  - Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 aerogel catalysts were synthesized using sol-gel method and super-critical drying in excess solvent, and investigated in the hydrodesulphurisation (HDS) of dibenzothiophene (DBT) and 4,6-dimethyl dibenzothiophene (4,6-DMDBT). The influence of supercritical drying on the final catalytic properties of the materials was determined by parallel synthesis of aerogels and xerogels for Re/Pd-TiO2/SiO2 catalysts. The sol-gel method and supercritical drying were found to result in amorphous aerogels with relatively high degree of uniformity, of both supports and active phases. Corresponding xerogels were found to be similar to aerogels in terms of composition and structure, but characterized by lower specific surface areas. Catalytic activity of Co/Mo-Al2O3/SiO2 aerogel catalysts in HDS of DBT and 4,6-DMDBT has shown no major improvement in comparison to conventional Co/Mo catalyst. On the other hand, Re/Pd-TiO2/SiO2 aerogels, obtained with the addition of mesitylene or without it, achieved 70 % and 64 % higher conversion of 4,6-DMDBT than conventional Co/Mo catalyst, respectively. Increased catalytic activity can be attributed to well dispersed Re and Pd active phases across the catalyst structure, good incorporation of Ti within silica matrix, increased mesopore volumes and high specific surface areas.
T2  - Catalysis Today
T1  - Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene
EP  - 23
SP  - 10
VL  - 378
DO  - 10.1016/j.cattod.2020.11.022
ER  - 
@article{
author = "Prokić-Vidojević, Dragana and Glišić, Sandra and Krstić, Jugoslav B. and Orlović, Aleksandar",
year = "2021",
abstract = "Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 aerogel catalysts were synthesized using sol-gel method and super-critical drying in excess solvent, and investigated in the hydrodesulphurisation (HDS) of dibenzothiophene (DBT) and 4,6-dimethyl dibenzothiophene (4,6-DMDBT). The influence of supercritical drying on the final catalytic properties of the materials was determined by parallel synthesis of aerogels and xerogels for Re/Pd-TiO2/SiO2 catalysts. The sol-gel method and supercritical drying were found to result in amorphous aerogels with relatively high degree of uniformity, of both supports and active phases. Corresponding xerogels were found to be similar to aerogels in terms of composition and structure, but characterized by lower specific surface areas. Catalytic activity of Co/Mo-Al2O3/SiO2 aerogel catalysts in HDS of DBT and 4,6-DMDBT has shown no major improvement in comparison to conventional Co/Mo catalyst. On the other hand, Re/Pd-TiO2/SiO2 aerogels, obtained with the addition of mesitylene or without it, achieved 70 % and 64 % higher conversion of 4,6-DMDBT than conventional Co/Mo catalyst, respectively. Increased catalytic activity can be attributed to well dispersed Re and Pd active phases across the catalyst structure, good incorporation of Ti within silica matrix, increased mesopore volumes and high specific surface areas.",
journal = "Catalysis Today",
title = "Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene",
pages = "23-10",
volume = "378",
doi = "10.1016/j.cattod.2020.11.022"
}
Prokić-Vidojević, D., Glišić, S., Krstić, J. B.,& Orlović, A.. (2021). Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene. in Catalysis Today, 378, 10-23.
https://doi.org/10.1016/j.cattod.2020.11.022
Prokić-Vidojević D, Glišić S, Krstić JB, Orlović A. Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene. in Catalysis Today. 2021;378:10-23.
doi:10.1016/j.cattod.2020.11.022 .
Prokić-Vidojević, Dragana, Glišić, Sandra, Krstić, Jugoslav B., Orlović, Aleksandar, "Aerogel Re/Pd-TiO2/SiO2 and Co/Mo-Al2O3/SiO2 catalysts for hydrodesulphurisation of dibenzothiophene and 4,6-dimethyldibenzothiophene" in Catalysis Today, 378 (2021):10-23,
https://doi.org/10.1016/j.cattod.2020.11.022 . .
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Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions

Ilić-Pajić, Jovana; Ivaniš, Gorica; Radović, Ivona; Grujić, Aleksandar; Stajić-Trošić, Jasna; Stijepović, Mirko; Kijevčanin, Mirjana

(Academic Press Ltd- Elsevier Science Ltd, London, 2020)

TY  - JOUR
AU  - Ilić-Pajić, Jovana
AU  - Ivaniš, Gorica
AU  - Radović, Ivona
AU  - Grujić, Aleksandar
AU  - Stajić-Trošić, Jasna
AU  - Stijepović, Mirko
AU  - Kijevčanin, Mirjana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4474
AB  - In order to reduce negative influence of fossil fuels on environment, use of various renewable resources is highly promoted. Terpenes, naturally occurring in plants, can be added to petroleum fuel as its substitute up to a certain share. Thermodynamic properties of a fuel under high pressure and moderate temperature conditions are of significant importance for engine efficiency. This work reports density measurements of pure p-cymene, alpha-pinene, limonene and citral at temperatures (293.15-413.15) K and pressures (0.1-60) MPa, applying an Anton Paar DMA HP measuring cell. Density data were fitted by modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was about 0.010%. The obtained parameters were used to estimate the isothermal compressibility, the isobaric thermal expansion coefficient, the internal pressure, and the difference between specific heat capacity at constant pressure and at constant volume. For examined compounds, all thermodynamic properties, except the internal pressure, decrease with pressure rise along an isotherm and increase as temperature increases at a constant pressure. The intersection point of isotherms for the isobaric thermal expansion coefficient for pure citral was registered at pressure 47 MPa, while for other analyzed terpenes the intersection point is above 60 MPa, outside the measurements pressure range.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions
VL  - 144
DO  - 10.1016/j.jct.2020.106065
ER  - 
@article{
author = "Ilić-Pajić, Jovana and Ivaniš, Gorica and Radović, Ivona and Grujić, Aleksandar and Stajić-Trošić, Jasna and Stijepović, Mirko and Kijevčanin, Mirjana",
year = "2020",
abstract = "In order to reduce negative influence of fossil fuels on environment, use of various renewable resources is highly promoted. Terpenes, naturally occurring in plants, can be added to petroleum fuel as its substitute up to a certain share. Thermodynamic properties of a fuel under high pressure and moderate temperature conditions are of significant importance for engine efficiency. This work reports density measurements of pure p-cymene, alpha-pinene, limonene and citral at temperatures (293.15-413.15) K and pressures (0.1-60) MPa, applying an Anton Paar DMA HP measuring cell. Density data were fitted by modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was about 0.010%. The obtained parameters were used to estimate the isothermal compressibility, the isobaric thermal expansion coefficient, the internal pressure, and the difference between specific heat capacity at constant pressure and at constant volume. For examined compounds, all thermodynamic properties, except the internal pressure, decrease with pressure rise along an isotherm and increase as temperature increases at a constant pressure. The intersection point of isotherms for the isobaric thermal expansion coefficient for pure citral was registered at pressure 47 MPa, while for other analyzed terpenes the intersection point is above 60 MPa, outside the measurements pressure range.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions",
volume = "144",
doi = "10.1016/j.jct.2020.106065"
}
Ilić-Pajić, J., Ivaniš, G., Radović, I., Grujić, A., Stajić-Trošić, J., Stijepović, M.,& Kijevčanin, M.. (2020). Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 144.
https://doi.org/10.1016/j.jct.2020.106065
Ilić-Pajić J, Ivaniš G, Radović I, Grujić A, Stajić-Trošić J, Stijepović M, Kijevčanin M. Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions. in Journal of Chemical Thermodynamics. 2020;144.
doi:10.1016/j.jct.2020.106065 .
Ilić-Pajić, Jovana, Ivaniš, Gorica, Radović, Ivona, Grujić, Aleksandar, Stajić-Trošić, Jasna, Stijepović, Mirko, Kijevčanin, Mirjana, "Experimental densities and derived thermodynamic properties of pure p-cymene, alpha-pinene, limonene and citral under high pressure conditions" in Journal of Chemical Thermodynamics, 144 (2020),
https://doi.org/10.1016/j.jct.2020.106065 . .
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6

Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications

Nešović, Katarina; Janković, Ana; Radetić, Tamara; Perić-Grujić, Aleksandra; Vukašinović-Sekulić, Maja; Kojić, Vesna; Rhee, Kyong Yop; Mišković-Stanković, Vesna

(Int Assoc Physical Chemists-Iapc, Zagreb, 2020)

TY  - JOUR
AU  - Nešović, Katarina
AU  - Janković, Ana
AU  - Radetić, Tamara
AU  - Perić-Grujić, Aleksandra
AU  - Vukašinović-Sekulić, Maja
AU  - Kojić, Vesna
AU  - Rhee, Kyong Yop
AU  - Mišković-Stanković, Vesna
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4495
AB  - Polymer-based hydrogel materials are excellent candidates for new-generation wound dressings with improved properties, such as high sorption ability, good mechanical properties and low adhesiveness. Cross-linked hydrogel matrices also serve as excellent carriers for controlled release of antibacterial agents, such as silver nanoparticles (AgNPs), which are preferred over conventional antibiotics due to low propensity to induce bacterial resistance. In this work, we aim to produce novel silver/poly(vinyl alcohol)/chitosan (Ag/PVA/CHI) hydrogels for wound dressing applications. The electrochemical AgNPs synthesis provided facile and green method for the reduction of Ag+ ions inside the hydrogel matrices, without the need to use toxic chemical reducing agents. The formation of AgNPs was confirmed using UV-visible spectroscopy, scanning and transmission electron microscopy. Release kinetics was investigated in modified phosphate buffer solution at 37 degrees C to mimic physiological conditions. Release profiles indicated "burst release" behavior, which is beneficial for wound dressing applications. The antibacterial activity was evaluated against Staphylococcus aureus and Escherichia coli strains using disc-diffusion test, and non-toxicity of hydrogels was proved by dye-exclusion test. The obtained results confirmed strong potential of Ag/PVA/CHI hydrogels for biomedical applications.
PB  - Int Assoc Physical Chemists-Iapc, Zagreb
T2  - Journal of Electrochemical Science and Engineering
T1  - Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications
EP  - 198
IS  - 2
SP  - 185
VL  - 10
DO  - 10.5599/jese.732
ER  - 
@article{
author = "Nešović, Katarina and Janković, Ana and Radetić, Tamara and Perić-Grujić, Aleksandra and Vukašinović-Sekulić, Maja and Kojić, Vesna and Rhee, Kyong Yop and Mišković-Stanković, Vesna",
year = "2020",
abstract = "Polymer-based hydrogel materials are excellent candidates for new-generation wound dressings with improved properties, such as high sorption ability, good mechanical properties and low adhesiveness. Cross-linked hydrogel matrices also serve as excellent carriers for controlled release of antibacterial agents, such as silver nanoparticles (AgNPs), which are preferred over conventional antibiotics due to low propensity to induce bacterial resistance. In this work, we aim to produce novel silver/poly(vinyl alcohol)/chitosan (Ag/PVA/CHI) hydrogels for wound dressing applications. The electrochemical AgNPs synthesis provided facile and green method for the reduction of Ag+ ions inside the hydrogel matrices, without the need to use toxic chemical reducing agents. The formation of AgNPs was confirmed using UV-visible spectroscopy, scanning and transmission electron microscopy. Release kinetics was investigated in modified phosphate buffer solution at 37 degrees C to mimic physiological conditions. Release profiles indicated "burst release" behavior, which is beneficial for wound dressing applications. The antibacterial activity was evaluated against Staphylococcus aureus and Escherichia coli strains using disc-diffusion test, and non-toxicity of hydrogels was proved by dye-exclusion test. The obtained results confirmed strong potential of Ag/PVA/CHI hydrogels for biomedical applications.",
publisher = "Int Assoc Physical Chemists-Iapc, Zagreb",
journal = "Journal of Electrochemical Science and Engineering",
title = "Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications",
pages = "198-185",
number = "2",
volume = "10",
doi = "10.5599/jese.732"
}
Nešović, K., Janković, A., Radetić, T., Perić-Grujić, A., Vukašinović-Sekulić, M., Kojić, V., Rhee, K. Y.,& Mišković-Stanković, V.. (2020). Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications. in Journal of Electrochemical Science and Engineering
Int Assoc Physical Chemists-Iapc, Zagreb., 10(2), 185-198.
https://doi.org/10.5599/jese.732
Nešović K, Janković A, Radetić T, Perić-Grujić A, Vukašinović-Sekulić M, Kojić V, Rhee KY, Mišković-Stanković V. Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications. in Journal of Electrochemical Science and Engineering. 2020;10(2):185-198.
doi:10.5599/jese.732 .
Nešović, Katarina, Janković, Ana, Radetić, Tamara, Perić-Grujić, Aleksandra, Vukašinović-Sekulić, Maja, Kojić, Vesna, Rhee, Kyong Yop, Mišković-Stanković, Vesna, "Poly(vinyl alcohol)/chitosan hydrogels with electrochemically synthesized silver nanoparticles for wound dressing applications" in Journal of Electrochemical Science and Engineering, 10, no. 2 (2020):185-198,
https://doi.org/10.5599/jese.732 . .
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8

Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering

Stevanović, Milena; Đošić, Marija; Janković, Ana; Kojić, Vesna; Vukašinović-Sekulić, Maja; Stojanović, Jovica; Odović, Jadranka; Crevar-Sakač, Milkica; Kyong Yop, Rhee; Mišković-Stanković, Vesna

(Wiley, Hoboken, 2020)

TY  - JOUR
AU  - Stevanović, Milena
AU  - Đošić, Marija
AU  - Janković, Ana
AU  - Kojić, Vesna
AU  - Vukašinović-Sekulić, Maja
AU  - Stojanović, Jovica
AU  - Odović, Jadranka
AU  - Crevar-Sakač, Milkica
AU  - Kyong Yop, Rhee
AU  - Mišković-Stanković, Vesna
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4501
AB  - Electrophoretic deposition process (EPD) was successfully used for obtaining graphene (Gr)-reinforced composite coating based on hydroxyapatite (HAP), chitosan (CS), and antibiotic gentamicin (Gent), from aqueous suspension. The deposition process was performed as a single step process at a constant voltage (5 V, deposition time 12 min) on pure titanium foils. The influence of graphene was examined through detailed physicochemical and biological characterization. Fourier transform infrared spectroscopy, field emission scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, Raman, and X-ray photoelectron analyses confirmed the formation of composite HAP/CS/Gr and HAP/CS/Gr/Gent coatings on Ti. Obtained coatings had porous, uniform, fracture-free surfaces, suggesting strong interfacial interaction between HAP, CS, and Gr. Large specific area of graphene enabled strong bonding with chitosan, acting as nanofiller throughout the polymer matrix. Gentamicin addition strongly improved the antibacterial activity of HAP/CS/Gr/Gent coating that was confirmed by antibacterial activity kinetics in suspension and agar diffusion testing, while results indicated more pronounced antibacterial effect againstStaphylococcus aureus(bactericidal, viable cells number reduction  gt 3 logarithmic units) compared toEscherichia coli(bacteriostatic, lt 3 logarithmic units).MTT assay indicated low cytotoxicity (75% cell viability) against MRC-5 and L929 (70% cell viability) tested cell lines, indicating good biocompatibility of HAP/CS/Gr/Gent coating. Therefore, electrodeposited HAP/CS/Gr/Gent coating on Ti can be considered as a prospective material for bone tissue engineering as a hard tissue implant.
PB  - Wiley, Hoboken
T2  - Journal of Biomedical Materials Research Part A
T1  - Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering
EP  - 2189
IS  - 11
SP  - 2175
VL  - 108
DO  - 10.1002/jbm.a.36974
ER  - 
@article{
author = "Stevanović, Milena and Đošić, Marija and Janković, Ana and Kojić, Vesna and Vukašinović-Sekulić, Maja and Stojanović, Jovica and Odović, Jadranka and Crevar-Sakač, Milkica and Kyong Yop, Rhee and Mišković-Stanković, Vesna",
year = "2020",
abstract = "Electrophoretic deposition process (EPD) was successfully used for obtaining graphene (Gr)-reinforced composite coating based on hydroxyapatite (HAP), chitosan (CS), and antibiotic gentamicin (Gent), from aqueous suspension. The deposition process was performed as a single step process at a constant voltage (5 V, deposition time 12 min) on pure titanium foils. The influence of graphene was examined through detailed physicochemical and biological characterization. Fourier transform infrared spectroscopy, field emission scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, Raman, and X-ray photoelectron analyses confirmed the formation of composite HAP/CS/Gr and HAP/CS/Gr/Gent coatings on Ti. Obtained coatings had porous, uniform, fracture-free surfaces, suggesting strong interfacial interaction between HAP, CS, and Gr. Large specific area of graphene enabled strong bonding with chitosan, acting as nanofiller throughout the polymer matrix. Gentamicin addition strongly improved the antibacterial activity of HAP/CS/Gr/Gent coating that was confirmed by antibacterial activity kinetics in suspension and agar diffusion testing, while results indicated more pronounced antibacterial effect againstStaphylococcus aureus(bactericidal, viable cells number reduction  gt 3 logarithmic units) compared toEscherichia coli(bacteriostatic, lt 3 logarithmic units).MTT assay indicated low cytotoxicity (75% cell viability) against MRC-5 and L929 (70% cell viability) tested cell lines, indicating good biocompatibility of HAP/CS/Gr/Gent coating. Therefore, electrodeposited HAP/CS/Gr/Gent coating on Ti can be considered as a prospective material for bone tissue engineering as a hard tissue implant.",
publisher = "Wiley, Hoboken",
journal = "Journal of Biomedical Materials Research Part A",
title = "Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering",
pages = "2189-2175",
number = "11",
volume = "108",
doi = "10.1002/jbm.a.36974"
}
Stevanović, M., Đošić, M., Janković, A., Kojić, V., Vukašinović-Sekulić, M., Stojanović, J., Odović, J., Crevar-Sakač, M., Kyong Yop, R.,& Mišković-Stanković, V.. (2020). Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering. in Journal of Biomedical Materials Research Part A
Wiley, Hoboken., 108(11), 2175-2189.
https://doi.org/10.1002/jbm.a.36974
Stevanović M, Đošić M, Janković A, Kojić V, Vukašinović-Sekulić M, Stojanović J, Odović J, Crevar-Sakač M, Kyong Yop R, Mišković-Stanković V. Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering. in Journal of Biomedical Materials Research Part A. 2020;108(11):2175-2189.
doi:10.1002/jbm.a.36974 .
Stevanović, Milena, Đošić, Marija, Janković, Ana, Kojić, Vesna, Vukašinović-Sekulić, Maja, Stojanović, Jovica, Odović, Jadranka, Crevar-Sakač, Milkica, Kyong Yop, Rhee, Mišković-Stanković, Vesna, "Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering" in Journal of Biomedical Materials Research Part A, 108, no. 11 (2020):2175-2189,
https://doi.org/10.1002/jbm.a.36974 . .
43
14
41

Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering

Stevanović, Milena; Đošić, Marija; Janković, Ana; Kojić, Vesna; Vukašinović-Sekulić, Maja; Stojanović, Jovica; Odović, Jadranka; Crevar-Sakač, Milkica; Kyong Yop, Rhee; Mišković-Stanković, Vesna

(Wiley, Hoboken, 2020)

TY  - JOUR
AU  - Stevanović, Milena
AU  - Đošić, Marija
AU  - Janković, Ana
AU  - Kojić, Vesna
AU  - Vukašinović-Sekulić, Maja
AU  - Stojanović, Jovica
AU  - Odović, Jadranka
AU  - Crevar-Sakač, Milkica
AU  - Kyong Yop, Rhee
AU  - Mišković-Stanković, Vesna
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4725
AB  - Electrophoretic deposition process (EPD) was successfully used for obtaining graphene (Gr)-reinforced composite coating based on hydroxyapatite (HAP), chitosan (CS), and antibiotic gentamicin (Gent), from aqueous suspension. The deposition process was performed as a single step process at a constant voltage (5 V, deposition time 12 min) on pure titanium foils. The influence of graphene was examined through detailed physicochemical and biological characterization. Fourier transform infrared spectroscopy, field emission scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, Raman, and X-ray photoelectron analyses confirmed the formation of composite HAP/CS/Gr and HAP/CS/Gr/Gent coatings on Ti. Obtained coatings had porous, uniform, fracture-free surfaces, suggesting strong interfacial interaction between HAP, CS, and Gr. Large specific area of graphene enabled strong bonding with chitosan, acting as nanofiller throughout the polymer matrix. Gentamicin addition strongly improved the antibacterial activity of HAP/CS/Gr/Gent coating that was confirmed by antibacterial activity kinetics in suspension and agar diffusion testing, while results indicated more pronounced antibacterial effect againstStaphylococcus aureus(bactericidal, viable cells number reduction  gt 3 logarithmic units) compared toEscherichia coli(bacteriostatic, lt 3 logarithmic units).MTT assay indicated low cytotoxicity (75% cell viability) against MRC-5 and L929 (70% cell viability) tested cell lines, indicating good biocompatibility of HAP/CS/Gr/Gent coating. Therefore, electrodeposited HAP/CS/Gr/Gent coating on Ti can be considered as a prospective material for bone tissue engineering as a hard tissue implant.
PB  - Wiley, Hoboken
T2  - Journal of Biomedical Materials Research Part A
T1  - Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering
EP  - 2189
IS  - 11
SP  - 2175
VL  - 108
DO  - 10.1002/jbm.a.36974
ER  - 
@article{
author = "Stevanović, Milena and Đošić, Marija and Janković, Ana and Kojić, Vesna and Vukašinović-Sekulić, Maja and Stojanović, Jovica and Odović, Jadranka and Crevar-Sakač, Milkica and Kyong Yop, Rhee and Mišković-Stanković, Vesna",
year = "2020",
abstract = "Electrophoretic deposition process (EPD) was successfully used for obtaining graphene (Gr)-reinforced composite coating based on hydroxyapatite (HAP), chitosan (CS), and antibiotic gentamicin (Gent), from aqueous suspension. The deposition process was performed as a single step process at a constant voltage (5 V, deposition time 12 min) on pure titanium foils. The influence of graphene was examined through detailed physicochemical and biological characterization. Fourier transform infrared spectroscopy, field emission scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, Raman, and X-ray photoelectron analyses confirmed the formation of composite HAP/CS/Gr and HAP/CS/Gr/Gent coatings on Ti. Obtained coatings had porous, uniform, fracture-free surfaces, suggesting strong interfacial interaction between HAP, CS, and Gr. Large specific area of graphene enabled strong bonding with chitosan, acting as nanofiller throughout the polymer matrix. Gentamicin addition strongly improved the antibacterial activity of HAP/CS/Gr/Gent coating that was confirmed by antibacterial activity kinetics in suspension and agar diffusion testing, while results indicated more pronounced antibacterial effect againstStaphylococcus aureus(bactericidal, viable cells number reduction  gt 3 logarithmic units) compared toEscherichia coli(bacteriostatic, lt 3 logarithmic units).MTT assay indicated low cytotoxicity (75% cell viability) against MRC-5 and L929 (70% cell viability) tested cell lines, indicating good biocompatibility of HAP/CS/Gr/Gent coating. Therefore, electrodeposited HAP/CS/Gr/Gent coating on Ti can be considered as a prospective material for bone tissue engineering as a hard tissue implant.",
publisher = "Wiley, Hoboken",
journal = "Journal of Biomedical Materials Research Part A",
title = "Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering",
pages = "2189-2175",
number = "11",
volume = "108",
doi = "10.1002/jbm.a.36974"
}
Stevanović, M., Đošić, M., Janković, A., Kojić, V., Vukašinović-Sekulić, M., Stojanović, J., Odović, J., Crevar-Sakač, M., Kyong Yop, R.,& Mišković-Stanković, V.. (2020). Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering. in Journal of Biomedical Materials Research Part A
Wiley, Hoboken., 108(11), 2175-2189.
https://doi.org/10.1002/jbm.a.36974
Stevanović M, Đošić M, Janković A, Kojić V, Vukašinović-Sekulić M, Stojanović J, Odović J, Crevar-Sakač M, Kyong Yop R, Mišković-Stanković V. Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering. in Journal of Biomedical Materials Research Part A. 2020;108(11):2175-2189.
doi:10.1002/jbm.a.36974 .
Stevanović, Milena, Đošić, Marija, Janković, Ana, Kojić, Vesna, Vukašinović-Sekulić, Maja, Stojanović, Jovica, Odović, Jadranka, Crevar-Sakač, Milkica, Kyong Yop, Rhee, Mišković-Stanković, Vesna, "Antibacterial graphene-based hydroxyapatite/chitosan coating with gentamicin for potential applications in bone tissue engineering" in Journal of Biomedical Materials Research Part A, 108, no. 11 (2020):2175-2189,
https://doi.org/10.1002/jbm.a.36974 . .
43
14
44

Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva

Zvicer, Jovana S.

(Универзитет у Београду, Технолошко-металуршки факултет, 2020)

TY  - THES
AU  - Zvicer, Jovana S.
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6348
AB  - Cilj istraživanja u ovoj doktorskoj disertaciji je bila primena biomimičnih bioreaktora zasveobuhvatnu i fiziološki relevantnu karakterizaciju novih bioaktivnih biomaterijala za potencijalnuprimenu u inženjerstvu tkiva, a time i razvoj novih metodologija za pouzdanu evaluacijubiomaterijala. Ispitani su nanokompozitni hidrogelovi alginata sa nanočesticama srebra zainženjerstvo tkiva artikularne hrskavice i hidrogelovi gelanske gume sa nanočesticama bioaktivnogstakla za inženjerstvo tkiva kosti i osteohondralnog tkiva primenom dva biomimična bioreaktora:protočnog i bioreaktora sa dinamičkom kompresijom. Poseban cilj ove disertacije je bio i razvojnovog bioreaktora za inženjerstvo tkiva intervertebralnog diska.Ispitivanja nanokompozitnih Ag/alginatih hidrogelova baziranih na dve vrste alginatapokazala su da polazni sastav alginata utiče na veličinu i kinetiku otpuštanja nanočestica srebra imehaničke karakteristike hidrogelova u fiziološki relevantnim bioreaktorskim uslovima, na osnovukojih je određena njihova potencijalna primena. Kinetika otpuštanja srebra je uspešno modelovanaprenosom mase difuzijom i konvekcijom.Makroporozni hidrogelovi na bazi gelanske gume i bioaktivnog stakla sa otvorenim poramasu dobijeni unapređenom procedurom, a u fiziološki relevantnim uslovima u protočnom bioreaktorudošlo je do značajnog formiranja kalcijum fosfata i poboljšanja mehaničkih karakteristika.Razvijena je i jednostavna metoda za dobijanje dvofaznih osteohondralnih implantata sa dobromintegracijom između slojeva.Rezultati dobijeni u ovoj doktorskoj disertaciji su potvrdili značaj i široki potencijal primenebiomimičnih bioreaktora i sprovedene metodologije u više naučnih oblasti, od razvoja novihbiomaterijala i inženjerstva tkiva do nanotoksikologije i biologije ćelija.
AB  - The aim of this doctoral dissertation was application of biomimetic bioreactors forcomprehensive and physiologically relevant characterization of novel, bioactive biomaterialsintended for tissue engineering (TE), and, consequently development of new methodologies forreliable biomaterial evaluation, as well. The focus was on nanocomposite alginate hydrogels withsilver nanoparticles (AgNPs) for articular cartilage TE and gellan gum hydrogels with bioactiveglass nanoparticles (GG-BAG) for bone and osteochondral TE, while two biomimetic bioreactorswere applied: perfusion and a bioreactor with dynamic compression. The specific goal of thisdissertation was also development of a novel bioreactor for intervertebral disc TE.Investigation of nanocomposite Ag/alginate hydrogels based on two alginate types hasshown that the initial alginate composition affects the size and release kinetics of AgNPs, as well ashydrogel mechanical properties under physiologically relevant bioreactor conditions, whichindicated the potential use for each alginate hydrogel type. The silver release kinetics wassuccessfully modeled by mass transfer by diffusion and advection-diffusion.Macroporous GG-BAG hydrogels with open pores were obtained by a novel procedure.Physiologically relevant conditions in perfusion bioreactors enhanced calcium phosphate formationand improved hydrogel mechanical properties. Also, a simple method was developed for obtainingbiphasic osteochondral implants with good integration between layers.The obtained results indicate the significance and vast potentials of biomimetic bioreactorsand methodologies developed in this doctoral dissertation for applications in different scientificfields from biomaterials science and TE to nanotoxicology and cell biology.
PB  - Универзитет у Београду, Технолошко-металуршки факултет
T2  - Универзитет у Београду
T1  - Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva
UR  - https://hdl.handle.net/21.15107/rcub_nardus_18301
ER  - 
@phdthesis{
author = "Zvicer, Jovana S.",
year = "2020",
abstract = "Cilj istraživanja u ovoj doktorskoj disertaciji je bila primena biomimičnih bioreaktora zasveobuhvatnu i fiziološki relevantnu karakterizaciju novih bioaktivnih biomaterijala za potencijalnuprimenu u inženjerstvu tkiva, a time i razvoj novih metodologija za pouzdanu evaluacijubiomaterijala. Ispitani su nanokompozitni hidrogelovi alginata sa nanočesticama srebra zainženjerstvo tkiva artikularne hrskavice i hidrogelovi gelanske gume sa nanočesticama bioaktivnogstakla za inženjerstvo tkiva kosti i osteohondralnog tkiva primenom dva biomimična bioreaktora:protočnog i bioreaktora sa dinamičkom kompresijom. Poseban cilj ove disertacije je bio i razvojnovog bioreaktora za inženjerstvo tkiva intervertebralnog diska.Ispitivanja nanokompozitnih Ag/alginatih hidrogelova baziranih na dve vrste alginatapokazala su da polazni sastav alginata utiče na veličinu i kinetiku otpuštanja nanočestica srebra imehaničke karakteristike hidrogelova u fiziološki relevantnim bioreaktorskim uslovima, na osnovukojih je određena njihova potencijalna primena. Kinetika otpuštanja srebra je uspešno modelovanaprenosom mase difuzijom i konvekcijom.Makroporozni hidrogelovi na bazi gelanske gume i bioaktivnog stakla sa otvorenim poramasu dobijeni unapređenom procedurom, a u fiziološki relevantnim uslovima u protočnom bioreaktorudošlo je do značajnog formiranja kalcijum fosfata i poboljšanja mehaničkih karakteristika.Razvijena je i jednostavna metoda za dobijanje dvofaznih osteohondralnih implantata sa dobromintegracijom između slojeva.Rezultati dobijeni u ovoj doktorskoj disertaciji su potvrdili značaj i široki potencijal primenebiomimičnih bioreaktora i sprovedene metodologije u više naučnih oblasti, od razvoja novihbiomaterijala i inženjerstva tkiva do nanotoksikologije i biologije ćelija., The aim of this doctoral dissertation was application of biomimetic bioreactors forcomprehensive and physiologically relevant characterization of novel, bioactive biomaterialsintended for tissue engineering (TE), and, consequently development of new methodologies forreliable biomaterial evaluation, as well. The focus was on nanocomposite alginate hydrogels withsilver nanoparticles (AgNPs) for articular cartilage TE and gellan gum hydrogels with bioactiveglass nanoparticles (GG-BAG) for bone and osteochondral TE, while two biomimetic bioreactorswere applied: perfusion and a bioreactor with dynamic compression. The specific goal of thisdissertation was also development of a novel bioreactor for intervertebral disc TE.Investigation of nanocomposite Ag/alginate hydrogels based on two alginate types hasshown that the initial alginate composition affects the size and release kinetics of AgNPs, as well ashydrogel mechanical properties under physiologically relevant bioreactor conditions, whichindicated the potential use for each alginate hydrogel type. The silver release kinetics wassuccessfully modeled by mass transfer by diffusion and advection-diffusion.Macroporous GG-BAG hydrogels with open pores were obtained by a novel procedure.Physiologically relevant conditions in perfusion bioreactors enhanced calcium phosphate formationand improved hydrogel mechanical properties. Also, a simple method was developed for obtainingbiphasic osteochondral implants with good integration between layers.The obtained results indicate the significance and vast potentials of biomimetic bioreactorsand methodologies developed in this doctoral dissertation for applications in different scientificfields from biomaterials science and TE to nanotoxicology and cell biology.",
publisher = "Универзитет у Београду, Технолошко-металуршки факултет",
journal = "Универзитет у Београду",
title = "Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva",
url = "https://hdl.handle.net/21.15107/rcub_nardus_18301"
}
Zvicer, J. S.. (2020). Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva. in Универзитет у Београду
Универзитет у Београду, Технолошко-металуршки факултет..
https://hdl.handle.net/21.15107/rcub_nardus_18301
Zvicer JS. Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva. in Универзитет у Београду. 2020;.
https://hdl.handle.net/21.15107/rcub_nardus_18301 .
Zvicer, Jovana S., "Primena biomimičnih bioreaktora u dizajniranju i karakterizaciji novih biomaterijala za inženjerstvo tkiva" in Универзитет у Београду (2020),
https://hdl.handle.net/21.15107/rcub_nardus_18301 .

Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications

Stojkovska, Jasmina; Zvicer, Jovana; Obradović, Bojana

(Springer, New York, 2020)

TY  - JOUR
AU  - Stojkovska, Jasmina
AU  - Zvicer, Jovana
AU  - Obradović, Bojana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4451
AB  - Nanocomposite hydrogels that contain silver nanoparticles (AgNPs) are especially attractive for various biomedical applications (e.g., antimicrobial wound dressings, coatings and soft tissue implants) due to strong antimicrobial activity of released silver nanoparticles and/or ions over prolonged times. However, all potential biomedical products have to be thoroughly specified fulfilling strict safety requirements. Characterization of nanocomposites is additionally complicated due to potential harmful effects of nanoparticles and accumulation in cells and tissues. This paper summarizes methods for preclinical characterization of hydrogel nanocomposites containing AgNPs with the particular attention on Ag/alginate hydrogels. Standard physicochemical characterization methods include transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force microscopy (AFM), UV-visible spectroscopy, and Fourier transform infrared spectroscopy (FTIR). Functional in vitro characterization relies on different methods for estimation of silver release, antimicrobial activity, and nanocomposite cytotoxicity. Here, we specially focus on utilization of 3D bioreactor systems that mimic native physiological environments with the aim to reliably predict nanocomposite behavior during implementation and so to decrease the need for animal experimentation. These systems were shown to provide more accurate and relevant data on silver release and cytotoxicity as compared to static systems such as 2D cell monolayer cultures. Finally, nanocomposites are evaluated in vivo in different animal models, which are in the case of wound dressings typically mice, rats, and pigs. The present review provides a basis for defining a strategy for comprehensive and efficient preclinical characterization of novel nanocomposites attractive not only for those containing AgNPs but also other metallic nanoparticles aimed for biomedical applications. Key points center dot A platform for devising comprehensive preclinical evaluation of nanocomposites. center dot Biomimetic bioreactors provide reliable functional nanocomposite evaluation. center dot Cells in 2D cultures are more sensitive to silver nanoparticles than in 3D cultures. center dot Biomimetic bioreactor 3D cell/tissue cultures can address the in vitro-in vivo gap.
PB  - Springer, New York
T2  - Applied Microbiology and Biotechnology
T1  - Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications
EP  - 4658
IS  - 11
SP  - 4643
VL  - 104
DO  - 10.1007/s00253-020-10521-2
ER  - 
@article{
author = "Stojkovska, Jasmina and Zvicer, Jovana and Obradović, Bojana",
year = "2020",
abstract = "Nanocomposite hydrogels that contain silver nanoparticles (AgNPs) are especially attractive for various biomedical applications (e.g., antimicrobial wound dressings, coatings and soft tissue implants) due to strong antimicrobial activity of released silver nanoparticles and/or ions over prolonged times. However, all potential biomedical products have to be thoroughly specified fulfilling strict safety requirements. Characterization of nanocomposites is additionally complicated due to potential harmful effects of nanoparticles and accumulation in cells and tissues. This paper summarizes methods for preclinical characterization of hydrogel nanocomposites containing AgNPs with the particular attention on Ag/alginate hydrogels. Standard physicochemical characterization methods include transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force microscopy (AFM), UV-visible spectroscopy, and Fourier transform infrared spectroscopy (FTIR). Functional in vitro characterization relies on different methods for estimation of silver release, antimicrobial activity, and nanocomposite cytotoxicity. Here, we specially focus on utilization of 3D bioreactor systems that mimic native physiological environments with the aim to reliably predict nanocomposite behavior during implementation and so to decrease the need for animal experimentation. These systems were shown to provide more accurate and relevant data on silver release and cytotoxicity as compared to static systems such as 2D cell monolayer cultures. Finally, nanocomposites are evaluated in vivo in different animal models, which are in the case of wound dressings typically mice, rats, and pigs. The present review provides a basis for defining a strategy for comprehensive and efficient preclinical characterization of novel nanocomposites attractive not only for those containing AgNPs but also other metallic nanoparticles aimed for biomedical applications. Key points center dot A platform for devising comprehensive preclinical evaluation of nanocomposites. center dot Biomimetic bioreactors provide reliable functional nanocomposite evaluation. center dot Cells in 2D cultures are more sensitive to silver nanoparticles than in 3D cultures. center dot Biomimetic bioreactor 3D cell/tissue cultures can address the in vitro-in vivo gap.",
publisher = "Springer, New York",
journal = "Applied Microbiology and Biotechnology",
title = "Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications",
pages = "4658-4643",
number = "11",
volume = "104",
doi = "10.1007/s00253-020-10521-2"
}
Stojkovska, J., Zvicer, J.,& Obradović, B.. (2020). Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications. in Applied Microbiology and Biotechnology
Springer, New York., 104(11), 4643-4658.
https://doi.org/10.1007/s00253-020-10521-2
Stojkovska J, Zvicer J, Obradović B. Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications. in Applied Microbiology and Biotechnology. 2020;104(11):4643-4658.
doi:10.1007/s00253-020-10521-2 .
Stojkovska, Jasmina, Zvicer, Jovana, Obradović, Bojana, "Preclinical functional characterization methods of nanocomposite hydrogels containing silver nanoparticles for biomedical applications" in Applied Microbiology and Biotechnology, 104, no. 11 (2020):4643-4658,
https://doi.org/10.1007/s00253-020-10521-2 . .
12
5
11

Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal

Popović, Ana L.; Rusmirović, Jelena; Veličković, Zlate; Radovanović, Željko; Ristić, Mirjana; Pavlović, Vera P.; Marinković, Aleksandar

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Popović, Ana L.
AU  - Rusmirović, Jelena
AU  - Veličković, Zlate
AU  - Radovanović, Željko
AU  - Ristić, Mirjana
AU  - Pavlović, Vera P.
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4540
AB  - Novel highly effective amino-functionalized lignin-based biosorbent in the microsphere geometry (A-LMS) for removal of heavy metal ions, was synthesized via inverse suspension copolymerization of kraft lignin with poly(ethylene imine) grafting-agent and epoxy chloropropane cross-linker. Optimization of A-LMS synthesis, performed with respect to the quantity of sodium alginate emulsifier (1, 5 and 10 wt%), provides highly porous microspheres A-LMS_5, using 5 wt% emulsifier, with 800 +/- 80 mu m diameter, 7.68 m(2) g(-1) surface area and 7.7 mmol g(-1) of terminal amino groups. Structural and surface characteristics were obtained from Brunauer-Emmett-Teller method, Fourier Transform-Infrared spectroscopy, scanning electron microscopy, X-ray photo-electron spectroscopy and porosity determination. In a batch test, the influence of pH, A-LMS_5 dose, temperature, contact time on adsorption efficiency of Ni2+, Cd2+, As(V) and Cr(VI) ions were studied. The adsorption is spontaneous and feasible with maximum adsorption capacity of 74.84, 54.20, 53.12 and 49.42 mg g(-1) for Cd2+, Cr(VI), As(V) and Ni2+ ions, respectively, obtained by using Langmuir model. Modeling of kinetic data indicated fast adsorbate removal rate with pore diffusional transport as rate limiting step (pseudo-second order model and Weber-Morris equations), thus further confirming high performances of produced bio-adsorbent for heavy metal ions removal.
PB  - Elsevier, Amsterdam
T2  - International Journal of Biological Macromolecules
T1  - Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal
EP  - 1173
SP  - 1160
VL  - 156
DO  - 10.1016/j.ijbiomac.2019.11.152
ER  - 
@article{
author = "Popović, Ana L. and Rusmirović, Jelena and Veličković, Zlate and Radovanović, Željko and Ristić, Mirjana and Pavlović, Vera P. and Marinković, Aleksandar",
year = "2020",
abstract = "Novel highly effective amino-functionalized lignin-based biosorbent in the microsphere geometry (A-LMS) for removal of heavy metal ions, was synthesized via inverse suspension copolymerization of kraft lignin with poly(ethylene imine) grafting-agent and epoxy chloropropane cross-linker. Optimization of A-LMS synthesis, performed with respect to the quantity of sodium alginate emulsifier (1, 5 and 10 wt%), provides highly porous microspheres A-LMS_5, using 5 wt% emulsifier, with 800 +/- 80 mu m diameter, 7.68 m(2) g(-1) surface area and 7.7 mmol g(-1) of terminal amino groups. Structural and surface characteristics were obtained from Brunauer-Emmett-Teller method, Fourier Transform-Infrared spectroscopy, scanning electron microscopy, X-ray photo-electron spectroscopy and porosity determination. In a batch test, the influence of pH, A-LMS_5 dose, temperature, contact time on adsorption efficiency of Ni2+, Cd2+, As(V) and Cr(VI) ions were studied. The adsorption is spontaneous and feasible with maximum adsorption capacity of 74.84, 54.20, 53.12 and 49.42 mg g(-1) for Cd2+, Cr(VI), As(V) and Ni2+ ions, respectively, obtained by using Langmuir model. Modeling of kinetic data indicated fast adsorbate removal rate with pore diffusional transport as rate limiting step (pseudo-second order model and Weber-Morris equations), thus further confirming high performances of produced bio-adsorbent for heavy metal ions removal.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Biological Macromolecules",
title = "Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal",
pages = "1173-1160",
volume = "156",
doi = "10.1016/j.ijbiomac.2019.11.152"
}
Popović, A. L., Rusmirović, J., Veličković, Z., Radovanović, Ž., Ristić, M., Pavlović, V. P.,& Marinković, A.. (2020). Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. in International Journal of Biological Macromolecules
Elsevier, Amsterdam., 156, 1160-1173.
https://doi.org/10.1016/j.ijbiomac.2019.11.152
Popović AL, Rusmirović J, Veličković Z, Radovanović Ž, Ristić M, Pavlović VP, Marinković A. Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. in International Journal of Biological Macromolecules. 2020;156:1160-1173.
doi:10.1016/j.ijbiomac.2019.11.152 .
Popović, Ana L., Rusmirović, Jelena, Veličković, Zlate, Radovanović, Željko, Ristić, Mirjana, Pavlović, Vera P., Marinković, Aleksandar, "Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal" in International Journal of Biological Macromolecules, 156 (2020):1160-1173,
https://doi.org/10.1016/j.ijbiomac.2019.11.152 . .
1
52
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51

Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites

Ćurčić, Milica; Hadžić, Branka; Gilić, Martina; Radojević, Vesna; Bjelajac, Anđelika; Radović, Ivana; Timotijević, Dejan; Romčević, Maja J.; Trajić, Jelena; Romčević, Nebojša Ž.

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Ćurčić, Milica
AU  - Hadžić, Branka
AU  - Gilić, Martina
AU  - Radojević, Vesna
AU  - Bjelajac, Anđelika
AU  - Radović, Ivana
AU  - Timotijević, Dejan
AU  - Romčević, Maja J.
AU  - Trajić, Jelena
AU  - Romčević, Nebojša Ž.
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4459
AB  - The polymer nanocomposite ZnS/Poly (methylmethacrylate) was prepared by the solution casting method and its structural and optical properties were investigated using XRD, SEM, TEM, HRTEM, and Raman spectroscopy. The basic material, ZnS, has the cubic structure and its crystallite size was estimated to be 2.3 nm, which implies that a strong confinement regime is in effect. Analysis of Raman spectra was performed using the fitting procedure based on effective medium theory. As a result, the surface optical phonon (SOP) mode was detected. It was found that the shape and position of the SOP mode depend on the type of the composite.
PB  - Elsevier, Amsterdam
T2  - Physica E-Low-Dimensional Systems & Nanostructures
T1  - Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites
VL  - 115
DO  - 10.1016/j.physe.2019.113708
ER  - 
@article{
author = "Ćurčić, Milica and Hadžić, Branka and Gilić, Martina and Radojević, Vesna and Bjelajac, Anđelika and Radović, Ivana and Timotijević, Dejan and Romčević, Maja J. and Trajić, Jelena and Romčević, Nebojša Ž.",
year = "2020",
abstract = "The polymer nanocomposite ZnS/Poly (methylmethacrylate) was prepared by the solution casting method and its structural and optical properties were investigated using XRD, SEM, TEM, HRTEM, and Raman spectroscopy. The basic material, ZnS, has the cubic structure and its crystallite size was estimated to be 2.3 nm, which implies that a strong confinement regime is in effect. Analysis of Raman spectra was performed using the fitting procedure based on effective medium theory. As a result, the surface optical phonon (SOP) mode was detected. It was found that the shape and position of the SOP mode depend on the type of the composite.",
publisher = "Elsevier, Amsterdam",
journal = "Physica E-Low-Dimensional Systems & Nanostructures",
title = "Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites",
volume = "115",
doi = "10.1016/j.physe.2019.113708"
}
Ćurčić, M., Hadžić, B., Gilić, M., Radojević, V., Bjelajac, A., Radović, I., Timotijević, D., Romčević, M. J., Trajić, J.,& Romčević, N. Ž.. (2020). Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites. in Physica E-Low-Dimensional Systems & Nanostructures
Elsevier, Amsterdam., 115.
https://doi.org/10.1016/j.physe.2019.113708
Ćurčić M, Hadžić B, Gilić M, Radojević V, Bjelajac A, Radović I, Timotijević D, Romčević MJ, Trajić J, Romčević NŽ. Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites. in Physica E-Low-Dimensional Systems & Nanostructures. 2020;115.
doi:10.1016/j.physe.2019.113708 .
Ćurčić, Milica, Hadžić, Branka, Gilić, Martina, Radojević, Vesna, Bjelajac, Anđelika, Radović, Ivana, Timotijević, Dejan, Romčević, Maja J., Trajić, Jelena, Romčević, Nebojša Ž., "Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites" in Physica E-Low-Dimensional Systems & Nanostructures, 115 (2020),
https://doi.org/10.1016/j.physe.2019.113708 . .
3
1
3

Guidelines for general adsorption kinetics modeling

Obradović, Bojana

(Savez hemijskih inženjera, Beograd, 2020)

TY  - JOUR
AU  - Obradović, Bojana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4488
AB  - Adsorption processes are widely used in different technological areas and industry sectors, thus continuously attracting attention in the scientific research and publications. Design and scale-up of these processes are essentially based on the knowledge and understanding of the adsorption kinetics and mechanism. Adsorption kinetics is usually modeled by using several well-known models including the pseudo-first and pseudo-second order models, the Elovich equation, and the intra-particle diffusion based models. However, in the scientific literature there are a significant number of cases with the inappropriate use of these models, utilization of erroneous expressions, and incorrect interpretation of the obtained results. This paper is especially focused on applications of the pseudo-second order, intra-particle diffusion and the Weber-Morris models, which are illustrated with typical examples. Finally, general recommendations for selection of the appropriate kinetic model and model assumptions, data regression analysis, and evaluation and presentation of the obtained results are outlined.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Guidelines for general adsorption kinetics modeling
EP  - 70
IS  - 1
SP  - 65
VL  - 74
DO  - 10.2298/HEMIND200201006O
ER  - 
@article{
author = "Obradović, Bojana",
year = "2020",
abstract = "Adsorption processes are widely used in different technological areas and industry sectors, thus continuously attracting attention in the scientific research and publications. Design and scale-up of these processes are essentially based on the knowledge and understanding of the adsorption kinetics and mechanism. Adsorption kinetics is usually modeled by using several well-known models including the pseudo-first and pseudo-second order models, the Elovich equation, and the intra-particle diffusion based models. However, in the scientific literature there are a significant number of cases with the inappropriate use of these models, utilization of erroneous expressions, and incorrect interpretation of the obtained results. This paper is especially focused on applications of the pseudo-second order, intra-particle diffusion and the Weber-Morris models, which are illustrated with typical examples. Finally, general recommendations for selection of the appropriate kinetic model and model assumptions, data regression analysis, and evaluation and presentation of the obtained results are outlined.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Guidelines for general adsorption kinetics modeling",
pages = "70-65",
number = "1",
volume = "74",
doi = "10.2298/HEMIND200201006O"
}
Obradović, B.. (2020). Guidelines for general adsorption kinetics modeling. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 74(1), 65-70.
https://doi.org/10.2298/HEMIND200201006O
Obradović B. Guidelines for general adsorption kinetics modeling. in Hemijska industrija. 2020;74(1):65-70.
doi:10.2298/HEMIND200201006O .
Obradović, Bojana, "Guidelines for general adsorption kinetics modeling" in Hemijska industrija, 74, no. 1 (2020):65-70,
https://doi.org/10.2298/HEMIND200201006O . .
1
29
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25

Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance

Stojanović, Dušica; Brajović, Ljiljana; Obradović, Vera; Mijailović, Daniel; Dramlić, Dragan; Kojović, Aleksandar; Uskoković, Petar

(Elsevier B.V., 2020)

TY  - JOUR
AU  - Stojanović, Dušica
AU  - Brajović, Ljiljana
AU  - Obradović, Vera
AU  - Mijailović, Daniel
AU  - Dramlić, Dragan
AU  - Kojović, Aleksandar
AU  - Uskoković, Petar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4454
AB  - The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermo-mechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55% with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75-80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones.
PB  - Elsevier B.V.
T2  - Progress in Organic Coatings
T1  - Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance
SP  - 105437
VL  - 139
DO  - 10.1016/j.porgcoat.2019.105437
ER  - 
@article{
author = "Stojanović, Dušica and Brajović, Ljiljana and Obradović, Vera and Mijailović, Daniel and Dramlić, Dragan and Kojović, Aleksandar and Uskoković, Petar",
year = "2020",
abstract = "The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermo-mechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55% with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75-80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones.",
publisher = "Elsevier B.V.",
journal = "Progress in Organic Coatings",
title = "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance",
pages = "105437",
volume = "139",
doi = "10.1016/j.porgcoat.2019.105437"
}
Stojanović, D., Brajović, L., Obradović, V., Mijailović, D., Dramlić, D., Kojović, A.,& Uskoković, P.. (2020). Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings
Elsevier B.V.., 139, 105437.
https://doi.org/10.1016/j.porgcoat.2019.105437
Stojanović D, Brajović L, Obradović V, Mijailović D, Dramlić D, Kojović A, Uskoković P. Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings. 2020;139:105437.
doi:10.1016/j.porgcoat.2019.105437 .
Stojanović, Dušica, Brajović, Ljiljana, Obradović, Vera, Mijailović, Daniel, Dramlić, Dragan, Kojović, Aleksandar, Uskoković, Petar, "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance" in Progress in Organic Coatings, 139 (2020):105437,
https://doi.org/10.1016/j.porgcoat.2019.105437 . .
4
5
2
4

Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation

Bebić, Jelena; Banjanac, Katarina; Ćorović, Marija; Milivojević, Ana; Simović, Milica; Marinković, Aleksandar; Bezbradica, Dejan

(Chemical Industry Press Co Ltd, Beijing, 2020)

TY  - JOUR
AU  - Bebić, Jelena
AU  - Banjanac, Katarina
AU  - Ćorović, Marija
AU  - Milivojević, Ana
AU  - Simović, Milica
AU  - Marinković, Aleksandar
AU  - Bezbradica, Dejan
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4384
AB  - This work is focused on immobilization of laccase from Myceliophthora thermophila expressed in Aspergillus oiyzae (Novozym 51003 (R) laccase) on amino modified fumed nano-silica (AFNS) and the possible use in bioremediation. Hereby, for the first time, factors affecting the immobilization of Novozym 51003 (R) laccase on AFNS were investigated for defining the immobilization mechanism and optimizing the utilization of AFNS as support for laccase immobilization. The highest specific activity (13.1 IU.mg(-1) proteins) was achieved at offered 160 mg per g of AFNS and for the same offered protein concentration the highest activity immobilization yield, reaching 68.3% after the equilibrium time, at optimum pH 5.0, was obtained. Laccase immobilization occurs by adsorption as monolayer enzyme binding in 40 min, following pseudo-first-order kinetics. The possible use of obtained immobilized preparation was investigated in degradation of pesticide lindane. Within 24 h, lindane concentration was reduced to 56.8% of initial concentration and after seven repeated reuses it retained 70% of the original activity.
PB  - Chemical Industry Press Co Ltd, Beijing
T2  - Chinese Journal of Chemical Engineering
T1  - Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation
EP  - 1144
IS  - 4
SP  - 1136
VL  - 28
DO  - 10.1016/j.cjche.2019.12.025
ER  - 
@article{
author = "Bebić, Jelena and Banjanac, Katarina and Ćorović, Marija and Milivojević, Ana and Simović, Milica and Marinković, Aleksandar and Bezbradica, Dejan",
year = "2020",
abstract = "This work is focused on immobilization of laccase from Myceliophthora thermophila expressed in Aspergillus oiyzae (Novozym 51003 (R) laccase) on amino modified fumed nano-silica (AFNS) and the possible use in bioremediation. Hereby, for the first time, factors affecting the immobilization of Novozym 51003 (R) laccase on AFNS were investigated for defining the immobilization mechanism and optimizing the utilization of AFNS as support for laccase immobilization. The highest specific activity (13.1 IU.mg(-1) proteins) was achieved at offered 160 mg per g of AFNS and for the same offered protein concentration the highest activity immobilization yield, reaching 68.3% after the equilibrium time, at optimum pH 5.0, was obtained. Laccase immobilization occurs by adsorption as monolayer enzyme binding in 40 min, following pseudo-first-order kinetics. The possible use of obtained immobilized preparation was investigated in degradation of pesticide lindane. Within 24 h, lindane concentration was reduced to 56.8% of initial concentration and after seven repeated reuses it retained 70% of the original activity.",
publisher = "Chemical Industry Press Co Ltd, Beijing",
journal = "Chinese Journal of Chemical Engineering",
title = "Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation",
pages = "1144-1136",
number = "4",
volume = "28",
doi = "10.1016/j.cjche.2019.12.025"
}
Bebić, J., Banjanac, K., Ćorović, M., Milivojević, A., Simović, M., Marinković, A.,& Bezbradica, D.. (2020). Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation. in Chinese Journal of Chemical Engineering
Chemical Industry Press Co Ltd, Beijing., 28(4), 1136-1144.
https://doi.org/10.1016/j.cjche.2019.12.025
Bebić J, Banjanac K, Ćorović M, Milivojević A, Simović M, Marinković A, Bezbradica D. Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation. in Chinese Journal of Chemical Engineering. 2020;28(4):1136-1144.
doi:10.1016/j.cjche.2019.12.025 .
Bebić, Jelena, Banjanac, Katarina, Ćorović, Marija, Milivojević, Ana, Simović, Milica, Marinković, Aleksandar, Bezbradica, Dejan, "Immobilization of laccase from Myceliophthora thermophila on functionalized silica nanoparticles: Optimization and application in lindane degradation" in Chinese Journal of Chemical Engineering, 28, no. 4 (2020):1136-1144,
https://doi.org/10.1016/j.cjche.2019.12.025 . .
34
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30

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Bjelajac, Anđelika; Petrović, Rada; Vujančević, Jelena; Veltruska, Katerina; Matolin, Vladimir; Siketić, Zdravko; Provatas, George; Jakšić, Milko; Stan, George E.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Pergamon-Elsevier Science Ltd, Oxford, 2020)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Vujančević, Jelena
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketić, Zdravko
AU  - Provatas, George
AU  - Jakšić, Milko
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4723
AB  - We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes' surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Journal of Physics and Chemistry of Solids
T1  - Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye
VL  - 147
DO  - 10.1016/j.jpcs.2020.109609
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Vujančević, Jelena and Veltruska, Katerina and Matolin, Vladimir and Siketić, Zdravko and Provatas, George and Jakšić, Milko and Stan, George E. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2020",
abstract = "We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes' surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Journal of Physics and Chemistry of Solids",
title = "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye",
volume = "147",
doi = "10.1016/j.jpcs.2020.109609"
}
Bjelajac, A., Petrović, R., Vujančević, J., Veltruska, K., Matolin, V., Siketić, Z., Provatas, G., Jakšić, M., Stan, G. E., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2020). Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye. in Journal of Physics and Chemistry of Solids
Pergamon-Elsevier Science Ltd, Oxford., 147.
https://doi.org/10.1016/j.jpcs.2020.109609
Bjelajac A, Petrović R, Vujančević J, Veltruska K, Matolin V, Siketić Z, Provatas G, Jakšić M, Stan GE, Socol G, Mihailescu IN, Janaćković Đ. Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye. in Journal of Physics and Chemistry of Solids. 2020;147.
doi:10.1016/j.jpcs.2020.109609 .
Bjelajac, Anđelika, Petrović, Rada, Vujančević, Jelena, Veltruska, Katerina, Matolin, Vladimir, Siketić, Zdravko, Provatas, George, Jakšić, Milko, Stan, George E., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye" in Journal of Physics and Chemistry of Solids, 147 (2020),
https://doi.org/10.1016/j.jpcs.2020.109609 . .
18
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19

alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility

Kazuz, A.; Radovanović, Željko; Veljović, Đorđe; Kojić, Vesna; Miletić, Vesna; Petrović, Rada; Janaćković, Đorđe

(Elsevier Sci Ltd, Oxford, 2020)

TY  - JOUR
AU  - Kazuz, A.
AU  - Radovanović, Željko
AU  - Veljović, Đorđe
AU  - Kojić, Vesna
AU  - Miletić, Vesna
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4371
AB  - Composite cements based on alpha-tricalcium phosphate (alpha-TCP) and nanostructured fluorapatite (FAp), alpha-TCP/FAp, appropriate for dental usage as root canal filling material, have been prepared with the improved mechanical properties and biocompatibility. The influence of FAp concentration on the composite cement properties was investigated. The processing conditions for FAp powders synthesis were optimized and the powder with optimal properties was chosen to obtain alpha-TCP/FAp composite types of cement alpha-TCP powder was prepared by calcination of hydrothermally synthesized hydroxyapatite (HAp) at 1500 degrees C for 2 h. Morphology and phase composition of powders were investigated by X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDS). Soaking of alpha-TCP/FAp specimens in simulated body fluid (SBF) affected the successful transformation of alpha-TCP into HAp, while the compressive test revealed the influence of this transformation and FAp content on the mechanical properties of the composites. Specimen containing 5% of FAp after 10 days in SBF showed the highest compressive strength. In vitro MIT and DET biocompatibility tests, performed in the culture of MRC-5 human fibroblast cells, revealed that alpha-TCP/FAp had no cytotoxic effect. These initial findings showed that alpha-TCP/FAp composite cements could yield favorable mechanical properties with no adverse effect on biocompatibility.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility
IS  - 16
VL  - 46
DO  - 10.1016/j.ceramint.2020.06.301
ER  - 
@article{
author = "Kazuz, A. and Radovanović, Željko and Veljović, Đorđe and Kojić, Vesna and Miletić, Vesna and Petrović, Rada and Janaćković, Đorđe",
year = "2020",
abstract = "Composite cements based on alpha-tricalcium phosphate (alpha-TCP) and nanostructured fluorapatite (FAp), alpha-TCP/FAp, appropriate for dental usage as root canal filling material, have been prepared with the improved mechanical properties and biocompatibility. The influence of FAp concentration on the composite cement properties was investigated. The processing conditions for FAp powders synthesis were optimized and the powder with optimal properties was chosen to obtain alpha-TCP/FAp composite types of cement alpha-TCP powder was prepared by calcination of hydrothermally synthesized hydroxyapatite (HAp) at 1500 degrees C for 2 h. Morphology and phase composition of powders were investigated by X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDS). Soaking of alpha-TCP/FAp specimens in simulated body fluid (SBF) affected the successful transformation of alpha-TCP into HAp, while the compressive test revealed the influence of this transformation and FAp content on the mechanical properties of the composites. Specimen containing 5% of FAp after 10 days in SBF showed the highest compressive strength. In vitro MIT and DET biocompatibility tests, performed in the culture of MRC-5 human fibroblast cells, revealed that alpha-TCP/FAp had no cytotoxic effect. These initial findings showed that alpha-TCP/FAp composite cements could yield favorable mechanical properties with no adverse effect on biocompatibility.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility",
number = "16",
volume = "46",
doi = "10.1016/j.ceramint.2020.06.301"
}
Kazuz, A., Radovanović, Ž., Veljović, Đ., Kojić, V., Miletić, V., Petrović, R.,& Janaćković, Đ.. (2020). alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility. in Ceramics International
Elsevier Sci Ltd, Oxford., 46(16).
https://doi.org/10.1016/j.ceramint.2020.06.301
Kazuz A, Radovanović Ž, Veljović Đ, Kojić V, Miletić V, Petrović R, Janaćković Đ. alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility. in Ceramics International. 2020;46(16).
doi:10.1016/j.ceramint.2020.06.301 .
Kazuz, A., Radovanović, Željko, Veljović, Đorđe, Kojić, Vesna, Miletić, Vesna, Petrović, Rada, Janaćković, Đorđe, "alpha-Tricalcium phosphate/fluorapatite based composite cements: Synthesis, mechanical properties, and biocompatibility" in Ceramics International, 46, no. 16 (2020),
https://doi.org/10.1016/j.ceramint.2020.06.301 . .
5
6

Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag

Nikolić, Irena; Đurović, Dijana; Tadić, Milena; Radmilović, Vuk; Radmilović, Velimir R.

(Taylor & Francis Inc, Philadelphia, 2020)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Đurović, Dijana
AU  - Tadić, Milena
AU  - Radmilović, Vuk
AU  - Radmilović, Velimir R.
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4356
AB  - Two adsorbents, pristine electric arc furnace slag (EAFS) and alkali activated slag (AAS) were used for Cu2+ removal from aquatic solutions. Batch adsorption tests were conducted at various temperatures and initial Cu2+ concentrations, while solid to liquid ratio and pH of solution were kept constant. Pseudo-first-order and pseudo-second-order (PSO) kinetics models, Langmuir and Freundlich isotherm models, as well as intraparticle and Boyd's diffusion models were applied in order to investigate the adsorption process. It has been found that alkali activation of EAFS leads to an increase in the specific surface of slag and thus improves the sorption properties of EAFS. The adsorption of Cu2+ onto both adsorbents proceeds via PSO adsorption mechanism, film diffusion mainly controls the adsorption process, and Langmuir isotherm model fits well the experimental data. Results indicated a fast adsorption process which is spontaneous and endothermic in nature. Microstructural investigation of EAFS and AAS revealed morphological changes in metal loaded EAFS and AAS samples in comparison to unloaded adsorbents. X-ray powder diffraction analysis indicated that adsorption of Cu2+ onto both adsorbents occurs through formation of a Cu-complex.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Chemical Engineering Communications
T1  - Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag
EP  - 1297
IS  - 9
SP  - 1278
VL  - 207
DO  - 10.1080/00986445.2019.1685986
ER  - 
@article{
author = "Nikolić, Irena and Đurović, Dijana and Tadić, Milena and Radmilović, Vuk and Radmilović, Velimir R.",
year = "2020",
abstract = "Two adsorbents, pristine electric arc furnace slag (EAFS) and alkali activated slag (AAS) were used for Cu2+ removal from aquatic solutions. Batch adsorption tests were conducted at various temperatures and initial Cu2+ concentrations, while solid to liquid ratio and pH of solution were kept constant. Pseudo-first-order and pseudo-second-order (PSO) kinetics models, Langmuir and Freundlich isotherm models, as well as intraparticle and Boyd's diffusion models were applied in order to investigate the adsorption process. It has been found that alkali activation of EAFS leads to an increase in the specific surface of slag and thus improves the sorption properties of EAFS. The adsorption of Cu2+ onto both adsorbents proceeds via PSO adsorption mechanism, film diffusion mainly controls the adsorption process, and Langmuir isotherm model fits well the experimental data. Results indicated a fast adsorption process which is spontaneous and endothermic in nature. Microstructural investigation of EAFS and AAS revealed morphological changes in metal loaded EAFS and AAS samples in comparison to unloaded adsorbents. X-ray powder diffraction analysis indicated that adsorption of Cu2+ onto both adsorbents occurs through formation of a Cu-complex.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Chemical Engineering Communications",
title = "Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag",
pages = "1297-1278",
number = "9",
volume = "207",
doi = "10.1080/00986445.2019.1685986"
}
Nikolić, I., Đurović, D., Tadić, M., Radmilović, V.,& Radmilović, V. R.. (2020). Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag. in Chemical Engineering Communications
Taylor & Francis Inc, Philadelphia., 207(9), 1278-1297.
https://doi.org/10.1080/00986445.2019.1685986
Nikolić I, Đurović D, Tadić M, Radmilović V, Radmilović VR. Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag. in Chemical Engineering Communications. 2020;207(9):1278-1297.
doi:10.1080/00986445.2019.1685986 .
Nikolić, Irena, Đurović, Dijana, Tadić, Milena, Radmilović, Vuk, Radmilović, Velimir R., "Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag" in Chemical Engineering Communications, 207, no. 9 (2020):1278-1297,
https://doi.org/10.1080/00986445.2019.1685986 . .
17
2
12

Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness

Drah, Abdusalam; Tomić, Nataša; Kovačević, Tihomir; Đokić, Veljko; Tomić, M.; Jančić-Heinemann, Radmila; Marinković, Aleksandar

(Springer, New York, 2020)

TY  - JOUR
AU  - Drah, Abdusalam
AU  - Tomić, Nataša
AU  - Kovačević, Tihomir
AU  - Đokić, Veljko
AU  - Tomić, M.
AU  - Jančić-Heinemann, Radmila
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4524
AB  - Commercial gamma - Al2O3 particles, Al2O3 n, and synthesized Al2O3 doped with iron oxide (Al2O3 Fe) were used as reinforcements to enhance the toughness of an unsaturated polyester resin (UPR). Alumina modification with vinyl, Al2O3 (n, Fe)-VT, and methacryloyl, Al2O3 (n, Fe)-ME functionalities contributed to the increase in the extent of covalent binding at the UPR/filler interface. Tensile tests showed a slight improvement in the toughness of UPR/Al2O3 Fe composite and a significant improvement for the UPR/Al2O3 Fe-VT composite at a 1.0 wt.% particle loading. An enhancement in the micro Vickers hardness for UPR/Al2O3 Fe-VT and improved DMA properties were also evidenced.
PB  - Springer, New York
T2  - Mechanics of Composite Materials
T1  - Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness
EP  - 260
IS  - 2
SP  - 249
VL  - 56
DO  - 10.1007/s11029-020-09877-3
ER  - 
@article{
author = "Drah, Abdusalam and Tomić, Nataša and Kovačević, Tihomir and Đokić, Veljko and Tomić, M. and Jančić-Heinemann, Radmila and Marinković, Aleksandar",
year = "2020",
abstract = "Commercial gamma - Al2O3 particles, Al2O3 n, and synthesized Al2O3 doped with iron oxide (Al2O3 Fe) were used as reinforcements to enhance the toughness of an unsaturated polyester resin (UPR). Alumina modification with vinyl, Al2O3 (n, Fe)-VT, and methacryloyl, Al2O3 (n, Fe)-ME functionalities contributed to the increase in the extent of covalent binding at the UPR/filler interface. Tensile tests showed a slight improvement in the toughness of UPR/Al2O3 Fe composite and a significant improvement for the UPR/Al2O3 Fe-VT composite at a 1.0 wt.% particle loading. An enhancement in the micro Vickers hardness for UPR/Al2O3 Fe-VT and improved DMA properties were also evidenced.",
publisher = "Springer, New York",
journal = "Mechanics of Composite Materials",
title = "Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness",
pages = "260-249",
number = "2",
volume = "56",
doi = "10.1007/s11029-020-09877-3"
}
Drah, A., Tomić, N., Kovačević, T., Đokić, V., Tomić, M., Jančić-Heinemann, R.,& Marinković, A.. (2020). Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness. in Mechanics of Composite Materials
Springer, New York., 56(2), 249-260.
https://doi.org/10.1007/s11029-020-09877-3
Drah A, Tomić N, Kovačević T, Đokić V, Tomić M, Jančić-Heinemann R, Marinković A. Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness. in Mechanics of Composite Materials. 2020;56(2):249-260.
doi:10.1007/s11029-020-09877-3 .
Drah, Abdusalam, Tomić, Nataša, Kovačević, Tihomir, Đokić, Veljko, Tomić, M., Jančić-Heinemann, Radmila, Marinković, Aleksandar, "Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness" in Mechanics of Composite Materials, 56, no. 2 (2020):249-260,
https://doi.org/10.1007/s11029-020-09877-3 . .
2
2

Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution

Milosević, Dragana L.; Tomić, Nataša; Đokić, Veljko; Vidović, Milka; Veličković, Zlate; Jančić-Heinemann, Radmila; Marinković, Aleksandar

(Desalination Publ, Hopkinton, 2020)

TY  - JOUR
AU  - Milosević, Dragana L.
AU  - Tomić, Nataša
AU  - Đokić, Veljko
AU  - Vidović, Milka
AU  - Veličković, Zlate
AU  - Jančić-Heinemann, Radmila
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4506
AB  - The adsorption performance of three-dimensionally ordered macroporous (3DOM) alumina doped with iron oxide, and subsequently modified with (3-aminopropyl)triethoxysilane (APTES), FeAl2O3 and FeAl(2)O(3)APTES, was used for enhanced Pb2+, Cd2+ and Ni2+ removal. The phase composition and the structural and surface/textural properties of the obtained adsorbents were analyzed by X-ray diffraction analysis, field emission scanning electron microscope, energy dispersive X-ray analysis, thermogravimetry, Fourier-transfer infrared spectroscopy, specific surface area of the samples and point of zero charge determination. Adsorption of selected cations was examined in the batch conditions using different contact time, adsorbent dosage and temperatures. Different models of the adsorption isotherms were used for determination of the adsorption capacities, in which the best fit of Freundlich and Langmuir model was obtained for FeAl2O3, that is, Freundlich model for FeAl(2)O(3)APTES. A significant increase of adsorption capacities: from 44.21 to 51.66 mg g(-1) for Pb2+, 25.69 to 32.96 mg g(-1) for Cd2+ and 19.48 to 24.64 mg g(-1) for Ni2+ was obtained for FeAl2O3 and FeAl(2)O(3)APTES, respectively, which indicated the significance of the macroporous structure of 3DOM alumina and subsequent amino-terminal modification. The values of the correlation coefficient (R-2) suggested that pseudo-second kinetic model best describes Pb2+, Cd2+ and Ni2+ adsorption on FeAl(2)O(3)APTES, and Cd2+ and Ni2+ onto FeAl2O3, while second kinetic model gave the highest correlation coefficients for Pb2+ adsorption on FeAl2O3.
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution
EP  - 239
SP  - 220
VL  - 178
DO  - 10.5004/dwt.2020.24982
ER  - 
@article{
author = "Milosević, Dragana L. and Tomić, Nataša and Đokić, Veljko and Vidović, Milka and Veličković, Zlate and Jančić-Heinemann, Radmila and Marinković, Aleksandar",
year = "2020",
abstract = "The adsorption performance of three-dimensionally ordered macroporous (3DOM) alumina doped with iron oxide, and subsequently modified with (3-aminopropyl)triethoxysilane (APTES), FeAl2O3 and FeAl(2)O(3)APTES, was used for enhanced Pb2+, Cd2+ and Ni2+ removal. The phase composition and the structural and surface/textural properties of the obtained adsorbents were analyzed by X-ray diffraction analysis, field emission scanning electron microscope, energy dispersive X-ray analysis, thermogravimetry, Fourier-transfer infrared spectroscopy, specific surface area of the samples and point of zero charge determination. Adsorption of selected cations was examined in the batch conditions using different contact time, adsorbent dosage and temperatures. Different models of the adsorption isotherms were used for determination of the adsorption capacities, in which the best fit of Freundlich and Langmuir model was obtained for FeAl2O3, that is, Freundlich model for FeAl(2)O(3)APTES. A significant increase of adsorption capacities: from 44.21 to 51.66 mg g(-1) for Pb2+, 25.69 to 32.96 mg g(-1) for Cd2+ and 19.48 to 24.64 mg g(-1) for Ni2+ was obtained for FeAl2O3 and FeAl(2)O(3)APTES, respectively, which indicated the significance of the macroporous structure of 3DOM alumina and subsequent amino-terminal modification. The values of the correlation coefficient (R-2) suggested that pseudo-second kinetic model best describes Pb2+, Cd2+ and Ni2+ adsorption on FeAl(2)O(3)APTES, and Cd2+ and Ni2+ onto FeAl2O3, while second kinetic model gave the highest correlation coefficients for Pb2+ adsorption on FeAl2O3.",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution",
pages = "239-220",
volume = "178",
doi = "10.5004/dwt.2020.24982"
}
Milosević, D. L., Tomić, N., Đokić, V., Vidović, M., Veličković, Z., Jančić-Heinemann, R.,& Marinković, A.. (2020). Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 178, 220-239.
https://doi.org/10.5004/dwt.2020.24982
Milosević DL, Tomić N, Đokić V, Vidović M, Veličković Z, Jančić-Heinemann R, Marinković A. Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. in Desalination and Water Treatment. 2020;178:220-239.
doi:10.5004/dwt.2020.24982 .
Milosević, Dragana L., Tomić, Nataša, Đokić, Veljko, Vidović, Milka, Veličković, Zlate, Jančić-Heinemann, Radmila, Marinković, Aleksandar, "Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution" in Desalination and Water Treatment, 178 (2020):220-239,
https://doi.org/10.5004/dwt.2020.24982 . .
1
1
1

Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye

Bjelajac, Anđelika; Petrović, Rada; Vujančević, Jelena; Veltruska, Katerina; Matolin, Vladimir; Siketić, Zdravko; Provatas, George; Jakšić, Milko; Stan, George E.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Pergamon-Elsevier Science Ltd, Oxford, 2020)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Vujančević, Jelena
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketić, Zdravko
AU  - Provatas, George
AU  - Jakšić, Milko
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4396
AB  - We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes' surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Journal of Physics and Chemistry of Solids
T1  - Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye
SP  - 109609
VL  - 147
DO  - 10.1016/j.jpcs.2020.109609
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Vujančević, Jelena and Veltruska, Katerina and Matolin, Vladimir and Siketić, Zdravko and Provatas, George and Jakšić, Milko and Stan, George E. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2020",
abstract = "We fabricated Sn-doped TiO2 nanotubular film via annealing of anodized TiO2 nanotubes grown on F-SnO2 (FTO) glass. Annealing was carried out at 500 degrees C in ambient air. Anatase crystal structure was achieved with no change in nanotubular morphology in respect to as-anodized amorphous TiO(2 )nanotubes. The X-ray photoelectron spectroscopy analysis revealed Sn on the surface of TiO2 film, following the thermal treatment, probably caused by the diffusion from FTO glass. Depth profile examination of the film chemical composition was conducted by elastic recoil detection analysis, which showed that in addition to the diffusion of Sn from FTO, diffusion of Ti to FTO concurrently occurred. Thus, a higher concentration of Sn was found at the bottom of the tubes, while a lower concentration was present on the tubes' surface top. This explains the improved optical response revealed by a diffuse reflectance spectroscopy. The absorption enhancement demonstrated that Sn-doped TiO2 film was efficient in the degradation of methyl orange dye under visible light.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Journal of Physics and Chemistry of Solids",
title = "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye",
pages = "109609",
volume = "147",
doi = "10.1016/j.jpcs.2020.109609"
}
Bjelajac, A., Petrović, R., Vujančević, J., Veltruska, K., Matolin, V., Siketić, Z., Provatas, G., Jakšić, M., Stan, G. E., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2020). Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye. in Journal of Physics and Chemistry of Solids
Pergamon-Elsevier Science Ltd, Oxford., 147, 109609.
https://doi.org/10.1016/j.jpcs.2020.109609
Bjelajac A, Petrović R, Vujančević J, Veltruska K, Matolin V, Siketić Z, Provatas G, Jakšić M, Stan GE, Socol G, Mihailescu IN, Janaćković Đ. Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye. in Journal of Physics and Chemistry of Solids. 2020;147:109609.
doi:10.1016/j.jpcs.2020.109609 .
Bjelajac, Anđelika, Petrović, Rada, Vujančević, Jelena, Veltruska, Katerina, Matolin, Vladimir, Siketić, Zdravko, Provatas, George, Jakšić, Milko, Stan, George E., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Sn-doped TiO2 nanotubular thin film for photocatalytic degradation of methyl orange dye" in Journal of Physics and Chemistry of Solids, 147 (2020):109609,
https://doi.org/10.1016/j.jpcs.2020.109609 . .
18
8
18

Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2

Bjelajac, Anđelika; Kopac, Drejc; Fecant, Antoine; Tavernier, Eugenie; Petrović, Rada; Likozar, Blaž; Janaćković, Đorđe

(Royal Soc Chemistry, Cambridge, 2020)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Kopac, Drejc
AU  - Fecant, Antoine
AU  - Tavernier, Eugenie
AU  - Petrović, Rada
AU  - Likozar, Blaž
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4466
AB  - CO2 photoreduction is studied using in-house synthesized undoped and N-doped TiO2 nanoparticle photocatalysts. Comparison with the commercial P25 TiO2 powder shows that the synthesized samples are more effective. P25 produced a negligible amount of CH4, unlike the synthesized samples. N-doping of TiO2 powder caused a higher productivity rate of all products, and provided the best performance for CO2 reduction. The average production rate of CH4 was 0.191 mu mol h(-1) g(-1), whereas that of CO was 0.111 mu mol h(-1) g(-1). The experimental data are used to fit the micro-kinetic modelling parameters. The kinetic constant of H2O dissociation is the lowest for all tested samples, revealing that this is the rate-determining step. The kinetic constants for the H-2, CO, and CH4 formation were of the same order for all catalyst samples, showing that the rates of these reactions are independent of the catalyst type.
PB  - Royal Soc Chemistry, Cambridge
T2  - Catalysis Science & Technology
T1  - Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2
EP  - 1698
IS  - 6
SP  - 1688
VL  - 10
DO  - 10.1039/c9cy02443c
ER  - 
@article{
author = "Bjelajac, Anđelika and Kopac, Drejc and Fecant, Antoine and Tavernier, Eugenie and Petrović, Rada and Likozar, Blaž and Janaćković, Đorđe",
year = "2020",
abstract = "CO2 photoreduction is studied using in-house synthesized undoped and N-doped TiO2 nanoparticle photocatalysts. Comparison with the commercial P25 TiO2 powder shows that the synthesized samples are more effective. P25 produced a negligible amount of CH4, unlike the synthesized samples. N-doping of TiO2 powder caused a higher productivity rate of all products, and provided the best performance for CO2 reduction. The average production rate of CH4 was 0.191 mu mol h(-1) g(-1), whereas that of CO was 0.111 mu mol h(-1) g(-1). The experimental data are used to fit the micro-kinetic modelling parameters. The kinetic constant of H2O dissociation is the lowest for all tested samples, revealing that this is the rate-determining step. The kinetic constants for the H-2, CO, and CH4 formation were of the same order for all catalyst samples, showing that the rates of these reactions are independent of the catalyst type.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Catalysis Science & Technology",
title = "Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2",
pages = "1698-1688",
number = "6",
volume = "10",
doi = "10.1039/c9cy02443c"
}
Bjelajac, A., Kopac, D., Fecant, A., Tavernier, E., Petrović, R., Likozar, B.,& Janaćković, Đ.. (2020). Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2. in Catalysis Science & Technology
Royal Soc Chemistry, Cambridge., 10(6), 1688-1698.
https://doi.org/10.1039/c9cy02443c
Bjelajac A, Kopac D, Fecant A, Tavernier E, Petrović R, Likozar B, Janaćković Đ. Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2. in Catalysis Science & Technology. 2020;10(6):1688-1698.
doi:10.1039/c9cy02443c .
Bjelajac, Anđelika, Kopac, Drejc, Fecant, Antoine, Tavernier, Eugenie, Petrović, Rada, Likozar, Blaž, Janaćković, Đorđe, "Micro-kinetic modelling of photocatalytic CO2 reduction over undoped and N-doped TiO2" in Catalysis Science & Technology, 10, no. 6 (2020):1688-1698,
https://doi.org/10.1039/c9cy02443c . .
1
37
7
32

Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials

Ayoub, Giuma; Ležaja-Zebić, Maja; Miletić, Vesna; Petrović, Rada; Veljović, Đorđe; Janaćković, Đorđe

(Wiley, Hoboken, 2020)

TY  - JOUR
AU  - Ayoub, Giuma
AU  - Ležaja-Zebić, Maja
AU  - Miletić, Vesna
AU  - Petrović, Rada
AU  - Veljović, Đorđe
AU  - Janaćković, Đorđe
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4476
AB  - The application of sintered calcium phosphate dental inserts in the central part of tooth cavities can reduce amount of embedded dental composite and polymerization shrinkage of final dental fillings. The aim of this study was to analyze comparatively physico-chemical and mechanical properties of dental inserts and shear bond strength (SBS) between three dissimilar hydroxyapatite-based dental inserts and different restorative materials, after application of different clinical protocols. Starting from two different hydroxyapatite nano powders and nanostructured stabilized zirconia (YSZ), monophasic two-step sintered dense HAp inserts (TSSHAp), biphasic single-step sintered controlled porous inserts (HAp/TCp), and single-step sintered reinforced HAp/YSZ inserts were processed and characterized. Obvious differences in the microstructure of inserts surface were visualized after etching with 37% phosphoric acid. Fracture toughness of sintered inserts was ranged between 1.01 and 1.85 MPam(1/2) (maximum value in the case of HAp/YSZ), while hardness values were in the range of 3.71-5.22 GPa (maximum value in the case of TSSHAp). Acid etching before application improved SBS between inserts and Maxcem compared to direct cement application. TSSHAp and HAP/TCp inserts showed comparable and relatively high SBS values, certainly higher compared to HAp/YSZ inserts. Slightly higher SBS values were measured in the case of TSSHAp insert group, and the highest mean SBS value of 18.51 MPa was determined between TSSHAp inserts and Filtek Z250_SBU following the "self-etch" protocol.
PB  - Wiley, Hoboken
T2  - Journal of Biomedical Materials Research Part B-Applied Biomaterials
T1  - Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials
EP  - 2470
IS  - 6
SP  - 2461
VL  - 108
DO  - 10.1002/jbm.b.34578
ER  - 
@article{
author = "Ayoub, Giuma and Ležaja-Zebić, Maja and Miletić, Vesna and Petrović, Rada and Veljović, Đorđe and Janaćković, Đorđe",
year = "2020",
abstract = "The application of sintered calcium phosphate dental inserts in the central part of tooth cavities can reduce amount of embedded dental composite and polymerization shrinkage of final dental fillings. The aim of this study was to analyze comparatively physico-chemical and mechanical properties of dental inserts and shear bond strength (SBS) between three dissimilar hydroxyapatite-based dental inserts and different restorative materials, after application of different clinical protocols. Starting from two different hydroxyapatite nano powders and nanostructured stabilized zirconia (YSZ), monophasic two-step sintered dense HAp inserts (TSSHAp), biphasic single-step sintered controlled porous inserts (HAp/TCp), and single-step sintered reinforced HAp/YSZ inserts were processed and characterized. Obvious differences in the microstructure of inserts surface were visualized after etching with 37% phosphoric acid. Fracture toughness of sintered inserts was ranged between 1.01 and 1.85 MPam(1/2) (maximum value in the case of HAp/YSZ), while hardness values were in the range of 3.71-5.22 GPa (maximum value in the case of TSSHAp). Acid etching before application improved SBS between inserts and Maxcem compared to direct cement application. TSSHAp and HAP/TCp inserts showed comparable and relatively high SBS values, certainly higher compared to HAp/YSZ inserts. Slightly higher SBS values were measured in the case of TSSHAp insert group, and the highest mean SBS value of 18.51 MPa was determined between TSSHAp inserts and Filtek Z250_SBU following the "self-etch" protocol.",
publisher = "Wiley, Hoboken",
journal = "Journal of Biomedical Materials Research Part B-Applied Biomaterials",
title = "Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials",
pages = "2470-2461",
number = "6",
volume = "108",
doi = "10.1002/jbm.b.34578"
}
Ayoub, G., Ležaja-Zebić, M., Miletić, V., Petrović, R., Veljović, Đ.,& Janaćković, Đ.. (2020). Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials. in Journal of Biomedical Materials Research Part B-Applied Biomaterials
Wiley, Hoboken., 108(6), 2461-2470.
https://doi.org/10.1002/jbm.b.34578
Ayoub G, Ležaja-Zebić M, Miletić V, Petrović R, Veljović Đ, Janaćković Đ. Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials. in Journal of Biomedical Materials Research Part B-Applied Biomaterials. 2020;108(6):2461-2470.
doi:10.1002/jbm.b.34578 .
Ayoub, Giuma, Ležaja-Zebić, Maja, Miletić, Vesna, Petrović, Rada, Veljović, Đorđe, Janaćković, Đorđe, "Dissimilar sintered calcium phosphate dental inserts as dentine substitutes: Shear bond strength to restorative materials" in Journal of Biomedical Materials Research Part B-Applied Biomaterials, 108, no. 6 (2020):2461-2470,
https://doi.org/10.1002/jbm.b.34578 . .
3
3

Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay

Stevanović, Maja; Bajić, Zoran J.; Veličković, Zlate; Karkalić, Radovan; Pecić, Ljiljana; Otrisal, Pavel; Marinković, Aleksandar

(Desalination Publ, Hopkinton, 2020)

TY  - JOUR
AU  - Stevanović, Maja
AU  - Bajić, Zoran J.
AU  - Veličković, Zlate
AU  - Karkalić, Radovan
AU  - Pecić, Ljiljana
AU  - Otrisal, Pavel
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4507
AB  - The synthesis and adsorption potential of Cy-npAg, obtained by modification of raw montmorillonite clay (raw-Cy) with silver nanoparticle (npAg), was studied in this work. Optimization procedure, with respect to time, temperature and amount of deposit npAg, obtained either by reductive precipitation or ultraviolet irradiation, was performed using response surface methodology (RSM). The most efficient adsorbent, obtained by chemical reduction of silver ion with sodium borohydride, named Cy-npAg, was characterized in detail using Brunauer-Emmett-Teller, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques, and point of zero charge determination. The Cy-npAg showed good adsorption capacity with respect to non-systemic organophosphate insecticide (diazinon) as well as of heavy metals ions (Cd2+ and Ni2+ ions), that is, 74.26, 62.33, and 35.49 mg g(-1), respectively, obtained from Langmuir model fitting. Temperature dependent kinetic study allowed determination of pseudo-second rate constant (10(3) g mg(-1) min(-1))/activation energies (kJ mol(-1)): 1.45/14.48 for diazinon, and 1.27/6.59 and 0.7/7.35 kJ mol(-1) for Cd2+ and Ni2+ ions, respectively. Thermodynamic parameters indicated feasible and spontaneous adsorption with main participation of physisorption. Antibacterial potential of npAg deposit for water disinfection was confirmed by the moderate reduction of bacterial growth of Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa, by 64%, 39%, and 70%, respectively. Thus, two synergistic effects contribute to water purification processes using Cy-npAg: pollutants removal with a simultaneous decrease of the microbial contamination contributing to overall water quality improvement.
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay
EP  - 369
SP  - 345
VL  - 187
DO  - 10.5004/dwt.2020.25451
ER  - 
@article{
author = "Stevanović, Maja and Bajić, Zoran J. and Veličković, Zlate and Karkalić, Radovan and Pecić, Ljiljana and Otrisal, Pavel and Marinković, Aleksandar",
year = "2020",
abstract = "The synthesis and adsorption potential of Cy-npAg, obtained by modification of raw montmorillonite clay (raw-Cy) with silver nanoparticle (npAg), was studied in this work. Optimization procedure, with respect to time, temperature and amount of deposit npAg, obtained either by reductive precipitation or ultraviolet irradiation, was performed using response surface methodology (RSM). The most efficient adsorbent, obtained by chemical reduction of silver ion with sodium borohydride, named Cy-npAg, was characterized in detail using Brunauer-Emmett-Teller, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques, and point of zero charge determination. The Cy-npAg showed good adsorption capacity with respect to non-systemic organophosphate insecticide (diazinon) as well as of heavy metals ions (Cd2+ and Ni2+ ions), that is, 74.26, 62.33, and 35.49 mg g(-1), respectively, obtained from Langmuir model fitting. Temperature dependent kinetic study allowed determination of pseudo-second rate constant (10(3) g mg(-1) min(-1))/activation energies (kJ mol(-1)): 1.45/14.48 for diazinon, and 1.27/6.59 and 0.7/7.35 kJ mol(-1) for Cd2+ and Ni2+ ions, respectively. Thermodynamic parameters indicated feasible and spontaneous adsorption with main participation of physisorption. Antibacterial potential of npAg deposit for water disinfection was confirmed by the moderate reduction of bacterial growth of Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa, by 64%, 39%, and 70%, respectively. Thus, two synergistic effects contribute to water purification processes using Cy-npAg: pollutants removal with a simultaneous decrease of the microbial contamination contributing to overall water quality improvement.",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay",
pages = "369-345",
volume = "187",
doi = "10.5004/dwt.2020.25451"
}
Stevanović, M., Bajić, Z. J., Veličković, Z., Karkalić, R., Pecić, L., Otrisal, P.,& Marinković, A.. (2020). Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 187, 345-369.
https://doi.org/10.5004/dwt.2020.25451
Stevanović M, Bajić ZJ, Veličković Z, Karkalić R, Pecić L, Otrisal P, Marinković A. Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay. in Desalination and Water Treatment. 2020;187:345-369.
doi:10.5004/dwt.2020.25451 .
Stevanović, Maja, Bajić, Zoran J., Veličković, Zlate, Karkalić, Radovan, Pecić, Ljiljana, Otrisal, Pavel, Marinković, Aleksandar, "Adsorption performances and antimicrobial activity of the nanosilver modified montmorillonite clay" in Desalination and Water Treatment, 187 (2020):345-369,
https://doi.org/10.5004/dwt.2020.25451 . .
5
5

Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release

Milosević, Miljan; Stojanović, Dušica; Simić, Vladimir; Grković, Mirjana; Bjelović, Miloš; Uskoković, Petar; Kojić, Miloš

(Nature Publishing Group, London, 2020)

TY  - JOUR
AU  - Milosević, Miljan
AU  - Stojanović, Dušica
AU  - Simić, Vladimir
AU  - Grković, Mirjana
AU  - Bjelović, Miloš
AU  - Uskoković, Petar
AU  - Kojić, Miloš
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4388
AB  - The authors present the preparation procedure and a computational model of a three-layered fibrous scaffold for prolonged drug release. The scaffold, produced by emulsion/sequential electrospinning, consists of a poly(d,l-lactic-co-glycolic acid) (PLGA) fiber layer sandwiched between two poly(epsilon -caprolactone) (PCL) layers. Experimental results of drug release rates from the scaffold are compared with the results of the recently introduced computational finite element (FE) models for diffusive drug release from nanofibers to the three-dimensional (3D) surrounding medium. Two different FE models are used: (1) a 3D discretized continuum and fibers represented by a simple radial one-dimensional (1D) finite elements, and (2) a 3D continuum discretized by composite smeared finite elements (CSFEs) containing the fiber smeared and surrounding domains. Both models include the effects of polymer degradation and hydrophobicity (as partitioning) of the drug at the fiber/surrounding interface. The CSFE model includes a volumetric fraction of fibers and diameter distribution, and is additionally enhanced by using correction function to improve the accuracy of the model. The computational results are validated on Rhodamine B (fluorescent drug l) and other hydrophilic drugs. Agreement with experimental results proves that numerical models can serve as efficient tools for drug release to the surrounding porous medium or biological tissue. It is demonstrated that the introduced three-layered scaffold delays the drug release process and can be used for the time-controlled release of drugs in postoperative therapy.
PB  - Nature Publishing Group, London
T2  - Scientific Reports
T1  - Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release
IS  - 1
VL  - 10
DO  - 10.1038/s41598-020-68117-9
ER  - 
@article{
author = "Milosević, Miljan and Stojanović, Dušica and Simić, Vladimir and Grković, Mirjana and Bjelović, Miloš and Uskoković, Petar and Kojić, Miloš",
year = "2020",
abstract = "The authors present the preparation procedure and a computational model of a three-layered fibrous scaffold for prolonged drug release. The scaffold, produced by emulsion/sequential electrospinning, consists of a poly(d,l-lactic-co-glycolic acid) (PLGA) fiber layer sandwiched between two poly(epsilon -caprolactone) (PCL) layers. Experimental results of drug release rates from the scaffold are compared with the results of the recently introduced computational finite element (FE) models for diffusive drug release from nanofibers to the three-dimensional (3D) surrounding medium. Two different FE models are used: (1) a 3D discretized continuum and fibers represented by a simple radial one-dimensional (1D) finite elements, and (2) a 3D continuum discretized by composite smeared finite elements (CSFEs) containing the fiber smeared and surrounding domains. Both models include the effects of polymer degradation and hydrophobicity (as partitioning) of the drug at the fiber/surrounding interface. The CSFE model includes a volumetric fraction of fibers and diameter distribution, and is additionally enhanced by using correction function to improve the accuracy of the model. The computational results are validated on Rhodamine B (fluorescent drug l) and other hydrophilic drugs. Agreement with experimental results proves that numerical models can serve as efficient tools for drug release to the surrounding porous medium or biological tissue. It is demonstrated that the introduced three-layered scaffold delays the drug release process and can be used for the time-controlled release of drugs in postoperative therapy.",
publisher = "Nature Publishing Group, London",
journal = "Scientific Reports",
title = "Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release",
number = "1",
volume = "10",
doi = "10.1038/s41598-020-68117-9"
}
Milosević, M., Stojanović, D., Simić, V., Grković, M., Bjelović, M., Uskoković, P.,& Kojić, M.. (2020). Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release. in Scientific Reports
Nature Publishing Group, London., 10(1).
https://doi.org/10.1038/s41598-020-68117-9
Milosević M, Stojanović D, Simić V, Grković M, Bjelović M, Uskoković P, Kojić M. Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release. in Scientific Reports. 2020;10(1).
doi:10.1038/s41598-020-68117-9 .
Milosević, Miljan, Stojanović, Dušica, Simić, Vladimir, Grković, Mirjana, Bjelović, Miloš, Uskoković, Petar, Kojić, Miloš, "Preparation and modeling of three-layered PCL/PLGA/PCL fibrous scaffolds for prolonged drug release" in Scientific Reports, 10, no. 1 (2020),
https://doi.org/10.1038/s41598-020-68117-9 . .
52
17
42

Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders

Radovanović, Željko; Kazuz, Abdul Moneim Mohamed; Vulić, Predrag; Radovanović, Lidija; Veljović, Đorđe; Petrović, Rada; Janaćković, Đorđe

(Belgrade : ETRAN Society, 2019)

TY  - CONF
AU  - Radovanović, Željko
AU  - Kazuz, Abdul Moneim Mohamed
AU  - Vulić, Predrag
AU  - Radovanović, Lidija
AU  - Veljović, Đorđe
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6701
AB  - The biomaterial powders of hydroxyapatite (HAp)
and fluorapatite (FAp) were synthesized by a hydrothermal
method. Powders were analyzed by energy-dispersive X-ray
spectroscopy (EDS), field emission scanning electron microscopy
(FESEM), and X-ray powder diffraction analysis (XRPD). EDS
analysis shows the presence of non-stoichiometries FAp and HAp
with molar ratio CA/P < 1.67. FESEM analysis of both powders
indicates the presence of agglomerates of micrometric dimensions,
while primary nanoparticles are rod-like. The Rietveld
refinement of XRPD data showed that the single phase powders of
FAp and HAp were synthesized. The results showed that obtained
nanomaterials can be potentially applied in dentistry.
PB  - Belgrade : ETRAN Society
PB  - Belgrade : Academic Mind
C3  - Proceedings of Papers / (Ic)ETRAN 2019, 6th International Conference on Electrical, Electronic and Computing Engineering in conjunction with ETRAN, 63rd National Conference on Electrical, Electronic and Computing Engineering, Silver Lake, Serbia, June 03 - 06, 2019
T1  - Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders
EP  - 679
SP  - 676
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6701
ER  - 
@conference{
author = "Radovanović, Željko and Kazuz, Abdul Moneim Mohamed and Vulić, Predrag and Radovanović, Lidija and Veljović, Đorđe and Petrović, Rada and Janaćković, Đorđe",
year = "2019",
abstract = "The biomaterial powders of hydroxyapatite (HAp)
and fluorapatite (FAp) were synthesized by a hydrothermal
method. Powders were analyzed by energy-dispersive X-ray
spectroscopy (EDS), field emission scanning electron microscopy
(FESEM), and X-ray powder diffraction analysis (XRPD). EDS
analysis shows the presence of non-stoichiometries FAp and HAp
with molar ratio CA/P < 1.67. FESEM analysis of both powders
indicates the presence of agglomerates of micrometric dimensions,
while primary nanoparticles are rod-like. The Rietveld
refinement of XRPD data showed that the single phase powders of
FAp and HAp were synthesized. The results showed that obtained
nanomaterials can be potentially applied in dentistry.",
publisher = "Belgrade : ETRAN Society, Belgrade : Academic Mind",
journal = "Proceedings of Papers / (Ic)ETRAN 2019, 6th International Conference on Electrical, Electronic and Computing Engineering in conjunction with ETRAN, 63rd National Conference on Electrical, Electronic and Computing Engineering, Silver Lake, Serbia, June 03 - 06, 2019",
title = "Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders",
pages = "679-676",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6701"
}
Radovanović, Ž., Kazuz, A. M. M., Vulić, P., Radovanović, L., Veljović, Đ., Petrović, R.,& Janaćković, Đ.. (2019). Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders. in Proceedings of Papers / (Ic)ETRAN 2019, 6th International Conference on Electrical, Electronic and Computing Engineering in conjunction with ETRAN, 63rd National Conference on Electrical, Electronic and Computing Engineering, Silver Lake, Serbia, June 03 - 06, 2019
Belgrade : ETRAN Society., 676-679.
https://hdl.handle.net/21.15107/rcub_technorep_6701
Radovanović Ž, Kazuz AMM, Vulić P, Radovanović L, Veljović Đ, Petrović R, Janaćković Đ. Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders. in Proceedings of Papers / (Ic)ETRAN 2019, 6th International Conference on Electrical, Electronic and Computing Engineering in conjunction with ETRAN, 63rd National Conference on Electrical, Electronic and Computing Engineering, Silver Lake, Serbia, June 03 - 06, 2019. 2019;:676-679.
https://hdl.handle.net/21.15107/rcub_technorep_6701 .
Radovanović, Željko, Kazuz, Abdul Moneim Mohamed, Vulić, Predrag, Radovanović, Lidija, Veljović, Đorđe, Petrović, Rada, Janaćković, Đorđe, "Sinthesis and Characterization of Hydroxyapatite and Fluorapatite Powders" in Proceedings of Papers / (Ic)ETRAN 2019, 6th International Conference on Electrical, Electronic and Computing Engineering in conjunction with ETRAN, 63rd National Conference on Electrical, Electronic and Computing Engineering, Silver Lake, Serbia, June 03 - 06, 2019 (2019):676-679,
https://hdl.handle.net/21.15107/rcub_technorep_6701 .