TY  - CONF
AU  - Ivanović, Aleksandra
AU  - Dimitrijević, Silvana
AU  - Dimitrijević, Stevan
AU  - Kovačević, Renata
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6733
AB  - Binary palladium alloys with nickel are known to have catalytic activity and are also used as catalyst-trap in the synthesis of nitric acid. High Pd alloys are corrosive resistant in many solutions, including highly alkaline and highly acidic. Although generally not prone to corrosion in low concentrations of mineral acids due to the high content of palladium in it, this alloy is still prone to the dealloying effect under specific conditions. The dealloying process was researched under anodic polarization in 1.0M nitric acid solution. Scanning electronic microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), inductively coupled plasma atomic emission spectroscopy (ICP-AES)  and electrochemical methods were used to study the susceptibility of PdNi5 alloy to dealloying.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
C3  - Congress Proceedings / 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023
T1  - Dealloying of PdNi5 Alloy in 1.0M Nitric Acid
EP  - 285
SP  - 279
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6733
ER  - 

@conference{
author = "Ivanović, Aleksandra and Dimitrijević, Silvana and Dimitrijević, Stevan and Kovačević, Renata",
year = "2023",
abstract = "Binary palladium alloys with nickel are known to have catalytic activity and are also used as catalyst-trap in the synthesis of nitric acid. High Pd alloys are corrosive resistant in many solutions, including highly alkaline and highly acidic. Although generally not prone to corrosion in low concentrations of mineral acids due to the high content of palladium in it, this alloy is still prone to the dealloying effect under specific conditions. The dealloying process was researched under anodic polarization in 1.0M nitric acid solution. Scanning electronic microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), inductively coupled plasma atomic emission spectroscopy (ICP-AES)  and electrochemical methods were used to study the susceptibility of PdNi5 alloy to dealloying.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)",
journal = "Congress Proceedings / 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023",
title = "Dealloying of PdNi5 Alloy in 1.0M Nitric Acid",
pages = "285-279",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6733"
}

Ivanović, A., Dimitrijević, S., Dimitrijević, S.,& Kovačević, R.. (2023). Dealloying of PdNi5 Alloy in 1.0M Nitric Acid. in Congress Proceedings / 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023
Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 279-285.
https://hdl.handle.net/21.15107/rcub_technorep_6733

Ivanović A, Dimitrijević S, Dimitrijević S, Kovačević R. Dealloying of PdNi5 Alloy in 1.0M Nitric Acid. in Congress Proceedings / 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023. 2023;:279-285.
https://hdl.handle.net/21.15107/rcub_technorep_6733 .

Ivanović, Aleksandra, Dimitrijević, Silvana, Dimitrijević, Stevan, Kovačević, Renata, "Dealloying of PdNi5 Alloy in 1.0M Nitric Acid" in Congress Proceedings / 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023 (2023):279-285,
https://hdl.handle.net/21.15107/rcub_technorep_6733 .

TY  - CONF
AU  - Dimitrijević, Stevan P.
AU  - Dimitrijević, Silvana B.
AU  - Ivanović, Aleksandra T.
AU  - Kovačević, Renata
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6801
AB  - Palladium alloys with low nickel content are commonly used as catalyst-trap for platinum or
platinum-rhodium catalysts in the process of production of nitric acid. Pure palladium and,
consequently, alloys with a high concentration of Pd are highly resistant in many corrosion
environments across the full pH range, from 0 to 14 and beyond, in the presence of different anions.
Mineral acids do not affect palladium, especially at lower concentrations; they can be dissolved
just in the mix of them. However, nickel in the alloy can be selectively dissolved in single mineral
acid with the use of an oxidation agent or anodic polarization, which is the more controllable
process. The aim of the work is the research of dealloying of PdNi5 in 0.5M sulfuric acid under
anodic polarization conditions. This study used open circuit potential, linear polarization
resistance, and chronoamperometry as electrochemical methods. Scanning electronic microscopy
with energy-dispersive X-ray spectroscopy (SEM-EDS) and inductively coupled plasma mass
spectrometry (ICP-MS) were used as structural and analytical techniques for the study of PdNi5
alloy dealloying in 0.5M sulfuric acid at three different anodic potentials.
AB  - Legure paladijuma sa niskim sadržajem nikla se obično koriste kao havatači katalizatora za platinu ili platina-rodijum katalizatore u procesu proizvodnje azotne kiseline. Čisti paladijum i posledično legure sa visokom koncentracijom Pd su visoko otporni u mnogim korozionim sredinama u punom pH opsegu, od 0 do 14 i više, u prisustvu različitih anjona. Mineralne kiseline ne utiču na paladijum, posebno na nižim koncentracijama; može se rastvoriti samo u njihovoj mešavini. Međutim, nikl u leguri može se selektivno rastvoriti u jednoj mineralnoj kiselini uz upotrebu oksidacionog agensa ili anodne polarizacije, što je proces koji se može više kontrolisati. Cilj rada je istraživanje dealloying-a PdNi5 u 0,5M sumpornoj kiselini u uslovima anodne polarizacije. Ova studija je koristila potencijal otvorenog kola, otpor linearne polarizacije i hronoamperometriju kao elektrohemijske metode. Skenirajuća elektronska mikroskopija sa energetski disperzivnom rendgenskom spektroskopijom (SEM-EDS) i masena spektrometrija induktivno spregnute plazme (ICP-MS) korišćene su kao strukturne i analitičke tehnike za proučavanje dealloying-a legure PdNi5 u 0,5M sumpornoj kiselini na tri različita anodna potencijala.
PB  - Beograd : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), Society for Renewable Electrical Power Sources
C3  - Proceedings / 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 02-03, 2023
T1  - DEALLOYING OF PdNi5 ALLOY IN 0.5M SULFURIC ACID
T1  - DEALLOYING PdNi5 LEGURE U 0.5M SULFATNOJ KISELINI
EP  - 349
SP  - 341
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6801
ER  - 

@conference{
author = "Dimitrijević, Stevan P. and Dimitrijević, Silvana B. and Ivanović, Aleksandra T. and Kovačević, Renata",
year = "2023",
abstract = "Palladium alloys with low nickel content are commonly used as catalyst-trap for platinum or
platinum-rhodium catalysts in the process of production of nitric acid. Pure palladium and,
consequently, alloys with a high concentration of Pd are highly resistant in many corrosion
environments across the full pH range, from 0 to 14 and beyond, in the presence of different anions.
Mineral acids do not affect palladium, especially at lower concentrations; they can be dissolved
just in the mix of them. However, nickel in the alloy can be selectively dissolved in single mineral
acid with the use of an oxidation agent or anodic polarization, which is the more controllable
process. The aim of the work is the research of dealloying of PdNi5 in 0.5M sulfuric acid under
anodic polarization conditions. This study used open circuit potential, linear polarization
resistance, and chronoamperometry as electrochemical methods. Scanning electronic microscopy
with energy-dispersive X-ray spectroscopy (SEM-EDS) and inductively coupled plasma mass
spectrometry (ICP-MS) were used as structural and analytical techniques for the study of PdNi5
alloy dealloying in 0.5M sulfuric acid at three different anodic potentials., Legure paladijuma sa niskim sadržajem nikla se obično koriste kao havatači katalizatora za platinu ili platina-rodijum katalizatore u procesu proizvodnje azotne kiseline. Čisti paladijum i posledično legure sa visokom koncentracijom Pd su visoko otporni u mnogim korozionim sredinama u punom pH opsegu, od 0 do 14 i više, u prisustvu različitih anjona. Mineralne kiseline ne utiču na paladijum, posebno na nižim koncentracijama; može se rastvoriti samo u njihovoj mešavini. Međutim, nikl u leguri može se selektivno rastvoriti u jednoj mineralnoj kiselini uz upotrebu oksidacionog agensa ili anodne polarizacije, što je proces koji se može više kontrolisati. Cilj rada je istraživanje dealloying-a PdNi5 u 0,5M sumpornoj kiselini u uslovima anodne polarizacije. Ova studija je koristila potencijal otvorenog kola, otpor linearne polarizacije i hronoamperometriju kao elektrohemijske metode. Skenirajuća elektronska mikroskopija sa energetski disperzivnom rendgenskom spektroskopijom (SEM-EDS) i masena spektrometrija induktivno spregnute plazme (ICP-MS) korišćene su kao strukturne i analitičke tehnike za proučavanje dealloying-a legure PdNi5 u 0,5M sumpornoj kiselini na tri različita anodna potencijala.",
publisher = "Beograd : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), Society for Renewable Electrical Power Sources",
journal = "Proceedings / 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 02-03, 2023",
title = "DEALLOYING OF PdNi5 ALLOY IN 0.5M SULFURIC ACID, DEALLOYING PdNi5 LEGURE U 0.5M SULFATNOJ KISELINI",
pages = "349-341",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6801"
}

Dimitrijević, S. P., Dimitrijević, S. B., Ivanović, A. T.,& Kovačević, R.. (2023). DEALLOYING OF PdNi5 ALLOY IN 0.5M SULFURIC ACID. in Proceedings / 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 02-03, 2023
Beograd : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), Society for Renewable Electrical Power Sources., 341-349.
https://hdl.handle.net/21.15107/rcub_technorep_6801

Dimitrijević SP, Dimitrijević SB, Ivanović AT, Kovačević R. DEALLOYING OF PdNi5 ALLOY IN 0.5M SULFURIC ACID. in Proceedings / 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 02-03, 2023. 2023;:341-349.
https://hdl.handle.net/21.15107/rcub_technorep_6801 .

Dimitrijević, Stevan P., Dimitrijević, Silvana B., Ivanović, Aleksandra T., Kovačević, Renata, "DEALLOYING OF PdNi5 ALLOY IN 0.5M SULFURIC ACID" in Proceedings / 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 02-03, 2023 (2023):341-349,
https://hdl.handle.net/21.15107/rcub_technorep_6801 .