TY  - JOUR
AU  - Trueba, Alondra Torres
AU  - Radović, Ivona
AU  - Zevenbergen, John F.
AU  - Peters, Cor J.
AU  - Kroon, Maaike C.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2499
AB  - The kinetics of formation of semi-clathrate hydrates of tetra n-butyl ammonium fluoride (TBAF) with hydrogen (H-2) and carbon dioxide (CO2) were studied in order to elucidate their potential for H-2 storage as well as for CO2 sequestration. The influence of pressure, TBAF concentration (1.8 mol% and 3.4 mol%) and formation method (T-cycle method and T-constant method) on the hydrate nucleation, hydrate growth and the amount of gas uptake were determined. The results showed that the kinetics of formation of H-2 TBAF semi-hydrates is favored at high pressures and TBAF concentrations. The TBAF concentration did not display a large influence on the kinetics of formation of CO2 TBAF semi-hydrates and pressure only showed a major influence on the formation rate. Instead, the induction time and the amount of CO2 consumed were favored at low temperatures. Additionally, in situ Raman spectroscopy was used to confirm the gas uptake in the hydrate structure and to observe structural changes.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - International Journal of Hydrogen Energy
T1  - Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide
EP  - 7334
IS  - 18
SP  - 7326
VL  - 38
DO  - 10.1016/j.ijhydene.2013.03.154
ER  - 

@article{
author = "Trueba, Alondra Torres and Radović, Ivona and Zevenbergen, John F. and Peters, Cor J. and Kroon, Maaike C.",
year = "2013",
abstract = "The kinetics of formation of semi-clathrate hydrates of tetra n-butyl ammonium fluoride (TBAF) with hydrogen (H-2) and carbon dioxide (CO2) were studied in order to elucidate their potential for H-2 storage as well as for CO2 sequestration. The influence of pressure, TBAF concentration (1.8 mol% and 3.4 mol%) and formation method (T-cycle method and T-constant method) on the hydrate nucleation, hydrate growth and the amount of gas uptake were determined. The results showed that the kinetics of formation of H-2 TBAF semi-hydrates is favored at high pressures and TBAF concentrations. The TBAF concentration did not display a large influence on the kinetics of formation of CO2 TBAF semi-hydrates and pressure only showed a major influence on the formation rate. Instead, the induction time and the amount of CO2 consumed were favored at low temperatures. Additionally, in situ Raman spectroscopy was used to confirm the gas uptake in the hydrate structure and to observe structural changes.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "International Journal of Hydrogen Energy",
title = "Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide",
pages = "7334-7326",
number = "18",
volume = "38",
doi = "10.1016/j.ijhydene.2013.03.154"
}

Trueba, A. T., Radović, I., Zevenbergen, J. F., Peters, C. J.,& Kroon, M. C.. (2013). Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide. in International Journal of Hydrogen Energy
Pergamon-Elsevier Science Ltd, Oxford., 38(18), 7326-7334.
https://doi.org/10.1016/j.ijhydene.2013.03.154

Trueba AT, Radović I, Zevenbergen JF, Peters CJ, Kroon MC. Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide. in International Journal of Hydrogen Energy. 2013;38(18):7326-7334.
doi:10.1016/j.ijhydene.2013.03.154 .

Trueba, Alondra Torres, Radović, Ivona, Zevenbergen, John F., Peters, Cor J., Kroon, Maaike C., "Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide" in International Journal of Hydrogen Energy, 38, no. 18 (2013):7326-7334,
https://doi.org/10.1016/j.ijhydene.2013.03.154 . .