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Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures

Vuksanović, Jelena; Radović, Ivona; Šerbanović, Slobodan P.; Kijevčanin, Mirjana

(Srpsko hemijsko društvo, Beograd, 2015)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Radović, Ivona
AU  - Šerbanović, Slobodan P.
AU  - Kijevčanin, Mirjana
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3115
AB  - Experimental density rho, refractive index n(D) and viscosity eta data of three binary systems of poly(ethylene glycol) diacrylate (PEGDA) + ethanol, + 1-propanol and + 1-butanol were measured at eight temperatures from 288.15 to 323.15 K, with temperature step of 5 K, and at atmospheric pressure. The experimental data were correlated as a function of the PEGDA mole fraction and temperature. The densities and refractive indices of the investigated mixtures could be fitted well with exponential function vs. composition, including the temperature dependence of the parameters, while in the case of the viscosities, a polynomial function fits well the composition of the mixtures. In the case of the temperature correlation, all three properties (rho In eta and n(D)) exhibited linear trends. The viscosity modeling was performed using four models: the UNIFAC-VISCO, ASOG-VISCO, McAllister and the Teja-Rice models. For application of the UNIFAC-VISCO model, interaction parameters of following groups were determined: CH2=CH/CH3, CH2=CH/CH2, CH2=CH/OH, CH2=CH/CH2O and CH2=CH/COO. In addition, in the same way, the binary interaction parameters used in the ASOG-VISCO model of the following groups were determined: CH2=CH/CH2, CH2=CH/OH, CH2=CH/CH2O and CH2=CH/COO.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures
EP  - 946
IS  - 7
SP  - 933
VL  - 80
DO  - 10.2298/JSC141009005V
ER  - 
@article{
author = "Vuksanović, Jelena and Radović, Ivona and Šerbanović, Slobodan P. and Kijevčanin, Mirjana",
year = "2015",
abstract = "Experimental density rho, refractive index n(D) and viscosity eta data of three binary systems of poly(ethylene glycol) diacrylate (PEGDA) + ethanol, + 1-propanol and + 1-butanol were measured at eight temperatures from 288.15 to 323.15 K, with temperature step of 5 K, and at atmospheric pressure. The experimental data were correlated as a function of the PEGDA mole fraction and temperature. The densities and refractive indices of the investigated mixtures could be fitted well with exponential function vs. composition, including the temperature dependence of the parameters, while in the case of the viscosities, a polynomial function fits well the composition of the mixtures. In the case of the temperature correlation, all three properties (rho In eta and n(D)) exhibited linear trends. The viscosity modeling was performed using four models: the UNIFAC-VISCO, ASOG-VISCO, McAllister and the Teja-Rice models. For application of the UNIFAC-VISCO model, interaction parameters of following groups were determined: CH2=CH/CH3, CH2=CH/CH2, CH2=CH/OH, CH2=CH/CH2O and CH2=CH/COO. In addition, in the same way, the binary interaction parameters used in the ASOG-VISCO model of the following groups were determined: CH2=CH/CH2, CH2=CH/OH, CH2=CH/CH2O and CH2=CH/COO.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures",
pages = "946-933",
number = "7",
volume = "80",
doi = "10.2298/JSC141009005V"
}
Vuksanović, J., Radović, I., Šerbanović, S. P.,& Kijevčanin, M.. (2015). Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 80(7), 933-946.
https://doi.org/10.2298/JSC141009005V
Vuksanović J, Radović I, Šerbanović SP, Kijevčanin M. Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures. in Journal of the Serbian Chemical Society. 2015;80(7):933-946.
doi:10.2298/JSC141009005V .
Vuksanović, Jelena, Radović, Ivona, Šerbanović, Slobodan P., Kijevčanin, Mirjana, "Experimental study of the thermodynamic and transport properties of binary mixtures of poly(ethylene glycol) diacrylate and alcohols at different temperatures" in Journal of the Serbian Chemical Society, 80, no. 7 (2015):933-946,
https://doi.org/10.2298/JSC141009005V . .
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