Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200214 (Institue of Pesticides and Environmental Protection, Belgrade)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200214 (Institue of Pesticides and Environmental Protection, Belgrade) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200214 (Institut za pesticide i zaštitu životne sredine, Beograd) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200214 (Институт за пестициде и заштиту животне средине, Београд) (sr)
Authors

Publications

Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential

Jovanović, Aleksandar; Stevanović, Marija; Barudžija, Tanja; Cvijetić, Ilija; Lazarević, Slavica; Tomašević, Anđelka; Marinković, Aleksandar

(Institution of Chemical Engineers, 2023) 

TY  - JOUR
AU  - Jovanović, Aleksandar
AU  - Stevanović, Marija
AU  - Barudžija, Tanja
AU  - Cvijetić, Ilija
AU  - Lazarević, Slavica
AU  - Tomašević, Anđelka
AU  - Marinković, Aleksandar
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6611
AB  - This study focuses on establishing an efficient two-step technology, which includes: (1) consecutive adsorption-desorption, using cellulose-based membranes, bCells, and (2) photocatalytic degradation of the fungicide thiophanate-methyl (TPM), using synthesized Ag-P25 and Ce-P25 catalysts. The catalysts, obtained by controlled deposition of Ag2O/Ag and CeO2 onto P25 TiO2 carrier (Degussa), were characterized using ATR-FTIR, XRPD, BET, FESEM, HRTEM, HAADF-EDS and UV–DRS techniques. In order to establish a feasible purification technology, preconcentration of TPM was performed by adsorption, achieving 75.5 and 92.9 mg/g of TPM removal using bCell-EpL and bCell–EpL–TA membranes, respectively, followed by efficient desorption (> 95%) that provided acceptable TPM concentration for photodegradation experiments. Under optimal conditions (0.07 g/L of both catalysts), complete degradation of TPM (5 mg/L) occurred within 2 h, compared to 4 h for the base TiO2 P25. Measurements of quantum yield and the results of HPLC-MS analysis, alongside DFT calculation, assisted in understanding the TPM degradation pathways. New degradation products were detected and proposed from HPLC–MS analysis. Embryotoxic assays, performed on zebrafish (Danio rerio), applied to estimate the toxicity evolution of time-dependent generated TPM degradation products, showed low embryotoxic potential. Chemical oxygen demand (26 mg O2/L) confirmed low ecotoxicological pressure of effluent water.
PB  - Institution of Chemical Engineers
T2  - Process Safety and Environmental Protection
T1  - Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential
EP  - 443
SP  - 423
VL  - 178
DO  - 10.1016/j.psep.2023.08.054
ER  - 
@article{
author = "Jovanović, Aleksandar and Stevanović, Marija and Barudžija, Tanja and Cvijetić, Ilija and Lazarević, Slavica and Tomašević, Anđelka and Marinković, Aleksandar",
year = "2023",
abstract = "This study focuses on establishing an efficient two-step technology, which includes: (1) consecutive adsorption-desorption, using cellulose-based membranes, bCells, and (2) photocatalytic degradation of the fungicide thiophanate-methyl (TPM), using synthesized Ag-P25 and Ce-P25 catalysts. The catalysts, obtained by controlled deposition of Ag2O/Ag and CeO2 onto P25 TiO2 carrier (Degussa), were characterized using ATR-FTIR, XRPD, BET, FESEM, HRTEM, HAADF-EDS and UV–DRS techniques. In order to establish a feasible purification technology, preconcentration of TPM was performed by adsorption, achieving 75.5 and 92.9 mg/g of TPM removal using bCell-EpL and bCell–EpL–TA membranes, respectively, followed by efficient desorption (> 95%) that provided acceptable TPM concentration for photodegradation experiments. Under optimal conditions (0.07 g/L of both catalysts), complete degradation of TPM (5 mg/L) occurred within 2 h, compared to 4 h for the base TiO2 P25. Measurements of quantum yield and the results of HPLC-MS analysis, alongside DFT calculation, assisted in understanding the TPM degradation pathways. New degradation products were detected and proposed from HPLC–MS analysis. Embryotoxic assays, performed on zebrafish (Danio rerio), applied to estimate the toxicity evolution of time-dependent generated TPM degradation products, showed low embryotoxic potential. Chemical oxygen demand (26 mg O2/L) confirmed low ecotoxicological pressure of effluent water.",
publisher = "Institution of Chemical Engineers",
journal = "Process Safety and Environmental Protection",
title = "Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential",
pages = "443-423",
volume = "178",
doi = "10.1016/j.psep.2023.08.054"
}
Jovanović, A., Stevanović, M., Barudžija, T., Cvijetić, I., Lazarević, S., Tomašević, A.,& Marinković, A.. (2023). Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential. in Process Safety and Environmental Protection
Institution of Chemical Engineers., 178, 423-443.
https://doi.org/10.1016/j.psep.2023.08.054
Jovanović A, Stevanović M, Barudžija T, Cvijetić I, Lazarević S, Tomašević A, Marinković A. Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential. in Process Safety and Environmental Protection. 2023;178:423-443.
doi:10.1016/j.psep.2023.08.054 .
Jovanović, Aleksandar, Stevanović, Marija, Barudžija, Tanja, Cvijetić, Ilija, Lazarević, Slavica, Tomašević, Anđelka, Marinković, Aleksandar, "Advanced technology for photocatalytic degradation of thiophanate-methyl: Degradation pathways, DFT calculations and embryotoxic potential" in Process Safety and Environmental Protection, 178 (2023):423-443,
https://doi.org/10.1016/j.psep.2023.08.054 . .

Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji

Tomašević, Anđelka V.; Mijin, Dušan Ž.; Grgur, Branimir N.; Stupar, Stevan Lj.; Stojisavljević, Predrag N.; Ivanković, Negovan D.

(Beograd : Srpsko hemijsko društvo, 2023) 

TY  - CONF
AU  - Tomašević, Anđelka V.
AU  - Mijin, Dušan Ž.
AU  - Grgur, Branimir N.
AU  - Stupar, Stevan Lj.
AU  - Stojisavljević, Predrag N.
AU  - Ivanković, Negovan D.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6952
PB  - Beograd : Srpsko hemijsko društvo
C3  - Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine
T1  - Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji
T1  - Dependence of the degradation efficiency of the carbamate pesticide methomyl on the initial pH value during direct electrochemical oxidation
EP  - 174
SP  - 173
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6952
ER  - 
@conference{
author = "Tomašević, Anđelka V. and Mijin, Dušan Ž. and Grgur, Branimir N. and Stupar, Stevan Lj. and Stojisavljević, Predrag N. and Ivanković, Negovan D.",
year = "2023",
publisher = "Beograd : Srpsko hemijsko društvo",
journal = "Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine",
title = "Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji, Dependence of the degradation efficiency of the carbamate pesticide methomyl on the initial pH value during direct electrochemical oxidation",
pages = "174-173",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6952"
}
Tomašević, A. V., Mijin, D. Ž., Grgur, B. N., Stupar, S. Lj., Stojisavljević, P. N.,& Ivanković, N. D.. (2023). Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji. in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine
Beograd : Srpsko hemijsko društvo., 173-174.
https://hdl.handle.net/21.15107/rcub_technorep_6952
Tomašević AV, Mijin DŽ, Grgur BN, Stupar SL, Stojisavljević PN, Ivanković ND. Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji. in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine. 2023;:173-174.
https://hdl.handle.net/21.15107/rcub_technorep_6952 .
Tomašević, Anđelka V., Mijin, Dušan Ž., Grgur, Branimir N., Stupar, Stevan Lj., Stojisavljević, Predrag N., Ivanković, Negovan D., "Zavisnost efikasnosti razgradnje karbamatnog pesticida metomila od početne pH vrednosti rastvora pri direktnoj elektrohemijskoj oksidaciji" in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine (2023):173-174,
https://hdl.handle.net/21.15107/rcub_technorep_6952 .

Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite

Tomašević, Anđelka V.; Mijin, Dušan Ž.; Stupar, Stevan Lj.; Stojisavljević, Predrag N.; Ivanković, Negovan D.; Dinić, Denis

(Beograd : Srpsko hemijsko društvo, 2023) 

TY  - CONF
AU  - Tomašević, Anđelka V.
AU  - Mijin, Dušan Ž.
AU  - Stupar, Stevan Lj.
AU  - Stojisavljević, Predrag N.
AU  - Ivanković, Negovan D.
AU  - Dinić, Denis
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6953
PB  - Beograd : Srpsko hemijsko društvo
C3  - Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine
T1  - Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite
EP  - 176
SP  - 175
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6953
ER  - 
@conference{
author = "Tomašević, Anđelka V. and Mijin, Dušan Ž. and Stupar, Stevan Lj. and Stojisavljević, Predrag N. and Ivanković, Negovan D. and Dinić, Denis",
year = "2023",
publisher = "Beograd : Srpsko hemijsko društvo",
journal = "Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine",
title = "Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite",
pages = "176-175",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6953"
}
Tomašević, A. V., Mijin, D. Ž., Stupar, S. Lj., Stojisavljević, P. N., Ivanković, N. D.,& Dinić, D.. (2023). Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite. in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine
Beograd : Srpsko hemijsko društvo., 175-176.
https://hdl.handle.net/21.15107/rcub_technorep_6953
Tomašević AV, Mijin DŽ, Stupar SL, Stojisavljević PN, Ivanković ND, Dinić D. Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite. in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine. 2023;:175-176.
https://hdl.handle.net/21.15107/rcub_technorep_6953 .
Tomašević, Anđelka V., Mijin, Dušan Ž., Stupar, Stevan Lj., Stojisavljević, Predrag N., Ivanković, Negovan D., Dinić, Denis, "Influence of the solution pH value on the adsorption of carbamate pesticide methomyl onto synthetized Cobalt-Beta Zeolite" in Knjiga izvoda / 9. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem, EnviroChem2023, Kladovo 4-7. jun 2023. godine (2023):175-176,
https://hdl.handle.net/21.15107/rcub_technorep_6953 .