Geochemical investigations of sedimentary rocks - fossil fuels and environmental pollutants

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Geochemical investigations of sedimentary rocks - fossil fuels and environmental pollutants (en)
Геохемијска испитивања седиментних стена - фосилна горива и загађивачи животне средине (sr)
Geohemijska ispitivanja sedimentnih stena - fosilna goriva i zagađivači životne sredine (sr_RS)
Authors

Publications

Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model

Perić, Milica; Komatina, Mirko; Avtonijević, Dragi Lj.; Bugarski, Branko; Dželetović, Željko

(Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd, 2019)

TY  - JOUR
AU  - Perić, Milica
AU  - Komatina, Mirko
AU  - Avtonijević, Dragi Lj.
AU  - Bugarski, Branko
AU  - Dželetović, Željko
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4202
AB  - In this paper "well-to-pump" environmental analysis of pyrolytic diesel from Miscanthus gigantheus is performed. The average annual yield of Miscanthus from III-V year of cultivation on 1 ha of chernozem soil in Serbia (23.5 t) is considered as an input for the process. Two pyrolytic diesel pathways are considered: distributed pyrolytic pathway with external hydrogen production (from natural gas) and integrated pyrolytic pathway with internal hydrogen production (from pyrolytic oil). and are compared to a conventionally produced diesel pathway. The results of the analysis reveal that integrated-internal pyrolytic diesel pathway has lowest resources consumption and lowest pollutant emissions. Compared to conventionally produced diesel, integrated-internal pyrolysis pathway consumes 80% less of fossil fuels, and 92% more of renewables, has 90% lower global warming potential, 30% lower terrestrial acidification potential but 38% higher particulate matter formation potential. Compared to the distributed-external pathway, 88% less fossil fuels, and 36% less renewables are consumed in the integrated-internal pathway, global warming potential is 97% lower, terrestrial acidification is 20% lower, and particulate matter formation is 49% lower. Nevertheless, this pathway has high coal and hydroelectrical power consumption due to electricity production and high emissions of particulate matter, CO2, SOx, and N2O. Another drawback of this production pathway is the low yield of diesel obtained (38% lower than in distributed-external pathway). With this regard, it is still hard to designate production of diesel from fast pyrolysis of Miscanthus as a more environmentally friendly replacement of the conventional production diesel pathway.
PB  - Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd
T2  - Thermal Science
T1  - Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model
EP  - 378
IS  - 1
SP  - 365
VL  - 23
DO  - 10.2298/TSCI171215113P
ER  - 
@article{
author = "Perić, Milica and Komatina, Mirko and Avtonijević, Dragi Lj. and Bugarski, Branko and Dželetović, Željko",
year = "2019",
abstract = "In this paper "well-to-pump" environmental analysis of pyrolytic diesel from Miscanthus gigantheus is performed. The average annual yield of Miscanthus from III-V year of cultivation on 1 ha of chernozem soil in Serbia (23.5 t) is considered as an input for the process. Two pyrolytic diesel pathways are considered: distributed pyrolytic pathway with external hydrogen production (from natural gas) and integrated pyrolytic pathway with internal hydrogen production (from pyrolytic oil). and are compared to a conventionally produced diesel pathway. The results of the analysis reveal that integrated-internal pyrolytic diesel pathway has lowest resources consumption and lowest pollutant emissions. Compared to conventionally produced diesel, integrated-internal pyrolysis pathway consumes 80% less of fossil fuels, and 92% more of renewables, has 90% lower global warming potential, 30% lower terrestrial acidification potential but 38% higher particulate matter formation potential. Compared to the distributed-external pathway, 88% less fossil fuels, and 36% less renewables are consumed in the integrated-internal pathway, global warming potential is 97% lower, terrestrial acidification is 20% lower, and particulate matter formation is 49% lower. Nevertheless, this pathway has high coal and hydroelectrical power consumption due to electricity production and high emissions of particulate matter, CO2, SOx, and N2O. Another drawback of this production pathway is the low yield of diesel obtained (38% lower than in distributed-external pathway). With this regard, it is still hard to designate production of diesel from fast pyrolysis of Miscanthus as a more environmentally friendly replacement of the conventional production diesel pathway.",
publisher = "Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd",
journal = "Thermal Science",
title = "Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model",
pages = "378-365",
number = "1",
volume = "23",
doi = "10.2298/TSCI171215113P"
}
Perić, M., Komatina, M., Avtonijević, D. Lj., Bugarski, B.,& Dželetović, Ž.. (2019). Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model. in Thermal Science
Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd., 23(1), 365-378.
https://doi.org/10.2298/TSCI171215113P
Perić M, Komatina M, Avtonijević DL, Bugarski B, Dželetović Ž. Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model. in Thermal Science. 2019;23(1):365-378.
doi:10.2298/TSCI171215113P .
Perić, Milica, Komatina, Mirko, Avtonijević, Dragi Lj., Bugarski, Branko, Dželetović, Željko, "Diesel production by fast pyrolysis of miscanthus giganteus, well-to-pump analysis using the greet model" in Thermal Science, 23, no. 1 (2019):365-378,
https://doi.org/10.2298/TSCI171215113P . .
1
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Distribution of saturated hydrocarbons in unweathered and erosional landforms

Kašanin-Grubin, Milica; Stefanović, Milica; Jovančićević, Branimir; Šajnović, Aleksandra

(Lodz University of Technology, 2019)

TY  - CONF
AU  - Kašanin-Grubin, Milica
AU  - Stefanović, Milica
AU  - Jovančićević, Branimir
AU  - Šajnović, Aleksandra
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6162
AB  - Badlands are worldwide erosional landforms. The
formation of different badland morphologies is due to
the type of sedimentary bedrock, especially texture
and cementation degree, as well as climate.
In this study badlandes mudstones which have high
silt and clay contents from different locations in Italy,
Spain and Canada (Figure 1) were investigated from
organic-geochemical point of view. It is known that
vegetation is commonly identified as a significant
controlling mechanism of land degradation in
sensitive, semi-arid environments [1].
Total of 18 samples were analysed from 9 different
locations. From each location unweathered mudstone
and crust were taken. Qualitative and semiquantitative composition of the mineral part of
samples was determined using X-ray diffractometer.
Additionally, chemical properties such as pH, EC, Eh,
SAR are determined. The content of organic carbon
(Corg), was determined by elemental analysis after
removal of carbonates with diluted hydrochloric acid
(1:3, v/v). Soluble organic matter, bitumen, was
extracted from sediments using the Soxhlet extraction
with an azeotrope mixture of dichloromethan and
methanol (88:12, volume %). Isolation of the
saturated and aromatic fraction was done using
column chromatography. Organic compound were
analyzed by gas chromatography-mass spectrometry
(GC-MS) technique in the fractions of saturated
hydrocarbons.
Many study has shown that clay mineralogy is
extremely important for the behaviour of different
materials undergone weathering/erosional processes as well as smectite-containing sediments have been
shown to be more erodable [2]. Additonally, the
presence of enough amount of organic matter, iron
and aluminum oxides causes to make marls durable
while, sodium ions cause more erosion associated
with dispersed clay particles [3].
In this study, it was observed that major changes in
the distribution of saturated hydrocarbons occurred in
samples containing smectite compared to those
samples where mentioned mineral was not identified.
This confirms that the presence of smectite is crucial
factor for changes inorganic and organic matter
during erosional processes.
Mentioned changes in distribution of saturated
hydrocarbons are most pronounced for n-alkanes,
whereby higher odd-numbered n-alkanes are most
sensitive during erosive processes. For that reason
parameters which reflect the ratio of higher and lower
n-alkanes (for example, TAR, TAR/MAR, CPI)
decrease in eroded samples compared to unweathered
mudstones.
Significant changes in distribution of polycyclic
alkanes of sterane and terpane types were not
observed.
PB  - Lodz University of Technology
C3  - 20th European Meeting on Environmental Chemistry 2019
T1  - Distribution of saturated hydrocarbons in unweathered and erosional landforms
SP  - 116
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6162
ER  - 
@conference{
author = "Kašanin-Grubin, Milica and Stefanović, Milica and Jovančićević, Branimir and Šajnović, Aleksandra",
year = "2019",
abstract = "Badlands are worldwide erosional landforms. The
formation of different badland morphologies is due to
the type of sedimentary bedrock, especially texture
and cementation degree, as well as climate.
In this study badlandes mudstones which have high
silt and clay contents from different locations in Italy,
Spain and Canada (Figure 1) were investigated from
organic-geochemical point of view. It is known that
vegetation is commonly identified as a significant
controlling mechanism of land degradation in
sensitive, semi-arid environments [1].
Total of 18 samples were analysed from 9 different
locations. From each location unweathered mudstone
and crust were taken. Qualitative and semiquantitative composition of the mineral part of
samples was determined using X-ray diffractometer.
Additionally, chemical properties such as pH, EC, Eh,
SAR are determined. The content of organic carbon
(Corg), was determined by elemental analysis after
removal of carbonates with diluted hydrochloric acid
(1:3, v/v). Soluble organic matter, bitumen, was
extracted from sediments using the Soxhlet extraction
with an azeotrope mixture of dichloromethan and
methanol (88:12, volume %). Isolation of the
saturated and aromatic fraction was done using
column chromatography. Organic compound were
analyzed by gas chromatography-mass spectrometry
(GC-MS) technique in the fractions of saturated
hydrocarbons.
Many study has shown that clay mineralogy is
extremely important for the behaviour of different
materials undergone weathering/erosional processes as well as smectite-containing sediments have been
shown to be more erodable [2]. Additonally, the
presence of enough amount of organic matter, iron
and aluminum oxides causes to make marls durable
while, sodium ions cause more erosion associated
with dispersed clay particles [3].
In this study, it was observed that major changes in
the distribution of saturated hydrocarbons occurred in
samples containing smectite compared to those
samples where mentioned mineral was not identified.
This confirms that the presence of smectite is crucial
factor for changes inorganic and organic matter
during erosional processes.
Mentioned changes in distribution of saturated
hydrocarbons are most pronounced for n-alkanes,
whereby higher odd-numbered n-alkanes are most
sensitive during erosive processes. For that reason
parameters which reflect the ratio of higher and lower
n-alkanes (for example, TAR, TAR/MAR, CPI)
decrease in eroded samples compared to unweathered
mudstones.
Significant changes in distribution of polycyclic
alkanes of sterane and terpane types were not
observed.",
publisher = "Lodz University of Technology",
journal = "20th European Meeting on Environmental Chemistry 2019",
title = "Distribution of saturated hydrocarbons in unweathered and erosional landforms",
pages = "116",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6162"
}
Kašanin-Grubin, M., Stefanović, M., Jovančićević, B.,& Šajnović, A.. (2019). Distribution of saturated hydrocarbons in unweathered and erosional landforms. in 20th European Meeting on Environmental Chemistry 2019
Lodz University of Technology., 116.
https://hdl.handle.net/21.15107/rcub_technorep_6162
Kašanin-Grubin M, Stefanović M, Jovančićević B, Šajnović A. Distribution of saturated hydrocarbons in unweathered and erosional landforms. in 20th European Meeting on Environmental Chemistry 2019. 2019;:116.
https://hdl.handle.net/21.15107/rcub_technorep_6162 .
Kašanin-Grubin, Milica, Stefanović, Milica, Jovančićević, Branimir, Šajnović, Aleksandra, "Distribution of saturated hydrocarbons in unweathered and erosional landforms" in 20th European Meeting on Environmental Chemistry 2019 (2019):116,
https://hdl.handle.net/21.15107/rcub_technorep_6162 .

Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation

Marković, Marija; Marinović, Sanja; Mudrinić, Tihana; Ajduković, Marija; Jović-Jovičić, Nataša; Mojović, Zorica; Orlić, Jovana; Milutinović Nikolić, Aleksandra; Banković, Predrag

(Elsevier, 2019)

TY  - JOUR
AU  - Marković, Marija
AU  - Marinović, Sanja
AU  - Mudrinić, Tihana
AU  - Ajduković, Marija
AU  - Jović-Jovičić, Nataša
AU  - Mojović, Zorica
AU  - Orlić, Jovana
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5883
AB  - Aluminum pillared clay was synthesized and impregnated with Co2+ (CoAP), using incipient wetness impregnation method. The obtained CoAP was characterized by chemical analysis, XRPD, SEM with EDS, XPS and low temperature N2 physisorption. By these methods the incorporation of Co2+ was confirmed in both micro and mesoporous region. The synthesized material was investigated as a catalyst in catalytic oxidation of organic water pollutants – dyes – in the presence of Oxone® (peroxymonosulfate). Oxone® is a precursor of sulfate radicals. Tartrazine was chosen as a model dye pollutant. The influence of the mass of the catalyst, temperature and initial pH was investigated. Temperature increase was beneficial for dye degradation rate. The reaction rate was the highest for initial pH values around those corresponding to neutral conditions, somewhat slower for pH < 4 values, while for pH > 10 decolorization was significantly less expressed. Along with decolorization of tartrazine solution the formation and degradation of tartrazine catalytic oxidation products were monitored using UV–Vis spectroscopy. CoAP was found to be efficient catalyst in Oxone® induced catalytic degradation of both tartrazine and detected products of its degradation.
PB  - Elsevier
T2  - Applied Clay Science
T1  - Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation
SP  - 105276
VL  - 182
DO  - 10.1016/j.clay.2019.105276
ER  - 
@article{
author = "Marković, Marija and Marinović, Sanja and Mudrinić, Tihana and Ajduković, Marija and Jović-Jovičić, Nataša and Mojović, Zorica and Orlić, Jovana and Milutinović Nikolić, Aleksandra and Banković, Predrag",
year = "2019",
abstract = "Aluminum pillared clay was synthesized and impregnated with Co2+ (CoAP), using incipient wetness impregnation method. The obtained CoAP was characterized by chemical analysis, XRPD, SEM with EDS, XPS and low temperature N2 physisorption. By these methods the incorporation of Co2+ was confirmed in both micro and mesoporous region. The synthesized material was investigated as a catalyst in catalytic oxidation of organic water pollutants – dyes – in the presence of Oxone® (peroxymonosulfate). Oxone® is a precursor of sulfate radicals. Tartrazine was chosen as a model dye pollutant. The influence of the mass of the catalyst, temperature and initial pH was investigated. Temperature increase was beneficial for dye degradation rate. The reaction rate was the highest for initial pH values around those corresponding to neutral conditions, somewhat slower for pH < 4 values, while for pH > 10 decolorization was significantly less expressed. Along with decolorization of tartrazine solution the formation and degradation of tartrazine catalytic oxidation products were monitored using UV–Vis spectroscopy. CoAP was found to be efficient catalyst in Oxone® induced catalytic degradation of both tartrazine and detected products of its degradation.",
publisher = "Elsevier",
journal = "Applied Clay Science",
title = "Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation",
pages = "105276",
volume = "182",
doi = "10.1016/j.clay.2019.105276"
}
Marković, M., Marinović, S., Mudrinić, T., Ajduković, M., Jović-Jovičić, N., Mojović, Z., Orlić, J., Milutinović Nikolić, A.,& Banković, P.. (2019). Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation. in Applied Clay Science
Elsevier., 182, 105276.
https://doi.org/10.1016/j.clay.2019.105276
Marković M, Marinović S, Mudrinić T, Ajduković M, Jović-Jovičić N, Mojović Z, Orlić J, Milutinović Nikolić A, Banković P. Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation. in Applied Clay Science. 2019;182:105276.
doi:10.1016/j.clay.2019.105276 .
Marković, Marija, Marinović, Sanja, Mudrinić, Tihana, Ajduković, Marija, Jović-Jovičić, Nataša, Mojović, Zorica, Orlić, Jovana, Milutinović Nikolić, Aleksandra, Banković, Predrag, "Co(II) impregnated Al(III)-pillared montmorillonite–Synthesis, characterization and catalytic properties in Oxone® activation for dye degradation" in Applied Clay Science, 182 (2019):105276,
https://doi.org/10.1016/j.clay.2019.105276 . .
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Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators

Zarić, Nenad M.; Deljanin, Isidora; Ilijević, Konstantin; Stanisavljević, Ljubiša; Ristić, Mirjana; Gržetić, Ivan

(Peerj Inc, London, 2018)

TY  - JOUR
AU  - Zarić, Nenad M.
AU  - Deljanin, Isidora
AU  - Ilijević, Konstantin
AU  - Stanisavljević, Ljubiša
AU  - Ristić, Mirjana
AU  - Gržetić, Ivan
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3884
AB  - With the increase in anthropogenic activities metal pollution is also increased and needs to be closely monitored. In this study honeybees were used as bioindicators to monitor metal pollution. Metal pollution in honeybees represents pollution present in air, water and soil. Concentrations of As, Cs, Hg, Mo, Sb, Se, U and V were measured. The aim of this study was to assess spatial and temporal variations of metal concentrations in honeybees. Samples of honeybees were taken at five different regions in Serbia (Belgrade - BG, Pancevo - PA, Pavlis - PV, Mesic - MS, and Kostolac - TPP) during 2014. Spatial variations were observed for Sb, which had higher concentrations in BG compared to all other regions, and for U, with higher concentrations in the TPP region. High concentrations of Sb in BG were attributed to intense traffic, while higher U concentrations in the TPP region are due to the vicinity of coal fired power plants. In order to assess temporal variations at two locations (PA and PV) samples were taken during July and September of 2014 and June, July, August and September of 2015. During 2014 observing months of sampling higher concentrations in July were detected for Sb and U in BG, which is attributed to lifecycle of plants and honeybees. During the same year higher concentrations in September were observed for As, Sb in PA and Hg in PV. This is due to high precipitation during the peak of bee activity in spring/summer of 2014. No differences between months of sampling were detected during 2015. Between 2014 and 2015 statistically significant differences were observed for Hg, Mo and V; all elements had higher concentrations in 2014. This is in accordance with the trend of reduction of metal concentrations in the bodies of honeybees throughout the years in this region.
PB  - Peerj Inc, London
T2  - PEERJ
T1  - Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators
VL  - 6
DO  - 10.7717/peerj.5197
ER  - 
@article{
author = "Zarić, Nenad M. and Deljanin, Isidora and Ilijević, Konstantin and Stanisavljević, Ljubiša and Ristić, Mirjana and Gržetić, Ivan",
year = "2018",
abstract = "With the increase in anthropogenic activities metal pollution is also increased and needs to be closely monitored. In this study honeybees were used as bioindicators to monitor metal pollution. Metal pollution in honeybees represents pollution present in air, water and soil. Concentrations of As, Cs, Hg, Mo, Sb, Se, U and V were measured. The aim of this study was to assess spatial and temporal variations of metal concentrations in honeybees. Samples of honeybees were taken at five different regions in Serbia (Belgrade - BG, Pancevo - PA, Pavlis - PV, Mesic - MS, and Kostolac - TPP) during 2014. Spatial variations were observed for Sb, which had higher concentrations in BG compared to all other regions, and for U, with higher concentrations in the TPP region. High concentrations of Sb in BG were attributed to intense traffic, while higher U concentrations in the TPP region are due to the vicinity of coal fired power plants. In order to assess temporal variations at two locations (PA and PV) samples were taken during July and September of 2014 and June, July, August and September of 2015. During 2014 observing months of sampling higher concentrations in July were detected for Sb and U in BG, which is attributed to lifecycle of plants and honeybees. During the same year higher concentrations in September were observed for As, Sb in PA and Hg in PV. This is due to high precipitation during the peak of bee activity in spring/summer of 2014. No differences between months of sampling were detected during 2015. Between 2014 and 2015 statistically significant differences were observed for Hg, Mo and V; all elements had higher concentrations in 2014. This is in accordance with the trend of reduction of metal concentrations in the bodies of honeybees throughout the years in this region.",
publisher = "Peerj Inc, London",
journal = "PEERJ",
title = "Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators",
volume = "6",
doi = "10.7717/peerj.5197"
}
Zarić, N. M., Deljanin, I., Ilijević, K., Stanisavljević, L., Ristić, M.,& Gržetić, I.. (2018). Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators. in PEERJ
Peerj Inc, London., 6.
https://doi.org/10.7717/peerj.5197
Zarić NM, Deljanin I, Ilijević K, Stanisavljević L, Ristić M, Gržetić I. Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators. in PEERJ. 2018;6.
doi:10.7717/peerj.5197 .
Zarić, Nenad M., Deljanin, Isidora, Ilijević, Konstantin, Stanisavljević, Ljubiša, Ristić, Mirjana, Gržetić, Ivan, "Assessment of spatial and temporal variations in trace element concentrations using honeybees (Apis mellifera) as bioindicators" in PEERJ, 6 (2018),
https://doi.org/10.7717/peerj.5197 . .
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Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps

Zarić, Nenad M.; Deljanin, Isidora; Ilijević, Konstantin; Stanisavljević, Ljubiša; Ristić, Mirjana; Gržetić, Ivan

(Elsevier, Amsterdam, 2018)

TY  - JOUR
AU  - Zarić, Nenad M.
AU  - Deljanin, Isidora
AU  - Ilijević, Konstantin
AU  - Stanisavljević, Ljubiša
AU  - Ristić, Mirjana
AU  - Gržetić, Ivan
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3887
AB  - In this study, honeybees were used to determine spatio-temporal variations and origin sources of Pb. Lead concentrations and isotopic composition were used in combination with selected statistical methods. The sampling was carried out at five different locations in Serbia: urban region (BG), petrochemical industry (PA), suburban region (PV), rural region (MS) and thermal power plant region (TPP) during 2014. At PA and PV locations, samples were taken during multiple years. This is the first use of Kohonen self-organizing map (SOM) in combination with honeybees as bioindicators to determine spatio-temporal variations and origin of Pb pollution. It was observed that during the years Pb concentrations were in decline. Anthropogenic sources are most dominant in BG and TPP, in PA there are mixed sources of natural and anthropogenic origin and in PV Pb is of natural origin. It can be concluded that honeybees in combination with SOM can be used to differentiate between slight changes in spatio-temporal variations of Pb, as well as for source appointment.
PB  - Elsevier, Amsterdam
T2  - Science of the Total Environment
T1  - Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps
EP  - 62
SP  - 56
VL  - 642
DO  - 10.1016/j.scitotenv.2018.06.040
ER  - 
@article{
author = "Zarić, Nenad M. and Deljanin, Isidora and Ilijević, Konstantin and Stanisavljević, Ljubiša and Ristić, Mirjana and Gržetić, Ivan",
year = "2018",
abstract = "In this study, honeybees were used to determine spatio-temporal variations and origin sources of Pb. Lead concentrations and isotopic composition were used in combination with selected statistical methods. The sampling was carried out at five different locations in Serbia: urban region (BG), petrochemical industry (PA), suburban region (PV), rural region (MS) and thermal power plant region (TPP) during 2014. At PA and PV locations, samples were taken during multiple years. This is the first use of Kohonen self-organizing map (SOM) in combination with honeybees as bioindicators to determine spatio-temporal variations and origin of Pb pollution. It was observed that during the years Pb concentrations were in decline. Anthropogenic sources are most dominant in BG and TPP, in PA there are mixed sources of natural and anthropogenic origin and in PV Pb is of natural origin. It can be concluded that honeybees in combination with SOM can be used to differentiate between slight changes in spatio-temporal variations of Pb, as well as for source appointment.",
publisher = "Elsevier, Amsterdam",
journal = "Science of the Total Environment",
title = "Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps",
pages = "62-56",
volume = "642",
doi = "10.1016/j.scitotenv.2018.06.040"
}
Zarić, N. M., Deljanin, I., Ilijević, K., Stanisavljević, L., Ristić, M.,& Gržetić, I.. (2018). Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps. in Science of the Total Environment
Elsevier, Amsterdam., 642, 56-62.
https://doi.org/10.1016/j.scitotenv.2018.06.040
Zarić NM, Deljanin I, Ilijević K, Stanisavljević L, Ristić M, Gržetić I. Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps. in Science of the Total Environment. 2018;642:56-62.
doi:10.1016/j.scitotenv.2018.06.040 .
Zarić, Nenad M., Deljanin, Isidora, Ilijević, Konstantin, Stanisavljević, Ljubiša, Ristić, Mirjana, Gržetić, Ivan, "Honeybees as sentinels of lead pollution: Spatio-temporal variations and source appointment using stable isotopes and Kohonen self-organizing maps" in Science of the Total Environment, 642 (2018):56-62,
https://doi.org/10.1016/j.scitotenv.2018.06.040 . .
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Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia

Perić, Milica; Komatina, Mirko; Antonijević, Dragi; Bugarski, Branko; Dželetović, Željko

(MDPI, Basel, 2018)

TY  - JOUR
AU  - Perić, Milica
AU  - Komatina, Mirko
AU  - Antonijević, Dragi
AU  - Bugarski, Branko
AU  - Dželetović, Željko
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3921
AB  - This paper investigates the environmental impacts and energy benefits of the cultivation of Miscanthus (Miscanthus x giganteus Greef et Deu.), in order to initiate its use in sustainable household heating in the Republic of Serbia. Based on the analysis of available data regarding the use of agricultural machinery in Serbia, a Miscanthus supply chain is constructed and examined in detail, scrutinizing all relevant operationsfrom planting of rhizomes to thermal energy production. Results of the life cycle assessment identify the briquetting process as the most environmentally burdensome operation due to high electricity consumption and low productivity. It is concluded that an average yield of 23.5 t dry matter (d.m.) year(-1) obtained from 1 ha of chernozem soil would have energy output:energy input (EO:EI) ratio of 51:1, and would release 365.5 gigajoules (GJ) of heat during combustion in a boiler. With this amount of energy, around 383 m(2) of a free-standing family house in Serbia can be heated annually. The same amount of energy is obtained by the combustion of 22 t of lignite or 23 t of wood logs. The substitution of lignite and wood with Miscanthus briquettes would lead to significant reduction of CO2 equivalents (eq), SO2 eq, P eq, N eq, 1,4 dichlorobenzene (1,4-DB) eq, Non-methane volatile organic compound (NMVOC), PM10 eq and U235 eq emissions. This designates Miscanthus as a more sustainable energy solution for household heating. In instances where more modern agricultural machinery is used, emission reduction is higher, except for CO2 eq due to higher emission factors predicted for more powerful engines. Depending on Miscanthus' annual yield, the replacement of set-aside land with Miscanthus plantations result in carbon
PB  - MDPI, Basel
T2  - Forests
T1  - Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia
IS  - 10
VL  - 9
DO  - 10.3390/f9100654
ER  - 
@article{
author = "Perić, Milica and Komatina, Mirko and Antonijević, Dragi and Bugarski, Branko and Dželetović, Željko",
year = "2018",
abstract = "This paper investigates the environmental impacts and energy benefits of the cultivation of Miscanthus (Miscanthus x giganteus Greef et Deu.), in order to initiate its use in sustainable household heating in the Republic of Serbia. Based on the analysis of available data regarding the use of agricultural machinery in Serbia, a Miscanthus supply chain is constructed and examined in detail, scrutinizing all relevant operationsfrom planting of rhizomes to thermal energy production. Results of the life cycle assessment identify the briquetting process as the most environmentally burdensome operation due to high electricity consumption and low productivity. It is concluded that an average yield of 23.5 t dry matter (d.m.) year(-1) obtained from 1 ha of chernozem soil would have energy output:energy input (EO:EI) ratio of 51:1, and would release 365.5 gigajoules (GJ) of heat during combustion in a boiler. With this amount of energy, around 383 m(2) of a free-standing family house in Serbia can be heated annually. The same amount of energy is obtained by the combustion of 22 t of lignite or 23 t of wood logs. The substitution of lignite and wood with Miscanthus briquettes would lead to significant reduction of CO2 equivalents (eq), SO2 eq, P eq, N eq, 1,4 dichlorobenzene (1,4-DB) eq, Non-methane volatile organic compound (NMVOC), PM10 eq and U235 eq emissions. This designates Miscanthus as a more sustainable energy solution for household heating. In instances where more modern agricultural machinery is used, emission reduction is higher, except for CO2 eq due to higher emission factors predicted for more powerful engines. Depending on Miscanthus' annual yield, the replacement of set-aside land with Miscanthus plantations result in carbon",
publisher = "MDPI, Basel",
journal = "Forests",
title = "Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia",
number = "10",
volume = "9",
doi = "10.3390/f9100654"
}
Perić, M., Komatina, M., Antonijević, D., Bugarski, B.,& Dželetović, Ž.. (2018). Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia. in Forests
MDPI, Basel., 9(10).
https://doi.org/10.3390/f9100654
Perić M, Komatina M, Antonijević D, Bugarski B, Dželetović Ž. Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia. in Forests. 2018;9(10).
doi:10.3390/f9100654 .
Perić, Milica, Komatina, Mirko, Antonijević, Dragi, Bugarski, Branko, Dželetović, Željko, "Life Cycle Impact Assessment of Miscanthus Crop for Sustainable Household Heating in Serbia" in Forests, 9, no. 10 (2018),
https://doi.org/10.3390/f9100654 . .
1
13
7
14

Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution

Zarić, Nenad M.; Ilijević, Konstantin; Stanisavljević, Ljubiša; Gržetić, Ivan

(Springer Heidelberg, Heidelberg, 2017)

TY  - JOUR
AU  - Zarić, Nenad M.
AU  - Ilijević, Konstantin
AU  - Stanisavljević, Ljubiša
AU  - Gržetić, Ivan
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5859
AB  - The ability of honeybees to collect particulate matter (PM) on their bodies makes them outstanding bioindicators. In this study, two cities, Pancevo (PA) and Vrac (VS), South Banat district, Vojvodina, Serbia, were covered with two sampling sites each. The aims of this study were to determine concentrations of Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Na, Ni, Sr, and Zn in the bodies of honeybees during July and September of 2013, 2014, and 2015 and to analyze their spatial and temporal variations and sources of analyzed elements, as well as to assess pollution levels in the two cities. Significant temporal differences were found for Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Na, Ni, and Zn. Trend of reduction in metal concentrations in bodies of honeybees during the years was observed. Statistically significant spatial variations were observed for Al, Ba, and Sr, with higher concentrations in VS. PCA and CA analyses were used for the first time to assess sources of metals found in honeybees. These analyses showed two sources of metals. Co, Cd, Na, Fe, Mn, Zn, and partly Cu were contributed to anthropogenic sources, while Ca, Al, Mg, Cr, Ba, Sr, and Ni were contributed to natural sources.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution
EP  - 25838
IS  - 33
SP  - 25828
VL  - 24
DO  - 10.1007/s11356-017-0196-7
ER  - 
@article{
author = "Zarić, Nenad M. and Ilijević, Konstantin and Stanisavljević, Ljubiša and Gržetić, Ivan",
year = "2017",
abstract = "The ability of honeybees to collect particulate matter (PM) on their bodies makes them outstanding bioindicators. In this study, two cities, Pancevo (PA) and Vrac (VS), South Banat district, Vojvodina, Serbia, were covered with two sampling sites each. The aims of this study were to determine concentrations of Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Na, Ni, Sr, and Zn in the bodies of honeybees during July and September of 2013, 2014, and 2015 and to analyze their spatial and temporal variations and sources of analyzed elements, as well as to assess pollution levels in the two cities. Significant temporal differences were found for Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Na, Ni, and Zn. Trend of reduction in metal concentrations in bodies of honeybees during the years was observed. Statistically significant spatial variations were observed for Al, Ba, and Sr, with higher concentrations in VS. PCA and CA analyses were used for the first time to assess sources of metals found in honeybees. These analyses showed two sources of metals. Co, Cd, Na, Fe, Mn, Zn, and partly Cu were contributed to anthropogenic sources, while Ca, Al, Mg, Cr, Ba, Sr, and Ni were contributed to natural sources.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution",
pages = "25838-25828",
number = "33",
volume = "24",
doi = "10.1007/s11356-017-0196-7"
}
Zarić, N. M., Ilijević, K., Stanisavljević, L.,& Gržetić, I.. (2017). Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 24(33), 25828-25838.
https://doi.org/10.1007/s11356-017-0196-7
Zarić NM, Ilijević K, Stanisavljević L, Gržetić I. Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution. in Environmental Science and Pollution Research. 2017;24(33):25828-25838.
doi:10.1007/s11356-017-0196-7 .
Zarić, Nenad M., Ilijević, Konstantin, Stanisavljević, Ljubiša, Gržetić, Ivan, "Use of honeybees (Apis mellifera L.) as bioindicators for assessment and source appointment of metal pollution" in Environmental Science and Pollution Research, 24, no. 33 (2017):25828-25838,
https://doi.org/10.1007/s11356-017-0196-7 . .
1
31
15
26

Recent development of bioaugmentation methods for tobacco wastewater treatment

Zarić, Milana; Zarić, Nenad M; Ivković, Jelena; Slavnić, Danijela; Bugarski, Branko

(University of Babes-Bolyai, Cluj-Napoca, 2015)

TY  - JOUR
AU  - Zarić, Milana
AU  - Zarić, Nenad M
AU  - Ivković, Jelena
AU  - Slavnić, Danijela
AU  - Bugarski, Branko
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3054
AB  - In production of cigarettes a lot of tobacco waste, with nicotine, goes into the environment. Hence, there is a need for an economic and efficient method to diminish the discharge of hazardous materials from tobacco wastewaters. Bioaugmentation using specialized bacteria strains could improve the efficiency of tobacco wastewater treatment. In this review paper we present bioaugmentation methods for tobacco wastewater treatment that were published in last few years. Bioaugmentation systems have proven to be very effective in removal of nicotine and TOC; it was shown that Pseudomonas sp. HF-1 and TW bacteria strains can be successfully used in reactors. Recent studies showed that controlling pH in the reactors can improve reactor performance in removing nicotine and TOC from tobacco wastewater.
PB  - University of Babes-Bolyai, Cluj-Napoca
T2  - Studia Universitatis Babes-Bolyai Chemia
T1  - Recent development of bioaugmentation methods for tobacco wastewater treatment
EP  - 124
IS  - 4
SP  - 115
VL  - 60
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3054
ER  - 
@article{
author = "Zarić, Milana and Zarić, Nenad M and Ivković, Jelena and Slavnić, Danijela and Bugarski, Branko",
year = "2015",
abstract = "In production of cigarettes a lot of tobacco waste, with nicotine, goes into the environment. Hence, there is a need for an economic and efficient method to diminish the discharge of hazardous materials from tobacco wastewaters. Bioaugmentation using specialized bacteria strains could improve the efficiency of tobacco wastewater treatment. In this review paper we present bioaugmentation methods for tobacco wastewater treatment that were published in last few years. Bioaugmentation systems have proven to be very effective in removal of nicotine and TOC; it was shown that Pseudomonas sp. HF-1 and TW bacteria strains can be successfully used in reactors. Recent studies showed that controlling pH in the reactors can improve reactor performance in removing nicotine and TOC from tobacco wastewater.",
publisher = "University of Babes-Bolyai, Cluj-Napoca",
journal = "Studia Universitatis Babes-Bolyai Chemia",
title = "Recent development of bioaugmentation methods for tobacco wastewater treatment",
pages = "124-115",
number = "4",
volume = "60",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3054"
}
Zarić, M., Zarić, N. M., Ivković, J., Slavnić, D.,& Bugarski, B.. (2015). Recent development of bioaugmentation methods for tobacco wastewater treatment. in Studia Universitatis Babes-Bolyai Chemia
University of Babes-Bolyai, Cluj-Napoca., 60(4), 115-124.
https://hdl.handle.net/21.15107/rcub_technorep_3054
Zarić M, Zarić NM, Ivković J, Slavnić D, Bugarski B. Recent development of bioaugmentation methods for tobacco wastewater treatment. in Studia Universitatis Babes-Bolyai Chemia. 2015;60(4):115-124.
https://hdl.handle.net/21.15107/rcub_technorep_3054 .
Zarić, Milana, Zarić, Nenad M, Ivković, Jelena, Slavnić, Danijela, Bugarski, Branko, "Recent development of bioaugmentation methods for tobacco wastewater treatment" in Studia Universitatis Babes-Bolyai Chemia, 60, no. 4 (2015):115-124,
https://hdl.handle.net/21.15107/rcub_technorep_3054 .