TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Marinković, Aleksandar
AU  - Mijin, Dušan
AU  - Radišić, Marina
AU  - Porobić, Slavica
AU  - Prlainović, Nevena
AU  - Gašić, Slavica
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4375
AB  - Photocatalytic degradation of the carbamate insecticide methomyl and its commercial product Lannate-90 in aqueous suspension of TiO2 and ZnO using an Osram ultra-vitalux lamp (315-400 nm) was investigated. The objective of the investigation was to study and compare the rates of photochemical degradation of the pure active compound and its formulated product in order to find out the impact of inert ingredients on degradation processes. The photo-chemical degradation of pure methomyl was found to be slower than the degradation of its commercial product Lannate-90. Photodegradation was investigated by UV-Vis spectrometry and HPLC, while mineralization was monitored using IC and TOC analyses. Light absorption capabilities of catalysts were characterized by ultraviolet-visible diffuse reflectance spectroscopy method, while the stability of catalysts was studied by infrared analyses. Degradation products of methomyl and its formulated product were identified by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) results and tentative photodegradation pathways were proposed.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - A study of photocatalytic degradation of methomyl and its commercial product lannate-90
EP  - 247
IS  - 3
SP  - 237
VL  - 26
DO  - 10.2298/CICEQ190424002T
ER  - 

@article{
author = "Tomašević, Anđelka and Marinković, Aleksandar and Mijin, Dušan and Radišić, Marina and Porobić, Slavica and Prlainović, Nevena and Gašić, Slavica",
year = "2020",
abstract = "Photocatalytic degradation of the carbamate insecticide methomyl and its commercial product Lannate-90 in aqueous suspension of TiO2 and ZnO using an Osram ultra-vitalux lamp (315-400 nm) was investigated. The objective of the investigation was to study and compare the rates of photochemical degradation of the pure active compound and its formulated product in order to find out the impact of inert ingredients on degradation processes. The photo-chemical degradation of pure methomyl was found to be slower than the degradation of its commercial product Lannate-90. Photodegradation was investigated by UV-Vis spectrometry and HPLC, while mineralization was monitored using IC and TOC analyses. Light absorption capabilities of catalysts were characterized by ultraviolet-visible diffuse reflectance spectroscopy method, while the stability of catalysts was studied by infrared analyses. Degradation products of methomyl and its formulated product were identified by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) results and tentative photodegradation pathways were proposed.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "A study of photocatalytic degradation of methomyl and its commercial product lannate-90",
pages = "247-237",
number = "3",
volume = "26",
doi = "10.2298/CICEQ190424002T"
}

Tomašević, A., Marinković, A., Mijin, D., Radišić, M., Porobić, S., Prlainović, N.,& Gašić, S.. (2020). A study of photocatalytic degradation of methomyl and its commercial product lannate-90. in Chemical Industry & Chemical Engineering Quarterly
Savez hemijskih inženjera, Beograd., 26(3), 237-247.
https://doi.org/10.2298/CICEQ190424002T

Tomašević A, Marinković A, Mijin D, Radišić M, Porobić S, Prlainović N, Gašić S. A study of photocatalytic degradation of methomyl and its commercial product lannate-90. in Chemical Industry & Chemical Engineering Quarterly. 2020;26(3):237-247.
doi:10.2298/CICEQ190424002T .

Tomašević, Anđelka, Marinković, Aleksandar, Mijin, Dušan, Radišić, Marina, Porobić, Slavica, Prlainović, Nevena, Gašić, Slavica, "A study of photocatalytic degradation of methomyl and its commercial product lannate-90" in Chemical Industry & Chemical Engineering Quarterly, 26, no. 3 (2020):237-247,
https://doi.org/10.2298/CICEQ190424002T . .

TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Radišić, Marina
AU  - Prlainović, Nevena
AU  - Cvijetić, Ilija
AU  - Kovačević, Danijela
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4480
AB  - This study describes photolysis of 1 x 10(-4) M methomyl solution in deionized water and in eleven organic solvents, both polar and nonpolar: methanol, ethanol, n-propanol, isopropanol, sec-butanol, tert-butanol, isobutanol, isopentanol, n-hexane, acetonitrile, and dichloromethane. Photolysis of methomyl at 254 nm was performed using Osram mercury lamp (6 x 8 W) by exposing to irradiation for five hours. All photolytic methomyl reactions were studied by UV/Vis spectroscopy within a wavelength range of 190 - 300 nm (Spectrum Mode), and at 233.4 nm (Quantitative Mode), while the rate of photodecomposition of methomyl was measured using UV spectroscopy and HPLC. In order to get better insight in the photolysis of methomyl, a liquid chromatography-mass spectrometry (LC-MSn) was used. The rate of methomyl photolysis was solvent-specific and the following reaction rate order was established: deionized water  gt  tert-butanol  gt  n-hexane  gt  sec-butanol  gt  ethanol  gt  isopentanol  gt  isobutanol  gt  isopropanol  gt  methanol  gt  acetonitrile  gt  dichloromethane  gt  n-propanol. Both nonspecific and specific solvent-solute interactions contribute mutually to the differences in the obtained quantum yields. Results of quantum chemical calculations, using CBS-QB3 method, provided insights into the solvent effects on both ground and excited state. The LC/MSn analysis showed the formation of several photolytic products.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Photochemistry and Photobiology A-Chemistry
T1  - Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study
VL  - 391
DO  - 10.1016/j.jphotochem.2020.112366
ER  - 

@article{
author = "Tomašević, Anđelka and Mijin, Dušan and Radišić, Marina and Prlainović, Nevena and Cvijetić, Ilija and Kovačević, Danijela and Marinković, Aleksandar",
year = "2020",
abstract = "This study describes photolysis of 1 x 10(-4) M methomyl solution in deionized water and in eleven organic solvents, both polar and nonpolar: methanol, ethanol, n-propanol, isopropanol, sec-butanol, tert-butanol, isobutanol, isopentanol, n-hexane, acetonitrile, and dichloromethane. Photolysis of methomyl at 254 nm was performed using Osram mercury lamp (6 x 8 W) by exposing to irradiation for five hours. All photolytic methomyl reactions were studied by UV/Vis spectroscopy within a wavelength range of 190 - 300 nm (Spectrum Mode), and at 233.4 nm (Quantitative Mode), while the rate of photodecomposition of methomyl was measured using UV spectroscopy and HPLC. In order to get better insight in the photolysis of methomyl, a liquid chromatography-mass spectrometry (LC-MSn) was used. The rate of methomyl photolysis was solvent-specific and the following reaction rate order was established: deionized water  gt  tert-butanol  gt  n-hexane  gt  sec-butanol  gt  ethanol  gt  isopentanol  gt  isobutanol  gt  isopropanol  gt  methanol  gt  acetonitrile  gt  dichloromethane  gt  n-propanol. Both nonspecific and specific solvent-solute interactions contribute mutually to the differences in the obtained quantum yields. Results of quantum chemical calculations, using CBS-QB3 method, provided insights into the solvent effects on both ground and excited state. The LC/MSn analysis showed the formation of several photolytic products.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Photochemistry and Photobiology A-Chemistry",
title = "Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study",
volume = "391",
doi = "10.1016/j.jphotochem.2020.112366"
}

Tomašević, A., Mijin, D., Radišić, M., Prlainović, N., Cvijetić, I., Kovačević, D.,& Marinković, A.. (2020). Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study. in Journal of Photochemistry and Photobiology A-Chemistry
Elsevier Science Sa, Lausanne., 391.
https://doi.org/10.1016/j.jphotochem.2020.112366

Tomašević A, Mijin D, Radišić M, Prlainović N, Cvijetić I, Kovačević D, Marinković A. Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study. in Journal of Photochemistry and Photobiology A-Chemistry. 2020;391.
doi:10.1016/j.jphotochem.2020.112366 .

Tomašević, Anđelka, Mijin, Dušan, Radišić, Marina, Prlainović, Nevena, Cvijetić, Ilija, Kovačević, Danijela, Marinković, Aleksandar, "Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study" in Journal of Photochemistry and Photobiology A-Chemistry, 391 (2020),
https://doi.org/10.1016/j.jphotochem.2020.112366 . .

TY  - CONF
AU  - Tomašević, Anđelka
AU  - Marinković, Aleksandar
AU  - Mijin, Dušan
AU  - Prlainović, Nevena
AU  - Gašić, Slavica
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7316
PB  - Ljubljana : Slovenian Chemical Society
C3  - EAAOP-6 : 6th European Conference on Environmental Applications of Advanced Oxidation Processes : 26-30 June 2019, Portorož - Portorose, Slovenia : book of abstracts
T1  - Photocatalytic degradation of methomyl and Lannate-90
EP  - 388
SP  - 387
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7316
ER  - 

@conference{
author = "Tomašević, Anđelka and Marinković, Aleksandar and Mijin, Dušan and Prlainović, Nevena and Gašić, Slavica",
year = "2019",
publisher = "Ljubljana : Slovenian Chemical Society",
journal = "EAAOP-6 : 6th European Conference on Environmental Applications of Advanced Oxidation Processes : 26-30 June 2019, Portorož - Portorose, Slovenia : book of abstracts",
title = "Photocatalytic degradation of methomyl and Lannate-90",
pages = "388-387",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7316"
}

Tomašević, A., Marinković, A., Mijin, D., Prlainović, N.,& Gašić, S.. (2019). Photocatalytic degradation of methomyl and Lannate-90. in EAAOP-6 : 6th European Conference on Environmental Applications of Advanced Oxidation Processes : 26-30 June 2019, Portorož - Portorose, Slovenia : book of abstracts
Ljubljana : Slovenian Chemical Society., 387-388.
https://hdl.handle.net/21.15107/rcub_technorep_7316

Tomašević A, Marinković A, Mijin D, Prlainović N, Gašić S. Photocatalytic degradation of methomyl and Lannate-90. in EAAOP-6 : 6th European Conference on Environmental Applications of Advanced Oxidation Processes : 26-30 June 2019, Portorož - Portorose, Slovenia : book of abstracts. 2019;:387-388.
https://hdl.handle.net/21.15107/rcub_technorep_7316 .

Tomašević, Anđelka, Marinković, Aleksandar, Mijin, Dušan, Prlainović, Nevena, Gašić, Slavica, "Photocatalytic degradation of methomyl and Lannate-90" in EAAOP-6 : 6th European Conference on Environmental Applications of Advanced Oxidation Processes : 26-30 June 2019, Portorož - Portorose, Slovenia : book of abstracts (2019):387-388,
https://hdl.handle.net/21.15107/rcub_technorep_7316 .

TY  - CONF
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Gašić, Slavica
AU  - Prlainović, Nevena
AU  - Marinković, Aleksandar
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7317
PB  - Leskovac : Faculty of Technology
C3  - Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019
T1  - Photocatalysis of carbofuran: comparison of ZnO and TiO2 efficiency
SP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7317
ER  - 

@conference{
author = "Tomašević, Anđelka and Mijin, Dušan and Gašić, Slavica and Prlainović, Nevena and Marinković, Aleksandar",
year = "2019",
publisher = "Leskovac : Faculty of Technology",
journal = "Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019",
title = "Photocatalysis of carbofuran: comparison of ZnO and TiO2 efficiency",
pages = "92",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7317"
}

Tomašević, A., Mijin, D., Gašić, S., Prlainović, N.,& Marinković, A.. (2019). Photocatalysis of carbofuran: comparison of ZnO and TiO2 efficiency. in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019
Leskovac : Faculty of Technology., 92.
https://hdl.handle.net/21.15107/rcub_technorep_7317

Tomašević A, Mijin D, Gašić S, Prlainović N, Marinković A. Photocatalysis of carbofuran: comparison of ZnO and TiO2 efficiency. in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019. 2019;:92.
https://hdl.handle.net/21.15107/rcub_technorep_7317 .

Tomašević, Anđelka, Mijin, Dušan, Gašić, Slavica, Prlainović, Nevena, Marinković, Aleksandar, "Photocatalysis of carbofuran: comparison of ZnO and TiO2 efficiency" in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019 (2019):92,
https://hdl.handle.net/21.15107/rcub_technorep_7317 .

TY  - CONF
AU  - Tomašević, Anđelka
AU  - Petrović, Slobodan
AU  - Mijin, Dušan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7307
PB  - Leskovac : Faculty of Technology
C3  - Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019
T1  - Photochemical processes for removal of carbamate pesticides from water
EP  - 34
SP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7307
ER  - 

@conference{
author = "Tomašević, Anđelka and Petrović, Slobodan and Mijin, Dušan",
year = "2019",
publisher = "Leskovac : Faculty of Technology",
journal = "Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019",
title = "Photochemical processes for removal of carbamate pesticides from water",
pages = "34-33",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7307"
}

Tomašević, A., Petrović, S.,& Mijin, D.. (2019). Photochemical processes for removal of carbamate pesticides from water. in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019
Leskovac : Faculty of Technology., 33-34.
https://hdl.handle.net/21.15107/rcub_technorep_7307

Tomašević A, Petrović S, Mijin D. Photochemical processes for removal of carbamate pesticides from water. in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019. 2019;:33-34.
https://hdl.handle.net/21.15107/rcub_technorep_7307 .

Tomašević, Anđelka, Petrović, Slobodan, Mijin, Dušan, "Photochemical processes for removal of carbamate pesticides from water" in Book of abstracts / 13th Symposium with international participation "Novel Technologies and Economic Development" Leskovac, October, 18-19, 2019 (2019):33-34,
https://hdl.handle.net/21.15107/rcub_technorep_7307 .

TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Marinković, Aleksandar
AU  - Cvijetić, Ilija
AU  - Gašić, Slavica
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4295
AB  - Photocatalytic degradation of a model compound of the carbamate insecticide carbofuran in water was studied using polychromatic light and ZnO and TiO2 catalysts. The influence of operational parameters, such as reaction time and initial carbofuran concentration, on photocatalytic degradation was studied. A pseudo-first-order kinetic model was established and an almost complete removal of 88.4 mg L-1 of carbofuran occurred within 2 h under optimized conditions. The reactions were examined by UV spectroscopy and high performance liquid chromatography (HPLC). In addition, the photocatalytic efficiencies of ZnO and TiO2 were compared under the same reaction conditions.
AB  - Proučavana je fotokatalitička degradacija model jedinjenja karbamatnog insekticida karbofurana u vodi, u prisustvu polihromatske svetlosti i katalizatora ZnO i TiO2. Ispitivan je uticaj reakcionih parametara, kao što su vreme reakcije i početna koncentracija karbofurana, na fotokatalitičku degradaciju. Ustanovljeno je da je reakcija bila pseudo-prvog reda i primenom optimalnih uslova skoro potpuno uklanjanje 88,4 mg L-1 karbofurana dogodilo se u toku 2 sata. Reakcije su praćene primenom UV spektroskopije i tečne hromatografije visokih performansi (HPLC). Naknadno, upoređena je fotokatalitička efikasnost katalizatora ZnO i TiO2 primenom identičnih reakcionih uslova.
PB  - Institute of Pesticides and Environmental Protection
T2  - Pesticidi i fitomedicina
T1  - Photocatalytic degradation of carbamate insecticides: Effect of different parameters
T1  - Fotokatalitička degradacija karbamatnih insekticida - efekti različitih parametara
EP  - 200
IS  - 3-4
SP  - 193
VL  - 34
DO  - 10.2298/PIF1904193T
ER  - 

@article{
author = "Tomašević, Anđelka and Mijin, Dušan and Marinković, Aleksandar and Cvijetić, Ilija and Gašić, Slavica",
year = "2019",
abstract = "Photocatalytic degradation of a model compound of the carbamate insecticide carbofuran in water was studied using polychromatic light and ZnO and TiO2 catalysts. The influence of operational parameters, such as reaction time and initial carbofuran concentration, on photocatalytic degradation was studied. A pseudo-first-order kinetic model was established and an almost complete removal of 88.4 mg L-1 of carbofuran occurred within 2 h under optimized conditions. The reactions were examined by UV spectroscopy and high performance liquid chromatography (HPLC). In addition, the photocatalytic efficiencies of ZnO and TiO2 were compared under the same reaction conditions., Proučavana je fotokatalitička degradacija model jedinjenja karbamatnog insekticida karbofurana u vodi, u prisustvu polihromatske svetlosti i katalizatora ZnO i TiO2. Ispitivan je uticaj reakcionih parametara, kao što su vreme reakcije i početna koncentracija karbofurana, na fotokatalitičku degradaciju. Ustanovljeno je da je reakcija bila pseudo-prvog reda i primenom optimalnih uslova skoro potpuno uklanjanje 88,4 mg L-1 karbofurana dogodilo se u toku 2 sata. Reakcije su praćene primenom UV spektroskopije i tečne hromatografije visokih performansi (HPLC). Naknadno, upoređena je fotokatalitička efikasnost katalizatora ZnO i TiO2 primenom identičnih reakcionih uslova.",
publisher = "Institute of Pesticides and Environmental Protection",
journal = "Pesticidi i fitomedicina",
title = "Photocatalytic degradation of carbamate insecticides: Effect of different parameters, Fotokatalitička degradacija karbamatnih insekticida - efekti različitih parametara",
pages = "200-193",
number = "3-4",
volume = "34",
doi = "10.2298/PIF1904193T"
}

Tomašević, A., Mijin, D., Marinković, A., Cvijetić, I.,& Gašić, S.. (2019). Photocatalytic degradation of carbamate insecticides: Effect of different parameters. in Pesticidi i fitomedicina
Institute of Pesticides and Environmental Protection., 34(3-4), 193-200.
https://doi.org/10.2298/PIF1904193T

Tomašević A, Mijin D, Marinković A, Cvijetić I, Gašić S. Photocatalytic degradation of carbamate insecticides: Effect of different parameters. in Pesticidi i fitomedicina. 2019;34(3-4):193-200.
doi:10.2298/PIF1904193T .

Tomašević, Anđelka, Mijin, Dušan, Marinković, Aleksandar, Cvijetić, Ilija, Gašić, Slavica, "Photocatalytic degradation of carbamate insecticides: Effect of different parameters" in Pesticidi i fitomedicina, 34, no. 3-4 (2019):193-200,
https://doi.org/10.2298/PIF1904193T . .

TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Petrović, Slobodan
AU  - Mijin, Dušan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4269
AB  - A large number of pesticide active ingredients have been registered and marketed for pest control purposes around the world. Most pesticides, including carbamates are resistant to chemical and natural photochemical degradation, so that developing adequate methods for remediation of contaminated waters is a priority. There are different methods for removing carbamate pesticide residues from water, and photodegradation methods are discussed in this study. According to literature data, the most beneficial photochemical processes for removal of pesticides from water are two well-known Advanced Oxidation Processes: heterogeneous photocatalysis with semiconductor oxides TiO2 and ZnO, and homogeneous photo-Fenton treatment, as well as direct UV photolysis. Photochemical investigations may contribute toward our better understanding of carbamate pesticide behavior in the environment, i.e. more information on the degradation time of active ingredients, their activity and environmental fate can be obtained by studying the kinetics of any photochemical reaction.
AB  - U cilju zaštite bilja u svetu je registrovan i u prometu se nalazi veliki broj aktivnih materija pesticida. Većina pesticida, uključujući karbamate je otporna na hemijske i prirodne fotohemijske degradacije i zato je prioritet razvijanje odgovarajućih metoda za prečišćavanje zagađenih voda. Postoje različite metode za odstranjivanje ostataka karbamatnih pesticide iz vode a u ovom radu su razmatrane fotodegradacione metode. Prema literaturnim podacima najkorisniji fotohemijski procesi za uklanjanje pesticide iz vode su dva dobro poznata Viša oksidaciona procesa: heterogena fotokataliza u prisustvu poluprovodnih oksida TiO2 i ZnO, i homogeni foto-Fenton postupak, isto kao i direktna ultraljubičasta fotoliza. Fotohemijska istraživanja doprinose boljem razumevanju ponašanja karbamatnih pesticida u životnoj sredini i puno informacija o vremenu degradacije aktivnih materija, njihovoj aktivnosti i sudbini u životnoj sredini može se dobiti proučavanjem kinetike svake fotohemijske reakcije.
PB  - Univerzitet u Nišu - Tehnološki fakultet, Leskovac
T2  - Advanced Technologies
T1  - Photochemical processes for removal of carbamate pesticides from water
T1  - Fotohemijski procesi za uklanjanje karbamatnih pesticida iz vode
EP  - 81
IS  - 2
SP  - 72
VL  - 8
DO  - 10.5937/savteh1902072T
ER  - 

@article{
author = "Tomašević, Anđelka and Petrović, Slobodan and Mijin, Dušan",
year = "2019",
abstract = "A large number of pesticide active ingredients have been registered and marketed for pest control purposes around the world. Most pesticides, including carbamates are resistant to chemical and natural photochemical degradation, so that developing adequate methods for remediation of contaminated waters is a priority. There are different methods for removing carbamate pesticide residues from water, and photodegradation methods are discussed in this study. According to literature data, the most beneficial photochemical processes for removal of pesticides from water are two well-known Advanced Oxidation Processes: heterogeneous photocatalysis with semiconductor oxides TiO2 and ZnO, and homogeneous photo-Fenton treatment, as well as direct UV photolysis. Photochemical investigations may contribute toward our better understanding of carbamate pesticide behavior in the environment, i.e. more information on the degradation time of active ingredients, their activity and environmental fate can be obtained by studying the kinetics of any photochemical reaction., U cilju zaštite bilja u svetu je registrovan i u prometu se nalazi veliki broj aktivnih materija pesticida. Većina pesticida, uključujući karbamate je otporna na hemijske i prirodne fotohemijske degradacije i zato je prioritet razvijanje odgovarajućih metoda za prečišćavanje zagađenih voda. Postoje različite metode za odstranjivanje ostataka karbamatnih pesticide iz vode a u ovom radu su razmatrane fotodegradacione metode. Prema literaturnim podacima najkorisniji fotohemijski procesi za uklanjanje pesticide iz vode su dva dobro poznata Viša oksidaciona procesa: heterogena fotokataliza u prisustvu poluprovodnih oksida TiO2 i ZnO, i homogeni foto-Fenton postupak, isto kao i direktna ultraljubičasta fotoliza. Fotohemijska istraživanja doprinose boljem razumevanju ponašanja karbamatnih pesticida u životnoj sredini i puno informacija o vremenu degradacije aktivnih materija, njihovoj aktivnosti i sudbini u životnoj sredini može se dobiti proučavanjem kinetike svake fotohemijske reakcije.",
publisher = "Univerzitet u Nišu - Tehnološki fakultet, Leskovac",
journal = "Advanced Technologies",
title = "Photochemical processes for removal of carbamate pesticides from water, Fotohemijski procesi za uklanjanje karbamatnih pesticida iz vode",
pages = "81-72",
number = "2",
volume = "8",
doi = "10.5937/savteh1902072T"
}

Tomašević, A., Petrović, S.,& Mijin, D.. (2019). Photochemical processes for removal of carbamate pesticides from water. in Advanced Technologies
Univerzitet u Nišu - Tehnološki fakultet, Leskovac., 8(2), 72-81.
https://doi.org/10.5937/savteh1902072T

Tomašević A, Petrović S, Mijin D. Photochemical processes for removal of carbamate pesticides from water. in Advanced Technologies. 2019;8(2):72-81.
doi:10.5937/savteh1902072T .

Tomašević, Anđelka, Petrović, Slobodan, Mijin, Dušan, "Photochemical processes for removal of carbamate pesticides from water" in Advanced Technologies, 8, no. 2 (2019):72-81,
https://doi.org/10.5937/savteh1902072T . .

TY  - JOUR
AU  - Dugandžić, Ana M.
AU  - Tomašević, Anđelka
AU  - Dabić, Dunja M.
AU  - Šekuljica, Nataša
AU  - Radišić, Marina
AU  - Petrović, Slobodan
AU  - Mijin, Dušan
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3892
AB  - Nicosulfuron, a sulfonylurea herbicide, was subjected to different Fenton reactions at pH of a nicosulfuron aqueous solution (pH 5). Usually, the optimal pH for the Fenton reaction is between 3 and 4, but the addition of acids is not environmentally acceptable. This is the reason why the reactions were performed at a higher pH value than usual. So, classical Fenton and Fenton-like reactions were applied as well as phot-Fenton and photo-Fenton-like reactions. In addition, microwave Fenton and Fenton-like reactions were used in nicosulfuron degradation. Influences of Fe2+ and Fe3+ concentrations, as well as hydrogen peroxide concentrations, were studied The Fenton reaction was much faster and more efficient than the Fenton-like reaction, while the photo-Fenton reaction proceeded much faster and more efficiently than the Fenton reaction. The microwave-Fenton and microwave-Fenton-like reactions proceeded with increased efficiency in comparison to the Fenton and Fenton-like reactions. The phytotoxicity and acute toxicity of the reaction products of nicosulfuron oxidation by the photo-Fenton reaction were analyzed The toxicity testing of nicosulfuron treatment by photo-Fenton process showed a decrease in phytotoxicity, while the acute toxicity tests showed that the samples after treatment had lower toxicity.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Degradation of nicosulfuron using fenton and fenton-like reactions
EP  - 208
IS  - 3
SP  - 201
VL  - 24
DO  - 10.2298/CICEQ170617032D
ER  - 

@article{
author = "Dugandžić, Ana M. and Tomašević, Anđelka and Dabić, Dunja M. and Šekuljica, Nataša and Radišić, Marina and Petrović, Slobodan and Mijin, Dušan",
year = "2018",
abstract = "Nicosulfuron, a sulfonylurea herbicide, was subjected to different Fenton reactions at pH of a nicosulfuron aqueous solution (pH 5). Usually, the optimal pH for the Fenton reaction is between 3 and 4, but the addition of acids is not environmentally acceptable. This is the reason why the reactions were performed at a higher pH value than usual. So, classical Fenton and Fenton-like reactions were applied as well as phot-Fenton and photo-Fenton-like reactions. In addition, microwave Fenton and Fenton-like reactions were used in nicosulfuron degradation. Influences of Fe2+ and Fe3+ concentrations, as well as hydrogen peroxide concentrations, were studied The Fenton reaction was much faster and more efficient than the Fenton-like reaction, while the photo-Fenton reaction proceeded much faster and more efficiently than the Fenton reaction. The microwave-Fenton and microwave-Fenton-like reactions proceeded with increased efficiency in comparison to the Fenton and Fenton-like reactions. The phytotoxicity and acute toxicity of the reaction products of nicosulfuron oxidation by the photo-Fenton reaction were analyzed The toxicity testing of nicosulfuron treatment by photo-Fenton process showed a decrease in phytotoxicity, while the acute toxicity tests showed that the samples after treatment had lower toxicity.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Degradation of nicosulfuron using fenton and fenton-like reactions",
pages = "208-201",
number = "3",
volume = "24",
doi = "10.2298/CICEQ170617032D"
}

Dugandžić, A. M., Tomašević, A., Dabić, D. M., Šekuljica, N., Radišić, M., Petrović, S.,& Mijin, D.. (2018). Degradation of nicosulfuron using fenton and fenton-like reactions. in Chemical Industry & Chemical Engineering Quarterly
Savez hemijskih inženjera, Beograd., 24(3), 201-208.
https://doi.org/10.2298/CICEQ170617032D

Dugandžić AM, Tomašević A, Dabić DM, Šekuljica N, Radišić M, Petrović S, Mijin D. Degradation of nicosulfuron using fenton and fenton-like reactions. in Chemical Industry & Chemical Engineering Quarterly. 2018;24(3):201-208.
doi:10.2298/CICEQ170617032D .

Dugandžić, Ana M., Tomašević, Anđelka, Dabić, Dunja M., Šekuljica, Nataša, Radišić, Marina, Petrović, Slobodan, Mijin, Dušan, "Degradation of nicosulfuron using fenton and fenton-like reactions" in Chemical Industry & Chemical Engineering Quarterly, 24, no. 3 (2018):201-208,
https://doi.org/10.2298/CICEQ170617032D . .

TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Marinković, Aleksandar
AU  - Radišić, Marina
AU  - Prlainović, Nevena
AU  - Đurović-Pejčev, Rada
AU  - Gašić, Slavica
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3711
AB  - A comparative study on photocatalytic degradation of the pesticide carbofuran and its commercial product Furadan 35-ST in an aqueous suspension of ZnO, irradiated by long-wave light (315-400 nm), is presented in this study. In order to assess the effects of inert ingredients present in the commercial product Furadan 35-ST, non-competitive and competitive adsorption and kinetic studies of carbofuran degradation processes were conducted. A higher photochemical degradation rate was found for pure carbofuran in comparison to a two-component system, carbofuran and single addition of ingredients at appropriate concentrations, and the commercial product Furadan 35-ST. The overall effect of inert ingredients was evaluated from a competitive study using the model system of Furadan 35-ST. The results of a mineralization study, obtained by ion chromatography (IC) and total organic carbon (TOC) analyses, revealed the formation of acetate, oxalate, and formate ions. Photodegradation products of carbofuran, three of them detected for the first time, were identified based on high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) and gas chromatography-mass spectrometry (GC-MS) results, and their photodegradation pathways were proposed.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - The photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredients
EP  - 13822
IS  - 15
SP  - 13808
VL  - 24
DO  - 10.1007/s11356-017-8949-x
ER  - 

@article{
author = "Tomašević, Anđelka and Mijin, Dušan and Marinković, Aleksandar and Radišić, Marina and Prlainović, Nevena and Đurović-Pejčev, Rada and Gašić, Slavica",
year = "2017",
abstract = "A comparative study on photocatalytic degradation of the pesticide carbofuran and its commercial product Furadan 35-ST in an aqueous suspension of ZnO, irradiated by long-wave light (315-400 nm), is presented in this study. In order to assess the effects of inert ingredients present in the commercial product Furadan 35-ST, non-competitive and competitive adsorption and kinetic studies of carbofuran degradation processes were conducted. A higher photochemical degradation rate was found for pure carbofuran in comparison to a two-component system, carbofuran and single addition of ingredients at appropriate concentrations, and the commercial product Furadan 35-ST. The overall effect of inert ingredients was evaluated from a competitive study using the model system of Furadan 35-ST. The results of a mineralization study, obtained by ion chromatography (IC) and total organic carbon (TOC) analyses, revealed the formation of acetate, oxalate, and formate ions. Photodegradation products of carbofuran, three of them detected for the first time, were identified based on high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) and gas chromatography-mass spectrometry (GC-MS) results, and their photodegradation pathways were proposed.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "The photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredients",
pages = "13822-13808",
number = "15",
volume = "24",
doi = "10.1007/s11356-017-8949-x"
}

Tomašević, A., Mijin, D., Marinković, A., Radišić, M., Prlainović, N., Đurović-Pejčev, R.,& Gašić, S.. (2017). The photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredients. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 24(15), 13808-13822.
https://doi.org/10.1007/s11356-017-8949-x

Tomašević A, Mijin D, Marinković A, Radišić M, Prlainović N, Đurović-Pejčev R, Gašić S. The photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredients. in Environmental Science and Pollution Research. 2017;24(15):13808-13822.
doi:10.1007/s11356-017-8949-x .

Tomašević, Anđelka, Mijin, Dušan, Marinković, Aleksandar, Radišić, Marina, Prlainović, Nevena, Đurović-Pejčev, Rada, Gašić, Slavica, "The photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredients" in Environmental Science and Pollution Research, 24, no. 15 (2017):13808-13822,
https://doi.org/10.1007/s11356-017-8949-x . .

TY  - JOUR
AU  - Dugandžić, Ana M.
AU  - Tomašević, Anđelka
AU  - Radišić, Marina
AU  - Šekuljica, Nataša
AU  - Mijin, Dušan
AU  - Petrović, Slobodan
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3701
AB  - In the present study, the photocatalytic degradation of nicosulfuron, using TiO2 as a catalyst under UV light (315-400 nm), was studied. The optimization of the nicosulfuron photodegradation was performed. It was found that the optimal concentration of the catalyst was 1 g L-1 at concentration of nicosulfuron solution of 20 mg L-1 while the highest reaction rate was obtained using 2 g L-1. The degradation rate was the highest at pH .= 5.0. Effects of anions (Cl-, SO42- NO3- and F-) and cations (Na+, Ca2+, Al3+) were investigated. In addition, the influence of isopropanol, acetone, and hydrogen peroxide was studied. It was shown that the photocatalytic degradation is mainly due to the reaction of nicosulfuron with (OH)-O-center dot in solution. Also, liquid chromatography coupled with mass spectrometry (HPLC-MS) was used to identify intermediates during the photocatalytic degradation of nicosulfuron. the mineralization was monitored with ion chromatography (IC) and total organic carbon (TOC) analysis. Although 100% HPLC removal of nicosulfuron was achieved, only 69% TOC removal after 90 min was recorded. The results of ion chromatography showed that the mineralization resulted in ammonium and nitrate ions during the process. The phytotoxicity experiments using mung bean seeds showed a reduction in phytotoxicity.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Photochemistry and Photobiology A-Chemistry
T1  - Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron
EP  - 155
SP  - 146
VL  - 336
DO  - 10.1016/j.jphotochem.2016.12.031
ER  - 

@article{
author = "Dugandžić, Ana M. and Tomašević, Anđelka and Radišić, Marina and Šekuljica, Nataša and Mijin, Dušan and Petrović, Slobodan",
year = "2017",
abstract = "In the present study, the photocatalytic degradation of nicosulfuron, using TiO2 as a catalyst under UV light (315-400 nm), was studied. The optimization of the nicosulfuron photodegradation was performed. It was found that the optimal concentration of the catalyst was 1 g L-1 at concentration of nicosulfuron solution of 20 mg L-1 while the highest reaction rate was obtained using 2 g L-1. The degradation rate was the highest at pH .= 5.0. Effects of anions (Cl-, SO42- NO3- and F-) and cations (Na+, Ca2+, Al3+) were investigated. In addition, the influence of isopropanol, acetone, and hydrogen peroxide was studied. It was shown that the photocatalytic degradation is mainly due to the reaction of nicosulfuron with (OH)-O-center dot in solution. Also, liquid chromatography coupled with mass spectrometry (HPLC-MS) was used to identify intermediates during the photocatalytic degradation of nicosulfuron. the mineralization was monitored with ion chromatography (IC) and total organic carbon (TOC) analysis. Although 100% HPLC removal of nicosulfuron was achieved, only 69% TOC removal after 90 min was recorded. The results of ion chromatography showed that the mineralization resulted in ammonium and nitrate ions during the process. The phytotoxicity experiments using mung bean seeds showed a reduction in phytotoxicity.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Photochemistry and Photobiology A-Chemistry",
title = "Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron",
pages = "155-146",
volume = "336",
doi = "10.1016/j.jphotochem.2016.12.031"
}

Dugandžić, A. M., Tomašević, A., Radišić, M., Šekuljica, N., Mijin, D.,& Petrović, S.. (2017). Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron. in Journal of Photochemistry and Photobiology A-Chemistry
Elsevier Science Sa, Lausanne., 336, 146-155.
https://doi.org/10.1016/j.jphotochem.2016.12.031

Dugandžić AM, Tomašević A, Radišić M, Šekuljica N, Mijin D, Petrović S. Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron. in Journal of Photochemistry and Photobiology A-Chemistry. 2017;336:146-155.
doi:10.1016/j.jphotochem.2016.12.031 .

Dugandžić, Ana M., Tomašević, Anđelka, Radišić, Marina, Šekuljica, Nataša, Mijin, Dušan, Petrović, Slobodan, "Effect of inorganic ions, photosensitisers and scavengers on the photocatalytic degradation of nicosulfuron" in Journal of Photochemistry and Photobiology A-Chemistry, 336 (2017):146-155,
https://doi.org/10.1016/j.jphotochem.2016.12.031 . .

TY  - CONF
AU  - Radišić, Marina
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Marinković, Aleksandar
AU  - Tolić, Ljiljana
AU  - Laušević, Mila
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7247
AB  - Photocatalytic degradation of the methomyl pesticide in aqueous suspension
of TiO2 using an Osram ultra-vitalux® lamp (315-400 nm) was investigated.
The effect of parameters such as initial concentration of catalyst, initial
methomyl concentration, and pH were studied. Complete removal of
methomyl was achieved but mineralization of organic carbon was
incomplete indicating the formation of methomyl degradation products.
Liquid chromatography tandem mass spectrometry technique was used in
order to identify the methomyl degradation products and three major
degradation products have been identified.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - Physical Chemistry 2016 : proceedings / 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 26-30 September 2016
T1  - Identification of methomyl photocatalytic degradation products
EP  - 234
SP  - 231
VL  - 1
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7247
ER  - 

@conference{
author = "Radišić, Marina and Tomašević, Anđelka and Mijin, Dušan and Marinković, Aleksandar and Tolić, Ljiljana and Laušević, Mila",
year = "2016",
abstract = "Photocatalytic degradation of the methomyl pesticide in aqueous suspension
of TiO2 using an Osram ultra-vitalux® lamp (315-400 nm) was investigated.
The effect of parameters such as initial concentration of catalyst, initial
methomyl concentration, and pH were studied. Complete removal of
methomyl was achieved but mineralization of organic carbon was
incomplete indicating the formation of methomyl degradation products.
Liquid chromatography tandem mass spectrometry technique was used in
order to identify the methomyl degradation products and three major
degradation products have been identified.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "Physical Chemistry 2016 : proceedings / 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 26-30 September 2016",
title = "Identification of methomyl photocatalytic degradation products",
pages = "234-231",
volume = "1",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7247"
}

Radišić, M., Tomašević, A., Mijin, D., Marinković, A., Tolić, L.,& Laušević, M.. (2016). Identification of methomyl photocatalytic degradation products. in Physical Chemistry 2016 : proceedings / 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 26-30 September 2016
Belgrade : Society of Physical Chemists of Serbia., 1, 231-234.
https://hdl.handle.net/21.15107/rcub_technorep_7247

Radišić M, Tomašević A, Mijin D, Marinković A, Tolić L, Laušević M. Identification of methomyl photocatalytic degradation products. in Physical Chemistry 2016 : proceedings / 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 26-30 September 2016. 2016;1:231-234.
https://hdl.handle.net/21.15107/rcub_technorep_7247 .

Radišić, Marina, Tomašević, Anđelka, Mijin, Dušan, Marinković, Aleksandar, Tolić, Ljiljana, Laušević, Mila, "Identification of methomyl photocatalytic degradation products" in Physical Chemistry 2016 : proceedings / 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 26-30 September 2016, 1 (2016):231-234,
https://hdl.handle.net/21.15107/rcub_technorep_7247 .

TY  - JOUR
AU  - Tomašević, Anđelka
AU  - Mijin, Dušan
AU  - Gašić, Slavica
AU  - Kiss, Erno
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2652
AB  - The photocatalytic degradation of the insecticide methomyl in water using TiO2 Merck Eusolex (R) T (anatase) under Osram ultra-vitalux (R) lamp light (315-400 nm, 300W) was studied. The effect of the operational parameters, such as initial concentration of catalyst, initial methomyl concentration, initial salt concentration (NaCl), and pH, was studied. The optimal concentration of catalyst was found to be 2.0 g/L. Using the Langmuir-Hinshelwood mechanism as a base, a pseudo-first-order kinetic model was illustrated and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (K-MT = 0.079 L/mg and k
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension
EP  - 4349
IS  - 22-24
SP  - 4342
VL  - 52
DO  - 10.1080/19443994.2013.803321
ER  - 

@article{
author = "Tomašević, Anđelka and Mijin, Dušan and Gašić, Slavica and Kiss, Erno",
year = "2014",
abstract = "The photocatalytic degradation of the insecticide methomyl in water using TiO2 Merck Eusolex (R) T (anatase) under Osram ultra-vitalux (R) lamp light (315-400 nm, 300W) was studied. The effect of the operational parameters, such as initial concentration of catalyst, initial methomyl concentration, initial salt concentration (NaCl), and pH, was studied. The optimal concentration of catalyst was found to be 2.0 g/L. Using the Langmuir-Hinshelwood mechanism as a base, a pseudo-first-order kinetic model was illustrated and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (K-MT = 0.079 L/mg and k",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension",
pages = "4349-4342",
number = "22-24",
volume = "52",
doi = "10.1080/19443994.2013.803321"
}

Tomašević, A., Mijin, D., Gašić, S.,& Kiss, E.. (2014). The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 52(22-24), 4342-4349.
https://doi.org/10.1080/19443994.2013.803321

Tomašević A, Mijin D, Gašić S, Kiss E. The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension. in Desalination and Water Treatment. 2014;52(22-24):4342-4349.
doi:10.1080/19443994.2013.803321 .

Tomašević, Anđelka, Mijin, Dušan, Gašić, Slavica, Kiss, Erno, "The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension" in Desalination and Water Treatment, 52, no. 22-24 (2014):4342-4349,
https://doi.org/10.1080/19443994.2013.803321 . .