@article{
author = "Trueba, Alondra Torres and Radović, Ivona and Zevenbergen, John F. and Kroon, Maaike C. and Peters, Cor J.",
year = "2012",
abstract = "The kinetics of formation of H-2-TBAB semi-clathrate hydrates was studied in this work in order to elucidate their potential for H-2 storage. The influence of pressure (5-16 MPa), TBAB concentration (2.6 mol% and 3.7 mol%) and formation method (T-cycle method and T-constant method) on the hydrate nucleation, hydrate growth and H-2 storage capacity was determined. The results showed that kinetics is favored at higher pressures and solute concentrations. Additionally, the hydrate phase formation and dissociation was study for a solution of 2.6 mol% of TBAB in situ by using the Raman spectroscopy technique. The inclusion of H-2 in the semi-hydrate phase was confirmed. The results showed the importance of H-2 mass transfer on the storage capacity of the H-2-TBAB semi-hydrates.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "International Journal of Hydrogen Energy",
title = "Kinetics measurements and in situ Raman spectroscopy of formation of hydrogen-tetrabutylammonium bromide semi-hydrates",
pages = "5797-5790",
number = "7",
volume = "37",
doi = "10.1016/j.ijhydene.2011.12.053"
}